#------------------------------------------------------------------------------ #$Date: 2018-01-23 18:47:37 +0200 (Tue, 23 Jan 2018) $ #$Revision: 362 $ #$URL: svn://172.16.1.111/rod/cif/1/00/00/1000012.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000012 loop_ _publ_author_name 'El Mendili, Y' 'Grasset, F.' 'Randrianantoandro, N' 'Nerambourg, N' 'Greneche, Jm' 'Bardeau, Jf' _publ_section_title ; Improvement of Thermal Stability of Maghemite Nanoparticles Coated with Oleic Acid and Oleylamine Molecules: Investigations under Laser Irradiation ; _journal_name_full 'Physical Chemistry C' _journal_page_first 10662 _journal_page_last 10668 _journal_volume 119 _journal_year 2015 _chemical_compound_source 'Commercial product' _chemical_formula_structural 'C18 H32 O2' _chemical_formula_sum 'C18 H32 O2' _chemical_name_common 'linoleic acid' _chemical_name_systematic '(9Z,12Z)-9,12-octadecadienoic acid' _space_group_IT_number 14 _cell_angle_alpha 90.00000 _cell_angle_beta 109.3800 _cell_angle_gamma 90.00000 _cell_formula_units_Z 3 _cell_length_a 42.98 _cell_length_b 4.632 _cell_length_c 9.377 _[local]_database_code_rod 10000009 _raman_determination_method experimental _[local]_chemical_compound_color Yellow _[local]_chemical_compound_state liquid _raman_measurement_device.location 'IMMM Maine university' _raman_measurement_device.company 'HORIBA Jobin Yvon' _raman_measurement_device.model T64000 _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 100 _raman_measurement_device.microscope_numerical_aperture 0.90 _raman_measurement_device.excitation_laser_type Argon-Krypton _raman_measurement_device.excitation_laser_wavelength 514 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 2 _raman_measurement_device.power_on_sample 2 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 0.8 _raman_measurement_device.diffraction_grating 600 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 600 _raman_measurement.range_min 82.1123 _raman_measurement.range_max 3821.91 _rod_data_source.file oleic.rod _rod_data_source.block 1000009 _rod_database.code 1000012 loop_ _raman_complementary.id _raman_complementary.method 1 EDX loop_ _raman_prediction.id _raman_prediction.method _raman_prediction.active_bands _raman_prediction.mode_count 1 DFT 'A1 + E + T1' 3 loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 Silicon_wafer 2 Diamond loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 5000081 COD http://www.crystallography.net/cod/5000081.html ; no XRD analysis data. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 82.1123 4200 84.0068 4232.26 85.9014 4264.52 87.7959 4202.79 89.6904 4029.9 91.585 3857.02 93.4795 3826.72 95.374 3808.99 97.2685 3789.62 99.1631 3767.54 101.058 3745.47 102.952 3775.56 104.847 3815.37 106.741 3837.2 108.636 3818.26 110.53 3799.32 112.425 3765.44 114.319 3727.15 116.214 3683.38 118.108 3622.16 120.003 3560.94 121.897 3503.34 123.792 3447.26 125.686 3388.11 127.581 3314.57 129.476 3241.03 131.37 3170.79 133.265 3102.35 135.159 3039.76 137.054 3020.76 138.948 3001.76 140.843 2961.69 142.737 2907.05 144.632 2855.19 146.526 2842.91 148.421 2830.63 150.315 2799.03 152.21 2751.07 154.104 2703.16 155.999 2657.95 157.893 2612.75 159.788 2593.55 161.683 2600.69 163.577 2607.83 165.472 2580.86 167.366 2553.06 169.261 2528.54 171.155 2507.88 173.05 2487.23 174.944 2474.79 176.839 2462.87 178.733 2452.13 180.628 2442.98 182.522 2433.83 184.417 2427.58 186.311 2421.61 188.206 2427.12 190.101 2450.21 191.995 2473.3 193.89 2492.53 195.784 2511.24 197.679 2522.56 199.573 2521.36 201.468 2520.16 203.362 2554.01 205.257 2593.46 207.151 2619.42 209.046 2620.62 210.94 2621.82 212.835 2620.99 214.729 2619.79 216.624 2624.97 218.518 2642.54 220.413 2660.1 222.308 2676.34 224.202 2692.32 226.097 2696.77 227.991 2677.99 229.886 2659.2 231.78 2659.98 233.675 2664.78 235.569 2666.55 237.464 2662.15 239.358 2657.75 241.253 2683.56 243.147 2715.58 245.042 2726.39 246.936 2694.35 248.831 2662.31 250.725 2647.97 252.62 2637.16 254.515 2628.51 256.409 2624.1 258.304 2619.69 260.198 2605.79 262.093 2590.14 263.987 2568.56 265.882 2536.06 267.776 2503.56 269.671 2470.7 271.565 2437.78 273.46 2418.19 275.354 2421.4 277.249 2424.62 279.143 2425.35 281.038 2425.76 282.932 2412.28 284.827 2377.28 286.722 2342.29 288.616 2333.9 290.511 2328.27 292.405 2319.93 294.3 2307.85 296.194 2295.77 298.089 2279.16 299.983 2262.25 301.878 2262.5 303.772 2283.45 305.667 2304.41 307.561 2281.09 309.456 2256.49 311.35 2244.99 313.245 2247.01 315.139 2248.83 317.034 2235.92 318.929 2223.01 320.823 2213.98 322.718 2208.32 324.612 2202.67 326.507 2197.01 328.401 2191.36 330.296 2200.32 332.19 2219.72 334.085 2234.65 335.979 2213.21 337.874 2191.78 339.768 2179.1 341.663 2171.41 343.557 2168.24 345.452 2187.67 347.346 2207.11 349.241 2203.97 351.136 2191.01 353.03 2184.04 354.925 2197.42 356.819 2210.79 358.714 2224.48 360.608 2238.27 362.503 2246.45 364.397 2241.17 366.292 2235.9 368.186 2223.56 370.081 2209.76 371.975 2203.08 373.87 2208.76 375.764 2214.45 377.659 2215.73 379.553 2216.55 381.448 2213.04 383.343 2204.1 385.237 2195.16 387.132 2203.79 389.026 2212.74 390.921 2216.15 392.815 2214.52 394.71 2211.82 396.604 2193.9 398.499 2175.98 400.393 2173.72 402.288 2181.46 404.182 2184.07 406.077 2158.8 407.971 2133.52 409.866 2136.88 411.76 2152.38 413.655 2166.45 415.55 2176.24 417.444 2186.03 419.339 2189.96 421.233 2192.41 423.128 2196.71 425.022 2204.47 426.917 2212.23 428.811 2189.44 430.706 2163.29 432.6 2155.3 434.495 2169.2 436.389 2182.89 438.284 2167.76 440.178 2152.62 442.073 2156.82 443.967 2176.06 445.862 2195.74 447.757 2218.67 449.651 2241.6 451.546 2245.12 453.44 2239.38 455.335 2232.2 457.229 2220.31 459.124 2208.42 461.018 2236.37 462.913 2274.5 464.807 2292.25 466.702 2273.37 468.596 2254.5 470.491 2270.77 472.385 2290.07 474.28 2308.77 476.175 2326.83 478.069 2342.28 479.964 2307.76 481.858 2273.24 483.753 2261.77 485.647 2264.65 487.542 2268.59 489.436 2277.23 491.331 2285.86 493.225 2296.98 495.12 2308.92 497.014 2318.46 498.909 2322.99 500.803 2327.52 502.698 2293.72 504.592 2255.4 506.487 2234.42 508.382 2233.19 510.276 2232.87 512.171 2253.9 514.065 2274.94 515.96 2272.57 517.854 2255.65 519.749 2246.78 521.643 2271.56 523.538 2296.34 525.432 2282.88 527.327 2258.1 529.221 2242.29 531.116 2243.12 533.01 2243.94 534.905 2257.84 536.799 2272.72 538.694 2271.12 540.589 2253.74 542.483 2238.39 544.378 2242.53 546.272 2246.67 548.167 2233.13 550.061 2211.17 551.956 2192.82 553.85 2184.54 555.745 2176.25 557.639 2191.54 559.534 2211.03 561.428 2229.61 563.323 2247.02 565.217 2263.67 567.112 2250.39 569.006 2237.11 570.901 2264.44 572.796 2317.17 574.69 2352.22 576.585 2319.4 578.479 2286.59 580.374 2317.85 582.268 2365.21 584.163 2389.93 586.057 2379.53 587.952 2369.14 589.846 2378.44 591.741 2388.01 593.635 2391.76 595.53 2391.34 597.424 2392.73 599.319 2402.3 601.214 2411.88 603.108 2422.76 605.003 2434.02 606.897 2436.1 608.792 2423.17 610.686 2410.25 612.581 2405.91 614.475 2401.74 616.37 2386.15 618.264 2362.37 620.159 2339.83 622.053 2322.7 623.948 2305.58 625.842 2334.36 627.737 2375.29 629.631 2394.87 631.526 2381.92 633.421 2368.98 635.315 2361.45 637.21 2353.92 639.104 2352.53 640.999 2355.04 642.893 2354.79 644.788 2344.74 646.682 2334.69 648.577 2348.67 650.471 2367.52 652.366 2370.19 654.26 2352.6 656.155 2337.25 658.049 2359.47 659.944 2381.69 661.838 2384.78 663.733 2378.49 665.628 2377.37 667.522 2389.12 669.417 2400.87 671.311 2416.41 673.206 2432.37 675.1 2443.29 676.995 2449.59 678.889 2453.05 680.784 2439.18 682.678 2425.31 684.573 2433.52 686.467 2448.65 688.362 2469.58 690.256 2499.87 692.151 2530 694.045 2529.15 695.94 2528.31 697.835 2522.17 699.729 2512.9 701.624 2513.41 703.518 2542.47 705.413 2571.54 707.307 2595.06 709.202 2617.82 711.096 2645.1 712.991 2676.72 714.885 2704 716.78 2704 718.674 2704 720.569 2732.52 722.463 2769.66 724.358 2797.73 726.252 2812.09 728.147 2825.15 730.042 2798.1 731.936 2771.05 733.831 2757.22 735.725 2750.03 737.62 2741.71 739.514 2730.71 741.409 2719.71 743.303 2722.96 745.198 2727.19 747.092 2704.01 748.987 2660.39 750.881 2639.17 752.776 2701.45 754.67 2763.73 756.565 2737.28 758.459 2695.32 760.354 2696.74 762.249 2742.96 764.143 2781.98 766.038 2774.34 767.932 2766.7 769.827 2771.27 771.721 2779.33 773.616 2787.93 775.51 2797.28 777.405 2806.82 779.299 2819.14 781.194 2831.47 783.088 2855.94 784.983 2885.27 786.877 2901.69 788.772 2895.32 790.667 2889.09 792.561 2898.03 794.456 2906.97 796.35 2918.72 798.245 2931.92 800.139 2954.95 802.034 2999.69 803.928 3044.43 805.823 3083.43 807.717 3122.22 809.612 3129.35 811.506 3116.98 813.401 3115.93 815.295 3144.95 817.19 3173.96 819.084 3191.48 820.979 3208.13 822.873 3228.8 824.768 3252.29 826.663 3288.09 828.557 3361.59 830.452 3435.09 832.346 3511.33 834.241 3587.86 836.135 3640.64 838.03 3675.29 839.924 3710.82 841.819 3749.33 843.713 3787.85 845.608 3808.81 847.502 3827.65 849.397 3834.57 851.291 3832 853.186 3826.86 855.081 3812.72 856.975 3798.58 858.87 3793.19 860.764 3788.9 862.659 3797.26 864.553 3815.71 866.448 3831.55 868.342 3838.42 870.237 3845.28 872.131 3838.69 874.026 3830.53 875.92 3788.96 877.815 3721.95 879.709 3670.18 881.604 3666.74 883.498 3663.3 885.393 3685.4 887.288 3709.91 889.182 3706.08 891.077 3682.41 892.971 3662.49 894.866 3653.02 896.76 3643.55 898.655 3673.04 900.549 3704.92 902.444 3725.29 904.338 3738.65 906.233 3743.87 908.127 3730.07 910.022 3716.27 911.916 3663.55 913.811 3610.06 915.705 3574.27 917.6 3547.51 919.495 3510.16 921.389 3452.73 923.284 3396.51 925.178 3380.1 927.073 3363.68 928.967 3372.29 930.862 3390.89 932.756 3407.74 934.651 3422.01 936.545 3432.24 938.44 3401.52 940.334 3370.81 942.229 3365.01 944.123 3366.31 946.018 3383.05 947.912 3417.26 949.807 3442.81 951.702 3422.89 953.596 3402.96 955.491 3411.82 957.385 3425.7 959.28 3450.7 961.174 3484.98 963.069 3518.42 964.963 3549.22 966.858 3580.02 968.752 3639.31 970.647 3700.54 972.541 3688.06 974.436 3632.88 976.33 3572.94 978.225 3503.39 980.119 3434.6 982.014 3389.39 983.909 3344.19 985.803 3332.32 987.698 3332.75 989.592 3333 991.487 3333 993.381 3337.11 995.276 3367.59 997.17 3398.08 999.065 3411.41 1000.96 3421.43 1002.85 3426.47 1004.75 3427.35 1006.64 3446.13 1008.54 3518.53 1010.43 3590.92 1012.33 3669.2 1014.22 3747.74 1016.12 3755.1 1018.01 3726.72 1019.9 3716.55 1021.8 3736.64 1023.69 3753.45 1025.59 3735.53 1027.48 3717.61 1029.38 3707.02 1031.27 3698.27 1033.17 3703.17 1035.06 3721.11 1036.96 3732.23 1038.85 3719.98 1040.74 3707.73 1042.64 3756.01 1044.53 3808.12 1046.43 3822.55 1048.32 3817.29 1050.22 3830.27 1052.11 3873.67 1054.01 3919.04 1055.9 3983.51 1057.8 4047.99 1059.69 4130.7 1061.58 4217.58 1063.48 4285 1065.37 4335.48 1067.27 4387.89 1069.16 4445.87 1071.06 4503.84 1072.95 4504.14 1074.85 4503.26 1076.74 4567.71 1078.64 4659.59 1080.53 4702.36 1082.42 4679.93 1084.32 4647 1086.21 4557.19 1088.11 4467.38 1090 4347.58 1091.9 4223.88 1093.79 4098.24 1095.69 3971.39 1097.58 3848.88 1099.47 3734.7 1101.37 3623.53 1103.26 3549.91 1105.16 3476.28 1107.05 3505.75 1108.95 3560.02 1110.84 3620.51 1112.74 3686.29 1114.63 3742 1116.53 3771.14 1118.42 3799.38 1120.31 3734.42 1122.21 3669.46 1124.1 3589.29 1126 3503.97 1127.89 3436.63 1129.79 3388.42 1131.68 3345.25 1133.58 3319.59 1135.47 3293.92 1137.37 3283.18 1139.26 3273 1141.15 3292.18 1143.05 3323.63 1144.94 3336.83 1146.84 3327.53 1148.73 3320.85 1150.63 3325.28 1152.52 3329.71 1154.42 3356.55 1156.31 3384.94 1158.21 3362.26 1160.1 3315.64 1161.99 3306.69 1163.89 3347.98 1165.78 3384.27 1167.68 3397.15 1169.57 3410.03 1171.47 3449.23 1173.36 3490.58 1175.26 3487.48 1177.15 3463.03 1179.05 3447.86 1180.94 3445.19 1182.83 3447.46 1184.73 3472.38 1186.62 3497.3 1188.52 3479.08 1190.41 3457.7 1192.31 3455.59 1194.2 3462.28 1196.1 3470.54 1197.99 3480.79 1199.88 3484.81 1201.78 3463.85 1203.67 3442.88 1205.57 3429.18 1207.46 3415.79 1209.36 3448.81 1211.25 3500.16 1213.15 3519.75 1215.04 3504.57 1216.94 3497.26 1218.83 3515.14 1220.72 3533.02 1222.62 3557.16 1224.51 3581.3 1226.41 3597.25 1228.3 3610.67 1230.2 3641.35 1232.09 3687.44 1233.99 3719.74 1235.88 3718.84 1237.78 3722.27 1239.67 3792.15 1241.56 3862.02 1243.46 3965.38 1245.35 4075.68 1247.25 4147.35 1249.14 4193.08 1251.04 4283.2 1252.93 4449.69 1254.83 4601.06 1256.72 4658.95 1258.62 4716.84 1260.51 4765.78 1262.4 4813.84 1264.3 4837.92 1266.19 4850.95 1268.09 4841.69 1269.98 4806.17 1271.88 4766.85 1273.77 4715.12 1275.67 4663.33 1277.56 4606.18 1279.46 4549.03 1281.35 4577.17 1283.24 4628.04 1285.14 4698.65 1287.03 4784.23 1288.93 4906.71 1290.82 5098.23 1292.72 5293.89 1294.61 5517.51 1296.51 5741.13 1298.4 5818.53 1300.3 5881.68 1302.19 5842.71 1304.08 5758.74 1305.98 5615.49 1307.87 5407.82 1309.77 5201.52 1311.66 4999.07 1313.56 4800.36 1315.45 4670.67 1317.35 4540.98 1319.24 4464.64 1321.13 4398.61 1323.03 4314.41 1324.92 4219.42 1326.82 4137.79 1328.71 4074.86 1330.61 4007.5 1332.5 3923.26 1334.4 3839.01 1336.29 3783.27 1338.19 3727.53 1340.08 3737.57 1341.97 3764.77 1343.87 3763.21 1345.76 3741.44 1347.66 3733.9 1349.55 3749.33 1351.45 3762.97 1353.34 3768.42 1355.24 3773.87 1357.13 3735.43 1359.03 3695.91 1360.92 3699.67 1362.81 3716.03 1364.71 3731.09 1366.6 3745.18 1368.5 3738.34 1370.39 3696.48 1372.29 3654.69 1374.18 3613.28 1376.08 3571.88 1377.97 3552.72 1379.87 3534.05 1381.76 3528.57 1383.65 3526.75 1385.55 3525.46 1387.44 3524.55 1389.34 3536.04 1391.23 3566.58 1393.13 3596.49 1395.02 3623.87 1396.92 3652.1 1398.81 3774.44 1400.71 3896.79 1402.6 3957.87 1404.49 4005.37 1406.39 4074.99 1408.28 4157.65 1410.18 4229.71 1412.07 4288.22 1413.97 4342.25 1415.86 4382.95 1417.76 4425.51 1419.65 4494.6 1421.54 4563.7 1423.44 4850.83 1425.33 5167.76 1427.23 5603 1429.12 6089.85 1431.02 6566.22 1432.91 7032.66 1434.81 7417.24 1436.7 7635.89 1438.6 7803.97 1440.49 7682.84 1442.38 7561.7 1444.28 7293.35 1446.17 7020.36 1448.07 6815.42 1449.96 6628.59 1451.86 6479.3 1453.75 6353.88 1455.65 6184.43 1457.54 5957.81 1459.44 5717.82 1461.33 5439.73 1463.22 5165.91 1465.12 4938.62 1467.01 4711.33 1468.91 4574.48 1470.8 4446.51 1472.7 4299.47 1474.59 4145.66 1476.49 4052.65 1478.38 4006.13 1480.28 3957.78 1482.17 3906.62 1484.06 3858.15 1485.96 3818.96 1487.85 3782.63 1489.75 3793.71 1491.64 3804.79 1493.54 3789.14 1495.43 3770.22 1497.33 3750.29 1499.22 3729.97 1501.12 3711.19 1503.01 3693.64 1504.9 3687.56 1506.8 3699.12 1508.69 3698.57 1510.59 3657.88 1512.48 3621.98 1514.38 3650.66 1516.27 3679.35 1518.17 3625.27 1520.06 3562.76 1521.96 3582 1523.85 3628.79 1525.74 3647.18 1527.64 3645.79 1529.53 3647.4 1531.43 3652.96 1533.32 3661.71 1535.22 3678.87 1537.11 3689.16 1539.01 3648.31 1540.9 3607.47 1542.79 3607.34 1544.69 3608.74 1546.58 3591.31 1548.48 3569.47 1550.37 3579.73 1552.27 3606.68 1554.16 3620.47 1556.06 3621.4 1557.95 3615.06 1559.85 3595.52 1561.74 3584.98 1563.63 3609.17 1565.53 3630.54 1567.42 3604.92 1569.32 3579.3 1571.21 3637.2 1573.11 3703.34 1575 3702.99 1576.9 3682.02 1578.79 3673.71 1580.69 3673.25 1582.58 3686.26 1584.47 3714.26 1586.37 3724.2 1588.26 3697.6 1590.16 3681.97 1592.05 3713.73 1593.95 3744.97 1595.84 3765.53 1597.74 3786.09 1599.63 3765.53 1601.53 3740.76 1603.42 3734.28 1605.31 3733.35 1607.21 3756.26 1609.1 3793.23 1611 3809.7 1612.89 3805.01 1614.79 3822.86 1616.68 3881.4 1618.58 3932.08 1620.47 3955.05 1622.37 3979.55 1624.26 4019.87 1626.15 4060.19 1628.05 4115.3 1629.94 4171.11 1631.84 4289.49 1633.73 4421.34 1635.63 4617.28 1637.52 4841.77 1639.42 5191.22 1641.31 5637.85 1643.2 6184.47 1645.1 6861.86 1646.99 7587.7 1648.89 8423.4 1650.78 9130.37 1652.68 9249.35 1654.57 9327.37 1656.47 8677.29 1658.36 8027.2 1660.26 7195.33 1662.15 6349.53 1664.04 5796.78 1665.94 5314.79 1667.83 4976.24 1669.73 4704.25 1671.62 4503.71 1673.52 4358.93 1675.41 4235.14 1677.31 4137.95 1679.2 4066.69 1681.1 4050.17 1682.99 4023.31 1684.88 3955.78 1686.78 3895.45 1688.67 3912.45 1690.57 3929.46 1692.46 3915.35 1694.36 3900.23 1696.25 3878.24 1698.15 3855.05 1700.04 3838.16 1701.94 3823.5 1703.83 3823.33 1705.72 3831.85 1707.62 3835.76 1709.51 3835.28 1711.41 3828.73 1713.3 3813.09 1715.2 3801.86 1717.09 3801.39 1718.99 3801.26 1720.88 3802.68 1722.78 3803.69 1724.67 3799.42 1726.56 3795.15 1728.46 3814.26 1730.35 3834.2 1732.25 3826.38 1734.14 3814.03 1736.04 3806.34 1737.93 3800.16 1739.83 3822.11 1741.72 3859.2 1743.61 3849.21 1745.51 3800.22 1747.4 3779.13 1749.3 3792.93 1751.19 3805.76 1753.09 3816.71 1754.98 3812.17 1756.88 3759.28 1758.77 3714.69 1760.67 3719.45 1762.56 3724.67 1764.45 3739.45 1766.35 3754.23 1768.24 3773.99 1770.14 3794.03 1772.03 3790.49 1773.93 3782.85 1775.82 3766.9 1777.72 3748.28 1779.61 3766.05 1781.51 3802.37 1783.4 3810.11 1785.29 3796.24 1787.19 3791.28 1789.08 3796.07 1790.98 3805.29 1792.87 3821.54 1794.77 3820.27 1796.66 3777.19 1798.56 3742.01 1800.45 3737.22 1802.35 3736.82 1804.24 3768.92 1806.13 3799.51 1808.03 3784.17 1809.92 3768.84 1811.82 3725.83 1813.71 3681.24 1815.61 3722.89 1817.5 3778.57 1819.4 3779.44 1821.29 3764.57 1823.19 3776.31 1825.08 3799.84 1826.97 3823.67 1828.87 3847.7 1830.76 3844.22 1832.66 3816.33 1834.55 3799.7 1836.45 3796.82 1838.34 3790.72 1840.24 3779.17 1842.13 3778.04 1844.03 3802.11 1845.92 3823.7 1847.81 3836.22 1849.71 3846.73 1851.6 3844.8 1853.5 3841.32 1855.39 3815.29 1857.29 3789.25 1859.18 3789.96 1861.08 3790.92 1862.97 3774.63 1864.86 3756.77 1866.76 3742.17 1868.65 3728.17 1870.55 3760.85 1872.44 3807.22 1874.34 3807.07 1876.23 3787.25 1878.13 3776.01 1880.02 3769.73 1881.92 3757.97 1883.81 3742.01 1885.7 3741.71 1887.6 3757.2 1889.49 3771.44 1891.39 3784.03 1893.28 3796.98 1895.18 3810.54 1897.07 3815.46 1898.97 3800.43 1900.86 3792.6 1902.76 3807.63 1904.65 3820.26 1906.54 3821.71 1908.44 3821.93 1910.33 3812.71 1912.23 3802.62 1914.12 3777.85 1916.02 3753.09 1917.91 3773.33 1919.81 3793.74 1921.7 3771.75 1923.6 3746.96 1925.49 3772.69 1927.38 3805.27 1929.28 3800.98 1931.17 3788.82 1933.07 3810.68 1934.96 3842.8 1936.86 3838.1 1938.75 3818.61 1940.65 3807.82 1942.54 3801.48 1944.44 3801.07 1946.33 3804.49 1948.22 3824.45 1950.12 3857.61 1952.01 3874.99 1953.91 3876.94 1955.8 3859.07 1957.7 3817.57 1959.59 3817.7 1961.49 3878.23 1963.38 3906.81 1965.28 3878.47 1967.17 3857.32 1969.06 3851.94 1970.96 3845.51 1972.85 3836.22 1974.75 3835.11 1976.64 3862.51 1978.54 3889.38 1980.43 3913.86 1982.33 3932.33 1984.22 3912.73 1986.11 3893.69 1988.01 3879.98 1989.9 3865.73 1991.8 3842.2 1993.69 3819.01 1995.59 3819.99 1997.48 3820.98 1999.38 3868.87 2001.27 3917.92 2003.17 3913.18 2005.06 3904.84 2006.95 3887.2 2008.85 3868.53 2010.74 3877.89 2012.64 3891.66 2014.53 3878.51 2016.43 3859.83 2018.32 3866.95 2020.22 3880.72 2022.11 3894.5 2024.01 3908.28 2025.9 3877.13 2027.79 3829.38 2029.69 3831.87 2031.58 3856.01 2033.48 3880.81 2035.37 3905.94 2037.27 3908.69 2039.16 3898.83 2041.06 3894.1 2042.95 3892.61 2044.85 3888.54 2046.74 3882.62 2048.63 3881.65 2050.53 3884.61 2052.42 3886.26 2054.32 3886.76 2056.21 3883.99 2058.11 3878.06 2060 3876.44 2061.9 3879.41 2063.79 3893.35 2065.69 3922.01 2067.58 3922.26 2069.47 3892.63 2071.37 3877.24 2073.26 3883.47 2075.16 3898.7 2077.05 3932.1 2078.95 3953.15 2080.84 3955.49 2082.74 3958.3 2084.63 3963.35 2086.52 3963.56 2088.42 3952.74 2090.31 3940.86 2092.21 3942.13 2094.1 3956.95 2096 3984.65 2097.89 3994.55 2099.79 3974.1 2101.68 3961.51 2103.58 3961.65 2105.47 3962.63 2107.36 3977.29 2109.26 3990.77 2111.15 4003.91 2113.05 4017.92 2114.94 4011.92 2116.84 4001.56 2118.73 4008.72 2120.63 4020.37 2122.52 4003.8 2124.42 3975.12 2126.31 3967.38 2128.2 3978.91 2130.1 4014.55 2131.99 4035.34 2133.89 4025.7 2135.78 4010.16 2137.68 3997.56 2139.57 4005.56 2141.47 4017.64 2143.36 4017.85 2145.26 4023.16 2147.15 4050.98 2149.04 4074.82 2150.94 4054.21 2152.83 4022.4 2154.73 4023.98 2156.62 4044.77 2158.52 4055.96 2160.41 4064.17 2162.31 4068.15 2164.2 4055.1 2166.1 4053.41 2167.99 4082.49 2169.88 4107.28 2171.78 4102.38 2173.67 4097.18 2175.57 4104.5 2177.46 4107.51 2179.36 4103.68 2181.25 4088.1 2183.15 4078.97 2185.04 4088.66 2186.94 4098.05 2188.83 4091.38 2190.72 4077.86 2192.62 4078.31 2194.51 4088.02 2196.41 4128.43 2198.3 4158.46 2200.2 4111.7 2202.09 4078.24 2203.99 4110.76 2205.88 4133.29 2207.77 4127.56 2209.67 4130.01 2211.56 4109.04 2213.46 4079.76 2215.35 4098.65 2217.25 4128.03 2219.14 4140.29 2221.04 4136.14 2222.93 4090.21 2224.83 4062.98 2226.72 4110.71 2228.61 4147.51 2230.51 4151.44 2232.4 4160.12 2234.3 4122.19 2236.19 4082.77 2238.09 4085.29 2239.98 4092.98 2241.88 4118.94 2243.77 4147.61 2245.67 4183.88 2247.56 4207.45 2249.45 4137.45 2251.35 4082.95 2253.24 4131.36 2255.14 4176.99 2257.03 4169.95 2258.93 4161.95 2260.82 4148.36 2262.72 4134.45 2264.61 4118.84 2266.51 4109.51 2268.4 4130.16 2270.29 4150.81 2272.19 4171.47 2274.08 4191.62 2275.98 4209.76 2277.87 4225.26 2279.77 4231.31 2281.66 4219.78 2283.56 4151.67 2285.45 4113.81 2287.35 4164.31 2289.24 4198.43 2291.13 4189.35 2293.03 4190.37 2294.92 4215.64 2296.82 4227.02 2298.71 4208.31 2300.61 4189.61 2302.5 4170.9 2304.4 4164.59 2306.29 4180.28 2308.18 4198.89 2310.08 4222.18 2311.97 4231.79 2313.87 4221.66 2315.76 4219.46 2317.66 4227.57 2319.55 4225.38 2321.45 4211.18 2323.34 4200.95 2325.24 4194.87 2327.13 4201.91 2329.02 4221.19 2330.92 4218.27 2332.81 4196.95 2334.71 4200.82 2336.6 4223.17 2338.5 4235.33 2340.39 4240.92 2342.29 4247.17 2344.18 4253.77 2346.08 4240.18 2347.97 4216.79 2349.86 4234.75 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3881.85 3192.93 3874.5 3194.82 3853.53 3196.72 3845.23 3198.61 3840.08 3200.51 3842.35 3202.4 3845.14 3204.3 3849.11 3206.19 3851.55 3208.09 3852.69 3209.98 3857.82 3211.88 3863.21 3213.77 3829.68 3215.66 3809.41 3217.56 3826.47 3219.45 3829.48 3221.35 3818.68 3223.24 3817.21 3225.14 3818.92 3227.03 3817.24 3228.93 3812.6 3230.82 3798.36 3232.72 3813.02 3234.61 3859.2 3236.5 3858.31 3238.4 3839.49 3240.29 3815.12 3242.19 3793.7 3244.08 3783.42 3245.98 3787.24 3247.87 3807.22 3249.77 3808.85 3251.66 3803.14 3253.56 3794.67 3255.45 3787.08 3257.34 3783.08 3259.24 3765.26 3261.13 3731.52 3263.03 3718.65 3264.92 3714.07 3266.82 3752.2 3268.71 3784.2 3270.61 3789.93 3272.5 3797.3 3274.4 3806.46 3276.29 3808.51 3278.18 3807.94 3280.08 3770.04 3281.97 3754.14 3283.87 3808.65 3285.76 3846.26 3287.66 3866.92 3289.55 3848.44 3291.45 3818.55 3293.34 3855.89 3295.24 3870.4 3297.13 3825 3299.02 3822.12 3300.92 3856.04 3302.81 3827.63 3304.71 3785.87 3306.6 3784.71 3308.5 3790.21 3310.39 3809.79 3312.29 3802.79 3314.18 3776.87 3316.07 3774.4 3317.97 3771.9 3319.86 3736.16 3321.76 3721.56 3323.65 3741.76 3325.55 3732.56 3327.44 3707.17 3329.34 3732.83 3331.23 3753.69 3333.13 3730.01 3335.02 3711.24 3336.91 3698.52 3338.81 3692.44 3340.7 3688.98 3342.6 3723.78 3344.49 3742.9 3346.39 3715.71 3348.28 3699.25 3350.18 3692.3 3352.07 3661.66 3353.97 3631.69 3355.86 3681.51 3357.75 3718.59 3359.65 3731.92 3361.54 3718.12 3363.44 3687.96 3365.33 3652.59 3367.23 3630.87 3369.12 3676.15 3371.02 3694.89 3372.91 3681.54 3374.81 3646.55 3376.7 3604.38 3378.59 3655.52 3380.49 3676.86 3382.38 3624.55 3384.28 3618.77 3386.17 3648.43 3388.07 3657.38 3389.96 3657.7 3391.86 3625.1 3393.75 3616.01 3395.65 3640.47 3397.54 3663.32 3399.43 3685.46 3401.33 3649.41 3403.22 3618.55 3405.12 3605.72 3407.01 3607.3 3408.91 3620.71 3410.8 3613.19 3412.7 3600.87 3414.59 3583.94 3416.48 3576.8 3418.38 3583.81 3420.27 3595.71 3422.17 3609.74 3424.06 3573.03 3425.96 3561.44 3427.85 3617.6 3429.75 3625.36 3431.64 3596.11 3433.54 3609.5 3435.43 3626.32 3437.32 3622.22 3439.22 3608.02 3441.11 3581.06 3443.01 3595.92 3444.9 3625.09 3446.8 3630.37 3448.69 3633.36 3450.59 3631.6 3452.48 3621.1 3454.38 3605.25 3456.27 3562.47 3458.16 3535.73 3460.06 3576.85 3461.95 3583.1 3463.85 3556.05 3465.74 3501.37 3467.64 3455.38 3469.53 3532.46 3471.43 3573.35 3473.32 3562.16 3475.22 3586.14 3477.11 3623.98 3479 3627.51 3480.9 3622.7 3482.79 3599.71 3484.69 3587.65 3486.58 3582.35 3488.48 3565.62 3490.37 3551.26 3492.27 3548.31 3494.16 3535.95 3496.06 3515.29 3497.95 3510.94 3499.84 3513.02 3501.74 3534.29 3503.63 3535.77 3505.53 3513.32 3507.42 3498.94 3509.32 3489.79 3511.21 3516.41 3513.11 3542.14 3515 3566.41 3516.9 3540.03 3518.79 3490.95 3520.68 3514.05 3522.58 3523.26 3524.47 3501.92 3526.37 3482.06 3528.26 3463.09 3530.16 3485.89 3532.05 3500.57 3533.95 3483.36 3535.84 3495.51 3537.73 3529.94 3539.63 3520.81 3541.52 3503.34 3543.42 3475.42 3545.31 3471.15 3547.21 3488.99 3549.1 3479.52 3551 3463.91 3552.89 3444.28 3554.79 3449.98 3556.68 3483.91 3558.57 3462.13 3560.47 3433.45 3562.36 3464.43 3564.26 3479.6 3566.15 3474.23 3568.05 3439.06 3569.94 3399.75 3571.84 3422.42 3573.73 3453.77 3575.63 3497.93 3577.52 3463.84 3579.41 3405.08 3581.31 3426.58 3583.2 3451.04 3585.1 3480.32 3586.99 3431.53 3588.89 3354.9 3590.78 3413.51 3592.68 3443.36 3594.57 3422.42 3596.47 3431.63 3598.36 3453.87 3600.25 3450.88 3602.15 3442.85 3604.04 3425.48 3605.94 3434.62 3607.83 3455.54 3609.73 3423.15 3611.62 3411.65 3613.52 3439.85 3615.41 3434.28 3617.31 3413.22 3619.2 3437.24 3621.09 3441.69 3622.99 3409.25 3624.88 3425.16 3626.78 3462.16 3628.67 3418.88 3630.57 3401.17 3632.46 3430.03 3634.36 3421.04 3636.25 3396.2 3638.15 3405.23 3640.04 3404.94 3641.93 3388.68 3643.83 3403.99 3645.72 3430.03 3647.62 3411.34 3649.51 3401.81 3651.41 3406.63 3653.3 3438.36 3655.2 3475.78 3657.09 3460.08 3658.98 3426.77 3660.88 3368.8 3662.77 3356.77 3664.67 3360.14 3666.56 3371.62 3668.46 3389.1 3670.35 3413.9 3672.25 3417.97 3674.14 3414.85 3676.04 3400.33 3677.93 3388.48 3679.82 3379.4 3681.72 3344.41 3683.61 3317.84 3685.51 3349.36 3687.4 3345.69 3689.3 3311.76 3691.19 3323.54 3693.09 3333.17 3694.98 3317.4 3696.88 3323.83 3698.77 3345.68 3700.66 3342.93 3702.56 3328.97 3704.45 3291.91 3706.35 3281.3 3708.24 3285.03 3710.14 3309.96 3712.03 3310.86 3713.93 3268.89 3715.82 3279.57 3717.72 3307.83 3719.61 3292.61 3721.5 3288.64 3723.4 3299.6 3725.29 3290.9 3727.19 3282.58 3729.08 3307.58 3730.98 3318.7 3732.87 3316.26 3734.77 3308.01 3736.66 3302.6 3738.55 3309.92 3740.45 3309.34 3742.34 3303.23 3744.24 3318.62 3746.13 3326.86 3748.03 3317.08 3749.92 3277.87 3751.82 3228.23 3753.71 3258.82 3755.61 3269.2 3757.5 3250.23 3759.39 3234.57 3761.29 3218.33 3763.18 3192.61 3765.08 3201.38 3766.97 3243.67 3768.87 3234.44 3770.76 3234.5 3772.66 3286.03 3774.55 3282.21 3776.45 3243.57 3778.34 3221.2 3780.23 3201.71 3782.13 3186.98 3784.02 3216.36 3785.92 3256.79 3787.81 3245.11 3789.71 3233.72 3791.6 3222.65 3793.5 3221.45 3795.39 3229.07 3797.29 3261.69 3799.18 3242.03 3801.07 3186.63 3802.97 3173.59 3804.86 3180.2 3806.76 3221.48 3808.65 3203.1 3810.55 3170.25 3812.44 3213.43 3814.34 3221.75 3816.23 3192.15 3818.13 3195.88 3820.02 3203.08 3821.91 3203.7