#------------------------------------------------------------------------------ #$Date: 2018-04-23 15:09:42 +0300 (Mon, 23 Apr 2018) $ #$Revision: 440 $ #$URL: svn://172.16.1.111/rod/cif/1/00/00/1000022.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000022 loop_ _publ_author_name 'Novak, G. A.' 'Gibbs, G. V.' _publ_section_title ; The crystal chemistry of the silicate garnets sample Al ; _journal_name_full 'American Mineralogist' _journal_page_first 791 _journal_page_last 825 _journal_volume 56 _journal_year 1971 _chemical_compound_source R040076 _chemical_formula_sum 'Al2 Ca0.12 Fe2.58 Mg0.27 O12 Si3' _chemical_name_mineral Almandine _space_group_IT_number 230 _symmetry_space_group_name_Hall '-I 4bd 2c 3' _symmetry_space_group_name_H-M 'I a -3 d' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 11.531 _cell_length_b 11.531 _cell_length_c 11.531 _cell_volume 1533.207 _exptl_crystal_density_diffrn 4.208 _cod_original_formula_sum 'Si3 Al2 Fe2.58 Mg.27 Ca.12 O12' _cod_database_code 9000233 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R040076.rod _rod_data_source.block 3500000 _rod_database.code 1000022 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9000233 COD http://www.crystallography.net/cod/9000233.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 127.2373 0.0000000E+00 127.7194 2.465332 128.2015 8.4716998E-02 128.6837 3.706299 129.1658 18.53833 129.6479 57.74585 130.1300 86.03857 130.6121 106.8215 131.0942 116.3118 131.5764 123.6648 132.0585 90.02930 132.5406 42.92578 133.0227 15.13062 133.5048 32.34912 133.9869 42.03467 134.4691 30.55542 134.9512 7.843018 135.4333 9.911865 135.9154 12.83691 136.3975 0.9191890 136.8796 20.71509 137.3618 60.36987 137.8439 100.1436 138.3260 135.4014 138.8081 164.7644 139.2902 182.6270 139.7723 180.0530 140.2545 157.1348 140.7366 143.8982 141.2187 149.2944 141.7008 161.8008 142.1829 169.6196 142.6650 171.2310 143.1472 168.3276 143.6293 159.1228 144.1114 145.2151 144.5935 135.0613 145.0756 131.4746 145.5577 134.1792 146.0399 144.3877 146.5220 172.1431 147.0041 195.0164 147.4862 191.6526 147.9683 163.4124 148.4504 135.2124 148.9326 129.8596 149.4147 149.5215 149.8968 168.3606 150.3789 183.7402 150.8610 195.5627 151.3431 203.5552 151.8252 207.6382 152.3074 207.6230 152.7895 202.3838 153.2716 188.5374 153.7537 176.5903 154.2358 164.4456 154.7179 155.8110 155.2001 155.0110 155.6822 163.9363 156.1643 179.3308 156.6464 191.2764 157.1285 201.2625 157.6106 205.2351 158.0928 201.3862 158.5749 191.6733 159.0570 177.2117 159.5391 157.9641 160.0212 135.1099 160.5033 123.4658 160.9855 130.9810 161.4676 139.8005 161.9497 147.6887 162.4318 152.9304 162.9139 151.7056 163.3960 139.6646 163.8782 116.3694 164.3603 100.7451 164.8424 94.23926 165.3245 93.16919 165.8066 96.47876 166.2887 103.8770 166.7709 113.6836 167.2530 127.8096 167.7351 145.6096 168.2172 149.2720 168.6993 120.3892 169.1814 82.84985 169.6636 66.48975 170.1457 77.47046 170.6278 101.8599 171.1099 127.7349 171.5920 155.0432 172.0741 185.6743 172.5563 223.7786 173.0384 266.2063 173.5205 301.9592 174.0026 323.5376 174.4847 347.0334 174.9668 390.0464 175.4490 450.9165 175.9311 507.9116 176.4132 547.0642 176.8953 568.7732 177.3774 580.7302 177.8595 582.1726 178.3417 574.4023 178.8238 557.0317 179.3059 530.2388 179.7880 497.8250 180.2701 463.0410 180.7522 424.8557 181.2344 387.9324 181.7165 354.7732 182.1986 321.9070 182.6807 286.1482 183.1628 246.9060 183.6449 207.5808 184.1271 173.2983 184.6092 142.9241 185.0913 120.8645 185.5734 107.7798 186.0555 101.6768 186.5376 102.4678 187.0198 110.0046 187.5019 121.4351 187.9840 129.6365 188.4661 135.8569 188.9482 136.2737 189.4303 121.5615 189.9125 103.8276 190.3946 98.87964 190.8767 115.3232 191.3588 147.3201 191.8409 167.6599 192.3230 162.0479 192.8052 160.5996 193.2873 168.2891 193.7694 183.5386 194.2515 203.0615 194.7336 223.8008 195.2157 246.3740 195.6979 274.4397 196.1800 313.6746 196.6621 349.5740 197.1442 375.0007 197.6263 393.0269 198.1084 410.2747 198.5906 431.5767 199.0727 456.3206 199.5548 477.3618 200.0369 483.5188 200.5190 495.4460 201.0011 532.8389 201.4833 593.7271 201.9654 650.7209 202.4475 682.2651 202.9296 690.7461 203.4117 707.4053 203.8938 735.3750 204.3760 771.6492 204.8581 817.5488 205.3402 872.6401 205.8223 922.2649 206.3044 955.5825 206.7865 977.1772 207.2687 996.2478 207.7508 1015.151 208.2329 1032.279 208.7150 1044.130 209.1971 1049.934 209.6792 1055.921 210.1614 1070.213 210.6435 1086.518 211.1256 1090.633 211.6077 1066.041 212.0898 1029.594 212.5719 1019.661 213.0541 1050.520 213.5362 1081.450 214.0183 1088.533 214.5004 1075.700 214.9825 1049.351 215.4646 1004.353 215.9468 946.3120 216.4289 900.9065 216.9110 876.3386 217.3931 854.7722 217.8752 826.0083 218.3573 791.2883 218.8395 755.0046 219.3216 718.1807 219.8037 681.5959 220.2858 651.7681 220.7679 634.2847 221.2500 617.2737 221.7322 597.8628 222.2143 574.8037 222.6964 545.5479 223.1785 502.7520 223.6606 445.0935 224.1427 404.0078 224.6249 397.4062 225.1070 392.8733 225.5891 379.4709 226.0712 357.1682 226.5533 330.9739 227.0354 301.7190 227.5176 266.2305 227.9997 240.8638 228.4818 236.9094 228.9639 234.9448 229.4460 226.5857 229.9281 212.5459 230.4103 199.1790 230.8924 194.0144 231.3745 199.8806 231.8566 200.9700 232.3387 195.0210 232.8208 186.6169 233.3030 174.1960 233.7851 159.8708 234.2672 150.4690 234.7493 155.6682 235.2314 183.7063 235.7135 195.8745 236.1957 184.4128 236.6778 166.5037 237.1599 148.6187 237.6420 132.6646 238.1241 119.3950 238.6062 110.3372 239.0884 108.0129 239.5705 101.3948 240.0526 82.14941 240.5347 65.81787 241.0168 64.33203 241.4989 77.37939 241.9811 94.09839 242.4632 101.6736 242.9453 95.70605 243.4274 93.79834 243.9095 105.5854 244.3916 113.8303 244.8738 102.2715 245.3559 71.42627 245.8380 38.93970 246.3201 24.53735 246.8022 31.29395 247.2843 51.77051 247.7665 112.4490 248.2486 167.3391 248.7307 176.6848 249.2128 138.6660 249.6949 87.19238 250.1770 61.16382 250.6592 71.67651 251.1413 70.76782 251.6234 48.97510 252.1055 22.89014 252.5876 1.483154 253.0697 12.87988 253.5519 17.85693 254.0340 9.478760 254.5161 16.66650 254.9982 40.66724 255.4803 69.37134 255.9624 91.50366 256.4445 97.33887 256.9267 85.86377 257.4088 63.03833 257.8909 31.66870 258.3730 12.21533 258.8551 38.34644 259.3372 34.02490 259.8194 20.10425 260.3015 10.93140 260.7836 8.676270 261.2657 12.76880 261.7478 26.27905 262.2299 51.72632 262.7121 58.09009 263.1942 24.75806 263.6763 14.62476 264.1584 31.58496 264.6405 23.77319 265.1227 8.513428 265.6048 1.788330 266.0869 4.229492 266.5690 1.377930 267.0511 31.00537 267.5332 58.46191 268.0154 55.67065 268.4975 22.19507 268.9796 10.58472 269.4617 14.49756 269.9438 10.61377 270.4259 24.94067 270.9081 19.72729 271.3902 8.909668 271.8723 2.704346 272.3544 1.602295 272.8365 1.996826 273.3186 0.9841310 273.8008 1.000000 274.2829 0.3715820 274.7650 6.056885 275.2471 12.76685 275.7292 14.83838 276.2113 12.50781 276.6935 10.71411 277.1756 13.61279 277.6577 20.08984 278.1398 22.57397 278.6219 19.54517 279.1040 13.76025 279.5862 6.930664 280.0683 0.9829100 280.5504 11.33130 281.0325 28.08765 281.5146 46.96191 281.9967 53.04663 282.4789 38.63452 282.9610 18.80859 283.4431 2.835693 283.9252 24.38062 284.4073 33.18335 284.8894 17.75928 285.3716 13.09229 285.8537 30.66235 286.3358 26.18628 286.8179 20.04565 287.3000 22.03125 287.7821 31.43896 288.2643 47.08813 288.7464 72.86621 289.2285 100.7124 289.7106 110.9458 290.1927 95.55420 290.6748 78.93237 291.1570 70.91479 291.6391 70.52856 292.1212 75.65918 292.6033 87.02441 293.0854 101.5081 293.5675 112.5793 294.0497 119.3545 294.5318 126.0779 295.0139 134.9739 295.4960 145.0745 295.9781 154.4658 296.4602 162.8767 296.9424 169.5967 297.4245 172.5559 297.9066 171.1555 298.3887 170.1721 298.8708 169.9512 299.3529 171.3120 299.8351 175.6887 300.3172 183.4863 300.7993 194.2876 301.2814 209.6553 301.7635 230.5283 302.2456 246.5063 302.7278 244.2490 303.2099 239.5618 303.6920 260.1672 304.1741 314.0095 304.6562 369.2876 305.1383 383.6211 305.6205 353.8142 306.1026 343.5042 306.5847 375.7803 307.0668 423.5371 307.5489 459.3135 308.0310 479.7239 308.5132 495.9031 308.9953 517.9199 309.4774 546.1023 309.9595 572.2849 310.4416 589.9019 310.9237 608.6887 311.4059 639.9583 311.8880 683.7207 312.3701 728.3613 312.8522 763.8660 313.3343 790.0974 313.8164 816.7634 314.2986 841.2302 314.7807 868.2273 315.2628 904.6956 315.7449 947.4866 316.2270 982.9485 316.7091 1002.029 317.1913 1008.734 317.6734 1017.516 318.1555 1035.421 318.6376 1046.877 319.1197 1038.227 319.6018 1017.587 320.0840 1005.723 320.5661 1015.910 321.0482 1042.656 321.5303 1058.917 322.0124 1055.742 322.4945 1052.449 322.9767 1047.293 323.4588 1045.615 323.9409 1057.725 324.4230 1087.634 324.9051 1126.257 325.3872 1158.476 325.8694 1179.504 326.3515 1209.629 326.8336 1252.094 327.3157 1300.735 327.7978 1350.578 328.2799 1400.258 328.7621 1451.318 329.2442 1503.934 329.7263 1550.661 330.2084 1619.641 330.6905 1735.998 331.1726 1855.367 331.6548 1940.690 332.1369 1990.901 332.6190 2036.040 333.1011 2107.452 333.5832 2210.775 334.0653 2311.868 334.5475 2414.579 335.0296 2511.801 335.5117 2590.897 335.9938 2659.583 336.4759 2741.255 336.9580 2855.498 337.4402 3001.685 337.9223 3139.325 338.4044 3265.669 338.8865 3385.861 339.3686 3494.178 339.8507 3598.611 340.3329 3711.446 340.8150 3840.699 341.2971 3983.022 341.7792 4124.203 342.2613 4254.824 342.7434 4399.299 343.2256 4563.558 343.7077 4739.601 344.1898 4920.695 344.6719 5104.091 345.1540 5288.545 345.6361 5469.898 346.1183 5629.578 346.6004 5824.219 347.0825 6069.720 347.5646 6335.052 348.0467 6602.646 348.5288 6865.907 349.0110 7128.595 349.4931 7390.125 349.9752 7646.873 350.4573 7920.541 350.9394 8241.955 351.4215 8558.306 351.9037 8851.261 352.3858 9118.230 352.8679 9360.942 353.3500 9588.106 353.8321 9798.093 354.3142 9943.890 354.7964 10007.84 355.2785 10019.93 355.7606 9996.041 356.2427 9933.897 356.7248 9829.271 357.2069 9683.994 357.6891 9492.611 358.1712 9230.098 358.6533 8863.938 359.1354 8495.508 359.6175 8169.450 360.0996 7862.909 360.5818 7548.417 361.0639 7211.072 361.5460 6876.061 362.0281 6579.708 362.5102 6323.438 362.9923 6085.140 363.4745 5862.243 363.9566 5651.232 364.4387 5451.438 364.9208 5262.792 365.4029 5085.011 365.8850 4914.200 366.3672 4752.431 366.8493 4607.843 367.3314 4483.287 367.8135 4378.135 368.2956 4294.701 368.7777 4231.395 369.2599 4169.576 369.7420 4098.734 370.2241 4026.413 370.7062 3967.857 371.1883 3926.521 371.6704 3886.897 372.1526 3835.949 372.6347 3773.477 373.1168 3704.632 373.5989 3617.608 374.0810 3534.719 374.5631 3480.333 375.0453 3449.503 375.5274 3409.382 376.0095 3340.254 376.4916 3245.987 376.9737 3146.492 377.4558 3033.884 377.9380 2926.456 378.4201 2831.384 378.9022 2745.086 379.3843 2663.434 379.8664 2584.933 380.3485 2505.898 380.8307 2420.436 381.3128 2324.314 381.7949 2230.112 382.2770 2135.935 382.7591 2045.186 383.2412 1964.155 383.7234 1892.802 384.2055 1823.862 384.6876 1749.103 385.1697 1665.579 385.6518 1587.533 386.1339 1517.668 386.6161 1449.629 387.0982 1377.779 387.5803 1304.557 388.0624 1238.785 388.5445 1187.257 389.0266 1147.930 389.5088 1099.659 389.9909 1031.131 390.4730 966.7175 390.9551 911.8282 391.4372 863.0422 391.9193 815.1270 392.4015 765.2509 392.8836 716.3270 393.3657 674.5081 393.8478 644.4456 394.3299 611.1200 394.8120 565.0322 395.2942 520.1572 395.7763 488.2247 396.2584 470.0248 396.7405 454.0773 397.2226 427.2106 397.7047 389.4448 398.1869 357.3032 398.6690 338.5886 399.1511 317.3767 399.6332 276.4016 400.1153 224.7921 400.5974 188.7335 401.0796 191.5536 401.5617 216.5393 402.0438 226.0071 402.5259 217.0670 403.0080 204.2444 403.4901 195.3781 403.9723 187.4497 404.4544 175.1246 404.9365 153.6671 405.4186 133.9556 405.9007 128.7917 406.3828 135.0304 406.8650 134.1976 407.3471 116.4220 407.8292 93.05078 408.3113 83.50964 408.7934 89.87354 409.2755 96.13220 409.7577 96.41577 410.2398 94.13501 410.7219 95.45691 411.2040 101.4823 411.6861 105.0763 412.1682 98.49036 412.6504 80.12659 413.1325 63.07092 413.6146 44.62329 414.0967 29.77063 414.5788 22.76099 415.0609 21.90820 415.5431 22.30188 416.0252 21.18445 416.5073 18.56409 416.9894 14.34790 417.4715 3.568481 417.9536 2.753906 418.4358 1.544067 418.9179 8.482910 419.4000 8.835083 419.8821 4.2236000E-02 420.3642 12.54224 420.8463 21.00964 421.3285 24.31738 421.8106 26.13672 422.2927 27.07861 422.7748 26.10193 423.2569 20.97913 423.7390 13.05591 424.2212 6.492310 424.7033 4.708984 425.1854 7.026245 425.6675 9.169312 426.1496 10.05176 426.6317 12.71899 427.1139 20.58081 427.5960 29.92139 428.0781 37.01782 428.5602 41.76294 429.0423 40.39368 429.5244 21.28601 430.0066 16.32092 430.4887 36.59338 430.9708 19.30835 431.4529 10.52673 431.9350 24.34436 432.4171 21.49597 432.8993 15.45435 433.3814 8.967041 433.8635 4.446167 434.3456 8.004028 434.8277 21.31494 435.3098 35.58374 435.7920 44.80627 436.2741 48.48425 436.7562 46.37183 437.2383 31.98364 437.7204 17.75342 438.2025 11.17346 438.6847 10.77637 439.1668 12.04883 439.6489 13.04382 440.1310 13.58557 440.6131 13.15002 441.0952 10.59448 441.5774 8.665405 442.0595 10.50073 442.5416 11.24023 443.0237 3.675415 443.5058 11.96216 443.9879 26.12610 444.4701 27.14526 444.9522 12.41382 445.4343 3.128296 445.9164 4.980347 446.3985 6.627319 446.8806 4.304810 447.3628 0.7681880 447.8449 6.477905 448.3270 12.30237 448.8091 16.57935 449.2912 13.84131 449.7733 0.2083740 450.2555 9.570679 450.7376 7.228149 451.2197 2.344727 451.7018 2.837158 452.1839 9.916870 452.6660 16.68567 453.1482 16.30457 453.6303 10.53381 454.1124 7.871704 454.5945 10.27600 455.0766 13.66614 455.5587 12.73083 456.0409 9.621094 456.5230 11.53967 457.0051 27.46191 457.4872 43.50562 457.9693 43.05408 458.4514 29.57056 458.9336 24.55054 459.4156 41.18127 459.8978 69.04907 460.3799 78.91101 460.8620 60.16333 461.3441 46.73804 461.8262 45.46790 462.3083 51.79736 462.7905 63.74438 463.2726 79.80811 463.7547 93.78650 464.2368 98.06079 464.7189 90.39294 465.2010 92.67712 465.6832 117.0304 466.1653 137.7456 466.6474 144.8293 467.1295 143.0015 467.6116 140.1161 468.0938 139.8450 468.5759 142.3586 469.0580 148.1652 469.5401 157.6953 470.0222 169.3936 470.5043 188.8829 470.9865 206.1052 471.4686 210.3118 471.9507 202.5671 472.4328 199.8625 472.9149 219.0138 473.3970 253.8815 473.8792 281.7020 474.3613 299.5787 474.8434 316.1078 475.3255 338.3219 475.8076 362.7612 476.2897 383.1476 476.7719 397.2501 477.2540 408.3086 477.7361 411.1102 478.2182 411.0896 478.7003 430.8833 479.1824 482.0735 479.6646 542.9756 480.1467 577.9854 480.6288 576.5425 481.1109 583.6311 481.5930 609.3105 482.0751 638.1519 482.5573 661.0129 483.0394 676.5076 483.5215 686.2842 484.0036 692.1807 484.4857 692.9028 484.9678 679.8391 485.4500 639.1262 485.9321 602.4469 486.4142 580.3190 486.8963 561.1167 487.3784 531.0764 487.8605 488.3352 488.3427 446.3380 488.8248 424.0042 489.3069 421.1774 489.7890 414.8455 490.2711 401.0652 490.7532 390.2474 491.2354 386.9250 491.7175 390.3444 492.1996 398.3798 492.6817 408.6613 493.1638 423.7423 493.6459 449.3331 494.1281 485.1327 494.6102 521.0061 495.0923 552.5336 495.5744 584.4081 496.0565 626.0393 496.5386 679.8181 497.0208 729.1383 497.5029 756.5565 497.9850 786.0181 498.4671 844.3276 498.9492 931.9049 499.4313 1030.423 499.9135 1125.792 500.3956 1218.007 500.8777 1312.029 501.3598 1404.180 501.8419 1502.056 502.3240 1621.458 502.8062 1739.763 503.2883 1832.778 503.7704 1893.600 504.2525 1932.994 504.7346 1967.085 505.2167 1998.239 505.6989 2004.232 506.1810 1987.052 506.6631 1938.934 507.1452 1848.549 507.6273 1728.286 508.1094 1601.767 508.5916 1473.765 509.0737 1349.752 509.5558 1242.372 510.0379 1151.499 510.5200 1053.747 511.0021 934.7490 511.4843 812.7566 511.9664 716.1372 512.4485 646.0288 512.9306 583.2949 513.4127 523.1208 513.8948 468.3402 514.3770 420.9463 514.8591 381.5049 515.3412 352.6644 515.8233 337.9033 516.3054 334.1970 516.7875 322.6401 517.2697 285.7471 517.7518 262.7908 518.2339 269.1373 518.7160 284.4551 519.1981 288.3644 519.6802 277.1969 520.1624 262.4120 520.6445 258.3038 521.1266 265.3623 521.6087 261.4320 522.0908 232.8206 522.5729 213.9315 523.0551 233.2727 523.5372 267.5863 524.0193 277.4695 524.5014 242.7555 524.9835 200.1633 525.4656 186.5621 525.9478 197.5051 526.4299 210.4362 526.9120 220.7719 527.3941 228.6740 527.8762 233.4635 528.3583 234.9821 528.8405 237.5331 529.3226 246.2996 529.8047 252.0033 530.2868 246.2615 530.7689 232.2587 531.2510 218.4917 531.7332 209.0687 532.2153 203.7711 532.6974 202.1732 533.1795 205.1606 533.6616 210.5394 534.1437 221.3867 534.6259 231.6642 535.1080 235.2053 535.5901 234.1298 536.0722 236.6050 536.5543 248.6782 537.0364 268.4358 537.5186 291.0941 538.0007 318.3248 538.4828 342.3457 538.9649 354.8052 539.4470 365.7999 539.9291 386.9779 540.4113 419.8301 540.8934 457.0641 541.3755 498.0234 541.8576 539.8979 542.3397 577.4570 542.8218 610.2183 543.3040 640.9749 543.7861 668.9780 544.2682 696.4990 544.7503 744.0487 545.2324 832.9673 545.7145 912.5809 546.1967 958.4115 546.6788 997.2015 547.1609 1059.764 547.6430 1151.418 548.1251 1253.501 548.6072 1343.819 549.0894 1421.691 549.5715 1515.494 550.0536 1637.038 550.5357 1758.597 551.0178 1862.675 551.4999 1963.300 551.9821 2083.364 552.4642 2233.041 552.9463 2386.691 553.4284 2515.946 553.9105 2628.546 554.3926 2756.125 554.8748 2908.431 555.3569 3062.494 555.8390 3196.337 556.3211 3309.592 556.8032 3421.997 557.2853 3560.335 557.7675 3671.941 558.2496 3738.922 558.7317 3760.760 559.2138 3733.964 559.6959 3658.033 560.1780 3542.922 560.6602 3400.470 561.1423 3225.769 561.6244 3041.563 562.1065 2840.587 562.5886 2639.150 563.0707 2438.606 563.5529 2242.096 564.0350 2051.580 564.5171 1867.663 564.9992 1693.526 565.4813 1534.870 565.9634 1391.101 566.4456 1251.848 566.9277 1111.109 567.4098 979.4160 567.8919 870.3757 568.3740 782.0881 568.8561 700.7615 569.3383 621.2654 569.8204 550.5769 570.3025 498.7386 570.7846 458.5842 571.2667 411.9460 571.7488 351.2107 572.2310 286.0837 572.7131 234.4645 573.1952 197.3850 573.6773 171.0643 574.1594 168.4027 574.6415 163.1299 575.1237 137.2964 575.6058 100.7899 576.0879 76.65662 576.5700 79.09717 577.0521 90.92773 577.5342 82.50647 578.0164 53.68469 578.4985 33.65417 578.9806 31.05737 579.4627 36.62354 579.9448 42.53699 580.4269 48.70386 580.9091 53.74988 581.3912 58.31201 581.8733 60.88818 582.3554 55.51550 582.8375 47.41248 583.3196 51.62964 583.8018 74.85718 584.2839 105.0115 584.7660 119.9711 585.2481 110.8552 585.7302 111.8051 586.2123 135.6528 586.6945 156.1370 587.1766 161.7430 587.6587 155.8860 588.1408 146.1245 588.6229 135.1071 589.1050 124.2421 589.5872 116.9980 590.0693 113.0375 590.5514 104.3671 591.0335 88.00452 591.5156 68.83875 591.9977 49.71521 592.4799 31.06519 592.9620 18.00293 593.4441 16.73462 593.9262 15.85718 594.4083 6.242554 594.8904 7.426270 595.3726 15.46826 595.8547 14.47998 596.3368 7.580811 596.8189 1.896606 597.3010 15.88733 597.7831 23.10095 598.2653 12.57349 598.7474 6.689453 599.2295 19.68372 599.7116 39.77039 600.1937 47.31396 600.6758 33.64795 601.1580 15.06360 601.6401 8.830078 602.1222 12.82690 602.6043 16.92932 603.0864 19.68042 603.5685 21.83972 604.0507 23.53345 604.5328 25.03503 605.0149 28.38367 605.4970 34.72864 605.9791 41.55457 606.4612 49.26697 606.9434 56.38159 607.4255 61.49548 607.9076 64.08752 608.3897 63.39966 608.8718 57.54468 609.3539 47.45825 609.8361 44.47485 610.3182 55.55029 610.8003 60.50806 611.2824 51.05615 611.7645 33.88477 612.2466 12.89441 612.7288 11.81433 613.2109 28.61438 613.6930 23.42285 614.1751 7.403931 614.6572 0.9041750 615.1393 5.594116 615.6215 13.81311 616.1036 21.37817 616.5857 28.51233 617.0678 36.39587 617.5499 51.37268 618.0320 57.86060 618.5142 48.54297 618.9963 34.52258 619.4784 24.29541 619.9605 18.70435 620.4426 14.40808 620.9247 9.642822 621.4069 4.141235 621.8890 2.409668 622.3711 9.656372 622.8532 21.58630 623.3353 41.79797 623.8174 65.31116 624.2996 87.76855 624.7817 109.1296 625.2638 126.7203 625.7459 135.6899 626.2280 144.1719 626.7101 158.5911 627.1923 177.6012 627.6744 196.1807 628.1565 212.1654 628.6386 231.1051 629.1207 263.4994 629.6028 315.2571 630.0850 355.3978 630.5671 365.8705 631.0492 383.4999 631.5313 421.2001 632.0134 473.2046 632.4955 533.3799 632.9777 602.0204 633.4598 663.9543 633.9419 693.0096 634.4240 702.6199 634.9061 743.8556 635.3882 827.5935 635.8704 909.8899 636.3525 959.2054 636.8346 979.6986 637.3167 995.8157 637.7988 1006.748 638.2809 1015.189 638.7631 1028.842 639.2452 1035.178 639.7273 1020.389 640.2094 985.2834 640.6915 941.7527 641.1736 897.4658 641.6558 852.8036 642.1379 813.8287 642.6200 784.7966 643.1021 742.4506 643.5842 669.1611 644.0663 590.0146 644.5485 531.9528 645.0306 494.4772 645.5127 461.1559 645.9948 428.2018 646.4769 396.7336 646.9590 366.8737 647.4412 339.5306 647.9233 318.5503 648.4054 305.5962 648.8875 294.1387 649.3696 273.3242 649.8517 240.4492 650.3339 212.4728 650.8160 188.0638 651.2981 171.0260 651.7802 166.6361 652.2623 168.3240 652.7444 166.5302 653.2266 158.3518 653.7087 150.1184 654.1908 148.2510 654.6729 149.2719 655.1550 145.4303 655.6371 136.0116 656.1193 125.8641 656.6014 118.1479 657.0835 112.0875 657.5656 105.0211 658.0477 95.82910 658.5298 87.27942 659.0120 79.73633 659.4941 72.27051 659.9762 64.01794 660.4583 55.34497 660.9404 47.17969 661.4225 39.48157 661.9047 33.37964 662.3868 31.01221 662.8689 32.34631 663.3510 36.30603 663.8331 44.16345 664.3152 51.10132 664.7974 53.34656 665.2795 50.60693 665.7616 42.19238 666.2437 18.70142 666.7258 0.3477780 667.2079 3.331726 667.6901 1.391602 668.1722 8.680725 668.6543 16.15906 669.1364 20.83789 669.6185 18.76227 670.1006 11.63550 670.5828 9.497192 671.0649 13.34973 671.5470 18.22223 672.0291 22.04779 672.5112 26.52020 672.9933 35.78998 673.4755 50.06592 673.9576 56.96600 674.4397 50.87946 674.9218 37.88416 675.4039 15.89020 675.8860 8.662964 676.3682 20.12915 676.8503 12.60913 677.3324 2.976379 677.8145 10.37543 678.2966 8.014771 678.7787 10.25897 679.2609 23.87585 679.7430 31.97437 680.2251 22.29956 680.7072 6.221680 681.1893 1.001831 681.6714 4.214417 682.1536 9.738159 682.6357 7.116882 683.1178 1.882385 683.5999 1.590332 684.0820 6.200928 684.5641 12.40564 685.0463 18.84705 685.5284 23.99432 686.0105 23.40552 686.4926 11.76813 686.9747 7.054138 687.4568 16.26788 687.9390 25.35718 688.4211 28.62299 688.9032 27.66382 689.3853 25.54974 689.8674 22.59412 690.3495 20.67877 690.8317 24.00500 691.3138 29.01288 691.7959 24.82825 692.2780 10.62329 692.7601 1.714478 693.2422 10.39166 693.7244 31.06421 694.2065 41.95013 694.6886 37.50024 695.1707 31.97687 695.6528 21.96100 696.1349 14.33795 696.6171 15.41327 697.0992 22.42938 697.5813 27.08557 698.0634 24.18774 698.5455 20.41388 699.0276 25.34698 699.5098 36.17126 699.9919 42.32959 700.4740 41.67700 700.9561 38.09937 701.4382 34.26611 701.9203 30.36084 702.4025 27.54236 702.8846 24.54388 703.3667 24.15405 703.8488 27.65338 704.3309 32.96710 704.8130 39.48224 705.2952 46.54004 705.7773 52.53870 706.2594 55.71344 706.7415 58.61969 707.2236 67.21606 707.7057 79.77490 708.1879 83.78546 708.6700 74.83789 709.1521 66.66925 709.6342 74.72864 710.1163 97.75165 710.5984 103.8880 711.0806 72.04218 711.5627 52.12329 712.0448 59.80280 712.5269 76.21674 713.0090 86.98840 713.4911 90.43018 713.9733 90.79840 714.4554 91.33948 714.9375 89.78271 715.4196 78.49957 715.9017 59.59143 716.3839 51.68365 716.8660 61.24982 717.3481 75.54944 717.8302 82.00757 718.3123 80.64319 718.7944 82.47974 719.2766 93.32800 719.7587 99.90277 720.2408 96.09479 720.7229 89.84741 721.2050 88.62427 721.6871 92.36072 722.1693 95.39050 722.6514 92.59949 723.1335 88.64075 723.6156 93.92047 724.0977 106.3821 724.5798 109.2930 725.0620 97.47552 725.5441 84.25598 726.0262 83.60876 726.5083 95.33203 726.9904 100.9043 727.4725 94.39008 727.9547 89.30865 728.4368 89.24976 728.9189 91.24945 729.4010 92.97351 729.8831 93.67383 730.3652 93.03320 730.8474 91.38007 731.3295 88.42401 731.8116 81.14905 732.2937 72.10120 732.7758 72.43201 733.2579 85.22412 733.7401 100.5339 734.2222 110.1585 734.7043 115.4362 735.1864 121.9666 735.6685 134.8268 736.1506 140.5438 736.6328 133.1511 737.1149 121.5386 737.5970 110.3707 738.0791 101.2745 738.5612 96.59460 739.0433 99.67609 739.5255 106.0165 740.0076 108.2070 740.4897 107.9029 740.9718 114.1530 741.4539 129.5922 741.9360 143.4507 742.4182 145.4279 742.9003 137.0282 743.3824 129.9351 743.8645 120.1014 744.3466 116.8790 744.8287 131.7325 745.3109 145.2123 745.7930 140.1698 746.2751 120.5914 746.7572 105.3161 747.2393 103.3893 747.7214 107.5173 748.2036 112.6263 748.6857 118.1725 749.1678 123.3480 749.6499 127.6071 750.1320 132.2098 750.6141 140.3422 751.0963 149.5221 751.5784 145.8513 752.0605 117.2941 752.5426 101.4045 753.0247 118.3264 753.5068 135.6942 753.9890 129.3604 754.4711 108.3221 754.9532 98.45624 755.4353 112.6854 755.9174 125.4164 756.3995 122.1989 756.8817 111.4041 757.3638 102.1616 757.8459 95.32776 758.3280 88.71954 758.8101 80.23236 759.2922 71.43945 759.7744 68.37457 760.2565 71.72888 760.7386 78.12238 761.2207 90.64838 761.7028 100.8142 762.1849 101.0257 762.6671 94.27985 763.1492 89.61237 763.6313 87.49011 764.1134 87.67328 764.5955 93.61304 765.0776 98.32928 765.5598 92.92432 766.0419 82.62292 766.5240 81.56012 767.0061 96.30573 767.4882 114.1047 767.9703 116.4874 768.4525 105.4194 768.9346 96.53473 769.4167 91.28491 769.8988 88.76532 770.3809 88.97351 770.8630 89.48572 771.3452 85.94421 771.8273 75.59241 772.3094 69.94348 772.7915 70.76312 773.2736 74.15955 773.7557 82.82861 774.2379 91.12836 774.7200 88.92926 775.2021 74.60321 775.6842 64.66052 776.1663 79.59845 776.6484 102.2589 777.1306 102.0344 777.6127 82.75946 778.0948 67.48376 778.5769 64.61340 779.0590 66.26044 779.5411 62.35608 780.0233 52.67578 780.5054 47.40210 780.9875 50.62964 781.4696 51.53247 781.9517 45.09924 782.4338 37.21075 782.9160 31.67200 783.3981 28.84283 783.8802 29.26337 784.3623 37.27600 784.8444 44.27008 785.3265 43.52051 785.8087 38.58356 786.2908 33.30273 786.7729 29.35046 787.2550 31.19171 787.7371 44.66779 788.2192 61.77069 788.7014 55.42340 789.1835 22.32697 789.6656 1.246216 790.1477 7.647705 790.6298 6.739502 791.1119 4.175537 791.5941 0.2877200 792.0762 3.480896 792.5583 8.341492 793.0404 11.05017 793.5225 8.022949 794.0046 5.383301 794.4868 9.536499 794.9689 17.36707 795.4510 20.92255 795.9331 16.54437 796.4152 9.651550 796.8973 4.050415 797.3795 0.6871950 797.8616 3.999573 798.3437 13.69263 798.8258 20.37616 799.3079 19.32904 799.7900 12.77875 800.2722 4.056335 800.7543 8.385986 801.2364 15.89270 801.7185 14.99432 802.2006 13.81812 802.6827 16.96155 803.1649 19.94916 803.6470 15.66650 804.1291 3.508789 804.6112 2.725281 805.0933 8.540894 805.5754 21.16364 806.0576 24.33124 806.5397 19.93268 807.0218 7.806946 807.5039 9.860962 807.9860 19.44385 808.4681 4.511963 808.9503 23.51849 809.4324 23.38330 809.9145 7.162109 810.3966 23.63538 810.8787 11.97900 811.3608 4.325806 811.8430 4.466675 812.3251 8.754272 812.8072 15.31934 813.2893 7.864380 813.7714 4.817505 814.2535 17.14258 814.7357 25.45081 815.2178 10.12537 815.6999 18.44250 816.1820 34.53784 816.6641 27.24780 817.1462 13.76746 817.6284 2.918823 818.1105 2.946411 818.5926 4.272827 819.0747 21.67993 819.5568 33.34180 820.0389 31.69922 820.5211 23.80225 821.0032 20.87476 821.4853 23.33191 821.9674 22.73584 822.4495 17.53894 822.9316 12.91223 823.4138 9.537231 823.8959 8.931396 824.3780 15.63794 824.8601 29.92639 825.3422 35.31750 825.8243 18.82837 826.3065 6.671753 826.7886 14.88940 827.2707 28.81055 827.7528 32.36609 828.2349 24.56799 828.7170 14.10864 829.1992 5.203735 829.6813 1.638428 830.1633 4.882813 830.6454 5.752319 831.1276 8.074707 831.6097 12.44775 832.0918 16.41064 832.5739 18.18823 833.0560 18.35803 833.5381 18.28967 834.0203 16.93835 834.5024 20.79565 834.9845 35.15784 835.4666 47.11023 835.9487 47.33923 836.4308 42.42542 836.9130 40.46094 837.3951 40.93433 837.8772 49.01697 838.3593 76.13721 838.8414 101.0497 839.3235 106.5691 839.8057 103.0065 840.2878 105.0468 840.7699 116.6945 841.2520 135.8237 841.7341 163.6908 842.2162 195.9330 842.6984 221.5935 843.1805 242.9482 843.6626 273.8511 844.1447 317.7209 844.6268 360.8944 845.1089 391.4635 845.5911 412.8911 846.0732 441.0609 846.5553 478.8430 847.0374 513.2738 847.5195 535.0273 848.0016 563.6606 848.4838 616.7477 848.9659 683.0789 849.4480 739.8831 849.9301 781.1467 850.4122 827.5864 850.8943 888.5293 851.3765 952.5209 851.8586 1007.518 852.3407 1061.816 852.8228 1131.695 853.3049 1220.271 853.7870 1309.782 854.2692 1380.318 854.7513 1443.256 855.2334 1524.066 855.7155 1618.106 856.1976 1699.026 856.6797 1759.108 857.1619 1815.775 857.6440 1886.888 858.1261 1967.709 858.6082 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