#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-04-26 13:27:57 +0300 (Thu, 26 Apr 2018) $ #$Revision: 466 $ #$URL: svn://172.16.1.111/rod/cif/1/00/00/1000031.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000031 loop_ _publ_author_name 'Cooper, M. A.' 'Hawthorne, F. C.' _publ_section_title ; The crystal structure of keyite, Cu3(Zn,Cu)4Cd2(AsO4)6(H2O)2, an oxysalt mineral with essential cadmium ; _journal_name_full 'The Canadian Mineralogist' _journal_page_first 623 _journal_page_last 630 _journal_volume 34 _journal_year 1996 _chemical_compound_source R050585 _chemical_formula_sum 'As3 Cd Cu1.5 H0.02 O14 Zn2' _chemical_name_mineral Keyite _space_group_IT_number 15 _symmetry_space_group_name_Hall '-I 2ya' _symmetry_space_group_name_H-M 'I 1 2/a 1' _cell_angle_alpha 90 _cell_angle_beta 99.11 _cell_angle_gamma 90 _cell_length_a 11.654 _cell_length_b 12.780 _cell_length_c 6.840 _cell_volume 1005.887 _exptl_crystal_density_diffrn 5.199 _cod_original_formula_sum 'Cu1.5 Zn2 Cd As3 O14 H.02' _cod_database_code 9010543 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R050585.rod _rod_data_source.block 3500000 _rod_database.code 1000031 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9010543 COD http://www.crystallography.net/cod/9010543.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 106.5063 0.0000000E+00 106.9884 49.54297 107.4705 109.4897 107.9526 146.4819 108.4348 156.0220 108.9169 139.9233 109.3990 109.0435 109.8811 35.67188 110.3632 5.174805 110.8453 0.7143550 111.3275 26.75098 111.8096 61.65186 112.2917 96.77246 112.7738 129.2949 113.2559 148.0571 113.7380 134.8271 114.2202 128.8872 114.7023 143.6826 115.1844 172.4824 115.6665 200.1001 116.1486 214.8623 116.6307 219.1162 117.1129 239.4424 117.5950 297.8672 118.0771 355.7842 118.5592 379.5220 119.0413 365.8511 119.5234 345.4712 120.0056 339.3057 120.4877 346.0605 120.9698 367.4019 121.4519 412.2163 121.9340 472.9668 122.4161 536.2212 122.8982 587.1567 123.3804 631.6753 123.8625 672.2852 124.3446 710.2720 124.8267 753.2036 125.3088 816.7437 125.7909 896.0713 126.2731 944.2349 126.7552 979.1982 127.2373 992.7808 127.7194 975.5176 128.2015 929.0708 128.6837 867.3804 129.1658 813.9829 129.6479 774.9307 130.1300 732.8965 130.6121 693.2749 131.0942 647.7798 131.5764 584.0679 132.0585 497.0977 132.5406 397.3486 133.0227 323.4380 133.5048 297.2031 133.9869 275.0820 134.4691 257.0400 134.9512 239.4678 135.4333 217.6392 135.9154 188.2520 136.3975 151.4722 136.8796 112.8618 137.3618 54.13135 137.8439 9.738770 138.3260 6.999512 138.8081 41.32373 139.2902 75.85352 139.7723 78.30176 140.2545 48.06445 140.7366 24.25635 141.2187 11.91797 141.7008 5.580566 142.1829 0.1005860 142.6650 4.713379 143.1472 10.39941 143.6293 23.52881 144.1114 41.76660 144.5935 49.68799 145.0756 33.64307 145.5577 1.051270 146.0399 21.94434 146.5220 21.75879 147.0041 22.58887 147.4862 50.65137 147.9683 104.0293 148.4504 149.4604 148.9326 146.9443 149.4147 89.36279 149.8968 59.07422 150.3789 103.7881 150.8610 161.0400 151.3431 199.9912 151.8252 213.4497 152.3074 210.9331 152.7895 204.1377 153.2716 185.7290 153.7537 179.7798 154.2358 196.6758 154.7179 220.9033 155.2001 238.5400 155.6822 243.6396 156.1643 241.7383 156.6464 250.2456 157.1285 296.7891 157.6106 318.5435 158.0928 287.1338 158.5749 232.5645 159.0570 198.1021 159.5391 211.2534 160.0212 266.1880 160.5033 289.1426 160.9855 252.2314 161.4676 215.9189 161.9497 201.6396 162.4318 204.2842 162.9139 208.0454 163.3960 202.2993 163.8782 190.5542 164.3603 176.2681 164.8424 149.5327 165.3245 127.7788 165.8066 127.0439 166.2887 148.2661 166.7709 174.2686 167.2530 192.9072 167.7351 203.4155 168.2172 138.8232 168.6993 213.0776 169.1814 255.6890 169.6636 268.8682 170.1457 162.0283 170.6278 210.7627 171.1099 196.0210 171.5920 178.2876 172.0741 247.2749 172.5563 156.2314 173.0384 223.7524 173.5205 227.9771 174.0026 261.6274 174.4847 233.1309 174.9668 222.8979 175.4490 275.2705 175.9311 292.8193 176.4132 255.7666 176.8953 290.5527 177.3774 197.0479 177.8595 216.0845 178.3417 283.6558 178.8238 249.6616 179.3059 285.4204 179.7880 294.6025 180.2701 183.0200 180.7522 282.1479 181.2344 289.7651 181.7165 203.7754 182.1986 294.5781 182.6807 221.3335 183.1628 206.6963 183.6449 236.0679 184.1271 219.3867 184.6092 275.0537 185.0913 260.9429 185.5734 241.5791 186.0555 250.8237 186.5376 240.0308 187.0198 240.0010 187.5019 240.7349 187.9840 246.7988 188.4661 263.7373 188.9482 279.9014 189.4303 294.7104 189.9125 308.2070 190.3946 321.7329 190.8767 336.4282 191.3588 350.0015 191.8409 351.5942 192.3230 328.9346 192.8052 307.9790 193.2873 289.6104 193.7694 276.2891 194.2515 273.6406 194.7336 286.8384 195.2157 312.6655 195.6979 320.9170 196.1800 306.7817 196.6621 286.9087 197.1442 258.5669 197.6263 226.6118 198.1084 205.9082 198.5906 209.6245 199.0727 235.1875 199.5548 245.0449 200.0369 233.5234 200.5190 212.9575 201.0011 181.8979 201.4833 142.6665 201.9654 115.0762 202.4475 119.4409 202.9296 154.5176 203.4117 181.2778 203.8938 205.4033 204.3760 213.9175 204.8581 186.9243 205.3402 121.8965 205.8223 56.70947 206.3044 20.83252 206.7865 9.417969 207.2687 7.045898 207.7508 17.06250 208.2329 32.61475 208.7150 45.13916 209.1971 54.62402 209.6792 59.01172 210.1614 49.42725 210.6435 32.42725 211.1256 24.54150 211.6077 42.45654 212.0898 72.39258 212.5719 82.32275 213.0541 63.42285 213.5362 39.01172 214.0183 22.41699 214.5004 12.68750 214.9825 8.534668 215.4646 13.41797 215.9468 24.43604 216.4289 27.93848 216.9110 15.42578 217.3931 7.281250 217.8752 21.57764 218.3573 50.42041 218.8395 70.97803 219.3216 63.36914 219.8037 30.08496 220.2858 1.388184 220.7679 26.43506 221.2500 43.92236 221.7322 44.17676 222.2143 30.32959 222.6964 12.11279 223.1785 4.298340 223.6606 19.00879 224.1427 29.85156 224.6249 38.07471 225.1070 40.52783 225.5891 32.74463 226.0712 16.96289 226.5533 0.3330080 227.0354 11.86475 227.5176 20.11963 227.9997 20.37012 228.4818 3.162598 228.9639 14.22363 229.4460 27.10107 229.9281 34.10498 230.4103 34.28223 230.8924 23.37256 231.3745 4.943848 231.8566 15.28857 232.3387 12.03418 232.8208 39.34424 233.3030 47.89648 233.7851 38.03223 234.2672 22.33789 234.7493 14.41602 235.2314 16.44189 235.7135 18.89307 236.1957 26.27490 236.6778 30.58447 237.1599 21.65967 237.6420 2.226074 238.1241 12.00537 238.6062 0.2612300 239.0884 55.97266 239.5705 81.08105 240.0526 52.60352 240.5347 17.33545 241.0168 6.003906 241.4989 19.86279 241.9811 36.87646 242.4632 29.54541 242.9453 17.51514 243.4274 40.22900 243.9095 30.31738 244.3916 6.359863 244.8738 27.37744 245.3559 66.83105 245.8380 100.6313 246.3201 114.1812 246.8022 97.71484 247.2843 91.42969 247.7665 108.9751 248.2486 126.2012 248.7307 119.0933 249.2128 87.57764 249.6949 57.73242 250.1770 61.13770 250.6592 112.6284 251.1413 147.5601 251.6234 157.6143 252.1055 157.8281 252.5876 156.9917 253.0697 157.0698 253.5519 158.8013 254.0340 163.0674 254.5161 170.4731 254.9982 178.7788 255.4803 187.3994 255.9624 197.2041 256.4445 213.7139 256.9267 234.9492 257.4088 249.0220 257.8909 239.0322 258.3730 196.2734 258.8551 177.6504 259.3372 199.9077 259.8194 235.4575 260.3015 264.5630 260.7836 284.4287 261.2657 299.3276 261.7478 313.4258 262.2299 326.7764 262.7121 335.4604 263.1942 334.8506 263.6763 332.2817 264.1584 335.5913 264.6405 345.1870 265.1227 352.5547 265.6048 347.1328 266.0869 327.9102 266.5690 324.1216 267.0511 353.5220 267.5332 387.0635 268.0154 401.9521 268.4975 396.4761 268.9796 378.6372 269.4617 349.8989 269.9438 311.1562 270.4259 289.1470 270.9081 299.3091 271.3902 315.8003 271.8723 316.2607 272.3544 300.3682 272.8365 285.6978 273.3186 287.3257 273.8008 303.7036 274.2829 311.6582 274.7650 305.9302 275.2471 295.1885 275.7292 282.7378 276.2113 269.5098 276.6935 263.4092 277.1756 275.4238 277.6577 299.8457 278.1398 302.5718 278.6219 254.2651 279.1040 206.0537 279.5862 200.0552 280.0683 232.6992 280.5504 265.9531 281.0325 276.7354 281.5146 267.5815 281.9967 259.4941 282.4789 250.3721 282.9610 243.9858 283.4431 246.4946 283.9252 255.6470 284.4073 258.1987 284.8894 244.6919 285.3716 220.1094 285.8537 200.6948 286.3358 186.5488 286.8179 178.8281 287.3000 183.0986 287.7821 195.9336 288.2643 202.4834 288.7464 193.0405 289.2285 175.1133 289.7106 168.4780 290.1927 178.7930 290.6748 192.5908 291.1570 206.7080 291.6391 220.0151 292.1212 227.9487 292.6033 226.5400 293.0854 222.0518 293.5675 230.1426 294.0497 260.7554 294.5318 277.1812 295.0139 253.2407 295.4960 204.3794 295.9781 164.2666 296.4602 144.4072 296.9424 140.2891 297.4245 148.8633 297.9066 172.7261 298.3887 192.2134 298.8708 202.5996 299.3529 204.5522 299.8351 196.2812 300.3172 174.9019 300.7993 150.2568 301.2814 139.7817 301.7635 147.1587 302.2456 150.3960 302.7278 140.9082 303.2099 123.8652 303.6920 101.1445 304.1741 71.39209 304.6562 51.36035 305.1383 68.27930 305.6205 124.9912 306.1026 163.2231 306.5847 169.1650 307.0668 156.3911 307.5489 131.3936 308.0310 95.25098 308.5132 67.03662 308.9953 70.11133 309.4774 105.7402 309.9595 120.2642 310.4416 84.83008 310.9237 46.54639 311.4059 54.98291 311.8880 107.1562 312.3701 144.3008 312.8522 112.5908 313.3343 17.91357 313.8164 29.50684 314.2986 7.661133 314.7807 56.62061 315.2628 79.83057 315.7449 78.86279 316.2270 65.72070 316.7091 43.19238 317.1913 15.93018 317.6734 9.730957 318.1555 39.18018 318.6376 70.41260 319.1197 97.80469 319.6018 117.6787 320.0840 118.4473 320.5661 90.73975 321.0482 46.84375 321.5303 29.25977 322.0124 50.42529 322.4945 75.83887 322.9767 101.6899 323.4588 126.7158 323.9409 148.6411 324.4230 166.5322 324.9051 182.1152 325.3872 199.9551 325.8694 232.0337 326.3515 247.1416 326.8336 224.4771 327.3157 191.1216 327.7978 174.5317 328.2799 182.5054 328.7621 203.6533 329.2442 221.5913 329.7263 231.9473 330.2084 248.5889 330.6905 272.6611 331.1726 302.7959 331.6548 346.3940 332.1369 399.0127 332.6190 441.3696 333.1011 455.4092 333.5832 432.4062 334.0653 432.1328 334.5475 467.8911 335.0296 510.5376 335.5117 548.8486 335.9938 580.1880 336.4759 605.5244 336.9580 629.3838 337.4402 651.7769 337.9223 666.0938 338.4044 661.5654 338.8865 660.8335 339.3686 669.1201 339.8507 685.3926 340.3329 706.7363 340.8150 731.4229 341.2971 760.3052 341.7792 797.9331 342.2613 863.6309 342.7434 913.1909 343.2256 933.8018 343.7077 939.5815 344.1898 942.6890 344.6719 948.1538 345.1540 959.1353 345.6361 984.6636 346.1183 1040.791 346.6004 1079.592 347.0825 1087.041 347.5646 1086.296 348.0467 1095.024 348.5288 1116.198 349.0110 1139.284 349.4931 1150.377 349.9752 1146.568 350.4573 1142.413 350.9394 1139.087 351.4215 1134.645 351.9037 1129.803 352.3858 1123.449 352.8679 1112.018 353.3500 1088.706 353.8321 1054.248 354.3142 1034.042 354.7964 1046.387 355.2785 1050.809 355.7606 1027.006 356.2427 984.4072 356.7248 941.6162 357.2069 908.1904 357.6891 882.5078 358.1712 862.8213 358.6533 855.9717 359.1354 838.9663 359.6175 793.9995 360.0996 737.8291 360.5818 690.1294 361.0639 659.3052 361.5460 633.4722 362.0281 593.8784 362.5102 537.8521 362.9923 491.1577 363.4745 470.4531 363.9566 457.5645 364.4387 433.7876 364.9208 395.8213 365.4029 358.3667 365.8850 332.5615 366.3672 316.9717 366.8493 303.9209 367.3314 294.1680 367.8135 283.0913 368.2956 262.8223 368.7777 234.3315 369.2599 212.6558 369.7420 209.5659 370.2241 215.7681 370.7062 216.1079 371.1883 208.7700 371.6704 195.9038 372.1526 181.0591 372.6347 163.1343 373.1168 139.8750 373.5989 96.13867 374.0810 58.00244 374.5631 53.47998 375.0453 78.53564 375.5274 101.6733 376.0095 105.2671 376.4916 91.79053 376.9737 74.30322 377.4558 43.61377 377.9380 19.69727 378.4201 13.98535 378.9022 20.29688 379.3843 25.66602 379.8664 23.50781 380.3485 17.24561 380.8307 11.77490 381.3128 7.354004 381.7949 3.518066 382.2770 4.317383 382.7591 3.550293 383.2412 8.813477 383.7234 31.60840 384.2055 51.96387 384.6876 55.55811 385.1697 34.37305 385.6518 19.80908 386.1339 17.41406 386.6161 15.26562 387.0982 3.606445 387.5803 13.48389 388.0624 21.84521 388.5445 8.515625 389.0266 22.45801 389.5088 26.17822 389.9909 39.18896 390.4730 83.83594 390.9551 82.56006 391.4372 55.31250 391.9193 22.24268 392.4015 8.523438 392.8836 30.45508 393.3657 27.67773 393.8478 10.45117 394.3299 47.75537 394.8120 86.89014 395.2942 117.3994 395.7763 129.8838 396.2584 123.8569 396.7405 110.0107 397.2226 91.67529 397.7047 68.74365 398.1869 71.30908 398.6690 119.5659 399.1511 172.9526 399.6332 213.9453 400.1153 241.7720 400.5974 255.4243 401.0796 246.0298 401.5617 224.3760 402.0438 215.9043 402.5259 224.1729 403.0080 231.9448 403.4901 227.5854 403.9723 218.8105 404.4544 212.7026 404.9365 208.8823 405.4186 211.8008 405.9007 230.2690 406.3828 260.6973 406.8650 282.8296 407.3471 287.3911 407.8292 282.8125 408.3113 283.2783 408.7934 289.9414 409.2755 294.5791 409.7577 286.6875 410.2398 278.2778 410.7219 290.9175 411.2040 328.3701 411.6861 366.0020 412.1682 377.0098 412.6504 356.5640 413.1325 350.2002 413.6146 367.8130 414.0967 389.7905 414.5788 415.2769 415.0609 437.1719 415.5431 435.4814 416.0252 394.7607 416.5073 326.1328 416.9894 281.4204 417.4715 282.1001 417.9536 281.6206 418.4358 274.8140 418.9179 265.1558 419.4000 255.0474 419.8821 245.7021 420.3642 239.7124 420.8463 243.2051 421.3285 264.1973 421.8106 272.2881 422.2927 257.3662 422.7748 239.1431 423.2569 225.3296 423.7390 216.6064 424.2212 211.5972 424.7033 212.3584 425.1854 216.1821 425.6675 204.2705 426.1496 165.4746 426.6317 129.6733 427.1139 107.9072 427.5960 95.27344 428.0781 85.55273 428.5602 76.38867 429.0423 70.49023 429.5244 76.53516 430.0066 95.10400 430.4887 98.28760 430.9708 66.20410 431.4529 26.70654 431.9350 10.03027 432.4171 16.82959 432.8993 33.19678 433.3814 64.80713 433.8635 98.49805 434.3456 107.4917 434.8277 86.37500 435.3098 55.61914 435.7920 26.64600 436.2741 1.513672 436.7562 5.892090 437.2383 19.82861 437.7204 49.58447 438.2025 71.01318 438.6847 82.96924 439.1668 82.92236 439.6489 68.49561 440.1310 44.41846 440.6131 23.01953 441.0952 11.61865 441.5774 23.00244 442.0595 15.54980 442.5416 64.73877 443.0237 88.22656 443.5058 79.92334 443.9879 58.58643 444.4701 45.52246 444.9522 43.03857 445.4343 37.32373 445.9164 22.30420 446.3985 8.834473 446.8806 3.697754 447.3628 11.95068 447.8449 9.840332 448.3270 3.866699 448.8091 23.71631 449.2912 37.48584 449.7733 45.56396 450.2555 44.97656 450.7376 25.86523 451.2197 4.764648 451.7018 5.132813 452.1839 3.953125 452.6660 2.239258 453.1482 10.15576 453.6303 19.38232 454.1124 28.33838 454.5945 38.11328 455.0766 45.10889 455.5587 45.86279 456.0409 41.51416 456.5230 33.79346 457.0051 15.92090 457.4872 0.2084960 457.9693 0.5722660 458.4514 11.60645 458.9336 26.81396 459.4157 43.14014 459.8978 55.90625 460.3799 49.25635 460.8620 5.475586 461.3441 21.20410 461.8262 10.36621 462.3083 16.19824 462.7905 37.82812 463.2726 49.95801 463.7547 55.99609 464.2368 59.03223 464.7189 58.57910 465.2010 58.97852 465.6832 62.10156 466.1653 63.93701 466.6474 60.92676 467.1295 56.17822 467.6116 53.76025 468.0938 55.36328 468.5759 62.74561 469.0580 83.33398 469.5401 127.2646 470.0222 155.6372 470.5043 148.0864 470.9865 132.6416 471.4686 127.9482 471.9507 134.6406 472.4328 138.7783 472.9149 124.8252 473.3970 99.37012 473.8792 86.40137 474.3613 88.32715 474.8434 98.65527 475.3255 118.8008 475.8076 143.9272 476.2897 165.0000 476.7719 187.2935 477.2540 196.8003 477.7361 170.9424 478.2182 123.0361 478.7003 94.19043 479.1824 99.70654 479.6646 125.7603 480.1467 154.4106 480.6288 192.4150 481.1109 210.1597 481.5930 180.7866 482.0751 150.3638 482.5573 159.8135 483.0394 202.2178 483.5215 238.5518 484.0036 239.6909 484.4857 211.4688 484.9678 192.6426 485.4500 188.8770 485.9321 187.6284 486.4142 185.8213 486.8963 186.3281 487.3784 194.4629 487.8605 211.6699 488.3427 228.7798 488.8248 233.7549 489.3069 227.5898 489.7890 219.5830 490.2711 209.4673 490.7532 200.3726 491.2354 190.1353 491.7175 181.2485 492.1996 178.5298 492.6817 184.3105 493.1638 197.1812 493.6459 218.4453 494.1281 245.4023 494.6102 264.5566 495.0923 270.1035 495.5744 268.5415 496.0565 275.3750 496.5386 295.3335 497.0208 302.1157 497.5029 275.2476 497.9850 240.8828 498.4671 230.0610 498.9492 241.2783 499.4313 249.3950 499.9135 234.9590 500.3956 198.2759 500.8777 174.5732 501.3598 171.1704 501.8419 172.2979 502.3240 182.1880 502.8062 192.3208 503.2883 189.9492 503.7704 171.2871 504.2525 153.4272 504.7346 164.1885 505.2167 211.2529 505.6989 230.8408 506.1810 200.9951 506.6631 166.7773 507.1452 148.2188 507.6273 142.0400 508.1094 139.6680 508.5916 137.3408 509.0737 137.1152 509.5558 143.8242 510.0379 157.4648 510.5200 166.9980 511.0021 167.1992 511.4843 162.4053 511.9664 159.2148 512.4485 158.0195 512.9306 155.3213 513.4127 146.6318 513.8948 138.3213 514.3770 140.6846 514.8591 151.8369 515.3412 155.6484 515.8233 79.58105 516.3054 150.8984 516.7875 190.4082 517.2697 199.7969 517.7518 88.68555 518.2339 133.1748 518.7160 115.1846 519.1981 93.35156 519.6802 159.0098 520.1624 65.35742 520.6445 130.3730 521.1266 132.0801 521.6087 162.7637 522.0908 130.7070 522.5729 118.0293 523.0551 168.1143 523.5372 183.4492 524.0193 144.1729 524.5014 176.7041 524.9835 80.94141 525.4656 97.75977 525.9478 163.1523 526.4299 127.0371 526.9120 160.7207 527.3941 167.8203 527.8762 54.11719 528.3583 150.5107 528.8405 156.0508 529.3226 68.29785 529.8047 157.5020 530.2868 82.61426 530.7689 66.29980 531.2510 94.06641 531.7332 75.88867 532.2153 130.1562 532.6974 114.6348 533.1795 92.87988 533.6616 98.33789 534.1437 26.68652 534.6259 98.09668 535.1080 71.80078 535.5901 94.08203 536.0722 127.3789 536.5543 76.37207 537.0364 114.6240 537.5186 14.47754 538.0007 30.14844 538.4828 33.35059 538.9649 110.5771 539.4470 11.11719 539.9291 86.55664 540.4113 60.97559 540.8934 37.26172 541.3755 43.29395 541.8576 61.95312 542.3397 66.13184 542.8218 52.90137 543.3040 34.64062 543.7861 19.61621 544.2682 7.564453 544.7503 3.457031 545.2324 26.71582 545.7145 32.75000 546.1967 6.728516 546.6788 54.66016 547.1609 62.74414 547.6430 24.96387 548.1251 15.21875 548.6072 1.967773 549.0894 67.90332 549.5715 92.35449 550.0536 34.75879 550.5357 16.29883 551.0178 23.56250 551.4999 7.209961 551.9821 5.497070 552.4642 6.271484 552.9463 4.393555 553.4284 10.72656 553.9105 22.07812 554.3926 24.49902 554.8748 13.84082 555.3569 0.7216800 555.8390 12.89258 556.3211 22.21289 556.8032 23.34277 557.2853 17.87793 557.7675 2.545898 558.2496 41.95898 558.7317 93.16211 559.2138 106.2803 559.6959 66.26367 560.1780 7.826172 560.6602 15.42090 561.1423 6.452148 561.6244 23.86133 562.1065 35.37305 562.5886 43.49512 563.0707 47.52930 563.5529 49.07031 564.0350 50.12402 564.5171 50.70410 564.9992 54.22949 565.4813 69.41211 565.9634 94.63477 566.4456 103.9863 566.9277 83.01758 567.4098 59.71191 567.8919 70.22852 568.3740 110.2285 568.8561 138.4551 569.3383 126.4521 569.8204 121.6357 570.3025 174.5107 570.7846 258.3867 571.2667 306.8252 571.7488 291.9863 572.2310 238.2422 572.7131 185.4805 573.1952 124.0322 573.6773 90.07129 574.1594 96.47070 574.6415 115.8350 575.1237 149.7783 575.6058 186.6934 576.0879 204.9248 576.5700 190.8379 577.0521 161.0576 577.5342 138.4912 578.0164 123.0557 578.4985 114.9443 578.9806 116.6465 579.4627 121.1523 579.9448 117.5684 580.4269 107.4424 580.9091 108.6650 581.3912 137.4385 581.8733 167.0391 582.3554 176.9902 582.8375 173.0225 583.3196 172.9717 583.8018 184.2158 584.2839 196.8662 584.7660 192.6963 585.2481 163.4609 585.7302 140.8486 586.2123 126.1758 586.6945 116.2891 587.1766 112.6211 587.6587 115.1240 588.1408 123.7295 588.6229 141.5537 589.1050 159.6484 589.5872 163.6670 590.0693 154.5400 590.5514 135.5762 591.0335 95.67969 591.5156 68.67969 591.9977 108.9092 592.4799 207.4248 592.9620 259.3945 593.4441 225.4277 593.9262 173.8477 594.4083 131.2822 594.8904 103.8838 595.3726 109.9648 595.8547 155.4219 596.3368 208.3154 596.8189 218.0918 597.3010 171.8203 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