#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-04-26 13:35:54 +0300 (Thu, 26 Apr 2018) $ #$Revision: 491 $ #$URL: svn://172.16.1.111/rod/cif/1/00/00/1000046.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000046 loop_ _publ_author_name 'Menchetti, S.' 'Sabelli, C.' _publ_section_title ; The halotrichite group: The crystal structure of apjohnite Locality: Terlano, Bolzano, Italy ; _journal_name_full 'Mineralogical Magazine' _journal_page_first 599 _journal_page_last 608 _journal_paper_doi 10.1180/minmag.1976.040.314.07 _journal_volume 40 _journal_year 1976 _chemical_compound_source R060231 _chemical_formula_sum 'Al2 Fe0.02 H44 Mg0.28 Mn0.64 O38 S4 Zn0.06' _chemical_name_mineral Apjohnite _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90 _cell_angle_beta 100.28 _cell_angle_gamma 90 _cell_length_a 6.198 _cell_length_b 24.347 _cell_length_c 21.266 _cell_volume 3157.583 _exptl_crystal_density_diffrn 1.854 _cod_original_formula_sum '(Mn.64 Mg.28 Zn.06 Fe.02) Al2 S4 O38 H44' _cod_database_code 9009454 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R060231.rod _rod_data_source.block 3500000 _rod_database.code 1000046 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9009454 COD http://www.crystallography.net/cod/9009454.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 150.1633 0.0000000E+00 150.6454 0.3898020 151.1275 4.204967 151.6096 6.778015 152.0917 5.668985 152.5739 2.972619 153.0560 2.193347 153.5381 3.926972 154.0202 6.014908 154.5023 5.937703 154.9844 3.453005 155.4665 1.222234 155.9487 0.7063350 156.4308 0.8705400 156.9129 1.276092 157.3950 2.391750 157.8771 2.329811 158.3592 2.014662 158.8414 2.397152 159.3235 2.781104 159.8056 3.224034 160.2877 3.575801 160.7698 3.658745 161.2519 3.415577 161.7341 2.998008 162.2162 2.557014 162.6983 1.839123 163.1804 0.9076560 163.6625 0.6100150 164.1446 2.1645000E-02 164.6268 0.3667010 165.1089 0.6717600 165.5910 0.7572600 166.0731 2.605163 166.5552 2.330756 167.0373 2.448257 167.5195 3.383124 168.0016 4.327416 168.4837 5.140235 168.9658 5.623707 169.4479 5.791756 169.9300 5.984361 170.4122 6.214298 170.8943 6.461123 171.3764 7.100327 171.8585 7.945860 172.3406 8.109981 172.8227 6.628038 173.3049 3.785005 173.7870 2.199211 174.2691 2.484467 174.7512 3.576185 175.2333 4.873186 175.7154 6.368865 176.1976 7.586500 176.6797 8.277375 177.1618 8.400773 177.6439 7.800182 178.1260 5.651821 178.6081 3.043921 179.0903 1.746464 179.5724 2.197152 180.0545 2.678530 180.5366 1.897829 181.0187 0.4539980 181.5008 0.7133100 181.9830 0.6414170 182.4651 0.8179600 182.9472 0.7833230 183.4293 0.1051110 183.9114 0.5949920 184.3935 0.2694500 184.8757 0.7346120 185.3578 0.5209220 185.8399 0.5522090 186.3220 3.923465 186.8041 6.052402 187.2862 7.007551 187.7684 3.280479 188.2505 5.591821 188.7326 5.478821 189.2147 5.263414 189.6968 8.415886 190.1789 5.354002 190.6611 8.447300 191.1432 9.079122 191.6253 10.83297 192.1074 10.14855 192.5895 10.21316 193.0716 9.114244 193.5538 8.736812 194.0359 9.147198 194.5180 9.683406 195.0001 10.62883 195.4822 11.43833 195.9643 11.90201 196.4465 12.00999 196.9286 11.78203 197.4107 11.13193 197.8928 9.952304 198.3749 9.512527 198.8570 10.30602 199.3392 11.37899 199.8213 12.70429 200.3034 14.24264 200.7855 15.33823 201.2676 15.02018 201.7497 13.24514 202.2319 12.53943 202.7140 14.52885 203.1961 17.03825 203.6782 16.75805 204.1603 13.64758 204.6424 10.98230 205.1246 11.41100 205.6067 14.54450 206.0888 17.44312 206.5709 19.20583 207.0530 20.67735 207.5351 22.63645 208.0173 25.38865 208.4994 27.53803 208.9815 27.55746 209.4636 26.26168 209.9457 25.26653 210.4278 25.43835 210.9100 26.30959 211.3921 26.80518 211.8742 26.47885 212.3563 26.29638 212.8384 26.84200 213.3205 27.89352 213.8027 28.96533 214.2848 29.84174 214.7669 30.54267 215.2490 31.29732 215.7311 32.57703 216.2132 33.13839 216.6954 31.94913 217.1775 29.82578 217.6596 28.16652 218.1417 27.94397 218.6238 28.90037 219.1059 29.20417 219.5881 28.34525 220.0702 27.45027 220.5523 26.74833 221.0344 26.26288 221.5165 25.97118 221.9986 25.94297 222.4808 26.16431 222.9629 26.28036 223.4450 26.33716 223.9271 26.27960 224.4092 26.13247 224.8913 25.86806 225.3735 25.39251 225.8556 24.61241 226.3377 23.57972 226.8198 22.80296 227.3019 22.69588 227.7840 22.42109 228.2662 21.59348 228.7483 20.48553 229.2304 19.59191 229.7125 19.22730 230.1946 19.34910 230.6767 19.53368 231.1589 20.57343 231.6410 20.80658 232.1231 19.08607 232.6052 16.28577 233.0873 14.07963 233.5694 13.51177 234.0516 14.36393 234.5337 15.11865 235.0158 16.35885 235.4979 16.91580 235.9800 15.83241 236.4621 13.78138 236.9443 12.29038 237.4264 12.32673 237.9085 13.45893 238.3906 13.66294 238.8727 12.18523 239.3548 10.75410 239.8370 10.14301 240.3191 10.12099 240.8012 10.07417 241.2833 9.694316 241.7654 9.085032 242.2475 8.657292 242.7297 8.287607 243.2118 8.299235 243.6939 8.860689 244.1760 9.852787 244.6581 11.06842 245.1402 12.93715 245.6224 14.26022 246.1045 12.47792 246.5866 6.318166 247.0687 0.8698570 247.5508 0.9197250 248.0329 0.1827600 248.5151 1.655092 248.9972 2.995309 249.4793 3.879797 249.9614 3.708913 250.4435 2.271538 250.9256 1.177731 251.4078 1.632859 251.8899 3.284648 252.3720 4.632104 252.8541 5.451133 253.3362 5.575360 253.8183 4.827822 254.3005 3.219285 254.7826 1.446562 255.2647 0.7002750 255.7468 0.4843070 256.2289 0.5874010 256.7110 1.029042 257.1931 4.959939 257.6753 4.973159 258.1574 1.608855 258.6395 0.7199310 259.1216 1.6763000E-02 259.6037 1.020679 260.0858 0.5576740 260.5680 0.3900170 261.0501 0.9749980 261.5322 0.7235600 262.0143 0.7011620 262.4964 0.4885940 262.9785 0.4982310 263.4607 0.9300400 263.9428 0.3340990 264.4249 0.1632290 264.9070 0.4628690 265.3891 1.179833 265.8712 4.6510000E-02 266.3534 1.533402 266.8355 3.669870 267.3176 5.954417 267.7997 5.938119 268.2818 1.569176 268.7639 0.5356700 269.2461 0.2849500 269.7282 0.7371180 270.2103 7.3035002E-02 270.6924 2.125108 271.1745 4.306330 271.6566 2.848523 272.1388 4.582154 272.6209 5.384307 273.1030 5.308980 273.5851 1.486383 274.0672 2.687698 274.5493 1.988684 275.0315 1.289044 275.5136 3.427995 275.9957 0.5656950 276.4778 2.822243 276.9599 3.148430 277.4420 4.475758 277.9242 3.890867 278.4063 4.002398 278.8884 6.188615 279.3705 7.352086 279.8526 6.861964 280.3347 8.734649 280.8169 6.613081 281.2990 8.149006 281.7811 11.30909 282.2632 11.32559 282.7453 13.64065 283.2274 12.89793 283.7096 14.15520 284.1917 14.79789 284.6738 14.49604 285.1559 13.91291 285.6380 13.21243 286.1201 12.53901 286.6023 12.18438 287.0844 12.55689 287.5665 13.88453 288.0486 15.03398 288.5307 15.42607 289.0128 16.15487 289.4950 18.19434 289.9771 21.17545 290.4592 23.73768 290.9413 24.48826 291.4234 23.20882 291.9055 23.00065 292.3877 25.31680 292.8698 27.23744 293.3519 27.46703 293.8340 26.54240 294.3161 25.74128 294.7982 25.97671 295.2804 27.16937 295.7625 28.20851 296.2446 29.01134 296.7267 29.72754 297.2088 30.62142 297.6909 31.40278 298.1731 31.45815 298.6552 30.39858 299.1373 28.71141 299.6194 28.26726 300.1015 30.81088 300.5836 32.52833 301.0658 32.40224 301.5479 31.60550 302.0300 31.41590 302.5121 32.33460 302.9942 33.94977 303.4763 35.44455 303.9585 37.03070 304.4406 38.15276 304.9227 38.39311 305.4048 38.32367 305.8869 38.64786 306.3690 39.40070 306.8512 40.35045 307.3333 41.12961 307.8154 41.60632 308.2975 42.35623 308.7796 44.07848 309.2617 45.34472 309.7439 45.05005 310.2260 43.27480 310.7081 40.87572 311.1902 38.44482 311.6723 35.67426 312.1544 35.14198 312.6366 39.06196 313.1187 42.76211 313.6008 44.62852 314.0829 44.67860 314.5650 43.42278 315.0471 40.84619 315.5293 37.05402 316.0114 34.31012 316.4935 33.19850 316.9756 32.53292 317.4577 32.57516 317.9398 32.73900 318.4220 31.84878 318.9041 29.36235 319.3862 26.23531 319.8683 25.20493 320.3504 29.32618 320.8326 31.60596 321.3147 30.77395 321.7968 28.50958 322.2789 26.14719 322.7610 24.19957 323.2431 22.72944 323.7253 21.93255 324.2074 22.06770 324.6895 22.18935 325.1716 21.83884 325.6537 21.50582 326.1358 21.76058 326.6180 22.55025 327.1001 23.46294 327.5822 23.94252 328.0643 23.95917 328.5464 24.23729 329.0285 25.31906 329.5107 26.11942 329.9928 26.25788 330.4749 25.75079 330.9570 24.64695 331.4391 22.82991 331.9212 20.45975 332.4034 19.33170 332.8855 21.02045 333.3676 22.31390 333.8497 22.51105 334.3318 21.95569 334.8139 21.09035 335.2961 20.15412 335.7782 19.05528 336.2603 17.50518 336.7424 14.43002 337.2245 12.59503 337.7066 13.09999 338.1888 14.29931 338.6709 14.67235 339.1530 13.84853 339.6351 12.56711 340.1172 11.82810 340.5993 11.54860 341.0815 12.09717 341.5636 15.07067 342.0457 17.44259 342.5278 16.81402 343.0099 13.67448 343.4920 10.69372 343.9742 10.61406 344.4563 13.67458 344.9384 15.16308 345.4205 13.18843 345.9026 11.39616 346.3847 11.11172 346.8669 11.65383 347.3490 11.60506 347.8311 10.00154 348.3132 7.372387 348.7953 5.915303 349.2774 6.488787 349.7596 6.934336 350.2417 6.593398 350.7238 6.064159 351.2059 6.079716 351.6880 6.877373 352.1701 7.837565 352.6523 7.748621 353.1344 5.996131 353.6165 5.094486 354.0986 6.551804 354.5807 7.950024 355.0628 7.724877 355.5450 5.877018 356.0271 3.612030 356.5092 1.876642 356.9913 0.6712540 357.4734 0.2330170 357.9555 1.186824 358.4377 2.266655 358.9198 3.282202 359.4019 4.016273 359.8840 4.022793 360.3661 2.815207 360.8482 0.8678630 361.3304 0.3947070 361.8125 0.7997470 362.2946 0.8585910 362.7767 0.6654450 363.2588 0.2875640 363.7409 0.3901920 364.2231 1.501876 364.7052 2.323060 365.1873 1.509218 365.6694 1.227262 366.1515 0.1315210 366.6336 0.8475540 367.1158 0.8561100 367.5979 0.2174150 368.0800 0.8828970 368.5621 1.199579 369.0442 1.292673 369.5263 1.098126 370.0085 8.5176997E-02 370.4906 0.8801390 370.9727 1.167979 371.4548 0.9596490 371.9369 0.7474640 372.4190 1.172410 372.9012 1.0080000E-02 373.3833 0.5362890 373.8654 0.4523340 374.3475 0.4779180 374.8296 1.657877 375.3117 1.769251 375.7939 0.7435960 376.2760 3.0576000E-02 376.7581 5.0145000E-02 377.2402 0.4028660 377.7223 1.010821 378.2044 2.909046 378.6866 5.460525 379.1687 5.786657 379.6508 4.602532 380.1329 2.408514 380.6150 0.7554730 381.0971 0.6755290 381.5793 1.629287 382.0614 3.152440 382.5435 3.026332 383.0256 1.080567 383.5077 0.9768730 383.9898 1.742628 384.4720 1.379557 384.9541 1.423440 385.4362 2.280463 385.9183 1.381481 386.4004 0.8406070 386.8825 0.5941040 387.3647 0.4371850 387.8468 0.3234340 388.3289 0.1595240 388.8110 0.3862710 389.2931 1.734329 389.7752 2.519458 390.2574 1.664619 390.7395 0.4491610 391.2216 0.6144940 391.7037 2.501024 392.1858 4.877810 392.6679 6.382339 393.1501 6.889318 393.6322 6.878304 394.1143 5.731984 394.5964 4.671161 395.0785 4.539473 395.5606 5.108501 396.0428 5.468391 396.5249 4.931250 397.0070 3.859867 397.4891 4.241756 397.9712 8.629462 398.4533 11.38135 398.9355 10.68913 399.4176 8.616138 399.8997 7.377041 400.3818 7.662750 400.8639 8.671298 401.3460 9.128165 401.8282 8.507690 402.3103 8.835268 402.7924 10.09460 403.2745 12.16648 403.7566 15.99101 404.2387 20.72290 404.7209 24.04846 405.2030 23.82504 405.6851 20.73783 406.1672 20.12812 406.6493 23.77704 407.1314 27.48140 407.6136 30.68776 408.0957 33.25219 408.5778 34.81585 409.0599 35.23179 409.5420 35.34610 410.0241 36.77668 410.5063 40.04937 410.9884 41.72036 411.4705 38.33023 411.9526 35.72818 412.4347 38.24055 412.9168 45.02084 413.3990 51.40593 413.8811 53.74670 414.3632 53.07002 414.8453 53.06099 415.3274 53.61773 415.8095 55.12165 416.2917 58.74822 416.7738 63.14156 417.2559 66.46711 417.7380 68.09111 418.2201 68.94964 418.7022 69.96427 419.1844 71.03546 419.6665 71.48653 420.1486 70.73646 420.6307 69.86241 421.1128 70.35024 421.5949 72.19384 422.0771 73.87497 422.5592 75.12839 423.0413 75.78463 423.5234 75.07339 424.0055 72.99390 424.4876 71.39921 424.9698 71.99167 425.4519 74.39528 425.9340 75.76595 426.4161 75.36211 426.8982 74.73985 427.3803 74.90442 427.8625 75.31707 428.3446 74.47115 428.8267 71.80097 429.3088 68.67485 429.7909 67.47193 430.2730 69.68707 430.7552 70.43867 431.2373 68.33254 431.7194 65.60493 432.2015 63.61484 432.6836 62.53617 433.1657 62.21870 433.6479 62.67749 434.1300 63.77994 434.6121 64.01945 435.0942 62.37218 435.5763 61.08478 436.0584 60.30952 436.5406 60.09626 437.0227 60.66751 437.5048 62.07043 437.9869 63.92985 438.4690 65.86279 438.9511 68.35764 439.4333 69.16494 439.9154 66.10680 440.3975 63.38733 440.8796 63.17490 441.3617 64.93526 441.8438 67.05369 442.3260 68.60958 442.8081 69.72253 443.2902 70.64194 443.7723 71.21576 444.2544 72.24464 444.7365 74.74526 445.2187 77.40987 445.7008 78.95229 446.1829 79.14023 446.6650 78.87411 447.1471 78.22575 447.6292 77.56143 448.1114 78.57232 448.5935 82.12779 449.0756 86.24340 449.5577 89.60197 450.0398 92.21242 450.5219 93.87461 451.0041 93.33118 451.4862 92.72309 451.9683 94.42530 452.4504 98.02484 452.9325 101.3111 453.4146 103.4142 453.8968 104.5486 454.3789 104.8989 454.8610 104.2851 455.3431 103.7550 455.8252 103.3771 456.3073 103.4385 456.7895 104.4785 457.2716 106.4614 457.7537 108.5000 458.2358 109.8657 458.7179 110.5596 459.2000 110.8746 459.6822 110.5278 460.1643 110.1962 460.6464 109.9129 461.1285 109.8349 461.6106 110.3116 462.0927 111.3413 462.5748 112.4140 463.0569 112.5647 463.5391 111.5666 464.0212 110.2297 464.5033 107.9970 464.9854 105.9673 465.4675 104.7049 465.9496 104.0791 466.4318 103.6945 466.9139 103.3750 467.3960 103.0183 467.8781 102.2243 468.3602 100.7371 468.8423 99.47560 469.3245 99.10433 469.8066 98.80922 470.2887 97.96304 470.7708 96.47430 471.2529 94.62655 471.7350 92.34930 472.2172 89.84511 472.6993 88.10281 473.1814 87.54195 473.6635 86.75150 474.1456 84.30126 474.6277 80.89852 475.1099 78.18418 475.5920 77.13007 476.0741 75.91205 476.5562 72.91570 477.0383 68.75117 477.5204 64.95768 478.0026 62.12226 478.4847 59.87814 478.9668 57.87637 479.4489 56.25576 479.9310 54.09413 480.4131 50.31699 480.8953 46.90178 481.3774 45.79111 481.8595 46.25844 482.3416 45.95916 482.8237 43.42533 483.3058 39.32066 483.7880 36.10850 484.2701 34.62394 484.7522 33.02631 485.2343 31.39481 485.7164 29.65108 486.1985 27.68063 486.6807 25.47687 487.1628 23.15623 487.6449 20.61458 488.1270 17.94471 488.6091 16.61049 489.0912 17.90597 489.5734 18.53779 490.0555 16.96511 490.5376 14.58481 491.0197 12.89382 491.5018 12.39245 491.9839 12.40344 492.4661 12.36566 492.9482 12.26676 493.4303 11.41200 493.9124 9.432674 494.3945 7.330129 494.8766 5.849493 495.3588 4.913279 495.8409 4.333762 496.3230 4.483910 496.8051 4.459897 497.2872 3.000788 497.7693 0.6370470 498.2515 0.4818660 498.7336 0.7182310 499.2157 3.155057 499.6978 5.591720 500.1799 8.465885 500.6620 9.294662 501.1442 6.263696 501.6263 2.640009 502.1084 0.7298920 502.5905 0.4139080 503.0726 0.1850250 503.5547 0.9640520 504.0369 1.879770 504.5190 0.9990200 505.0011 2.091212 505.4832 1.178460 505.9653 0.1779540 506.4474 0.6018220 506.9296 1.041076 507.4117 1.132373 507.8938 0.9034850 508.3759 0.2273340 508.8580 0.7491380 509.3401 1.000444 509.8223 3.4076001E-02 510.3044 0.5836320 510.7865 0.7031040 511.2686 1.467249 511.7507 0.9722990 512.2328 1.769009 512.7150 0.3956580 513.1971 0.6015360 513.6792 1.244704 514.1613 1.551986 514.6434 1.477547 515.1255 1.284688 515.6077 1.019524 516.0898 0.8011310 516.5719 1.084725 517.0540 2.867070 517.5361 3.967290 518.0182 2.348042 518.5004 0.3286370 518.9825 0.8613290 519.4646 1.583726 519.9467 4.621142 520.4288 5.319582 520.9109 3.208537 521.3931 1.889832 521.8752 1.483536 522.3573 1.580467 522.8394 2.565988 523.3215 3.805620 523.8036 4.188736 524.2858 3.296544 524.7679 2.143843 525.2500 2.639705 525.7321 5.314739 526.2142 6.930774 526.6964 6.395966 527.1785 5.714298 527.6606 5.843821 528.1427 6.539479 528.6248 7.218694 529.1069 7.703576 529.5891 7.946898 530.0712 8.013678 530.5533 7.874602 531.0354 6.850961 531.5175 4.229954 531.9996 1.482406 532.4818 0.6978710 532.9639 1.700580 533.4460 2.227015 533.9281 0.8783890 534.4102 0.3220320 534.8923 0.7926040 535.3745 3.509681 535.8566 5.315725 536.3387 4.996591 536.8208 3.325136 537.3029 1.851362 537.7850 0.5485650 538.2672 0.4916720 538.7493 1.199932 539.2314 0.6380230 539.7135 0.6779200 540.1956 1.191152 540.6777 0.5859060 541.1599 0.4360030 541.6420 1.302838 542.1241 0.7893100 542.6062 0.7604480 543.0883 1.060830 543.5704 1.070714 544.0526 0.6233140 544.5347 0.4882070 545.0168 0.6461620 545.4989 0.7434830 545.9810 0.3505730 546.4631 7.4132003E-02 546.9453 0.6441300 547.4274 2.448835 547.9095 2.919791 548.3916 0.4733480 548.8737 0.6102580 549.3558 1.853216 549.8380 0.4728690 550.3201 0.4575180 550.8022 0.1687510 551.2843 1.041702 551.7664 1.085398 552.2485 0.3834080 552.7307 0.4641120 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30.55943 948.5484 31.39623 949.0305 32.36547 949.5126 33.63824 949.9948 35.50642 950.4769 37.23661 950.9590 37.69597 951.4411 37.82535 951.9232 39.24011 952.4053 41.82289 952.8875 44.63682 953.3696 47.30769 953.8517 50.02739 954.3338 53.35451 954.8159 56.73749 955.2980 58.30558 955.7802 58.43816 956.2623 60.02359 956.7444 63.54258 957.2265 66.92591 957.7086 68.90819 958.1907 70.65645 958.6729 74.22486 959.1550 79.59235 959.6371 85.65230 960.1192 92.93240 960.6013 98.64810 961.0834 101.5517 961.5656 103.8146 962.0477 106.8403 962.5298 110.9029 963.0119 116.9919 963.4940 126.7989 963.9761 134.8051 964.4583 139.9495 964.9404 144.4347 965.4225 147.7128 965.9046 151.2964 966.3867 157.0153 966.8688 164.6909 967.3510 172.6456 967.8331 181.5187 968.3152 188.6851 968.7973 191.6142 969.2794 195.0950 969.7615 202.3790 970.2437 211.6184 970.7258 220.4984 971.2079 228.6711 971.6900 236.0013 972.1721 241.9810 972.6542 247.5432 973.1364 255.1207 973.6185 261.6783 974.1006 262.6288 974.5827 259.8775 975.0648 259.0497 975.5469 261.7254 976.0291 263.1687 976.5112 258.5783 976.9933 251.4550 977.4754 245.7697 977.9575 241.5024 978.4396 238.5567 978.9218 236.9304 979.4039 236.1977 979.8860 236.1068 980.3681 237.4088 980.8502 240.4669 981.3323 246.0278 981.8145 258.0182 982.2966 275.5676 982.7787 291.6291 983.2608 304.7099 983.7429 318.6666 984.2250 335.8632 984.7072 355.6170 985.1893 376.8823 985.6714 399.6509 986.1535 423.1080 986.6356 447.3095 987.1177 472.2134 987.5999 498.3311 988.0820 524.3951 988.5641 549.9409 989.0462 573.9553 989.5283 592.7143 990.0104 605.3943 990.4926 615.4921 990.9747 623.7452 991.4568 627.7370 991.9389 624.3436 992.4210 618.8794 992.9031 617.2953 993.3853 618.6625 993.8674 616.5689 994.3495 610.9763 994.8316 602.0478 995.3137 591.2989 995.7958 575.4052 996.2780 553.0426 996.7601 524.9863 997.2422 490.2092 997.7243 449.6949 998.2064 410.2496 998.6885 372.9370 999.1707 337.4203 999.6528 303.3930 1000.135 271.3334 1000.617 241.4627 1001.099 213.9059 1001.581 188.8913 1002.063 166.3540 1002.545 147.0759 1003.028 132.3142 1003.510 119.4624 1003.992 107.7197 1004.474 96.72180 1004.956 85.65955 1005.438 75.25919 1005.920 67.08545 1006.402 61.37749 1006.885 56.23677 1007.367 50.10096 1007.849 44.52011 1008.331 41.73972 1008.813 39.97186 1009.295 36.59572 1009.777 31.86468 1010.259 26.99986 1010.741 22.55601 1011.224 19.23717 1011.706 18.26181 1012.188 18.12378 1012.670 16.27229 1013.152 13.54099 1013.634 12.08151 1014.116 11.82693 1014.598 11.11597 1015.081 9.232578 1015.563 7.041895 1016.045 5.379047 1016.527 4.223963 1017.009 3.589795 1017.491 3.423970 1017.973 3.700296 1018.455 4.318163 1018.937 4.281410 1019.420 3.055319 1019.902 1.344777 1020.384 1.8010000E-03 1020.866 0.9730020 1021.348 1.566551 1021.830 1.605704 1022.312 1.640737 1022.794 1.518210 1023.276 1.240171 1023.759 1.013748 1024.241 0.9602020 1024.723 1.282210 1025.205 1.568921 1025.687 0.5418040 1026.169 1.048925 1026.651 1.122476 1027.133 1.086883 1027.616 0.6882020 1028.098 0.8514000 1028.580 1.803514 1029.062 1.817167 1029.544 0.4682840 1030.026 0.1263580 1030.508 1.243577 1030.990 1.623882 1031.473 0.3507650 1031.955 0.4365790 1032.437 0.9039390 1032.919 0.8291730 1033.401 0.2090790 1033.883 0.1619550 1034.365 0.1054020 1034.847 0.6904920 1035.329 1.189380 1035.812 0.8610980 1036.294 0.7999400 1036.776 2.449039 1037.258 4.320628 1037.740 3.174402 1038.222 1.662338 1038.704 0.5636740 1039.186 2.237839 1039.668 3.012805 1040.151 2.087294 1040.633 1.325840 1041.115 2.423160 1041.597 4.256085 1042.079 4.407746 1042.561 2.443329 1043.043 1.717848 1043.525 3.341707 1044.008 4.735204 1044.490 5.366367 1044.972 5.758991 1045.454 6.087867 1045.936 6.453515 1046.418 7.294030 1046.900 8.815725 1047.382 8.914878 1047.865 5.051632 1048.347 3.005671 1048.829 6.319784 1049.311 9.572295 1049.793 8.214533 1050.275 4.827299 1050.757 4.357770 1051.239 7.468042 1051.721 9.581587 1052.203 8.926006 1052.686 8.410682 1053.168 9.034706 1053.650 9.865859 1054.132 10.35521 1054.614 10.56610 1055.096 10.74713 1055.578 10.92049 1056.060 10.61411 1056.543 8.636074 1057.025 7.642683 1057.507 8.931358 1057.989 11.03328 1058.471 13.86367 1058.953 16.33143 1059.435 16.53065 1059.917 14.37819 1060.400 12.66885 1060.882 11.96707 1061.364 12.31157 1061.846 14.81247 1062.328 17.25488 1062.810 17.88268 1063.292 17.46398 1063.774 17.21338 1064.256 17.30077 1064.739 17.35817 1065.221 17.56087 1065.703 17.19738 1066.185 14.89173 1066.667 13.03469 1067.149 13.83000 1067.631 15.89510 1068.113 17.42961 1068.595 18.10401 1069.078 18.02824 1069.560 16.98557 1070.042 15.75483 1070.524 14.02473 1071.006 12.92237 1071.488 13.75340 1071.970 15.37302 1072.452 16.31452 1072.935 16.47206 1073.417 16.34650 1073.899 15.67195 1074.381 16.06385 1074.863 20.13002 1075.345 23.49806 1075.827 22.72459 1076.309 19.86799 1076.792 16.68737 1077.274 13.98581 1077.756 13.34769 1078.238 15.75154 1078.720 17.76278 1079.202 17.71393 1079.684 16.94266 1080.166 15.63270 1080.648 14.56386 1081.130 14.87938 1081.613 16.07592 1082.095 16.48334 1082.577 15.50684 1083.059 14.72814 1083.541 15.08981 1084.023 15.61330 1084.505 15.97443 1084.987 16.19894 1085.469 16.38653 1085.952 16.35953 1086.434 15.91415 1086.916 15.10021 1087.398 13.76996 1087.880 10.75485 1088.362 8.329026 1088.844 8.112309 1089.326 8.710754 1089.809 8.682546 1090.291 8.409991 1090.773 9.285677 1091.255 11.46630 1091.737 12.55714 1092.219 10.71703 1092.701 8.950314 1093.183 8.526793 1093.666 8.543058 1094.148 8.655093 1094.630 8.441862 1095.112 7.238611 1095.594 5.375858 1096.076 4.376451 1096.558 4.965343 1097.040 5.571705 1097.522 5.712814 1098.005 5.760982 1098.487 6.099568 1098.969 6.346961 1099.451 6.028707 1099.933 5.189998 1100.415 4.093202 1100.897 2.445374 1101.379 1.603153 1101.861 2.433330 1102.344 3.490335 1102.826 4.370044 1103.308 5.020979 1103.790 5.255030 1104.272 5.271193 1104.754 5.599690 1105.236 6.372977 1105.718 7.128483 1106.201 8.716876 1106.683 9.000543 1107.165 5.786875 1107.647 2.642034 1108.129 2.288302 1108.611 3.941153 1109.093 6.769417 1109.575 10.73850 1110.057 12.03932 1110.540 7.854233 1111.022 4.554843 1111.504 2.635177 1111.986 2.447460 1112.468 6.487983 1112.950 11.22503 1113.432 11.30276 1113.914 7.070817 1114.396 5.008749 1114.879 6.708024 1115.361 7.847734 1115.843 8.054982 1116.325 8.168130 1116.807 8.582759 1117.289 8.920184 1117.771 8.634166 1118.253 7.954880 1118.736 8.140425 1119.218 9.767565 1119.700 9.981079 1120.182 7.138355 1120.664 6.769325 1121.146 12.14853 1121.628 16.81389 1122.110 15.62303 1122.593 11.14134 1123.075 8.607530 1123.557 8.070339 1124.039 8.548088 1124.521 10.38785 1125.003 12.09943 1125.485 13.53851 1125.967 14.35734 1126.449 14.20280 1126.932 13.54324 1127.414 12.82745 1127.896 12.24108 1128.378 12.53423 1128.860 13.92677 1129.342 15.06172 1129.824 15.72890 1130.306 15.79356 1130.788 14.87659 1131.271 14.36831 1131.753 15.58936 1132.235 17.87584 1132.717 19.40232 1133.199 20.24471 1133.681 19.98462 1134.163 18.68133 1134.645 17.35946 1135.128 16.27048 1135.610 16.46175 1136.092 18.51514 1136.574 21.12851 1137.056 22.31557 1137.538 23.54978 1138.020 23.16741 1138.502 24.30637 1138.984 24.33933 1139.467 23.25073 1139.949 20.75583 1140.431 17.00575 1140.913 14.49882 1141.395 16.06545 1141.877 19.39220 1142.359 21.01805 1142.841 21.46792 1143.323 21.80865 1143.806 21.91914 1144.288 20.99994 1144.770 19.05978 1145.252 17.20860 1145.734 16.00605 1146.216 15.72539 1146.698 17.49043 1147.180 19.53064 1147.663 19.86314 1148.145 19.07712 1148.627 17.60540 1149.109 16.07150 1149.591 15.96415 1150.073 17.81980 1150.555 18.46936 1151.037 14.26827 1151.520 10.43070 1152.002 11.23238 1152.484 13.19789 1152.966 13.04874 1153.448 11.54602 1153.930 10.11204 1154.412 9.252618 1154.894 9.303135 1155.376 11.00027 1155.859 12.46428 1156.341 13.24213 1156.823 13.20561 1157.305 12.01208 1157.787 10.24256 1158.269 7.936174 1158.751 5.424184 1159.233 3.762171 1159.715 3.171751 1160.198 2.591856 1160.680 1.604426 1161.162 1.323090 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