#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-04-26 13:42:54 +0300 (Thu, 26 Apr 2018) $
#$Revision: 523 $
#$URL: svn://172.16.1.111/rod/cif/1/00/00/1000075.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000075
loop_
_publ_author_name
'Atencio, D.'
'Matioli, P. A.'
'Smith, J. B.'
'Chukanov, N. V.'
'Coutinho, J. M. V.'
'Rastsvetaeva, R. K.'
'Mockel, S.'
_publ_section_title
;
 Footemineite, the Mn-analog of atencioite, from the Foote mine, Kings
 Mountain, Cleveland County, North Carolina, U.S.A., and its relationship
 with other roscherite-group minerals Locality: Foote mine, Kings
 Mountain, Cleveland County, North Carolina, USA
;
_journal_name_full               'American Mineralogist'
_journal_page_first              1
_journal_page_last               6
_journal_paper_doi               10.2138/am.2008.2469
_journal_volume                  93
_journal_year                    2008
_chemical_compound_source        R060893
_chemical_formula_sum
'Be4 Ca2 Fe0.52 H16 Li0.17 Mg0.05 Mn4.14 O34 P6'
_chemical_name_mineral           Footemineite
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                73.84
_cell_angle_beta                 85.34
_cell_angle_gamma                87.44
_cell_length_a                   6.788
_cell_length_b                   9.972
_cell_length_c                   10.014
_cell_volume                     648.740
_exptl_crystal_density_diffrn    2.869
_cod_original_formula_sum        'Ca2 Mn4.14 Li.17 Mg.05 Fe.52 P6 Be4 O34 H16'
_cod_database_code               9010368
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 780
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 12
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R060893.rod
_rod_data_source.block           3500000
_rod_database.code               1000075
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9010368 COD http://www.crystallography.net/cod/9010368.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
95.41687 0.0000000E+00
95.89898 0.2329410
96.38110 0.2901000
96.86321 1.232788
97.34533 3.110596
97.82745 4.607513
98.30956 5.682678
98.79168 5.956207
99.27380 5.462433
99.75591 4.135773
100.2380 2.387360
100.7201 1.080231
101.2023 0.2440190
101.6844 5.2979000E-02
102.1665 4.5380000E-02
102.6486 0.3875430
103.1307 0.8840940
103.6128 1.148071
104.0950 1.309601
104.5771 1.414948
105.0592 1.173157
105.5413 0.8010860
106.0234 0.7206120
106.5055 1.289215
106.9877 2.329529
107.4698 3.093872
107.9519 3.176788
108.4340 3.243378
108.9161 3.467926
109.3982 3.941010
109.8804 4.846405
110.3625 6.631805
110.8446 9.119720
111.3267 10.81360
111.8088 12.57980
112.2909 14.41891
112.7731 15.80228
113.2552 16.25946
113.7373 16.53305
114.2194 17.18216
114.7015 18.17093
115.1836 18.78229
115.6658 19.42633
116.1479 19.78549
116.6300 19.43835
117.1121 18.18866
117.5942 16.31622
118.0763 14.41434
118.5584 12.37677
119.0406 10.65350
119.5227 9.433014
120.0048 8.637817
120.4869 8.090027
120.9690 7.857727
121.4511 7.721741
121.9333 7.311523
122.4154 6.593994
122.8975 5.668396
123.3796 4.541321
123.8617 3.158752
124.3438 1.816315
124.8260 0.4284670
125.3081 0.6905520
125.7902 1.098450
126.2723 0.3212590
126.7544 0.9756470
127.2365 1.501404
127.7187 0.9084170
128.2008 0.5015260
128.6829 4.7851998E-02
129.1650 0.6174320
129.6471 0.7493590
130.1292 0.2990720
130.6114 0.4956970
131.0935 0.8823550
131.5756 0.5463260
132.0577 0.1780700
132.5398 0.1745300
133.0219 0.4461980
133.5041 0.5360720
133.9862 0.3479000
134.4683 0.1307070
134.9504 0.8199160
135.4325 1.888672
135.9146 2.979919
136.3968 3.857574
136.8789 4.518585
137.3610 5.180542
137.8431 6.093231
138.3252 7.304199
138.8073 8.624481
139.2895 9.893738
139.7716 11.32443
140.2537 13.37646
140.7358 16.30435
141.2179 19.21896
141.7000 20.82245
142.1821 21.25580
142.6643 21.48550
143.1464 22.02185
143.6285 22.69693
144.1106 22.91769
144.5927 22.55453
145.0748 21.61990
145.5570 20.09412
146.0391 17.99075
146.5212 15.80386
147.0033 13.94040
147.4854 12.42068
147.9675 10.99750
148.4497 9.676117
148.9318 8.394653
149.4139 7.085022
149.8960 5.747284
150.3781 4.471497
150.8602 3.381226
151.3424 2.400269
151.8245 1.796692
152.3066 1.899658
152.7887 2.135254
153.2708 2.306885
153.7529 1.905151
154.2351 1.201752
154.7172 0.8892520
155.1993 1.691681
155.6814 2.020935
156.1635 1.342010
156.6456 0.2870790
157.1278 0.3348690
157.6099 0.1018680
158.0920 0.7444150
158.5741 1.207794
159.0562 1.295532
159.5383 1.067230
160.0205 0.1490480
160.5026 1.102844
160.9847 1.828125
161.4668 1.399017
161.9489 0.1275020
162.4310 0.5162050
162.9131 0.1218870
163.3953 0.4528500
163.8774 0.8241580
164.3595 0.9819030
164.8416 0.8729250
165.3237 0.3932190
165.8058 0.3781130
166.2880 1.239838
166.7701 2.336761
167.2522 3.391937
167.7343 4.022125
168.2164 4.139771
168.6985 4.248413
169.1807 4.680695
169.6628 5.265503
170.1449 5.827362
170.6270 6.357483
171.1091 6.792694
171.5912 6.925995
172.0734 6.518768
172.5555 6.250397
173.0376 6.399414
173.5197 6.823822
174.0018 7.328003
174.4839 7.800201
174.9661 8.259064
175.4482 8.825867
175.9303 9.776550
176.4124 10.50864
176.8945 10.61328
177.3766 10.40491
177.8588 10.42328
178.3409 11.07205
178.8230 12.35883
179.3051 13.74005
179.7872 15.45465
180.2693 17.02655
180.7515 18.28644
181.2336 19.26917
181.7157 20.06512
182.1978 20.72119
182.6799 21.18414
183.1620 21.88553
183.6441 23.44717
184.1263 24.78012
184.6084 25.30737
185.0905 24.99210
185.5726 24.11996
186.0547 22.86099
186.5368 21.11975
187.0190 19.82950
187.5011 19.54309
187.9832 19.38611
188.4653 18.66788
188.9474 17.29584
189.4296 15.69974
189.9117 14.18472
190.3938 12.77316
190.8759 11.74591
191.3580 11.36685
191.8401 11.32242
192.3223 11.24939
192.8044 11.07532
193.2865 10.96841
193.7686 11.03882
194.2507 11.27917
194.7328 11.80441
195.2150 12.80609
195.6971 14.09079
196.1792 15.26437
196.6613 16.23639
197.1434 17.22882
197.6255 18.34500
198.1077 19.59885
198.5898 21.02911
199.0719 22.79553
199.5540 24.79871
200.0361 26.54675
200.5182 27.72556
201.0004 29.09747
201.4825 31.30496
201.9646 34.02856
202.4467 36.45667
202.9288 37.95612
203.4109 38.58157
203.8930 39.18240
204.3752 39.62299
204.8573 40.19354
205.3394 41.23044
205.8215 42.50519
206.3036 43.49261
206.7857 43.66748
207.2679 42.97348
207.7500 42.57172
208.2321 42.80283
208.7142 43.03287
209.1963 42.91882
209.6784 42.60413
210.1606 42.49432
210.6427 42.96182
211.1248 44.05609
211.6069 45.25049
212.0890 46.87939
212.5711 48.28857
213.0533 49.17749
213.5354 49.59525
214.0175 49.81839
214.4996 50.13507
214.9817 50.63809
215.4638 50.47861
215.9460 49.24719
216.4281 47.87820
216.9102 46.92053
217.3923 46.31100
217.8744 45.54892
218.3565 44.12308
218.8387 41.95975
219.3208 39.85251
219.8029 37.73666
220.2850 35.73083
220.7671 33.85114
221.2492 32.11911
221.7314 30.70218
222.2135 29.89551
222.6956 29.74948
223.1777 29.00812
223.6598 26.93381
224.1419 24.78043
224.6240 23.61588
225.1062 23.45636
225.5883 23.42084
226.0704 22.66821
226.5525 21.36185
227.0346 20.71980
227.5167 21.50380
227.9989 22.55618
228.4810 22.76678
228.9631 22.06639
229.4452 21.13788
229.9273 20.26303
230.4094 19.55127
230.8916 19.30083
231.3737 20.09235
231.8558 21.09212
232.3379 21.24376
232.8200 20.41164
233.3021 19.55353
233.7843 19.18097
234.2664 19.18272
234.7485 19.51457
235.2306 20.47806
235.7127 21.57028
236.1948 22.01387
236.6770 21.64183
237.1591 21.12274
237.6412 20.81764
238.1233 20.63226
238.6054 20.39426
239.0875 19.98474
239.5697 19.56285
240.0518 19.47849
240.5339 19.89691
241.0160 20.08255
241.4981 19.50055
241.9802 18.60611
242.4624 17.83408
242.9445 17.35269
243.4266 17.11794
243.9087 17.12183
244.3908 17.52823
244.8729 17.71460
245.3550 17.30107
245.8372 16.71654
246.3193 16.31386
246.8014 16.21126
247.2835 16.30443
247.7656 16.47601
248.2477 16.89484
248.7299 16.96725
249.2120 16.17462
249.6941 15.27809
250.1762 14.92157
250.6583 15.29041
251.1404 15.99976
251.6226 16.41560
252.1047 16.42770
252.5868 16.38527
253.0689 16.16547
253.5510 16.01198
254.0331 16.16592
254.5153 16.66225
254.9974 17.26343
255.4795 17.60231
255.9616 17.55780
256.4437 17.49710
256.9258 17.34819
257.4080 17.24615
257.8901 17.36734
258.3722 17.69960
258.8543 18.00148
259.3364 17.95456
259.8185 17.50900
260.3007 16.79097
260.7828 15.40462
261.2649 14.09528
261.7470 13.45422
262.2291 13.46056
262.7112 13.56689
263.1934 13.09550
263.6755 11.74715
264.1576 10.92754
264.6397 10.95779
265.1218 11.13753
265.6039 11.13530
266.0861 10.91475
266.5682 10.52469
267.0503 9.903427
267.5324 8.843323
268.0145 9.074127
268.4966 12.04872
268.9788 14.72859
269.4609 15.45305
269.9430 14.44395
270.4251 12.92635
270.9072 11.82838
271.3893 11.16209
271.8715 10.84624
272.3536 11.13274
272.8357 11.43954
273.3178 11.54822
273.7999 11.47519
274.2820 11.33125
274.7642 11.20729
275.2463 11.08250
275.7284 10.66029
276.2105 9.699020
276.6926 8.775803
277.1747 8.045151
277.6568 7.490616
278.1389 7.065735
278.6211 6.747574
279.1032 6.535812
279.5853 6.444138
280.0674 6.713531
280.5495 6.800415
281.0316 6.495117
281.5138 5.925735
281.9959 5.315018
282.4780 4.759933
282.9601 4.215469
283.4422 3.563477
283.9243 2.691711
284.4065 1.933273
284.8886 1.346405
285.3707 0.9161990
285.8528 0.6369170
286.3349 0.5126340
286.8170 0.5028690
287.2992 0.5814820
287.7813 0.8343960
288.2634 0.8860320
288.7455 0.5000150
289.2276 4.8232999E-02
289.7097 0.4375000
290.1919 0.5958250
290.6740 0.5958250
291.1561 0.4587860
291.6382 0.1417540
292.1203 5.9586000E-02
292.6024 0.5530550
293.0846 1.131287
293.5667 1.213135
294.0488 0.7357030
294.5309 0.2568970
295.0130 0.3272090
295.4951 0.9637600
295.9773 1.459320
296.4594 1.761765
296.9415 1.934830
297.4236 2.057571
297.9057 2.109589
298.3878 1.953598
298.8700 1.382217
299.3521 0.4706570
299.8342 0.1398620
300.3163 0.2194370
300.7984 0.2148590
301.2805 0.3239590
301.7627 0.5364690
302.2448 0.8560330
302.7269 1.323883
303.2090 1.906815
303.6911 2.533600
304.1732 3.461395
304.6554 4.013519
305.1375 3.612000
305.6196 2.614548
306.1017 1.941589
306.5838 1.954193
307.0659 2.439941
307.5481 3.030289
308.0302 3.719604
308.5123 4.379074
308.9944 5.045776
309.4765 5.689621
309.9586 6.182968
310.4408 6.446793
310.9229 6.750412
311.4050 7.530289
311.8871 8.798462
312.3692 9.971695
312.8513 11.17525
313.3335 12.11168
313.8156 12.24998
314.2977 11.48322
314.7798 10.63121
315.2619 10.51042
315.7440 11.06932
316.2262 11.38290
316.7083 11.21381
317.1904 10.88721
317.6725 10.63048
318.1546 10.45540
318.6367 10.36732
319.1188 10.43456
319.6010 10.58231
320.0831 10.48996
320.5652 10.02243
321.0473 9.458923
321.5294 8.907745
322.0115 8.378479
322.4937 7.909241
322.9758 7.552826
323.4579 7.231125
323.9400 6.733170
324.4221 5.929718
324.9042 5.252731
325.3864 4.961456
325.8685 4.885117
326.3506 4.708710
326.8327 4.337036
327.3148 3.822403
327.7969 3.159607
328.2791 2.268524
328.7612 1.679337
329.2433 1.631226
329.7254 1.874084
330.2075 2.151810
330.6896 2.420532
331.1718 2.698654
331.6539 3.075394
332.1360 3.557068
332.6181 3.636368
333.1002 2.832031
333.5823 1.973251
334.0645 1.691727
334.5466 1.970901
335.0287 2.406372
335.5108 2.750366
335.9929 3.008881
336.4750 3.245331
336.9572 3.329117
337.4393 3.526993
337.9214 4.125275
338.4035 4.929840
338.8856 5.445953
339.3677 5.412323
339.8499 5.025482
340.3320 4.807144
340.8141 4.782120
341.2962 4.843597
341.7783 5.035324
342.2604 5.279282
342.7426 5.504013
343.2247 5.689560
343.7068 5.778152
344.1889 5.655838
344.6710 5.169632
345.1531 4.950867
345.6353 5.243637
346.1174 5.642242
346.5995 5.944519
347.0816 6.073441
347.5637 5.853256
348.0458 5.073532
348.5280 3.697632
349.0101 2.835159
349.4922 2.748016
349.9743 2.823822
350.4564 2.817337
350.9385 2.735458
351.4207 2.712234
351.9028 2.862961
352.3849 3.108612
352.8670 3.063049
353.3491 2.563431
353.8312 1.908386
354.3134 0.8552090
354.7955 0.2013400
355.2776 0.7285920
355.7597 0.5514370
356.2418 4.7851998E-02
356.7239 0.1441500
357.2061 0.1755220
357.6882 0.3772130
358.1703 0.5545200
358.6524 0.6201630
359.1345 0.3945310
359.6166 6.4438000E-02
360.0987 0.4308930
360.5808 0.3446040
361.0630 0.2799070
361.5451 0.5221100
362.0272 2.6505001E-02
362.5093 0.5067290
362.9914 0.6394650
363.4735 0.4851530
363.9557 0.1514280
364.4378 0.3238980
364.9199 0.8344120
365.4020 0.9174650
365.8841 0.1625980
366.3662 0.4796600
366.8484 0.8168790
367.3305 1.032501
367.8126 1.267273
368.2947 1.577347
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369.7411 3.706879
370.2232 4.603668
370.7053 5.350479
371.1874 5.965836
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372.1516 6.769592
372.6338 7.016510
373.1159 7.115372
373.5980 7.082886
374.0801 7.538177
374.5622 8.701736
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375.5265 12.04584
376.0086 14.03792
376.4907 15.42255
376.9728 15.74466
377.4549 15.58026
377.9370 16.24533
378.4192 17.98148
378.9013 19.87483
379.3834 21.89566
379.8655 23.84267
380.3476 25.51128
380.8297 26.86470
381.3119 28.13150
381.7940 29.62970
382.2761 31.35139
382.7582 32.66441
383.2403 33.19112
383.7224 33.63432
384.2046 34.68246
384.6867 36.11009
385.1688 37.11874
385.6509 37.06853
386.1330 36.32571
386.6151 35.76041
387.0973 35.47815
387.5794 35.00641
388.0615 33.98167
388.5436 32.60822
389.0257 31.14107
389.5078 29.62434
389.9900 28.02634
390.4721 26.20808
390.9542 24.21059
391.4363 22.45668
391.9184 21.14255
392.4005 20.07574
392.8827 19.01483
393.3648 17.97012
393.8469 16.84396
394.3290 15.41177
394.8111 13.93755
395.2932 12.90959
395.7754 12.41588
396.2575 12.08615
396.7396 11.61746
397.2217 11.02037
397.7038 10.44722
398.1859 9.603165
398.6681 9.043610
399.1501 9.240158
399.6323 10.05756
400.1144 11.02419
400.5965 11.93996
401.0786 12.79382
401.5607 13.52342
402.0428 14.00951
402.5250 14.59738
403.0071 15.16484
403.4892 15.97556
403.9713 17.37469
404.4534 19.45096
404.9355 21.88416
405.4177 24.38931
405.8998 27.11307
406.3819 28.96690
406.8640 29.24522
407.3461 29.43803
407.8282 30.29500
408.3104 31.68266
408.7925 33.13370
409.2746 34.38121
409.7567 35.43887
410.2388 36.40347
410.7209 37.66103
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