#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-04-26 13:59:28 +0300 (Thu, 26 Apr 2018) $ #$Revision: 577 $ #$URL: svn://172.16.1.111/rod/cif/1/00/01/1000120.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000120 loop_ _publ_author_name 'Kampf, A. R.' 'Downs, R. T.' 'Housley, R. M.' 'Jenkins, R. A.' 'Hyrsl, J.' _publ_section_title ; Anorpiment, As2S3, the triclinic dimorph of orpiment ; _journal_name_full 'Mineralogical Magazine' _journal_page_first 2857 _journal_page_last 2867 _journal_paper_doi 10.1180/minmag.2011.075.6.2857 _journal_volume 75 _journal_year 2011 _chemical_compound_source 'Palomo mine, Castrovirreyna Province, Huancavelica Department, Peru' _chemical_formula_sum 'As2 S3' _chemical_name_mineral Anorpiment _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 78.152 _cell_angle_beta 75.817 _cell_angle_gamma 89.861 _cell_length_a 5.7577 _cell_length_b 8.7169 _cell_length_c 10.2682 _cell_volume 488.377 _exptl_crystal_density_diffrn 3.346 _cod_database_code 9015549 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R110016.rod _rod_data_source.block 3500000 _rod_database.code 1000120 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9015549 COD http://www.crystallography.net/cod/9015549.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 93.49817 0.0000000E+00 93.98029 57.74390 94.46240 165.2209 94.94452 305.3359 95.42664 459.7844 95.90874 628.7908 96.39086 812.9614 96.87298 980.3503 97.35509 1092.899 97.83721 1150.621 98.31933 1151.816 98.80145 1102.575 99.28356 1049.159 99.76568 946.5571 100.2478 806.0710 100.7299 656.6123 101.2120 515.3147 101.6941 367.5679 102.1763 243.5454 102.6584 144.7676 103.1405 68.62134 103.6226 13.41895 104.1047 21.71899 104.5868 37.56543 105.0690 40.20483 105.5511 30.25000 106.0332 10.74902 106.5153 18.10205 106.9974 57.52393 107.4795 105.3828 107.9617 159.4880 108.4438 219.5757 108.9259 284.9377 109.4080 353.1301 109.8901 427.6511 110.3722 512.2715 110.8544 604.8018 111.3365 713.7637 111.8186 831.4250 112.3007 965.6335 112.7828 1138.017 113.2649 1359.898 113.7471 1631.384 114.2292 1941.534 114.7113 2301.570 115.1934 2700.132 115.6755 3178.432 116.1576 3706.820 116.6397 4202.850 117.1219 4608.738 117.6040 4980.239 118.0861 5056.682 118.5682 4748.618 119.0503 4276.667 119.5324 3720.610 120.0146 3128.239 120.4967 2536.463 120.9788 2022.526 121.4609 1599.642 121.9430 1250.410 122.4251 999.0055 122.9073 822.9812 123.3894 704.7966 123.8715 639.1548 124.3536 615.5380 124.8357 613.1379 125.3178 631.2939 125.8000 662.1997 126.2821 703.2574 126.7642 754.8141 127.2463 816.2262 127.7284 882.1108 128.2105 964.6362 128.6927 1074.519 129.1748 1207.349 129.6569 1376.496 130.1390 1588.224 130.6211 1838.951 131.1032 2154.229 131.5854 2561.763 132.0675 3036.088 132.5496 3592.443 133.0317 4287.807 133.5138 4999.619 133.9959 5452.805 134.4781 5637.984 134.9602 5525.929 135.4423 5013.839 135.9244 4272.274 136.4065 3508.691 136.8886 2837.696 137.3708 2256.364 137.8529 1782.112 138.3350 1441.012 138.8171 1186.619 139.2992 1041.072 139.7813 978.1259 140.2635 952.6445 140.7456 932.2793 141.2277 921.1831 141.7098 865.8982 142.1919 744.8538 142.6740 608.0903 143.1561 473.6566 143.6383 346.4825 144.1204 231.5405 144.6025 133.6925 145.0846 55.48596 145.5667 5.752441 146.0488 46.82153 146.5310 71.49341 147.0131 81.89587 147.4952 77.63855 147.9773 64.44006 148.4594 47.27917 148.9415 26.68713 149.4237 0.5511470 149.9058 30.16443 150.3879 66.68982 150.8700 111.6537 151.3521 164.6753 151.8342 229.9954 152.3164 306.6104 152.7985 394.4530 153.2806 496.6061 153.7627 616.5051 154.2448 754.5635 154.7269 902.3171 155.2091 1093.025 155.6912 1265.270 156.1733 1396.722 156.6554 1481.925 157.1375 1514.521 157.6196 1478.909 158.1018 1352.244 158.5839 1220.362 159.0660 1075.340 159.5481 935.4260 160.0302 808.6946 160.5123 698.8235 160.9945 609.4180 161.4766 547.7981 161.9587 522.0015 162.4408 513.4487 162.9229 526.8617 163.4050 555.3031 163.8871 592.2705 164.3693 634.4592 164.8514 683.4957 165.3335 745.4976 165.8156 823.3346 166.2977 909.9355 166.7798 1007.027 167.2620 1112.445 167.7441 1225.639 168.2262 1348.793 168.7083 1473.978 169.1904 1578.050 169.6725 1664.903 170.1547 1731.330 170.6368 1763.116 171.1189 1769.945 171.6010 1781.388 172.0831 1800.698 172.5652 1843.941 173.0474 1932.972 173.5295 2079.143 174.0116 2248.263 174.4937 2449.396 174.9758 2682.887 175.4579 2830.703 175.9401 2815.808 176.4222 2691.964 176.9043 2503.864 177.3864 2242.535 177.8685 1956.111 178.3506 1695.360 178.8328 1455.660 179.3149 1259.856 179.7970 1118.461 180.2791 1019.832 180.7612 961.2000 181.2433 942.3225 181.7255 958.2883 182.2076 1000.150 182.6897 1074.766 183.1718 1166.166 183.6539 1280.924 184.1360 1403.292 184.6181 1526.122 185.1003 1648.573 185.5824 1754.524 186.0645 1784.595 186.5466 1675.311 187.0287 1559.350 187.5108 1439.716 187.9930 1327.991 188.4751 1234.947 188.9572 1166.682 189.4393 1123.522 189.9214 1110.380 190.4035 1150.399 190.8857 1194.618 191.3678 1253.969 191.8499 1309.993 192.3320 1333.498 192.8141 1306.304 193.2962 1231.896 193.7784 1132.174 194.2605 991.1924 194.7426 848.7407 195.2247 707.9607 195.7068 574.4860 196.1889 462.0485 196.6711 380.6457 197.1532 328.1455 197.6353 283.8875 198.1174 249.0446 198.5995 220.0381 199.0816 194.7382 199.5638 173.2644 200.0459 157.0566 200.5280 148.1537 201.0101 145.2334 201.4922 142.9639 201.9743 141.6478 202.4565 140.0125 202.9386 137.5955 203.4207 133.2015 203.9028 123.7201 204.3849 106.2560 204.8670 85.44867 205.3492 67.74036 205.8313 55.49390 206.3134 46.47827 206.7955 38.03430 207.2776 30.32971 207.7597 24.11072 208.2419 19.61938 208.7240 16.14270 209.2061 12.92822 209.6882 9.505249 210.1703 6.413330 210.6524 5.363159 211.1346 7.593506 211.6167 7.907349 212.0988 1.666138 212.5809 5.457275 213.0630 7.164612 213.5451 0.4589840 214.0273 9.888916 214.5094 13.06561 214.9915 3.298279 215.4736 2.764893 215.9557 0.8313600 216.4378 7.874756 216.9200 12.06995 217.4021 10.48138 217.8842 4.917175 218.3663 1.002563 218.8484 5.9386998E-02 219.3305 0.6455690 219.8127 1.102417 220.2948 1.900391 220.7769 3.875977 221.2590 7.303711 221.7411 11.13928 222.2232 12.70239 222.7054 9.649292 223.1875 7.013611 223.6696 5.486938 224.1517 4.299072 224.6338 2.526489 225.1159 0.2545780 225.5980 3.661072 226.0802 6.589172 226.5623 6.553406 227.0444 9.058228 227.5265 16.82568 228.0086 26.71655 228.4907 34.31293 228.9729 37.66455 229.4550 38.65582 229.9371 42.18134 230.4192 50.48737 230.9013 57.66357 231.3834 63.06384 231.8656 66.72168 232.3477 68.26550 232.8298 67.32690 233.3119 65.12610 233.7940 64.31567 234.2761 65.06873 234.7583 66.31189 235.2404 68.41846 235.7225 70.74304 236.2046 71.91370 236.6867 71.17590 237.1688 69.91992 237.6510 71.21387 238.1331 75.68628 238.6152 78.56580 239.0973 77.83789 239.5794 74.41272 240.0615 69.99377 240.5437 64.69019 241.0258 59.18835 241.5079 54.14246 241.9900 49.44861 242.4721 45.78259 242.9542 43.52515 243.4364 42.52283 243.9185 42.36194 244.4006 42.89514 244.8827 44.47351 245.3648 48.45142 245.8469 54.39038 246.3290 58.43237 246.8112 56.80310 247.2933 51.63965 247.7754 49.70117 248.2575 52.84839 248.7396 57.74951 249.2217 61.35669 249.7039 64.23132 250.1860 68.39600 250.6681 76.80725 251.1502 87.68640 251.6323 94.43005 252.1144 95.58081 252.5966 94.11719 253.0787 91.14221 253.5608 87.23999 254.0429 83.75439 254.5250 82.00647 255.0071 81.30334 255.4893 78.91162 255.9714 74.42200 256.4535 68.43152 256.9356 59.53381 257.4177 49.80847 257.8998 42.82544 258.3820 41.44568 258.8641 43.90991 259.3462 43.91187 259.8283 40.89001 260.3104 36.04224 260.7925 28.65857 261.2747 20.34570 261.7568 13.10388 262.2389 7.813354 262.7210 4.160034 263.2031 1.591064 263.6852 1.015381 264.1674 0.1528320 264.6495 1.194824 265.1316 3.276855 265.6137 6.534546 266.0958 11.18628 266.5779 16.56201 267.0601 21.30579 267.5422 26.29224 268.0243 28.83557 268.5064 25.84949 268.9885 21.85181 269.4706 21.71277 269.9528 27.32983 270.4349 35.74109 270.9170 40.38782 271.3991 37.67712 271.8812 36.57239 272.3633 39.36353 272.8455 43.83362 273.3276 48.49146 273.8097 52.11609 274.2918 53.82568 274.7739 52.40332 275.2560 46.12598 275.7382 41.33594 276.2202 39.88599 276.7024 38.01697 277.1845 32.41040 277.6666 23.15552 278.1487 13.81372 278.6308 9.070557 279.1129 11.12512 279.5951 10.64294 280.0772 7.273193 280.5593 1.697021 281.0414 6.579712 281.5235 16.82898 282.0056 27.16711 282.4878 35.78296 282.9699 42.54224 283.4520 49.58789 283.9341 56.95032 284.4162 64.38684 284.8983 72.15613 285.3805 80.37329 285.8626 88.85327 286.3447 97.38953 286.8268 105.7554 287.3089 112.9117 287.7910 116.4615 288.2732 121.4861 288.7553 129.1943 289.2374 139.4259 289.7195 151.9984 290.2016 167.0392 290.6837 183.7750 291.1659 198.3640 291.6480 207.4471 292.1301 218.2096 292.6122 231.9211 293.0943 247.9918 293.5764 265.4672 294.0586 283.9974 294.5407 303.7523 295.0228 325.3319 295.5049 347.3260 295.9870 373.2555 296.4691 401.9688 296.9513 435.2054 297.4334 473.8605 297.9155 518.2053 298.3976 570.2848 298.8797 633.2793 299.3618 708.2622 299.8440 795.4756 300.3261 888.3813 300.8082 996.4062 301.2903 1127.497 301.7724 1282.922 302.2545 1461.543 302.7367 1664.781 303.2188 1898.349 303.7009 2136.638 304.1830 2383.970 304.6651 2632.992 305.1472 2879.708 305.6294 3123.899 306.1115 3367.064 306.5936 3609.669 307.0757 3852.441 307.5578 4098.305 308.0399 4344.312 308.5221 4595.840 309.0042 4843.725 309.4863 5097.755 309.9684 5372.533 310.4505 5671.615 310.9326 6002.746 311.4148 6416.869 311.8969 6882.699 312.3790 7452.974 312.8611 8121.067 313.3432 8904.947 313.8253 9837.651 314.3075 10931.10 314.7896 12179.09 315.2717 13584.70 315.7538 15264.31 316.2359 16942.05 316.7180 18630.64 317.2001 20292.87 317.6823 21881.12 318.1644 23389.27 318.6465 24842.50 319.1286 26292.76 319.6107 27784.68 320.0928 29118.54 320.5750 30347.69 321.0571 31394.36 321.5392 32166.68 322.0213 32669.47 322.5034 33027.28 322.9855 33365.48 323.4677 33703.20 323.9498 33839.22 324.4319 33693.62 324.9140 33455.56 325.3961 33070.38 325.8782 32648.86 326.3604 32419.04 326.8425 32503.50 327.3246 32930.21 327.8067 34068.49 328.2888 35919.85 328.7709 38357.86 329.2531 41467.65 329.7352 45122.70 330.2173 49241.89 330.6994 53814.34 331.1815 58594.94 331.6636 62954.91 332.1458 68294.51 332.6279 71321.87 333.1100 71792.80 333.5921 69973.02 334.0742 65578.66 334.5563 58705.78 335.0385 50534.24 335.5206 42729.56 336.0027 35052.98 336.4848 28480.77 336.9669 22965.60 337.4490 18387.08 337.9312 14785.54 338.4133 12066.06 338.8954 10012.47 339.3775 8461.272 339.8596 7438.516 340.3417 6567.671 340.8239 5885.636 341.3060 5294.123 341.7881 4778.821 342.2702 4326.267 342.7523 3922.440 343.2344 3559.881 343.7166 3255.064 344.1987 2974.956 344.6808 2786.363 345.1629 2634.224 345.6450 2522.379 346.1271 2444.064 346.6093 2395.862 347.0914 2376.061 347.5735 2378.275 348.0556 2393.466 348.5377 2440.322 349.0198 2464.850 349.5020 2480.690 349.9841 2468.775 350.4662 2412.806 350.9483 2313.403 351.4304 2182.843 351.9125 2028.517 352.3947 1842.403 352.8768 1686.446 353.3589 1553.849 353.8410 1458.152 354.3231 1403.875 354.8052 1390.972 355.2874 1420.228 355.7695 1494.864 356.2516 1609.799 356.7337 1739.602 357.2158 1907.972 357.6979 2057.888 358.1800 2191.627 358.6621 2298.518 359.1443 2363.034 359.6264 2379.619 360.1085 2363.248 360.5906 2336.290 361.0727 2288.317 361.5548 2258.325 362.0370 2243.116 362.5191 2250.384 363.0012 2284.953 363.4833 2347.681 363.9654 2436.979 364.4475 2552.098 364.9297 2693.388 365.4118 2857.446 365.8939 3042.277 366.3760 3255.450 366.8581 3486.727 367.3402 3746.374 367.8224 4051.624 368.3045 4401.901 368.7866 4810.358 369.2687 5318.369 369.7508 5929.168 370.2329 6638.608 370.7151 7466.078 371.1972 8372.686 371.6793 9363.320 372.1614 10443.67 372.6435 11518.69 373.1256 12565.97 373.6078 13613.30 374.0899 14222.49 374.5720 14256.68 375.0541 13807.15 375.5362 12849.19 376.0183 11429.39 376.5005 9916.021 376.9826 8441.379 377.4647 7047.642 377.9468 5879.018 378.4289 4953.415 378.9110 4240.794 379.3932 3770.122 379.8753 3483.150 380.3574 3295.781 380.8395 3203.453 381.3216 3179.503 381.8037 3195.507 382.2859 3251.320 382.7680 3347.352 383.2501 3485.641 383.7322 3668.154 384.2143 3889.766 384.6964 4151.639 385.1786 4444.604 385.6607 4795.516 386.1428 5172.112 386.6249 5520.929 387.1070 5864.312 387.5891 6075.443 388.0713 5964.688 388.5534 5563.291 389.0355 5043.187 389.5176 4344.269 389.9997 3600.661 390.4818 2925.788 390.9640 2327.060 391.4461 1811.317 391.9282 1385.440 392.4103 1051.429 392.8924 785.8327 393.3745 606.6216 393.8567 468.7159 394.3388 366.4362 394.8209 292.1324 395.3030 234.0868 395.7851 187.9708 396.2672 152.0356 396.7494 123.3557 397.2315 105.0048 397.7136 87.45203 398.1957 68.92059 398.6778 51.75537 399.1599 37.80261 399.6420 27.22418 400.1241 19.30658 400.6063 13.75757 401.0884 10.64020 401.5705 6.630920 402.0526 0.9071660 402.5347 4.769104 403.0168 10.22290 403.4990 15.17523 403.9811 19.39337 404.4632 22.76276 404.9453 24.96912 405.4274 24.87482 405.9095 19.13782 406.3917 16.62738 406.8738 18.98499 407.3559 23.39600 407.8380 29.11230 408.3201 35.21881 408.8022 39.59375 409.2844 39.68994 409.7665 35.12799 410.2486 32.31134 410.7307 32.82483 411.2128 33.49927 411.6949 33.32635 412.1771 32.70654 412.6592 32.57666 413.1413 33.57831 413.6234 34.73773 414.1055 33.53656 414.5876 28.83655 415.0698 25.34198 415.5519 26.09100 416.0340 27.07031 416.5161 24.81647 416.9982 19.19489 417.4803 14.02948 417.9625 13.45306 418.4446 16.57599 418.9267 17.42621 419.4088 15.17249 419.8909 11.29419 420.3730 4.893372 420.8552 2.255188 421.3373 6.224609 421.8194 4.578125 422.3015 0.3708500 422.7836 4.023010 423.2657 8.531494 423.7479 9.422729 424.2300 3.127808 424.7121 5.742065 425.1942 9.920715 425.6763 8.815857 426.1584 6.560059 426.6406 3.848999 427.1227 1.412231 427.6048 0.8903810 428.0869 2.622192 428.5690 4.663086 429.0511 5.169861 429.5333 4.133606 430.0154 3.865295 430.4975 4.420349 430.9796 5.692444 431.4617 8.311523 431.9438 11.64203 432.4260 14.05603 432.9081 14.74945 433.3902 14.25977 433.8723 13.81293 434.3544 13.09222 434.8365 12.98486 435.3187 13.58875 435.8008 14.76239 436.2829 16.64105 436.7650 19.09332 437.2471 21.62433 437.7292 23.86487 438.2114 25.82874 438.6935 26.75824 439.1756 24.57343 439.6577 23.66888 440.1398 25.24841 440.6219 28.65405 441.1040 33.49457 441.5862 39.58466 442.0683 45.60992 442.5504 48.76892 443.0325 47.71863 443.5146 47.94733 443.9967 50.67719 444.4789 54.17999 444.9610 58.04462 445.4431 61.99176 445.9252 65.43451 446.4073 67.52057 446.8894 68.82178 447.3716 71.76172 447.8537 77.07074 448.3358 82.18701 448.8179 86.03058 449.3000 89.06921 449.7821 91.84692 450.2643 94.58649 450.7464 96.51660 451.2285 96.69086 451.7106 95.37622 452.1927 93.70209 452.6748 91.35895 453.1570 89.84158 453.6391 92.01651 454.1212 96.89145 454.6033 99.53052 455.0854 96.62131 455.5675 92.61249 456.0497 92.03326 456.5318 94.35928 457.0139 95.77679 457.4960 94.27072 457.9781 90.70419 458.4602 87.09363 458.9424 82.22665 459.4245 79.71204 459.9066 82.11850 460.3887 86.02332 460.8708 87.67773 461.3529 86.66675 461.8351 85.42389 462.3172 86.50671 462.7993 90.10696 463.2814 91.16821 463.7635 85.71466 464.2456 82.85550 464.7278 87.09753 465.2099 94.19910 465.6920 98.19373 466.1741 96.80872 466.6562 92.52490 467.1383 89.47464 467.6205 88.13022 468.1026 87.44507 468.5847 87.84732 469.0668 88.15018 469.5489 87.63522 470.0310 86.62585 470.5132 85.94214 470.9953 85.95862 471.4774 86.62906 471.9595 88.73358 472.4416 93.60577 472.9237 95.81467 473.4059 89.53436 473.8880 81.64764 474.3701 79.15582 474.8522 83.16602 475.3343 87.81519 475.8164 88.87747 476.2986 87.30478 476.7807 86.02948 477.2628 85.56348 477.7449 85.63495 478.2270 86.21588 478.7091 87.29877 479.1913 88.48151 479.6734 90.22171 480.1555 90.85681 480.6376 87.96661 481.1197 83.50912 481.6018 82.59601 482.0839 87.48279 482.5660 94.19159 483.0482 96.50067 483.5303 92.49527 484.0124 89.54846 484.4945 86.54016 484.9766 85.46344 485.4587 89.51685 485.9409 96.61469 486.4230 101.2869 486.9051 100.2249 487.3872 95.59650 487.8693 94.13611 488.3514 98.42236 488.8336 101.2355 489.3157 102.4028 489.7978 102.0465 490.2799 98.85117 490.7620 93.64819 491.2441 89.83054 491.7263 90.94858 492.2084 95.69443 492.6905 97.52444 493.1726 95.23584 493.6547 93.05319 494.1368 93.32330 494.6190 94.33197 495.1011 94.25876 495.5832 92.68713 496.0653 90.76529 496.5474 88.59045 497.0295 86.61075 497.5117 87.26428 497.9938 91.76099 498.4759 95.76660 498.9580 94.72403 499.4401 89.85468 499.9222 87.84412 500.4044 91.85956 500.8865 95.73196 501.3686 95.63660 501.8507 93.31073 502.3328 92.25510 502.8149 93.66437 503.2971 96.49796 503.7792 99.60651 504.2613 103.9000 504.7434 104.7196 505.2255 98.70172 505.7076 92.99933 506.1898 91.18387 506.6719 92.25644 507.1540 93.63861 507.6361 93.96103 508.1182 94.07135 508.6003 96.47946 509.0825 103.3847 509.5646 106.6524 510.0467 102.4148 510.5288 96.95853 511.0109 93.32709 511.4930 91.53281 511.9752 90.31244 512.4573 88.84802 512.9394 87.34573 513.4215 86.49896 513.9036 86.49167 514.3857 86.30481 514.8679 85.32623 515.3500 84.05383 515.8321 83.08188 516.3142 82.41388 516.7963 82.03772 517.2784 82.30469 517.7606 82.83945 518.2427 82.44690 518.7248 81.09991 519.2069 81.44278 519.6890 86.31097 520.1711 94.06592 520.6533 95.95337 521.1354 87.98795 521.6175 80.53226 522.0996 74.55963 522.5817 70.17422 523.0638 68.41040 523.5460 69.16574 524.0281 70.79272 524.5102 71.90527 524.9923 72.53265 525.4744 71.90222 525.9565 69.15549 526.4387 66.47125 526.9208 62.97980 527.4029 59.63992 527.8850 58.60184 528.3671 60.48804 528.8492 62.52075 529.3314 61.46805 529.8135 57.75375 530.2956 54.60388 530.7777 51.42188 531.2598 49.95694 531.7419 53.20422 532.2241 58.31482 532.7062 61.01062 533.1883 60.17499 533.6704 58.42020 534.1525 56.09619 534.6346 53.43710 535.1168 52.55417 535.5989 54.44205 536.0810 56.60007 536.5631 55.85098 537.0452 51.86465 537.5273 50.60699 538.0095 54.93610 538.4916 58.55225 538.9737 58.71616 539.4558 56.87000 539.9379 55.07953 540.4200 54.09323 540.9022 53.68439 541.3843 53.54868 541.8664 53.67313 542.3485 54.52023 542.8306 57.11667 543.3127 58.61954 543.7948 57.52231 544.2769 55.41766 544.7590 54.66623 545.2411 56.20679 545.7233 58.34598 546.2054 59.09778 546.6875 58.51849 547.1696 57.35983 547.6517 55.35617 548.1339 54.04013 548.6160 54.90805 549.0981 56.95477 549.5802 58.27048 550.0623 57.66702 550.5444 57.71124 551.0266 61.47360 551.5087 66.93039 551.9908 68.88531 552.4729 65.50082 552.9550 59.86176 553.4371 55.49713 553.9193 52.26202 554.4014 52.16705 554.8835 58.82419 555.3656 63.96985 555.8477 63.90457 556.3298 60.66110 556.8120 56.92914 557.2941 53.75470 557.7762 51.65405 558.2583 51.83728 558.7404 54.72800 559.2225 56.24136 559.7047 54.88995 560.1868 53.95483 560.6689 55.64169 561.1510 58.55725 561.6331 60.50742 562.1152 61.02289 562.5974 59.85565 563.0795 55.40231 563.5616 48.87820 564.0437 44.95889 564.5258 44.85037 565.0079 46.16162 565.4901 47.43176 565.9722 48.42593 566.4543 46.91400 566.9364 40.13968 567.4185 34.03735 567.9006 31.40082 568.3828 30.61172 568.8649 29.13333 569.3470 26.39813 569.8291 23.95468 570.3112 23.93073 570.7933 26.58688 571.2755 26.89981 571.7576 22.26007 572.2397 18.50964 572.7218 17.38226 573.2039 17.66086 573.6860 18.27222 574.1682 18.90488 574.6503 18.91443 575.1324 16.78177 575.6145 13.32663 576.0966 12.72293 576.5787 16.01422 577.0609 19.09924 577.5430 20.04440 578.0251 18.76053 578.5072 14.88394 578.9893 5.910492 579.4714 2.0569000E-02 579.9536 2.684326 580.4357 8.832336 580.9178 12.63678 581.3999 13.19827 581.8820 11.43948 582.3641 7.754944 582.8463 2.593109 583.3284 1.551208 583.8105 6.244568 584.2926 7.409668 584.7747 1.400757 585.2568 5.522552 585.7390 8.886536 586.2211 8.426971 586.7032 6.028381 587.1853 2.328064 587.6674 1.840637 588.1495 4.178009 588.6317 4.560394 589.1138 3.667114 589.5959 0.1023860 590.0780 3.126892 590.5601 1.384705 591.0422 5.223572 591.5244 9.080261 592.0065 4.930664 592.4886 0.6415410 592.9707 1.327271 593.4528 1.847595 593.9349 4.705780 594.4171 5.433838 594.8992 4.906128 595.3813 4.563293 595.8634 4.394623 596.3455 4.372314 596.8276 4.379517 597.3098 4.655090 597.7919 5.307251 598.2740 6.298981 598.7561 7.962524 599.2382 10.51108 599.7203 12.31558 600.2025 10.28979 600.6846 4.571777 601.1667 1.218109 601.6488 1.554535 602.1309 2.876068 602.6130 3.536041 603.0952 3.824493 603.5773 4.265869 604.0594 4.600220 604.5415 5.715485 605.0236 9.758270 605.5057 14.22595 605.9879 14.30994 606.4700 9.645233 606.9521 4.988525 607.4342 4.372131 607.9163 7.239716 608.3984 9.405853 608.8806 11.61734 609.3627 11.95099 609.8448 8.059143 610.3269 3.929840 610.8090 3.145844 611.2911 5.406830 611.7733 7.668732 612.2554 8.079468 612.7375 6.789429 613.2196 3.345306 613.7017 2.677704 614.1838 6.327423 614.6660 4.864838 615.1481 1.957947 615.6302 1.452240 616.1123 3.217712 616.5944 6.942688 617.0765 16.02524 617.5587 23.77322 618.0408 23.57559 618.5229 18.83646 619.0050 17.20535 619.4871 21.34708 619.9692 28.54700 620.4514 35.37537 620.9335 41.89816 621.4156 47.74023 621.8977 51.90799 622.3798 56.56833 622.8619 61.45200 623.3441 67.48877 623.8262 75.80450 624.3083 86.61102 624.7904 98.97495 625.2725 112.6732 625.7546 127.2322 626.2367 141.1313 626.7188 154.2516 627.2009 167.3800 627.6830 180.5266 628.1652 194.3402 628.6473 210.8679 629.1294 230.8098 629.6115 250.3448 630.0936 268.1669 630.5757 286.1230 631.0579 304.8859 631.5400 325.0428 632.0221 347.9866 632.5042 374.3543 632.9863 402.8111 633.4684 431.2311 633.9506 460.2228 634.4327 486.8689 634.9148 508.4302 635.3969 530.6720 635.8790 557.4877 636.3611 586.4896 636.8433 613.9121 637.3254 639.1989 637.8075 661.3023 638.2896 677.7304 638.7717 690.3853 639.2538 704.5882 639.7360 720.7333 640.2181 732.0874 640.7002 733.1983 641.1823 726.2094 641.6644 720.0907 642.1465 716.3246 642.6287 712.4313 643.1108 710.2186 643.5929 705.9556 644.0750 695.0741 644.5571 679.9407 645.0392 667.7456 645.5214 663.2509 646.0035 660.9118 646.4856 651.0734 646.9677 633.8410 647.4498 615.3565 647.9319 595.6799 648.4141 576.6461 648.8962 560.9392 649.3783 547.2601 649.8604 530.9368 650.3425 507.4827 650.8246 486.7826 651.3068 476.0533 651.7889 468.3172 652.2710 454.5100 652.7531 434.1045 653.2352 413.0663 653.7173 396.0038 654.1995 382.1266 654.6816 368.0851 655.1637 353.8747 655.6458 339.5193 656.1279 324.6874 656.6100 309.9104 657.0922 294.8495 657.5743 280.0245 658.0564 267.1412 658.5385 256.4616 659.0206 248.6428 659.5027 245.5667 659.9849 245.7468 660.4670 245.4182 660.9491 243.7639 661.4312 240.4285 661.9133 234.4071 662.3954 226.1003 662.8776 221.7057 663.3597 227.1503 663.8418 228.9094 664.3239 222.4018 664.8060 214.6289 665.2881 211.1115 665.7703 211.6578 666.2524 213.0506 666.7345 213.7354 667.2166 213.4325 667.6987 211.1370 668.1808 206.8826 668.6630 203.2631 669.1451 200.6403 669.6272 199.2078 670.1093 200.1035 670.5914 203.0118 671.0735 203.5207 671.5557 198.5553 672.0378 194.6904 672.5199 195.2169 673.0020 197.2686 673.4841 198.3627 673.9662 197.7479 674.4484 194.6179 674.9305 187.6031 675.4126 178.7612 675.8947 175.6305 676.3768 179.8489 676.8589 182.4736 677.3411 180.6387 677.8232 177.9137 678.3053 177.6410 678.7874 178.9921 679.2695 178.8741 679.7516 175.5364 680.2338 171.8920 680.7159 169.6600 681.1980 168.2326 681.6801 166.6923 682.1622 164.8643 682.6443 162.9562 683.1265 161.1454 683.6086 159.3826 684.0907 157.4155 684.5728 155.1882 685.0549 152.8740 685.5370 149.3171 686.0192 146.7403 686.5013 147.1144 686.9834 149.5732 687.4655 151.7487 687.9476 153.6021 688.4297 153.3395 688.9119 146.9323 689.3940 137.6008 689.8761 133.3629 690.3582 135.5365 690.8403 139.4597 691.3224 141.6929 691.8046 142.5828 692.2867 143.7594 692.7688 144.7543 693.2509 146.8666 693.7330 150.8571 694.2151 155.2368 694.6973 158.7743 695.1794 162.0225 695.6615 166.6566 696.1436 173.8260 696.6257 181.1081 697.1078 185.8578 697.5900 188.5027 698.0721 190.0091 698.5542 190.3312 699.0363 192.0375 699.5184 197.0902 700.0005 204.6845 700.4827 212.0167 700.9648 220.3357 701.4469 226.1824 701.9290 226.9615 702.4111 227.6537 702.8932 232.3521 703.3754 239.0543 703.8575 243.5850 704.3396 244.2245 704.8217 241.9725 705.3038 236.5236 705.7859 228.9059 706.2681 224.2623 706.7502 223.2838 707.2323 223.5519 707.7144 224.4273 708.1965 225.1014 708.6786 223.4282 709.1607 218.2514 709.6428 214.2557 710.1249 213.9923 710.6071 212.7183 711.0892 207.1533 711.5713 198.9038 712.0534 190.8690 712.5355 183.9905 713.0176 177.3204 713.4998 169.0656 713.9819 159.8900 714.4640 153.3113 714.9461 149.6031 715.4282 147.2742 715.9103 146.0572 716.3925 145.5752 716.8746 145.7555 717.3567 146.9484 717.8388 145.8763 718.3209 140.4919 718.8030 134.7209 719.2852 131.1666 719.7673 128.0196 720.2494 121.8290 720.7315 112.3501 721.2136 103.6503 721.6957 99.98596 722.1779 99.79517 722.6600 97.21545 723.1421 91.82269 723.6242 87.72589 724.1063 86.83151 724.5884 86.48294 725.0706 83.32629 725.5527 77.66458 726.0348 74.05450 726.5169 73.95551 726.9990 74.41858 727.4811 76.29657 727.9633 77.08701 728.4454 72.79434 728.9275 64.28397 729.4096 57.25244 729.8917 55.82535 730.3738 57.04956 730.8560 54.58835 731.3381 48.29694 731.8202 42.09821 732.3023 35.89618 732.7844 32.20462 733.2665 33.96521 733.7487 39.32648 734.2308 41.84506 734.7129 40.42474 735.1950 38.80490 735.6771 36.62863 736.1592 34.97858 736.6414 34.80493 737.1235 36.05829 737.6056 38.42691 738.0877 41.98315 738.5698 46.33752 739.0519 50.20740 739.5341 53.33966 740.0162 57.43323 740.4983 63.07043 740.9804 69.43277 741.4625 76.79623 741.9446 83.69324 742.4268 86.62744 742.9089 84.12927 743.3910 84.31058 743.8731 89.94662 744.3552 96.80865 744.8373 102.7504 745.3195 107.9229 745.8016 114.1919 746.2837 121.8839 746.7658 128.0154 747.2479 128.7768 747.7300 125.7178 748.2122 123.9927 748.6943 123.7961 749.1764 121.9770 749.6585 116.9932 750.1406 111.4135 750.6227 108.4453 751.1049 107.9514 751.5870 104.1759 752.0691 94.30182 752.5512 85.35834 753.0333 78.49072 753.5154 73.10962 753.9976 69.54074 754.4797 66.89539 754.9618 63.11819 755.4439 57.05841 755.9260 49.97644 756.4081 42.65213 756.8903 35.48807 757.3724 31.09482 757.8545 29.97836 758.3366 28.47208 758.8187 24.03262 759.3008 17.87341 759.7830 13.02667 760.2651 9.395966 760.7472 7.369080 761.2293 7.551849 761.7114 8.503906 762.1935 10.76831 762.6757 12.98865 763.1578 12.38913 763.6399 8.573853 764.1220 6.817841 764.6041 13.14056 765.0862 22.48737 765.5684 27.40991 766.0505 28.31387 766.5326 26.82401 767.0147 23.22488 767.4968 21.20963 767.9789 25.53278 768.4611 35.77887 768.9432 41.82303 769.4253 41.30643 769.9074 40.65942 770.3895 40.62289 770.8716 40.97366 771.3538 41.94354 771.8359 43.20914 772.3180 43.78027 772.8001 43.20282 773.2822 42.23370 773.7643 41.17667 774.2465 40.07434 774.7286 38.79019 775.2107 37.49463 775.6928 36.93213 776.1749 37.53610 776.6570 38.94769 777.1392 41.18234 777.6213 44.94772 778.1034 43.99585 778.5855 35.53183 779.0676 27.72748 779.5497 25.07272 780.0319 24.48785 780.5140 22.00836 780.9961 17.37625 781.4782 12.93631 781.9603 8.675201 782.4424 5.369781 782.9246 4.026978 783.4067 3.665558 783.8888 2.745270 784.3709 1.082031 784.8530 0.1217650 785.3351 0.4541320 785.8173 1.577179 786.2994 0.4432070 786.7815 5.587372 787.2636 8.957611 787.7457 9.451233 788.2278 8.698608 788.7100 7.345825 789.1921 5.837006 789.6742 6.044098 790.1563 9.664734 790.6384 11.78265 791.1205 10.60910 791.6026 9.408295 792.0847 10.82269 792.5668 13.19186 793.0490 13.32446 793.5311 10.31992 794.0132 6.995300 794.4953 4.954681 794.9774 4.453278 795.4595 7.574646 795.9417 13.26328 796.4238 14.62793 796.9059 9.194092 797.3880 2.420837 797.8701 0.3957820 798.3522 2.773224 798.8344 4.214050 799.3165 4.868347 799.7986 4.325317 800.2807 0.2521970 800.7628 2.986542 801.2449 1.340424 801.7271 3.175385 802.2092 4.597565 802.6913 0.2782290 803.1734 3.797272 803.6555 0.1474910 804.1376 5.859894 804.6198 6.750244 805.1019 3.778412 805.5840 1.400574 806.0661 1.532593 806.5482 2.379700 807.0303 1.582306 807.5125 0.7151490 807.9946 3.187622 808.4767 5.896118 808.9588 8.546234 809.4409 11.55573 809.9230 13.64154 810.4052 12.80020 810.8873 9.038818 811.3694 6.959625 811.8515 8.035309 812.3336 8.736633 812.8157 7.195190 813.2979 6.015137 813.7800 8.351563 814.2621 12.81558 814.7442 15.12854 815.2263 13.19183 815.7084 10.26968 816.1906 9.446899 816.6727 9.972290 817.1548 10.11740 817.6369 9.941010 818.1190 11.15973 818.6011 14.69019 819.0833 18.34189 819.5654 18.73407 820.0475 15.71027 820.5296 13.73093 821.0117 12.58304 821.4938 12.92752 821.9760 16.83206 822.4581 20.63812 822.9402 20.86987 823.4223 18.24228 823.9044 16.21103 824.3865 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