#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 15:33:29 +0300 (Thu, 24 May 2018) $ #$Revision: 721 $ #$URL: svn://172.16.1.111/rod/cif/1/00/02/1000226.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000226 loop_ _publ_author_name 'Kolitsch, U.' _publ_section_title ; The crystal structures of kidwellite and 'laubmannite', two complex fibrous iron phosphates Locality: Clara mine, Black Forest, Germany ; _journal_name_full 'Mineralogical Magazine' _journal_page_first 147 _journal_page_last 165 _journal_paper_doi 10.1180/0026461046810177 _journal_volume 68 _journal_year 2004 _chemical_compound_source R060324 _chemical_formula_sum 'As0.476 Cu0.356 Fe9 H19 Na O38 P5.524' _chemical_name_mineral Kidwellite _space_group_IT_number 13 _symmetry_space_group_name_Hall '-P 2yc' _symmetry_space_group_name_H-M 'P 1 2/c 1' _cell_angle_alpha 90 _cell_angle_beta 107.07 _cell_angle_gamma 90 _cell_length_a 20.117 _cell_length_b 5.185 _cell_length_c 13.978 _cell_volume 1393.769 _exptl_crystal_density_diffrn 3.293 _cod_original_formula_sum 'Na Fe9 (P5.524 As.476) Cu.356 O38 H19' _cod_database_code 9011825 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R060324.rod _rod_data_source.block 3500000 _rod_database.code 1000226 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9011825 COD http://www.crystallography.net/cod/9011825.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 160.8812 0.0000000E+00 161.3633 0.8223880 161.8455 2.107056 162.3276 2.322632 162.8097 10.68262 163.2918 23.54980 163.7739 39.33337 164.2560 56.83472 164.7382 67.10535 165.2203 80.83679 165.7024 97.69714 166.1845 115.4601 166.6666 134.0291 167.1487 152.6855 167.6309 170.7010 168.1130 188.7142 168.5951 207.7246 169.0772 230.0331 169.5593 252.7278 170.0414 273.3125 170.5236 291.1667 171.0057 307.4430 171.4878 323.7633 171.9699 339.6644 172.4520 353.2401 172.9341 362.7831 173.4163 369.8109 173.8984 375.9443 174.3805 381.2041 174.8626 386.1735 175.3447 392.3728 175.8268 399.2690 176.3090 404.4581 176.7911 404.6854 177.2732 402.3627 177.7553 401.7408 178.2374 405.7401 178.7195 409.7620 179.2017 407.1311 179.6838 398.3589 180.1659 388.4664 180.6480 380.4017 181.1301 374.0898 181.6122 369.4575 182.0944 367.7090 182.5765 366.9009 183.0586 363.3464 183.5407 356.9956 184.0228 349.6912 184.5049 343.4033 184.9871 337.6896 185.4692 331.1055 185.9513 321.9697 186.4334 312.0719 186.9155 305.9978 187.3976 304.0383 187.8798 302.8907 188.3619 298.9036 188.8440 292.4957 189.3261 286.6726 189.8082 282.7988 190.2903 280.1976 190.7725 276.3618 191.2546 271.0809 191.7367 265.4093 192.2188 260.5540 192.7009 256.4144 193.1830 252.0376 193.6652 246.7990 194.1473 240.8795 194.6294 235.6750 195.1115 231.1008 195.5936 227.4865 196.0757 225.7283 196.5579 225.8975 197.0400 225.8483 197.5221 224.8237 198.0042 222.8698 198.4863 220.0194 198.9684 215.9064 199.4506 211.7719 199.9327 209.6453 200.4148 209.6605 200.8969 210.2305 201.3790 211.2361 201.8611 214.1041 202.3433 218.7064 202.8254 225.3921 203.3075 232.3071 203.7896 237.2626 204.2717 239.7849 204.7538 242.4625 205.2360 244.3621 205.7181 244.5834 206.2002 244.2428 206.6823 244.9240 207.1644 245.8278 207.6465 245.4208 208.1287 243.5099 208.6108 241.0844 209.0929 238.6047 209.5750 236.1555 210.0571 233.3116 210.5392 230.0795 211.0214 226.5088 211.5035 222.5742 211.9856 218.2068 212.4677 213.9285 212.9498 210.0424 213.4319 206.7653 213.9140 203.2893 214.3962 199.7140 214.8783 195.8333 215.3604 191.0088 215.8425 184.4452 216.3246 178.5243 216.8067 174.6061 217.2889 173.7299 217.7710 171.2764 218.2531 166.9138 218.7352 159.8064 219.2173 151.7845 219.6994 142.0544 220.1816 133.0481 220.6637 125.8268 221.1458 121.0603 221.6279 115.9177 222.1100 109.6653 222.5921 103.2753 223.0743 99.40112 223.5564 99.54907 224.0385 99.69043 224.5206 97.82300 225.0027 92.79138 225.4848 88.82178 225.9670 85.97290 226.4491 84.28369 226.9312 84.00598 227.4133 86.02881 227.8954 88.02649 228.3775 88.68860 228.8597 86.77869 229.3418 86.53540 229.8239 88.69531 230.3060 92.28528 230.7881 94.65979 231.2702 95.48499 231.7524 95.49194 232.2345 94.89575 232.7166 93.20972 233.1987 92.03809 233.6808 92.20312 234.1629 92.69043 234.6451 90.52222 235.1272 84.27454 235.6093 77.61145 236.0914 72.42957 236.5735 70.52979 237.0556 65.94958 237.5378 57.22559 238.0199 46.32031 238.5020 38.37683 238.9841 35.18628 239.4662 32.20837 239.9483 27.45337 240.4305 20.28503 240.9126 12.88831 241.3947 4.800781 241.8768 3.407227 242.3589 10.25928 242.8410 15.26624 243.3232 19.73755 243.8053 24.34961 244.2874 30.01733 244.7695 33.64050 245.2516 34.77515 245.7337 34.09045 246.2159 32.95483 246.6980 30.95667 247.1801 29.13696 247.6622 28.30444 248.1443 29.92456 248.6264 28.25403 249.1086 22.48328 249.5907 13.81519 250.0728 4.731689 250.5549 4.383423 251.0370 14.56897 251.5191 26.43555 252.0013 40.40869 252.4834 54.17944 252.9655 67.10400 253.4476 80.04822 253.9297 94.78284 254.4118 112.1390 254.8940 129.3892 255.3761 145.1168 255.8582 158.3535 256.3403 174.3085 256.8224 193.8876 257.3046 215.5165 257.7867 236.3113 258.2688 256.4443 258.7509 275.7775 259.2330 293.9075 259.7151 310.6639 260.1973 328.2091 260.6794 346.6031 261.1615 365.2942 261.6436 383.1620 262.1257 400.4847 262.6078 417.0018 263.0900 432.2828 263.5721 446.3108 264.0542 460.0220 264.5363 473.6183 265.0184 487.0063 265.5005 500.4745 265.9827 513.9948 266.4648 527.0868 266.9469 539.3987 267.4290 550.8340 267.9111 563.0549 268.3932 576.4429 268.8754 589.4443 269.3575 599.9987 269.8396 607.5334 270.3217 615.3684 270.8038 624.6750 271.2859 635.3342 271.7681 644.0167 272.2502 649.8641 272.7323 655.1946 273.2144 662.8652 273.6965 673.7299 274.1786 682.4374 274.6608 687.7551 275.1429 689.9698 275.6250 691.4246 276.1071 691.9343 276.5892 691.6091 277.0714 690.9861 277.5535 690.3271 278.0356 687.5208 278.5177 681.6343 278.9998 673.4963 279.4819 667.1118 279.9641 663.1357 280.4462 657.9712 280.9283 647.6946 281.4104 632.2000 281.8925 618.5699 282.3746 608.6766 282.8568 600.7404 283.3389 589.5660 283.8210 574.8790 284.3031 558.9656 284.7852 543.2410 285.2673 527.7799 285.7495 511.6744 286.2316 494.6053 286.7137 477.0664 287.1958 460.0217 287.6779 443.4521 288.1600 427.2637 288.6422 411.8203 289.1243 396.7587 289.6064 380.6650 290.0885 363.0212 290.5706 344.7992 291.0527 327.2670 291.5349 310.4573 292.0170 294.5283 292.4991 280.4913 292.9812 267.5886 293.4633 253.2466 293.9454 236.9280 294.4276 220.5350 294.9097 206.6947 295.3918 195.1218 295.8739 184.6324 296.3560 174.6476 296.8381 165.3580 297.3203 157.6702 297.8024 151.6985 298.2845 146.5278 298.7666 141.5852 299.2487 136.7701 299.7308 131.2948 300.2130 124.5005 300.6951 117.1208 301.1772 110.0577 301.6593 103.3116 302.1414 96.96265 302.6235 91.80261 303.1057 87.42993 303.5878 82.88794 304.0699 77.34924 304.5520 71.93115 305.0341 67.93237 305.5162 65.21094 305.9984 62.80676 306.4805 60.61267 306.9626 58.73547 307.4447 57.13745 307.9268 55.60754 308.4089 54.49194 308.8911 54.19446 309.3732 54.23413 309.8553 53.69006 310.3374 52.14307 310.8195 49.67163 311.3016 45.99207 311.7838 39.98816 312.2659 35.06885 312.7480 34.72339 313.2301 37.36230 313.7122 39.00049 314.1943 37.17639 314.6765 34.11169 315.1586 31.36658 315.6407 29.31140 316.1228 27.12439 316.6049 23.87415 317.0870 20.31213 317.5692 17.72510 318.0513 18.09546 318.5334 18.23975 319.0155 16.20093 319.4976 11.40503 319.9797 7.189697 320.4619 5.291626 320.9440 4.272949 321.4261 2.552979 321.9082 1.180420 322.3903 4.815552 322.8724 7.597168 323.3546 9.478516 323.8367 11.48743 324.3188 14.56836 324.8009 17.41418 325.2830 18.99414 325.7651 17.53162 326.2473 16.59082 326.7294 16.84778 327.2115 18.14490 327.6936 19.32397 328.1757 20.93188 328.6578 21.92212 329.1400 21.76282 329.6221 19.70752 330.1042 17.52319 330.5863 15.00427 331.0684 12.36426 331.5505 10.35278 332.0327 10.18945 332.5148 9.236938 332.9969 6.142456 333.4790 0.3986820 333.9611 5.136597 334.4432 6.954468 334.9254 7.588867 335.4075 10.08948 335.8896 15.30664 336.3717 20.76782 336.8538 25.49988 337.3359 29.38757 337.8180 34.43579 338.3001 40.79053 338.7823 48.08411 339.2644 55.85986 339.7465 64.20715 340.2286 73.02075 340.7107 82.79407 341.1928 93.16992 341.6750 100.0845 342.1571 102.8339 342.6392 105.0981 343.1213 110.3534 343.6034 118.5898 344.0855 126.1625 344.5677 132.2452 345.0498 137.4465 345.5319 142.8171 346.0140 148.3344 346.4961 154.6061 346.9782 162.6218 347.4604 171.9762 347.9425 180.2377 348.4246 187.1963 348.9067 193.3220 349.3888 199.0891 349.8709 204.5793 350.3531 210.1715 350.8352 216.4941 351.3173 222.9506 351.7994 228.5259 352.2815 233.1592 352.7636 236.9445 353.2458 239.1522 353.7279 240.5763 354.2100 242.9749 354.6921 248.6118 355.1742 254.4138 355.6563 257.0544 356.1385 256.6752 356.6206 255.1158 357.1027 252.2550 357.5848 249.4135 358.0669 248.2694 358.5490 250.3370 359.0312 252.5798 359.5133 253.1897 359.9954 252.4241 360.4775 251.1260 360.9596 249.0243 361.4417 246.9604 361.9239 245.5061 362.4060 244.8406 362.8881 244.4933 363.3702 244.4750 363.8523 244.6268 364.3344 244.7145 364.8166 244.6350 365.2987 244.5173 365.7808 244.3317 366.2629 244.0437 366.7450 244.0754 367.2271 244.5757 367.7093 245.4167 368.1914 246.4865 368.6735 248.3053 369.1556 249.8110 369.6377 250.4088 370.1198 250.2942 370.6020 251.2866 371.0841 253.9224 371.5662 257.1934 372.0483 260.5742 372.5304 264.2037 373.0125 267.7180 373.4947 271.2935 373.9768 274.6415 374.4589 276.9825 374.9410 277.7859 375.4231 278.6676 375.9052 280.8529 376.3874 284.8680 376.8695 285.6951 377.3516 282.4760 377.8337 277.2557 378.3158 272.7633 378.7979 269.2668 379.2801 264.7167 379.7622 258.5645 380.2443 250.7936 380.7264 240.7963 381.2085 228.4713 381.6906 215.2388 382.1728 202.2450 382.6549 189.2986 383.1370 175.8177 383.6191 161.5214 384.1012 147.2153 384.5833 134.2225 385.0655 122.3073 385.5476 110.3062 386.0297 96.95630 386.5118 83.06714 386.9939 69.62988 387.4760 56.81348 387.9582 45.23767 388.4403 35.59534 388.9224 27.54895 389.4045 20.37708 389.8866 13.69141 390.3687 7.607178 390.8509 1.965576 391.3330 2.902222 391.8151 5.893311 392.2972 5.165161 392.7793 3.000366 393.2614 1.559082 393.7436 2.023315 394.2257 2.495117 394.7078 2.433960 395.1899 1.795044 395.6720 0.4511720 396.1541 1.632813 396.6363 4.453247 397.1184 7.859863 397.6005 11.51990 398.0826 16.81958 398.5647 24.73682 399.0468 34.14966 399.5290 43.69812 400.0111 53.58850 400.4932 63.28564 400.9753 72.27686 401.4574 80.61035 401.9395 90.39038 402.4217 102.0183 402.9038 114.7181 403.3859 128.0140 403.8680 141.9379 404.3501 156.4545 404.8322 171.6472 405.3144 187.3157 405.7965 202.4644 406.2786 217.0364 406.7607 231.5215 407.2428 245.6355 407.7249 259.3651 408.2071 275.7740 408.6892 295.5188 409.1713 316.2406 409.6534 334.9575 410.1355 351.6954 410.6176 368.5244 411.0998 386.3562 411.5819 404.6240 412.0640 422.1743 412.5461 438.8698 413.0282 454.8182 413.5103 470.1178 413.9925 484.5154 414.4746 497.5426 414.9567 508.9619 415.4388 519.5358 415.9209 530.9514 416.4030 542.2858 416.8852 551.5327 417.3673 556.8784 417.8494 560.1116 418.3315 562.7676 418.8136 564.9192 419.2957 565.7887 419.7779 564.6501 420.2600 562.1279 420.7421 558.8888 421.2242 555.6915 421.7063 551.2054 422.1884 544.7836 422.6706 536.6870 423.1527 527.5784 423.6348 517.7291 424.1169 506.9691 424.5990 495.0229 425.0811 481.5503 425.5633 467.8538 426.0454 454.0043 426.5275 440.0171 427.0096 425.6229 427.4917 410.2019 427.9738 395.4712 428.4560 381.7961 428.9381 369.0411 429.4202 357.3540 429.9023 347.8093 430.3844 337.6201 430.8665 324.1191 431.3487 306.3007 431.8308 291.5258 432.3129 281.1879 432.7950 273.1661 433.2771 263.0601 433.7592 250.8434 434.2414 239.3658 434.7235 230.3311 435.2056 223.1646 435.6877 215.3417 436.1698 206.7921 436.6519 198.7698 437.1341 192.9333 437.6162 188.7594 438.0983 184.6801 438.5804 180.1693 439.0625 175.7623 439.5446 171.8209 440.0268 168.4504 440.5089 166.0010 440.9910 164.8530 441.4731 164.6440 441.9552 164.8999 442.4373 165.4703 442.9195 167.1946 443.4016 171.5366 443.8837 176.9475 444.3658 181.5336 444.8479 182.2629 445.3300 184.5850 445.8122 190.7159 446.2943 200.3051 446.7764 210.2527 447.2585 220.4672 447.7406 230.6412 448.2227 240.6497 448.7049 250.2394 449.1870 259.8960 449.6691 268.6937 450.1512 278.0138 450.6333 290.0709 451.1154 306.2057 451.5976 322.3634 452.0797 337.5664 452.5618 351.8639 453.0439 364.9729 453.5260 376.3718 454.0081 387.5601 454.4903 399.5533 454.9724 412.2664 455.4545 425.7854 455.9366 440.2019 456.4187 455.0447 456.9008 468.7806 457.3830 481.8094 457.8651 495.8510 458.3472 513.3138 458.8293 532.0358 459.3114 548.5035 459.7935 562.5895 460.2757 575.2133 460.7578 585.7388 461.2399 595.6050 461.7220 607.0344 462.2041 622.1373 462.6862 636.1580 463.1684 645.0657 463.6505 650.5430 464.1326 656.3285 464.6147 665.7930 465.0968 674.7433 465.5789 681.3302 466.0611 685.4712 466.5432 686.5614 467.0253 682.5319 467.5074 676.2101 467.9895 670.0304 468.4716 665.8990 468.9538 659.6119 469.4359 650.6860 469.9180 639.4944 470.4001 627.2439 470.8822 614.5302 471.3643 600.0751 471.8465 582.9943 472.3286 563.0505 472.8107 543.4569 473.2928 524.2458 473.7749 506.0042 474.2570 490.2520 474.7392 476.8369 475.2213 462.6943 475.7034 446.8146 476.1855 430.5436 476.6676 416.2559 477.1497 403.7114 477.6319 392.1810 478.1140 381.4254 478.5961 371.1332 479.0782 360.5928 479.5603 349.7219 480.0424 339.9996 480.5246 332.7747 481.0067 327.3115 481.4888 322.5753 481.9709 318.1060 482.4530 314.4202 482.9352 311.8881 483.4173 310.3676 483.8994 309.4154 484.3815 309.4418 484.8636 309.5284 485.3457 309.0443 485.8279 307.5183 486.3100 306.9937 486.7921 308.9067 487.2742 311.2080 487.7563 312.0150 488.2384 310.1019 488.7206 308.8524 489.2027 309.1346 489.6848 310.2845 490.1669 309.9056 490.6490 307.7703 491.1311 304.9064 491.6133 301.7485 492.0954 298.2859 492.5775 294.7533 493.0596 291.1987 493.5417 287.5350 494.0238 284.1462 494.5060 280.7172 494.9881 275.5985 495.4702 267.7635 495.9523 259.1470 496.4344 252.9257 496.9165 248.5376 497.3987 243.9127 497.8808 238.5958 498.3629 231.9678 498.8450 222.6846 499.3271 210.4010 499.8092 198.9410 500.2914 190.9585 500.7735 184.3713 501.2556 176.8875 501.7377 166.9086 502.2198 157.3859 502.7019 149.0220 503.1841 141.5250 503.6662 134.0247 504.1483 126.3610 504.6304 118.5997 505.1125 110.8971 505.5946 103.2838 506.0768 95.25562 506.5589 86.39880 507.0410 77.88318 507.5231 70.73486 508.0052 65.15363 508.4873 59.90240 508.9695 55.04828 509.4516 50.41693 509.9337 45.84747 510.4158 41.32159 510.8979 36.58350 511.3800 31.22101 511.8622 25.58600 512.3443 19.99060 512.8264 14.55377 513.3085 10.27588 513.7906 8.936584 514.2728 8.850403 514.7549 7.615417 515.2370 4.273621 515.7191 1.294189 516.2012 0.7712400 516.6833 1.513794 517.1655 1.632690 517.6476 0.3557130 518.1297 1.462341 518.6118 4.064270 519.0939 7.270996 519.5760 9.307800 520.0582 9.269165 520.5403 8.546692 521.0224 7.458435 521.5045 5.360779 521.9866 4.916016 522.4688 6.767700 522.9509 9.582275 523.4330 12.01544 523.9151 14.18585 524.3972 15.27045 524.8793 14.74200 525.3615 13.27533 525.8436 12.77118 526.3257 13.22382 526.8078 13.56781 527.2899 12.88922 527.7720 11.73163 528.2542 11.26672 528.7363 11.53198 529.2184 12.32892 529.7005 13.89014 530.1826 15.70947 530.6647 17.16760 531.1469 18.39948 531.6290 18.65540 532.1111 16.68011 532.5932 13.45526 533.0753 10.97955 533.5574 11.06567 534.0396 10.82343 534.5217 9.210144 535.0038 6.114807 535.4859 2.752686 535.9680 1.288635 536.4501 5.130005 536.9323 8.134949 537.4144 9.695190 537.8965 12.14795 538.3786 15.64874 538.8607 19.89813 539.3428 24.51935 539.8250 29.55585 540.3071 34.71454 540.7892 39.84735 541.2713 45.08655 541.7534 50.49060 542.2355 56.10645 542.7177 62.37390 543.1998 69.89191 543.6819 78.18866 544.1640 86.54016 544.6461 94.89508 545.1282 103.3275 545.6104 111.3553 546.0925 119.6348 546.5746 128.9204 547.0567 139.7656 547.5388 151.1298 548.0209 162.9582 548.5031 174.9546 548.9852 186.6842 549.4673 196.6238 549.9494 207.8649 550.4315 221.8636 550.9136 238.6008 551.3958 253.2074 551.8779 264.7448 552.3600 275.7659 552.8421 287.9708 553.3242 301.4725 553.8063 315.3271 554.2885 329.8105 554.7706 343.7738 555.2527 354.9587 555.7348 363.8878 556.2169 373.9400 556.6990 386.4631 557.1812 400.0219 557.6633 412.9435 558.1454 425.1984 558.6275 436.7079 559.1096 446.7190 559.5917 456.3771 560.0739 466.8555 560.5560 478.3030 561.0381 488.6500 561.5202 497.1432 562.0023 504.0747 562.4844 509.6804 562.9666 514.9553 563.4487 517.3469 563.9308 516.2176 564.4129 512.4618 564.8950 507.4916 565.3771 501.9778 565.8593 493.8524 566.3414 482.3756 566.8235 468.0066 567.3056 451.9722 567.7877 434.2556 568.2698 415.6158 568.7520 395.5195 569.2341 374.7474 569.7162 355.3827 570.1983 337.6924 570.6804 321.1236 571.1625 305.5418 571.6447 290.8984 572.1268 277.1717 572.6089 264.2037 573.0910 252.1743 573.5731 241.0756 574.0552 230.9113 574.5374 221.4409 575.0195 211.8154 575.5016 203.7187 575.9837 198.3535 576.4658 195.4598 576.9479 191.6824 577.4301 185.9554 577.9122 180.8401 578.3943 177.5357 578.8764 176.4694 579.3585 175.2159 579.8406 173.6938 580.3228 171.7219 580.8049 168.8171 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5.779663 955.4095 9.054321 955.8916 13.13251 956.3737 16.63123 956.8558 18.15588 957.3380 19.05914 957.8201 20.22955 958.3022 21.75677 958.7843 23.68835 959.2664 26.33862 959.7485 28.43652 960.2307 28.98285 960.7128 28.71490 961.1949 29.76245 961.6770 31.67120 962.1591 32.80206 962.6412 31.73346 963.1234 30.35199 963.6055 29.62793 964.0876 28.87415 964.5697 26.85986 965.0518 23.48022 965.5339 19.58142 966.0161 15.19757 966.4982 10.27814 966.9803 5.024780 967.4624 0.9868160 967.9445 8.380005 968.4266 17.47168 968.9088 27.12689 969.3909 37.43372 969.8730 47.84357 970.3551 57.84204 970.8372 67.33405 971.3193 79.06860 971.8015 92.95386 972.2836 108.9067 972.7657 127.5477 973.2478 147.3172 973.7299 166.4174 974.2120 185.3340 974.6942 205.5172 975.1763 226.8683 975.6584 250.3044 976.1405 276.5771 976.6226 304.4130 977.1047 331.8105 977.5869 359.1958 978.0690 388.6820 978.5511 420.3898 979.0332 453.2107 979.5153 486.4824 979.9974 520.5967 980.4796 556.1331 980.9617 593.2849 981.4438 630.8896 981.9259 669.4182 982.4080 708.2542 982.8901 747.4354 983.3723 787.0774 983.8544 827.4348 984.3365 868.5464 984.8186 910.5798 985.3007 955.4346 985.7828 999.2124 986.2650 1038.787 986.7471 1076.921 987.2292 1118.497 987.7113 1164.742 988.1934 1209.778 988.6755 1252.918 989.1577 1295.612 989.6398 1339.386 990.1219 1383.314 990.6040 1424.992 991.0861 1464.113 991.5682 1504.193 992.0504 1546.622 992.5325 1590.448 993.0146 1635.544 993.4967 1681.237 993.9788 1728.384 994.4609 1777.022 994.9431 1825.766 995.4252 1873.230 995.9073 1922.016 996.3894 1977.243 996.8715 2035.653 997.3536 2093.048 997.8358 2148.519 998.3179 2201.359 998.8000 2250.986 999.2821 2298.974 999.7642 2348.324 1000.246 2398.486 1000.728 2444.602 1001.211 2486.884 1001.693 2522.866 1002.175 2550.564 1002.657 2572.369 1003.139 2589.717 1003.621 2602.267 1004.103 2608.241 1004.585 2608.073 1005.068 2599.398 1005.550 2580.743 1006.032 2554.815 1006.514 2526.171 1006.996 2493.335 1007.478 2452.286 1007.960 2400.353 1008.442 2344.729 1008.924 2286.252 1009.407 2224.995 1009.889 2159.857 1010.371 2090.989 1010.853 2021.273 1011.335 1949.895 1011.817 1877.622 1012.299 1802.626 1012.781 1727.990 1013.263 1655.588 1013.746 1585.398 1014.228 1516.266 1014.710 1446.954 1015.192 1381.123 1015.674 1320.488 1016.156 1262.209 1016.638 1199.359 1017.120 1134.453 1017.603 1076.069 1018.085 1025.623 1018.567 978.0706 1019.049 929.9251 1019.531 883.8760 1020.013 841.5356 1020.495 802.8360 1020.977 765.2491 1021.459 728.6418 1021.942 694.0561 1022.424 662.1769 1022.906 632.4705 1023.388 603.5643 1023.870 575.9030 1024.352 550.3270 1024.834 527.3412 1025.316 506.2648 1025.799 487.2407 1026.281 469.5397 1026.763 451.7847 1027.245 434.6542 1027.727 421.3040 1028.209 411.7980 1028.691 402.9457 1029.173 391.9009 1029.656 381.3152 1030.138 373.5125 1030.620 367.9933 1031.102 361.3611 1031.584 352.8525 1032.066 346.2535 1032.548 342.7328 1033.030 340.7544 1033.512 338.5194 1033.995 336.1026 1034.477 333.3705 1034.959 329.6569 1035.441 328.1151 1035.923 331.7258 1036.405 335.1615 1036.887 335.1865 1037.369 332.3297 1037.851 331.0845 1038.334 331.4341 1038.816 332.8555 1039.298 336.7019 1039.780 339.9150 1040.262 339.4650 1040.744 337.2186 1041.226 336.9511 1041.708 339.3765 1042.191 342.0007 1042.673 344.5657 1043.155 347.7312 1043.637 352.4708 1044.119 358.1951 1044.601 363.5287 1045.083 368.5240 1045.565 375.1987 1046.047 385.5493 1046.530 396.2524 1047.012 405.9500 1047.494 415.3674 1047.976 426.6120 1048.458 439.6429 1048.940 452.9277 1049.422 465.9208 1049.904 479.7220 1050.386 495.5724 1050.869 512.5466 1051.351 529.6348 1051.833 546.4746 1052.315 565.4073 1052.797 586.9065 1053.279 608.4940 1053.761 628.9411 1054.243 648.8564 1054.726 669.3140 1055.208 690.2131 1055.690 711.3040 1056.172 733.7514 1056.654 754.5793 1057.136 773.2574 1057.618 790.6900 1058.100 808.9214 1058.583 827.2065 1059.065 840.1980 1059.547 847.5619 1060.029 852.4052 1060.511 857.0717 1060.993 859.6273 1061.475 858.5218 1061.957 854.1666 1062.439 848.1717 1062.922 840.5176 1063.404 831.2673 1063.886 820.3813 1064.368 808.2910 1064.850 794.9476 1065.332 780.8565 1065.814 766.5364 1066.296 752.1011 1066.778 737.9648 1067.261 723.3850 1067.743 710.4206 1068.225 700.8051 1068.707 693.2831 1069.189 683.7438 1069.671 672.8599 1070.153 663.0332 1070.635 656.4437 1071.118 649.5580 1071.600 641.1749 1072.082 631.9449 1072.564 622.0304 1073.046 611.2816 1073.528 603.8916 1074.010 600.1921 1074.492 595.2557 1074.974 584.4539 1075.457 571.3536 1075.939 558.4726 1076.421 546.1970 1076.903 535.0020 1077.385 526.1920 1077.867 515.3217 1078.349 501.3201 1078.831 485.8452 1079.313 470.7336 1079.796 455.8422 1080.278 441.1227 1080.760 426.5189 1081.242 412.0857 1081.724 398.1429 1082.206 384.0298 1082.688 369.8026 1083.170 355.2057 1083.652 339.6600 1084.135 323.2549 1084.617 307.5103 1085.099 293.1972 1085.581 279.3832 1086.063 265.1577 1086.545 251.4065 1087.027 238.7643 1087.509 227.5320 1087.992 214.5774 1088.474 199.8185 1088.956 185.9367 1089.438 174.8267 1089.920 165.0439 1090.402 155.2000 1090.884 145.4551 1091.366 135.9238 1091.849 126.1179 1092.331 117.2698 1092.813 109.6824 1093.295 102.5054 1093.777 94.81274 1094.259 86.95496 1094.741 79.04016 1095.223 71.23438 1095.705 64.75348 1096.188 61.25537 1096.670 57.99084 1097.152 54.19812 1097.634 50.26001 1098.116 46.72479 1098.598 43.58954 1099.080 40.87238 1099.562 38.52887 1100.044 36.49768 1100.527 34.37323 1101.009 32.93976 1101.491 33.12054 1101.973 34.45172 1102.455 34.32727 1102.937 32.67365 1103.419 31.52661 1103.901 31.67084 1104.384 32.41968 1104.866 33.23901 1105.348 34.18719 1105.830 35.37000 1106.312 36.92139 1106.794 38.31464 1107.276 39.59155 1107.758 40.47290 1108.240 40.37506 1108.723 40.11737 1109.205 41.03516 1109.687 42.85284 1110.169 44.90961 1110.651 47.96741 1111.133 49.68188 1111.615 49.37903 1112.097 48.61218 1112.579 48.85864 1113.062 49.81653 1113.544 50.46344 1114.026 50.75092 1114.508 50.72784 1114.990 50.79572 1115.472 50.04462 1115.954 47.71033 1116.436 44.80585 1116.919 42.92743 1117.401 41.96411 1117.883 40.84692 1118.365 39.44653 1118.847 38.00934 1119.329 37.24991 1119.811 36.03293 1120.293 33.28296 1120.776 29.34241 1121.258 25.59900 1121.740 22.05905 1122.222 18.57858 1122.704 15.01511 1123.186 11.88770 1123.668 10.12695 1124.150 8.670013 1124.632 6.186371 1125.115 2.358154 1125.597 0.8152160 1126.079 3.092865 1126.561 5.455353 1127.043 8.483276 1127.525 11.51495 1128.007 13.29333 1128.489 14.38675 1128.971 15.74939 1129.454 17.75925 1129.936 19.64218 1130.418 21.44702 1130.900 22.93286 1131.382 24.19513 1131.864 24.96167 1132.346 24.03259 1132.828 21.97928 1133.311 20.59747 1133.793 20.88660 1134.275 21.65488 1134.757 23.32129 1135.239 24.66577 1135.721 24.59009 1136.203 23.17090 1136.685 20.91559 1137.167 17.99515 1137.650 15.77945 1138.132 15.34259 1138.614 15.47516 1139.096 16.42679 1139.578 17.22647 1140.060 16.36404 1140.542 13.81976 1141.024 10.72690 1141.506 7.158997 1141.989 4.352081 1142.471 3.996857 1142.953 4.017181 1143.435 3.099152 1143.917 1.313873 1144.399 0.9754030 1144.881 3.961334 1145.363 5.801819 1145.846 6.049622 1146.328 6.063507 1146.810 7.688354 1147.292 9.511169 1147.774 9.638672 1148.256 8.075897 1148.738 8.550415 1149.220 11.73416 1149.703 14.50525 1150.185 15.99460 1150.667 16.82651 1151.149 17.26654 1151.631 17.77731 1152.113 19.28912 1152.595 22.23453 1153.077 23.66519 1153.559 22.75607 1154.042 22.16574 1154.524 23.18683 1155.006 24.80344 1155.488 24.95767 1155.970 24.30347 1156.452 24.31351 1156.934 25.76312 1157.416 26.54250 1157.898 25.84012 1158.381 25.49086 1158.863 26.74359 1159.345 28.94859 1159.827 30.41246 1160.309 31.26978 1160.791 31.84187 1161.273 31.65034 1161.755 32.34799 1162.238 34.65454 1162.720 37.33400 1163.202 39.37784 1163.684 41.02496 1164.166 43.60042 1164.648 46.93207 1165.130 50.25467 1165.612 53.26401 1166.094 56.07779 1166.577 57.91348 1167.059 60.35707 1167.541 65.61566 1168.023 73.23019 1168.505 78.64981 1168.987 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1195.986 31.12536 1196.468 29.63072 1196.950 28.75953 1197.432 28.77802 1197.914 27.64592 1198.396 25.25310 1198.878 23.25453 1199.360 22.61990 1199.843 22.50729 1200.325 22.03754 1200.807 21.25841 1201.289 20.23988 1201.771 18.90224 1202.253 18.11597 1202.735 17.92072 1203.217 18.17587 1203.700 19.16378 1204.182 20.02911 1204.664 19.51451 1205.146 18.41810 1205.628 17.97625 1206.110 18.46253 1206.592 18.96767 1207.074 19.64862 1207.557 20.02690 1208.039 19.34276 1208.521 18.54951 1209.003 18.77094 1209.485 19.62292 1209.967 20.46304 1210.449 21.30673 1210.931 21.97832 1211.413 22.43105 1211.896 22.63432 1212.378 22.23430 1212.860 21.93835 1213.342 22.94209 1213.824 24.45181 1214.306 24.73215 1214.788 23.07439 1215.270 22.52303 1215.752 23.21172 1216.235 24.18543 1216.717 24.93934 1217.199 25.53207 1217.681 26.07565 1218.163 26.43578 1218.645 26.25198 1219.127 25.20839 1219.609 24.92500 1220.092 25.55494 1220.574 26.34403 1221.056 26.72489 1221.538 26.92471 1222.020 27.07368 1222.502 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