#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 15:35:26 +0300 (Thu, 24 May 2018) $ #$Revision: 751 $ #$URL: svn://172.16.1.111/rod/cif/1/00/02/1000255.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000255 loop_ _publ_author_name 'Redhammer, G. J.' 'Amthauer, G.' 'Roth, G.' 'Tippelt, G.' 'Lottermoser, W.' _publ_section_title ; Single crystal X-ray diffraction and temperature dependent 57Fe Mossbauer spectroscopy on the hedenbergite - aegirine (Ca,Na)(Fe2+,Fe3+)Si2O6 solid solution Locality: synthetic Sample: Hd21, T = 298 K ; _journal_name_full 'American Mineralogist' _journal_page_first 1271 _journal_page_last 1292 _journal_paper_doi 10.2138/am.2006.2173 _journal_volume 91 _journal_year 2006 _chemical_compound_source R070253 _chemical_formula_sum 'Ca Fe O6 Si2' _chemical_name_mineral Hedenbergite _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90 _cell_angle_beta 104.775 _cell_angle_gamma 90 _cell_length_a 9.8450 _cell_length_b 9.0293 _cell_length_c 5.2450 _cell_volume 450.830 _diffrn_ambient_temperature 298 _exptl_crystal_density_diffrn 3.655 _cod_original_formula_sum 'Ca Fe Si2 O6' _cod_database_code 9010072 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R070253.rod _rod_data_source.block 3500000 _rod_database.code 1000255 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9010072 COD http://www.crystallography.net/cod/9010072.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 129.5436 0.0000000E+00 130.0258 2.273804 130.5079 5.118454 130.9900 8.409607 131.4721 9.017776 131.9542 12.76671 132.4363 19.11136 132.9185 16.24800 133.4006 11.36882 133.8827 5.457947 134.3648 0.6948240 134.8469 3.991379 135.3290 4.184250 135.8112 2.713821 136.2933 1.472260 136.7754 0.5338130 137.2575 1.699890 137.7396 6.460480 138.2217 13.41721 138.7039 18.23151 139.1860 19.49622 139.6681 20.83783 140.1502 29.23697 140.6323 46.97229 141.1144 63.60938 141.5966 74.79980 142.0787 79.12198 142.5608 83.57144 143.0429 87.44226 143.5250 91.78207 144.0071 99.11313 144.4893 110.2607 144.9714 122.8598 145.4535 135.7205 145.9356 149.1915 146.4177 162.5558 146.8998 175.5020 147.3820 188.3397 147.8641 202.9993 148.3462 217.3479 148.8283 235.2503 149.3104 259.2942 149.7925 296.1536 150.2747 330.2553 150.7568 359.0036 151.2389 382.8860 151.7210 407.7536 152.2031 435.1683 152.6852 462.3094 153.1674 487.7820 153.6495 506.5591 154.1316 528.5832 154.6137 557.5223 155.0958 593.5756 155.5779 625.4916 156.0601 645.9020 156.5422 664.4118 157.0243 688.9540 157.5064 725.6182 157.9885 764.1131 158.4706 802.0297 158.9528 839.1913 159.4349 875.7006 159.9170 912.8130 160.3991 948.9507 160.8812 982.2773 161.3633 1017.517 161.8455 1045.615 162.3276 1062.604 162.8097 1067.348 163.2918 1063.517 163.7739 1046.643 164.2560 1021.027 164.7382 986.5742 165.2203 956.2939 165.7024 929.7654 166.1845 903.5439 166.6666 875.3973 167.1487 852.9294 167.6309 841.0103 168.1130 837.3614 168.5951 837.4158 169.0772 841.3900 169.5593 846.7106 170.0414 850.6488 170.5236 851.3524 171.0057 853.8450 171.4878 862.0504 171.9699 875.1236 172.4520 890.3023 172.9341 906.7563 173.4163 924.2869 173.8984 942.1694 174.3805 958.8257 174.8626 978.1907 175.3447 1006.753 175.8268 1042.786 176.3090 1078.513 176.7911 1105.083 177.2732 1128.181 177.7553 1157.745 178.2374 1201.181 178.7195 1246.748 179.2017 1283.441 179.6838 1311.234 180.1659 1325.048 180.6480 1313.806 181.1301 1285.807 181.6122 1259.941 182.0944 1240.672 182.5765 1227.091 183.0586 1216.125 183.5407 1207.895 184.0228 1206.733 184.5049 1216.960 184.9871 1237.645 185.4692 1265.341 185.9513 1301.748 186.4334 1343.451 186.9155 1384.039 187.3976 1421.655 187.8798 1459.829 188.3619 1503.224 188.8440 1551.227 189.3261 1595.807 189.8082 1634.135 190.2903 1667.525 190.7725 1703.144 191.2546 1742.835 191.7367 1776.315 192.2188 1792.709 192.7009 1792.670 193.1830 1781.964 193.6652 1760.765 194.1473 1729.971 194.6294 1696.252 195.1115 1659.427 195.5936 1620.068 196.0757 1578.531 196.5579 1534.930 197.0400 1491.148 197.5221 1446.930 198.0042 1402.482 198.4863 1360.094 198.9684 1319.345 199.4506 1281.647 199.9327 1250.055 200.4148 1224.713 200.8969 1202.830 201.3790 1184.144 201.8611 1168.835 202.3433 1150.771 202.8254 1128.142 203.3075 1106.352 203.7896 1096.043 204.2717 1099.052 204.7538 1101.730 205.2360 1096.404 205.7181 1081.398 206.2002 1075.530 206.6823 1081.055 207.1644 1092.973 207.6465 1101.717 208.1287 1105.777 208.6108 1111.571 209.0929 1123.257 209.5750 1142.900 210.0571 1157.555 210.5392 1166.462 211.0214 1171.303 211.5035 1176.341 211.9856 1183.425 212.4677 1185.636 212.9498 1179.463 213.4319 1163.830 213.9140 1144.699 214.3962 1122.062 214.8783 1095.892 215.3604 1066.415 215.8425 1032.976 216.3246 997.1199 216.8067 958.4849 217.2889 916.0937 217.7710 875.4600 218.2531 837.0666 218.7352 800.2896 219.2173 762.4146 219.6994 721.6699 220.1816 682.9129 220.6637 647.8879 221.1458 617.4076 221.6279 588.1966 222.1100 560.2440 222.5921 533.4521 223.0743 506.7463 223.5564 480.1323 224.0385 453.9330 224.5206 428.6694 225.0027 403.6505 225.4848 380.6162 225.9670 359.7424 226.4491 341.0167 226.9312 324.3875 227.4133 311.1442 227.8954 298.0338 228.3775 283.5281 228.8597 265.9336 229.3418 250.6229 229.8239 238.4122 230.3060 228.2236 230.7881 217.5069 231.2702 206.1634 231.7524 194.1729 232.2345 181.2756 232.7166 165.6674 233.1987 153.1635 233.6808 145.5908 234.1629 140.6973 234.6451 131.9041 235.1272 116.1223 235.6093 101.1708 236.0914 90.75458 236.5735 87.21771 237.0556 83.08344 237.5378 78.92542 238.0199 74.05798 238.5020 65.96002 238.9841 50.19855 239.4662 37.69861 239.9483 34.40619 240.4305 47.68140 240.9126 52.55121 241.3947 45.67969 241.8768 31.43982 242.3589 20.62463 242.8410 15.07910 243.3232 10.06842 243.8053 2.959412 244.2874 9.765991 244.7695 15.71069 245.2516 11.81958 245.7337 2.390869 246.2159 3.204407 246.6980 4.548218 247.1801 2.716064 247.6622 2.722412 248.1443 14.55127 248.6264 21.97937 249.1086 23.50592 249.5907 21.41327 250.0728 20.31219 250.5549 20.55933 251.0370 21.20605 251.5191 21.99634 252.0013 23.10583 252.4834 23.66107 252.9655 22.73718 253.4476 21.84479 253.9297 24.29346 254.4118 32.44122 254.8940 39.55939 255.3761 43.27478 255.8582 43.09680 256.3403 41.28650 256.8224 37.25073 257.3046 32.02472 257.7867 27.47949 258.2688 23.90161 258.7509 20.18250 259.2330 15.34058 259.7151 8.450684 260.1973 6.081055 260.6794 10.77563 261.1615 17.55920 261.6436 18.81909 262.1257 12.58057 262.6078 5.585205 263.0900 0.4438480 263.5721 5.637451 264.0542 8.957031 264.5363 9.679077 265.0184 9.418091 265.5005 10.17773 265.9827 11.87915 266.4648 14.86365 266.9469 20.22400 267.4290 28.07739 267.9111 31.07288 268.3932 27.42932 268.8754 21.60693 269.3575 18.72351 269.8396 19.50647 270.3217 20.51160 270.8038 20.76392 271.2859 20.36975 271.7681 21.21069 272.2502 23.78528 272.7323 26.58325 273.2144 26.92065 273.6965 23.58789 274.1786 24.53064 274.6608 32.65002 275.1429 46.79321 275.6250 59.25903 276.1071 70.20471 276.5892 79.02612 277.0714 84.00061 277.5535 84.61670 278.0356 86.62292 278.5177 91.62207 278.9998 98.69116 279.4819 103.5052 279.9641 105.4945 280.4462 107.8969 280.9283 114.3103 281.4104 124.8839 281.8925 132.7307 282.3746 135.7076 282.8568 136.1261 283.3389 140.8585 283.8210 150.3014 284.3031 160.9158 284.7852 170.4044 285.2673 178.7294 285.7495 186.9019 286.2316 194.7297 286.7137 202.8442 287.1958 213.2852 287.6779 226.1355 288.1600 238.1454 288.6422 247.5619 289.1243 254.4921 289.6064 258.6678 290.0885 259.4081 290.5706 259.2722 291.0527 262.0690 291.5349 267.7424 292.0170 275.3794 292.4991 285.7292 292.9812 297.8688 293.4633 308.2891 293.9454 317.0243 294.4276 323.5642 294.9097 325.7360 295.3918 324.3964 295.8739 323.9818 296.3560 326.7620 296.8381 331.9791 297.3203 338.5959 297.8024 346.8018 298.2845 354.0554 298.7666 356.6320 299.2487 355.8005 299.7308 355.5417 300.2130 356.1501 300.6951 358.8374 301.1772 366.7927 301.6593 379.8591 302.1414 392.8827 302.6235 401.8953 303.1057 408.6396 303.5878 415.5599 304.0699 422.9271 304.5520 430.8137 305.0341 439.0833 305.5162 447.6329 305.9984 457.2539 306.4805 470.6058 306.9626 485.4893 307.4447 498.1987 307.9268 506.8488 308.4089 514.1533 308.8911 523.4299 309.3732 533.7856 309.8553 541.6088 310.3374 542.7858 310.8195 541.4207 311.3016 542.1157 311.7838 547.8015 312.2659 550.6724 312.7480 544.8179 313.2301 532.4899 313.7122 518.9894 314.1943 505.0465 314.6765 492.0154 315.1586 481.3989 315.6407 474.3901 316.1228 466.2097 316.6049 453.1041 317.0870 437.5935 317.5692 424.0536 318.0513 413.5630 318.5334 404.8710 319.0155 397.2853 319.4976 390.7864 319.9797 386.8959 320.4619 387.9546 320.9440 391.0106 321.4261 392.6859 321.9082 386.7430 322.3903 384.5056 322.8724 391.0990 323.3546 406.8138 323.8367 421.4270 324.3188 429.9648 324.8009 438.4163 325.2830 451.2598 325.7651 471.7705 326.2473 493.8053 326.7294 515.5266 327.2115 537.4877 327.6936 564.0752 328.1757 598.8539 328.6578 635.6721 329.1400 671.5421 329.6221 701.6071 330.1042 736.7183 330.5863 778.0870 331.0684 824.7496 331.5505 873.0909 332.0327 924.3079 332.5148 976.1608 332.9969 1028.372 333.4790 1080.466 333.9611 1131.556 334.4432 1182.730 334.9254 1232.421 335.4075 1277.330 335.8896 1317.359 336.3717 1353.624 336.8538 1386.810 337.3359 1417.627 337.8180 1440.686 338.3001 1455.615 338.7823 1463.439 339.2644 1465.909 339.7465 1464.168 340.2286 1452.013 340.7107 1426.660 341.1928 1389.100 341.6750 1348.601 342.1571 1303.846 342.6392 1258.824 343.1213 1216.567 343.6034 1177.481 344.0855 1137.037 344.5677 1094.264 345.0498 1050.377 345.5319 1009.130 346.0140 970.5359 346.4961 934.3926 346.9782 902.2607 347.4604 872.8302 347.9425 840.2878 348.4246 802.5082 348.9067 765.3086 349.3888 737.7418 349.8709 718.5806 350.3531 700.9487 350.8352 681.6755 351.3173 661.6205 351.7994 641.0646 352.2815 619.8639 352.7636 601.5001 353.2458 590.2181 353.7279 584.2649 354.2100 579.8531 354.6921 575.1798 355.1742 571.5908 355.6563 570.5889 356.1385 572.0862 356.6206 575.0105 357.1027 578.5286 357.5848 583.0842 358.0669 589.0635 358.5490 595.7263 359.0312 605.0270 359.5133 619.4763 359.9954 637.8578 360.4775 656.5568 360.9596 676.0441 361.4417 693.8138 361.9239 707.6886 362.4060 715.5160 362.8881 724.5769 363.3702 740.2511 363.8523 758.8130 364.3344 773.8829 364.8166 780.7636 365.2987 785.5869 365.7808 790.4320 366.2629 795.3825 366.7450 800.0662 367.2271 808.4218 367.7093 815.1320 368.1914 815.3558 368.6735 800.3278 369.1556 788.4764 369.6377 785.0817 370.1198 788.0783 370.6020 783.9873 371.0841 766.5778 371.5662 748.2740 372.0483 735.6524 372.5304 730.6265 373.0125 726.7328 373.4947 724.1646 373.9768 723.0595 374.4589 723.0624 374.9410 723.6680 375.4231 726.5588 375.9052 732.4432 376.3874 741.4650 376.8695 750.7844 377.3516 759.8826 377.8337 770.1616 378.3158 784.1900 378.7979 802.6262 379.2801 821.3677 379.7622 839.2257 380.2443 856.3533 380.7264 874.6265 381.2085 894.1368 381.6906 913.5650 382.1728 931.1870 382.6549 947.4499 383.1370 964.9413 383.6191 984.9714 384.1012 1005.451 384.5833 1023.987 385.0655 1040.476 385.5476 1054.018 386.0297 1063.705 386.5118 1070.152 386.9939 1074.778 387.4760 1077.737 387.9582 1078.477 388.4403 1077.589 388.9224 1074.158 389.4045 1066.116 389.8866 1052.372 390.3687 1033.416 390.8509 1008.375 391.3330 977.8878 391.8151 945.6126 392.2972 914.5632 392.7793 882.5924 393.2614 847.4855 393.7436 808.6104 394.2257 767.3380 394.7078 723.3871 395.1899 677.6828 395.6720 632.6620 396.1541 587.7985 396.6363 544.8912 397.1184 505.0096 397.6005 468.9019 398.0826 433.8208 398.5647 398.2146 399.0468 363.8025 399.5290 332.6650 400.0111 307.6493 400.4932 282.9988 400.9753 256.9969 401.4574 229.5479 401.9395 205.7524 402.4217 186.6343 402.9038 169.8209 403.3859 153.8338 403.8680 138.7023 404.3501 124.0421 404.8322 109.1176 405.3144 95.05829 405.7965 85.62122 406.2786 81.46259 406.7607 79.51013 407.2428 79.67249 407.7249 82.11169 408.2071 79.90704 408.6892 72.18042 409.1713 62.34564 409.6534 54.57367 410.1355 48.80231 410.6176 42.63953 411.0998 34.16638 411.5819 25.55206 412.0640 23.30450 412.5461 27.22211 413.0282 31.09967 413.5103 29.81793 413.9925 25.14136 414.4746 20.21692 414.9567 15.01331 415.4388 11.26306 415.9209 12.28540 416.4030 16.24854 416.8852 18.55750 417.3673 15.85736 417.8494 11.24060 418.3315 6.907104 418.8136 3.040833 419.2957 0.4556880 419.7779 2.598755 420.2600 4.786560 420.7421 8.347656 421.2242 17.31909 421.7063 23.96283 422.1884 25.12158 422.6706 21.82635 423.1527 18.12024 423.6348 12.63770 424.1169 8.766113 424.5990 8.151855 425.0811 11.87372 425.5633 16.73914 426.0454 25.15009 426.5275 33.56592 427.0096 37.37860 427.4917 33.22150 427.9738 29.53082 428.4560 28.50378 428.9381 29.94946 429.4202 28.96112 429.9023 24.20312 430.3844 19.46930 430.8665 17.67181 431.3487 19.24268 431.8308 21.38007 432.3129 24.32507 432.7950 27.10687 433.2771 27.39996 433.7592 25.12262 434.2414 22.18054 434.7235 18.79767 435.2056 15.38226 435.6877 14.00610 436.1698 14.81470 436.6519 15.86127 437.1341 15.27869 437.6162 13.39355 438.0983 11.10400 438.5804 8.789673 439.0625 5.966736 439.5446 0.7222290 440.0268 5.915588 440.5089 10.17065 440.9910 8.468567 441.4731 4.223083 441.9552 3.3691000E-02 442.4373 4.152344 442.9195 7.058655 443.4016 7.613464 443.8837 6.828674 444.3658 5.933533 444.8479 4.952454 445.3300 4.253174 445.8122 5.085144 446.2943 6.959167 446.7764 5.810242 447.2585 4.065369 447.7406 13.18469 448.2227 16.45203 448.7049 9.450073 449.1870 5.010498 449.6691 3.834717 450.1512 4.900574 450.6333 6.664185 451.1154 9.039978 451.5976 12.39825 452.0797 17.38403 452.5618 23.77802 453.0439 27.84308 453.5260 29.04639 454.0081 29.39923 454.4903 30.40320 454.9724 32.04547 455.4545 33.63074 455.9366 35.09326 456.4187 36.41656 456.9008 37.39929 457.3830 38.11420 457.8651 39.07800 458.3472 40.78467 458.8293 42.83044 459.3114 44.72858 459.7935 46.45398 460.2757 47.46954 460.7578 45.55566 461.2399 43.19183 461.7220 44.42566 462.2041 53.39844 462.6862 60.90619 463.1684 59.00598 463.6505 51.03430 464.1326 44.76105 464.6147 44.84839 465.0968 46.11578 465.5789 45.68475 466.0611 42.95349 466.5432 41.53009 467.0253 44.08527 467.5074 47.20245 467.9895 48.00916 468.4716 44.19775 468.9538 40.77448 469.4359 37.83826 469.9180 35.52991 470.4001 34.35406 470.8822 34.56616 471.3643 35.53271 471.8465 37.47870 472.3286 40.70190 472.8107 41.57001 473.2928 39.51508 473.7749 36.53131 474.2570 34.18402 474.7392 32.48737 475.2213 33.52124 475.7034 38.62689 476.1855 45.55817 476.6676 49.72949 477.1497 51.23407 477.6319 51.91217 478.1140 51.55109 478.5961 51.39789 479.0782 53.54327 479.5603 58.37323 480.0424 64.58276 480.5246 72.65723 481.0067 81.16479 481.4888 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508.4873 161.9843 508.9695 155.7520 509.4516 152.2678 509.9337 146.9201 510.4158 139.8183 510.8979 133.0097 511.3800 126.0124 511.8622 120.2634 512.3443 119.8261 512.8264 124.4836 513.3085 130.1825 513.7906 133.6153 514.2728 136.3356 514.7549 140.9036 515.2370 148.8946 515.7191 155.4213 516.2012 153.4569 516.6833 148.8926 517.1655 150.7361 517.6476 166.4398 518.1297 184.5138 518.6118 202.3129 519.0939 219.5585 519.5760 234.6057 520.0582 245.7747 520.5403 255.7949 521.0224 264.6653 521.5045 269.1686 521.9866 282.7823 522.4688 309.9546 522.9509 341.3305 523.4330 364.3623 523.9151 376.5974 524.3972 394.5100 524.8793 423.0898 525.3615 458.0121 525.8436 488.0162 526.3257 513.2983 526.8078 539.0173 527.2899 569.9921 527.7720 603.6389 528.2542 632.9166 528.7363 657.2896 529.2184 681.8097 529.7005 711.1398 530.1826 742.7692 530.6647 772.9879 531.1469 798.6451 531.6290 825.7847 532.1111 857.8346 532.5932 893.5522 533.0753 930.2552 533.5574 966.5591 534.0396 1004.602 534.5217 1044.800 535.0038 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882.6099 345.1973 883.0920 330.0763 883.5741 313.7596 884.0562 298.0357 884.5383 285.7383 885.0204 277.4398 885.5026 268.9968 885.9847 259.7401 886.4668 249.8969 886.9489 239.7920 887.4310 229.2880 887.9131 217.5520 888.3953 202.6378 888.8774 191.5988 889.3595 192.0242 889.8416 195.0651 890.3237 192.0452 890.8058 180.4243 891.2880 169.7288 891.7701 159.9674 892.2522 151.2986 892.7343 143.9230 893.2164 137.6861 893.6985 132.8129 894.1807 129.3136 894.6628 124.4783 895.1449 114.1755 895.6270 103.9473 896.1091 97.86499 896.5912 96.55579 897.0734 94.38818 897.5555 91.05371 898.0376 87.64337 898.5197 85.09106 899.0018 82.74634 899.4839 77.76831 899.9661 70.62769 900.4482 64.07538 900.9303 59.89081 901.4124 56.51624 901.8945 53.75964 902.3766 51.03815 902.8588 46.12634 903.3409 36.00275 903.8230 29.44623 904.3051 29.47986 904.7872 32.12708 905.2693 28.25934 905.7515 19.21454 906.2336 13.56073 906.7157 14.90765 907.1978 16.72235 907.6799 11.06720 908.1620 3.651184 908.6442 1.723083 909.1263 13.62988 909.6084 18.46204 910.0905 12.67310 910.5726 3.956299 911.0547 0.9175420 911.5369 2.239441 912.0190 3.660217 912.5011 5.394775 912.9832 7.112366 913.4653 8.879333 913.9474 10.26678 914.4296 11.04443 914.9117 11.20496 915.3938 9.885376 915.8759 4.569519 916.3580 1.266602 916.8401 3.686646 917.3223 10.20819 917.8044 10.35602 918.2865 4.548889 918.7686 0.4782100 919.2507 0.1148070 919.7328 2.075806 920.2150 1.188110 920.6971 1.616943 921.1792 4.057739 921.6613 5.772339 922.1434 6.532532 922.6255 4.987244 923.1077 3.719543 923.5898 8.958130 924.0719 20.07947 924.5540 26.17206 925.0361 24.21191 925.5182 20.30066 926.0004 18.58923 926.4825 19.43774 926.9646 23.89886 927.4467 34.34827 927.9288 41.84412 928.4109 42.85229 928.8931 44.06268 929.3752 51.14203 929.8573 63.87347 930.3394 71.37842 930.8215 73.59937 931.3036 75.31311 931.7858 80.79169 932.2679 86.88348 932.7500 89.34955 933.2321 88.87659 933.7142 91.99207 934.1964 103.2896 934.6785 114.0126 935.1606 121.0539 935.6427 126.5264 936.1248 137.5876 936.6069 153.8053 937.0891 167.5192 937.5712 174.7150 938.0533 181.7755 938.5354 196.6304 939.0175 214.8658 939.4996 229.7022 939.9818 233.6587 940.4639 243.5565 940.9460 262.2786 941.4281 283.6622 941.9102 301.2863 942.3923 315.4623 942.8745 329.1826 943.3566 342.7124 943.8387 359.1891 944.3208 383.2546 944.8029 409.4155 945.2850 433.2211 945.7672 454.1301 946.2493 476.1866 946.7314 501.6824 947.2135 524.6003 947.6956 541.1742 948.1777 553.9002 948.6599 571.0648 949.1420 592.3974 949.6241 616.2466 950.1062 646.0424 950.5883 673.1176 951.0704 689.3788 951.5526 699.0075 952.0347 710.8753 952.5168 728.8629 952.9989 742.8834 953.4810 751.3276 953.9631 757.3366 954.4453 765.4566 954.9274 774.4673 955.4095 779.2019 955.8916 778.5904 956.3737 778.7306 956.8558 785.4326 957.3380 793.0298 957.8201 797.0238 958.3022 796.9446 958.7843 797.7914 959.2664 799.9401 959.7485 801.7778 960.2307 802.2934 960.7128 803.5401 961.1949 802.8856 961.6770 804.2780 962.1591 804.9025 962.6412 804.3742 963.1234 802.7057 963.6055 799.2242 964.0876 794.8777 964.5697 791.9832 965.0518 792.1117 965.5339 785.4881 966.0161 769.3840 966.4982 751.9606 966.9803 743.6951 967.4624 740.4310 967.9445 736.4125 968.4266 731.1033 968.9088 721.2001 969.3909 701.7933 969.8730 680.7424 970.3551 661.2191 970.8372 643.5504 971.3193 630.3131 971.8015 621.9144 972.2836 609.0290 972.7657 583.0237 973.2478 553.1829 973.7299 530.7082 974.2120 513.0295 974.6942 493.5341 975.1763 465.7504 975.6584 442.4543 976.1405 427.1268 976.6226 415.0908 977.1047 399.6749 977.5869 380.9277 978.0690 361.1003 978.5511 340.5417 979.0332 320.3934 979.5153 299.4568 979.9974 280.7506 980.4796 268.4748 980.9617 264.3532 981.4438 254.9308 981.9259 236.9214 982.4080 219.4968 982.8901 206.9402 983.3723 197.8329 983.8544 188.4675 984.3365 178.7015 984.8186 167.9514 985.3007 151.9191 985.7828 139.2548 986.2650 137.9731 986.7471 141.2191 987.2292 137.0383 987.7113 122.6433 988.1934 110.5914 988.6755 101.9595 989.1577 95.65442 989.6398 92.81342 990.1219 90.63702 990.6040 83.73492 991.0861 71.45007 991.5682 59.14679 992.0504 46.36554 992.5325 37.01038 993.0146 33.73584 993.4967 35.30487 993.9788 34.91187 994.4609 32.56989 994.9431 27.79669 995.4252 18.87402 995.9073 9.747375 996.3894 4.145325 996.8715 1.381104 997.3536 0.2035520 997.8358 3.232361 998.3179 3.253601 998.8000 1.452087 999.2821 6.753784 999.7642 8.452332 1000.246 7.188965 1000.728 6.471619 1001.211 6.452209 1001.693 5.870300 1002.175 2.545776 1002.657 0.4028320 1003.139 0.4666140 1003.621 1.985291 1004.103 3.904114 1004.585 5.835205 1005.068 4.783325 1005.550 1.140137 1006.032 8.359558 1006.514 12.27423 1006.996 12.96851 1007.478 9.717407 1007.960 1.191528 1008.442 6.959595 1008.924 0.1698610 1009.407 10.23975 1009.889 19.95020 1010.371 29.09351 1010.853 29.88025 1011.335 22.20917 1011.817 16.54956 1012.299 21.66547 1012.781 30.46594 1013.263 37.77106 1013.746 43.37671 1014.228 47.13220 1014.710 47.84442 1015.192 48.95215 1015.674 50.88214 1016.156 53.52161 1016.638 56.71582 1017.120 60.49420 1017.603 65.19617 1018.085 71.06812 1018.567 76.46796 1019.049 79.57147 1019.531 82.59363 1020.013 87.13177 1020.495 93.12933 1020.977 99.84375 1021.459 107.6284 1021.942 112.8069 1022.424 111.9052 1022.906 109.5266 1023.388 112.0425 1023.870 117.8375 1024.352 123.7479 1024.834 127.4615 1025.316 133.3605 1025.799 142.5040 1026.281 152.8743 1026.763 162.9478 1027.245 172.4600 1027.727 179.6500 1028.209 184.6749 1028.691 191.7105 1029.173 203.5596 1029.656 218.5680 1030.138 237.5558 1030.620 259.0640 1031.102 276.0894 1031.584 287.4055 1032.066 298.8378 1032.548 311.5978 1033.030 326.2556 1033.512 343.0498 1033.995 361.9636 1034.477 383.1090 1034.959 407.9637 1035.441 431.9766 1035.923 454.1309 1036.405 475.0587 1036.887 495.1417 1037.369 514.3109 1037.851 533.6284 1038.334 552.7444 1038.816 571.1456 1039.298 589.7465 1039.780 606.0470 1040.262 618.8342 1040.744 628.2195 1041.226 634.7743 1041.708 639.0585 1042.191 639.7578 1042.673 636.9092 1043.155 630.0855 1043.637 619.3851 1044.119 604.0492 1044.601 581.2593 1045.083 550.9147 1045.565 520.8353 1046.047 495.2594 1046.530 468.0691 1047.012 436.4576 1047.494 402.7925 1047.976 373.8066 1048.458 348.8031 1048.940 325.4928 1049.422 303.4740 1049.904 281.5555 1050.386 257.4628 1050.869 233.5801 1051.351 211.8765 1051.833 191.8805 1052.315 177.6650 1052.797 170.4266 1053.279 163.3293 1053.761 151.1929 1054.243 137.1614 1054.726 126.8612 1055.208 119.0793 1055.690 110.6208 1056.172 97.50940 1056.654 87.86420 1057.136 84.29736 1057.618 82.10535 1058.100 74.44464 1058.583 62.69537 1059.065 57.13556 1059.547 58.42322 1060.029 59.24213 1060.511 53.59875 1060.993 46.60052 1061.475 40.44025 1061.957 35.55066 1062.439 34.03162 1062.922 36.89081 1063.404 37.60114 1063.886 34.00116 1064.368 28.56927 1064.850 22.33978 1065.332 17.08105 1065.814 16.03668 1066.296 21.38556 1066.778 23.00964 1067.261 17.33508 1067.743 12.17169 1068.225 12.23236 1068.707 15.44995 1069.189 14.36481 1069.671 10.29114 1070.153 8.021790 1070.635 11.88513 1071.118 14.99658 1071.600 13.94812 1072.082 11.18695 1072.564 8.768555 1073.046 6.626160 1073.528 6.652954 1074.010 9.006104 1074.492 10.52368 1074.974 6.707275 1075.457 2.716675 1075.939 4.071472 1076.421 9.418640 1076.903 12.46576 1077.385 11.68332 1077.867 12.16138 1078.349 15.56030 1078.831 18.18509 1079.313 13.04300 1079.796 4.436096 1080.278 0.2687680 1080.760 1.748260 1081.242 4.132568 1081.724 7.774292 1082.206 9.654022 1082.688 8.026001 1083.170 4.226837 1083.652 2.850586 1084.135 3.351288 1084.617 2.892395 1085.099 9.6984997E-02 1085.581 2.534851 1086.063 1.838165 1086.545 0.1707460 1087.027 0.4755250 1087.509 1.8310999E-02 1087.992 0.9555660 1088.474 2.513153 1088.956 3.476318 1089.438 1.860626 1089.920 0.3900450 1090.402 4.152069 1090.884 9.868866 1091.366 10.21005 1091.849 0.5742190 1092.331 7.120789 1092.813 7.886810 1093.295 6.503723 1093.777 6.522614 1094.259 7.052094 1094.741 5.964508 1095.223 3.407288 1095.705 1.171326 1096.188 0.9705810 1096.670 0.8781130 1097.152 2.910095 1097.634 7.549866 1098.116 7.459778 1098.598 3.641907 1099.080 1.518250 1099.562 2.227356 1100.044 3.647430 1100.527 3.637024 1101.009 4.143402 1101.491 7.473297 1101.973 12.77695 1102.455 13.93420 1102.937 10.87460 1103.419 8.374756 1103.901 7.617645 1104.384 8.417999 1104.866 11.89230 1105.348 16.31036 1105.830 19.20627 1106.312 19.24652 1106.794 22.43085 1107.276 29.89398 1107.758 36.05804 1108.240 37.10318 1108.723 35.43723 1109.205 34.81900 1109.687 35.09543 1110.169 35.03076 1110.651 32.65942 1111.133 32.64392 1111.615 36.30347 1112.097 40.90131 1112.579 44.01703 1113.062 45.85410 1113.544 46.12451 1114.026 45.42023 1114.508 47.39264 1114.990 60.28992 1115.472 68.29922 1115.954 61.56772 1116.436 49.93341 1116.919 48.98438 1117.401 57.89728 1117.883 63.79007 1118.365 65.15030 1118.847 66.25906 1119.329 71.71014 1119.811 76.79880 1120.293 76.96848 1120.776 73.77316 1121.258 74.21460 1121.740 78.92892 1122.222 81.33029 1122.704 79.44250 1123.186 76.53748 1123.668 75.41010 1124.150 75.45349 1124.632 76.04190 1125.115 77.12860 1125.597 78.70642 1126.079 80.86868 1126.561 83.32602 1127.043 86.08554 1127.525 88.94931 1128.007 92.07211 1128.489 94.95398 1128.971 96.64529 1129.454 96.64130 1129.936 96.05258 1130.418 94.17276 1130.900 93.40057 1131.382 96.24481 1131.864 100.7248 1132.346 100.3103 1132.828 96.41412 1133.311 93.52057 1133.793 94.99896 1134.275 95.45020 1134.757 92.48050 1135.239 89.40076 1135.721 89.72049 1136.203 92.83386 1136.685 93.07889 1137.167 90.73807 1137.650 89.20163 1138.132 92.99734 1138.614 95.14249 1139.096 91.56064 1139.578 84.79959 1140.060 77.24561 1140.542 68.78619 1141.024 64.98953 1141.506 66.36673 1141.989 68.03006 1142.471 67.68332 1142.953 65.00281 1143.435 57.67361 1143.917 47.91116 1144.399 42.64618 1144.881 42.56543 1145.363 41.56943 1145.846 38.40399 1146.328 35.62857 1146.810 38.85672 1147.292 41.82068 1147.774 36.02322 1148.256 21.22797 1148.738 14.44955 1149.220 18.64792 1149.703 21.79755 1150.185 19.71161 1150.667 15.52876 1151.149 12.81947 1151.631 10.87326 1152.113 8.765244 1152.595 6.358292 1153.077 3.327499 1153.559 1.425232 1154.042 3.930084 1154.524 1.722763 1155.006 2.599213 1155.488 4.971756 1155.970 5.506943 1156.452 3.995270 1156.934 0.9902340 1157.416 3.704041 1157.898 3.126373 1158.381 1.082932 1158.863 2.419891 1159.345 6.083954 1159.827 5.326187 1160.309 1.613678 1160.791 0.9516600 1161.273 0.2326200 1161.755 0.6635440 1162.238 0.9593810 1162.720 3.022354 1163.202 4.716690 1163.684 5.889374 1164.166 5.557434 1164.648 3.906189 1165.130 1.786896 1165.612 2.615280 1166.094 4.392700 1166.577 1.452927 1167.059 7.210403 1167.541 3.240036 1168.023 8.805344 1168.505 12.66370 1168.987 8.736603 1169.469 4.836761 1169.951 6.011230 1170.433 7.656860 1170.916 7.384003 1171.398 6.581192 1171.880 7.375916 1172.362 9.638428 1172.844 10.33817 1173.326 9.299118 1173.808 8.429413 1174.290 8.366364 1174.773 9.549057 1175.255 14.35046 1175.737 19.78889 1176.219 18.60889 1176.701 10.73839 1177.183 9.624619 1177.665 17.41580 1178.147 23.89685 1178.630 17.30147 1179.112 9.917511 1179.594 12.23131 1180.076 20.86989 1180.558 24.10840 1181.040 21.66525 1181.522 19.46201 1182.004 18.51700 1182.486 18.72743 1182.969 22.37097 1183.451 25.18413 1183.933 21.59734 1184.415 13.16670 1184.897 11.84047 1185.379 18.37048 1185.861 23.57513 1186.343 25.05226 1186.825 24.60722 1187.308 22.68938 1187.790 20.63521 1188.272 19.84703 1188.754 20.36885 1189.236 21.10457 1189.718 22.11873 1190.200 22.76759 1190.682 22.60767 1191.165 22.65854 1191.647 24.91098 1192.129 27.36476 1192.611 27.73923 1193.093 25.74190 1193.575 22.80492 1194.057 18.54723 1194.539 16.07811 1195.021 16.75385 1195.504 19.38672 1195.986 23.94205 1196.468 28.97060 1196.950 32.71373 1197.432 35.11070 1197.914 35.23918 1198.396 32.72565 1198.878 30.46124 1199.360 29.98758 1199.843 30.19910 1200.325 29.71606 1200.807 29.13936 1201.289 29.59299 1201.771 31.78595 1202.253 31.79507 1202.735 29.16582 1203.217 27.34676 1203.700 28.88437 1204.182 31.49586 1204.664 32.99232 1205.146 33.60118 1205.628 33.56932 1206.110 32.56866 1206.592 32.19667 1207.074 32.48997 1207.557 33.39807 1208.039 35.94742 1208.521 38.07768 1209.003 36.95546 1209.485 33.91960 1209.967 31.24706 1210.449 28.25104 1210.931 28.56454 1211.413 32.57092 1211.896 36.44334 1212.378 37.74719 1212.860 37.95792 1213.342 37.58470 1213.824 37.20351 1214.306 38.41049 1214.788 42.64786 1215.270 42.49425 1215.752 37.50047 1216.235 32.56664 1216.717 31.00366 1217.199 31.40599 1217.681 33.74356 1218.163 36.52229 1218.645 36.36412 1219.127 32.48503 1219.609 29.32587 1220.092 26.84549 1220.574 25.80191 1221.056 27.86346 1221.538 30.77016 1222.020 33.53302 1222.502 35.36098 1222.984 34.28050 1223.466 29.24966 1223.948 27.16803 1224.431 28.37067 1224.913 29.22914 1225.395 27.06148 1225.877 24.61922 1226.359 23.62704 1226.841 23.45644 1227.323 22.50084 1227.805 20.57745 1228.287 20.18837 1228.770 21.53188 1229.252 23.09476 1229.734 24.20067 1230.216 24.64378 1230.698 22.60721 1231.180 20.24765 1231.662 23.16995 1232.144 32.09721 1232.627 36.07454 1233.109 34.14310 1233.591 31.28499 1234.073 31.50877 1234.555 31.55255 1235.037 28.33324 1235.519 24.14047 1236.001 23.07622 1236.484 25.02058 1236.966 28.11014 1237.448 32.28503 1237.930 34.38139 1238.412 29.73877 1238.894 24.82660 1239.376 23.95103 1239.858 24.89131 1240.340 23.99089 1240.823 21.49940 1241.305 19.80875 1241.787 19.13542 1242.269 18.56024 1242.751 17.37527 1243.233 16.90091 1243.715 17.98021 1244.197 19.64684 1244.679 20.64183 1245.162 20.96312 1245.644 20.51648 1246.126 19.31323 1246.608 17.82434 1247.090 14.64613 1247.572 13.53336 1248.054 16.61111 1248.536 20.73775 1249.019 20.79860 1249.501 18.15808 1249.983 16.28293 1250.465 15.52856 1250.947 16.66330 1251.429 22.27199 1251.911 26.84541 1252.393 29.60913 1252.875 30.27211 1253.358 27.13863 1253.840 21.96997 1254.322 18.72151 1254.804 17.44838 1255.286 15.92790 1255.768 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