#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 15:35:46 +0300 (Thu, 24 May 2018) $ #$Revision: 756 $ #$URL: svn://172.16.1.111/rod/cif/1/00/02/1000260.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000260 loop_ _publ_author_name 'Rastsvetaeva, R. K.' 'Tamazyan, R. A.' 'Pushcharovskii D Yu' 'Nadezhina, T. N.' 'Voloshin, A. V.' _publ_section_title ; K-nenadkevichite, a new representative of the nenadkevichite-labuntsovite series ; _journal_name_full 'Crystallography Reports' _journal_page_first 908 _journal_page_last 914 _journal_volume 39 _journal_year 1994 _chemical_compound_source 'Vuoriyarvi, Kola Peninsula' _chemical_formula_sum 'H10.3 K2.98 Na1.22 Nb2.2 O31.15 Si8 Ti1.8' _chemical_name_mineral Vuoriyarvite _space_group_IT_number 8 _symmetry_space_group_name_Hall 'C -2y' _symmetry_space_group_name_H-M 'C 1 m 1' _cell_angle_alpha 90 _cell_angle_beta 117.87 _cell_angle_gamma 90 _cell_length_a 14.692 _cell_length_b 14.164 _cell_length_c 7.859 _cell_volume 1445.745 _exptl_crystal_density_diffrn 2.684 _cod_original_formula_sum 'Si8 (Nb2.2 Ti1.8) K2.98 Na1.22 O31.15 H10.3' _cod_database_code 9014345 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R070610.rod _rod_data_source.block 3500000 _rod_database.code 1000260 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9014345 COD http://www.crystallography.net/cod/9014345.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 149.7655 0.0000000E+00 150.2476 12.16211 150.7297 1.207031 151.2118 95.22852 151.6939 258.6738 152.1760 513.6133 152.6582 763.8594 153.1403 983.4551 153.6224 1175.479 154.1045 1387.363 154.5866 1625.219 155.0687 1886.641 155.5508 2169.965 156.0330 2497.467 156.5151 2815.740 156.9972 3107.154 157.4793 3370.445 157.9614 3634.146 158.4435 3910.703 158.9257 4205.311 159.4078 4519.197 159.8899 4872.148 160.3720 5213.074 160.8541 5523.912 161.3362 5803.238 161.8184 6055.533 162.3005 6281.211 162.7826 6481.984 163.2647 6660.475 163.7468 6829.729 164.2289 6971.543 164.7111 7072.971 165.1932 7134.807 165.6753 7154.342 166.1574 7171.801 166.6395 7209.143 167.1216 7214.699 167.6038 7173.605 168.0859 7084.586 168.5680 6951.051 169.0501 6765.012 169.5322 6538.088 170.0143 6256.121 170.4965 5920.545 170.9786 5582.215 171.4607 5261.207 171.9428 4947.617 172.4249 4629.094 172.9070 4290.219 173.3892 3949.814 173.8713 3632.357 174.3534 3340.613 174.8355 3055.344 175.3176 2750.252 175.7997 2436.328 176.2819 2147.049 176.7640 1903.764 177.2461 1691.160 177.7282 1494.111 178.2103 1312.238 178.6924 1134.732 179.1745 935.1621 179.6567 720.7832 180.1388 530.9199 180.6209 401.7227 181.1030 312.9375 181.5851 198.8105 182.0672 43.90625 182.5494 114.8848 183.0315 215.6699 183.5136 262.3457 183.9957 289.6816 184.4778 321.0781 184.9599 353.6621 185.4421 375.0762 185.9242 382.8867 186.4063 379.2480 186.8884 367.2480 187.3705 346.6641 187.8526 321.5703 188.3348 299.3730 188.8169 278.3945 189.2990 242.7402 189.7811 190.8652 190.2632 121.2734 190.7453 27.80469 191.2275 89.63477 191.7096 229.8574 192.1917 394.6680 192.6738 586.1777 193.1559 788.3047 193.6380 997.9922 194.1202 1214.639 194.6023 1439.408 195.0844 1669.266 195.5665 1911.553 196.0486 2173.287 196.5307 2453.490 197.0129 2760.424 197.4950 3106.566 197.9771 3492.912 198.4592 3864.662 198.9413 4213.834 199.4234 4561.000 199.9055 4941.518 200.3877 5357.617 200.8698 5797.809 201.3519 6260.762 201.8340 6752.721 202.3161 7224.682 202.7982 7667.525 203.2804 8094.969 203.7625 8548.121 204.2446 9039.932 204.7267 9516.988 205.2088 9938.576 205.6909 10285.03 206.1731 10663.17 206.6552 11097.31 207.1373 11566.04 207.6194 11974.88 208.1015 12310.10 208.5836 12633.67 209.0658 12996.29 209.5479 13414.13 210.0300 13799.15 210.5121 14135.75 210.9942 14426.91 211.4763 14718.79 211.9585 15028.65 212.4406 15312.47 212.9227 15524.13 213.4048 15646.47 213.8869 15750.09 214.3690 15852.28 214.8512 15951.93 215.3333 16019.05 215.8154 16070.19 216.2975 16067.50 216.7796 15961.73 217.2617 15716.54 217.7439 15445.13 218.2260 15164.70 218.7081 14877.19 219.1902 14590.29 219.6723 14306.12 220.1544 14020.90 220.6366 13720.17 221.1187 13393.44 221.6008 13075.76 222.0829 12772.45 222.5650 12472.71 223.0471 12227.75 223.5293 12049.07 224.0114 11915.90 224.4935 11787.46 224.9756 11656.37 225.4577 11544.81 225.9398 11461.04 226.4220 11400.38 226.9041 11380.39 227.3862 11402.77 227.8683 11465.83 228.3504 11567.76 228.8325 11717.07 229.3147 11892.34 229.7968 12077.74 230.2789 12251.61 230.7610 12488.06 231.2431 12807.48 231.7252 13187.58 232.2074 13564.85 232.6895 13946.42 233.1716 14320.05 233.6537 14676.19 234.1358 14984.82 234.6179 15334.26 235.1001 15748.69 235.5822 16209.42 236.0643 16641.91 236.5464 17025.09 237.0285 17407.42 237.5106 17822.44 237.9928 18289.58 238.4749 18737.73 238.9570 19150.35 239.4391 19534.45 239.9212 19936.85 240.4033 20377.76 240.8855 20803.78 241.3676 21185.80 241.8497 21534.74 242.3318 21810.88 242.8139 21990.98 243.2960 22084.14 243.7782 22194.49 244.2603 22364.13 244.7424 22505.31 245.2245 22546.59 245.7066 22455.04 246.1887 22327.50 246.6708 22174.86 247.1530 21997.64 247.6351 21790.04 248.1172 21549.02 248.5993 21282.78 249.0814 20995.36 249.5635 20694.53 250.0457 20356.22 250.5278 19971.44 251.0099 19539.82 251.4920 19081.90 251.9741 18603.25 252.4562 18098.93 252.9384 17558.99 253.4205 16952.91 253.9026 16372.07 254.3847 15848.49 254.8668 15381.44 255.3489 14877.71 255.8311 14316.34 256.3132 13735.26 256.7953 13188.44 257.2774 12692.98 257.7595 12178.48 258.2416 11633.85 258.7238 11048.89 259.2059 10475.39 259.6880 9896.713 260.1701 9341.833 260.6522 8840.433 261.1343 8414.170 261.6165 7998.938 262.0986 7573.584 262.5807 7129.638 263.0628 6748.262 263.5449 6432.053 264.0270 6175.866 264.5092 5972.957 264.9913 5840.437 265.4734 5702.949 265.9555 5531.904 266.4376 5328.489 266.9197 5159.754 267.4019 5027.544 267.8840 4927.586 268.3661 4859.302 268.8482 4824.451 269.3303 4814.098 269.8124 4833.237 270.2946 4884.733 270.7767 4918.973 271.2588 4925.374 271.7409 4927.244 272.2230 4960.373 272.7051 5029.055 273.1873 5115.104 273.6694 5215.381 274.1515 5329.260 274.6336 5436.143 275.1157 5535.818 275.5978 5630.668 276.0800 5723.115 276.5621 5813.909 277.0442 5905.129 277.5263 5993.218 278.0084 6078.707 278.4905 6183.501 278.9726 6309.482 279.4547 6445.836 279.9369 6593.754 280.4190 6757.779 280.9011 6879.221 281.3832 6911.863 281.8653 6864.279 282.3474 6859.034 282.8296 6909.980 283.3117 6964.900 283.7938 6939.926 284.2759 6836.584 284.7580 6731.881 285.2401 6669.098 285.7223 6637.561 286.2044 6569.971 286.6865 6462.067 287.1686 6335.417 287.6507 6223.328 288.1328 6123.264 288.6150 6015.488 289.0971 5889.207 289.5792 5748.227 290.0613 5601.184 290.5434 5446.177 291.0255 5294.699 291.5077 5161.254 291.9898 5043.130 292.4719 4930.105 292.9540 4821.112 293.4361 4711.373 293.9182 4591.067 294.4004 4457.558 294.8825 4317.811 295.3646 4175.095 295.8467 4030.897 296.3288 3892.739 296.8109 3760.544 297.2931 3638.384 297.7752 3541.467 298.2573 3473.183 298.7394 3411.683 299.2215 3337.479 299.7036 3253.590 300.1858 3171.406 300.6679 3093.896 301.1500 3021.214 301.6321 2951.378 302.1142 2884.979 302.5963 2821.839 303.0785 2767.203 303.5606 2714.995 304.0427 2655.210 304.5248 2587.362 305.0069 2507.103 305.4890 2406.654 305.9712 2282.525 306.4533 2159.712 306.9354 2055.652 307.4175 1962.161 307.8996 1869.230 308.3817 1777.157 308.8639 1680.567 309.3460 1571.748 309.8281 1449.816 310.3102 1337.000 310.7923 1264.704 311.2744 1203.972 311.7566 1118.469 312.2387 952.5752 312.7208 792.6992 313.2029 694.4004 313.6850 660.1953 314.1671 627.2598 314.6493 575.4326 315.1314 508.6680 315.6135 432.2998 316.0956 319.1328 316.5777 222.8457 317.0598 175.9414 317.5420 178.2324 318.0241 164.6016 318.5062 95.20801 318.9883 12.27734 319.4704 48.75879 319.9525 54.69043 320.4347 64.36328 320.9168 100.7920 321.3989 162.0684 321.8810 200.6641 322.3631 186.3193 322.8452 159.6357 323.3273 149.5137 323.8094 178.7100 324.2916 202.4814 324.7737 214.7480 325.2558 216.1250 325.7379 215.3652 326.2200 210.8623 326.7021 205.4873 327.1843 201.2764 327.6664 203.2949 328.1485 199.5342 328.6306 184.5811 329.1127 161.4814 329.5948 149.6738 330.0770 159.8740 330.5591 169.8340 331.0412 165.4561 331.5233 138.2715 332.0054 114.8975 332.4875 95.44824 332.9697 80.71387 333.4518 75.07910 333.9339 82.82520 334.4160 92.13037 334.8981 98.99414 335.3802 107.0020 335.8624 98.57373 336.3445 67.51025 336.8266 23.82422 337.3087 8.994629 337.7908 29.43750 338.2729 43.84766 338.7551 51.95801 339.2372 53.06299 339.7193 65.41309 340.2014 94.57861 340.6835 127.1914 341.1656 132.0615 341.6478 106.7026 342.1299 93.65479 342.6120 123.5693 343.0941 188.8687 343.5762 234.0522 344.0583 255.4077 344.5405 267.1206 345.0226 296.6304 345.5047 339.2856 345.9868 358.7207 346.4689 315.9204 346.9510 239.8892 347.4332 204.3145 347.9153 212.1401 348.3974 239.5962 348.8795 266.1709 349.3616 293.2959 349.8438 325.2261 350.3259 365.3389 350.8080 410.2603 351.2901 458.2637 351.7722 509.2075 352.2543 556.6699 352.7365 591.9775 353.2186 620.3657 353.7007 650.1914 354.1828 685.2485 354.6649 722.5000 355.1470 760.2188 355.6292 798.4790 356.1113 838.1597 356.5934 879.1187 357.0755 923.5845 357.5576 973.2207 358.0397 1021.943 358.5219 1077.237 359.0040 1149.687 359.4861 1235.353 359.9682 1313.832 360.4503 1377.304 360.9324 1431.331 361.4146 1478.080 361.8967 1505.679 362.3788 1543.434 362.8609 1606.754 363.3430 1685.211 363.8251 1750.796 364.3073 1777.903 364.7894 1809.306 365.2715 1865.508 365.7536 1972.967 366.2357 2058.926 366.7178 2109.716 367.2000 2137.706 367.6820 2165.765 368.1642 2194.188 368.6463 2222.526 369.1284 2250.933 369.6105 2279.637 370.0926 2307.200 370.5747 2337.193 371.0569 2363.054 371.5390 2375.146 372.0211 2365.984 372.5032 2360.620 372.9853 2371.292 373.4674 2398.365 373.9496 2396.216 374.4317 2358.313 374.9138 2304.225 375.3959 2250.369 375.8780 2194.910 376.3601 2150.263 376.8423 2122.864 377.3244 2104.101 377.8065 2067.083 378.2886 2008.588 378.7707 1948.247 379.2528 1907.767 379.7350 1884.096 380.2171 1848.667 380.6992 1791.801 381.1813 1726.310 381.6634 1671.232 382.1455 1627.032 382.6277 1591.658 383.1098 1573.296 383.5919 1562.360 384.0740 1537.151 384.5561 1489.550 385.0382 1442.409 385.5204 1423.603 386.0025 1426.021 386.4846 1429.022 386.9667 1416.655 387.4488 1402.200 387.9309 1399.991 388.4131 1413.891 388.8952 1426.435 389.3773 1431.910 389.8594 1428.850 390.3415 1415.385 390.8236 1370.909 391.3058 1331.146 391.7879 1318.195 392.2700 1334.016 392.7521 1344.323 393.2342 1339.486 393.7163 1324.435 394.1985 1303.855 394.6806 1268.199 395.1627 1238.971 395.6448 1228.008 396.1269 1232.109 396.6090 1215.953 397.0912 1155.709 397.5733 1089.721 398.0554 1038.603 398.5375 1010.850 399.0196 984.3643 399.5017 962.2207 399.9839 939.8271 400.4660 901.3154 400.9481 834.4229 401.4302 772.6655 401.9123 733.6807 402.3944 726.1660 402.8766 707.5352 403.3587 677.6982 403.8408 637.5776 404.3229 583.3428 404.8050 510.8799 405.2871 448.2417 405.7693 410.7451 406.2514 395.7651 406.7335 375.9443 407.2156 351.8735 407.6977 320.4614 408.1798 273.6846 408.6620 214.4175 409.1441 159.2212 409.6262 104.8379 410.1083 62.93311 410.5904 70.76660 411.0725 124.3345 411.5547 164.9370 412.0368 134.0112 412.5189 62.86426 413.0010 7.224121 413.4831 12.01514 413.9652 28.28467 414.4473 86.53076 414.9294 168.9360 415.4116 224.2856 415.8937 200.4570 416.3758 154.4854 416.8579 129.2134 417.3400 135.0762 417.8221 147.7656 418.3043 163.4111 418.7864 177.9512 419.2685 185.3276 419.7506 186.7793 420.2327 178.1880 420.7148 153.0474 421.1970 107.7549 421.6791 73.31299 422.1612 60.37451 422.6433 56.14355 423.1254 50.26758 423.6075 53.36377 424.0897 39.93750 424.5718 0.3398440 425.0539 60.75146 425.5360 110.9028 426.0181 142.5322 426.5002 173.8765 426.9824 217.7666 427.4645 279.8027 427.9466 331.1479 428.4287 365.9854 428.9108 393.5244 429.3929 434.5103 429.8751 490.2881 430.3572 549.0449 430.8393 605.7891 431.3214 660.7432 431.8035 712.9727 432.2856 762.7319 432.7678 811.1074 433.2499 856.2236 433.7320 900.1992 434.2141 952.8730 434.6962 1025.954 435.1783 1103.860 435.6605 1159.271 436.1426 1193.902 436.6247 1228.441 437.1068 1281.038 437.5889 1341.430 438.0710 1396.224 438.5532 1438.466 439.0353 1478.987 439.5174 1519.201 439.9995 1562.292 440.4816 1617.301 440.9637 1705.761 441.4459 1793.374 441.9280 1854.811 442.4101 1870.967 442.8922 1911.620 443.3743 2013.361 443.8564 2142.502 444.3386 2252.558 444.8207 2326.910 445.3028 2395.251 445.7849 2460.545 446.2670 2522.147 446.7491 2591.776 447.2313 2673.301 447.7134 2759.653 448.1955 2843.720 448.6776 2922.431 449.1597 3010.000 449.6418 3110.517 450.1240 3219.333 450.6061 3317.900 451.0882 3403.676 451.5703 3490.216 452.0524 3592.782 452.5345 3708.269 453.0167 3792.373 453.4988 3840.721 453.9809 3863.398 454.4630 3868.887 454.9451 3858.267 455.4272 3836.766 455.9094 3802.585 456.3915 3760.530 456.8736 3720.829 457.3557 3683.117 457.8378 3632.370 458.3199 3558.767 458.8020 3466.444 459.2841 3357.267 459.7663 3217.614 460.2484 3083.265 460.7305 2979.816 461.2126 2900.210 461.6947 2822.269 462.1768 2727.820 462.6590 2641.819 463.1411 2579.691 463.6232 2555.997 464.1053 2519.836 464.5874 2444.168 465.0695 2358.148 465.5517 2299.472 466.0338 2270.966 466.5159 2267.428 466.9980 2299.223 467.4801 2364.169 467.9622 2395.380 468.4444 2366.121 468.9265 2346.449 469.4086 2397.910 469.8907 2539.800 470.3728 2647.156 470.8549 2699.647 471.3371 2721.989 471.8192 2765.006 472.3013 2827.307 472.7834 2897.623 473.2655 2971.561 473.7477 3054.184 474.2298 3154.211 474.7119 3271.267 475.1940 3391.651 475.6761 3500.936 476.1582 3603.651 476.6404 3710.132 477.1225 3829.557 477.6046 3950.742 478.0867 4062.975 478.5688 4168.272 479.0509 4271.622 479.5331 4354.664 480.0152 4447.348 480.4973 4578.288 480.9794 4776.785 481.4615 4961.700 481.9436 5105.810 482.4258 5223.065 482.9079 5337.481 483.3900 5464.079 483.8721 5576.675 484.3542 5663.717 484.8363 5720.797 485.3185 5793.654 485.8006 5902.138 486.2827 6004.496 486.7648 6063.883 487.2469 6063.808 487.7290 6079.331 488.2112 6125.965 488.6933 6188.907 489.1754 6229.215 489.6575 6246.967 490.1396 6246.073 490.6217 6232.764 491.1039 6203.750 491.5860 6140.825 492.0681 6040.248 492.5502 5922.333 493.0323 5796.288 493.5144 5668.615 493.9966 5554.434 494.4787 5466.368 494.9608 5388.238 495.4429 5307.507 495.9250 5224.147 496.4071 5142.605 496.8893 5066.973 497.3714 4991.679 497.8535 4912.491 498.3356 4823.564 498.8177 4738.589 499.2998 4669.568 499.7820 4604.177 500.2641 4522.258 500.7462 4381.352 501.2283 4264.222 501.7104 4199.969 502.1925 4192.159 502.6746 4157.775 503.1567 4083.967 503.6389 4000.300 504.1210 3930.202 504.6031 3877.236 505.0852 3818.903 505.5673 3751.315 506.0494 3679.048 506.5316 3610.409 507.0137 3545.933 507.4958 3481.542 507.9779 3419.822 508.4600 3357.009 508.9421 3279.897 509.4243 3187.252 509.9064 3090.030 510.3885 2996.520 510.8706 2904.388 511.3527 2809.146 511.8348 2702.234 512.3170 2601.591 512.7991 2528.084 513.2812 2473.024 513.7633 2409.064 514.2454 2316.148 514.7275 2215.831 515.2097 2119.875 515.6918 2030.676 516.1739 1945.077 516.6560 1862.694 517.1381 1782.152 517.6202 1702.456 518.1024 1615.212 518.5845 1544.740 519.0666 1506.364 519.5487 1490.121 520.0308 1427.859 520.5129 1297.727 520.9951 1177.029 521.4772 1123.312 521.9593 1138.178 522.4414 1114.296 522.9235 1039.627 523.4056 945.3535 523.8878 873.1982 524.3699 820.8125 524.8520 768.7344 525.3341 702.3730 525.8162 636.6069 526.2983 593.9014 526.7805 572.8789 527.2626 559.1357 527.7447 551.0713 528.2268 540.7886 528.7089 520.6406 529.1910 486.5366 529.6732 450.3237 530.1553 409.4961 530.6374 369.4541 531.1195 338.1021 531.6016 322.8188 532.0837 310.1919 532.5659 296.8701 533.0480 282.9019 533.5301 276.5874 534.0122 287.7979 534.4943 295.4253 534.9764 280.6284 535.4586 232.9365 535.9407 198.8921 536.4228 187.1182 536.9049 185.5024 537.3870 166.9014 537.8691 132.5747 538.3513 110.1079 538.8334 110.8428 539.3155 128.0806 539.7976 156.9775 540.2797 199.0278 540.7618 234.9448 541.2440 236.7539 541.7261 220.2383 542.2082 203.3911 542.6903 192.2354 543.1724 186.4199 543.6545 204.5068 544.1367 232.3848 544.6188 239.7573 545.1009 193.5869 545.5830 157.3184 546.0651 169.0571 546.5472 232.7207 547.0294 269.3091 547.5115 263.4155 547.9936 245.5459 548.4757 233.8535 548.9578 230.2002 549.4399 229.0483 549.9221 228.2461 550.4042 228.8398 550.8863 234.2759 551.3684 245.8657 551.8505 260.7891 552.3326 277.6538 552.8148 295.8643 553.2969 318.1992 553.7790 345.2227 554.2611 364.8218 554.7432 358.0391 555.2253 339.0786 555.7075 330.4849 556.1896 337.4146 556.6717 357.1235 557.1538 394.9800 557.6359 439.8120 558.1180 476.3369 558.6002 504.6748 559.0823 521.5122 559.5644 523.3545 560.0465 510.9155 560.5286 501.0415 561.0107 487.5674 561.4929 476.5835 561.9750 473.4346 562.4571 482.0815 562.9392 494.0396 563.4213 513.7021 563.9034 534.1079 564.3856 540.8828 564.8677 531.5449 565.3498 526.6880 565.8319 534.6860 566.3140 551.3604 566.7961 564.6924 567.2783 575.0337 567.7604 589.1118 568.2425 625.1685 568.7246 661.9385 569.2067 667.3916 569.6888 631.6201 570.1709 592.1553 570.6530 563.0630 571.1351 549.1406 571.6172 555.0688 572.0994 617.1392 572.5815 660.9980 573.0636 652.7622 573.5457 602.1274 574.0278 576.5337 574.5099 601.4302 574.9921 624.0889 575.4742 619.1294 575.9563 578.7217 576.4384 556.1631 576.9205 558.4106 577.4026 565.0781 577.8848 550.9990 578.3669 516.6870 578.8490 481.6831 579.3311 446.3511 579.8132 418.0054 580.2953 417.8389 580.7775 439.6265 581.2596 453.5293 581.7417 428.6953 582.2238 395.6304 582.7059 390.1460 583.1880 415.6899 583.6702 434.1211 584.1523 419.7417 584.6344 392.7251 585.1165 370.7554 585.5986 367.4868 586.0807 356.5903 586.5629 327.2900 587.0450 289.8184 587.5271 264.3896 588.0092 254.6890 588.4913 250.7319 588.9734 252.7725 589.4556 259.6558 589.9377 255.9131 590.4198 241.0029 590.9019 218.3125 591.3840 179.1523 591.8661 131.8315 592.3483 118.6733 592.8304 152.0186 593.3125 191.1196 593.7946 191.8296 594.2767 164.9976 594.7589 132.6753 595.2410 89.88623 595.7231 56.80859 596.2052 50.99268 596.6873 67.92725 597.1694 82.72461 597.6516 51.44043 598.1337 1.659668 598.6158 54.97510 599.0979 85.12793 599.5800 90.21924 600.0621 3.978516 600.5443 29.27246 601.0264 10.90381 601.5085 9.847656 601.9906 40.49170 602.4727 40.91846 602.9548 7.421875 603.4370 3.254883 603.9191 16.51562 604.4012 33.18115 604.8833 35.00830 605.3654 25.70801 605.8475 7.729004 606.3297 18.46777 606.8118 40.26416 607.2939 42.65234 607.7760 40.17383 608.2581 47.23242 608.7402 72.98779 609.2224 95.18408 609.7045 104.1221 610.1866 106.7305 610.6687 114.8608 611.1508 137.0288 611.6329 151.9912 612.1151 151.9634 612.5972 140.8159 613.0793 146.1616 613.5614 173.9346 614.0435 195.5815 614.5256 186.5581 615.0078 153.2593 615.4899 138.1382 615.9720 143.3687 616.4541 164.2861 616.9362 217.7388 617.4183 280.8252 617.9005 308.0405 618.3826 268.4482 618.8647 220.4980 619.3468 198.0107 619.8289 196.4521 620.3110 207.0029 620.7932 245.4424 621.2753 277.2441 621.7574 285.9395 622.2395 270.9902 622.7216 265.2959 623.2037 274.2002 623.6859 285.2744 624.1680 292.6377 624.6501 297.3525 625.1322 290.0430 625.6143 267.9727 626.0964 240.0176 626.5786 212.1787 627.0607 187.3242 627.5428 180.4111 628.0249 207.2695 628.5070 237.5527 628.9891 234.8408 629.4713 204.7715 629.9534 165.3545 630.4355 111.7158 630.9176 63.50586 631.3997 44.73047 631.8818 58.71387 632.3640 45.37793 632.8461 37.24316 633.3282 128.5820 633.8103 189.8076 634.2924 213.7363 634.7745 221.6094 635.2567 197.7803 635.7388 176.7188 636.2209 220.4648 636.7030 332.3291 637.1851 431.4863 637.6672 495.5928 638.1494 536.8721 638.6315 561.8037 639.1136 577.5137 639.5957 615.3408 640.0778 714.1885 640.5599 832.9629 641.0421 931.0723 641.5242 1005.858 642.0063 1080.181 642.4884 1166.220 642.9705 1254.303 643.4526 1340.308 643.9348 1412.358 644.4169 1497.770 644.8990 1604.500 645.3811 1718.206 645.8632 1814.136 646.3453 1891.781 646.8275 1959.219 647.3096 2010.649 647.7917 2060.264 648.2738 2151.535 648.7559 2280.412 649.2380 2410.467 649.7202 2509.864 650.2023 2601.278 650.6844 2718.591 651.1665 2863.595 651.6486 3009.773 652.1307 3143.202 652.6129 3271.435 653.0950 3401.225 653.5771 3535.544 654.0592 3670.945 654.5413 3808.664 655.0234 3945.260 655.5056 4069.560 655.9877 4166.669 656.4698 4291.425 656.9519 4460.354 657.4340 4657.162 657.9161 4833.424 658.3983 4997.252 658.8804 5150.347 659.3624 5290.727 659.8445 5430.029 660.3267 5574.600 660.8088 5732.629 661.2909 5893.184 661.7730 6040.226 662.2551 6195.101 662.7372 6380.328 663.2194 6609.301 663.7015 6842.594 664.1836 7079.342 664.6657 7310.933 665.1478 7528.557 665.6299 7728.346 666.1121 7919.214 666.5942 8093.766 667.0763 8264.775 667.5584 8480.465 668.0405 8744.055 668.5226 9003.738 669.0048 9232.624 669.4869 9443.987 669.9690 9649.699 670.4511 9854.951 670.9332 10084.07 671.4153 10371.51 671.8975 10679.39 672.3796 10979.76 672.8617 11271.35 673.3438 11555.57 673.8259 11818.45 674.3080 12080.65 674.7902 12356.22 675.2723 12646.63 675.7544 12953.20 676.2365 13281.16 676.7186 13625.45 677.2007 13963.52 677.6829 14295.64 678.1650 14636.98 678.6471 14990.85 679.1292 15357.04 679.6113 15731.30 680.0934 16115.88 680.5756 16492.19 681.0577 16843.11 681.5398 17187.67 682.0219 17550.87 682.5040 17933.12 682.9861 18333.96 683.4683 18767.15 683.9504 19214.01 684.4325 19668.17 684.9146 20134.07 685.3967 20590.66 685.8788 21039.58 686.3610 21485.10 686.8431 21931.98 687.3252 22384.21 687.8073 22850.89 688.2894 23330.56 688.7715 23831.54 689.2537 24367.23 689.7358 24926.60 690.2179 25461.75 690.7000 25939.93 691.1821 26397.38 691.6642 26858.97 692.1464 27326.03 692.6285 27804.13 693.1106 28307.53 693.5927 28806.78 694.0748 29284.61 694.5569 29742.54 695.0391 30178.35 695.5212 30600.71 696.0033 30989.22 696.4854 31312.90 696.9675 31572.95 697.4496 31848.92 697.9318 32153.64 698.4139 32468.02 698.8960 32790.07 699.3781 33101.97 699.8602 33361.31 700.3423 33542.25 700.8245 33677.75 701.3066 33788.34 701.7887 33870.89 702.2708 33918.05 702.7529 33901.03 703.2350 33876.05 703.7172 33877.66 704.1993 33898.80 704.6814 33831.11 705.1635 33651.59 705.6456 33446.38 706.1277 33276.69 706.6099 33134.23 707.0920 32914.89 707.5741 32613.06 708.0562 32290.13 708.5383 32019.17 709.0204 31763.81 709.5026 31472.40 709.9847 31133.52 710.4668 30768.48 710.9489 30377.62 711.4310 29971.18 711.9131 29555.18 712.3953 29127.72 712.8774 28700.45 713.3595 28281.85 713.8416 27857.22 714.3237 27392.62 714.8058 26875.99 715.2880 26368.70 715.7701 25894.54 716.2522 25437.05 716.7343 24942.44 717.2164 24417.62 717.6985 23892.20 718.1807 23383.88 718.6628 22890.41 719.1449 22419.58 719.6270 21966.06 720.1091 21525.31 720.5912 21121.16 721.0734 20704.69 721.5555 20241.84 722.0376 19708.22 722.5197 19201.66 723.0018 18724.22 723.4839 18277.75 723.9661 17865.93 724.4482 17492.87 724.9303 17115.57 725.4124 16722.87 725.8945 16324.86 726.3766 15932.33 726.8588 15544.59 727.3409 15151.96 727.8230 14755.46 728.3051 14357.97 728.7872 13950.52 729.2693 13542.45 729.7515 13163.65 730.2336 12834.34 730.7157 12513.88 731.1978 12194.32 731.6799 11877.79 732.1620 11552.84 732.6442 11215.75 733.1263 10889.55 733.6084 10595.81 734.0905 10324.58 734.5726 10035.99 735.0547 9728.071 735.5369 9436.267 736.0190 9202.522 736.5011 8986.796 736.9832 8745.885 737.4653 8464.345 737.9474 8186.348 738.4296 7918.251 738.9117 7662.258 739.3938 7422.393 739.8759 7197.590 740.3580 6987.924 740.8401 6796.086 741.3223 6612.414 741.8044 6421.393 742.2865 6223.965 742.7686 6025.465 743.2507 5828.229 743.7328 5636.299 744.2150 5459.345 744.6971 5293.485 745.1792 5131.844 745.6613 4974.902 746.1434 4817.379 746.6255 4650.440 747.1077 4477.515 747.5898 4329.438 748.0719 4226.027 748.5540 4124.846 749.0361 4011.656 749.5182 3886.688 750.0003 3736.120 750.4824 3556.248 750.9645 3389.660 751.4467 3294.580 751.9288 3240.472 752.4109 3136.004 752.8930 2972.867 753.3751 2821.693 753.8572 2752.357 754.3394 2703.993 754.8215 2637.933 755.3036 2541.995 755.7857 2429.458 756.2678 2295.076 756.7499 2160.535 757.2321 2077.549 757.7142 2055.563 758.1963 2016.534 758.6784 1944.066 759.1605 1853.107 759.6426 1767.467 760.1248 1688.134 760.6069 1618.130 761.0890 1574.595 761.5711 1529.752 762.0532 1456.625 762.5353 1366.957 763.0175 1289.263 763.4996 1222.688 763.9817 1174.383 764.4638 1150.306 764.9459 1149.431 765.4280 1156.034 765.9102 1170.882 766.3923 1167.815 766.8744 1126.827 767.3565 1063.479 767.8386 1012.898 768.3207 973.4824 768.8029 956.7666 769.2850 1012.694 769.7671 1071.389 770.2492 1058.231 770.7313 957.8574 771.2134 871.9209 771.6956 824.5820 772.1777 801.6455 772.6598 797.4404 773.1419 821.8047 773.6240 825.5283 774.1061 805.0381 774.5883 775.5586 775.0704 751.3525 775.5525 732.5723 776.0346 718.5947 776.5167 711.7373 776.9988 698.4473 777.4810 655.4053 777.9631 600.9180 778.4452 558.6074 778.9273 540.6025 779.4094 532.1494 779.8915 532.9775 780.3737 540.1289 780.8558 551.6533 781.3379 573.9102 781.8200 574.5703 782.3021 538.2256 782.7842 486.9590 783.2664 478.9092 783.7485 506.6094 784.2306 523.6074 784.7127 504.1650 785.1948 466.9385 785.6769 414.8711 786.1591 355.7793 786.6412 315.1123 787.1233 320.3818 787.6054 326.0527 788.0875 317.3447 788.5696 295.0654 789.0518 259.2070 789.5339 205.1553 790.0160 157.4316 790.4981 131.9443 790.9802 124.4678 791.4623 129.0283 791.9445 144.2656 792.4266 142.2656 792.9087 77.26855 793.3908 2.856445 793.8729 21.24902 794.3550 20.24316 794.8372 35.67578 795.3193 29.05957 795.8014 100.4014 796.2835 132.6924 796.7656 114.2471 797.2477 105.7969 797.7299 109.4541 798.2120 117.6318 798.6941 119.2324 799.1762 118.9883 799.6583 136.1533 800.1404 178.4268 800.6226 215.7197 801.1047 223.0049 801.5868 214.2490 802.0689 205.2148 802.5510 190.3105 803.0331 189.7578 803.5153 217.0088 803.9974 250.6523 804.4795 257.7236 804.9616 232.6035 805.4437 226.7852 805.9258 255.1035 806.4080 292.3936 806.8901 305.6348 807.3722 296.4551 807.8543 268.2686 808.3364 206.6543 808.8185 145.8672 809.3007 237.3965 809.7828 130.3896 810.2649 66.10547 810.7470 42.22949 811.2291 179.4570 811.7112 108.9521 812.1934 121.9111 812.6755 138.4248 813.1576 39.11230 813.6397 153.6621 814.1218 56.48975 814.6039 44.03809 815.0861 6.978027 815.5682 76.94287 816.0503 123.4492 816.5324 102.0112 817.0145 60.68848 817.4966 9.130371 817.9788 47.99121 818.4609 73.21143 818.9430 58.10205 819.4251 27.71973 819.9072 13.60986 820.3893 61.10254 820.8715 85.55225 821.3536 88.15771 821.8357 98.01611 822.3178 157.4517 822.7999 220.1782 823.2820 228.5449 823.7642 181.6841 824.2463 144.6392 824.7284 157.1475 825.2105 169.5269 825.6926 155.0894 826.1747 110.5093 826.6569 76.36768 827.1390 53.26416 827.6211 39.60010 828.1032 40.33252 828.5853 49.46631 829.0674 50.25586 829.5496 41.63525 830.0317 22.62598 830.5138 15.82715 830.9959 59.85742 831.4780 99.96240 831.9601 137.4282 832.4423 159.5308 832.9244 158.6357 833.4065 151.4551 833.8886 148.4648 834.3707 149.6616 834.8528 161.6167 835.3350 187.6318 835.8171 208.6089 836.2992 198.9121 836.7813 173.5293 837.2634 154.8628 837.7455 146.4707 838.2277 148.1113 838.7097 163.7266 839.1918 187.2383 839.6740 213.9653 840.1561 248.7593 840.6382 273.6870 841.1203 284.7812 841.6024 292.9937 842.0845 311.0024 842.5667 337.4180 843.0488 364.2407 843.5309 390.0869 844.0130 416.1997 844.4951 443.0674 844.9772 471.1304 845.4594 500.9883 845.9415 532.5176 846.4236 566.5352 846.9057 603.2866 847.3878 642.5435 847.8699 685.2437 848.3521 732.4580 848.8342 774.8906 849.3163 809.6655 849.7984 844.5654 850.2805 890.3794 850.7626 944.3018 851.2448 999.3398 851.7269 1047.387 852.2090 1107.202 852.6911 1195.316 853.1732 1297.427 853.6553 1390.713 854.1375 1465.958 854.6196 1552.686 855.1017 1657.169 855.5838 1766.863 856.0659 1855.292 856.5480 1927.260 857.0302 2016.283 857.5123 2134.000 857.9944 2262.102 858.4765 2369.146 858.9586 2481.102 859.4407 2640.710 859.9229 2907.492 860.4050 3161.234 860.8871 3399.010 861.3692 3606.359 861.8513 3745.604 862.3334 3807.876 862.8156 3910.630 863.2977 4080.881 863.7798 4295.299 864.2619 4536.726 864.7440 4799.699 865.2261 5074.103 865.7083 5389.718 866.1904 5676.127 866.6725 5875.544 867.1546 6029.736 867.6367 6245.583 868.1188 6546.312 868.6010 6846.438 869.0831 7127.472 869.5652 7400.988 870.0473 7669.498 870.5294 7935.062 871.0115 8218.992 871.4937 8532.741 871.9758 8839.437 872.4579 9087.620 872.9400 9299.901 873.4221 9510.443 873.9042 9730.503 874.3864 9955.951 874.8685 10201.90 875.3506 10442.18 875.8327 10610.51 876.3148 10707.07 876.7969 10808.43 877.2791 10950.32 877.7612 11072.36 878.2433 11093.11 878.7254 11046.48 879.2075 10993.46 879.6896 10959.85 880.1718 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95.33643 987.6837 94.42920 988.1658 91.68066 988.6479 92.77588 989.1301 102.6650 989.6122 105.0190 990.0943 99.18408 990.5764 85.59033 991.0585 56.99902 991.5406 17.89600 992.0228 8.853516 992.5049 29.62305 992.9870 47.59814 993.4691 35.98486 993.9512 16.31250 994.4333 0.6660160 994.9155 9.462402 995.3976 7.543457 995.8797 14.47705 996.3618 28.76074 996.8439 23.89014 997.3260 5.612793 997.8082 17.53760 998.2903 42.68506 998.7724 60.48975 999.2545 53.66943 999.7366 52.64307 1000.219 78.77441 1000.701 116.5791 1001.183 138.3594 1001.665 139.6494 1002.147 144.9468 1002.629 159.5176 1003.111 172.4629 1003.594 160.7012 1004.076 140.4653 1004.558 142.1797 1005.040 178.5977 1005.522 210.4946 1006.004 222.5981 1006.486 228.3062 1006.968 234.8228 1007.451 242.1997 1007.933 248.1421 1008.415 252.5249 1008.897 257.2812 1009.379 263.7524 1009.861 271.3203 1010.343 280.7983 1010.825 291.4946 1011.307 297.5068 1011.790 291.0083 1012.272 291.1069 1012.754 305.4517 1013.236 327.7275 1013.718 342.8574 1014.200 350.9663 1014.682 352.6841 1015.164 344.2070 1015.646 335.4565 1016.129 328.7002 1016.611 327.0425 1017.093 336.4463 1017.575 363.8149 1018.057 381.7236 1018.539 387.5161 1019.021 386.5059 1019.503 381.8022 1019.985 375.5825 1020.468 372.0527 1020.950 371.8921 1021.432 373.1875 1021.914 372.8604 1022.396 376.4214 1022.878 389.4468 1023.360 411.0024 1023.842 418.1411 1024.325 410.6011 1024.807 405.2759 1025.289 415.1758 1025.771 429.5908 1026.253 438.5771 1026.735 442.9253 1027.217 444.7349 1027.699 438.2437 1028.182 439.1514 1028.664 450.1504 1029.146 469.0679 1029.628 497.4541 1030.110 531.2627 1030.592 550.0181 1031.074 544.1885 1031.556 538.7290 1032.038 546.9712 1032.521 564.9487 1033.003 591.3711 1033.485 631.9121 1033.967 655.8623 1034.449 660.8384 1034.931 658.8516 1035.413 651.6255 1035.895 647.5146 1036.377 667.1235 1036.860 707.3135 1037.342 737.1216 1037.824 727.4331 1038.306 725.6592 1038.788 748.8428 1039.270 788.8066 1039.752 818.3589 1040.234 837.4927 1040.717 857.4365 1041.199 890.0273 1041.681 918.4004 1042.163 913.8921 1042.645 897.3848 1043.127 902.8618 1043.609 954.2866 1044.091 987.6855 1044.573 997.7012 1045.056 1001.567 1045.538 1015.748 1046.020 1037.886 1046.502 1064.044 1046.984 1093.205 1047.466 1119.691 1047.948 1138.888 1048.430 1158.164 1048.912 1186.902 1049.395 1221.666 1049.877 1226.578 1050.359 1199.128 1050.841 1174.838 1051.323 1177.796 1051.805 1184.753 1052.287 1164.485 1052.769 1129.806 1053.252 1105.906 1053.734 1102.963 1054.216 1103.777 1054.698 1117.347 1055.180 1120.176 1055.662 1066.688 1056.144 977.9248 1056.626 927.3584 1057.109 925.5469 1057.591 923.8091 1058.073 886.5952 1058.555 848.8979 1059.037 838.2080 1059.519 851.6665 1060.001 833.8145 1060.483 782.8403 1060.965 730.5312 1061.448 690.1538 1061.930 659.2954 1062.412 640.1514 1062.894 627.7227 1063.376 609.7324 1063.858 582.1543 1064.340 549.2012 1064.822 506.6504 1065.304 466.2251 1065.786 448.1094 1066.269 445.1006 1066.751 431.3892 1067.233 401.9253 1067.715 372.7222 1068.197 357.7363 1068.679 341.7524 1069.161 313.2686 1069.643 272.4067 1070.126 236.1040 1070.608 203.3926 1071.090 184.3750 1071.572 198.7026 1072.054 216.9292 1072.536 199.8564 1073.018 161.2891 1073.500 135.2476 1073.983 144.3320 1074.465 140.7490 1074.947 114.9692 1075.429 83.77393 1075.911 72.12988 1076.393 73.03662 1076.875 62.32959 1077.357 33.99170 1077.839 15.82275 1078.322 40.48193 1078.804 62.97070 1079.286 52.02832 1079.768 10.35596 1080.250 8.388184 1080.732 3.993652 1081.214 0.2495120 1081.696 14.16553 1082.178 30.71631 1082.661 36.44678 1083.143 34.12939 1083.625 30.79688 1084.107 35.79639 1084.589 19.91650 1085.071 27.11426 1085.553 77.90527 1086.035 85.24072 1086.518 73.43213 1087.000 108.5449 1087.482 205.3599 1087.964 266.4771 1088.446 200.6230 1088.928 140.1499 1089.410 157.1299 1089.892 235.0713 1090.375 271.5020 1090.857 269.1880 1091.339 261.2295 1091.821 254.3794 1092.303 258.3418 1092.785 289.0024 1093.267 333.0034 1093.749 365.0537 1094.231 381.2510 1094.714 393.3511 1095.196 400.3535 1095.678 410.5229 1096.160 434.4902 1096.642 466.5347 1097.124 498.0029 1097.606 528.1069 1098.088 561.7183 1098.570 603.4849 1099.053 643.4922 1099.535 677.9341 1100.017 708.3735 1100.499 737.6230 1100.981 767.4858 1101.463 806.4639 1101.945 865.3418 1102.427 923.1201 1102.910 974.1494 1103.392 1015.032 1103.874 1036.979 1104.356 1034.589 1104.838 1058.836 1105.320 1112.985 1105.802 1177.736 1106.284 1250.914 1106.766 1317.408 1107.249 1358.344 1107.731 1374.707 1108.213 1399.889 1108.695 1432.675 1109.177 1485.231 1109.659 1569.792 1110.141 1660.539 1110.623 1720.548 1111.105 1752.981 1111.588 1760.847 1112.070 1726.318 1112.552 1717.361 1113.034 1762.670 1113.516 1816.570 1113.998 1851.887 1114.480 1872.078 1114.962 1891.415 1115.445 1902.800 1115.927 1909.494 1116.409 1904.736 1116.891 1906.228 1117.373 1925.570 1117.855 1958.006 1118.337 1999.094 1118.819 2053.156 1119.302 2070.976 1119.784 2036.271 1120.266 1991.489 1120.748 1985.395 1121.230 1993.229 1121.712 1978.979 1122.194 1932.191 1122.676 1907.486 1123.158 1915.573 1123.641 1916.980 1124.123 1887.420 1124.605 1840.552 1125.087 1805.488 1125.569 1777.004 1126.051 1740.456 1126.533 1664.904 1127.015 1613.796 1127.497 1610.366 1127.980 1614.688 1128.462 1569.270 1128.944 1487.489 1129.426 1439.969 1129.908 1434.310 1130.390 1422.632 1130.872 1374.937 1131.354 1311.666 1131.837 1234.625 1132.319 1152.288 1132.801 1109.635 1133.283 1106.503 1133.765 1098.679 1134.247 1067.323 1134.729 1027.797 1135.211 993.9873 1135.693 959.5801 1136.176 914.5669 1136.658 849.8623 1137.140 809.6074 1137.622 797.1367 1138.104 785.1846 1138.586 754.8975 1139.068 713.6655 1139.550 665.4536 1140.032 613.3228 1140.515 573.7144 1140.997 564.6201 1141.479 545.5532 1141.961 504.8340 1142.443 455.7642 1142.925 414.3711 1143.407 381.3833 1143.889 360.3394 1144.372 350.9795 1144.854 337.5332 1145.336 306.5903 1145.818 280.3340 1146.300 273.1118 1146.782 278.5684 1147.264 258.4570 1147.746 218.5127 1148.229 192.3242 1148.711 204.3892 1149.193 225.4404 1149.675 247.9004 1150.157 260.5806 1150.639 249.4824 1151.121 211.8052 1151.603 184.6426 1152.085 169.2505 1152.568 161.5166 1153.050 160.3555 1153.532 163.0752 1154.014 174.2988 1154.496 188.8950 1154.978 178.2925 1155.460 135.0195 1155.942 100.7749 1156.424 85.51465 1156.906 82.39160 1157.389 93.14990 1157.871 105.8550 1158.353 102.1357 1158.835 71.76904 1159.317 59.32031 1159.799 75.42480 1160.281 85.02783 1160.763 60.99951 1161.246 23.71973 1161.728 21.82764 1162.210 42.85303 1162.692 53.94287 1163.174 35.34082 1163.656 16.32324 1164.138 2.601074 1164.620 16.30225 1165.103 16.33838 1165.585 7.004883 1166.067 3.539063 1166.549 6.621582 1167.031 7.945801 1167.513 0.6513670 1167.995 7.110352 1168.477 8.572266 1168.959 4.183594 1169.442 15.19971 1169.924 44.89160 1170.406 51.66992 1170.888 20.82324 1171.370 7.591797 1171.852 20.30029 1172.334 84.28906 1172.816 27.61572 1173.298 13.18945 1173.781 38.41406 1174.263 15.62598 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