#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 15:48:14 +0300 (Thu, 24 May 2018) $ #$Revision: 784 $ #$URL: svn://172.16.1.111/rod/cif/1/00/02/1000281.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000281 loop_ _publ_author_name 'Kampf, A. R.' 'Yang, H.' 'Downs, R. T.' 'Pinch, W. W.' _publ_section_title ; The crystal structures and Raman spectra of aravaipaite and calcioaravaipaite ; _journal_name_full 'American Mineralogist' _journal_page_first 402 _journal_page_last 407 _journal_paper_doi 10.2138/am.2011.3620 _journal_volume 96 _journal_year 2011 _chemical_compound_source 'Grand Reef mine, Aravaipa mining district, Arizona, USA' _chemical_formula_sum 'Al F9 H2 O Pb3' _chemical_name_mineral Aravaipaite _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 98.725 _cell_angle_beta 94.020 _cell_angle_gamma 90.683 _cell_length_a 5.6637 _cell_length_b 5.8659 _cell_length_c 12.7041 _cell_volume 416.045 _exptl_crystal_density_diffrn 6.686 _cod_original_formula_sum 'Pb3 Al F9 O H2' _cod_database_code 9014374 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R100004.rod _rod_data_source.block 3500000 _rod_database.code 1000281 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9014374 COD http://www.crystallography.net/cod/9014374.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 144.9714 0.0000000E+00 145.4535 5.992004 145.9356 5.247528 146.4177 0.9055480 146.8998 2.346954 147.3820 0.1496580 147.8641 3.974060 148.3462 10.43530 148.8283 17.36499 149.3104 23.90442 149.7925 28.68396 150.2747 34.30261 150.7568 41.06842 151.2389 48.76819 151.7210 55.49677 152.2031 60.37201 152.6852 64.54462 153.1674 68.86304 153.6495 72.53314 154.1316 76.99933 154.6137 83.48529 155.0958 92.04449 155.5779 97.94739 156.0601 97.25958 156.5422 95.18878 157.0243 96.12463 157.5064 102.9929 157.9885 110.9220 158.4706 118.6008 158.9528 125.8682 159.4349 133.5602 159.9170 140.7783 160.3991 148.8354 160.8812 159.2542 161.3633 175.5336 161.8455 191.7982 162.3276 205.3340 162.8097 215.1771 163.2918 224.6613 163.7739 234.2105 164.2560 239.8201 164.7382 245.9124 165.2203 249.0376 165.7024 252.5911 166.1845 255.3184 166.6666 257.0564 167.1487 258.1448 167.6309 258.8098 168.1130 259.0399 168.5951 258.7393 169.0772 256.7302 169.5593 254.8107 170.0414 254.7990 170.5236 257.7895 171.0057 260.8473 171.4878 261.5331 171.9699 260.5179 172.4520 259.7635 172.9341 260.6867 173.4163 262.3795 173.8984 263.6479 174.3805 263.7593 174.8626 264.0328 175.3447 266.5089 175.8268 270.6449 176.3090 273.9328 176.7911 274.4857 177.2732 273.0831 177.7553 270.9030 178.2374 268.1281 178.7195 264.8251 179.2017 260.9309 179.6838 256.4728 180.1659 251.8927 180.6480 247.5431 181.1301 243.3214 181.6122 238.9515 182.0944 234.4814 182.5765 229.7386 183.0586 223.9691 183.5407 217.2556 184.0228 210.8752 184.5049 206.4611 184.9871 203.4887 185.4692 200.2639 185.9513 196.8949 186.4334 192.6937 186.9155 184.5552 187.3976 172.0804 187.8798 160.6240 188.3619 156.7180 188.8440 159.3152 189.3261 161.9023 189.8082 162.1980 190.2903 160.8121 190.7725 159.8384 191.2546 159.2692 191.7367 159.1517 192.2188 160.1482 192.7009 162.1581 193.1830 162.8977 193.6652 160.7473 194.1473 156.3264 194.6294 153.8063 195.1115 153.4974 195.5936 154.0317 196.0757 153.5380 196.5579 151.9768 197.0400 150.6401 197.5221 150.2963 198.0042 150.8395 198.4863 150.5458 198.9684 149.2467 199.4506 147.4928 199.9327 146.1537 200.4148 145.2863 200.8969 144.2732 201.3790 142.3391 201.8611 139.3873 202.3433 138.9400 202.8254 140.1565 203.3075 142.3024 203.7896 140.3788 204.2717 133.4930 204.7538 127.1823 205.2360 124.1485 205.7181 124.7716 206.2002 124.3879 206.6823 122.6241 207.1644 120.2807 207.6465 119.0209 208.1287 119.2144 208.6108 119.1960 209.0929 117.9395 209.5750 114.9941 210.0571 113.4520 210.5392 113.8052 211.0214 115.1600 211.5035 115.4418 211.9856 114.0535 212.4677 113.2668 212.9498 114.2013 213.4319 117.1562 213.9140 120.5188 214.3962 124.3408 214.8783 128.5290 215.3604 132.5410 215.8425 135.7762 216.3246 140.2177 216.8067 147.1760 217.2889 157.5089 217.7710 167.0318 218.2531 175.4497 218.7352 183.0914 219.2173 190.8788 219.6994 198.6611 220.1816 206.9033 220.6637 215.9492 221.1458 225.9106 221.6279 236.5557 222.1100 248.5414 222.5921 261.0114 223.0743 271.8593 223.5564 279.9767 224.0385 288.3654 224.5206 298.2798 225.0027 310.4069 225.4848 322.5781 225.9670 334.4271 226.4491 346.3116 226.9312 359.6171 227.4133 375.2520 227.8954 390.7173 228.3775 404.5844 228.8597 416.8975 229.3418 427.9360 229.8239 437.3381 230.3060 445.5350 230.7881 453.4407 231.2702 461.0620 231.7524 468.4398 232.2345 475.6488 232.7166 483.4348 233.1987 489.4969 233.6808 493.6450 234.1629 496.1069 234.6451 497.5182 235.1272 497.9438 235.6093 497.2726 236.0914 495.3375 236.5735 491.5153 237.0556 488.0325 237.5378 485.2646 238.0199 482.8162 238.5020 479.6352 238.9841 475.4170 239.4662 470.8663 239.9483 466.3786 240.4305 462.6870 240.9126 457.4080 241.3947 450.2670 241.8768 441.6304 242.3589 432.1111 242.8410 420.4733 243.3232 409.7275 243.8053 401.5497 244.2874 397.6187 244.7695 392.1285 245.2516 384.4871 245.7337 375.4276 246.2159 366.5627 246.6980 357.7268 247.1801 349.3881 247.6622 341.5765 248.1443 334.0844 248.6264 327.7493 249.1086 323.1962 249.5907 319.4898 250.0728 314.3979 250.5549 306.2924 251.0370 299.5510 251.5191 296.3488 252.0013 298.4624 252.4834 298.0958 252.9655 294.2057 253.4476 288.4530 253.9297 283.9434 254.4118 281.2860 254.8940 278.7935 255.3761 275.6487 255.8582 271.2667 256.3403 268.6682 256.8224 268.6589 257.3046 269.8248 257.7867 269.7817 258.2688 267.9697 258.7509 266.1701 259.2330 265.1935 259.7151 265.3722 260.1973 264.3312 260.6794 261.5739 261.1615 258.1831 261.6436 255.9397 262.1257 255.3831 262.6078 254.5938 263.0900 252.9572 263.5721 250.3468 264.0542 247.8613 264.5363 245.6573 265.0184 243.3178 265.5005 240.2171 265.9827 236.3923 266.4648 231.7615 266.9469 226.2961 267.4290 220.0206 267.9111 212.9478 268.3932 204.7452 268.8754 196.3381 269.3575 188.9901 269.8396 183.0356 270.3217 176.7784 270.8038 169.6436 271.2859 161.6545 271.7681 154.6603 272.2502 149.0192 272.7323 143.7825 273.2144 138.3064 273.6965 132.5658 274.1786 126.1219 274.6608 118.3782 275.1429 109.7394 275.6250 102.5655 276.1071 97.15491 276.5892 92.89899 277.0714 89.75470 277.5535 87.79663 278.0356 85.01886 278.5177 80.94550 278.9998 75.97253 279.4819 71.73090 279.9641 68.30145 280.4462 64.95923 280.9283 60.65094 281.4104 55.35425 281.8925 51.56104 282.3746 50.09393 282.8568 50.06976 283.3389 48.82935 283.8210 46.11359 284.3031 43.60529 284.7852 43.02216 285.2673 44.22687 285.7495 43.99384 286.2316 41.49097 286.7137 37.86401 287.1958 35.65839 287.6779 34.93549 288.1600 34.10028 288.6422 31.87213 289.1243 28.43860 289.6064 25.68048 290.0885 23.78284 290.5706 22.27783 291.0527 20.59930 291.5349 18.76337 292.0170 16.56958 292.4991 14.01392 292.9812 11.04016 293.4633 7.377258 293.9454 6.425206 294.4276 5.915603 294.9097 5.062683 295.3918 7.187500 295.8739 8.530396 296.3560 9.108093 296.8381 9.061035 297.3203 8.457703 297.8024 7.236206 298.2845 6.069519 298.7666 5.954651 299.2487 6.525696 299.7308 6.697998 300.2130 5.391907 300.6951 3.652283 301.1772 3.470886 301.6593 4.828308 302.1414 6.210022 302.6235 6.025818 303.1057 4.892029 303.5878 4.029297 304.0699 4.208191 304.5520 4.572571 305.0341 3.979980 305.5162 2.531738 305.9984 1.146484 306.4805 0.6922610 306.9626 0.6554570 307.4447 0.2813110 307.9268 0.7396850 308.4089 1.971741 308.8911 2.909546 309.3732 3.670593 309.8553 4.757568 310.3374 6.823425 310.8195 9.188110 311.3016 11.17731 311.7838 12.59534 312.2659 13.74011 312.7480 14.67383 313.2301 15.48553 313.7122 16.36823 314.1943 17.27618 314.6765 18.37860 315.1586 19.88477 315.6407 21.97760 316.1228 23.95026 316.6049 25.42047 317.0870 26.55383 317.5692 27.63068 318.0513 28.98676 318.5334 30.09747 319.0155 30.79584 319.4976 31.08411 319.9797 30.66559 320.4619 28.87518 320.9440 26.49005 321.4261 24.43286 321.9082 23.45319 322.3903 22.27173 322.8724 20.44611 323.3546 17.95459 323.8367 15.36572 324.3188 12.37952 324.8009 9.554993 325.2830 7.374878 325.7651 6.575012 326.2473 5.650391 326.7294 4.386230 327.2115 2.817505 327.6936 1.173279 328.1757 0.4925540 328.6578 2.215881 329.1400 4.046387 329.6221 6.764771 330.1042 8.476501 330.5863 8.740173 331.0684 7.994080 331.5505 7.422058 332.0327 6.557434 332.5148 6.453186 332.9969 7.917175 333.4790 12.30981 333.9611 14.25195 334.4432 12.51642 334.9254 9.047852 335.4075 7.178833 335.8896 7.525452 336.3717 8.233582 336.8538 8.841248 337.3359 9.395569 337.8180 9.428040 338.3001 8.735901 338.7823 7.818909 339.2644 7.381958 339.7465 7.691223 340.2286 7.282410 340.7107 5.503906 341.1928 2.642395 341.6750 0.8969120 342.1571 0.5289310 342.6392 0.2948610 343.1213 0.9703370 343.6034 3.282166 344.0855 5.296753 344.5677 6.751648 345.0498 7.813110 345.5319 8.718018 346.0140 9.449097 346.4961 10.51172 346.9782 12.28717 347.4604 14.70062 347.9425 17.53955 348.4246 21.01550 348.9067 24.29236 349.3888 25.75354 349.8709 25.73969 350.3531 26.11246 350.8352 27.70322 351.3173 30.34109 351.7994 33.81281 352.2815 38.11459 352.7636 42.94830 353.2458 48.54218 353.7279 54.47891 354.2100 59.86212 354.6921 63.95212 355.1742 67.54926 355.6563 71.67319 356.1385 76.25769 356.6206 80.59491 357.1027 83.12384 357.5848 85.46277 358.0669 89.75616 358.5490 97.74289 359.0312 106.0693 359.5133 112.8999 359.9954 118.3862 360.4775 123.1580 360.9596 126.4234 361.4417 129.7921 361.9239 134.4561 362.4060 140.8945 362.8881 147.6156 363.3702 154.7521 363.8523 161.7868 364.3344 167.8458 364.8166 172.4652 365.2987 176.1140 365.7808 178.7914 366.2629 180.4753 366.7450 181.9400 367.2271 183.6536 367.7093 185.1001 368.1914 185.7624 368.6735 184.6833 369.1556 183.6718 369.6377 183.5247 370.1198 184.0314 370.6020 183.0501 371.0841 180.1199 371.5662 176.0860 372.0483 171.4060 372.5304 165.7229 373.0125 159.9631 373.4947 153.8461 373.9768 147.8119 374.4589 142.9957 374.9410 140.0658 375.4231 136.9540 375.9052 132.5471 376.3874 126.4855 376.8695 121.8394 377.3516 118.8568 377.8337 116.8253 378.3158 114.7526 378.7979 112.5803 379.2801 110.6866 379.7622 109.0116 380.2443 107.7047 380.7264 107.8671 381.2085 109.7919 381.6906 111.1031 382.1728 108.6152 382.6549 103.1518 383.1370 100.4054 383.6191 101.9012 384.1012 105.4846 384.5833 107.6478 385.0655 108.5004 385.5476 109.2893 386.0297 110.8691 386.5118 112.8700 386.9939 114.8326 387.4760 116.6940 387.9582 117.8090 388.4403 117.1581 388.9224 115.4507 389.4045 114.0046 389.8866 113.5130 390.3687 113.3785 390.8509 112.9912 391.3330 112.1929 391.8151 111.5291 392.2972 112.2428 392.7793 113.1883 393.2614 112.8715 393.7436 109.1129 394.2257 106.2284 394.7078 107.0454 395.1899 110.2542 395.6720 112.4242 396.1541 111.3585 396.6363 109.9901 397.1184 109.7388 397.6005 111.1028 398.0826 112.3558 398.5647 113.4963 399.0468 114.4973 399.5290 115.1675 400.0111 115.6332 400.4932 115.4228 400.9753 114.7261 401.4574 113.5987 401.9395 110.8583 402.4217 105.7840 402.9038 99.75793 403.3859 93.43591 403.8680 85.91107 404.3501 80.39407 404.8322 78.02228 405.3144 77.42902 405.7965 74.99841 406.2786 70.39456 406.7607 65.03973 407.2428 59.02893 407.7249 52.24744 408.2071 47.28558 408.6892 44.36899 409.1713 42.69421 409.6534 41.72952 410.1355 41.36325 410.6176 39.74744 411.0998 35.41153 411.5819 30.02240 412.0640 28.20322 412.5461 29.83286 413.0282 31.43774 413.5103 29.58578 413.9925 25.88458 414.4746 23.86487 414.9567 24.54456 415.4388 25.75555 415.9209 25.07242 416.4030 23.10162 416.8852 21.23761 417.3673 20.15802 417.8494 19.62503 418.3315 19.05975 418.8136 18.46255 419.2957 18.57175 419.7779 21.35886 420.2600 24.38535 420.7421 25.16205 421.2242 19.95682 421.7063 15.57285 422.1884 14.81720 422.6706 16.79913 423.1527 18.11185 423.6348 17.86508 424.1169 16.86786 424.5990 15.24673 425.0811 12.11343 425.5633 10.48688 426.0454 11.49368 426.5275 13.61188 427.0096 14.92502 427.4917 14.82471 427.9738 14.84494 428.4560 15.46777 428.9381 16.67004 429.4202 17.05481 429.9023 16.26727 430.3844 15.23248 430.8665 14.61401 431.3487 14.52670 431.8308 14.37558 432.3129 14.04727 432.7950 13.82709 433.2771 14.58896 433.7592 16.35434 434.2414 17.72687 434.7235 17.86447 435.2056 17.08600 435.6877 16.71732 436.1698 16.78336 436.6519 16.91150 437.1341 16.76608 437.6162 16.39047 438.0983 15.88733 438.5804 15.22983 439.0625 14.54068 439.5446 14.07526 440.0268 13.73703 440.5089 13.16479 440.9910 11.64078 441.4731 10.09634 441.9552 9.553131 442.4373 10.35611 442.9195 10.89929 443.4016 9.680023 443.8837 7.966614 444.3658 7.300323 444.8479 9.830597 445.3300 11.77496 445.8122 11.58414 446.2943 9.490723 446.7764 7.768036 447.2585 6.723083 447.7406 6.141510 448.2227 5.997711 448.7049 6.850525 449.1870 7.009979 449.6691 5.872620 450.1512 4.340912 450.6333 3.941833 451.1154 5.285706 451.5976 6.451355 452.0797 6.915802 452.5618 6.722839 453.0439 6.415405 453.5260 5.973297 454.0081 5.480957 454.4903 5.021820 454.9724 4.595978 455.4545 4.055634 455.9366 3.348511 456.4187 2.598785 456.9008 1.849396 457.3830 1.156036 457.8651 0.9844970 458.3472 1.950409 458.8293 3.456787 459.3114 4.576355 459.7935 5.285614 460.2757 5.485229 460.7578 4.692749 461.2399 3.450134 461.7220 2.473602 462.2041 1.826904 462.6862 1.681274 463.1684 2.451996 463.6505 3.816620 464.1326 5.007721 464.6147 6.390411 465.0968 6.970062 465.5789 5.705811 466.0611 2.171967 466.5432 0.2766720 467.0253 0.2046200 467.5074 0.8255920 467.9895 1.505859 468.4716 1.169342 468.9538 1.265778 469.4359 2.154663 469.9180 3.515930 470.4001 4.377899 470.8822 4.813690 471.3643 4.559174 471.8465 3.071930 472.3286 7.5714000E-02 472.8107 0.6488950 473.2928 1.688110 473.7749 4.384888 474.2570 3.669891 474.7392 0.4141850 475.2213 2.576355 475.7034 1.138519 476.1855 2.238220 476.6676 4.406464 477.1497 5.433380 477.6319 5.820862 478.1140 5.510529 478.5961 4.815430 479.0782 4.165222 479.5603 3.558960 480.0424 3.198517 480.5246 3.456482 481.0067 4.012787 481.4888 4.418549 481.9709 4.547485 482.4530 4.448578 482.9352 3.976990 483.4173 3.264648 483.8994 2.709045 484.3815 2.896667 484.8636 2.892212 485.3457 2.068756 485.8279 2.362079 486.3100 1.452667 486.7921 2.156647 487.2742 2.287262 487.7563 1.913239 488.2384 9.7626001E-02 488.7206 0.5180970 489.2027 0.9915770 489.6848 3.798553 490.1669 4.881256 490.6490 3.900940 491.1311 2.169373 491.6133 7.4127004E-02 492.0954 2.811737 492.5775 4.213837 493.0596 4.084290 493.5417 3.378082 494.0238 2.909241 494.5060 2.703918 494.9881 3.001770 495.4702 4.176941 495.9523 5.366791 496.4344 4.992950 496.9165 3.446930 497.3987 2.208527 497.8808 2.098602 498.3629 2.680542 498.8450 3.460907 499.3271 4.390381 499.8092 5.925262 500.2914 9.435913 500.7735 13.14075 501.2556 15.42712 501.7377 14.95300 502.2198 14.09888 502.7019 13.10406 503.1841 12.10516 503.6662 11.51050 504.1483 10.55658 504.6304 10.86932 505.1125 13.54651 505.5946 18.95490 506.0768 21.95776 506.5589 21.33331 507.0410 20.11841 507.5231 20.75043 508.0052 23.40088 508.4873 26.87878 508.9695 31.52759 509.4516 36.18890 509.9337 38.10040 510.4158 37.42511 510.8979 37.34949 511.3800 39.63910 511.8622 43.36603 512.3443 46.43964 512.8264 48.87012 513.3085 51.44769 513.7906 54.90540 514.2728 58.79510 514.7549 62.58154 515.2370 66.20398 515.7191 69.60187 516.2012 72.37982 516.6833 75.00403 517.1655 78.24786 517.6476 82.73169 518.1297 87.50476 518.6118 91.98822 519.0939 96.28430 519.5760 101.6271 520.0582 109.6497 520.5403 117.4419 521.0224 123.6175 521.5045 127.6223 521.9866 131.7059 522.4688 135.8679 522.9509 140.0958 523.4330 144.4143 523.9151 148.7812 524.3972 153.3788 524.8793 158.3497 525.3615 163.5627 525.8436 168.9231 526.3257 174.4309 526.8078 179.1384 527.2899 182.0660 527.7720 183.9376 528.2542 186.5297 528.7363 189.9470 529.2184 192.9859 529.7005 194.1168 530.1826 194.3645 530.6647 195.2452 531.1469 198.1016 531.6290 200.2695 532.1111 199.8852 532.5932 197.7238 533.0753 195.3720 533.5574 193.5835 534.0396 191.7216 534.5217 189.4068 535.0038 186.6249 535.4859 183.9650 535.9680 181.9926 536.4501 179.6135 536.9323 176.0237 537.4144 170.3257 537.8965 165.8621 538.3786 162.8998 538.8607 160.9064 539.3428 159.2607 539.8250 157.9754 540.3071 156.7908 540.7892 155.7300 541.2713 154.6691 541.7534 153.1180 542.2355 151.1552 542.7177 149.5786 543.1998 149.2618 543.6819 149.5078 544.1640 149.0992 544.6461 147.9194 545.1282 146.8809 545.6104 146.6472 546.0925 146.9417 546.5746 147.3961 547.0567 148.0372 547.5388 148.5332 548.0209 148.1928 548.5031 147.8008 548.9852 148.9154 549.4673 154.2099 549.9494 158.3618 550.4315 159.7681 550.9136 158.4421 551.3958 157.3781 551.8779 156.6688 552.3600 156.0660 552.8421 155.5260 553.3242 155.1136 553.8063 154.0022 554.2885 151.9449 554.7706 149.7752 555.2527 148.9860 555.7348 149.2766 556.2169 148.7568 556.6990 146.8014 557.1812 143.8508 557.6633 140.0524 558.1454 135.6677 558.6275 131.6658 559.1096 129.3474 559.5917 127.1605 560.0739 123.7953 560.5560 119.1368 561.0381 114.2659 561.5202 109.5394 562.0023 104.8736 562.4844 100.1630 562.9666 94.31305 563.4487 90.10034 563.9308 88.98096 564.4129 88.96674 564.8950 86.96484 565.3771 82.19897 565.8593 77.19861 566.3414 72.38849 566.8235 67.80109 567.3056 63.24072 567.7877 58.63635 568.2698 54.73755 568.7520 52.55554 569.2341 51.50433 569.7162 48.99164 570.1983 44.87909 570.6804 40.68213 571.1625 37.96204 571.6447 36.11163 572.1268 34.19708 572.6089 32.04285 573.0910 29.64893 573.5731 26.76770 574.0552 23.68103 574.5374 20.81635 575.0195 18.28619 575.5016 16.06891 575.9837 14.21515 576.4658 12.72052 576.9479 11.37549 577.4301 10.40900 577.9122 9.337158 578.3943 7.881165 578.8764 5.932983 579.3585 4.219604 579.8406 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