#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 15:48:26 +0300 (Thu, 24 May 2018) $ #$Revision: 787 $ #$URL: svn://172.16.1.111/rod/cif/1/00/02/1000283.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000283 loop_ _publ_author_name 'Kampf, A. R.' 'Foord, E. E.' _publ_section_title ; Artroeite, PbAlF3(OH)2, a new mineral from the Grand Reef mine, Graham County, Arizona: Description and crystal structure ; _journal_name_full 'American Mineralogist' _journal_page_first 179 _journal_page_last 183 _journal_volume 80 _journal_year 1995 _chemical_compound_source R100034 _chemical_formula_sum 'Al F3 H2 O2 Pb' _chemical_name_mineral Artroeite _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 90.68 _cell_angle_beta 107.69 _cell_angle_gamma 104.46 _cell_length_a 6.270 _cell_length_b 6.821 _cell_length_c 5.057 _cell_volume 198.618 _exptl_crystal_density_diffrn 5.438 _cod_original_formula_sum 'Pb Al F3 O2 H2' _cod_database_code 9001665 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R100034.rod _rod_data_source.block 3500000 _rod_database.code 1000283 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9001665 COD http://www.crystallography.net/cod/9001665.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 155.5779 0.0000000E+00 156.0601 0.1220090 156.5422 0.8417360 157.0243 2.468445 157.5064 3.630341 157.9885 5.549042 158.4706 8.567566 158.9528 12.71948 159.4349 17.29547 159.9170 22.55502 160.3991 27.93060 160.8812 32.78143 161.3633 35.59259 161.8455 38.95032 162.3276 44.46054 162.8097 52.74243 163.2918 60.04935 163.7739 64.18027 164.2560 66.02170 164.7382 65.36609 165.2203 64.65137 165.7024 64.46179 166.1845 65.07721 166.6666 67.16333 167.1487 68.12482 167.6309 66.34659 168.1130 62.10172 168.5951 57.33957 169.0772 52.35388 169.5593 47.61545 170.0414 43.64725 170.5236 40.66522 171.0057 38.04440 171.4878 35.58060 171.9699 33.13452 172.4520 30.32724 172.9341 26.56281 173.4163 22.43665 173.8984 18.59171 174.3805 15.00772 174.8626 11.96024 175.3447 9.763397 175.8268 8.311066 176.3090 7.141724 176.7911 6.310516 177.2732 5.495605 177.7553 4.076019 178.2374 3.748975 178.7195 3.293279 179.2017 2.822784 179.6838 2.973633 180.1659 2.651978 180.6480 2.352448 181.1301 2.051422 181.6122 1.675659 182.0944 1.205444 182.5765 0.6532900 183.0586 0.1072390 183.5407 1.053375 184.0228 1.818573 184.5049 1.862549 184.9871 1.380615 185.4692 1.081024 185.9513 1.232361 186.4334 1.691986 186.9155 2.221497 187.3976 2.832581 187.8798 3.340454 188.3619 3.187347 188.8440 2.567657 189.3261 2.767670 189.8082 4.748627 190.2903 7.875671 190.7725 9.652252 191.2546 9.891724 191.7367 9.912872 192.2188 11.27612 192.7009 13.93988 193.1830 16.91647 193.6652 20.05438 194.1473 23.28497 194.6294 25.58640 195.1115 26.57343 195.5936 27.89731 196.0757 31.94720 196.5579 38.78470 197.0400 46.31729 197.5221 53.78134 198.0042 61.17178 198.4863 69.05447 198.9684 77.48328 199.4506 86.23398 199.9327 95.16891 200.4148 104.4706 200.8969 112.7415 201.3790 119.0804 201.8611 123.3624 202.3433 128.4424 202.8254 134.5396 203.3075 141.0977 203.7896 147.1965 204.2717 152.8923 204.7538 157.9912 205.2360 162.1759 205.7181 165.2886 206.2002 168.9042 206.6823 173.1151 207.1644 177.7057 207.6465 182.0076 208.1287 185.5393 208.6108 190.2947 209.0929 197.1330 209.5750 206.2124 210.0571 216.6356 210.5392 228.2390 211.0214 241.3996 211.5035 257.0649 211.9856 275.3500 212.4677 295.3689 212.9498 317.5828 213.4319 342.7830 213.9140 365.1785 214.3962 384.8481 214.8783 401.6874 215.3604 416.1014 215.8425 430.4818 216.3246 437.3988 216.8067 433.0363 217.2889 415.6875 217.7710 392.7357 218.2531 362.5515 218.7352 327.7577 219.2173 293.4011 219.6994 258.2656 220.1816 225.6398 220.6637 196.3895 221.1458 170.5338 221.6279 147.8087 222.1100 128.0308 222.5921 111.3430 223.0743 97.81949 223.5564 88.43109 224.0385 80.67087 224.5206 73.65613 225.0027 67.33908 225.4848 61.64441 225.9670 56.60791 226.4491 52.23459 226.9312 48.47971 227.4133 45.44135 227.8954 42.89761 228.3775 40.84995 228.8597 39.45712 229.3418 38.06232 229.8239 36.59415 230.3060 35.11584 230.7881 33.84378 231.2702 32.74142 231.7524 31.85513 232.2345 31.21133 232.7166 30.81882 233.1987 30.59750 233.6808 30.47241 234.1629 30.53348 234.6451 30.99414 235.1272 31.68796 235.6093 33.03928 236.0914 35.38535 236.5735 39.45499 237.0556 42.73944 237.5378 44.89044 238.0199 46.43387 238.5020 48.73251 238.9841 52.50934 239.4662 56.03217 239.9483 58.67209 240.4305 60.57260 240.9126 61.19171 241.3947 60.41013 241.8768 58.53119 242.3589 55.80783 242.8410 51.75647 243.3232 47.10675 243.8053 42.09680 244.2874 36.15826 244.7695 31.42163 245.2516 28.10001 245.7337 26.04877 246.2159 24.78717 246.6980 24.38632 247.1801 24.22397 247.6622 24.10849 248.1443 23.99939 248.6264 24.26370 249.1086 25.03461 249.5907 26.14380 250.0728 27.22610 250.5549 28.21939 251.0370 29.44669 251.5191 31.00458 252.0013 32.93176 252.4834 34.80121 252.9655 36.62308 253.4476 38.41113 253.9297 40.15295 254.4118 41.79370 254.8940 43.51547 255.3761 45.27927 255.8582 47.01807 256.3403 48.80438 256.8224 50.71939 257.3046 52.78931 257.7867 54.99750 258.2688 57.40982 258.7509 59.92300 259.2330 62.48743 259.7151 65.12833 260.1973 67.47003 260.6794 69.33322 261.1615 71.06903 261.6436 73.07010 262.1257 75.31116 262.6078 77.95703 263.0900 81.28690 263.5721 85.51138 264.0542 88.48709 264.5363 89.76294 265.0184 90.35330 265.5005 91.80170 265.9827 94.67096 266.4648 96.69278 266.9469 97.09943 267.4290 95.86218 267.9111 94.38724 268.3932 92.67917 268.8754 90.73395 269.3575 88.47769 269.8396 85.76593 270.3217 83.21588 270.8038 81.06259 271.2859 79.26071 271.7681 77.11673 272.2502 74.43735 272.7323 71.82242 273.2144 69.98636 273.6965 69.02600 274.1786 68.25964 274.6608 67.52655 275.1429 66.85788 275.6250 66.46552 276.1071 66.37701 276.5892 66.48737 277.0714 66.75601 277.5535 67.21048 278.0356 67.60001 278.5177 67.86545 278.9998 68.03836 279.4819 68.55753 279.9641 69.73004 280.4462 70.00967 280.9283 67.40457 281.4104 61.80020 281.8925 57.94644 282.3746 57.28049 282.8568 58.28519 283.3389 56.44464 283.8210 51.49069 284.3031 45.74405 284.7852 40.37180 285.2673 35.44839 285.7495 31.73853 286.2316 29.61801 286.7137 28.33765 287.1958 26.28998 287.6779 23.44400 288.1600 20.64423 288.6422 18.25366 289.1243 16.28775 289.6064 15.16824 290.0885 15.14667 290.5706 15.38947 291.0527 14.48318 291.5349 12.49225 292.0170 10.30890 292.4991 7.982605 292.9812 5.795807 293.4633 5.213745 293.9454 6.625000 294.4276 8.306488 294.9097 7.646240 295.3918 5.059814 295.8739 2.727570 296.3560 1.857269 296.8381 1.982788 297.3203 2.287384 297.8024 2.819489 298.2845 2.895081 298.7666 1.023376 299.2487 2.044861 299.7308 1.253216 300.2130 3.303314 300.6951 1.203156 301.1772 0.2492070 301.6593 1.055847 302.1414 1.076019 302.6235 0.7223210 303.1057 3.364685 303.5878 4.815125 304.0699 3.725769 304.5520 1.660065 305.0341 0.2396240 305.5162 0.5607600 305.9984 0.9768680 306.4805 1.161072 306.9626 1.058746 307.4447 0.5199890 307.9268 0.8876650 308.4089 2.235657 308.8911 2.572815 309.3732 2.099396 309.8553 1.628601 310.3374 1.594147 310.8195 1.821930 311.3016 2.276093 311.7838 3.314453 312.2659 3.791534 312.7480 2.689697 313.2301 4.166976 313.7122 2.016998 314.1943 5.472778 314.6765 8.107635 315.1586 8.143433 315.6407 4.473389 316.1228 1.269501 316.6049 1.018524 317.0870 2.486633 317.5692 3.639435 318.0513 3.195343 318.5334 2.714264 319.0155 3.144897 319.4976 4.749390 319.9797 5.890900 320.4619 5.336853 320.9440 4.270294 321.4261 4.019440 321.9082 5.340576 322.3903 7.085785 322.8724 9.163086 323.3546 11.57141 323.8367 13.47513 324.3188 14.37076 324.8009 14.90500 325.2830 15.56519 325.7651 15.88739 326.2473 16.96701 326.7294 19.62863 327.2115 23.52792 327.6936 26.26215 328.1757 26.37155 328.6578 26.28448 329.1400 27.20551 329.6221 29.76035 330.1042 32.48837 330.5863 35.57712 331.0684 38.81531 331.5505 41.70947 332.0327 44.14822 332.5148 46.50119 332.9969 48.97180 333.4790 51.55365 333.9611 53.83456 334.4432 55.53320 334.9254 57.20306 335.4075 59.74997 335.8896 63.25116 336.3717 67.20538 336.8538 71.56058 337.3359 76.47668 337.8180 81.40735 338.3001 86.58081 338.7823 91.32596 339.2644 94.66428 339.7465 96.29852 340.2286 97.96436 340.7107 100.1703 341.1928 102.7872 341.6750 104.7748 342.1571 106.2061 342.6392 106.8550 343.1213 106.3440 343.6034 104.6573 344.0855 102.7693 344.5677 100.6620 345.0498 98.63431 345.5319 97.55225 346.0140 97.43689 346.4961 97.66812 346.9782 98.01151 347.4604 98.41550 347.9425 98.52441 348.4246 98.23013 348.9067 97.89386 349.3888 97.99481 349.8709 98.51004 350.3531 99.28918 350.8352 100.2537 351.3173 101.4308 351.7994 102.9048 352.2815 104.6782 352.7636 106.6928 353.2458 108.9525 353.7279 111.4092 354.2100 113.9717 354.6921 116.9996 355.1742 119.8297 355.6563 121.7033 356.1385 122.6614 356.6206 123.2801 357.1027 123.6692 357.5848 123.8709 358.0669 124.0767 358.5490 124.4720 359.0312 124.7565 359.5133 124.6765 359.9954 124.2577 360.4775 123.5922 360.9596 123.4221 361.4417 122.5582 361.9239 120.0633 362.4060 115.2337 362.8881 110.5393 363.3702 106.5639 363.8523 103.3047 364.3344 100.7893 364.8166 100.2272 365.2987 99.29630 365.7808 96.90198 366.2629 92.80917 366.7450 88.85681 367.2271 85.57971 367.7093 82.51627 368.1914 79.23541 368.6735 75.62573 369.1556 71.81812 369.6377 67.79309 370.1198 63.58133 370.6020 59.49500 371.0841 55.75092 371.5662 52.00839 372.0483 48.02533 372.5304 43.45084 373.0125 39.15314 373.4947 35.01334 373.9768 31.20166 374.4589 28.34531 374.9410 27.02350 375.4231 25.57272 375.9052 23.26279 376.3874 19.93829 376.8695 16.79266 377.3516 13.63458 377.8337 10.92160 378.3158 9.281158 378.7979 8.831268 379.2801 8.585144 379.7622 8.407104 380.2443 8.206268 380.7264 7.500702 381.2085 6.243256 381.6906 4.816132 382.1728 3.448975 382.6549 2.150574 383.1370 1.017639 383.6191 2.4048001E-02 384.1012 -0.1546611 384.5833 0.6461790 385.0655 0.2123410 385.5476 1.112030 386.0297 1.944275 386.5118 2.482452 386.9939 2.069275 387.4760 0.5019840 387.9582 0.9527590 388.4403 0.7514340 388.9224 0.4322200 389.4045 1.193268 389.8866 0.3705140 390.3687 0.7140500 390.8509 0.6626280 391.3330 0.4003300 391.8151 1.032684 392.2972 0.3796390 392.7793 2.295013 393.2614 3.184448 393.7436 1.970093 394.2257 0.6385500 394.7078 0.2957150 395.1899 0.5006410 395.6720 9.6588001E-02 396.1541 2.422913 396.6363 4.733002 397.1184 5.477356 397.6005 3.763519 398.0826 2.878601 398.5647 3.973999 399.0468 5.936859 399.5290 7.418274 400.0111 7.493103 400.4932 7.991058 400.9753 9.478973 401.4574 11.95724 401.9395 13.76334 402.4217 14.47138 402.9038 14.96909 403.3859 15.80139 403.8680 16.92850 404.3501 18.55673 404.8322 20.99753 405.3144 23.79639 405.7965 25.56128 406.2786 26.00696 406.7607 26.40427 407.2428 27.40463 407.7249 29.04077 408.2071 30.26566 408.6892 30.99615 409.1713 31.58005 409.6534 32.57343 410.1355 33.93610 410.6176 34.98010 411.0998 35.58823 411.5819 35.70752 412.0640 34.92087 412.5461 33.27231 413.0282 31.75580 413.5103 31.54053 413.9925 31.96957 414.4746 31.66287 414.9567 30.31866 415.4388 28.41574 415.9209 25.98730 416.4030 23.34982 416.8852 21.22821 417.3673 20.28909 417.8494 19.84842 418.3315 19.37811 418.8136 18.84930 419.2957 18.35123 419.7779 18.11304 420.2600 17.85672 420.7421 17.30505 421.2242 15.56955 421.7063 14.37363 422.1884 14.87399 422.6706 16.51144 423.1527 17.19189 423.6348 15.24481 424.1169 13.18921 424.5990 12.15802 425.0811 12.55170 425.5633 13.28873 426.0454 14.34061 426.5275 15.73001 427.0096 17.45758 427.4917 20.01035 427.9738 22.22385 428.4560 23.73749 428.9381 24.60324 429.4202 25.76584 429.9023 27.32178 430.3844 29.01135 430.8665 30.77475 431.3487 32.71332 431.8308 33.86053 432.3129 34.07938 432.7950 33.49951 433.2771 32.03027 433.7592 29.65125 434.2414 27.71249 434.7235 27.19376 435.2056 27.66486 435.6877 27.44476 436.1698 26.46561 436.6519 25.19977 437.1341 24.34723 437.6162 23.66458 438.0983 22.32642 438.5804 19.57291 439.0625 16.75851 439.5446 15.49741 440.0268 15.53351 440.5089 15.97586 440.9910 16.65060 441.4731 17.28564 441.9552 17.45483 442.4373 17.00235 442.9195 17.13074 443.4016 19.09662 443.8837 21.74939 444.3658 23.69220 444.8479 22.85504 445.3300 22.90735 445.8122 25.71033 446.2943 30.89166 446.7764 34.93802 447.2585 35.68384 447.7406 36.35376 448.2227 38.63733 448.7049 43.81635 449.1870 48.26822 449.6691 51.21240 450.1512 53.69650 450.6333 57.42572 451.1154 63.29657 451.5976 68.86902 452.0797 73.27158 452.5618 76.57071 453.0439 80.34705 453.5260 84.57916 454.0081 89.25732 454.4903 94.45282 454.9724 100.1125 455.4545 105.6866 455.9366 110.9605 456.4187 116.3217 456.9008 122.3510 457.3830 129.0710 457.8651 135.9289 458.3472 142.7648 458.8293 149.6384 459.3114 157.2411 459.7935 165.4910 460.2757 172.9193 460.7578 177.9240 461.2399 181.4103 461.7220 184.7527 462.2041 189.0525 462.6862 192.0789 463.1684 192.1741 463.6505 189.9002 464.1326 186.5437 464.6147 183.3229 465.0968 178.5455 465.5789 171.0168 466.0611 160.3450 466.5432 149.4579 467.0253 139.1321 467.5074 128.7921 467.9895 117.9921 468.4716 104.9052 468.9538 93.46652 469.4359 84.48544 469.9180 77.38739 470.4001 70.32581 470.8822 63.22937 471.3643 56.38571 471.8465 49.77112 472.3286 43.30621 472.8107 37.99045 473.2928 33.99673 473.7749 30.87973 474.2570 28.45090 474.7392 26.70682 475.2213 24.86133 475.7034 22.74350 476.1855 20.42850 476.6676 18.00467 477.1497 15.47672 477.6319 13.01138 478.1140 10.17059 478.5961 7.592957 479.0782 6.656616 479.5603 7.550323 480.0424 8.618835 480.5246 8.685547 481.0067 8.032715 481.4888 7.055817 481.9709 5.664276 482.4530 4.224396 482.9352 2.542511 483.4173 0.8935550 483.8994 0.1486510 484.3815 1.803741 484.8636 3.446442 485.3457 3.828369 485.8279 2.514984 486.3100 1.269257 486.7921 0.1289060 487.2742 0.8171390 487.7563 1.505951 488.2384 2.019073 488.7206 2.098236 489.2027 1.521851 489.6848 0.5198970 490.1669 0.1404420 490.6490 0.5092470 491.1311 0.3702390 491.6133 0.6264650 492.0954 2.459930 492.5775 3.701019 493.0596 4.318146 493.5417 4.435638 494.0238 3.735016 494.5060 2.504150 494.9881 2.264679 495.4702 3.870789 495.9523 5.891846 496.4344 6.188019 496.9165 5.088043 497.3987 3.829681 497.8808 3.020142 498.3629 2.419220 498.8450 1.791290 499.3271 1.108704 499.8092 0.5154720 500.2914 1.0040000E-02 500.7735 -8.8422291E-02 501.2556 0.4524230 501.7377 8.7402001E-02 502.2198 0.4837950 502.7019 0.8662110 503.1841 1.004578 503.6662 0.2676390 504.1483 3.100037 504.6304 5.528046 505.1125 5.444305 505.5946 2.494751 506.0768 1.873993 506.5589 4.900330 507.0410 8.315552 507.5231 9.160309 508.0052 6.914124 508.4873 5.595947 508.9695 5.783752 509.4516 6.897186 509.9337 7.909607 510.4158 8.836121 510.8979 9.970367 511.3800 11.67200 511.8622 13.60379 512.3443 14.88412 512.8264 15.53775 513.3085 16.30624 513.7906 18.18607 514.2728 20.34875 514.7549 21.60309 515.2370 21.45654 515.7191 21.20557 516.2012 21.31824 516.6833 21.92746 517.1655 23.23840 517.6476 26.34409 518.1297 29.14862 518.6118 30.90732 519.0939 31.66370 519.5760 32.10300 520.0582 31.41232 520.5403 31.19183 521.0224 32.31714 521.5045 35.67886 521.9866 37.75418 522.4688 38.15533 522.9509 37.68942 523.4330 37.20395 523.9151 36.61618 524.3972 36.51657 524.8793 37.24576 525.3615 38.35529 525.8436 38.47543 526.3257 37.62476 526.8078 37.01208 527.2899 37.54013 527.7720 38.78442 528.2542 39.82724 528.7363 40.62766 529.2184 41.25623 529.7005 41.47803 530.1826 41.64850 530.6647 42.31610 531.1469 44.03250 531.6290 45.59671 532.1111 45.62646 532.5932 45.05753 533.0753 45.79208 533.5574 49.93082 534.0396 53.97430 534.5217 56.39697 535.0038 56.98428 535.4859 58.72006 535.9680 62.64581 536.4501 66.74594 536.9323 69.79987 537.4144 71.34274 537.8965 73.20877 538.3786 75.45889 538.8607 77.99829 539.3428 80.50058 539.8250 82.93771 540.3071 86.19794 540.7892 90.88733 541.2713 96.24792 541.7534 99.85367 542.2355 101.9646 542.7177 104.5622 543.1998 110.0193 543.6819 116.4278 544.1640 120.4108 544.6461 121.5850 545.1282 122.7776 545.6104 126.2693 546.0925 130.7691 546.5746 134.8983 547.0567 138.7974 547.5388 141.6481 548.0209 142.4260 548.5031 141.9059 548.9852 141.8452 549.4673 143.6785 549.9494 144.5823 550.4315 143.6351 550.9136 140.8828 551.3958 138.5782 551.8779 136.8244 552.3600 135.5057 552.8421 134.5223 553.3242 133.8010 553.8063 132.8795 554.2885 131.7377 554.7706 130.8699 555.2527 130.6790 555.7348 131.1732 556.2169 132.5842 556.6990 135.0398 557.1812 138.3477 557.6633 142.2906 558.1454 146.8445 558.6275 151.9567 559.1096 157.4920 559.5917 163.6024 560.0739 170.4806 560.5560 178.1769 561.0381 185.9873 561.5202 193.1139 562.0023 200.5095 562.4844 208.9297 562.9666 220.0125 563.4487 229.8219 563.9308 237.3293 564.4129 243.8145 564.8950 251.4212 565.3771 261.2785 565.8593 269.4993 566.3414 275.0191 566.8235 278.2250 567.3056 281.2340 567.7877 284.1569 568.2698 285.8916 568.7520 286.0777 569.2341 284.5830 569.7162 280.8150 570.1983 274.7701 570.6804 266.7986 571.1625 256.8183 571.6447 245.3103 572.1268 232.8623 572.6089 218.8135 573.0910 205.3808 573.5731 194.5062 574.0552 185.0672 574.5374 174.8546 575.0195 161.4552 575.5016 149.0163 575.9837 139.3954 576.4658 132.4236 576.9479 124.8426 577.4301 115.9552 577.9122 107.2866 578.3943 99.28400 578.8764 91.90158 579.3585 85.75262 579.8406 81.00439 580.3228 77.10916 580.8049 73.65765 581.2870 70.63916 581.7691 67.68661 582.2512 64.77698 582.7333 61.84982 583.2155 58.52686 583.6975 55.08154 584.1796 52.23529 584.6617 50.39536 585.1439 49.29279 585.6260 49.05264 586.1081 49.47021 586.5902 49.57681 587.0723 48.60593 587.5544 47.45889 588.0366 46.50388 588.5187 45.65042 589.0008 45.62646 589.4829 47.54370 589.9650 49.63062 590.4471 50.55032 590.9293 49.84610 591.4114 48.98483 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26.83972 618.8920 25.93069 619.3741 24.32684 619.8563 21.97830 620.3384 19.74194 620.8205 18.55505 621.3026 17.77264 621.7847 16.50558 622.2668 14.20044 622.7490 12.35861 623.2311 11.93304 623.7132 12.23096 624.1953 12.36679 624.6774 12.64771 625.1595 12.16568 625.6417 10.13788 626.1238 7.331451 626.6059 6.121490 627.0880 7.061584 627.5701 7.933624 628.0522 7.816406 628.5344 7.005188 629.0165 7.124359 629.4986 8.206879 629.9807 9.188782 630.4628 9.369507 630.9449 8.852051 631.4271 7.647583 631.9092 5.728027 632.3913 4.105743 632.8734 3.589020 633.3555 3.713043 633.8376 3.988068 634.3198 4.245331 634.8019 4.740570 635.2840 6.152405 635.7661 7.557434 636.2482 7.638092 636.7303 5.020111 637.2125 3.454559 637.6946 4.004608 638.1767 5.701843 638.6588 5.627380 639.1409 3.505890 639.6230 1.449066 640.1052 0.2279050 640.5873 0.2976070 641.0694 0.3404240 641.5515 5.6701999E-02 642.0336 0.3548580 642.5157 6.2256001E-02 642.9979 0.6344910 643.4800 0.5678710 643.9621 0.2379760 644.4442 0.7743530 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