#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 15:49:19 +0300 (Thu, 24 May 2018) $ #$Revision: 800 $ #$URL: svn://172.16.1.111/rod/cif/1/00/02/1000294.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000294 loop_ _publ_author_name 'Keller, P.' 'Lissner, F.' 'Schleid, T.' _publ_section_title ; The crystal structures of zincroselite and gaitite: Two natural polymorphs of Ca2Zn[AsO4]2*2H2O from Tsumeb, Namibia Locality: Tsumeb, Namibia ; _journal_name_full 'European Journal of Mineralogy' _journal_page_first 353 _journal_page_last 359 _journal_paper_doi 10.1127/0935-1221/2004/0016-0353 _journal_volume 16 _journal_year 2004 _chemical_compound_source R100192 _chemical_formula_sum 'As2 Ca2 H4 Mg0.14 O10 Zn0.86' _chemical_name_mineral Zincroselite _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90 _cell_angle_beta 107.69 _cell_angle_gamma 90 _cell_length_a 5.827 _cell_length_b 12.899 _cell_length_c 5.646 _cell_volume 404.301 _exptl_crystal_density_diffrn 3.727 _cod_original_formula_sum 'Ca2 (Zn.86 Mg.14) As2 O10 H4' _cod_database_code 9005671 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R100192.rod _rod_data_source.block 3500000 _rod_database.code 1000294 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9005671 COD http://www.crystallography.net/cod/9005671.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 132.0151 0.0000000E+00 132.4972 1.733223 132.9794 3.758999 133.4615 5.855602 133.9436 8.558239 134.4257 11.10843 134.9078 12.08879 135.3899 13.47256 135.8721 12.49637 136.3542 8.961174 136.8363 5.701065 137.3184 3.139431 137.8005 0.7186620 138.2826 1.623264 138.7648 3.248085 139.2469 4.154602 139.7290 4.269592 140.2111 3.195801 140.6932 0.6634600 141.1753 2.614494 141.6575 5.750114 142.1396 8.396446 142.6217 12.08475 143.1038 17.41895 143.5859 24.59252 144.0681 30.88869 144.5502 35.91856 145.0323 40.48244 145.5144 45.79268 145.9965 52.83214 146.4786 58.98906 146.9608 63.24234 147.4429 65.18665 147.9250 67.37462 148.4071 69.24310 148.8892 71.56949 149.3713 75.37541 149.8535 80.84216 150.3356 87.71519 150.8177 95.99641 151.2998 105.8997 151.7819 116.7408 152.2640 128.1066 152.7462 140.4970 153.2283 154.5434 153.7104 171.3223 154.1925 188.9251 154.6746 206.5260 155.1567 222.9622 155.6389 240.8433 156.1210 261.3276 156.6031 283.6129 157.0852 305.9521 157.5673 328.3379 158.0495 350.3467 158.5316 372.1096 159.0137 394.2938 159.4958 415.0194 159.9779 433.7511 160.4600 450.7377 160.9422 466.7902 161.4243 482.2722 161.9064 496.8378 162.3885 510.1369 162.8706 521.4456 163.3527 532.4745 163.8349 543.2682 164.3170 554.1742 164.7991 566.8586 165.2812 581.7796 165.7633 599.0050 166.2454 618.5945 166.7276 640.7840 167.2097 665.1619 167.6918 691.7767 168.1739 720.4141 168.6560 751.3993 169.1381 785.7181 169.6203 821.8214 170.1024 850.9258 170.5845 875.6765 171.0666 901.1849 171.5487 927.6820 172.0309 955.1265 172.5130 985.3279 172.9951 1021.261 173.4772 1060.428 173.9593 1099.090 174.4414 1134.012 174.9236 1168.480 175.4057 1205.570 175.8878 1245.636 176.3699 1286.408 176.8520 1326.925 177.3341 1367.143 177.8163 1407.135 178.2984 1446.233 178.7805 1484.990 179.2626 1525.153 179.7447 1566.299 180.2268 1605.779 180.7090 1640.342 181.1911 1670.581 181.6732 1697.770 182.1553 1722.755 182.6374 1745.050 183.1195 1763.401 183.6017 1778.313 184.0838 1787.977 184.5659 1790.900 185.0480 1787.231 185.5301 1777.583 186.0123 1761.508 186.4944 1739.620 186.9765 1714.061 187.4586 1684.522 187.9407 1651.891 188.4228 1616.836 188.9050 1579.582 189.3871 1540.606 189.8692 1499.251 190.3513 1456.569 190.8334 1414.741 191.3155 1374.437 191.7977 1334.208 192.2798 1292.156 192.7619 1248.317 193.2440 1202.598 193.7261 1153.106 194.2082 1100.546 194.6904 1050.555 195.1725 1003.671 195.6546 958.8724 196.1367 915.8210 196.6188 874.2924 197.1009 834.9595 197.5831 798.3843 198.0652 764.4792 198.5473 732.9045 199.0294 703.6647 199.5115 676.3478 199.9937 650.1851 200.4758 625.4945 200.9579 601.9974 201.4400 579.6268 201.9221 558.2440 202.4042 538.5251 202.8864 520.9104 203.3685 504.6072 203.8506 487.3129 204.3327 468.6796 204.8148 451.3338 205.2969 437.0348 205.7791 426.1181 206.2612 414.6823 206.7433 402.1262 207.2254 389.4177 207.7075 379.1902 208.1896 372.1700 208.6718 364.8105 209.1539 354.3189 209.6360 339.5461 210.1181 328.4848 210.6002 322.8346 211.0823 320.4981 211.5645 315.6003 212.0466 307.7648 212.5287 298.5977 213.0108 288.7071 213.4929 277.7220 213.9750 267.3623 214.4572 257.9092 214.9393 249.0843 215.4214 239.6144 215.9035 228.8301 216.3856 218.6768 216.8678 210.3738 217.3499 204.0745 217.8320 198.7687 218.3141 194.5538 218.7962 191.2594 219.2783 188.3868 219.7605 185.7709 220.2426 183.8649 220.7247 182.9432 221.2068 183.1276 221.6889 183.9530 222.1710 185.5978 222.6532 187.8243 223.1353 189.7642 223.6174 191.2751 224.0995 192.8134 224.5816 194.6962 225.0637 197.3458 225.5459 199.2779 226.0280 199.9400 226.5101 199.9830 226.9922 201.3222 227.4743 204.2750 227.9564 208.0459 228.4386 212.4771 228.9207 217.9668 229.4028 222.8219 229.8849 226.5720 230.3670 229.7807 230.8492 234.2590 231.3313 240.4526 231.8134 247.1432 232.2955 254.0650 232.7776 261.7108 233.2597 268.1528 233.7419 273.2036 234.2240 277.1362 234.7061 280.4643 235.1882 283.1639 235.6703 285.3201 236.1524 287.0732 236.6346 288.7553 237.1167 289.2878 237.5988 288.8219 238.0809 287.1890 238.5630 283.7970 239.0451 277.7233 239.5273 271.2806 240.0094 265.4937 240.4915 260.9639 240.9736 255.3867 241.4557 248.3073 241.9378 240.3360 242.4200 232.9504 242.9021 227.2233 243.3842 220.2711 243.8663 210.7515 244.3484 197.6084 244.8306 184.9734 245.3127 172.9154 245.7948 161.4289 246.2769 150.6533 246.7590 141.1502 247.2411 131.5973 247.7233 121.5692 248.2054 110.9933 248.6875 100.1031 249.1696 88.49561 249.6517 76.94788 250.1338 66.81851 250.6160 58.45786 251.0981 50.87054 251.5802 43.92828 252.0623 37.72504 252.5444 31.48145 253.0265 25.11392 253.5087 18.81509 253.9908 12.93350 254.4729 7.387573 254.9550 2.352081 255.4371 2.157837 255.9192 6.126617 256.4014 9.424652 256.8835 11.81448 257.3656 13.77335 257.8477 16.04141 258.3298 19.11057 258.8120 21.37476 259.2941 22.24588 259.7762 21.62128 260.2583 21.33112 260.7404 21.34930 261.2225 21.73288 261.7047 22.73679 262.1868 24.94418 262.6689 26.21887 263.1510 25.78064 263.6331 23.71103 264.1152 22.65741 264.5974 23.36526 265.0795 23.95242 265.5616 22.49512 266.0437 18.35843 266.5258 14.11252 267.0079 10.12756 267.4901 6.363647 267.9722 2.953003 268.4543 0.1229550 268.9364 2.936829 269.4185 5.422058 269.9006 7.395172 270.3828 9.869873 270.8649 13.10931 271.3470 16.97528 271.8291 20.76929 272.3112 24.30557 272.7933 28.37637 273.2755 33.66577 273.7576 40.34396 274.2397 46.94040 274.7218 53.09167 275.2039 59.08597 275.6860 65.67392 276.1682 72.84918 276.6503 80.90732 277.1324 89.88025 277.6145 99.60928 278.0966 111.4216 278.5787 125.8733 279.0609 141.8836 279.5430 157.5097 280.0251 172.6808 280.5072 187.5385 280.9893 202.7059 281.4715 218.0538 281.9536 231.2356 282.4357 241.9931 282.9178 250.8774 283.3999 259.3203 283.8820 267.4454 284.3642 272.7061 284.8463 273.4801 285.3284 269.9724 285.8105 264.6341 286.2926 257.2513 286.7747 248.6555 287.2569 239.0219 287.7390 228.4540 288.2211 219.9041 288.7032 214.6672 289.1853 212.4562 289.6674 211.6854 290.1496 212.2274 290.6317 214.9753 291.1138 221.7094 291.5959 232.0283 292.0780 242.6704 292.5602 251.8201 293.0423 260.9362 293.5244 274.1181 294.0065 291.4135 294.4886 310.5150 294.9707 330.2560 295.4529 350.4612 295.9350 370.0683 296.4171 389.1453 296.8992 407.4672 297.3813 424.8412 297.8634 441.1109 298.3456 455.3227 298.8277 467.0648 299.3098 476.0620 299.7919 481.4919 300.2740 482.9323 300.7561 481.0699 301.2383 476.3560 301.7204 468.9195 302.2025 459.5596 302.6846 447.9545 303.1667 434.9458 303.6488 421.5974 304.1310 408.2796 304.6131 394.3524 305.0952 378.2170 305.5773 360.9225 306.0594 345.3704 306.5415 333.0869 307.0237 323.2128 307.5058 314.6606 307.9879 307.3494 308.4700 301.6115 308.9521 297.7642 309.4343 295.6360 309.9164 294.8152 310.3985 294.8288 310.8806 296.2838 311.3627 299.3313 311.8448 303.9993 312.3270 311.1606 312.8091 321.6478 313.2912 334.5917 313.7733 349.2269 314.2554 364.8787 314.7375 382.6150 315.2197 402.9373 315.7018 425.9490 316.1839 451.0416 316.6660 477.7173 317.1481 506.8186 317.6302 538.6741 318.1124 573.4417 318.5945 610.9720 319.0766 651.9931 319.5587 695.9907 320.0408 741.8162 320.5229 790.8063 321.0051 840.7399 321.4872 890.4548 321.9693 937.5067 322.4514 986.9249 322.9335 1039.325 323.4156 1094.741 323.8978 1153.264 324.3799 1213.987 324.8620 1278.755 325.3441 1348.627 325.8262 1423.347 326.3083 1501.475 326.7905 1582.738 327.2726 1667.609 327.7547 1755.597 328.2368 1846.100 328.7189 1941.005 329.2010 2040.772 329.6832 2144.413 330.1653 2253.567 330.6474 2371.798 331.1295 2492.907 331.6116 2613.398 332.0938 2734.756 332.5759 2854.056 333.0580 2972.213 333.5401 3088.878 334.0222 3193.809 334.5043 3289.739 334.9865 3371.457 335.4686 3437.926 335.9507 3492.562 336.4328 3522.751 336.9149 3527.393 337.3970 3507.520 337.8792 3466.183 338.3613 3401.569 338.8434 3319.483 339.3255 3219.445 339.8076 3099.132 340.2898 2974.677 340.7719 2843.290 341.2540 2710.850 341.7361 2581.193 342.2182 2456.015 342.7003 2338.408 343.1825 2231.126 343.6646 2132.900 344.1467 2041.827 344.6288 1956.843 345.1109 1880.350 345.5930 1814.177 346.0752 1758.709 346.5573 1709.248 347.0394 1664.364 347.5215 1624.625 348.0036 1590.609 348.4857 1562.429 348.9679 1538.489 349.4500 1519.161 349.9321 1503.029 350.4142 1486.188 350.8963 1467.997 351.3784 1448.848 351.8606 1430.665 352.3427 1412.663 352.8248 1391.405 353.3069 1364.590 353.7890 1333.779 354.2711 1300.723 354.7533 1265.788 355.2354 1227.925 355.7175 1186.634 356.1996 1142.118 356.6817 1094.722 357.1638 1042.560 357.6460 989.0942 358.1281 936.3881 358.6102 884.6089 359.0923 832.2190 359.5744 777.3349 360.0565 722.4172 360.5387 669.8382 361.0208 620.4039 361.5029 573.0429 361.9850 527.7208 362.4671 484.3533 362.9492 443.3192 363.4314 404.3039 363.9135 367.9784 364.3956 334.9408 364.8777 305.9559 365.3598 278.3122 365.8419 250.5453 366.3241 223.9548 366.8062 200.6921 367.2883 183.2762 367.7704 167.0637 368.2526 150.7006 368.7347 133.8024 369.2168 118.5141 369.6989 104.9054 370.1810 92.79138 370.6631 81.90448 371.1453 72.56976 371.6274 63.98077 372.1095 56.13025 372.5916 48.91827 373.0737 41.90265 373.5558 34.77979 374.0380 28.21124 374.5201 22.53162 375.0022 17.98779 375.4843 13.64923 375.9664 9.311340 376.4485 5.321411 376.9307 2.651733 377.4128 1.838562 377.8949 0.1388550 378.3770 4.077942 378.8591 10.60291 379.3412 15.63123 379.8234 19.08167 380.3055 21.17981 380.7876 21.51318 381.2697 20.21423 381.7518 19.65424 382.2339 20.88739 382.7161 22.91449 383.1982 23.32275 383.6803 22.14545 384.1624 20.54218 384.6445 19.37598 385.1266 18.44177 385.6088 17.27979 386.0909 15.87299 386.5730 14.06714 387.0551 11.51233 387.5372 8.401062 388.0193 5.239319 388.5015 3.034424 388.9836 0.5440670 389.4657 3.997437 389.9478 10.74451 390.4299 17.38403 390.9120 22.23993 391.3942 26.11517 391.8763 29.91547 392.3584 32.90454 392.8405 36.90662 393.3226 42.90771 393.8047 50.74561 394.2869 59.67664 394.7690 70.45569 395.2511 81.52966 395.7332 91.79669 396.2154 100.2536 396.6975 109.6144 397.1796 120.7739 397.6617 133.2501 398.1438 146.1057 398.6259 160.4543 399.1081 174.0724 399.5902 186.1603 400.0723 196.5057 400.5544 206.8876 401.0365 218.2483 401.5186 228.9577 402.0008 237.6117 402.4829 244.0972 402.9650 248.8254 403.4471 251.7908 403.9292 253.0236 404.4113 252.4261 404.8935 249.3916 405.3756 245.9208 405.8577 243.0994 406.3398 241.1136 406.8219 238.4598 407.3040 234.7164 407.7862 231.0980 408.2683 228.9885 408.7504 228.3798 409.2325 229.8272 409.7146 233.9049 410.1967 240.0975 410.6789 247.0226 411.1610 254.6928 411.6431 263.0371 412.1252 271.9940 412.6073 281.5327 413.0894 291.6090 413.5716 302.1649 414.0537 312.9047 414.5358 323.5192 415.0179 333.9091 415.5000 344.1073 415.9821 353.9619 416.4643 363.5726 416.9464 373.2940 417.4285 383.1566 417.9106 392.0071 418.3927 398.2428 418.8748 403.3265 419.3570 408.8992 419.8391 416.9559 420.3212 424.2682 420.8033 429.6832 421.2854 433.2856 421.7675 435.6156 422.2497 435.9034 422.7318 435.6895 423.2139 435.9612 423.6960 437.7635 424.1781 438.0524 424.6602 436.7017 425.1424 433.6013 425.6245 428.6422 426.1066 422.8763 426.5887 414.0335 427.0709 400.8923 427.5530 383.4490 428.0351 366.8423 428.5172 351.7748 428.9993 336.2791 429.4814 318.6354 429.9636 298.1339 430.4457 278.2341 430.9278 259.3936 431.4099 241.1246 431.8920 221.9749 432.3741 201.4555 432.8563 182.4802 433.3384 166.4374 433.8205 153.0455 434.3026 141.1412 434.7847 130.7383 435.2668 121.1879 435.7490 111.6127 436.2311 102.0728 436.7132 93.53082 437.1953 86.48822 437.6774 80.45953 438.1595 74.62939 438.6417 69.20209 439.1238 64.71149 439.6059 61.67926 440.0880 59.43579 440.5701 57.42157 441.0522 55.69458 441.5344 54.15167 442.0165 52.16669 442.4986 50.46252 442.9807 49.95612 443.4628 51.57837 443.9449 53.87927 444.4271 56.17017 444.9092 58.62891 445.3913 62.16168 445.8734 67.63306 446.3555 73.61047 446.8376 79.44208 447.3198 85.22168 447.8019 90.46259 448.2840 95.00439 448.7661 99.09036 449.2482 103.0515 449.7303 106.9116 450.2125 110.5082 450.6946 113.9472 451.1767 117.2797 451.6588 120.1257 452.1409 122.7165 452.6230 124.1077 453.1052 123.3200 453.5873 120.2260 454.0694 117.3842 454.5515 115.0920 455.0337 112.8571 455.5158 109.4486 455.9979 104.9888 456.4800 101.9077 456.9621 101.6028 457.4442 103.1932 457.9264 104.3568 458.4085 105.1681 458.8906 107.2937 459.3727 112.2840 459.8548 119.3314 460.3369 127.3907 460.8191 136.8905 461.3012 146.2345 461.7833 153.3665 462.2654 159.3309 462.7475 166.3107 463.2296 176.1146 463.7118 186.5998 464.1939 196.4590 464.6760 205.6715 465.1581 215.4597 465.6402 225.8525 466.1223 237.1215 466.6045 249.3434 467.0866 264.3484 467.5687 277.9119 468.0508 289.2335 468.5329 299.0804 469.0150 309.3061 469.4972 320.2434 469.9793 330.9315 470.4614 341.1799 470.9435 351.0388 471.4256 359.6224 471.9077 366.8998 472.3899 372.9998 472.8720 378.1609 473.3541 382.4563 473.8362 384.8312 474.3183 385.0457 474.8004 383.5934 475.2826 381.0508 475.7647 377.3679 476.2468 373.1300 476.7289 369.2854 477.2110 365.0110 477.6931 358.0477 478.1753 348.3633 478.6574 338.3315 479.1395 330.8222 479.6216 323.9379 480.1037 314.6676 480.5858 301.1350 481.0680 287.0887 481.5501 275.2227 482.0322 264.6696 482.5143 253.7626 482.9964 241.1597 483.4786 228.7010 483.9607 217.3614 484.4428 207.3982 484.9249 197.2591 485.4070 186.1377 485.8892 175.1832 486.3713 165.2419 486.8534 157.4757 487.3355 149.1315 487.8176 139.7294 488.2997 129.8651 488.7819 120.4769 489.2640 111.2791 489.7461 103.1328 490.2282 96.66052 490.7103 91.69308 491.1924 85.96924 491.6746 79.26688 492.1567 72.41953 492.6388 66.15396 493.1209 60.37689 493.6030 55.14786 494.0851 50.46439 494.5673 46.05817 495.0494 41.46143 495.5315 36.80984 496.0136 32.78275 496.4957 29.77713 496.9778 27.47513 497.4600 25.64935 497.9421 24.24100 498.4242 22.62494 498.9063 20.24750 499.3884 17.58170 499.8705 14.90237 500.3527 12.09607 500.8348 9.786163 501.3169 8.743835 501.7990 8.241333 502.2811 7.241211 502.7632 4.655579 503.2454 2.586212 503.7275 1.830322 504.2096 2.211609 504.6917 1.706848 505.1738 0.3491210 505.6559 2.342590 506.1381 3.382111 506.6202 3.267242 507.1023 2.882050 507.5844 1.987885 508.0665 1.235931 508.5486 1.808807 509.0308 3.758453 509.5129 5.067322 509.9950 4.966675 510.4771 4.178680 510.9592 4.399811 511.4413 5.532135 511.9235 6.581268 512.4056 6.838745 512.8877 6.640198 513.3698 6.537598 513.8519 6.592865 514.3340 6.515533 514.8162 5.876007 515.2983 5.052185 515.7804 4.520294 516.2625 4.822754 516.7446 4.938385 517.2267 4.071686 517.7089 2.680786 518.1910 1.911041 518.6731 2.753235 519.1552 3.549805 519.6373 3.657745 520.1194 3.010071 520.6016 2.433044 521.0837 1.927917 521.5658 1.485046 522.0479 1.096161 522.5300 0.7479550 523.0121 0.5649410 523.4943 0.6360170 523.9764 0.7691650 524.4585 0.5926820 524.9406 8.9782998E-02 525.4227 0.4581600 525.9048 0.9907840 526.3870 1.469574 526.8691 1.803711 527.3513 1.996002 527.8334 2.083984 528.3155 2.023621 528.7976 1.906921 529.2797 1.760132 529.7618 1.513641 530.2440 1.663696 530.7261 3.376465 531.2082 5.441193 531.6903 6.280304 532.1724 3.444489 532.6545 1.355743 533.1367 1.975800 533.6188 4.583130 534.1009 6.571838 534.5830 7.313263 535.0651 7.589752 535.5472 7.512604 536.0294 6.971832 536.5115 6.922485 536.9936 7.693329 537.4757 8.513062 537.9578 8.524750 538.4399 7.446350 538.9221 7.425476 539.4042 8.941101 539.8863 11.13080 540.3684 12.56314 540.8505 13.26874 541.3326 13.62335 541.8148 13.66156 542.2969 13.52594 542.7790 13.36908 543.2611 13.23209 543.7432 13.30927 544.2253 13.61276 544.7075 14.23917 545.1896 15.28262 545.6717 16.75739 546.1538 18.66675 546.6359 22.47125 547.1180 26.10498 547.6002 27.32031 548.0823 22.45157 548.5644 18.74554 549.0465 17.98819 549.5286 19.33380 550.0107 20.30356 550.4929 20.42871 550.9750 20.91861 551.4571 22.42883 551.9392 24.99271 552.4213 26.34238 552.9034 26.26862 553.3856 25.57846 553.8677 24.68143 554.3498 23.62784 554.8319 23.00479 555.3140 22.88712 555.7961 23.16434 556.2783 23.91913 556.7604 24.97406 557.2425 25.80988 557.7246 26.03433 558.2067 26.17554 558.6888 27.09232 559.1710 28.44742 559.6531 29.06171 560.1352 27.19873 560.6173 25.38971 561.0994 25.36993 561.5815 27.49814 562.0637 29.12360 562.5458 29.43753 563.0279 29.21585 563.5100 28.98880 563.9921 28.93723 564.4742 28.73679 564.9564 28.30884 565.4385 27.88217 565.9206 27.85822 566.4027 28.25940 566.8848 28.34796 567.3669 27.82339 567.8491 27.05411 568.3312 27.20145 568.8133 28.17120 569.2954 28.73016 569.7775 27.69141 570.2596 25.90543 570.7418 24.99060 571.2239 25.03510 571.7060 24.98730 572.1881 23.63547 572.6702 22.05478 573.1523 21.48898 573.6345 22.97775 574.1166 24.07776 574.5987 23.64594 575.0808 22.37814 575.5629 21.35455 576.0450 20.85986 576.5272 20.29672 577.0093 19.73315 577.4914 19.13538 577.9735 17.84247 578.4556 15.26303 578.9377 13.17529 579.4199 12.66138 579.9020 13.75571 580.3841 14.68646 580.8662 15.52493 581.3483 15.75757 581.8304 14.17819 582.3126 11.48456 582.7947 10.16620 583.2768 10.90594 583.7589 12.44211 584.2410 14.02533 584.7231 15.35483 585.2053 15.84698 585.6874 14.64023 586.1696 13.07996 586.6517 11.74573 587.1338 10.62341 587.6159 9.634766 588.0980 8.292847 588.5801 7.559662 589.0623 8.139832 589.5444 10.34067 590.0265 11.41406 590.5086 10.84668 590.9907 9.864471 591.4728 9.342438 591.9550 9.291901 592.4371 9.530121 592.9192 10.22900 593.4013 10.76361 593.8834 10.00977 594.3655 8.165985 594.8477 6.385742 595.3298 4.935120 595.8119 3.873627 596.2940 3.390259 596.7761 3.403748 597.2582 3.617950 597.7404 3.669006 598.2225 4.004242 598.7046 5.471130 599.1867 8.052155 599.6688 9.270813 600.1509 6.727570 600.6331 3.798615 601.1152 2.727692 601.5973 4.771790 602.0794 5.820374 602.5615 5.450012 603.0436 4.483398 603.5258 3.837799 604.0079 3.596924 604.4900 3.253204 604.9721 2.662598 605.4542 1.994598 605.9363 1.484802 606.4185 1.151031 606.9006 1.218597 607.3827 2.424622 607.8648 3.704407 608.3469 2.994049 608.8290 0.6738590 609.3112 1.144897 609.7933 1.071442 610.2754 0.1382140 610.7575 1.099457 611.2396 2.625671 611.7217 3.756561 612.2039 4.232819 612.6860 4.254303 613.1681 3.944427 613.6502 2.841919 614.1323 2.231140 614.6144 2.360107 615.0966 2.775726 615.5787 2.928040 616.0608 2.844604 616.5429 2.204590 617.0250 0.7396850 617.5071 1.097290 617.9893 2.402222 618.4714 3.157776 618.9535 3.322693 619.4356 2.372925 619.9177 1.087616 620.3998 0.6014400 620.8820 0.8372190 621.3641 0.8998720 621.8462 0.4120480 622.3283 1.633820 622.8104 1.417725 623.2925 0.9462280 623.7747 2.530426 624.2568 2.317078 624.7389 1.412018 625.2210 0.6433110 625.7031 0.2210390 626.1852 0.3337100 626.6674 0.6576230 627.1495 2.064209 627.6316 2.838470 628.1137 2.978607 628.5958 2.548492 629.0779 1.353821 629.5601 0.1688540 630.0422 1.203156 630.5243 1.790985 631.0064 2.196747 631.4885 2.763733 631.9706 3.097412 632.4528 2.479645 632.9349 1.025269 633.4170 0.1558230 633.8991 1.022308 634.3812 2.274384 634.8633 2.997803 635.3455 2.649811 635.8276 3.256622 636.3097 5.612183 636.7918 8.229004 637.2739 9.933685 637.7560 10.65775 638.2382 10.48163 638.7203 9.019531 639.2024 7.374084 639.6845 7.455536 640.1666 9.044312 640.6487 10.37964 641.1309 10.82901 641.6130 10.94678 642.0951 11.44540 642.5772 12.22046 643.0594 12.94492 643.5415 13.25589 644.0236 13.64352 644.5057 14.60342 644.9879 16.05630 645.4700 17.10034 645.9521 17.41641 646.4342 17.39810 646.9163 17.18613 647.3984 16.74231 647.8806 16.49658 648.3627 16.49554 648.8448 16.61920 649.3269 16.95123 649.8090 17.49579 650.2911 17.23703 650.7733 15.92340 651.2554 14.64505 651.7375 14.78986 652.2196 15.96912 652.7017 17.28040 653.1838 18.57861 653.6660 19.71216 654.1481 20.51947 654.6302 21.08078 655.1123 21.55630 655.5944 22.26263 656.0765 22.57379 656.5587 21.82080 657.0408 20.37869 657.5229 20.05591 658.0050 21.51556 658.4871 22.88742 658.9692 23.51706 659.4514 23.49435 659.9335 23.57919 660.4156 23.79160 660.8977 23.81583 661.3798 23.40842 661.8619 22.64413 662.3441 21.61655 662.8262 20.32312 663.3083 19.12979 663.7904 18.64093 664.2725 18.27060 664.7546 17.27744 665.2368 15.19104 665.7189 13.41766 666.2010 12.35248 666.6831 11.84003 667.1652 11.74768 667.6473 12.64560 668.1295 13.12213 668.6116 12.96756 669.0937 12.42010 669.5758 11.85498 670.0579 11.24112 670.5400 10.86472 671.0222 10.88367 671.5043 11.09073 671.9864 11.05191 672.4685 10.82391 672.9506 10.68634 673.4327 10.79288 673.9149 11.02908 674.3970 11.49249 674.8791 12.08521 675.3612 12.16821 675.8433 11.03815 676.3254 9.755981 676.8076 8.882233 677.2897 8.528503 677.7718 8.686737 678.2539 9.541138 678.7360 10.55032 679.2181 11.37106 679.7003 11.99225 680.1824 13.04456 680.6645 14.53442 681.1466 16.06155 681.6287 16.99661 682.1108 17.75620 682.5930 19.46265 683.0751 22.60083 683.5572 25.84311 684.0393 27.65726 684.5214 28.94751 685.0035 31.03958 685.4857 35.32474 685.9678 39.28796 686.4499 41.80249 686.9320 43.53696 687.4141 46.07242 687.8962 50.00015 688.3784 53.68481 688.8605 56.69324 689.3426 59.26813 689.8247 62.32849 690.3068 65.89188 690.7889 69.51425 691.2711 72.93469 691.7532 76.22711 692.2353 79.43167 692.7174 82.57278 693.1995 85.84335 693.6816 89.98660 694.1638 93.72406 694.6459 95.54288 695.1280 95.36438 695.6101 96.21832 696.0922 99.44516 696.5743 103.3054 697.0565 106.9655 697.5386 110.6251 698.0207 113.5020 698.5028 115.3434 698.9849 116.9380 699.4670 119.3487 699.9492 122.4741 700.4313 124.5655 700.9135 125.2721 701.3956 125.6256 701.8777 126.6501 702.3598 128.0876 702.8419 129.4612 703.3240 130.4263 703.8062 131.7198 704.2883 134.3959 704.7704 137.4216 705.2525 139.2193 705.7346 138.1939 706.2167 137.6867 706.6989 138.3716 707.1810 139.6136 707.6631 139.8685 708.1452 138.9099 708.6273 138.2678 709.1094 138.5900 709.5916 139.3445 710.0737 139.2032 710.5558 138.3192 711.0379 137.5140 711.5200 137.2239 712.0021 137.2042 712.4843 137.8999 712.9664 138.9264 713.4485 138.3604 713.9306 133.2644 714.4127 128.4065 714.8948 126.4597 715.3770 127.4763 715.8591 127.2349 716.3412 125.2768 716.8233 122.9696 717.3054 121.1596 717.7875 119.8082 718.2697 117.9693 718.7518 115.6436 719.2339 112.8322 719.7160 108.9684 720.1981 104.8361 720.6802 101.8723 721.1624 100.3752 721.6445 98.74982 722.1266 95.92743 722.6087 92.64136 723.0908 89.52881 723.5729 86.85803 724.0551 84.03821 724.5372 80.91156 725.0193 77.76788 725.5014 75.01373 725.9835 72.77618 726.4656 70.11517 726.9478 66.87183 727.4299 63.29919 727.9120 59.49170 728.3941 55.62872 728.8762 52.50690 729.3583 50.74426 729.8405 48.90906 730.3226 45.71277 730.8047 41.64001 731.2868 37.54840 731.7689 33.12048 732.2510 29.35059 732.7332 27.17633 733.2153 25.65820 733.6974 22.72736 734.1795 17.63007 734.6616 13.24872 735.1437 10.59784 735.6259 8.886841 736.1080 5.949036 736.5901 1.924438 737.0722 1.942627 737.5543 5.467041 738.0364 8.220642 738.5186 9.071411 739.0007 8.588196 739.4828 8.768250 739.9649 10.73322 740.4470 13.29895 740.9291 16.14502 741.4113 19.22034 741.8934 22.12024 742.3755 25.02740 742.8576 27.43579 743.3397 29.23505 743.8218 30.38318 744.3040 30.11664 744.7861 28.40234 745.2682 27.11212 745.7503 27.94757 746.2324 29.84644 746.7145 31.20300 747.1967 31.97070 747.6788 32.56238 748.1609 33.54517 748.6430 34.17346 749.1251 33.78369 749.6072 32.03381 750.0894 30.73950 750.5715 30.50012 751.0536 30.02118 751.5357 28.20349 752.0178 24.78809 752.4999 23.13147 752.9821 23.48029 753.4642 23.82581 753.9463 22.13104 754.4284 19.11560 754.9105 16.31079 755.3926 13.92755 755.8748 11.16663 756.3569 7.324158 756.8390 2.942139 757.3211 1.522400 757.8032 5.548523 758.2853 10.59491 758.7675 16.86517 759.2496 23.94434 759.7318 31.65680 760.2139 39.97412 760.6960 48.59839 761.1781 57.51056 761.6602 66.51819 762.1423 74.40143 762.6245 82.28333 763.1066 93.01801 763.5887 107.4967 764.0708 123.8582 764.5529 141.3705 765.0350 159.6316 765.5172 178.1616 765.9993 196.2213 766.4814 215.3710 766.9635 235.0187 767.4456 256.1982 767.9277 280.1855 768.4099 307.3187 768.8920 336.4307 769.3741 367.4315 769.8562 400.3304 770.3383 435.5994 770.8204 473.2220 771.3026 513.2629 771.7847 556.1725 772.2668 600.6950 772.7489 645.3773 773.2310 691.4928 773.7131 740.3395 774.1953 793.4566 774.6774 848.4492 775.1595 905.0404 775.6416 963.3068 776.1237 1023.317 776.6058 1085.058 777.0880 1149.054 777.5701 1214.874 778.0522 1282.635 778.5343 1353.942 779.0164 1427.116 779.4985 1497.708 779.9807 1564.549 780.4628 1626.255 780.9449 1681.953 781.4270 1731.494 781.9091 1776.007 782.3912 1820.986 782.8734 1852.890 783.3555 1869.303 783.8376 1871.629 784.3197 1863.177 784.8018 1843.932 785.2839 1813.397 785.7661 1771.420 786.2482 1718.443 786.7303 1651.237 787.2124 1573.682 787.6945 1495.077 788.1766 1418.873 788.6588 1341.636 789.1409 1266.635 789.6230 1189.246 790.1051 1113.762 790.5872 1039.061 791.0693 969.0626 791.5515 905.3015 792.0336 846.7077 792.5157 792.0634 792.9978 741.4141 793.4799 695.3213 793.9620 653.7299 794.4442 616.3340 794.9263 582.0720 795.4084 551.2026 795.8905 524.0144 796.3726 501.8561 796.8547 482.4656 797.3369 464.2686 797.8190 447.8804 798.3011 435.1157 798.7832 426.2689 799.2653 420.1180 799.7474 416.3115 800.2296 415.0433 800.7117 416.9813 801.1938 422.1122 801.6759 429.9402 802.1580 439.9116 802.6401 453.0741 803.1223 469.6854 803.6044 490.1717 804.0865 515.4492 804.5686 545.6747 805.0507 581.2112 805.5328 621.3234 806.0150 667.1842 806.4971 722.5010 806.9792 786.6962 807.4613 862.3997 807.9434 950.0818 808.4255 1049.937 808.9077 1163.510 809.3898 1291.395 809.8719 1436.046 810.3540 1599.577 810.8361 1778.752 811.3182 1974.689 811.8004 2183.606 812.2825 2400.819 812.7646 2627.947 813.2467 2859.451 813.7288 3090.847 814.2109 3327.844 814.6931 3577.934 815.1752 3842.107 815.6573 4127.737 816.1394 4436.241 816.6215 4772.642 817.1037 5141.009 817.5858 5542.572 818.0679 5989.606 818.5500 6492.081 819.0322 7039.671 819.5143 7623.269 819.9964 8241.462 820.4785 8889.264 820.9606 9576.066 821.4427 10260.62 821.9249 10949.26 822.4070 11621.21 822.8891 12250.55 823.3712 12830.12 823.8533 13289.84 824.3354 13637.98 824.8176 13807.92 825.2997 13713.99 825.7818 13389.48 826.2639 12893.97 826.7460 12125.91 827.2281 11332.21 827.7103 10500.66 828.1924 9695.661 828.6745 8988.615 829.1566 8386.454 829.6387 7877.978 830.1208 7469.221 830.6030 7145.820 831.0851 6910.493 831.5672 6751.630 832.0493 6639.606 832.5314 6571.496 833.0135 6539.176 833.4957 6543.763 833.9778 6578.909 834.4599 6637.734 834.9420 6732.451 835.4241 6832.349 835.9063 6937.997 836.3884 7048.034 836.8705 7164.456 837.3526 7286.681 837.8347 7391.156 838.3168 7476.667 838.7990 7541.626 839.2811 7592.719 839.7632 7620.504 840.2453 7613.116 840.7274 7569.299 841.2095 7485.776 841.6917 7354.705 842.1738 7186.131 842.6559 6987.644 843.1380 6755.847 843.6201 6503.563 844.1022 6228.050 844.5844 5941.868 845.0665 5652.037 845.5486 5360.002 846.0307 5073.150 846.5128 4790.655 846.9949 4520.030 847.4771 4264.594 847.9592 4024.585 848.4413 3799.941 848.9234 3591.027 849.4055 3398.087 849.8876 3224.012 850.3698 3063.022 850.8519 2914.323 851.3340 2777.386 851.8161 2652.551 852.2982 2539.652 852.7803 2435.904 853.2625 2339.427 853.7446 2251.360 854.2267 2171.091 854.7088 2098.448 855.1909 2030.957 855.6730 1968.545 856.1552 1911.736 856.6373 1861.119 857.1194 1816.469 857.6015 1774.151 858.0836 1733.726 858.5657 1695.923 859.0479 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