#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 15:59:36 +0300 (Thu, 24 May 2018) $ #$Revision: 848 $ #$URL: svn://172.16.1.111/rod/cif/1/00/03/1000335.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000335 loop_ _publ_author_name 'Redhammer, G. J.' 'Amthauer, G.' 'Roth, G.' 'Tippelt, G.' 'Lottermoser, W.' _publ_section_title ; Single crystal X-ray diffraction and temperature dependent 57Fe Mossbauer spectroscopy on the hedenbergite - aegirine (Ca,Na)(Fe2+,Fe3+)Si2O6 solid solution Locality: synthetic Sample: Hd21, T = 298 K ; _journal_name_full 'American Mineralogist' _journal_page_first 1271 _journal_page_last 1292 _journal_paper_doi 10.2138/am.2006.2173 _journal_volume 91 _journal_year 2006 _chemical_compound_source R120167 _chemical_formula_sum 'Ca Fe O6 Si2' _chemical_name_mineral Hedenbergite _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90 _cell_angle_beta 104.775 _cell_angle_gamma 90 _cell_length_a 9.8450 _cell_length_b 9.0293 _cell_length_c 5.2450 _cell_volume 450.830 _diffrn_ambient_temperature 298 _exptl_crystal_density_diffrn 3.655 _cod_original_formula_sum 'Ca Fe Si2 O6' _cod_database_code 9010072 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R120167.rod _rod_data_source.block 3500000 _rod_database.code 1000335 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9010072 COD http://www.crystallography.net/cod/9010072.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 175.1784 0.0000000E+00 175.6605 2.349640 176.1426 0.4603880 176.6248 20.83722 177.1069 51.09766 177.5890 87.22882 178.0711 128.0930 178.5532 175.9246 179.0353 228.4905 179.5175 277.5774 179.9996 328.3124 180.4817 370.9415 180.9638 383.7591 181.4459 357.8737 181.9280 317.8386 182.4102 287.3043 182.8923 267.9852 183.3744 267.5163 183.8565 291.2894 184.3386 337.8582 184.8207 401.5990 185.3029 481.0421 185.7850 579.2961 186.2671 700.7296 186.7492 845.2434 187.2313 1018.909 187.7134 1225.955 188.1956 1467.049 188.6777 1736.706 189.1598 2041.493 189.6419 2370.408 190.1240 2714.891 190.6061 3080.967 191.0883 3421.955 191.5704 3754.072 192.0525 4064.577 192.5346 4195.479 193.0167 4104.863 193.4988 3824.446 193.9810 3399.604 194.4631 2815.939 194.9452 2237.483 195.4273 1765.895 195.9094 1398.048 196.3915 1106.701 196.8737 894.0118 197.3558 748.0986 197.8379 631.4948 198.3200 546.1381 198.8021 480.6331 199.2842 427.3563 199.7664 385.8293 200.2485 354.7761 200.7306 336.0411 201.2127 327.7842 201.6948 321.8036 202.1769 317.7323 202.6591 317.2992 203.1412 322.7010 203.6233 334.4233 204.1054 349.6424 204.5875 365.9557 205.0696 383.9894 205.5518 408.6646 206.0339 439.5315 206.5160 477.2224 206.9981 521.2731 207.4802 570.3353 207.9623 628.5015 208.4445 696.6002 208.9266 775.2368 209.4087 862.0829 209.8908 959.1868 210.3729 1061.284 210.8550 1165.929 211.3372 1276.889 211.8193 1376.194 212.3014 1468.774 212.7835 1554.593 213.2656 1582.762 213.7477 1548.373 214.2299 1464.551 214.7120 1339.837 215.1941 1157.153 215.6762 978.2310 216.1583 813.1136 216.6404 662.4614 217.1226 535.7549 217.6047 435.0142 218.0868 355.2422 218.5689 290.4293 219.0510 243.1691 219.5331 204.0330 220.0153 170.6382 220.4974 143.0042 220.9795 119.5611 221.4616 100.7180 221.9437 85.34518 222.4258 71.97800 222.9080 61.27252 223.3901 51.31989 223.8722 41.70386 224.3543 32.20053 224.8364 24.04373 225.3185 17.34439 225.8007 11.93753 226.2828 7.781219 226.7649 5.731903 227.2470 3.231964 227.7291 0.5690000 228.2112 5.996216 228.6934 10.58829 229.1755 14.18729 229.6576 17.11493 230.1397 19.64673 230.6218 21.46652 231.1039 23.54242 231.5861 26.25320 232.0682 29.80927 232.5503 32.64719 233.0324 34.18277 233.5145 35.08179 233.9966 35.81314 234.4788 37.05826 234.9609 37.43488 235.4430 36.34262 235.9251 33.49039 236.4072 31.41818 236.8893 30.42075 237.3715 29.99512 237.8536 29.56577 238.3357 29.27908 238.8178 28.78528 239.2999 28.06873 239.7820 27.19171 240.2642 25.68604 240.7463 23.16733 241.2284 20.37152 241.7105 18.18561 242.1926 16.77924 242.6747 15.71683 243.1569 15.03857 243.6390 14.84457 244.1211 14.26868 244.6032 13.43634 245.0853 12.12186 245.5674 9.981873 246.0496 6.554047 246.5317 3.140381 247.0138 3.4637000E-02 247.4959 2.741211 247.9780 5.587067 248.4601 8.293762 248.9423 11.30600 249.4244 15.30942 249.9065 21.27847 250.3886 26.31363 250.8707 29.48676 251.3528 30.66348 251.8350 32.57874 252.3171 35.18796 252.7992 38.54929 253.2813 42.86322 253.7634 48.58200 254.2455 54.13989 254.7277 59.05621 255.2098 63.32654 255.6919 68.19482 256.1740 73.35114 256.6561 79.45731 257.1382 87.15845 257.6204 96.98227 258.1025 107.2165 258.5846 117.2714 259.0667 127.2414 259.5488 138.6298 260.0309 151.5995 260.5131 165.3836 260.9952 179.0585 261.4773 192.5532 261.9594 206.4936 262.4415 221.1904 262.9236 236.5905 263.4058 250.8405 263.8879 264.6089 264.3700 276.3994 264.8521 285.3121 265.3342 291.0087 265.8163 294.4894 266.2985 294.7760 266.7806 292.7964 267.2627 293.7321 267.7448 297.4632 268.2269 304.3572 268.7090 314.7398 269.1912 328.9171 269.6733 345.9391 270.1554 366.2402 270.6375 389.2345 271.1196 411.7560 271.6017 433.4579 272.0839 455.5366 272.5660 478.5267 273.0481 502.7846 273.5302 526.7341 274.0123 551.7247 274.4944 575.6252 274.9766 592.9063 275.4587 603.5469 275.9408 607.7256 276.4229 605.1836 276.9050 595.8706 277.3871 581.0433 277.8693 560.6959 278.3514 535.0356 278.8335 503.2700 279.3156 464.1950 279.7977 424.4662 280.2798 386.8044 280.7620 351.5031 281.2441 318.9270 281.7262 289.0757 282.2083 261.9637 282.6904 237.7419 283.1725 216.3404 283.6547 197.1868 284.1368 179.9328 284.6189 164.7914 285.1010 151.9190 285.5831 141.2037 286.0652 132.5902 286.5474 126.7181 287.0295 123.6088 287.5116 121.3650 287.9937 119.0128 288.4758 116.8293 288.9579 116.1666 289.4401 117.1171 289.9222 118.8721 290.4043 120.8183 290.8864 122.9849 291.3685 125.1340 291.8506 127.3773 292.3328 129.4482 292.8149 130.9928 293.2970 132.2444 293.7791 131.8597 294.2612 127.9510 294.7433 120.9073 295.2255 112.3734 295.7076 102.5054 296.1897 91.72955 296.6718 80.82574 297.1539 69.84821 297.6360 59.16022 298.1182 48.77441 298.6003 39.04901 299.0824 30.50891 299.5645 23.05859 300.0466 16.98706 300.5287 12.92914 301.0109 10.74658 301.4930 9.600159 301.9751 8.765686 302.4572 8.653992 302.9393 9.979736 303.4214 13.17401 303.9036 17.64325 304.3857 22.44257 304.8678 27.78247 305.3499 34.66327 305.8320 44.76776 306.3141 56.26373 306.7963 66.67010 307.2784 75.40576 307.7605 83.89832 308.2426 94.25745 308.7247 105.2986 309.2068 114.2526 309.6890 119.2319 310.1711 121.7772 310.6532 123.2070 311.1353 123.7965 311.6174 122.5392 312.0995 118.3094 312.5817 111.8527 313.0638 104.3569 313.5459 94.08368 314.0280 84.51508 314.5101 77.84515 314.9922 74.32324 315.4744 72.26825 315.9565 70.50830 316.4386 69.96973 316.9207 71.70087 317.4028 76.04840 317.8849 82.72345 318.3671 91.49390 318.8492 102.4527 319.3313 115.9393 319.8134 131.8232 320.2955 150.4985 320.7776 172.0567 321.2598 197.2830 321.7419 224.7532 322.2240 253.2896 322.7061 283.4240 323.1882 317.9724 323.6703 359.2126 324.1525 403.9730 324.6346 450.0370 325.1167 496.2715 325.5988 545.4907 326.0809 597.4003 326.5630 652.4193 327.0452 711.9462 327.5273 776.0307 328.0094 843.9888 328.4915 915.6330 328.9736 989.1185 329.4557 1068.582 329.9379 1153.587 330.4200 1245.127 330.9021 1343.084 331.3842 1445.240 331.8663 1557.562 332.3484 1682.744 332.8306 1818.818 333.3127 1965.138 333.7948 2121.993 334.2769 2289.490 334.7590 2466.286 335.2411 2655.844 335.7233 2850.495 336.2054 3049.386 336.6875 3253.462 337.1696 3452.369 337.6517 3651.872 338.1339 3834.791 338.6160 3988.961 339.0981 4119.045 339.5802 4203.537 340.0623 4240.526 340.5444 4228.422 341.0266 4157.204 341.5087 4021.226 341.9908 3849.533 342.4729 3648.659 342.9550 3420.428 343.4371 3193.941 343.9193 2971.247 344.4014 2755.522 344.8835 2556.118 345.3656 2373.049 345.8477 2204.594 346.3298 2053.837 346.8120 1917.131 347.2941 1784.880 347.7762 1655.296 348.2583 1532.121 348.7404 1417.702 349.2225 1312.481 349.7047 1218.289 350.1868 1135.075 350.6689 1063.894 351.1510 1006.072 351.6331 961.8591 352.1152 928.9827 352.5974 907.0497 353.0795 894.9128 353.5616 890.6461 354.0437 894.5756 354.5258 904.9849 355.0079 920.5801 355.4901 941.3270 355.9722 967.2102 356.4543 997.7783 356.9364 1033.644 357.4185 1075.421 357.9006 1122.532 358.3828 1177.292 358.8649 1241.048 359.3470 1313.872 359.8291 1396.305 360.3112 1486.497 360.7933 1587.818 361.2755 1703.399 361.7576 1833.811 362.2397 1975.376 362.7218 2128.451 363.2039 2291.538 363.6860 2462.800 364.1682 2652.948 364.6503 2841.653 365.1324 3024.215 365.6145 3201.396 366.0966 3358.003 366.5787 3509.660 367.0609 3628.685 367.5430 3697.368 368.0251 3722.608 368.5072 3686.902 368.9893 3574.057 369.4714 3397.481 369.9536 3200.638 370.4357 2964.225 370.9178 2727.558 371.3999 2506.071 371.8820 2294.522 372.3641 2106.694 372.8463 1943.974 373.3284 1806.062 373.8105 1691.931 374.2926 1604.164 374.7747 1534.157 375.2568 1479.580 375.7390 1440.247 376.2211 1414.296 376.7032 1402.115 377.1853 1401.949 377.6674 1412.515 378.1495 1434.229 378.6317 1463.947 379.1138 1501.484 379.5959 1546.511 380.0780 1600.741 380.5601 1664.448 381.0422 1731.722 381.5244 1800.509 382.0065 1870.463 382.4886 1937.093 382.9707 2001.827 383.4528 2059.491 383.9349 2107.744 384.4171 2145.013 384.8992 2163.218 385.3813 2161.618 385.8634 2137.933 386.3455 2085.340 386.8276 2003.401 387.3098 1903.733 387.7919 1787.302 388.2740 1659.764 388.7561 1532.083 389.2382 1403.702 389.7203 1279.032 390.2025 1162.405 390.6846 1054.306 391.1667 953.6453 391.6488 860.5567 392.1309 775.4982 392.6130 698.7041 393.0952 631.8665 393.5773 571.8657 394.0594 519.3983 394.5415 473.3694 395.0236 431.7238 395.5057 394.8464 395.9879 361.3736 396.4700 331.0278 396.9521 303.9496 397.4342 279.0117 397.9163 256.3518 398.3984 235.5687 398.8806 216.3155 399.3627 198.2411 399.8448 182.1177 400.3269 168.8291 400.8090 157.8949 401.2911 146.1370 401.7733 132.0650 402.2554 118.8009 402.7375 108.0752 403.2196 100.7980 403.7017 93.77866 404.1838 87.08231 404.6660 80.60461 405.1481 74.29260 405.6302 68.04306 406.1123 62.18970 406.5944 56.89185 407.0765 52.10788 407.5587 47.53296 408.0408 43.11774 408.5229 38.96213 409.0050 35.14749 409.4871 31.68805 409.9692 28.61194 410.4514 26.12650 410.9335 23.74429 411.4156 20.05243 411.8977 15.23145 412.3798 10.90414 412.8619 8.588013 413.3441 7.514923 413.8262 6.231323 414.3083 4.587646 414.7904 2.659698 415.2725 0.2013240 415.7546 2.491150 416.2368 4.897034 416.7189 6.841797 417.2010 8.311829 417.6831 9.309052 418.1652 9.820801 418.6473 9.924286 419.1295 8.775330 419.6116 7.669434 420.0937 7.820190 420.5758 10.43909 421.0579 13.02887 421.5400 15.08023 422.0222 16.54099 422.5043 17.36685 422.9864 17.11093 423.4685 16.56339 423.9506 15.98193 424.4327 15.34378 424.9149 14.79617 425.3970 15.08002 425.8791 15.05811 426.3612 13.40430 426.8433 7.818542 427.3254 4.361938 427.8076 4.679504 428.2897 8.145050 428.7718 10.16211 429.2539 10.23834 429.7360 9.832458 430.2181 9.741669 430.7003 10.00067 431.1824 10.46011 431.6645 11.27209 432.1466 12.01199 432.6287 11.81839 433.1108 10.66827 433.5930 9.423126 434.0751 8.282227 434.5572 7.303558 435.0393 6.719604 435.5214 6.527802 436.0035 6.577454 436.4857 6.908234 436.9678 7.368896 437.4499 7.606506 437.9320 7.506836 438.4141 7.235443 438.8962 6.961639 439.3784 6.667297 439.8605 6.292999 440.3426 5.635101 440.8247 4.999634 441.3068 4.766449 441.7889 5.017975 442.2711 5.034088 442.7532 4.013489 443.2353 2.751495 443.7174 2.073547 444.1995 3.125244 444.6816 3.830994 445.1638 3.638153 445.6459 2.624023 446.1280 1.181274 446.6101 1.542664 447.0922 3.934753 447.5743 5.212280 448.0565 4.827393 448.5386 4.662628 449.0207 4.556580 449.5028 4.776245 449.9849 5.752411 450.4670 7.898682 450.9492 9.903198 451.4313 11.50156 451.9134 12.72485 452.3955 13.79556 452.8776 14.80826 453.3597 15.31375 453.8419 14.37711 454.3240 12.08191 454.8061 11.69696 455.2882 13.73373 455.7703 17.13077 456.2524 20.69205 456.7346 24.36279 457.2167 27.44360 457.6988 29.29636 458.1809 30.57538 458.6630 32.51428 459.1451 35.05609 459.6273 37.62277 460.1094 39.88962 460.5915 41.84763 461.0736 43.50067 461.5557 44.92422 462.0378 45.92154 462.5200 46.03479 463.0021 45.66293 463.4842 45.57718 463.9663 46.50726 464.4484 47.43021 464.9305 47.73236 465.4127 47.34088 465.8948 47.22971 466.3769 48.54865 466.8590 49.65112 467.3411 49.33344 467.8232 45.48074 468.3054 42.89392 468.7875 42.01126 469.2696 42.44519 469.7517 43.34402 470.2338 44.91150 470.7159 46.55219 471.1981 48.09372 471.6802 49.53702 472.1623 50.72519 472.6444 51.49380 473.1265 52.39023 473.6086 54.00201 474.0908 56.29099 474.5729 58.30020 475.0550 59.58139 475.5371 60.95255 476.0192 64.13025 476.5013 68.99481 476.9835 74.34134 477.4656 79.20663 477.9477 84.15024 478.4298 89.93597 478.9119 96.60007 479.3940 104.2722 479.8762 112.8464 480.3583 122.6402 480.8404 134.0814 481.3225 147.4537 481.8046 162.4235 482.2867 178.8751 482.7689 196.8004 483.2510 216.1332 483.7331 237.4874 484.2152 259.9677 484.6973 282.8985 485.1794 305.6490 485.6616 331.3881 486.1437 360.9165 486.6258 393.0148 487.1079 427.0630 487.5900 462.3511 488.0721 501.1319 488.5543 542.9897 489.0364 588.5259 489.5185 639.2309 490.0006 694.6932 490.4827 755.2707 490.9648 820.4135 491.4470 890.3607 491.9291 965.8635 492.4112 1046.897 492.8933 1131.714 493.3754 1218.874 493.8575 1308.454 494.3397 1400.847 494.8218 1498.015 495.3039 1592.830 495.7860 1682.504 496.2681 1762.283 496.7502 1815.571 497.2324 1837.028 497.7145 1826.267 498.1966 1780.686 498.6787 1699.849 499.1608 1595.509 499.6429 1456.157 500.1251 1304.967 500.6072 1158.251 501.0893 1014.676 501.5714 885.4449 502.0535 771.2028 502.5356 672.3150 503.0178 588.8445 503.4999 526.8093 503.9820 472.3686 504.4641 422.8899 504.9462 378.1973 505.4283 340.0485 505.9105 310.0877 506.3926 284.4271 506.8747 259.9244 507.3568 236.2201 507.8389 217.0287 508.3210 203.7575 508.8032 193.9388 509.2853 183.6826 509.7674 173.0299 510.2495 162.9506 510.7316 153.4082 511.2137 144.7810 511.6959 138.1502 512.1780 133.4294 512.6601 129.0943 513.1422 123.5344 513.6243 117.9349 514.1064 113.6536 514.5886 110.8127 515.0707 109.7373 515.5528 111.8540 516.0349 115.5652 516.5170 118.5915 516.9991 119.1007 517.4813 119.9567 517.9634 122.0348 518.4455 125.2996 518.9276 129.2462 519.4097 133.4068 519.8918 138.6079 520.3740 145.1111 520.8561 152.9893 521.3382 161.9219 521.8203 171.5354 522.3024 182.6281 522.7845 196.4586 523.2667 213.3108 523.7488 231.2030 524.2309 249.3157 524.7130 268.3705 525.1951 290.0393 525.6772 314.4508 526.1594 342.3331 526.6415 374.5557 527.1236 410.8369 527.6057 450.1310 528.0878 492.2341 528.5699 537.5734 529.0521 585.3698 529.5342 636.4276 530.0163 691.8538 530.4984 751.7015 530.9805 815.5107 531.4626 881.8990 531.9448 951.7131 532.4269 1026.267 532.9090 1105.132 533.3911 1190.226 533.8732 1282.385 534.3553 1380.859 534.8375 1489.282 535.3196 1606.670 535.8017 1733.778 536.2838 1870.548 536.7659 2018.748 537.2480 2175.023 537.7302 2337.799 538.2123 2510.300 538.6944 2697.058 539.1765 2900.796 539.6586 3104.347 540.1407 3304.936 540.6229 3498.734 541.1050 3678.732 541.5871 3842.693 542.0692 3966.745 542.5513 4047.765 543.0334 4076.249 543.5156 4035.078 543.9977 3923.279 544.4798 3759.711 544.9619 3534.606 545.4440 3275.527 545.9261 3011.015 546.4083 2736.001 546.8904 2475.015 547.3725 2234.149 547.8546 2015.853 548.3367 1820.004 548.8188 1649.838 549.3010 1499.519 549.7831 1369.039 550.2652 1258.299 550.7473 1160.512 551.2294 1076.274 551.7115 1003.743 552.1937 941.9772 552.6758 891.5234 553.1579 847.6385 553.6400 810.8228 554.1221 778.7842 554.6042 748.2363 555.0864 719.5383 555.5685 695.0070 556.0506 676.0635 556.5327 661.0468 557.0148 648.9764 557.4969 639.2564 557.9791 629.6132 558.4612 618.9346 558.9433 607.7347 559.4254 596.8271 559.9075 586.2341 560.3896 574.6360 560.8718 563.1874 561.3539 549.5624 561.8360 531.9177 562.3181 507.0304 562.8002 482.7091 563.2823 460.1028 563.7645 438.1161 564.2466 414.9989 564.7287 390.3228 565.2108 365.8305 565.6929 341.5188 566.1750 317.8903 566.6572 295.8921 567.1393 275.5582 567.6214 257.2703 568.1035 241.3008 568.5856 227.5648 569.0677 215.2769 569.5499 204.5703 570.0320 194.5084 570.5141 184.3114 570.9962 174.2321 571.4783 164.6251 571.9604 155.0909 572.4426 147.0175 572.9247 142.3947 573.4068 139.5021 573.8889 135.2003 574.3710 125.7994 574.8531 117.8371 575.3353 114.6102 575.8174 115.7369 576.2995 114.7130 576.7816 110.0043 577.2637 104.7832 577.7458 100.2411 578.2280 96.39880 578.7101 93.39792 579.1922 91.48071 579.6743 89.76614 580.1564 87.24139 580.6385 84.00830 581.1207 81.18695 581.6028 79.15231 582.0849 77.22183 582.5670 74.04260 583.0491 70.08331 583.5313 66.67056 584.0134 64.79654 584.4955 63.54291 584.9776 61.90344 585.4597 60.04379 585.9418 58.91647 586.4240 60.49142 586.9061 61.76450 587.3882 60.69241 587.8703 56.33743 588.3524 52.47488 588.8345 49.47412 589.3167 47.18616 589.7988 45.65576 590.2809 45.60495 590.7630 44.61310 591.2451 42.32809 591.7272 39.19327 592.2094 35.69104 592.6915 31.77600 593.1736 28.83212 593.6557 27.69125 594.1378 27.59360 594.6199 26.89557 595.1021 25.61966 595.5842 23.84558 596.0663 21.37915 596.5484 18.58109 597.0305 15.68332 597.5126 12.69055 597.9948 10.06656 598.4769 8.063141 598.9590 6.586273 599.4411 5.615448 599.9232 5.943909 600.4053 5.462616 600.8875 2.999847 601.3696 0.1326600 601.8517 2.064819 602.3338 2.179993 602.8159 2.244232 603.2980 2.502808 603.7802 2.968231 604.2623 3.879425 604.7444 5.311371 605.2265 6.458130 605.7086 6.610016 606.1907 6.143707 606.6729 6.590607 607.1550 7.927887 607.6371 9.030975 608.1192 8.777954 608.6013 7.830383 609.0834 6.926758 609.5656 6.093872 610.0477 5.716461 610.5298 6.382202 611.0119 7.448914 611.4940 8.210236 611.9761 8.480804 612.4583 8.426239 612.9404 7.910217 613.4225 7.099792 613.9046 6.339508 614.3867 5.577545 614.8688 4.974640 615.3510 4.630951 615.8331 4.495026 616.3152 4.186005 616.7973 3.679657 617.2794 3.301483 617.7615 3.644287 618.2437 4.274689 618.7258 3.615295 619.2079 1.528137 619.6900 0.1586610 620.1721 0.6904300 620.6542 2.622192 621.1364 3.815552 621.6185 3.750946 622.1006 3.172272 622.5827 1.862549 623.0648 0.3991090 623.5469 0.4108280 624.0291 0.3200990 624.5112 0.7778630 624.9933 0.4701230 625.4754 0.2918090 625.9575 0.4049990 626.4396 0.3082280 626.9218 1.146515 627.4039 1.984100 627.8860 2.739746 628.3681 2.701508 628.8502 1.834656 629.3323 1.132904 629.8145 1.998199 630.2966 3.389862 630.7787 2.930817 631.2608 0.2459410 631.7429 2.174316 632.2250 2.118073 632.7072 0.9714360 633.1893 0.2167660 633.6714 0.3722230 634.1535 0.6874080 634.6356 1.005615 635.1177 1.356293 635.5999 1.765015 636.0820 1.992706 636.5641 2.698975 637.0462 4.244720 637.5283 6.275635 638.0104 7.497284 638.4926 7.769592 638.9747 8.202576 639.4568 9.581238 639.9389 11.47098 640.4210 12.10583 640.9031 11.57504 641.3853 11.30569 641.8674 12.77942 642.3495 14.88315 642.8316 16.09070 643.3137 16.12451 643.7958 16.54633 644.2780 18.89337 644.7601 21.56540 645.2422 23.07962 645.7243 21.43588 646.2064 21.40265 646.6885 24.26865 647.1707 28.18524 647.6528 30.52533 648.1349 30.64743 648.6170 31.34613 649.0991 33.32892 649.5812 35.99786 650.0634 37.86859 650.5455 39.00690 651.0276 40.29263 651.5097 42.17227 651.9918 44.44284 652.4739 47.09964 652.9561 49.97064 653.4382 52.31378 653.9203 52.95145 654.4024 53.44110 654.8845 54.95233 655.3666 57.69916 655.8488 60.27359 656.3309 61.99268 656.8130 63.75806 657.2951 66.03189 657.7772 68.74664 658.2593 72.28745 658.7415 77.13995 659.2236 82.06961 659.7057 85.15881 660.1878 86.47083 660.6699 89.13190 661.1520 93.81128 661.6342 99.63358 662.1163 105.6415 662.5984 111.7650 663.0805 117.8577 663.5626 123.2711 664.0447 129.3392 664.5269 137.2800 665.0090 146.5307 665.4911 155.7969 665.9732 164.2355 666.4553 173.2236 666.9374 183.3436 667.4196 194.5832 667.9017 206.0074 668.3838 217.2728 668.8659 229.3779 669.3480 243.0820 669.8301 258.4073 670.3123 274.1694 670.7944 290.5025 671.2765 307.0031 671.7586 322.8749 672.2407 338.9448 672.7228 357.2010 673.2050 378.4200 673.6871 399.4144 674.1692 417.8910 674.6513 435.0900 675.1334 452.3238 675.6155 472.0171 676.0977 488.8274 676.5798 502.1751 677.0619 511.5738 677.5440 516.0040 678.0261 514.7290 678.5082 509.6257 678.9904 501.3919 679.4725 489.4365 679.9546 470.8330 680.4367 445.9081 680.9188 418.6695 681.4009 390.5804 681.8831 361.5128 682.3652 330.8220 682.8473 299.0277 683.3294 269.9883 683.8115 246.7724 684.2936 226.0533 684.7758 204.2371 685.2579 181.3398 685.7400 161.6545 686.2221 148.1326 686.7042 137.0516 687.1863 126.3014 687.6685 115.5935 688.1506 106.1906 688.6327 98.38013 689.1148 91.46701 689.5969 84.69064 690.0790 77.87720 690.5612 71.32697 691.0433 65.08566 691.5254 59.23038 692.0075 53.80103 692.4896 48.91959 692.9717 44.88702 693.4539 41.92526 693.9360 39.55582 694.4181 37.78128 694.9002 36.44879 695.3823 35.26880 695.8644 34.92142 696.3466 33.69824 696.8287 30.84940 697.3108 27.14059 697.7929 24.73788 698.2750 24.06036 698.7571 23.12027 699.2393 21.11044 699.7214 18.48734 700.2035 16.62854 700.6856 15.48389 701.1677 14.70297 701.6498 14.17078 702.1320 13.83173 702.6141 13.65271 703.0962 13.61691 703.5783 13.64310 704.0604 13.70599 704.5425 13.79123 705.0247 14.08173 705.5068 14.78583 705.9889 14.29095 706.4710 11.58490 706.9531 8.976074 707.4352 8.157135 707.9174 9.332001 708.3995 9.987579 708.8816 10.04547 709.3637 9.779633 709.8458 9.491943 710.3279 9.107117 710.8101 8.105469 711.2922 6.054352 711.7743 4.989105 712.2564 8.221893 712.7385 12.61395 713.2206 14.32590 713.7028 9.379395 714.1849 5.786316 714.6670 6.312256 715.1491 8.493042 715.6312 8.886688 716.1133 6.494659 716.5955 5.155151 717.0776 5.757111 717.5597 7.477875 718.0418 8.576355 718.5239 9.122314 719.0060 9.810425 719.4882 11.23053 719.9703 12.58353 720.4524 12.72891 720.9345 11.96213 721.4166 11.16483 721.8987 10.72656 722.3809 10.35117 722.8630 9.997131 723.3451 9.641632 723.8272 9.051422 724.3093 8.074493 724.7914 7.054077 725.2736 5.933746 725.7557 4.816406 726.2378 5.090820 726.7199 6.930939 727.2020 8.718079 727.6841 9.417542 728.1663 9.284271 728.6484 8.643036 729.1305 7.575165 729.6126 6.858307 730.0947 7.413147 730.5768 8.181702 731.0590 8.186157 731.5411 7.066101 732.0232 6.600983 732.5053 7.860901 732.9874 9.214142 733.4695 9.655212 733.9517 8.863159 734.4338 8.343140 734.9159 8.111725 735.3980 7.992798 735.8801 7.690826 736.3622 7.369080 736.8444 7.798523 737.3265 9.224823 737.8086 10.45035 738.2907 10.04208 738.7728 8.941986 739.2549 8.379089 739.7371 9.051025 740.2192 9.733643 740.7013 9.719177 741.1834 9.552795 741.6655 10.21713 742.1476 12.49759 742.6298 13.71915 743.1119 13.08005 743.5940 11.78497 744.0761 12.31906 744.5582 14.49652 745.0403 16.25635 745.5225 16.74884 746.0046 17.07492 746.4867 18.94742 746.9688 21.48074 747.4509 22.95853 747.9330 21.11270 748.4152 19.75250 748.8973 20.69189 749.3794 23.41357 749.8615 25.88379 750.3436 28.12842 750.8257 29.79398 751.3079 30.56287 751.7900 30.88138 752.2721 32.51089 752.7542 35.47858 753.2363 37.96933 753.7184 38.51059 754.2006 38.31522 754.6827 39.28735 755.1648 41.34018 755.6469 43.69669 756.1290 46.62378 756.6111 48.93631 757.0933 49.95560 757.5754 49.80154 758.0575 49.77875 758.5396 49.71875 759.0217 50.00406 759.5038 51.16876 759.9860 52.97565 760.4681 52.66470 760.9502 50.10175 761.4323 46.99103 761.9144 44.33020 762.3965 41.89960 762.8787 39.31143 763.3608 36.65222 763.8429 34.07248 764.3250 31.25369 764.8071 28.79587 765.2892 27.34494 765.7714 27.13852 766.2535 26.86517 766.7356 26.23080 767.2177 25.63898 767.6998 25.37695 768.1819 25.54233 768.6641 25.08163 769.1462 23.94748 769.6283 22.76321 770.1104 21.81702 770.5925 21.20071 771.0746 21.26740 771.5568 22.07166 772.0389 22.88409 772.5210 23.63550 773.0031 24.00220 773.4852 23.59335 773.9673 21.94754 774.4495 20.76965 774.9316 20.14578 775.4137 19.99863 775.8958 20.49353 776.3779 21.74121 776.8600 22.07242 777.3422 21.36212 777.8243 20.22141 778.3064 18.73929 778.7885 17.39664 779.2706 17.38705 779.7527 19.15402 780.2349 20.63486 780.7170 20.05261 781.1991 18.95251 781.6812 18.84402 782.1633 21.64029 782.6454 21.87570 783.1276 18.17145 783.6097 13.54019 784.0918 10.86493 784.5739 10.17706 785.0560 10.78928 785.5381 12.95609 786.0203 14.63242 786.5024 12.46814 786.9845 8.527985 787.4666 6.567383 787.9487 8.020355 788.4308 9.523651 788.9130 9.175720 789.3951 8.176544 789.8772 7.802948 790.3593 8.979340 790.8414 9.213715 791.3235 8.002838 791.8057 6.491821 792.2878 6.295227 792.7699 7.295258 793.2520 7.386902 793.7341 6.013947 794.2162 4.872894 794.6984 6.738098 795.1805 9.789124 795.6626 11.07248 796.1447 9.349426 796.6268 7.065643 797.1089 4.117279 797.5911 1.582306 798.0732 0.7228090 798.5553 2.627319 799.0374 3.553680 799.5195 3.018951 800.0016 2.042908 800.4838 2.090820 800.9659 2.929077 801.4480 3.247437 801.9301 2.788940 802.4122 1.893677 802.8943 0.3263850 803.3765 1.275330 803.8586 2.050293 804.3407 1.333282 804.8228 0.6059270 805.3049 1.9409001E-02 805.7870 0.3957210 806.2692 0.2498470 806.7513 0.7004390 807.2334 0.9688720 807.7155 0.2523190 808.1976 0.6498110 808.6797 0.7189330 809.1619 0.1234130 809.6440 0.7379760 810.1261 1.906952 810.6082 2.844360 811.0903 2.946045 811.5724 2.692902 812.0546 2.647644 812.5367 3.750092 813.0188 3.534119 813.5009 0.7673340 813.9830 2.221344 814.4651 2.591766 814.9473 0.1639400 815.4294 1.658722 815.9115 2.518188 816.3936 2.798767 816.8757 2.751312 817.3578 2.487122 817.8400 2.203339 818.3221 1.969452 818.8042 1.621704 819.2863 0.8079530 819.7684 1.1047000E-02 820.2505 0.2352600 820.7327 0.6668700 821.2148 0.7438960 821.6969 0.4246830 822.1790 1.637573 822.6611 1.310547 823.1432 0.2589420 823.6254 1.228729 824.1075 1.405609 824.5896 0.9905400 825.0717 0.5409850 825.5538 2.202301 826.0359 2.670990 826.5181 1.256073 827.0002 0.3208620 827.4823 0.5769650 827.9644 1.376770 828.4465 2.477570 828.9286 4.072601 829.4108 4.908966 829.8929 4.828766 830.3750 4.689056 830.8571 5.512054 831.3392 6.831665 831.8214 7.447937 832.3035 7.196808 832.7856 7.384888 833.2677 8.950928 833.7498 11.10291 834.2319 13.47717 834.7141 16.33743 835.1962 17.88004 835.6783 17.25760 836.1604 16.66351 836.6425 17.74246 837.1246 20.30154 837.6068 21.95502 838.0889 22.70883 838.5710 23.72406 839.0531 26.60327 839.5352 29.84918 840.0173 31.48892 840.4995 31.36517 840.9816 31.66812 841.4637 33.75809 841.9458 35.96750 842.4279 37.32907 842.9100 37.89294 843.3922 39.99161 843.8743 43.81705 844.3564 48.03830 844.8385 52.23465 845.3206 56.16321 845.8027 58.73730 846.2849 60.27502 846.7670 62.49155 847.2491 66.63260 847.7312 71.47702 848.2133 76.50040 848.6954 81.68262 849.1776 86.92389 849.6597 92.34894 850.1418 97.64426 850.6239 102.4004 851.1060 107.0684 851.5881 113.4727 852.0703 121.4026 852.5524 129.1023 853.0345 135.0002 853.5166 140.7628 853.9987 148.1465 854.4808 156.6273 854.9630 164.9268 855.4451 171.5753 855.9272 179.2968 856.4093 189.5399 856.8914 200.7406 857.3735 209.4257 857.8557 215.3185 858.3378 222.3470 858.8199 231.9045 859.3020 242.5585 859.7841 252.1779 860.2662 261.2121 860.7484 270.3925 861.2305 280.3424 861.7126 289.9089 862.1947 298.0695 862.6768 305.9090 863.1589 314.9644 863.6411 326.3552 864.1232 335.9583 864.6053 343.3312 865.0874 348.8655 865.5695 353.7636 866.0516 357.3335 866.5338 357.2344 867.0159 352.7443 867.4980 345.9153 867.9801 338.0775 868.4622 328.6370 868.9443 316.8665 869.4265 301.6053 869.9086 286.2475 870.3907 271.2045 870.8728 255.4102 871.3549 237.7571 871.8370 218.3917 872.3192 200.0389 872.8013 182.4655 873.2834 166.2556 873.7655 152.2101 874.2476 139.6378 874.7297 127.9968 875.2119 117.1537 875.6940 106.9189 876.1761 97.31726 876.6582 88.38025 877.1403 80.31546 877.6224 73.05560 878.1046 65.66376 878.5867 58.09027 879.0688 50.47034 879.5509 42.07904 880.0330 34.39243 880.5151 30.13461 880.9973 28.53067 881.4794 26.85526 881.9615 24.63907 882.4436 21.55719 882.9257 16.57504 883.4078 10.77719 883.8900 7.273102 884.3721 6.416443 884.8542 5.837494 885.3363 4.996613 885.8184 3.993591 886.3005 2.783600 886.7827 1.502777 887.2648 0.5708620 887.7469 0.4932860 888.2290 0.2472840 888.7111 0.7376400 889.1932 2.119507 889.6754 3.448090 890.1575 4.914978 890.6396 5.712708 891.1217 5.618713 891.6038 5.215851 892.0859 5.330627 892.5681 5.726746 893.0502 5.738983 893.5323 5.289124 894.0144 4.256805 894.4965 1.381226 894.9786 1.315430 895.4608 1.926453 895.9429 0.4674680 896.4250 2.488342 896.9071 4.466858 897.3892 5.394531 897.8713 3.961670 898.3535 0.6955570 898.8356 1.117126 899.3177 1.530273 899.7998 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926.7983 217.3038 927.2805 228.6971 927.7626 242.5931 928.2447 257.9939 928.7268 273.8486 929.2089 290.1007 929.6910 307.0682 930.1732 324.6095 930.6553 343.1827 931.1374 362.4782 931.6195 383.3871 932.1016 407.4344 932.5837 434.4306 933.0659 463.5296 933.5480 493.5625 934.0301 526.5248 934.5122 562.3654 934.9943 601.6885 935.4764 646.0834 935.9586 696.1153 936.4407 751.5152 936.9228 812.4303 937.4049 879.9162 937.8870 955.1646 938.3691 1038.249 938.8513 1127.387 939.3334 1220.996 939.8155 1324.576 940.2976 1436.752 940.7797 1559.441 941.2618 1693.000 941.7440 1837.479 942.2261 1991.485 942.7082 2155.293 943.1903 2334.922 943.6724 2534.790 944.1545 2751.755 944.6367 2984.348 945.1188 3230.878 945.6009 3495.355 946.0830 3780.410 946.5651 4076.952 947.0472 4380.582 947.5294 4693.805 948.0115 5014.503 948.4936 5340.945 948.9757 5639.176 949.4578 5916.761 949.9399 6132.516 950.4221 6264.830 950.9042 6310.083 951.3863 6250.022 951.8684 6077.059 952.3505 5822.050 952.8326 5473.690 953.3148 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