#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 16:00:59 +0300 (Thu, 24 May 2018) $ #$Revision: 869 $ #$URL: svn://172.16.1.111/rod/cif/1/00/03/1000353.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000353 loop_ _publ_author_name 'Fortes, A. D.' 'Wood, I. G.' 'Alfredsson, M.' 'Vocadlo, L.' 'Knight, K. S.' _publ_section_title ; The thermoelastic properties of MgSO4*7D2O (epsomite) from powder neutron diffraction and ab initio calculation Locality: synthetic Sample: T = 2 K ; _journal_name_full 'European Journal of Mineralogy' _journal_page_first 449 _journal_page_last 462 _journal_paper_doi 10.1127/0935-1221/2006/0018-0449 _journal_volume 18 _journal_year 2006 _chemical_compound_source R150060 _chemical_formula_sum 'D14 Mg O11 S' _chemical_name_mineral 'Epsomite (deuterated)' _space_group_IT_number 19 _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 11.897133 _cell_length_b 11.90851 _cell_length_c 6.78729 _cell_volume 961.604 _diffrn_ambient_temperature 2 _exptl_crystal_density_diffrn 1.800 _cod_original_formula_sum 'Mg S O11 D14' _cod_database_code 9010743 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R150060.rod _rod_data_source.block 3500000 _rod_database.code 1000353 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9010743 COD http://www.crystallography.net/cod/9010743.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 93.15802 0.0000000E+00 93.64014 6.829590 94.12225 3.605164 94.60437 1.239868 95.08649 7.506531 95.56860 18.86206 96.05072 25.44592 96.53284 26.33246 97.01495 23.34729 97.49707 20.23889 97.97919 18.98669 98.46130 19.35468 98.94342 21.60101 99.42554 22.41321 99.90765 22.11591 100.3898 23.05939 100.8719 23.61609 101.3540 20.36353 101.8361 13.46136 102.3182 7.600189 102.8004 3.872589 103.2825 2.501831 103.7646 1.369171 104.2467 0.1173710 104.7288 0.8270260 105.2109 7.4065998E-02 105.6931 3.596100 106.1752 8.615692 106.6573 15.06674 107.1394 24.49139 107.6215 33.64508 108.1036 43.64020 108.5858 51.95093 109.0679 53.79187 109.5500 46.29218 110.0321 38.48511 110.5142 34.59503 110.9963 33.45157 111.4785 31.56183 111.9606 30.04929 112.4427 29.98343 112.9248 29.92685 113.4069 29.89105 113.8890 30.08582 114.3712 30.20468 114.8533 29.23178 115.3354 28.78915 115.8175 29.98184 116.2996 33.06924 116.7817 34.50430 117.2639 32.17212 117.7460 28.00641 118.2281 24.95169 118.7102 25.15021 119.1923 25.12393 119.6744 23.17526 120.1566 19.03864 120.6387 14.20810 121.1208 10.64664 121.6029 8.440674 122.0850 7.084778 122.5671 5.634277 123.0493 5.194092 123.5314 7.677368 124.0135 14.97440 124.4956 21.58276 124.9777 21.27072 125.4598 15.32556 125.9420 8.601837 126.4241 3.529297 126.9062 0.1068120 127.3883 2.695435 127.8704 4.360382 128.3525 4.971771 128.8347 3.886139 129.3168 1.171997 129.7989 1.746307 130.2810 3.971893 130.7631 5.511200 131.2452 6.497162 131.7274 6.972260 132.2095 6.913239 132.6916 6.045868 133.1737 4.266235 133.6558 2.386719 134.1379 1.092346 134.6201 0.3831790 135.1022 0.1205750 135.5843 0.3939210 136.0664 1.125122 136.5485 1.653687 137.0306 1.872803 137.5128 2.156586 137.9949 2.937653 138.4770 4.227203 138.9591 6.014587 139.4412 8.688324 139.9233 12.38577 140.4055 14.76105 140.8876 16.01743 141.3697 15.72092 141.8518 12.70050 142.3339 5.587555 142.8160 1.150482 143.2982 5.940399 143.7803 8.411316 144.2624 9.900726 144.7445 9.934662 145.2266 9.128021 145.7087 8.983124 146.1909 10.31650 146.6730 11.25537 147.1551 10.99445 147.6372 8.564545 148.1193 6.578094 148.6014 5.062592 149.0836 3.987671 149.5657 3.189606 150.0478 3.004822 150.5299 2.841583 151.0120 0.7829590 151.4941 0.9592590 151.9763 3.375549 152.4584 7.006165 152.9405 11.56485 153.4226 15.46948 153.9047 18.26541 154.3868 20.56949 154.8690 22.72540 155.3511 24.04382 155.8332 25.94308 156.3153 29.46890 156.7974 34.26721 157.2795 37.47134 157.7617 36.72110 158.2438 35.12854 158.7259 34.93378 159.2080 38.21347 159.6901 41.39740 160.1722 43.29755 160.6544 43.96259 161.1365 44.66025 161.6186 45.73572 162.1007 47.05783 162.5828 48.53979 163.0649 50.36084 163.5471 52.41309 164.0292 54.91412 164.5113 57.85016 164.9934 60.04196 165.4755 60.30209 165.9576 59.59525 166.4398 59.11649 166.9219 59.28699 167.4040 59.77710 167.8861 60.43372 168.3682 61.26227 168.8503 62.14813 169.3325 62.75696 169.8146 63.43674 170.2967 64.71536 170.7788 67.42731 171.2609 70.53012 171.7430 73.06506 172.2252 74.96466 172.7073 76.54440 173.1894 77.74808 173.6715 78.82712 174.1536 80.27133 174.6357 82.17654 175.1179 84.63382 175.6000 88.10886 176.0821 92.81821 176.5642 97.33160 177.0463 99.74820 177.5284 100.6773 178.0106 101.9685 178.4927 104.9467 178.9748 108.8673 179.4569 112.3650 179.9390 115.2891 180.4211 118.1200 180.9033 121.6460 181.3854 125.8588 181.8675 130.1085 182.3496 133.7751 182.8317 137.0737 183.3138 140.7512 183.7960 144.7669 184.2781 149.2464 184.7602 154.5180 185.2423 160.5825 185.7244 166.7577 186.2065 173.1274 186.6887 179.5435 187.1708 185.2219 187.6529 189.9288 188.1350 194.0406 188.6171 197.8422 189.0992 201.3708 189.5814 205.3049 190.0635 210.1959 190.5456 215.9957 191.0277 221.9042 191.5098 227.9005 191.9919 233.9037 192.4741 239.5412 192.9562 244.7886 193.4383 250.2351 193.9204 256.3262 194.4025 262.9882 194.8846 269.4435 195.3668 275.5211 195.8489 281.4356 196.3310 287.6901 196.8131 294.3021 197.2952 301.0845 197.7773 307.9677 198.2595 314.9099 198.7416 322.1842 199.2237 329.8058 199.7058 337.6869 200.1879 345.5110 200.6700 353.3340 201.1522 360.8793 201.6343 368.1270 202.1164 375.1190 202.5985 382.2961 203.0806 389.7992 203.5627 397.4292 204.0449 404.6904 204.5270 411.8309 205.0091 417.9467 205.4912 422.1761 205.9733 424.0999 206.4554 426.2916 206.9376 429.2549 207.4197 432.5740 207.9018 434.8144 208.3839 435.8755 208.8660 436.1502 209.3481 436.0053 209.8303 435.6710 210.3124 433.7777 210.7945 429.6207 211.2766 423.9094 211.7587 419.3582 212.2408 416.1192 212.7230 413.6935 213.2051 411.8688 213.6872 410.8655 214.1693 409.5738 214.6514 407.4933 215.1335 405.0185 215.6157 404.2692 216.0978 405.8373 216.5799 407.9787 217.0620 409.5085 217.5441 410.0560 218.0262 411.0677 218.5084 412.7941 218.9905 415.1167 219.4726 417.2874 219.9547 419.1281 220.4368 421.1935 220.9189 423.9567 221.4011 427.9637 221.8832 431.3326 222.3653 433.8927 222.8474 435.7229 223.3295 437.1592 223.8116 437.8607 224.2938 438.6703 224.7759 440.0566 225.2580 442.0018 225.7401 444.5717 226.2222 448.0338 226.7043 452.1136 227.1865 455.7635 227.6686 458.4635 228.1507 461.3833 228.6328 465.1865 229.1149 470.1451 229.5970 475.3169 230.0792 480.6031 230.5613 486.0693 231.0434 491.6787 231.5255 496.8818 232.0076 502.9973 232.4897 510.9245 232.9719 522.0115 233.4540 531.7141 233.9361 539.1442 234.4182 545.1883 234.9003 553.1074 235.3824 563.7943 235.8646 575.1464 236.3467 586.1523 236.8288 596.7166 237.3109 607.0101 237.7930 616.9070 238.2751 626.5923 238.7573 636.2396 239.2394 645.4836 239.7215 655.0846 240.2036 665.9822 240.6857 680.5305 241.1678 690.9760 241.6500 695.7525 242.1321 696.7126 242.6142 698.8756 243.0963 703.6858 243.5784 707.6749 244.0605 709.0956 244.5427 706.6539 245.0248 704.9844 245.5069 705.0822 245.9890 705.5449 246.4711 703.3845 246.9532 698.2574 247.4354 691.2336 247.9175 682.5746 248.3996 671.8978 248.8817 660.6171 249.3638 648.9719 249.8459 636.6813 250.3281 623.1969 250.8102 608.2495 251.2923 592.5376 251.7744 575.9543 252.2565 558.4066 252.7386 541.1909 253.2208 524.0119 253.7029 507.2569 254.1850 491.2719 254.6671 476.5182 255.1492 461.5328 255.6313 445.9525 256.1135 429.7836 256.5956 413.2005 257.0777 395.8930 257.5598 378.5525 258.0419 362.2735 258.5240 347.7122 259.0062 333.0894 259.4883 317.5364 259.9704 301.1963 260.4525 286.1028 260.9346 272.6424 261.4167 260.3223 261.8989 248.6204 262.3810 237.7689 262.8631 227.0406 263.3452 216.2486 263.8273 205.2701 264.3094 195.2780 264.7916 186.3785 265.2737 178.1186 265.7558 169.8756 266.2379 161.5481 266.7200 153.7481 267.2021 146.5869 267.6843 140.0409 268.1664 133.4439 268.6485 126.6488 269.1306 120.1755 269.6127 114.7711 270.0948 110.8149 270.5770 106.2076 271.0591 100.3750 271.5412 93.68265 272.0233 87.65457 272.5054 82.38538 272.9875 77.79114 273.4697 74.00909 273.9518 71.13467 274.4339 68.22290 274.9160 65.25015 275.3981 62.13605 275.8802 58.25430 276.3624 53.34827 276.8445 48.96277 277.3266 46.45343 277.8087 45.99695 278.2908 44.79175 278.7729 42.50809 279.2551 39.49017 279.7372 36.53381 280.2193 33.63992 280.7014 30.73395 281.1835 27.71115 281.6656 24.57471 282.1478 21.42419 282.6299 18.11334 283.1120 15.09085 283.5941 13.37787 284.0762 13.03613 284.5583 12.60034 285.0405 11.23309 285.5226 9.059998 286.0047 7.265656 286.4868 5.904236 286.9689 4.760590 287.4510 3.599670 287.9332 2.418182 288.4153 1.147430 288.8974 0.3754880 289.3795 2.002441 289.8616 3.025085 290.3438 3.393158 290.8259 3.514313 291.3080 3.732941 291.7901 4.054474 292.2722 4.580200 292.7543 5.510040 293.2365 6.578552 293.7186 7.087708 294.2007 7.022430 294.6828 6.793457 295.1649 6.855042 295.6470 7.063019 296.1292 6.889069 296.6113 5.905792 297.0934 4.788483 297.5755 4.850769 298.0576 5.985840 298.5397 7.023926 299.0219 6.840027 299.5040 5.961975 299.9861 5.612366 300.4682 6.248871 300.9503 7.017456 301.4324 6.895569 301.9146 6.002289 302.3967 4.862000 302.8788 3.392883 303.3609 1.999023 303.8430 1.489563 304.3251 2.224243 304.8073 2.893341 305.2894 1.978668 305.7715 3.1615999E-02 306.2536 1.618530 306.7357 1.965576 307.2178 1.825409 307.7000 2.174225 308.1821 3.164886 308.6642 3.808990 309.1463 2.675446 309.6284 0.8273320 310.1105 9.5702998E-02 310.5927 1.453003 311.0748 3.576477 311.5569 5.231567 312.0390 6.365082 312.5211 6.646606 313.0032 5.030029 313.4854 2.794922 313.9675 1.328644 314.4496 1.773834 314.9317 2.488708 315.4138 2.666107 315.8959 2.403290 316.3781 2.273254 316.8602 3.068726 317.3423 3.791748 317.8244 3.649078 318.3065 1.686066 318.7886 4.1565001E-02 319.2708 0.8494260 319.7529 0.8987730 320.2350 0.6426390 320.7171 0.1881100 321.1992 0.9868770 321.6813 1.416443 322.1635 1.236420 322.6456 1.125183 323.1277 1.050232 323.6098 1.142578 324.0919 1.624847 324.5740 2.751678 325.0562 4.068695 325.5383 5.650452 326.0204 7.791443 326.5025 8.985474 326.9846 8.214966 327.4667 6.833588 327.9489 6.279144 328.4310 6.831848 328.9131 7.931183 329.3952 9.899994 329.8773 12.80212 330.3594 14.57947 330.8416 14.08047 331.3237 13.46280 331.8058 14.23581 332.2879 16.82880 332.7700 20.09418 333.2521 24.61258 333.7343 29.79526 334.2164 32.74716 334.6985 32.16238 335.1806 31.47974 335.6627 32.66434 336.1448 36.54733 336.6270 39.32422 337.1091 40.40564 337.5912 40.81982 338.0733 42.62509 338.5554 46.14856 339.0375 49.70026 339.5197 52.53543 340.0018 54.56555 340.4839 57.05579 340.9660 60.10367 341.4481 63.43484 341.9302 66.61981 342.4124 69.66528 342.8945 72.80695 343.3766 76.17294 343.8587 79.68997 344.3408 83.13254 344.8229 86.46552 345.3051 89.87589 345.7872 93.68155 346.2693 97.77188 346.7514 101.4920 347.2335 104.5290 347.7156 107.2589 348.1978 110.0723 348.6799 113.0418 349.1620 116.8325 349.6441 122.8771 350.1262 130.0093 350.6083 135.1448 351.0905 137.5812 351.5726 139.4143 352.0547 143.4044 352.5368 148.8990 353.0189 153.8810 353.5010 156.7865 353.9832 158.8936 354.4653 161.7586 354.9474 165.4934 355.4295 169.4453 355.9116 172.9378 356.3937 176.3517 356.8759 180.2718 357.3580 186.4132 357.8401 191.9362 358.3222 194.2404 358.8043 193.8167 359.2864 193.5766 359.7686 195.8315 360.2507 198.5970 360.7328 200.0437 361.2149 198.8237 361.6970 197.7909 362.1791 198.6228 362.6613 200.4434 363.1434 201.3145 363.6255 200.6905 364.1076 198.9265 364.5897 195.8659 365.0718 191.0887 365.5540 186.6692 366.0361 183.6575 366.5182 180.9714 367.0003 177.3131 367.4824 171.8861 367.9645 166.0828 368.4467 160.1356 368.9288 154.0910 369.4109 148.2426 369.8930 143.0898 370.3751 137.7631 370.8572 131.5947 371.3394 123.8569 371.8215 116.5818 372.3036 109.8847 372.7857 103.8070 373.2678 98.54468 373.7499 94.71783 374.2321 90.48001 374.7142 84.76996 375.1963 76.90594 375.6784 70.30368 376.1605 65.25922 376.6426 61.00571 377.1248 56.64096 377.6069 52.09634 378.0890 47.86249 378.5711 44.20493 379.0532 41.03931 379.5353 38.05649 380.0175 35.21774 380.4996 32.45648 380.9817 29.54623 381.4638 26.57712 381.9459 24.21674 382.4280 22.84933 382.9102 21.90051 383.3923 20.44131 383.8744 18.43936 384.3565 15.91660 384.8386 12.17389 385.3207 8.033356 385.8029 5.535034 386.2850 5.058289 386.7671 5.106781 387.2492 4.213959 387.7313 2.661682 388.2134 1.111115 388.6956 0.3013310 389.1777 1.444550 389.6598 2.190277 390.1419 2.534851 390.6240 2.588196 391.1061 2.038727 391.5883 1.390137 392.0704 1.209015 392.5525 2.107361 393.0346 2.857819 393.5167 2.629669 393.9988 1.787354 394.4810 1.359100 394.9631 2.364990 395.4452 3.357971 395.9273 3.575958 396.4094 2.736298 396.8915 1.747833 397.3737 0.5787350 397.8558 0.5832820 398.3379 1.506805 398.8200 2.039581 399.3021 2.456848 399.7842 2.763062 400.2664 2.956482 400.7485 3.199188 401.2306 3.497589 401.7127 3.830505 402.1948 4.159302 402.6769 4.347900 403.1591 4.804779 403.6412 5.489868 404.1233 6.483154 404.6054 8.140198 405.0875 10.72836 405.5696 13.15314 406.0518 14.94577 406.5339 16.09421 407.0160 17.01105 407.4981 17.55270 407.9802 18.26178 408.4623 20.01779 408.9445 22.80374 409.4266 25.15176 409.9087 26.54160 410.3908 27.37573 410.8729 28.56964 411.3550 30.12234 411.8372 31.73764 412.3193 33.22110 412.8014 34.62073 413.2835 35.96503 413.7656 37.17545 414.2477 38.68637 414.7299 41.14282 415.2120 44.26990 415.6941 47.34732 416.1762 50.14725 416.6583 52.69980 417.1404 54.89261 417.6226 56.75851 418.1047 58.75812 418.5868 61.21277 419.0689 63.90967 419.5510 66.67242 420.0331 69.25287 420.5153 72.13712 420.9974 75.75858 421.4795 79.83038 421.9616 83.48502 422.4437 85.85568 422.9258 88.37039 423.4080 91.70767 423.8901 96.21432 424.3722 100.5814 424.8543 104.5174 425.3364 108.3770 425.8185 112.4678 426.3007 116.7089 426.7828 121.3741 427.2649 126.5242 427.7470 132.1153 428.2291 138.0686 428.7112 144.4053 429.1934 150.9895 429.6755 157.9922 430.1576 165.5418 430.6397 172.5310 431.1218 178.6463 431.6039 184.6143 432.0861 191.7811 432.5682 200.2177 433.0503 208.7994 433.5324 217.2226 434.0145 225.5423 434.4966 233.8120 434.9788 242.0223 435.4609 250.5905 435.9430 260.1029 436.4251 270.3630 436.9072 280.8310 437.3893 291.6370 437.8715 302.2461 438.3536 311.6989 438.8357 320.4052 439.3178 329.5049 439.7999 339.7419 440.2820 350.5728 440.7642 361.4481 441.2463 372.4223 441.7284 383.3764 442.2105 394.9641 442.6926 406.2639 443.1747 416.3644 443.6569 424.5728 444.1390 432.1086 444.6211 439.0222 445.1032 445.4874 445.5853 451.8213 446.0674 457.9894 446.5496 464.1561 447.0317 470.3960 447.5138 476.8236 447.9959 483.2226 448.4780 489.4467 448.9601 495.8871 449.4423 502.9832 449.9244 510.3260 450.4065 518.8710 450.8886 528.8370 451.3707 540.1445 451.8528 552.7086 452.3350 566.8296 452.8171 581.3506 453.2992 595.4872 453.7813 609.3091 454.2634 625.4453 454.7455 644.1604 455.2277 665.0404 455.7098 688.5052 456.1919 713.9026 456.6740 739.2704 457.1561 763.1193 457.6382 787.0154 458.1204 813.1360 458.6025 841.3078 459.0846 868.9631 459.5667 894.0245 460.0488 918.2297 460.5309 944.2424 461.0131 972.7492 461.4952 1001.520 461.9773 1029.934 462.4594 1056.767 462.9415 1080.649 463.4236 1101.423 463.9058 1118.581 464.3879 1132.678 464.8700 1143.309 465.3521 1148.793 465.8342 1148.148 466.3163 1142.624 466.7985 1132.925 467.2806 1119.310 467.7627 1101.163 468.2448 1078.050 468.7269 1050.750 469.2090 1019.979 469.6912 984.7051 470.1733 947.1046 470.6554 907.2612 471.1375 865.4442 471.6196 823.2156 472.1017 780.0173 472.5839 737.4248 473.0660 695.4385 473.5481 654.2704 474.0302 614.5938 474.5123 576.3659 474.9944 539.9908 475.4766 506.1642 475.9587 474.7546 476.4408 444.9819 476.9229 416.9856 477.4050 390.5140 477.8871 365.1715 478.3693 341.0310 478.8514 318.7458 479.3335 299.2738 479.8156 281.6252 480.2977 264.6914 480.7798 248.0907 481.2620 232.9701 481.7441 220.9597 482.2262 210.6644 482.7083 200.0293 483.1904 187.3696 483.6725 175.1697 484.1547 164.4536 484.6368 155.2192 485.1189 146.4954 485.6010 138.2107 486.0831 130.3458 486.5652 122.9642 487.0474 116.1654 487.5295 109.5093 488.0116 102.9068 488.4937 96.58878 488.9758 90.85468 489.4579 85.80646 489.9401 81.00714 490.4222 76.34381 490.9043 71.83548 491.3864 67.27353 491.8685 62.58026 492.3506 58.26392 492.8328 54.80350 493.3149 52.05600 493.7970 49.26794 494.2791 46.34561 494.7612 43.54657 495.2433 41.27206 495.7255 39.33093 496.2076 37.19736 496.6897 34.49258 497.1718 31.70160 497.6539 29.24222 498.1360 27.11163 498.6182 25.24631 499.1003 23.94199 499.5824 22.68100 500.0645 21.02045 500.5466 18.70868 501.0287 16.81180 501.5109 15.97418 501.9930 15.54141 502.4751 14.87106 502.9572 14.06287 503.4393 12.76965 503.9214 10.48306 504.4036 7.666412 504.8857 5.990997 505.3678 6.225677 505.8499 6.233185 506.3320 4.910553 506.8141 2.098755 507.2963 0.4514470 507.7784 0.1935730 508.2605 0.4621890 508.7426 0.4471740 509.2247 0.1614380 509.7068 0.2102360 510.1890 0.6517030 510.6711 1.131775 511.1532 1.532135 511.6353 1.898132 512.1174 2.429108 512.5995 3.835297 513.0817 5.147125 513.5638 4.666046 514.0459 2.479584 514.5280 0.9743960 515.0101 2.680420 515.4922 5.252808 515.9744 6.377777 516.4565 4.748962 516.9386 3.288757 517.4207 2.801727 517.9028 3.110443 518.3849 3.927094 518.8671 6.549347 519.3492 8.212891 519.8313 7.949554 520.3134 5.925598 520.7955 4.543854 521.2776 3.980011 521.7598 3.801453 522.2419 3.865997 522.7240 4.270264 523.2061 4.361542 523.6882 4.026276 524.1703 3.600220 524.6525 3.614929 525.1346 4.030762 525.6167 4.232117 526.0988 4.018219 526.5809 3.531464 527.0630 2.733917 527.5452 1.761963 528.0273 1.373291 528.5094 2.895264 528.9915 4.775452 529.4736 5.087555 529.9557 3.646851 530.4379 1.998077 530.9200 0.6535950 531.4021 0.2559510 531.8842 0.5563050 532.3663 0.5797730 532.8484 1.205566 533.3306 0.4603580 533.8127 1.093933 534.2948 2.251068 534.7769 2.667328 535.2590 2.978943 535.7411 3.283752 536.2233 3.584320 536.7054 3.983398 537.1875 4.453247 537.6696 5.076508 538.1517 6.025635 538.6339 7.342957 539.1160 8.273376 539.5981 8.689545 540.0802 8.953156 540.5623 9.509338 541.0444 10.33997 541.5266 11.38116 542.0087 12.73782 542.4908 14.14447 542.9729 15.04944 543.4550 15.59341 543.9371 16.37799 544.4193 18.04968 544.9014 19.90994 545.3835 21.47104 545.8656 22.69479 546.3477 23.48215 546.8298 23.16327 547.3120 22.75427 547.7941 23.09705 548.2762 24.95453 548.7583 26.70465 549.2404 28.10486 549.7225 29.36023 550.2047 30.83789 550.6868 32.68588 551.1689 34.47025 551.6510 36.02847 552.1331 37.41824 552.6152 39.06595 553.0974 41.08124 553.5795 42.83282 554.0616 43.60275 554.5437 43.64487 555.0258 44.43588 555.5079 46.10153 555.9901 48.24954 556.4722 50.83975 556.9543 53.59601 557.4364 55.86963 557.9185 57.12341 558.4006 58.41510 558.8828 60.75873 559.3649 63.78619 559.8470 66.70499 560.3291 69.27646 560.8112 71.57483 561.2933 73.46948 561.7755 74.95139 562.2576 76.82285 562.7397 79.71667 563.2218 82.56339 563.7039 84.78439 564.1860 85.91748 564.6682 87.61578 565.1503 90.12048 565.6324 92.96396 566.1145 95.38126 566.5966 97.30225 567.0787 99.57654 567.5609 102.4719 568.0430 105.7250 568.5251 108.7267 569.0072 111.5306 569.4893 114.2485 569.9714 117.0452 570.4536 119.7148 570.9357 121.8749 571.4178 123.6705 571.8999 125.9700 572.3820 129.2012 572.8641 132.8959 573.3463 136.8398 573.8284 141.4531 574.3105 145.7067 574.7926 148.6432 575.2747 151.1624 575.7568 154.4128 576.2390 159.0302 576.7211 163.5415 577.2032 167.9277 577.6853 172.2942 578.1674 176.4147 578.6495 179.9690 579.1317 184.0266 579.6138 189.2027 580.0959 195.3257 580.5780 200.8620 581.0601 205.8002 581.5422 211.1273 582.0244 218.2923 582.5065 226.4448 582.9886 233.2039 583.4707 238.1994 583.9528 242.8442 584.4349 248.0844 584.9171 253.9095 585.3992 260.2844 585.8813 267.1103 586.3634 274.4479 586.8455 282.5345 587.3276 291.2455 587.8098 299.8034 588.2919 307.0628 588.7740 315.1364 589.2561 325.2156 589.7382 337.3514 590.2203 347.1156 590.7025 353.3137 591.1846 359.1262 591.6667 366.7078 592.1488 376.2415 592.6309 385.0755 593.1130 392.9844 593.5952 400.8882 594.0773 409.8794 594.5594 419.8624 595.0415 430.3674 595.5236 441.7493 596.0057 452.9182 596.4879 462.0897 596.9700 470.0163 597.4521 478.3653 597.9342 488.3046 598.4163 498.5622 598.8984 508.7861 599.3806 518.8973 599.8627 528.0262 600.3448 535.0068 600.8269 541.7641 601.3090 549.3878 601.7911 558.3256 602.2733 566.5060 602.7554 573.9752 603.2375 580.6110 603.7196 586.0489 604.2017 590.2382 604.6838 594.1868 605.1660 598.0203 605.6481 601.7294 606.1302 605.2905 606.6123 608.6902 607.0944 611.8961 607.5765 615.4591 608.0587 618.2834 608.5408 618.8314 609.0229 617.4982 609.5050 615.7227 609.9871 613.9044 610.4692 612.1459 610.9514 610.7799 611.4335 609.8643 611.9156 607.9966 612.3977 604.2587 612.8798 599.9409 613.3619 595.7648 613.8441 591.3527 614.3262 587.9935 614.8083 586.1180 615.2904 584.6926 615.7725 582.4424 616.2546 579.3327 616.7368 576.0959 617.2189 572.7067 617.7010 569.4848 618.1831 567.0208 618.6652 565.2457 619.1473 563.8792 619.6295 563.0869 620.1116 562.4577 620.5937 561.7346 621.0758 560.8654 621.5579 559.5565 622.0400 556.8020 622.5222 554.2784 623.0043 553.1909 623.4864 553.9955 623.9685 554.2011 624.4506 553.4697 624.9327 552.1407 625.4149 550.4148 625.8970 548.3484 626.3791 545.6991 626.8612 542.2421 627.3433 538.5704 627.8254 535.9047 628.3076 534.1472 628.7897 531.1015 629.2718 525.9323 629.7539 519.6373 630.2360 514.0084 630.7181 508.6819 631.2003 502.6077 631.6824 495.4068 632.1645 487.3065 632.6466 477.9266 633.1287 467.3248 633.6108 457.0975 634.0930 448.5912 634.5751 439.8249 635.0572 429.6890 635.5393 417.6482 636.0214 406.9555 636.5035 398.6400 636.9857 390.0773 637.4678 379.1193 637.9499 365.4323 638.4320 352.4337 638.9141 340.3267 639.3962 328.8746 639.8784 318.0223 640.3605 307.8421 640.8426 297.9453 641.3247 288.5278 641.8068 279.1483 642.2889 268.7237 642.7711 257.7778 643.2532 247.4076 643.7353 239.1285 644.2174 230.8301 644.6995 220.7446 645.1816 209.3565 645.6638 199.8550 646.1459 194.8142 646.6280 189.6123 647.1101 182.4350 647.5922 173.1993 648.0743 164.6924 648.5565 157.0750 649.0386 150.1718 649.5207 144.1726 650.0028 138.9497 650.4849 133.7040 650.9670 128.4348 651.4492 123.1534 651.9313 117.9137 652.4134 112.7307 652.8955 107.7347 653.3776 102.9441 653.8597 98.12631 654.3419 92.90466 654.8240 87.66177 655.3061 82.94547 655.7882 79.53476 656.2703 76.14520 656.7524 72.33102 657.2346 68.34784 657.7167 64.96167 658.1988 62.39346 658.6809 59.80234 659.1630 56.77826 659.6451 53.48227 660.1273 51.01059 660.6094 49.39127 661.0915 47.69922 661.5736 45.04070 662.0557 41.87755 662.5378 39.08786 663.0200 36.72568 663.5021 34.65530 663.9842 33.01682 664.4663 31.48581 664.9484 29.73557 665.4305 27.55063 665.9127 25.55878 666.3948 23.75681 666.8769 22.32272 667.3590 21.47867 667.8411 21.88327 668.3232 21.46877 668.8054 19.79057 669.2875 17.56752 669.7696 16.04288 670.2517 15.22682 670.7338 14.68770 671.2159 14.48880 671.6981 14.25929 672.1802 13.23494 672.6623 11.59975 673.1444 9.957123 673.6265 8.394226 674.1086 7.156250 674.5908 6.825989 675.0729 7.187393 675.5550 6.798676 676.0371 4.107437 676.5192 1.578201 677.0013 0.3688200 677.4835 0.6110530 677.9656 0.6995850 678.4477 0.5222170 678.9298 0.3862150 679.4119 0.6187740 679.8940 1.219513 680.3762 1.342361 680.8583 0.8898620 681.3404 0.3612980 681.8225 0.3809050 682.3046 0.6807560 682.7867 0.6563420 683.2689 0.1132200 683.7510 0.5127720 684.2331 0.9502560 684.7152 1.250320 685.1973 1.457016 685.6794 1.622864 686.1616 1.653580 686.6437 1.407013 687.1258 1.046890 687.6079 0.7735900 688.0900 0.3215940 688.5721 0.7424470 689.0543 2.723373 689.5364 5.448944 690.0185 6.378662 690.5006 5.556900 690.9827 4.500610 691.4648 3.597855 691.9470 3.126450 692.4291 3.941345 692.9112 5.768448 693.3933 7.078217 693.8754 6.536301 694.3575 5.598175 694.8397 5.381943 695.3218 6.074371 695.8039 5.987030 696.2860 3.965851 696.7681 1.996704 697.2502 1.040115 697.7324 1.217346 698.2145 2.012177 698.6966 3.711502 699.1787 5.219147 699.6608 5.165039 700.1429 3.890884 700.6251 3.165985 701.1072 3.295334 701.5893 3.567749 702.0714 3.324951 702.5535 2.759857 703.0356 2.145660 703.5178 1.539505 703.9999 0.9387820 704.4820 9.3369000E-02 704.9641 0.6740260 705.4462 0.8224490 705.9283 0.3292690 706.4105 1.025314 706.8926 0.9378660 707.3747 0.3326420 707.8568 0.2236330 708.3389 0.7425990 708.8210 1.071259 709.3032 1.059570 709.7853 0.9212190 710.2674 1.221725 710.7495 1.827759 711.2316 2.178970 711.7137 0.9049380 712.1959 0.1342620 712.6780 2.431747 713.1601 7.211517 713.6422 10.00792 714.1243 7.731339 714.6064 4.990250 715.0886 3.588791 715.5707 3.548523 716.0528 3.840866 716.5349 4.685593 717.0170 5.305252 717.4991 4.975647 717.9813 3.870758 718.4634 3.295349 718.9455 3.285202 719.4276 3.742279 719.9097 5.095490 720.3918 6.644638 720.8740 7.308014 721.3561 6.785385 721.8382 6.309555 722.3203 6.392868 722.8024 6.818726 723.2845 7.417130 723.7667 8.509140 724.2488 9.138916 724.7309 9.086487 725.2130 8.806046 725.6951 8.885056 726.1772 9.364700 726.6594 9.538116 727.1415 9.220490 727.6236 8.798996 728.1057 8.834412 728.5878 9.193008 729.0699 9.521286 729.5521 9.674393 730.0342 9.813004 730.5163 10.00793 730.9984 10.27148 731.4805 10.62434 731.9626 11.17854 732.4448 11.70262 732.9269 12.15834 733.4090 12.54491 733.8911 12.89023 734.3732 13.19788 734.8553 13.42703 735.3375 13.48114 735.8196 13.51576 736.3017 14.09355 736.7838 15.10536 737.2659 15.88747 737.7480 15.95099 738.2302 15.71103 738.7123 15.42459 739.1944 15.13953 739.6765 15.05188 740.1586 15.61528 740.6407 16.02771 741.1229 15.77257 741.6050 14.88631 742.0871 14.46239 742.5692 14.64714 743.0513 14.94127 743.5334 14.97079 744.0156 14.83368 744.4977 15.50696 744.9798 16.99544 745.4619 18.36856 745.9440 18.85010 746.4261 18.80246 746.9083 18.56435 747.3904 18.08931 747.8725 17.57932 748.3546 16.93562 748.8367 16.58501 749.3188 16.90985 749.8010 18.17577 750.2831 18.98434 750.7652 19.32402 751.2473 19.08775 751.7294 17.97694 752.2115 16.04491 752.6937 15.07819 753.1758 15.21913 753.6579 15.69371 754.1400 15.80888 754.6221 15.79578 755.1042 16.08786 755.5864 16.87845 756.0685 17.16289 756.5506 15.89328 757.0327 14.05621 757.5148 12.75226 757.9969 12.43694 758.4791 12.30603 758.9612 12.34958 759.4433 12.46469 759.9254 12.63612 760.4075 12.89954 760.8896 12.89015 761.3718 12.52101 761.8539 11.95462 762.3360 11.24263 762.8181 10.52446 763.3002 10.07832 763.7823 9.972626 764.2645 10.00519 764.7466 10.25290 765.2287 10.59543 765.7108 10.80508 766.1929 10.57483 766.6750 10.59790 767.1572 11.10489 767.6393 11.73045 768.1214 11.75768 768.6035 11.15215 769.0856 10.62071 769.5677 10.28230 770.0499 10.01447 770.5320 9.774811 771.0141 9.557892 771.4962 9.362610 771.9783 9.232086 772.4604 9.081223 772.9426 9.075241 773.4247 9.028656 773.9068 8.404068 774.3889 6.087341 774.8710 4.771042 775.3531 5.248871 775.8353 6.828003 776.3174 7.656113 776.7995 7.729965 777.2816 7.413208 777.7637 6.657135 778.2458 5.812775 778.7280 5.502029 779.2101 5.596725 779.6922 5.721924 780.1743 5.530182 780.6564 5.503479 781.1385 6.250427 781.6207 7.467270 782.1028 7.725143 782.5849 6.086441 783.0670 4.877457 783.5491 4.837143 784.0313 5.653625 784.5134 6.117828 784.9955 6.225815 785.4776 6.179245 785.9597 6.107849 786.4418 5.920715 786.9240 5.289215 787.4061 4.368011 787.8882 3.740509 788.3703 4.335358 788.8524 4.702072 789.3345 3.631393 789.8167 1.435577 790.2988 0.7488400 790.7809 2.546173 791.2630 4.099777 791.7451 4.330414 792.2272 3.620758 792.7094 3.844681 793.1915 4.956497 793.6736 5.816711 794.1557 5.509232 794.6378 4.743896 795.1199 4.370407 795.6021 4.343170 796.0842 4.395126 796.5663 4.616074 797.0484 4.697067 797.5305 4.441452 798.0126 3.888702 798.4948 3.314255 798.9769 2.612473 799.4590 2.181366 799.9411 2.334427 800.4232 2.857376 800.9053 2.776031 801.3875 2.164566 801.8696 1.752029 802.3517 2.132965 802.8338 2.811554 803.3159 3.443039 803.7980 3.976135 804.2802 4.195267 804.7623 3.398361 805.2444 2.948196 805.7265 3.507233 806.2086 4.919434 806.6907 5.843002 807.1729 6.241257 807.6550 6.289291 808.1371 5.964325 808.6192 5.398956 809.1013 4.867813 809.5834 4.397461 810.0656 4.110260 810.5477 4.189560 811.0298 4.393738 811.5119 4.573410 811.9940 4.729294 812.4761 4.900558 812.9583 4.809784 813.4404 5.147018 813.9225 6.474472 814.4046 8.444199 814.8867 8.751144 815.3688 7.307205 815.8510 6.031647 816.3331 6.156281 816.8152 6.924515 817.2973 7.070221 817.7794 6.729736 818.2615 6.448105 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