#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 16:33:03 +0300 (Thu, 24 May 2018) $ #$Revision: 883 $ #$URL: svn://172.16.1.111/rod/cif/1/00/03/1000362.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000362 loop_ _publ_author_name 'Geiger, C. A.' 'Armbruster, T.' 'Lager, G. A.' 'Jiang, K.' 'Lottermoser, W.' 'Amthauer, G.' _publ_section_title ; A combined temperature dependent 57Fe Mossbauer and single crystal X-ray diffraction study of synthetic almandine: evidence for the Gol'danskii-Karyagin Effect Sample: T = 293 K (B) ; _journal_name_full 'Physics and Chemistry of Minerals' _journal_page_first 121 _journal_page_last 126 _journal_volume 19 _journal_year 1992 _chemical_compound_source R040079 _chemical_formula_sum 'Al2 Fe3 O12 Si3' _chemical_name_mineral Almandine _space_group_IT_number 230 _symmetry_space_group_name_Hall '-I 4bd 2c 3' _symmetry_space_group_name_H-M 'I a -3 d' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 11.525 _cell_length_b 11.525 _cell_length_c 11.525 _cell_volume 1530.815 _diffrn_ambient_temperature 293 _exptl_crystal_density_diffrn 4.319 _cod_original_formula_sum 'Fe3 Al2 Si3 O12' _cod_database_code 9006109 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R040079.rod _rod_data_source.block 3500000 _rod_database.code 1000362 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9006109 COD http://www.crystallography.net/cod/9006109.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 128.6837 0.0000000E+00 129.1658 0.2639160 129.6479 8.431396 130.1300 22.26831 130.6121 49.07129 131.0942 74.73462 131.5764 85.52393 132.0585 75.44067 132.5406 50.19653 133.0227 30.98242 133.5048 12.03394 133.9869 2.753906 134.4691 13.61719 134.9512 34.27246 135.4333 46.71167 135.9154 38.08350 136.3975 10.17529 136.8796 3.921387 137.3618 1.736328 137.8439 8.487793 138.3260 27.12329 138.8081 52.52661 139.2902 76.37524 139.7723 92.25342 140.2545 99.46631 140.7366 101.9941 141.2187 98.09229 141.7008 90.48901 142.1829 79.36768 142.6650 62.59766 143.1472 51.51709 143.6293 66.44019 144.1114 100.8613 144.5935 122.1255 145.0756 105.0059 145.5577 62.09229 146.0399 35.36475 146.5220 35.37964 147.0041 50.63599 147.4862 74.69336 147.9683 106.5334 148.4504 134.2217 148.9326 146.5413 149.4147 142.4128 149.8968 135.2695 150.3789 115.6274 150.8610 101.2507 151.3431 105.1870 151.8252 129.9487 152.3074 163.8657 152.7895 189.8967 153.2716 207.5901 153.7537 217.2905 154.2358 215.4402 154.7179 211.5996 155.2001 209.5305 155.6822 204.9438 156.1643 205.4973 156.6464 224.5461 157.1285 288.6326 157.6106 339.8799 158.0928 357.4841 158.5749 359.6147 159.0570 357.2761 159.5391 356.5129 160.0212 357.5513 160.5033 363.4160 160.9855 371.7998 161.4676 386.3618 161.9497 415.0967 162.4318 452.5300 162.9139 484.0007 163.3960 497.8584 163.8782 492.9658 164.3603 487.8032 164.8424 473.0483 165.3245 464.8257 165.8066 475.4036 166.2887 505.2410 166.7709 544.5471 167.2530 589.6904 167.7351 640.0012 168.2172 673.8989 168.6993 690.9822 169.1814 689.6165 169.6636 660.9263 170.1457 597.7383 170.6278 530.4932 171.1099 492.6111 171.5920 478.7012 172.0741 469.0671 172.5563 465.1875 173.0384 460.7046 173.5205 434.7505 174.0026 372.8213 174.4847 303.1616 174.9668 248.1953 175.4490 207.3240 175.9311 176.1892 176.4132 153.9341 176.8953 140.2295 177.3774 128.4736 177.8595 122.9211 178.3417 114.3984 178.8238 94.74829 179.3059 63.59888 179.7880 31.08862 180.2701 7.876953 180.7522 5.348145 181.2344 12.15332 181.7165 6.765137 182.1986 0.6193850 182.6807 3.916260 183.1628 1.454346 183.6449 4.377930 184.1271 9.919434 184.6092 15.71973 185.0913 19.89478 185.5734 32.69897 186.0555 39.21509 186.5376 19.69458 187.0198 25.15649 187.5019 40.02295 187.9840 50.75806 188.4661 57.63281 188.9482 48.96094 189.4303 60.37183 189.9125 63.67529 190.3946 66.64941 190.8767 80.92358 191.3588 74.37671 191.8409 88.47803 192.3230 94.34009 192.8052 103.9761 193.2873 105.4438 193.7694 109.6646 194.2515 114.9673 194.7336 120.8743 195.2157 127.7893 195.6979 139.5945 196.1800 167.9531 196.6621 188.5371 197.1442 184.6865 197.6263 163.8252 198.1084 148.3286 198.5906 154.2043 199.0727 180.2490 199.5548 202.3765 200.0369 216.4832 200.5190 230.4258 201.0011 250.6941 201.4833 276.5737 201.9654 299.5149 202.4475 310.3586 202.9296 311.4287 203.4117 324.0005 203.8938 361.5166 204.3760 402.8938 204.8581 427.1619 205.3402 432.5066 205.8223 435.9028 206.3044 453.6021 206.7865 481.1313 207.2687 502.0408 207.7508 508.6826 208.2329 508.4785 208.7150 513.1606 209.1971 524.4888 209.6792 537.0508 210.1614 547.8174 210.6435 556.7009 211.1256 562.6660 211.6077 558.5234 212.0898 551.9565 212.5719 565.4883 213.0541 613.5698 213.5362 652.5945 214.0183 649.9363 214.5004 618.9292 214.9825 588.1470 215.4646 573.8596 215.9468 573.4797 216.4289 573.4832 216.9110 577.0444 217.3931 573.8997 217.8752 556.0786 218.3573 526.5139 218.8395 496.3503 219.3216 473.6064 219.8037 457.7820 220.2858 441.9360 220.7679 426.6184 221.2500 410.5547 221.7322 392.3447 222.2143 372.7500 222.6964 354.1729 223.1785 335.8535 223.6606 316.4893 224.1427 308.9453 224.6249 333.7153 225.1070 353.2795 225.5891 350.5051 226.0712 328.3503 226.5533 300.7395 227.0354 280.0889 227.5176 267.8601 227.9997 258.4883 228.4818 252.9314 228.9639 246.6357 229.4460 237.7095 229.9281 227.6299 230.4103 219.0662 230.8924 215.0044 231.3745 216.2612 231.8566 218.3857 232.3387 223.9133 232.8208 228.1521 233.3030 229.2664 233.7851 226.9902 234.2672 221.5911 234.7493 212.2800 235.2314 195.8672 235.7135 187.6992 236.1957 196.2822 236.6778 204.7852 237.1599 202.3064 237.6420 189.2883 238.1241 174.8926 238.6062 170.4368 239.0884 182.6023 239.5705 184.1069 240.0526 167.2488 240.5347 147.8481 241.0168 134.1777 241.4989 127.2847 241.9811 124.4585 242.4632 122.6636 242.9453 122.1987 243.4274 122.0171 243.9095 133.9438 244.3916 139.8147 244.8738 118.3020 245.3559 69.37378 245.8380 21.66284 246.3201 10.35522 246.8022 52.76172 247.2843 77.84497 247.7665 72.45850 248.2486 60.89136 248.7307 62.56299 249.2128 78.94165 249.6949 95.64062 250.1770 95.45947 250.6592 71.02319 251.1413 54.29224 251.6234 52.47925 252.1055 53.04028 252.5876 43.86670 253.0697 24.45605 253.5519 6.719238 254.0340 5.270508 254.5161 26.62744 254.9982 38.38989 255.4803 26.62915 255.9624 14.57690 256.4445 26.07617 256.9267 62.52246 257.4088 98.79590 257.8909 107.1094 258.3730 78.96753 258.8551 62.74585 259.3372 71.15210 259.8194 83.33496 260.3015 81.15381 260.7836 62.92432 261.2657 40.34546 261.7478 23.08569 262.2299 11.81250 262.7121 9.411865 263.1942 28.91187 263.6763 48.87817 264.1584 46.24731 264.6405 20.11108 265.1227 3.269775 265.6048 4.110107 266.0869 44.97754 266.5690 65.29907 267.0511 43.05176 267.5332 13.95288 268.0154 13.61377 268.4975 43.01050 268.9796 66.46143 269.4617 47.88843 269.9438 11.83423 270.4259 42.21533 270.9081 14.86987 271.3902 23.67334 271.8723 36.65698 272.3544 22.88403 272.8365 1.797119 273.3186 14.91626 273.8008 26.35278 274.2829 31.69360 274.7650 30.88159 275.2471 23.99658 275.7292 5.829590 276.2113 22.13525 276.6935 43.80786 277.1756 46.43335 277.6577 31.94458 278.1398 21.30859 278.6219 17.85449 279.1040 15.53931 279.5862 8.323730 280.0683 2.843262 280.5504 9.418701 281.0325 3.792480 281.5146 10.38403 281.9967 16.96021 282.4789 9.853516 282.9610 0.8779300 283.4431 1.403076 283.9252 1.614746 284.4073 1.169922 284.8894 10.33545 285.3716 26.90723 285.8537 30.64917 286.3358 13.23804 286.8179 5.918457 287.3000 15.01465 287.7821 16.37939 288.2643 19.26050 288.7464 28.15649 289.2285 41.15601 289.7106 54.23169 290.1927 72.82935 290.6748 82.38965 291.1570 65.38306 291.6391 31.95776 292.1212 15.83545 292.6033 35.57324 293.0854 72.26196 293.5675 86.86475 294.0497 74.76709 294.5318 58.63940 295.0139 44.42310 295.4960 32.83203 295.9781 25.03223 296.4602 20.82080 296.9424 21.86011 297.4245 34.45703 297.9066 62.21436 298.3887 82.60767 298.8708 86.03394 299.3529 77.96973 299.8351 65.75781 300.3172 49.67700 300.7993 35.53418 301.2814 32.65137 301.7635 41.06519 302.2456 52.55322 302.7278 65.79346 303.2099 80.86963 303.6920 98.86108 304.1741 120.2861 304.6562 141.4207 305.1383 157.9043 305.6205 169.6489 306.1026 177.9912 306.5847 174.8381 307.0668 172.7834 307.5489 187.8848 308.0310 222.1548 308.5132 259.7107 308.9953 288.0232 309.4774 306.1274 309.9595 314.5156 310.4416 294.9338 310.9237 278.4722 311.4059 295.1741 311.8880 343.9604 312.3701 395.7976 312.8522 429.5610 313.3343 444.9468 313.8164 459.2063 314.2986 479.1704 314.7807 492.2241 315.2628 484.7568 315.7449 461.6748 316.2270 443.6323 316.7091 444.0869 317.1913 460.1216 317.6734 473.2656 318.1555 485.4841 318.6376 493.3989 319.1197 490.3767 319.6018 481.8711 320.0840 481.0769 320.5661 495.2058 321.0482 520.1082 321.5303 541.6758 322.0124 560.2874 322.4945 575.8625 322.9767 584.6328 323.4588 591.5459 323.9409 602.0742 324.4230 618.2070 324.9051 638.7051 325.3872 661.5588 325.8694 688.3867 326.3515 714.7361 326.8336 741.5217 327.3157 766.8372 327.7978 784.0393 328.2799 791.5623 328.7621 804.2263 329.2442 838.6948 329.7263 906.8467 330.2084 962.9888 330.6905 1004.711 331.1726 1035.650 331.6548 1053.532 332.1369 1061.487 332.6190 1073.060 333.1011 1102.693 333.5832 1154.428 334.0653 1206.791 334.5475 1258.193 335.0296 1310.452 335.5117 1364.171 335.9938 1419.372 336.4759 1474.634 336.9580 1526.799 337.4402 1575.595 337.9223 1654.925 338.4044 1815.620 338.8865 1951.455 339.3686 2024.943 339.8507 2055.545 340.3329 2074.766 340.8150 2098.992 341.2971 2131.529 341.7792 2187.299 342.2613 2278.300 342.7434 2379.284 343.2256 2503.090 343.7077 2629.188 344.1898 2734.492 344.6719 2807.535 345.1540 2860.549 345.6361 2926.902 346.1183 3030.917 346.6004 3103.035 347.0825 3141.278 347.5646 3149.633 348.0467 3126.491 348.5288 3074.008 349.0110 3002.608 349.4931 2925.722 349.9752 2845.322 350.4573 2747.099 350.9394 2618.484 351.4215 2481.949 351.9037 2339.695 352.3858 2194.524 352.8679 2057.658 353.3500 1940.326 353.8321 1842.149 354.3142 1742.614 354.7964 1635.607 355.2785 1535.928 355.7606 1448.839 356.2427 1372.527 356.7248 1302.551 357.2069 1236.484 357.6891 1175.379 358.1712 1122.949 358.6533 1079.976 359.1354 1043.773 359.6175 1011.960 360.0996 986.2341 360.5818 970.2874 361.0639 967.0579 361.5460 969.5186 362.0281 968.5286 362.5102 963.6462 362.9923 959.1450 363.4745 955.9458 363.9566 954.1267 364.4387 952.0000 364.9208 948.4644 365.4029 951.7646 365.8850 975.4038 366.3672 1014.152 366.8493 1038.936 367.3314 1039.634 367.8135 1029.892 368.2956 1022.762 368.7777 1018.085 369.2599 1014.462 369.7420 1013.284 370.2241 1012.312 370.7062 1007.897 371.1883 999.5889 371.6704 987.9458 372.1526 971.1228 372.6347 950.3901 373.1168 933.3245 373.5989 932.9043 374.0810 927.5220 374.5631 889.8772 375.0453 824.3828 375.5274 772.7795 376.0095 767.7942 376.4916 792.7788 376.9737 775.8728 377.4558 677.1670 377.9380 587.2732 378.4201 547.7534 378.9022 538.9929 379.3843 523.2510 379.8664 485.1230 380.3485 435.6064 380.8307 398.3110 381.3128 381.7908 381.7949 361.4797 382.2770 330.9248 382.7591 298.5603 383.2412 273.8228 383.7234 257.9187 384.2055 244.0371 384.6876 223.8198 385.1697 194.2476 385.6518 171.4114 386.1339 166.0151 386.6161 156.3376 387.0982 121.3433 387.5803 71.31445 388.0624 37.51270 388.5445 45.66040 389.0266 90.16748 389.5088 109.9465 389.9909 79.57935 390.4730 51.88794 390.9551 35.16431 391.4372 26.35791 391.9193 22.34448 392.4015 21.95654 392.8836 22.27441 393.3657 15.94556 393.8478 2.497070 394.3299 13.85083 394.8120 11.84375 395.2942 5.005859 395.7763 1.486328 396.2584 6.744873 396.7405 12.55615 397.2226 22.73560 397.7047 37.33130 398.1869 44.86890 398.6690 41.13306 399.1511 33.93481 399.6332 29.44751 400.1153 25.76489 400.5974 16.87402 401.0796 8.012207 401.5617 38.02393 402.0438 45.43335 402.5259 24.19800 403.0080 4.176025 403.4901 4.784180 403.9723 15.99927 404.4544 22.91528 404.9365 20.96094 405.4186 17.70117 405.9007 20.95508 406.3828 29.15283 406.8650 33.04858 407.3471 27.84717 407.8292 18.83081 408.3113 16.64331 408.7934 24.42114 409.2755 23.69922 409.7577 8.0565996E-02 410.2398 32.21069 410.7219 51.44556 411.2040 53.95312 411.6861 51.24561 412.1682 53.81250 412.6504 62.27490 413.1325 74.08032 413.6146 97.15771 414.0967 116.3274 414.5788 121.7419 415.0609 115.7935 415.5431 106.1277 416.0252 96.77026 416.5073 88.46460 416.9894 84.56177 417.4715 82.82959 417.9536 88.66504 418.4358 112.6843 418.9179 139.9182 419.4000 151.8547 419.8821 143.7529 420.3642 129.4019 420.8463 131.2107 421.3285 158.2776 421.8106 176.4436 422.2927 179.7642 422.7748 179.8870 423.2569 179.5737 423.7390 180.6130 424.2212 186.2878 424.7033 201.2444 425.1854 223.1072 425.6675 235.9067 426.1496 229.7756 426.6317 231.5332 427.1139 264.2043 427.5960 305.3230 428.0781 322.7261 428.5602 299.1038 429.0423 266.0486 429.5244 267.0554 430.0066 303.0312 430.4887 331.9104 430.9708 340.8276 431.4529 338.2087 431.9350 331.6548 432.4171 320.5825 432.8993 316.5527 433.3814 328.8760 433.8635 350.9663 434.3456 371.6309 434.8277 389.4551 435.3098 405.5693 435.7920 422.1831 436.2741 438.4502 436.7562 447.3362 437.2383 440.1406 437.7204 433.2776 438.2025 433.3477 438.6847 441.3411 439.1668 462.8455 439.6489 503.6567 440.1310 551.1436 440.6131 570.4180 441.0952 530.5105 441.5774 505.7661 442.0595 509.0630 442.5416 523.3752 443.0237 536.2703 443.5058 544.1375 443.9879 546.0491 444.4701 540.0762 444.9522 524.8657 445.4343 511.5969 445.9164 494.2473 446.3985 485.1267 446.8806 493.8889 447.3628 513.2593 447.8449 531.3733 448.3270 543.0303 448.8091 546.6113 449.2912 535.5291 449.7733 502.8408 450.2555 474.9333 450.7376 461.6616 451.2197 453.9294 451.7018 441.2249 452.1839 421.7695 452.6660 414.0420 453.1482 453.5781 453.6303 523.0051 454.1124 533.1072 454.5945 452.3083 455.0766 358.6492 455.5587 320.7788 456.0409 323.0090 456.5230 324.1440 457.0051 312.9358 457.4872 298.4438 457.9693 289.1931 458.4514 284.1174 458.9336 278.1016 459.4156 268.6660 459.8978 257.3208 460.3799 245.6592 460.8620 232.7109 461.3441 219.9219 461.8262 204.7998 462.3083 191.5222 462.7905 186.2561 463.2726 187.9778 463.7547 189.0986 464.2368 184.6316 464.7189 175.0073 465.2010 163.3860 465.6832 141.4543 466.1653 126.2141 466.6474 123.0747 467.1295 129.1511 467.6116 143.2290 468.0938 164.6379 468.5759 187.2070 469.0580 192.8674 469.5401 159.3633 470.0222 170.0242 470.5043 176.4343 470.9865 179.7029 471.4686 167.4934 471.9507 174.4744 472.4328 172.7559 472.9149 170.7048 473.3970 179.9534 473.8792 168.3806 474.3613 177.4507 474.8434 178.2808 475.3255 184.5112 475.8076 192.0969 476.2897 194.2563 476.7719 181.5713 477.2540 170.5552 477.7361 177.8423 478.2182 180.9807 478.7003 180.1943 479.1824 163.7219 479.6646 167.5029 480.1467 163.1687 480.6288 158.5012 481.1109 165.1343 481.5930 150.9453 482.0751 152.3079 482.5573 152.4641 483.0394 152.2100 483.5215 148.3464 484.0036 138.2886 484.4857 122.8706 484.9678 107.3044 485.4500 83.31226 485.9321 70.95044 486.4142 78.98267 486.8963 95.93408 487.3784 112.9006 487.8605 126.9192 488.3427 136.6460 488.8248 135.4548 489.3069 122.2146 489.7890 127.9629 490.2711 168.3091 490.7532 209.3140 491.2354 227.7598 491.7175 232.7336 492.1996 246.1997 492.6817 280.5901 493.1638 322.8752 493.6459 355.4910 494.1281 379.6846 494.6102 413.4199 495.0923 468.1240 495.5744 530.3020 496.0565 574.2021 496.5386 595.8291 497.0208 622.2185 497.5029 664.6797 497.9850 711.7661 498.4671 751.4214 498.9492 783.0132 499.4313 815.7827 499.9135 860.3035 500.3956 913.3025 500.8777 932.0300 501.3598 893.4746 501.8419 848.0012 502.3240 799.9304 502.8062 750.7388 503.2883 699.9868 503.7704 648.0410 504.2525 597.9124 504.7346 553.5049 505.2167 515.8467 505.6989 478.4783 506.1810 445.5608 506.6631 407.6912 507.1452 355.2542 507.6273 295.1348 508.1094 242.1577 508.5916 202.6196 509.0737 173.1077 509.5558 151.2451 510.0379 136.9060 510.5200 124.4990 511.0021 113.1538 511.4843 101.6223 511.9664 86.95044 512.4485 68.17603 512.9306 53.12988 513.4127 48.59424 513.8948 45.67700 514.3770 32.64673 514.8591 10.71460 515.3412 6.604248 515.8233 9.214600 516.3054 0.4353030 516.7875 6.734863 517.2697 6.160889 517.7518 6.554932 518.2339 13.30420 518.7160 18.70898 519.1981 11.58472 519.6802 8.428955 520.1624 26.94165 520.6445 24.68823 521.1266 0.8559570 521.6087 9.789795 522.0908 0.1762700 522.5729 12.80737 523.0551 23.21973 523.5372 30.12769 524.0193 30.05566 524.5014 18.78955 524.9835 7.804688 525.4656 12.33081 525.9478 28.58740 526.4299 35.42383 526.9120 24.87549 527.3941 10.06226 527.8762 8.492432 528.3583 21.01538 528.8405 24.36108 529.3226 7.477295 529.8047 11.35278 530.2868 21.30273 530.7689 23.23291 531.2510 19.86133 531.7332 11.88818 532.2153 3.799316 532.6974 7.633789 533.1795 35.54785 533.6616 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560.6602 546.8811 561.1423 521.3379 561.6244 489.3359 562.1065 445.0864 562.5886 400.1492 563.0707 354.8418 563.5529 312.2783 564.0350 277.1104 564.5171 251.9822 564.9992 233.6108 565.4813 218.9993 565.9634 207.9414 566.4456 197.3003 566.9277 186.7417 567.4098 175.6482 567.8919 162.2217 568.3740 146.8826 568.8561 134.4045 569.3383 129.3523 569.8204 123.7158 570.3025 110.4270 570.7846 92.39209 571.2667 76.51025 571.7488 65.62622 572.2310 59.00342 572.7131 56.06958 573.1952 58.64062 573.6773 58.28491 574.1594 48.09131 574.6415 42.96021 575.1237 52.05322 575.6058 70.98096 576.0879 90.97192 576.5700 109.2227 577.0521 122.6772 577.5342 123.0818 578.0164 109.8381 578.4985 100.0183 578.9806 96.11426 579.4627 100.5583 579.9448 123.5894 580.4269 161.8135 580.9091 187.9028 581.3912 190.4465 581.8733 185.8252 582.3554 183.9619 582.8375 184.5991 583.3196 184.6860 583.8018 182.5894 584.2839 180.1091 584.7660 180.3115 585.2481 183.2246 585.7302 189.0442 586.2123 208.6885 586.6945 219.0151 587.1766 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