#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-05-24 16:34:28 +0300 (Thu, 24 May 2018) $ #$Revision: 904 $ #$URL: svn://172.16.1.111/rod/cif/1/00/03/1000382.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000382 loop_ _publ_author_name 'Novak, G. A.' 'Gibbs, G. V.' _publ_section_title ; The crystal chemistry of the silicate garnets sample An ; _journal_name_full 'American Mineralogist' _journal_page_first 791 _journal_page_last 823 _journal_volume 56 _journal_year 1971 _chemical_compound_source R070722 _chemical_formula_sum 'Ca3 Fe2 O12 Si3' _chemical_name_mineral Andradite _space_group_IT_number 230 _symmetry_space_group_name_Hall '-I 4bd 2c 3' _symmetry_space_group_name_H-M 'I a -3 d' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 12.058 _cell_length_b 12.058 _cell_length_c 12.058 _cell_volume 1753.177 _exptl_crystal_density_diffrn 3.851 _cod_original_formula_sum 'Si3 Fe2 Ca3 O12' _cod_database_code 9000239 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R070722.rod _rod_data_source.block 3500000 _rod_database.code 1000382 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9000239 COD http://www.crystallography.net/cod/9000239.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 127.2373 0.0000000E+00 127.7194 49.19629 128.2015 98.06152 128.6837 134.3818 129.1658 142.6426 129.6479 84.09863 130.1300 34.24512 130.6121 9.210938 131.0942 0.9785160 131.5764 0.8251950 132.0585 0.1562500 132.5406 7.616211 133.0227 19.74414 133.5048 44.16406 133.9869 58.55469 134.4691 58.18359 134.9512 47.63574 135.4333 34.79590 135.9154 21.91016 136.3975 10.15039 136.8796 1.138672 137.3618 4.907227 137.8439 6.940430 138.3260 29.54199 138.8081 29.46680 139.2902 31.74121 139.7723 60.32812 140.2545 114.4033 140.7366 147.4346 141.2187 150.0352 141.7008 133.5088 142.1829 104.0928 142.6650 58.49805 143.1472 17.22266 143.6293 2.635742 144.1114 9.965820 144.5935 25.85547 145.0756 55.20703 145.5577 90.69238 146.0399 107.3057 146.5220 95.45605 147.0041 67.74023 147.4862 29.62109 147.9683 17.53711 148.4504 56.54102 148.9326 71.23730 149.4147 60.08203 149.8968 42.40234 150.3789 12.30957 150.8610 17.77637 151.3431 37.74316 151.8252 45.80078 152.3074 53.46777 152.7895 82.06250 153.2716 150.3574 153.7537 198.4736 154.2358 210.0547 154.7179 207.2822 155.2001 209.7588 155.6822 225.9707 156.1643 249.5361 156.6464 260.3623 157.1285 231.0957 157.6106 220.6279 158.0928 248.6777 158.5749 296.1885 159.0570 336.5420 159.5391 353.1650 160.0212 348.9072 160.5033 354.8008 160.9855 364.8408 161.4676 389.0186 161.9497 447.7158 162.4318 527.0928 162.9139 588.5596 163.3960 599.0840 163.8782 556.1289 164.3603 533.4717 164.8424 538.1289 165.3245 554.9287 165.8066 582.3789 166.2887 618.6816 166.7709 644.8105 167.2530 635.7910 167.7351 592.3623 168.2172 567.0547 168.6993 571.8701 169.1814 595.0557 169.6636 625.8389 170.1457 665.1416 170.6278 703.0137 171.1099 731.1562 171.5920 750.8516 172.0741 758.8721 172.5563 741.0547 173.0384 709.2441 173.5205 698.6572 174.0026 719.9707 174.4847 758.0273 174.9668 801.8184 175.4490 850.6855 175.9311 894.5928 176.4132 930.4678 176.8953 958.1523 177.3774 967.2188 177.8595 942.5840 178.3417 907.6318 178.8238 869.6504 179.3059 830.6221 179.7880 804.5146 180.2701 805.4404 180.7522 833.8584 181.2344 888.9893 181.7165 1031.244 182.1986 1161.144 182.6807 1204.945 183.1628 1144.371 183.6449 1033.214 184.1271 960.5498 184.6092 943.7939 185.0913 934.2139 185.5734 931.0684 186.0555 929.1768 186.5376 918.9102 187.0198 896.5635 187.5019 874.8154 187.9840 888.5527 188.4661 995.6045 188.9482 1065.361 189.4303 1065.619 189.9125 1031.470 190.3946 1003.045 190.8767 1000.691 191.3588 1018.985 191.8409 1032.154 192.3230 1038.839 192.8052 1041.850 193.2873 1027.000 193.7694 1009.573 194.2515 1021.207 194.7336 1086.201 195.2157 1194.600 195.6979 1248.463 196.1800 1200.790 196.6621 1159.811 197.1442 1161.909 197.6263 1203.206 198.1084 1271.123 198.5906 1367.599 199.0727 1485.362 199.5548 1551.403 200.0369 1519.392 200.5190 1480.225 201.0011 1485.643 201.4833 1535.009 201.9654 1601.177 202.4475 1670.807 202.9296 1742.523 203.4117 1800.060 203.8938 1832.947 204.3760 1859.377 204.8581 1898.019 205.3402 1951.835 205.8223 2003.000 206.3044 2018.661 206.7865 2013.965 207.2687 2046.880 207.7508 2158.816 208.2329 2302.329 208.7150 2407.768 209.1971 2461.774 209.6792 2512.486 210.1614 2611.457 210.6435 2737.654 211.1256 2841.541 211.6077 2877.632 212.0898 2884.897 212.5719 2956.293 213.0541 3126.436 213.5362 3293.649 214.0183 3375.049 214.5004 3398.429 214.9825 3431.561 215.4646 3511.466 215.9468 3630.776 216.4289 3758.271 216.9110 3898.047 217.3931 4036.446 217.8752 4170.646 218.3573 4301.664 218.8395 4427.406 219.3216 4540.736 219.8037 4640.339 220.2858 4741.495 220.7679 4836.260 221.2500 4948.527 221.7322 5101.670 222.2143 5283.706 222.6964 5458.603 223.1785 5599.246 223.6606 5705.064 224.1427 5790.448 224.6249 5840.255 225.1070 5880.676 225.5891 5920.088 226.0712 5958.675 226.5533 5993.717 227.0354 6026.535 227.5176 6060.197 227.9997 6067.891 228.4818 6039.879 228.9639 5992.658 229.4460 5931.739 229.9281 5857.191 230.4103 5765.168 230.8924 5650.447 231.3745 5508.053 231.8566 5362.268 232.3387 5196.420 232.8208 5040.320 233.3030 4909.392 233.7851 4802.812 234.2672 4713.030 234.7493 4642.520 235.2314 4622.809 235.7135 4500.777 236.1957 4199.758 236.6778 3877.208 237.1599 3609.069 237.6420 3405.062 238.1241 3239.498 238.6062 3085.296 239.0884 2941.924 239.5705 2813.397 240.0526 2695.653 240.5347 2593.163 241.0168 2515.357 241.4989 2459.475 241.9811 2412.248 242.4632 2361.656 242.9453 2319.843 243.4274 2227.735 243.9095 2048.228 244.3916 1854.390 244.8738 1681.531 245.3559 1539.204 245.8380 1426.019 246.3201 1343.436 246.8022 1305.226 247.2843 1255.902 247.7665 1196.663 248.2486 1126.558 248.7307 1035.549 249.2128 926.2227 249.6949 823.1904 250.1770 756.5645 250.6592 741.9043 251.1413 712.5576 251.6234 646.7295 252.1055 581.8164 252.5876 555.0693 253.0697 567.9209 253.5519 580.8027 254.0340 548.2109 254.5161 453.9492 254.9982 374.3965 255.4803 310.5312 255.9624 260.5459 256.4445 225.6963 256.9267 205.5166 257.4088 194.6250 257.8909 191.4023 258.3730 200.3789 258.8551 184.3438 259.3372 109.9189 259.8194 32.05273 260.3015 1.591797 260.7836 22.56934 261.2657 55.05664 261.7478 62.88477 262.2299 41.82227 262.7121 9.558594 263.1942 52.20996 263.6763 112.9805 264.1584 146.0049 264.6405 149.2764 265.1227 140.6309 265.6048 134.6660 266.0869 131.6045 266.5690 126.3379 267.0511 118.8887 267.5332 109.0850 268.0154 90.65918 268.4975 64.45410 268.9796 50.18262 269.4617 69.72852 269.9438 123.0127 270.4259 158.2686 270.9081 163.3672 271.3902 157.7354 271.8723 154.7949 272.3544 155.4287 272.8365 157.7520 273.3186 163.1992 273.8008 169.7363 274.2829 163.7236 274.7650 125.9268 275.2471 89.58789 275.7292 89.19434 276.2113 121.8262 276.6935 143.6016 277.1756 121.0176 277.6577 58.89258 278.1398 8.424805 278.6219 26.85938 279.1040 53.73828 279.5862 73.61328 280.0683 87.58398 280.5504 102.2432 281.0325 120.0576 281.5146 142.5293 281.9967 172.1191 282.4789 206.9961 282.9610 250.3506 283.4431 305.8926 283.9252 372.5732 284.4073 444.0010 284.8894 517.9277 285.3716 594.1035 285.8537 672.1602 286.3358 755.8154 286.8179 836.4092 287.3000 907.4941 287.7821 970.9277 288.2643 1031.813 288.7464 1090.618 289.2285 1151.007 289.7106 1220.215 290.1927 1296.105 290.6748 1382.687 291.1570 1484.039 291.6391 1598.216 292.1212 1718.656 292.6033 1843.418 293.0854 1972.825 293.5675 2108.514 294.0497 2255.861 294.5318 2397.778 295.0139 2520.296 295.4960 2632.624 295.9781 2755.079 296.4602 2893.519 296.9424 3046.238 297.4245 3216.130 297.9066 3412.057 298.3887 3585.636 298.8708 3713.667 299.3529 3810.926 299.8351 3897.478 300.3172 3974.572 300.7993 4056.231 301.2814 4163.810 301.7635 4294.927 302.2456 4444.639 302.7278 4636.322 303.2099 4836.617 303.6920 4998.830 304.1741 5113.030 304.6562 5197.454 305.1383 5266.049 305.6205 5317.514 306.1026 5373.836 306.5847 5441.411 307.0668 5513.331 307.5489 5584.454 308.0310 5654.344 308.5132 5720.354 308.9953 5785.150 309.4774 5847.467 309.9595 5877.605 310.4416 5857.576 310.9237 5816.890 311.4059 5776.869 311.8880 5738.821 312.3701 5695.979 312.8522 5644.309 313.3343 5582.549 313.8164 5506.797 314.2986 5405.099 314.7807 5301.134 315.2628 5204.359 315.7449 5116.312 316.2270 5036.204 316.7091 4959.506 317.1913 4892.915 317.6734 4870.315 318.1555 4945.010 318.6376 4999.814 319.1197 4960.973 319.6018 4865.930 320.0840 4806.380 320.5661 4829.948 321.0482 4908.296 321.5303 4956.738 322.0124 4948.783 322.4945 4956.824 322.9767 5005.699 323.4588 5077.943 323.9409 5146.544 324.4230 5201.205 324.9051 5252.338 325.3872 5321.207 325.8694 5409.497 326.3515 5514.782 326.8336 5652.438 327.3157 5795.932 327.7978 5917.926 328.2799 6012.741 328.7621 6094.460 329.2442 6182.059 329.7263 6281.242 330.2084 6368.485 330.6905 6419.641 331.1726 6475.853 331.6548 6580.227 332.1369 6730.924 332.6190 6881.310 333.1011 6978.443 333.5832 7005.910 334.0653 7055.408 334.5475 7136.436 335.0296 7229.484 335.5117 7327.877 335.9938 7429.913 336.4759 7537.844 336.9580 7655.641 337.4402 7783.023 337.9223 7900.826 338.4044 7987.096 338.8865 8087.292 339.3686 8214.279 339.8507 8363.809 340.3329 8528.076 340.8150 8704.362 341.2971 8889.784 341.7792 9072.782 342.2613 9242.853 342.7434 9424.453 343.2256 9617.147 343.7077 9822.945 344.1898 10039.73 344.6719 10266.99 345.1540 10513.99 345.6361 10802.24 346.1183 11140.34 346.6004 11506.61 347.0825 11898.01 347.5646 12309.35 348.0467 12737.80 348.5288 13180.69 349.0110 13645.27 349.4931 14139.81 349.9752 14672.40 350.4573 15209.31 350.9394 15734.42 351.4215 16283.49 351.9037 16882.47 352.3858 17526.18 352.8679 18185.52 353.3500 18823.92 353.8321 19443.19 354.3142 20128.26 354.7964 20919.61 355.2785 21722.50 355.7606 22495.47 356.2427 23257.96 356.7248 24050.29 357.2069 24899.62 357.6891 25780.60 358.1712 26612.05 358.6533 27364.47 359.1354 28152.68 359.6175 29060.10 360.0996 30007.00 360.5818 30902.39 361.0639 31711.64 361.5460 32482.46 362.0281 33291.11 362.5102 34152.86 362.9923 34931.98 363.4745 35590.18 363.9566 36132.49 364.4387 36567.89 364.9208 36902.22 365.4029 37112.64 365.8850 37183.43 366.3672 37113.29 366.8493 36911.15 367.3314 36599.66 367.8135 36118.80 368.2956 35399.36 368.7777 34462.04 369.2599 33417.50 369.7420 32289.58 370.2241 31092.12 370.7062 29844.81 371.1883 28543.88 371.6704 27232.25 372.1526 25930.42 372.6347 24630.41 373.1168 23314.05 373.5989 21917.76 374.0810 20550.54 374.5631 19293.96 375.0453 18140.90 375.5274 17046.15 376.0095 15976.16 376.4916 14943.56 376.9737 13981.20 377.4558 13100.42 377.9380 12262.01 378.4201 11446.28 378.9022 10660.45 379.3843 9929.102 379.8664 9263.751 380.3485 8648.781 380.8307 8064.937 381.3128 7506.995 381.7949 6987.727 382.2770 6513.262 382.7591 6073.755 383.2412 5668.034 383.7234 5293.374 384.2055 4944.958 384.6876 4620.171 385.1697 4320.668 385.6518 4037.942 386.1339 3777.160 386.6161 3524.804 387.0982 3261.293 387.5803 2997.905 388.0624 2769.928 388.5445 2604.724 389.0266 2496.470 389.5088 2385.661 389.9909 2295.652 390.4730 2173.866 390.9551 1971.579 391.4372 1746.494 391.9193 1574.204 392.4015 1488.397 392.8836 1453.076 393.3657 1395.344 393.8478 1306.811 394.3299 1216.948 394.8120 1124.060 395.2942 1035.131 395.7763 955.6641 396.2584 886.0674 396.7405 822.1416 397.2226 759.6162 397.7047 698.7695 398.1869 640.6943 398.6690 587.0674 399.1511 534.5088 399.6332 478.5293 400.1153 421.9072 400.5974 372.1328 401.0796 335.0176 401.5617 307.0195 402.0438 282.6074 402.5259 264.4600 403.0080 239.3320 403.4901 187.5576 403.9723 127.6982 404.4544 89.68750 404.9365 85.63281 405.4186 92.57715 405.9007 98.34180 406.3828 101.1719 406.8650 88.67285 407.3471 49.32617 407.8292 2.187500 408.3113 20.19043 408.7934 14.86230 409.2755 9.521484 409.7577 8.175781 410.2398 12.17969 410.7219 27.93164 411.2040 56.53906 411.6861 80.83008 412.1682 79.80469 412.6504 48.45020 413.1325 39.77441 413.6146 82.93262 414.0967 121.2949 414.5788 114.8809 415.0609 75.26172 415.5431 41.78809 416.0252 39.26270 416.5073 60.52637 416.9894 72.16797 417.4715 54.82422 417.9536 51.20703 418.4358 78.51074 418.9179 115.3760 419.4000 140.2188 419.8821 146.1904 420.3642 139.5449 420.8463 126.6699 421.3285 99.19629 421.8106 88.99414 422.2927 122.7588 422.7748 149.5059 423.2569 137.4609 423.7390 93.72266 424.2212 48.80762 424.7033 23.78516 425.1854 17.40234 425.6675 25.09863 426.1496 61.90820 426.6317 86.70801 427.1139 72.06934 427.5960 42.05273 428.0781 30.38965 428.5602 54.26465 429.0423 83.79102 429.5244 73.84961 430.0066 23.17285 430.4887 8.890625 430.9708 5.589844 431.4529 35.42969 431.9350 44.79883 432.4171 32.79395 432.8993 17.49512 433.3814 5.002930 433.8635 4.486328 434.3456 7.911133 434.8277 3.640625 435.3098 4.101563 435.7920 24.16895 436.2741 61.55273 436.7562 84.42676 437.2383 77.21484 437.7204 68.57227 438.2025 76.28223 438.6847 96.54492 439.1668 117.9053 439.6489 135.3916 440.1310 148.6426 440.6131 156.2559 441.0952 140.4648 441.5774 144.4941 442.0595 186.5752 442.5416 239.8154 443.0237 279.8525 443.5058 302.6143 443.9879 318.4463 444.4701 337.4717 444.9522 358.7256 445.4343 389.8018 445.9164 450.4385 446.3985 500.8447 446.8806 521.5010 447.3628 523.1875 447.8449 525.4316 448.3270 537.8926 448.8091 559.6270 449.2912 589.2988 449.7733 628.6562 450.2555 670.9580 450.7376 718.9346 451.2197 766.3887 451.7018 813.0801 452.1839 858.4307 452.6660 889.0791 453.1482 881.2334 453.6303 845.9043 454.1124 841.1602 454.5945 890.3975 455.0766 933.7422 455.5587 907.1660 456.0409 832.0752 456.5230 768.8682 457.0051 747.5986 457.4872 730.4561 457.9693 676.3955 458.4514 592.2012 458.9336 520.7363 459.4156 485.9775 459.8978 472.4082 460.3799 437.5889 460.8620 368.3027 461.3441 306.6348 461.8262 268.1709 462.3083 236.3125 462.7905 189.8232 463.2726 126.5586 463.7547 65.63281 464.2368 26.53711 464.7189 10.85059 465.2010 3.875000 465.6832 4.306641 466.1653 13.32129 466.6474 40.31445 467.1295 75.76953 467.6116 103.4775 468.0938 114.1855 468.5759 116.5850 469.0580 130.7783 469.5401 159.6318 470.0222 195.0703 470.5043 246.6504 470.9865 297.9033 471.4686 332.5039 471.9507 351.3643 472.4328 374.3213 472.9149 420.5547 473.3970 483.1865 473.8792 534.8027 474.3613 568.4678 474.8434 603.1738 475.3255 653.9561 475.8076 715.3340 476.2897 777.4902 476.7719 842.8428 477.2540 903.5625 477.7361 944.6787 478.2182 977.2080 478.7003 1037.525 479.1824 1143.111 479.6646 1264.572 480.1467 1352.982 480.6288 1396.664 481.1109 1449.326 481.5930 1516.625 482.0751 1594.443 482.5573 1682.338 483.0394 1776.748 483.5215 1869.757 484.0036 1954.733 484.4857 2032.748 484.9678 2107.678 485.4500 2161.560 485.9321 2238.396 486.4142 2358.417 486.8963 2490.982 487.3784 2612.769 487.8605 2718.408 488.3427 2810.703 488.8248 2881.796 489.3069 2928.753 489.7890 3008.493 490.2711 3163.696 490.7532 3301.285 491.2354 3352.884 491.7175 3350.665 492.1996 3373.230 492.6817 3473.938 493.1638 3588.006 493.6459 3634.476 494.1281 3617.599 494.6102 3594.850 495.0923 3585.853 495.5744 3584.287 496.0565 3581.138 496.5386 3578.331 497.0208 3566.855 497.5029 3539.670 497.9850 3505.717 498.4671 3474.053 498.9492 3445.290 499.4313 3413.660 499.9135 3372.872 500.3956 3324.775 500.8777 3292.990 501.3598 3304.501 501.8419 3300.041 502.3240 3233.857 502.8062 3163.716 503.2883 3164.688 503.7704 3255.375 504.2525 3374.577 504.7346 3433.084 505.2167 3414.806 505.6989 3452.443 506.1810 3578.105 506.6631 3730.146 507.1452 3878.662 507.6273 4029.374 508.1094 4197.184 508.5916 4389.441 509.0737 4600.366 509.5558 4814.330 510.0379 5031.632 510.5200 5287.772 511.0021 5601.211 511.4843 5952.521 511.9664 6316.659 512.4485 6694.492 512.9306 7074.252 513.4127 7442.648 513.8948 7816.513 514.3770 8214.693 514.8591 8636.864 515.3412 9061.351 515.8233 9466.609 516.3054 9865.256 516.7875 10323.34 517.2697 10900.26 517.7518 11467.42 518.2339 12027.76 518.7160 12567.60 519.1981 13069.67 519.6802 13534.93 520.1624 13982.08 520.6445 14451.94 521.1266 14947.88 521.6087 15330.92 522.0908 15577.87 522.5729 15734.11 523.0551 15846.90 523.5372 15888.12 524.0193 15811.41 524.5014 15599.72 524.9835 15274.41 525.4656 14834.36 525.9478 14293.04 526.4299 13709.36 526.9120 13101.01 527.3941 12454.57 527.8762 11734.73 528.3583 10938.06 528.8405 10182.98 529.3226 9497.531 529.8047 8839.689 530.2868 8159.921 530.7689 7480.146 531.2510 6860.256 531.7332 6331.777 532.2153 5873.320 532.6974 5433.324 533.1795 5000.225 533.6616 4611.068 534.1437 4283.748 534.6259 3979.171 535.1080 3671.014 535.5901 3362.151 536.0722 3077.499 536.5543 2834.812 537.0364 2629.964 537.5186 2457.393 538.0007 2321.557 538.4828 2199.305 538.9649 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565.9634 185.6885 566.4456 125.0635 566.9277 90.90332 567.4098 67.88965 567.8919 40.39209 568.3740 9.154785 568.8561 18.41699 569.3383 40.57861 569.8204 59.64746 570.3025 76.10059 570.7846 90.96338 571.2667 109.4297 571.7488 134.0127 572.2310 153.6421 572.7131 145.3374 573.1952 93.64746 573.6773 57.21191 574.1594 53.28271 574.6415 46.56885 575.1237 21.54053 575.6058 17.98242 576.0879 63.88477 576.5700 115.3779 577.0521 163.0923 577.5342 191.4707 578.0164 200.3794 578.4985 203.2153 578.9806 201.4302 579.4627 196.2954 579.9448 188.5669 580.4269 178.6445 580.9091 169.4077 581.3912 167.5967 581.8733 162.9478 582.3554 141.0605 582.8375 109.3022 583.3196 86.50000 583.8018 80.54980 584.2839 86.12646 584.7660 97.55371 585.2481 127.1938 585.7302 126.3472 586.2123 60.04297 586.6945 0.2246090 587.1766 20.05664 587.6587 10.58643 588.1408 0.7138670 588.6229 6.409180 589.1050 16.17432 589.5872 10.38672 590.0693 10.54346 590.5514 28.97510 591.0335 43.68164 591.5156 50.94092 591.9977 41.38330 592.4799 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619.4784 111.4775 619.9605 114.5430 620.4426 123.9224 620.9247 136.1758 621.4069 146.8955 621.8890 138.6084 622.3711 107.1304 622.8532 90.93604 623.3353 113.2168 623.8174 141.5854 624.2996 140.1172 624.7817 111.2891 625.2638 87.36084 625.7459 76.00537 626.2280 72.37988 626.7101 75.32617 627.1923 82.51611 627.6744 91.19385 628.1565 100.5811 628.6386 103.7920 629.1207 86.87158 629.6028 40.12939 630.0850 10.53809 630.5671 17.32910 631.0492 26.59375 631.5313 24.84180 632.0134 16.71436 632.4955 11.64893 632.9777 13.49463 633.4598 19.58154 633.9419 31.82861 634.4240 46.25146 634.9061 46.83398 635.3882 29.59814 635.8704 12.63086 636.3525 10.21143 636.8346 19.86816 637.3167 24.89746 637.7988 27.32227 638.2809 22.77881 638.7631 3.961426 639.2452 17.62402 639.7273 32.29932 640.2094 38.76270 640.6915 39.49365 641.1736 35.66357 641.6558 28.08154 642.1379 19.77832 642.6200 11.09180 643.1021 0.2866210 643.5842 22.43945 644.0663 40.14160 644.5485 32.35400 645.0306 0.2280270 645.5127 21.15332 645.9948 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672.9933 157.4409 673.4755 137.1030 673.9576 128.5635 674.4397 139.5352 674.9218 148.8350 675.4039 131.3555 675.8860 98.83008 676.3682 85.65918 676.8503 104.9980 677.3324 128.8232 677.8145 108.3203 678.2966 32.08350 678.7787 6.387207 679.2609 64.35254 679.7430 125.4307 680.2251 168.9531 680.7072 192.2632 681.1893 186.8843 681.6714 147.9038 682.1536 108.2192 682.6357 80.33057 683.1178 65.97412 683.5999 73.37012 684.0820 99.54639 684.5641 126.9160 685.0463 146.3560 685.5284 157.0215 686.0105 156.3291 686.4926 135.1865 686.9747 123.0879 687.4568 130.9473 687.9390 138.6597 688.4211 131.9434 688.9032 120.1450 689.3853 125.4399 689.8674 160.7896 690.3495 191.8765 690.8317 179.6738 691.3138 143.2261 691.7959 126.0176 692.2780 134.4346 692.7601 154.1992 693.2422 177.2295 693.7244 200.4434 694.2065 211.7524 694.6886 194.2612 695.1707 188.8140 695.6528 208.5376 696.1349 232.4731 696.6171 246.6353 697.0992 250.9199 697.5813 253.4585 698.0634 260.9775 698.5455 265.8745 699.0276 253.5332 699.5098 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