#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 10:41:39 +0300 (Thu, 07 Jun 2018) $ #$Revision: 928 $ #$URL: svn://172.16.1.111/rod/cif/1/00/04/1000400.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000400 loop_ _publ_author_name 'Giuseppetti, G.' 'Mazzi, F.' 'Tadini, C.' _publ_section_title ; The crystal structure of chalcosiderite, CuFe3+6(PO4)4(OH)8*4H2O Locality: Wheal Phoenix Mine, Cornwall, England ; _journal_name_full 'Neues Jahrbuch fur Mineralogie, Monatshefte' _journal_page_first 227 _journal_page_last 239 _journal_volume 1989 _journal_year 1989 _chemical_compound_source R060007 _chemical_formula_sum 'Al0.54 Cu Fe5.46 H16 O28 P4' _chemical_name_mineral Chalcosiderite _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 67.57 _cell_angle_beta 69.17 _cell_angle_gamma 64.93 _cell_length_a 7.653 _cell_length_b 7.873 _cell_length_c 10.190 _cell_volume 500.076 _exptl_crystal_density_diffrn 3.224 _cod_original_formula_sum 'Cu (Fe5.46 Al.54) P4 O28 H16' _cod_database_code 9009359 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R060007.rod _rod_data_source.block 3500000 _rod_database.code 1000400 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9009359 COD http://www.crystallography.net/cod/9009359.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 156.0814 0.0000000E+00 156.5635 2.415527 157.0456 3.670288 157.5278 5.971313 158.0099 7.003662 158.4920 3.366455 158.9741 1.222900 159.4562 0.8913570 159.9383 0.5642090 160.4205 2.8320000E-02 160.9026 0.4492190 161.3847 2.004761 161.8668 2.592285 162.3489 1.097168 162.8310 1.601440 163.3132 4.485352 163.7953 6.660156 164.2774 9.320801 164.7595 13.23206 165.2416 18.59082 165.7237 24.08936 166.2059 28.76013 166.6880 33.20935 167.1701 38.36731 167.6522 43.93323 168.1343 50.74634 168.6164 59.79248 169.0986 71.61292 169.5807 83.74463 170.0628 94.13452 170.5449 103.6998 171.0270 114.1267 171.5091 126.1051 171.9913 139.4229 172.4734 154.0370 172.9555 170.2008 173.4376 187.0371 173.9197 203.6138 174.4018 220.2666 174.8840 237.8126 175.3661 256.8521 175.8482 276.8365 176.3303 297.0173 176.8124 317.3984 177.2945 337.8209 177.7767 358.3020 178.2588 378.9003 178.7409 399.0120 179.2230 418.7332 179.7051 437.8876 180.1872 455.8945 180.6694 472.7952 181.1515 488.5869 181.6336 501.9210 182.1157 513.2683 182.5978 525.9480 183.0799 544.1733 183.5621 565.8494 184.0442 584.6687 184.5263 598.8663 185.0084 610.6896 185.4905 624.0476 185.9726 638.8416 186.4547 653.9263 186.9369 668.8303 187.4190 683.4656 187.9011 696.7501 188.3832 708.1320 188.8653 718.5525 189.3474 730.5232 189.8296 744.2275 190.3117 757.4879 190.7938 767.7750 191.2759 775.5786 191.7580 784.6863 192.2401 796.3864 192.7223 809.7948 193.2044 822.5203 193.6865 834.6403 194.1686 846.2722 194.6507 857.3870 195.1328 867.9751 195.6150 878.2401 196.0971 888.2148 196.5792 897.7905 197.0613 906.5605 197.5434 914.4341 198.0255 921.7397 198.5077 928.7302 198.9898 935.4431 199.4719 941.2819 199.9540 945.9545 200.4361 949.6177 200.9182 953.2417 201.4004 956.9109 201.8825 960.2961 202.3646 963.3789 202.8467 966.3190 203.3288 967.7413 203.8109 967.4241 204.2931 965.3616 204.7752 961.0354 205.2573 953.9160 205.7394 945.8314 206.2215 939.2301 206.7036 934.9401 207.1858 928.1764 207.6679 917.6741 208.1500 903.6172 208.6321 887.5203 209.1142 868.5886 209.5963 849.2743 210.0785 832.5656 210.5606 819.7710 211.0427 806.8315 211.5248 792.4491 212.0069 776.8267 212.4890 762.5385 212.9712 750.6176 213.4533 739.2776 213.9354 724.0891 214.4175 706.3053 214.8996 690.5492 215.3817 678.2218 215.8639 669.4897 216.3460 659.9104 216.8281 648.7611 217.3102 637.1436 217.7923 626.7577 218.2744 618.0464 218.7566 609.5280 219.2387 601.1001 219.7208 592.6879 220.2029 584.0175 220.6850 575.2604 221.1671 566.1669 221.6493 556.5187 222.1314 545.8091 222.6135 535.5143 223.0956 526.2723 223.5777 517.9851 224.0598 509.9200 224.5420 502.1981 225.0241 494.4861 225.5062 486.3888 225.9883 478.3527 226.4704 469.0305 226.9525 457.8605 227.4347 444.5457 227.9168 432.6624 228.3989 422.5702 228.8810 413.5231 229.3631 405.2253 229.8452 398.7252 230.3274 390.5911 230.8095 379.2112 231.2916 364.3602 231.7737 352.8770 232.2558 346.3623 232.7379 341.5549 233.2201 335.4518 233.7022 328.1234 234.1843 319.3246 234.6664 308.2317 235.1485 294.8859 235.6306 284.0485 236.1128 276.4161 236.5949 270.4227 237.0770 264.6483 237.5591 259.2167 238.0412 253.7638 238.5233 248.1274 239.0055 242.2834 239.4876 237.2560 239.9697 233.6937 240.4518 230.2028 240.9339 225.3899 241.4160 218.1696 241.8982 211.7932 242.3803 206.8584 242.8624 203.3234 243.3445 200.5238 243.8266 198.6396 244.3087 197.2389 244.7909 196.1702 245.2730 196.3035 245.7551 194.8809 246.2372 190.6694 246.7193 184.0017 247.2014 179.7257 247.6836 179.1425 248.1657 179.4061 248.6478 178.4308 249.1299 175.8092 249.6120 172.8407 250.0941 169.9314 250.5762 166.9192 251.0584 162.2560 251.5405 155.1547 252.0226 147.5499 252.5047 140.9149 252.9868 135.6395 253.4689 130.3668 253.9511 124.9688 254.4332 119.4627 254.9153 114.0859 255.3974 108.9966 255.8795 103.8546 256.3617 98.59808 256.8438 93.35602 257.3259 87.55518 257.8080 80.88904 258.2901 73.67712 258.7722 66.91168 259.2544 60.67065 259.7365 54.66815 260.2186 48.50073 260.7007 41.95367 261.1828 36.07678 261.6649 31.15668 262.1471 26.85242 262.6292 21.87659 263.1113 15.83905 263.5934 9.943542 264.0755 4.747742 264.5576 0.1728520 265.0398 3.523132 265.5219 5.978882 266.0040 7.810730 266.4861 10.82800 266.9682 15.77679 267.4503 19.94989 267.9325 21.63245 268.4146 20.06360 268.8967 19.85309 269.3788 21.67297 269.8609 24.16113 270.3430 24.54706 270.8252 22.29993 271.3073 19.71216 271.7894 17.69116 272.2715 16.28833 272.7536 15.08423 273.2357 14.46912 273.7179 13.52026 274.2000 10.54498 274.6821 5.139465 275.1642 0.3707280 275.6463 4.876343 276.1284 8.367065 276.6106 13.52258 277.0927 20.71576 277.5748 28.75348 278.0569 36.02142 278.5390 42.34497 279.0211 49.14868 279.5032 56.69000 279.9854 64.96869 280.4675 74.75830 280.9496 86.31580 281.4317 98.56213 281.9138 110.2971 282.3959 121.4927 282.8781 133.1362 283.3602 145.6752 283.8423 158.8917 284.3244 171.2620 284.8065 182.6586 285.2886 194.3831 285.7708 207.7469 286.2529 222.6743 286.7350 237.9281 287.2171 253.4754 287.6992 269.0724 288.1813 283.5255 288.6635 296.8313 289.1456 310.1066 289.6277 324.2733 290.1098 339.2704 290.5919 354.3520 291.0740 369.7441 291.5562 384.8757 292.0383 397.6587 292.5204 408.3401 293.0025 419.8518 293.4846 435.4854 293.9667 453.8291 294.4489 469.6885 294.9310 481.8083 295.4131 492.6087 295.8952 505.6915 296.3773 520.7009 296.8594 535.5309 297.3416 548.9294 297.8237 561.4784 298.3058 574.3361 298.7879 587.7453 299.2700 601.1821 299.7521 613.3995 300.2343 624.8946 300.7164 636.6584 301.1985 649.6267 301.6806 663.1540 302.1627 676.1527 302.6448 688.6986 303.1270 700.5629 303.6091 712.2418 304.0912 723.2500 304.5733 732.9507 305.0554 740.2983 305.5375 746.6767 306.0197 753.8707 306.5018 761.7292 306.9839 768.5963 307.4660 772.3687 307.9481 774.4482 308.4302 776.8220 308.9124 781.5428 309.3945 785.7153 309.8766 786.2789 310.3587 783.8016 310.8408 781.4736 311.3229 782.8397 311.8051 784.6661 312.2872 783.4482 312.7693 776.6841 313.2514 769.4359 313.7335 765.1249 314.2156 762.9043 314.6978 759.9082 315.1799 754.7614 315.6620 748.3376 316.1441 741.2098 316.6262 733.1580 317.1083 725.1115 317.5905 717.4162 318.0726 709.9795 318.5547 702.5538 319.0368 695.8663 319.5189 688.5303 320.0010 679.8570 320.4832 669.5702 320.9653 658.7456 321.4474 647.6599 321.9295 636.1917 322.4116 624.1307 322.8937 611.1350 323.3759 597.8883 323.8580 584.8129 324.3401 572.0068 324.8222 557.9966 325.3043 541.5704 325.7864 524.6675 326.2686 508.8673 326.7507 495.4984 327.2328 481.6038 327.7149 466.3226 328.1970 450.0516 328.6791 434.6892 329.1613 420.9004 329.6434 407.6143 330.1255 394.3248 330.6076 381.5226 331.0897 367.8777 331.5718 352.4988 332.0540 336.4303 332.5361 322.4204 333.0182 311.5894 333.5003 301.0723 333.9824 289.5927 334.4645 276.3141 334.9467 264.5161 335.4288 254.7374 335.9109 246.0813 336.3930 237.2559 336.8751 227.7777 337.3572 219.0720 337.8394 211.5885 338.3215 205.4124 338.8036 199.4680 339.2857 194.0470 339.7678 188.3265 340.2499 180.7408 340.7321 170.8488 341.2142 162.5226 341.6963 157.0219 342.1784 153.7689 342.6605 150.2731 343.1426 146.5291 343.6248 142.6488 344.1069 138.6437 344.5890 134.5674 345.0711 130.7622 345.5532 127.4641 346.0353 124.2444 346.5175 119.8906 346.9996 114.3953 347.4817 109.5940 347.9638 107.3911 348.4459 106.9095 348.9280 104.8435 349.4102 100.8027 349.8923 95.85376 350.3744 91.50208 350.8565 87.51514 351.3386 82.85779 351.8207 76.07007 352.3029 68.69226 352.7850 63.84302 353.2671 61.56763 353.7492 58.70618 354.2313 51.16553 354.7134 41.35291 355.1956 33.41736 355.6777 29.59375 356.1598 27.53113 356.6419 25.36890 357.1240 23.11877 357.6061 20.80981 358.0883 18.67017 358.5704 16.38782 359.0525 13.64490 359.5346 10.23145 360.0167 6.606445 360.4988 2.392822 360.9810 1.849243 361.4631 4.840576 361.9452 4.478516 362.4273 3.928711 362.9094 5.334961 363.3915 9.535889 363.8737 12.93335 364.3558 14.30090 364.8379 14.25220 365.3200 13.48608 365.8021 10.55713 366.2842 8.498535 366.7664 8.926270 367.2485 11.88110 367.7306 13.31348 368.2127 11.54993 368.6948 8.837524 369.1769 6.643433 369.6591 5.894775 370.1412 4.535034 370.6233 2.246826 371.1054 0.7784420 371.5875 3.800171 372.0696 6.670532 372.5518 9.665283 373.0339 12.78381 373.5160 15.62817 373.9981 19.96460 374.4802 26.83362 374.9623 34.41199 375.4445 39.38196 375.9266 40.69775 376.4087 42.44641 376.8908 45.81323 377.3729 50.76941 377.8550 56.37085 378.3372 62.82178 378.8193 69.24048 379.3014 74.23206 379.7835 77.72473 380.2656 82.54272 380.7477 89.59546 381.2299 97.91858 381.7120 105.3444 382.1941 111.7941 382.6762 117.7318 383.1583 122.7510 383.6404 127.3423 384.1226 133.6379 384.6047 142.2628 385.0868 151.0220 385.5689 156.7196 386.0510 160.0795 386.5331 163.9054 387.0153 170.1844 387.4974 177.4983 387.9795 183.8018 388.4616 189.0814 388.9437 194.1862 389.4258 199.8726 389.9080 205.8143 390.3901 211.4078 390.8722 216.0886 391.3543 220.8457 391.8364 226.8887 392.3185 233.6909 392.8007 239.5151 393.2828 242.6057 393.7649 244.9886 394.2470 248.1144 394.7291 252.5872 395.2112 256.7117 395.6934 260.0089 396.1755 262.5295 396.6576 264.3621 397.1397 264.7123 397.6218 265.1172 398.1039 266.3669 398.5861 268.6366 399.0682 269.8889 399.5503 269.2251 400.0324 267.8973 400.5145 266.8492 400.9966 266.5852 401.4788 265.9861 401.9609 265.7000 402.4430 265.1169 402.9251 261.5328 403.4072 252.9189 403.8893 244.3772 404.3714 238.5034 404.8535 236.1737 405.3357 232.5343 405.8178 227.0139 406.2999 220.9819 406.7820 217.0071 407.2641 215.7506 407.7462 212.6104 408.2284 205.5454 408.7105 195.5327 409.1926 186.6925 409.6747 179.0696 410.1568 172.3241 410.6389 166.7642 411.1211 162.1096 411.6032 156.3356 412.0853 148.8450 412.5674 140.6110 413.0495 132.5134 413.5316 124.6003 414.0138 117.3231 414.4959 110.9652 414.9780 105.2771 415.4601 100.0836 415.9422 95.34497 416.4243 90.69678 416.9065 85.41345 417.3886 80.07886 417.8707 75.68494 418.3528 73.22986 418.8349 70.96313 419.3170 67.67773 419.7992 63.75525 420.2813 60.33105 420.7634 56.92383 421.2455 54.41199 421.7276 53.74426 422.2097 56.09009 422.6919 58.26367 423.1740 58.91418 423.6561 59.20361 424.1382 60.78979 424.6203 63.99756 425.1024 68.06433 425.5846 73.22119 426.0667 79.69885 426.5488 85.75464 427.0309 91.03394 427.5130 96.22766 427.9951 101.9934 428.4773 108.3297 428.9594 115.1598 429.4415 122.1422 429.9236 129.5100 430.4057 138.2872 430.8878 149.0348 431.3700 159.2349 431.8521 167.3489 432.3342 173.4331 432.8163 181.0784 433.2984 190.6571 433.7805 200.5941 434.2627 208.8945 434.7448 215.7455 435.2269 222.9733 435.7090 231.3348 436.1911 240.2100 436.6732 248.1619 437.1554 255.2971 437.6375 262.3873 438.1196 270.3369 438.6017 278.4589 439.0838 285.6465 439.5659 291.7783 440.0481 297.1345 440.5302 301.8577 441.0123 305.9822 441.4944 309.5604 441.9765 312.6057 442.4586 315.2554 442.9408 317.2472 443.4229 318.7041 443.9050 320.6643 444.3871 325.0576 444.8692 329.1082 445.3513 330.8126 445.8335 328.2622 446.3156 326.2356 446.7977 326.2885 447.2798 327.2971 447.7619 327.2797 448.2440 325.3501 448.7262 323.1917 449.2083 321.1901 449.6904 319.3494 450.1725 317.2766 450.6546 314.9658 451.1367 312.4711 451.6189 310.1031 452.1010 308.4183 452.5831 304.7474 453.0652 298.3245 453.5473 290.2524 454.0294 282.6014 454.5116 275.3055 454.9937 268.7986 455.4758 264.0427 455.9579 260.4169 456.4400 253.8040 456.9221 243.8611 457.4043 233.5084 457.8864 225.3298 458.3685 218.9613 458.8506 213.3248 459.3327 208.8555 459.8148 203.8992 460.2970 195.8131 460.7791 185.3771 461.2612 175.4491 461.7433 168.2234 462.2254 161.8008 462.7076 154.4703 463.1897 145.9009 463.6718 137.8507 464.1539 132.0419 464.6360 126.9191 465.1181 121.0435 465.6003 112.1321 466.0824 104.4989 466.5645 100.3999 467.0466 98.77209 467.5287 95.52649 468.0108 88.85522 468.4930 81.67712 468.9751 74.77539 469.4572 67.82568 469.9393 62.49231 470.4214 59.81226 470.9035 57.82349 471.3857 54.20593 471.8678 48.17163 472.3499 42.99268 472.8320 39.37195 473.3141 36.85449 473.7962 33.68445 474.2784 29.74158 474.7605 26.09106 475.2426 23.62195 475.7247 22.09399 476.2068 20.03345 476.6889 17.32129 477.1711 14.49585 477.6532 12.14343 478.1353 10.15564 478.6174 8.202026 479.0995 5.982300 479.5816 3.948486 480.0638 3.080688 480.5459 2.979004 481.0280 2.198364 481.5101 1.348022 481.9922 5.129883 482.4743 6.947510 482.9565 6.312012 483.4386 5.280518 483.9207 3.846313 484.4028 2.782593 484.8849 2.910156 485.3670 6.143555 485.8492 8.603149 486.3313 9.093750 486.8134 8.017944 487.2955 7.612427 487.7776 8.600037 488.2597 9.319275 488.7419 8.933289 489.2240 7.031067 489.7061 6.013672 490.1882 6.232727 490.6703 6.814331 491.1524 6.759705 491.6346 5.989807 492.1167 5.294312 492.5988 4.805908 493.0809 4.549438 493.5630 4.811829 494.0451 5.585083 494.5273 5.932434 495.0094 4.952148 495.4915 3.221741 495.9736 1.969482 496.4557 1.254944 496.9378 1.017883 497.4200 1.838989 497.9021 2.940796 498.3842 3.041504 498.8663 1.220215 499.3484 0.9338380 499.8305 2.834290 500.3127 4.329346 500.7948 5.021973 501.2769 3.495056 501.7590 2.235779 502.2411 2.454102 502.7232 4.375061 503.2054 6.712646 503.6875 10.51978 504.1696 13.87756 504.6517 15.27100 505.1338 13.19019 505.6159 11.74597 506.0981 11.15845 506.5802 11.33563 507.0623 12.21350 507.5444 14.03107 508.0265 15.74237 508.5086 16.83429 508.9908 17.43292 509.4729 18.76038 509.9550 20.92548 510.4371 22.98236 510.9192 23.63495 511.4013 23.39734 511.8835 24.34747 512.3655 27.01440 512.8477 30.27014 513.3298 33.27557 513.8119 35.87878 514.2940 37.70575 514.7761 37.33850 515.2582 37.11108 515.7404 38.83246 516.2225 42.37756 516.7046 46.61053 517.1867 52.42719 517.6688 57.78772 518.1509 61.05200 518.6331 60.65613 519.1152 61.43988 519.5973 64.75464 520.0794 69.42804 520.5615 73.95837 521.0436 78.54932 521.5258 82.63715 522.0079 85.92572 522.4900 88.60223 522.9721 91.72632 523.4542 95.46613 523.9363 99.02679 524.4185 101.7872 524.9006 103.7653 525.3827 106.6792 525.8648 110.7878 526.3469 114.6570 526.8290 116.0951 527.3112 115.8438 527.7933 116.8453 528.2754 120.2975 528.7575 124.4084 529.2396 127.2328 529.7217 128.9990 530.2039 130.3440 530.6860 131.1704 531.1681 132.0126 531.6502 133.5443 532.1323 135.7478 532.6144 137.1667 533.0966 136.1356 533.5787 134.7877 534.0608 134.6376 534.5429 136.8319 535.0250 138.7308 535.5071 140.1423 535.9893 141.1245 536.4714 141.6738 536.9535 141.3759 537.4356 141.4784 537.9177 142.3882 538.3998 143.9587 538.8820 145.3480 539.3641 146.5078 539.8462 147.1505 540.3283 146.9498 540.8104 146.1987 541.2925 146.0636 541.7747 146.5906 542.2568 147.9280 542.7389 151.1070 543.2210 155.0125 543.7031 157.2047 544.1852 156.2003 544.6674 154.8690 545.1495 156.0561 545.6316 158.8484 546.1137 161.1428 546.5958 161.7870 547.0779 162.0311 547.5601 162.1372 548.0422 162.0616 548.5243 162.7867 549.0064 164.8148 549.4885 167.5859 549.9706 170.8308 550.4528 175.5660 550.9349 178.6287 551.4170 178.9215 551.8991 178.3481 552.3812 179.9153 552.8633 184.1998 553.3455 188.5984 553.8276 192.4606 554.3097 195.9490 554.7918 199.6898 555.2739 203.6056 555.7560 207.4407 556.2382 210.9365 556.7203 214.4003 557.2024 218.4709 557.6845 223.1351 558.1666 227.6416 558.6487 231.4210 559.1309 234.6479 559.6130 237.5314 560.0951 240.2566 560.5772 242.4180 561.0593 243.7417 561.5414 244.3726 562.0236 244.5847 562.5057 243.7397 562.9878 243.1846 563.4699 243.3260 563.9520 244.1140 564.4341 245.1162 564.9163 247.1398 565.3984 248.2115 565.8805 246.9454 566.3626 242.6801 566.8447 240.1531 567.3268 239.7157 567.8090 239.8527 568.2911 238.8037 568.7732 236.6927 569.2553 234.9094 569.7374 233.8353 570.2195 232.9344 570.7017 231.3282 571.1838 229.1598 571.6659 226.9601 572.1480 225.0242 572.6301 223.0879 573.1122 221.0801 573.5944 218.9186 574.0765 216.2533 574.5586 212.2838 575.0407 208.2562 575.5228 204.9456 576.0049 202.8383 576.4871 200.4586 576.9692 197.7187 577.4513 194.6141 577.9334 190.9883 578.4155 186.7079 578.8976 182.4650 579.3798 178.4844 579.8619 174.4832 580.3440 169.7423 580.8261 164.2127 581.3082 158.9499 581.7903 154.5800 582.2725 150.7892 582.7546 146.9189 583.2367 142.9568 583.7188 138.6543 584.2009 133.7823 584.6830 128.5424 585.1652 123.1143 585.6473 117.4374 586.1294 111.9222 586.6115 106.8736 587.0936 101.9749 587.5757 96.98322 588.0579 91.32593 588.5400 86.14441 589.0221 81.91028 589.5042 78.26355 589.9863 74.37122 590.4684 70.26855 590.9506 65.93994 591.4327 61.24420 591.9148 56.27307 592.3969 51.74072 592.8790 47.58820 593.3611 44.15472 593.8433 42.15833 594.3254 41.27972 594.8075 39.22131 595.2896 35.82538 595.7717 32.05280 596.2538 28.45288 596.7360 25.21466 597.2181 22.64447 597.7002 20.92871 598.1823 19.90454 598.6644 20.05304 599.1465 20.73846 599.6287 20.86737 600.1108 19.29761 600.5929 17.99030 601.0750 17.42712 601.5571 17.66797 602.0392 18.64923 602.5214 21.11853 603.0035 23.10797 603.4856 23.70538 603.9677 22.78162 604.4498 22.55115 604.9319 22.98486 605.4141 24.05817 605.8962 26.24640 606.3783 29.24316 606.8604 30.99316 607.3425 31.00049 607.8246 30.77087 608.3068 32.52435 608.7889 35.41040 609.2710 37.50751 609.7531 37.19580 610.2352 36.84161 610.7173 38.52887 611.1995 41.65051 611.6816 44.22809 612.1637 44.99658 612.6458 45.43280 613.1279 46.09277 613.6100 47.05560 614.0922 47.91449 614.5743 48.36786 615.0564 49.13458 615.5385 50.86377 616.0206 53.93585 616.5027 55.69836 616.9849 55.84540 617.4670 55.45367 617.9491 55.50354 618.4312 56.08551 618.9133 57.89648 619.3954 61.50354 619.8776 65.16901 620.3597 66.69165 620.8418 66.67145 621.3239 66.50671 621.8060 66.90485 622.2881 67.17743 622.7703 66.91821 623.2524 66.23553 623.7345 65.46515 624.2166 63.87781 624.6987 62.91003 625.1808 63.51367 625.6630 65.84265 626.1451 66.86176 626.6272 66.02527 627.1093 64.65515 627.5914 63.64398 628.0735 63.08398 628.5557 62.89581 629.0378 63.21375 629.5199 63.15350 630.0020 61.50110 630.4841 58.61505 630.9662 55.36029 631.4484 51.43542 631.9305 48.29175 632.4126 48.16486 632.8947 49.91626 633.3768 50.96973 633.8589 49.95715 634.3411 48.26398 634.8232 46.22754 635.3053 43.94366 635.7874 41.76740 636.2695 39.40863 636.7516 37.58008 637.2338 36.77509 637.7159 37.03320 638.1980 36.47632 638.6801 34.90167 639.1622 33.04724 639.6443 31.42206 640.1265 30.01352 640.6086 28.54321 641.0907 26.98373 641.5728 25.52362 642.0549 24.36655 642.5370 23.42963 643.0192 22.52768 643.5013 21.68622 643.9834 20.73007 644.4655 19.45160 644.9476 17.99161 645.4297 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