#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 10:47:34 +0300 (Thu, 07 Jun 2018) $
#$Revision: 970 $
#$URL: svn://172.16.1.111/rod/cif/1/00/04/1000430.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000430
loop_
_publ_author_name
'Mereiter, K.'
_publ_section_title
;
 Chenite, Pb4Cu(SO4)2(OH)6, from Susanna mine, Leadhills, Scotland. Note:
 Crystal is from the Paar et al (1986) mineral description paper Locality:
 Susanna mine, Leadhills, Scotland
;
_journal_name_full               'Private communication'
_journal_page_first              1
_journal_page_last               1
_journal_volume                  1
_journal_year                    2009
_chemical_compound_source        R130276
_chemical_formula_structural     Pb4Cu(SO4)2(OH)6
_chemical_formula_sum            'Cu H6 O14 Pb4 S2'
_chemical_name_mineral           Chenite
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                111.994
_cell_angle_beta                 97.765
_cell_angle_gamma                100.426
_cell_length_a                   5.7960
_cell_length_b                   7.9471
_cell_length_c                   7.9836
_cell_volume                     326.939
_exptl_crystal_density_diffrn    6.026
_cod_original_formula_sum        'Pb4 Cu S2 O14 H6'
_cod_database_code               9014000
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type other
_raman_measurement_device.excitation_laser_wavelength 532
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 15
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R130276.rod
_rod_data_source.block           3500000
_rod_database.code               1000430
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9014000 COD http://www.crystallography.net/cod/9014000.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
171.3215 0.0000000E+00
171.8036 0.2555960
172.2857 0.7571220
172.7678 1.469009
173.2499 1.590885
173.7321 1.098473
174.2142 2.488522
174.6963 2.327168
175.1784 2.170971
175.6605 1.885277
176.1426 0.8049160
176.6248 0.4347190
177.1069 0.8676830
177.5890 0.2896840
178.0711 0.5886840
178.5532 0.9132500
179.0353 0.8653110
179.5175 1.052032
179.9996 2.014297
180.4817 3.419140
180.9638 4.671448
181.4459 5.704033
181.9280 6.571648
182.4102 7.303772
182.8923 7.904434
183.3744 8.575584
183.8565 9.421082
184.3386 10.42760
184.8207 11.52197
185.3029 12.73399
185.7850 13.98647
186.2671 15.28960
186.7492 16.62106
187.2313 17.72191
187.7134 18.13647
188.1956 18.07395
188.6777 18.53638
189.1598 19.83505
189.6419 21.57921
190.1240 22.86468
190.6061 23.68899
191.0883 24.60661
191.5704 26.18775
192.0525 28.37097
192.5346 30.30873
193.0167 31.70190
193.4988 32.78284
193.9810 34.06099
194.4631 35.47101
194.9452 37.05284
195.4273 38.33220
195.9094 39.31940
196.3915 40.51768
196.8737 42.04368
197.3558 43.82374
197.8379 45.71297
198.3200 47.73725
198.8021 49.72436
199.2842 51.53810
199.7664 53.20450
200.2485 54.61394
200.7306 55.70395
201.2127 56.53311
201.6948 57.45178
202.1769 58.48615
202.6591 59.54784
203.1412 60.52115
203.6233 61.39941
204.1054 62.30296
204.5875 63.21745
205.0696 64.16301
205.5518 65.45949
206.0339 67.31662
206.5160 69.05624
206.9981 69.79798
207.4802 69.24727
207.9623 69.05612
208.4445 69.74433
208.9266 71.26437
209.4087 72.34815
209.8908 72.90435
210.3729 73.21967
210.8550 73.64665
211.3372 74.28283
211.8193 74.66451
212.3014 74.65130
212.7835 74.24230
213.2656 73.70267
213.7477 72.92031
214.2299 72.16132
214.7120 71.79149
215.1941 71.97231
215.6762 72.08015
216.1583 71.96088
216.6404 71.60506
217.1226 71.18943
217.6047 70.78330
218.0868 70.23637
218.5689 69.30684
219.0510 67.78469
219.5331 66.36863
220.0153 65.22656
220.4974 64.37572
220.9795 63.60203
221.4616 62.94855
221.9437 62.32825
222.4258 61.59175
222.9080 60.60944
223.3901 59.80472
223.8722 59.35516
224.3543 59.31759
224.8364 59.09840
225.3185 58.60558
225.8007 58.01228
226.2828 57.52419
226.7649 57.16527
227.2470 56.95883
227.7291 56.82399
228.2112 56.77634
228.6934 56.91530
229.1755 57.20402
229.6576 57.53186
230.1397 57.53964
230.6218 57.02781
231.1039 56.55444
231.5861 56.29048
232.0682 56.27507
232.5503 56.22369
233.0324 56.10726
233.5145 56.00269
233.9966 55.95003
234.4788 55.67410
234.9609 55.86240
235.4430 56.99481
235.9251 59.32674
236.4072 60.51283
236.8893 60.03883
237.3715 58.85238
237.8536 58.15390
238.3357 58.27676
238.8178 58.24747
239.2999 57.68923
239.7820 56.45671
240.2642 55.83023
240.7463 56.12384
241.2284 56.75089
241.7105 57.01878
242.1926 56.87793
242.6747 56.46347
243.1569 55.79934
243.6390 54.88022
244.1211 53.68034
244.6032 51.93910
245.0853 50.14092
245.5674 48.93350
246.0496 48.85760
246.5317 48.36311
247.0138 46.96434
247.4959 44.54853
247.9780 42.48474
248.4601 40.75774
248.9423 39.38120
249.4244 38.43823
249.9065 38.23157
250.3886 37.86433
250.8707 37.09548
251.3528 35.91000
251.8350 34.79079
252.3171 33.68898
252.7992 32.71502
253.2813 32.00245
253.7634 31.64627
254.2455 31.36105
254.7277 31.17690
255.2098 31.09898
255.6919 30.57048
256.1740 29.33039
256.6561 27.96119
257.1382 27.01007
257.6204 26.52060
258.1025 26.34983
258.5846 26.63498
259.0667 27.33594
259.5488 27.50868
260.0309 27.02686
260.5131 26.19682
260.9952 25.21751
261.4773 23.94168
261.9594 22.92218
262.4415 22.28737
262.9236 22.00826
263.4058 21.88285
263.8879 22.09216
264.3700 22.15373
264.8521 21.59110
265.3342 20.15247
265.8163 18.96353
266.2985 18.26416
266.7806 17.95966
267.2627 17.51273
267.7448 16.91808
268.2269 16.19138
268.7090 15.27893
269.1912 14.07715
269.6733 13.12440
270.1554 12.58910
270.6375 12.32182
271.1196 11.68790
271.6017 10.55788
272.0839 9.417877
272.5660 8.693604
273.0481 8.487915
273.5302 7.982635
274.0123 7.011261
274.4944 5.745850
274.9766 4.609131
275.4587 3.559097
275.9408 2.807632
276.4229 2.637741
276.9050 3.116226
277.3871 3.325668
277.8693 3.170212
278.3514 2.751541
278.8335 2.214905
279.3156 1.512604
279.7977 0.9547880
280.2798 0.8744510
280.7620 1.276016
281.2441 1.129913
281.7262 0.2296300
282.2083 0.9547270
282.6904 1.557938
283.1725 1.547256
283.6547 1.443436
284.1368 1.492111
284.6189 1.680389
285.1010 1.862427
285.5831 2.053146
286.0652 2.187698
286.5474 2.171143
287.0295 2.003952
287.5116 1.737762
287.9937 1.286407
288.4758 0.7128600
288.9579 0.4233860
289.4401 0.4307100
289.9222 0.6180880
290.4043 0.9506990
290.8864 1.395477
291.3685 1.689301
291.8506 1.756073
292.3328 1.593903
292.8149 1.053116
293.2970 9.1109999E-02
293.7791 0.7660220
294.2612 0.7224120
294.7433 3.1265002E-02
295.2255 0.2801670
295.7076 0.3403470
296.1897 1.431778
296.6718 2.077621
297.1539 2.284378
297.6360 2.371918
298.1182 2.615631
298.6003 2.947052
299.0824 3.192307
299.5645 3.251633
300.0466 3.261307
300.5287 3.377594
301.0109 3.602737
301.4930 3.966415
301.9751 4.651688
302.4572 5.460159
302.9393 5.988449
303.4214 6.003326
303.9036 5.999969
304.3857 6.540710
304.8678 7.528107
305.3499 8.621780
305.8320 9.670471
306.3141 10.68144
306.7963 11.64365
307.2784 12.56577
307.7605 13.44214
308.2426 14.18831
308.7247 14.87869
309.2068 15.69220
309.6890 16.76358
310.1711 17.96997
310.6532 19.20442
311.1353 20.45029
311.6174 21.71048
312.0995 22.88908
312.5817 24.07811
313.0638 25.44240
313.5459 27.17967
314.0280 29.02946
314.5101 30.84879
314.9922 32.61984
315.4744 34.39912
315.9565 36.15961
316.4386 37.95682
316.9207 39.82994
317.4028 41.79567
317.8849 43.86189
318.3671 46.13420
318.8492 48.61182
319.3313 50.87839
319.8134 52.56323
320.2955 54.11276
320.7776 55.86176
321.2598 57.76529
321.7419 60.01266
322.2240 62.90591
322.7061 66.28468
323.1882 69.32309
323.6703 71.65266
324.1525 73.74991
324.6346 75.84729
325.1167 77.99289
325.5988 80.13179
326.0809 82.18005
326.5630 84.21237
327.0452 86.44034
327.5273 89.16519
328.0094 91.81613
328.4915 94.20006
328.9736 96.20451
329.4557 98.13802
329.9379 99.94760
330.4200 101.7105
330.9021 103.5216
331.3842 105.3978
331.8663 107.3148
332.3484 109.3327
332.8306 111.4708
333.3127 113.3157
333.7948 114.6746
334.2769 115.9209
334.7590 117.5040
335.2411 119.7097
335.7233 121.6421
336.2054 123.0203
336.6875 123.9046
337.1696 125.1004
337.6517 126.8696
338.1339 128.4375
338.6160 129.0523
339.0981 128.5155
339.5802 127.9798
340.0623 127.6448
340.5444 127.4150
341.0266 126.9175
341.5087 126.0957
341.9908 125.0956
342.4729 124.0794
342.9550 123.0747
343.4371 121.7377
343.9193 120.0156
344.4014 118.0022
344.8835 115.8044
345.3656 113.4104
345.8477 111.0455
346.3298 109.0651
346.8120 107.2974
347.2941 104.8456
347.7762 101.5300
348.2583 98.20139
348.7404 95.98680
349.2225 94.67947
349.7047 93.38513
350.1868 91.71182
350.6689 89.88554
351.1510 88.13554
351.6331 86.45485
352.1152 85.16373
352.5974 84.79677
353.0795 84.96965
353.5616 84.98279
354.0437 84.53300
354.5258 83.96733
355.0079 83.52769
355.4901 83.24033
355.9722 83.20560
356.4543 83.73007
356.9364 84.42524
357.4185 84.81956
357.9006 84.64475
358.3828 84.66933
358.8649 85.33193
359.3470 86.54469
359.8291 88.12737
360.3112 90.40839
360.7933 92.72852
361.2755 94.61224
361.7576 95.92427
362.2397 97.47039
362.7218 99.73710
363.2039 102.3324
363.6860 104.8187
364.1682 107.2681
364.6503 109.4257
365.1324 111.1748
365.6145 112.5345
366.0966 113.5642
366.5787 114.3558
367.0609 114.7712
367.5430 114.7216
368.0251 114.3979
368.5072 113.3625
368.9893 111.3817
369.4714 108.6500
369.9536 105.8300
370.4357 103.1039
370.9178 100.0851
371.3999 96.66456
371.8820 92.82346
372.3641 88.53813
372.8463 83.66360
373.3284 78.48958
373.8105 73.32040
374.2926 67.89765
374.7747 63.05682
375.2568 59.18744
375.7390 56.28671
376.2211 52.83856
376.7032 48.54794
377.1853 44.24164
377.6674 40.64126
378.1495 37.79382
378.6317 35.13734
379.1138 32.56315
379.5959 30.08851
380.0780 27.64696
380.5601 25.24109
381.0422 22.99001
381.5244 21.02282
382.0065 19.28897
382.4886 17.57697
382.9707 15.79869
383.4528 14.18652
383.9349 13.21072
384.4171 12.74971
384.8992 12.14907
385.3813 10.87062
385.8634 9.301315
386.3455 8.036797
386.8276 7.102310
387.3098 6.441147
387.7919 6.312164
388.2740 6.371498
388.7561 5.987961
389.2382 4.505600
389.7203 2.929039
390.2025 2.198929
390.6846 2.169159
391.1667 2.134415
391.6488 1.656296
392.1309 1.030930
392.6130 0.5060040
393.0952 0.1732560
393.5773 0.1305470
394.0594 0.4954220
394.5415 0.8706820
395.0236 1.163025
395.5057 1.364319
395.9879 1.457390
396.4700 1.369507
396.9521 1.042839
397.4342 0.8840480
397.9163 1.191788
398.3984 1.580711
398.8806 1.699112
399.3627 1.116882
399.8448 0.7313610
400.3269 0.7306440
400.8090 1.056404
401.2911 1.268600
401.7733 1.431793
402.2554 1.411407
402.7375 1.083977
403.2196 0.2080610
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404.6660 0.3410640
405.1481 0.3873210
405.6302 0.6208720
406.1123 0.9395600
406.5944 1.287254
407.0765 1.672653
407.5587 2.264168
408.0408 3.089317
408.5229 4.019897
409.0050 4.930992
409.4871 5.822830
409.9692 6.731438
410.4514 7.605713
410.9335 8.571281
411.4156 9.932587
411.8977 11.65884
412.3798 13.52941
412.8619 15.56330
413.3441 17.58611
413.8262 19.17471
414.3083 20.19461
414.7904 21.24081
415.2725 23.07838
415.7546 25.37523
416.2368 27.48517
416.7189 28.87067
417.2010 30.10432
417.6831 31.59844
418.1652 33.35059
418.6473 35.33231
419.1295 37.63024
419.6116 40.08620
420.0937 42.51308
420.5758 44.73572
421.0579 47.15053
421.5400 49.89855
422.0222 52.94779
422.5043 56.29420
422.9864 59.89422
423.4685 63.78995
423.9506 68.00746
424.4327 72.48383
424.9149 77.44983
425.3970 83.13818
425.8791 89.17386
426.3612 95.27837
426.8433 101.5008
427.3254 107.6631
427.8076 113.8272
428.2897 119.9664
428.7718 125.7450
429.2539 131.6131
429.7360 136.0928
430.2181 138.3166
430.7003 138.2348
431.1824 135.9713
431.6645 131.2962
432.1466 124.9069
432.6287 117.6502
433.1108 109.5748
433.5930 101.5913
434.0751 93.98991
434.5572 86.76753
435.0393 79.72346
435.5214 72.88101
436.0035 66.80951
436.4857 62.30093
436.9678 59.02118
437.4499 56.05406
437.9320 53.17332
438.4141 50.61292
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439.8605 46.13260
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440.8247 44.50155
441.3068 43.97673
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442.2711 43.49454
442.7532 43.40234
443.2353 43.45995
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445.6459 46.47355
446.1280 47.14180
446.6101 48.22144
447.0922 49.22527
447.5743 49.96202
448.0565 50.42017
448.5386 50.63936
449.0207 50.44590
449.5028 50.11739
449.9849 50.04727
450.4670 50.41935
450.9492 50.62856
451.4313 50.53241
451.9134 50.14987
452.3955 49.65311
452.8776 49.03313
453.3597 48.40923
453.8419 47.88496
454.3240 47.47107
454.8061 47.01793
455.2882 46.48130
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456.2524 45.63668
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458.6630 43.37132
459.1451 43.23122
459.6273 43.03593
460.1094 42.51570
460.5915 41.79020
461.0736 41.03309
461.5557 40.27295
462.0378 39.36293
462.5200 38.19135
463.0021 36.82098
463.4842 35.38858
463.9663 33.92093
464.4484 32.41759
464.9305 30.91179
465.4127 29.40590
465.8948 27.84393
466.3769 26.07715
466.8590 24.34335
467.3411 22.82293
467.8232 21.62346
468.3054 20.48679
468.7875 19.53909
469.2696 18.63478
469.7517 17.33598
470.2338 15.29056
470.7159 13.52943
471.1981 12.50137
471.6802 12.24088
472.1623 11.79217
472.6444 11.12184
473.1265 10.37338
473.6086 9.725029
474.0908 9.172211
474.5729 8.491768
475.0550 7.596786
475.5371 6.625671
476.0192 5.815422
476.5013 5.156937
476.9835 4.614998
477.4656 4.116249
477.9477 3.731026
478.4298 3.686005
478.9119 4.001396
479.3940 4.202194
479.8762 3.757668
480.3583 3.022285
480.8404 2.472427
481.3225 2.373032
481.8046 2.309967
482.2867 2.073341
482.7689 1.710976
483.2510 1.343788
483.7331 0.9554370
484.2152 0.6206210
484.6973 0.3604740
485.1794 0.1646190
485.6616 9.6709996E-02
486.1437 0.4093400
486.6258 0.7017750
487.1079 0.6238630
487.5900 0.3157120
488.0721 0.7260360
488.5543 0.2255780
489.0364 0.7981490
489.5185 1.166771
490.0006 0.6743930
490.4827 0.1680220
490.9648 7.7399999E-02
491.4470 0.3705520
491.9291 0.3788530
492.4112 5.7755001E-02
492.8933 0.3331150
493.3754 0.5653920
493.8575 0.6487730
494.3397 0.5966570
494.8218 0.3602600
495.3039 8.4022999E-02
495.7860 1.9135000E-02
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