#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 10:54:41 +0300 (Thu, 07 Jun 2018) $
#$Revision: 1011 $
#$URL: svn://172.16.1.111/rod/cif/1/00/04/1000467.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000467
loop_
_publ_author_name
'Geiger, C. A.'
'Armbruster, T.'
'Khomenko, V.'
'Quartieri, S.'
_publ_section_title
;
 Cordierite I: The coordination of Fe2+ Sample: DA-1
;
_journal_name_full               'American Mineralogist'
_journal_page_first              1255
_journal_page_last               1264
_journal_volume                  85
_journal_year                    2000
_chemical_compound_source        R100150
_chemical_formula_sum            'Al4 Fe0.14 Mg1.86 Na0.09 O18.58 Si5'
_chemical_name_mineral           Cordierite
_space_group_IT_number           66
_symmetry_space_group_name_Hall  '-C 2 2c'
_symmetry_space_group_name_H-M   'C c c m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   17.072
_cell_length_b                   9.727
_cell_length_c                   9.351
_cell_volume                     1552.821
_exptl_crystal_density_diffrn    2.570
_cod_original_formula_sum        'Si5 Al4 (Mg1.86 Fe.14) Na.09 O18.58'
_cod_database_code               9002408
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type other
_raman_measurement_device.excitation_laser_wavelength 532
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 15
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R100150.rod
_rod_data_source.block           3500000
_rod_database.code               1000467
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9002408 COD http://www.crystallography.net/cod/9002408.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
137.3184 5.1357001E-02
137.8005 8.3452001E-02
138.2826 8.0358997E-02
138.7648 0.5332030
139.2469 1.660471
139.7290 3.359283
140.2111 4.672903
140.6932 5.410738
141.1753 6.147192
141.6575 7.499796
142.1396 9.804214
142.6217 11.85034
143.1038 13.28929
143.5859 14.09551
144.0681 15.19269
144.5502 16.81108
145.0323 18.52692
145.5144 19.87202
145.9965 20.61201
146.4786 21.32515
146.9608 22.16526
147.4429 23.24714
147.9250 24.01921
148.4071 24.02935
148.8892 23.89987
149.3713 24.52931
149.8535 25.97823
150.3356 28.15025
150.8177 31.12690
151.2998 35.35147
151.7819 39.40749
152.2640 42.86716
152.7462 46.21632
153.2283 50.24968
153.7104 55.49561
154.1925 61.04437
154.6746 66.65219
155.1567 72.69134
155.6389 77.95332
156.1210 82.45565
156.6031 86.11019
157.0852 88.77032
157.5673 90.57162
158.0495 91.25213
158.5316 90.65983
159.0137 88.37376
159.4958 85.35279
159.9779 81.70184
160.4600 77.47305
160.9422 72.83271
161.4243 66.89719
161.9064 61.10754
162.3885 56.48089
162.8706 53.92867
163.3527 51.72850
163.8349 48.94859
164.3170 45.79723
164.7991 43.26937
165.2812 42.01241
165.7633 41.51241
166.2454 41.30314
166.7276 41.08347
167.2097 41.26205
167.6918 42.53266
168.1739 44.70420
168.6560 46.31299
169.1381 45.72990
169.6203 44.28113
170.1024 42.98610
170.5845 43.81099
171.0666 45.02443
171.5487 44.84135
172.0309 43.29953
172.5130 41.47360
172.9951 39.77919
173.4772 38.34740
173.9593 37.34243
174.4414 37.38885
174.9236 37.69423
175.4057 37.20645
175.8878 35.91181
176.3699 34.75099
176.8520 34.89061
177.3341 35.75496
177.8163 36.09156
178.2984 34.81361
178.7805 32.88543
179.2626 31.75603
179.7447 31.49099
180.2268 31.60168
180.7090 31.69900
181.1911 31.79369
181.6732 31.91688
182.1553 32.32961
182.6374 32.75000
183.1195 32.40495
183.6017 31.16949
184.0838 29.79874
184.5659 29.19363
185.0480 29.23731
185.5301 29.26388
186.0123 28.99814
186.4944 28.54868
186.9765 28.34061
187.4586 28.46792
187.9407 28.54111
188.4228 27.84477
188.9050 26.45635
189.3871 25.20630
189.8692 24.59842
190.3513 24.51742
190.8334 24.42290
191.3155 24.27820
191.7977 24.01854
192.2798 23.51574
192.7619 22.76368
193.2440 22.01397
193.7261 21.44830
194.2082 21.04005
194.6904 20.46265
195.1725 19.69177
195.6546 18.76734
196.1367 17.65150
196.6188 16.30289
197.1009 15.22634
197.5831 14.91466
198.0652 15.36211
198.5473 15.21812
199.0294 14.24598
199.5115 12.87998
199.9937 11.94691
200.4758 11.46111
200.9579 11.32690
201.4400 11.67199
201.9221 12.55811
202.4042 12.98001
202.8864 12.71004
203.3685 12.11734
203.8506 12.16135
204.3327 12.99780
204.8148 13.82246
205.2969 14.13480
205.7791 13.84331
206.2612 13.77594
206.7433 14.17049
207.2254 14.67387
207.7075 14.30020
208.1896 12.83496
208.6718 11.11897
209.1539 9.501228
209.6360 7.940620
210.1181 6.819374
210.6002 6.398369
211.0823 6.299416
211.5645 5.329308
212.0466 3.112198
212.5287 0.9091490
213.0108 0.5921100
213.4929 1.270973
213.9750 1.760727
214.4572 2.091576
214.9393 2.256943
215.4214 2.196259
215.9035 1.793213
216.3856 1.398956
216.8678 1.229790
217.3499 1.361290
217.8320 1.475525
218.3141 1.625343
218.7962 1.733688
219.2783 1.509094
219.7605 0.7932050
220.2426 4.3853998E-02
220.7247 0.4546360
221.2068 0.5403370
221.6889 0.8376850
222.1710 1.427200
222.6532 2.232338
223.1353 2.984657
223.6174 3.657272
224.0995 4.340149
224.5816 5.066620
225.0637 5.820732
225.5459 6.679230
226.0280 7.616547
226.5101 8.669525
226.9922 9.939545
227.4743 11.57974
227.9564 13.21468
228.4386 14.62167
228.9207 15.46046
229.4028 16.85349
229.8849 19.05681
230.3670 21.76566
230.8492 24.20836
231.3313 26.29314
231.8134 28.21330
232.2955 29.91820
232.7776 30.67065
233.2597 32.90012
233.7419 37.01254
234.2240 42.51006
234.7061 48.01922
235.1882 53.54587
235.6703 59.05873
236.1524 64.59058
236.6346 70.07992
237.1167 75.75364
237.5988 82.02652
238.0809 88.35458
238.5630 93.67058
239.0451 98.32843
239.5273 101.3707
240.0094 102.2410
240.4915 100.1852
240.9736 97.87110
241.4557 95.21857
241.9378 92.32497
242.4200 89.34854
242.9021 85.98650
243.3842 82.95535
243.8663 80.47519
244.3484 78.48772
244.8306 77.24622
245.3127 76.93983
245.7948 77.28516
246.2769 77.75154
246.7590 78.15501
247.2411 78.97894
247.7233 80.40414
248.2054 82.50134
248.6875 84.91291
249.1696 87.42034
249.6517 90.35994
250.1338 94.31544
250.6160 99.61208
251.0981 105.3411
251.5802 110.9198
252.0623 115.9634
252.5444 123.0868
253.0265 132.8595
253.5087 144.1975
253.9908 155.3681
254.4729 166.1757
254.9550 177.3579
255.4371 189.1894
255.9192 201.5605
256.4014 214.6675
256.8835 229.4417
257.3656 244.0327
257.8477 256.7098
258.3298 267.5467
258.8120 276.4095
259.2941 284.2730
259.7762 291.4956
260.2583 291.5836
260.7404 284.0211
261.2225 269.9812
261.7047 249.5946
262.1868 220.6002
262.6689 190.7659
263.1510 160.2638
263.6331 129.4910
264.1152 103.8291
264.5974 84.21700
265.0795 68.55151
265.5616 55.56212
266.0437 45.32823
266.5258 36.86623
267.0079 30.19555
267.4901 25.16879
267.9722 21.13197
268.4543 18.28762
268.9364 15.94718
269.4185 13.42458
269.9006 10.48817
270.3828 8.429321
270.8649 7.618752
271.3470 7.793907
271.8291 7.650101
272.3112 6.992592
272.7933 6.534622
273.2755 6.874733
273.7576 8.128601
274.2397 9.411087
274.7218 10.60552
275.2039 11.74366
275.6860 12.85416
276.1682 13.85462
276.6503 15.17075
277.1324 17.24305
277.6145 20.13841
278.0966 22.73905
278.5787 24.81436
279.0609 26.69855
279.5430 29.32336
280.0251 32.80470
280.5072 36.29044
280.9893 39.45839
281.4715 42.28156
281.9536 44.13443
282.4357 44.72877
282.9178 44.92664
283.3999 46.26013
283.8820 48.77742
284.3642 51.52768
284.8463 53.95457
285.3284 56.13255
285.8105 58.84106
286.2926 62.09196
286.7747 65.89908
287.2569 70.31314
287.7390 75.32610
288.2211 80.80250
288.7032 86.85371
289.1853 93.34586
289.6674 99.63235
290.1496 105.6550
290.6317 112.0297
291.1138 120.2631
291.5959 129.9480
292.0780 137.9591
292.5602 143.0571
293.0423 145.9518
293.5244 148.6174
294.0065 151.0854
294.4886 152.2583
294.9707 150.8197
295.4529 147.1768
295.9350 142.8808
296.4171 138.4403
296.8992 133.4109
297.3813 126.7985
297.8634 118.7338
298.3456 110.2724
298.8277 101.8634
299.3098 93.73811
299.7919 86.50266
300.2740 80.45897
300.7561 75.13878
301.2383 70.25813
301.7204 65.73005
302.2025 61.50111
302.6846 57.32779
303.1667 53.45449
303.6488 50.22038
304.1310 47.80107
304.6131 45.74213
305.0952 43.98457
305.5773 42.31145
306.0594 40.14679
306.5415 36.93554
307.0237 33.19001
307.5058 29.26357
307.9879 25.15337
308.4700 21.28904
308.9521 18.01209
309.4343 15.18971
309.9164 12.50469
310.3985 9.758736
310.8806 7.111588
311.3627 4.589973
311.8448 2.169174
312.3270 0.1771770
312.8091 1.049919
313.2912 1.789383
313.7733 2.368530
314.2554 3.043945
314.7375 3.467529
315.2197 3.369308
315.7018 2.797127
316.1839 2.148964
316.6660 1.553955
317.1481 0.9826970
317.6302 0.4058990
318.1124 0.3708720
318.5945 0.9267580
319.0766 0.9133990
319.5587 0.5170520
320.0408 0.3810500
320.5229 0.6942670
321.0051 1.331291
321.4872 2.273254
321.9693 3.751663
322.4514 5.074951
322.9335 5.660500
323.4156 6.029938
323.8978 7.188919
324.3799 10.42484
324.8620 13.50909
325.3441 15.55573
325.8262 16.08555
326.3083 16.84624
326.7905 18.29660
327.2726 19.94118
327.7547 21.15778
328.2368 21.99255
328.7189 22.37262
329.2010 22.15761
329.6832 21.27242
330.1653 20.50089
330.6474 20.39620
331.1295 20.01615
331.6116 18.52172
332.0938 15.03971
332.5759 11.76682
333.0580 8.860912
333.5401 6.354435
334.0222 4.682003
334.5043 4.270851
334.9865 4.022217
335.4686 3.298180
335.9507 1.947952
336.4328 0.6470640
336.9149 0.8539240
337.3970 2.315037
337.8792 2.642944
338.3613 1.394032
338.8434 2.7470000E-03
339.3255 0.8064230
339.8076 0.8472370
340.2898 0.8986590
340.7719 0.9918370
341.2540 1.082169
341.7361 1.021015
342.2182 0.7967340
342.7003 0.8645710
343.1825 1.336403
343.6646 2.166847
344.1467 3.456379
344.6288 5.284092
345.1109 7.067055
345.5930 8.142097
346.0752 8.604424
346.5573 9.386997
347.0394 10.78615
347.5215 12.57495
348.0036 14.34770
348.4857 16.09602
348.9679 17.77085
349.4500 19.52022
349.9321 21.18062
350.4142 22.19701
350.8963 22.33304
351.3784 22.23528
351.8606 22.85274
352.3427 23.98210
352.8248 24.90539
353.3069 24.95871
353.7890 24.65634
354.2711 24.74382
354.7533 25.31551
355.2354 25.93192
355.7175 26.21338
356.1996 26.27995
356.6817 26.34076
357.1638 26.25040
357.6460 26.35675
358.1281 26.98478
358.6102 28.10616
359.0923 29.37919
359.5744 30.56457
360.0565 31.81968
360.5387 33.29306
361.0208 34.99395
361.5029 36.96772
361.9850 39.31047
362.4671 41.94973
362.9492 44.63779
363.4314 47.17041
363.9135 49.81472
364.3956 52.83608
364.8777 56.69740
365.3598 59.93126
365.8419 62.57116
366.3241 64.33435
366.8062 64.76685
367.2883 63.28917
367.7704 60.97476
368.2526 58.05734
368.7347 54.52022
369.2168 50.43258
369.6989 45.20784
370.1810 39.78428
370.6631 34.80530
371.1453 30.10569
371.6274 26.13963
372.1095 23.07489
372.5916 20.81043
373.0737 18.72063
373.5558 16.80574
374.0380 15.09573
374.5201 13.58825
375.0022 12.32135
375.4843 11.16273
375.9664 10.07117
376.4485 9.099880
376.9307 8.368519
377.4128 7.887939
377.8949 7.639610
378.3770 7.754772
378.8591 8.198441
379.3412 8.249016
379.8234 7.874447
380.3055 7.222511
380.7876 6.345001
381.2697 5.255676
381.7518 4.356773
382.2339 3.783657
382.7161 3.445827
383.1982 3.129837
383.6803 2.841103
384.1624 2.627514
384.6445 2.723831
385.1266 2.921566
385.6088 2.600536
386.0909 1.529148
386.5730 0.3670040
387.0551 6.6574000E-02
387.5372 5.6332000E-02
388.0193 0.2365880
388.5015 0.1937450
388.9836 8.8558003E-02
389.4657 0.1331980
389.9478 0.3451160
390.4299 0.4905590
390.9120 0.2871860
391.3942 3.7666000E-02
391.8763 0.1948660
392.3584 0.2858120
392.8405 0.6032560
393.3226 4.7465999E-02
393.8047 1.137310
394.2869 1.835293
394.7690 0.9947360
395.2511 6.4960003E-02
395.7332 2.4666000E-02
396.2154 1.426430
396.6975 2.319954
397.1796 1.978355
397.6617 0.9191630
398.1438 7.4080001E-03
398.6259 1.078754
399.1081 1.639278
399.5902 1.258442
400.0723 0.2878300
400.5544 1.235157
401.0365 1.419788
401.5186 1.120407
402.0008 0.5029370
402.4829 0.8017880
402.9650 1.721237
403.4471 2.034363
403.9292 1.874641
404.4113 1.788502
404.8935 1.784863
405.3756 1.831253
405.8577 1.874203
406.3398 1.881168
406.8219 2.169380
407.3040 2.828785
407.7862 3.607040
408.2683 4.053543
408.7504 4.151031
409.2325 4.522156
409.7146 5.537266
410.1967 6.946491
410.6789 7.816734
411.1610 8.119595
411.6431 8.639347
412.1252 10.38223
412.6073 12.89989
413.0894 14.84925
413.5716 15.78832
414.0537 16.38945
414.5358 17.43676
415.0179 18.81438
415.5000 20.18069
415.9821 21.09476
416.4643 22.02280
416.9464 23.50256
417.4285 25.59147
417.9106 27.84963
418.3927 30.18483
418.8748 32.46789
419.3570 34.50423
419.8391 35.72126
420.3212 37.19115
420.8033 39.40691
421.2854 42.28343
421.7675 45.44392
422.2497 48.93018
422.7318 52.55708
423.2139 56.19388
423.6960 59.76730
424.1781 63.46808
424.6602 67.50204
425.1424 71.61545
425.6245 75.41106
426.1066 79.12062
426.5887 82.16882
427.0709 84.46245
427.5530 86.00141
428.0351 86.68746
428.5172 86.72098
428.9993 85.62789
429.4814 82.92974
429.9636 78.30962
430.4457 73.22594
430.9278 67.61220
431.4099 61.78063
431.8920 56.48881
432.3741 51.75549
432.8563 47.04274
433.3384 41.78617
433.8205 36.19250
434.3026 31.87655
434.7847 28.86606
435.2668 26.70377
435.7490 25.24369
436.2311 24.29871
436.7132 23.21183
437.1953 21.64003
437.6774 20.08525
438.1595 19.29539
438.6417 19.13535
439.1238 19.04616
439.6059 18.71935
440.0880 18.27774
440.5701 17.85465
441.0522 17.46986
441.5344 17.04312
442.0165 16.38812
442.4986 15.71075
442.9807 15.26382
443.4628 15.29248
443.9449 15.37324
444.4271 15.25056
444.9092 15.00478
445.3913 15.05192
445.8734 15.72088
446.3555 16.51619
446.8376 17.23854
447.3198 17.93388
447.8019 18.37355
448.2840 18.42358
448.7661 18.30344
449.2482 18.37729
449.7303 18.47358
450.2125 18.89299
450.6946 19.73046
451.1767 20.93235
451.6588 21.98631
452.1409 22.95977
452.6230 24.01402
453.1052 25.17876
453.5873 26.37068
454.0694 27.46712
454.5515 28.55033
455.0337 29.48180
455.5158 30.15848
455.9979 30.56536
456.4800 30.09239
456.9621 27.74884
457.4442 24.44162
457.9264 22.46707
458.4085 21.81226
458.8906 21.51328
459.3727 21.03460
459.8548 20.35227
460.3369 19.29829
460.8191 17.48967
461.3012 15.95017
461.7833 15.72764
462.2654 16.37439
462.7475 16.95603
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