#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 10:57:23 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1019 $ #$URL: svn://172.16.1.111/rod/cif/1/00/04/1000475.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000475 loop_ _publ_author_name 'Tait, K. T.' 'Yang, H.' 'Downs, R. T.' 'Li, C.' 'Pinch, W. W.' _publ_section_title ; The crystal structure of esperite, with a revised chemical formula, PbCa2(ZnSiO4)3, isostructural with beryllonite ; _journal_name_full 'American Mineralogist' _journal_page_first 699 _journal_page_last 705 _journal_paper_doi 10.2138/am.2010.3415 _journal_volume 95 _journal_year 2010 _chemical_compound_source '2 Franklin, New Jersey, USA' _chemical_formula_sum 'Ca2 O12 Pb Si3 Zn3' _chemical_name_mineral Esperite _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90 _cell_angle_beta 90.050 _cell_angle_gamma 90 _cell_length_a 8.7889 _cell_length_b 8.2685 _cell_length_c 15.2535 _cell_volume 1108.487 _exptl_crystal_density_diffrn 4.553 _cod_original_formula_sum 'Pb Ca2 Zn3 Si3 O12' _cod_database_code 9016115 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R060552.rod _rod_data_source.block 3500000 _rod_database.code 1000475 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9016115 COD http://www.crystallography.net/cod/9016115.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 134.8804 0.0000000E+00 135.3625 0.9945070 135.8447 0.3804930 136.3268 1.237305 136.8089 3.800415 137.2910 7.174561 137.7731 11.23193 138.2552 15.52686 138.7374 19.66882 139.2195 26.97412 139.7016 38.99487 140.1837 52.68573 140.6658 61.01794 141.1479 61.96173 141.6301 62.49414 142.1122 66.23877 142.5943 75.28601 143.0764 81.58203 143.5585 84.02991 144.0406 83.74579 144.5228 84.83984 145.0049 88.51904 145.4870 92.04578 145.9691 94.00897 146.4512 94.63617 146.9333 93.48810 147.4155 90.76801 147.8976 86.31793 148.3797 79.25189 148.8618 67.23694 149.3439 54.23193 149.8260 42.78424 150.3082 30.48920 150.7903 22.25635 151.2724 19.61603 151.7545 22.78992 152.2366 25.38385 152.7188 25.45105 153.2009 25.61328 153.6830 27.97882 154.1651 35.06085 154.6472 42.07288 155.1293 47.48810 155.6115 51.17932 156.0936 56.35504 156.5757 63.63696 157.0578 72.21179 157.5399 81.54865 158.0220 91.24524 158.5042 101.8193 158.9863 113.6934 159.4684 128.0684 159.9505 141.1772 160.4326 150.2563 160.9147 157.1633 161.3969 163.5990 161.8790 173.8227 162.3611 181.2038 162.8432 181.6221 163.3253 173.1207 163.8074 162.1248 164.2896 148.7524 164.7717 134.9139 165.2538 124.4475 165.7359 119.8320 166.2180 118.7524 166.7001 119.4053 167.1823 121.1880 167.6644 125.5743 168.1465 136.9143 168.6286 152.0346 169.1107 164.3809 169.5928 173.7988 170.0750 178.5196 170.5571 176.1761 171.0392 164.5397 171.5213 147.0422 172.0034 124.0945 172.4855 97.05743 172.9677 72.31586 173.4498 53.55444 173.9319 39.42908 174.4140 28.15967 174.8961 19.71863 175.3782 13.42340 175.8604 8.550049 176.3425 5.039429 176.8246 2.575134 177.3067 1.248474 177.7888 0.7467040 178.2709 0.4747310 178.7531 0.4225460 179.2352 0.3774410 179.7173 7.9406999E-02 180.1994 0.9312130 180.6815 1.736450 181.1636 2.155701 181.6458 2.222290 182.1279 2.007324 182.6100 1.260620 183.0921 0.3613890 183.5742 0.4599000 184.0563 1.637146 184.5385 2.339172 185.0206 0.5991210 185.5027 3.149902 185.9848 6.731567 186.4669 9.217896 186.9490 10.99554 187.4312 13.51978 187.9133 16.85431 188.3954 20.14545 188.8775 21.41034 189.3596 21.01660 189.8417 22.69373 190.3239 29.24805 190.8060 39.44470 191.2881 46.25800 191.7702 49.04816 192.2523 50.71106 192.7344 55.84888 193.2166 64.21393 193.6987 71.14008 194.1808 74.81616 194.6629 75.34698 195.1450 74.57123 195.6271 72.77783 196.1093 68.96851 196.5914 60.66595 197.0735 47.47736 197.5556 34.61877 198.0377 23.98785 198.5198 15.48987 199.0020 9.241333 199.4841 5.671875 199.9662 3.557312 200.4483 0.6152340 200.9304 3.462830 201.4125 6.535461 201.8947 7.168396 202.3768 5.093506 202.8589 4.088135 203.3410 4.412415 203.8231 5.485413 204.3052 6.386597 204.7874 7.208923 205.2695 7.485413 205.7516 7.094727 206.2337 6.089539 206.7158 3.875305 207.1979 2.4963001E-02 207.6801 4.696655 208.1622 8.112366 208.6443 9.990723 209.1264 11.57391 209.6085 13.23138 210.0906 14.77124 210.5728 17.41748 211.0549 21.63440 211.5370 26.62939 212.0191 30.38019 212.5012 32.47058 212.9833 34.44336 213.4655 37.30646 213.9476 41.81726 214.4297 44.45624 214.9118 44.85742 215.3939 43.51038 215.8760 41.06622 216.3581 36.13422 216.8403 33.00317 217.3224 34.41870 217.8045 42.58948 218.2866 48.35388 218.7687 50.55707 219.2508 50.57385 219.7330 51.95264 220.2151 54.82623 220.6972 58.75250 221.1793 63.77716 221.6614 70.88556 222.1435 76.31171 222.6257 78.99207 223.1078 80.26013 223.5899 83.94531 224.0720 90.71198 224.5541 98.88361 225.0362 108.1667 225.5184 119.5320 226.0005 129.3317 226.4826 136.8333 226.9647 142.9575 227.4468 150.5117 227.9289 159.8196 228.4111 170.0204 228.8932 180.6886 229.3753 191.4937 229.8574 203.7814 230.3395 219.0714 230.8216 235.4010 231.3038 247.5013 231.7859 254.0063 232.2680 258.1313 232.7501 261.3527 233.2322 264.2904 233.7143 265.0652 234.1965 264.8568 234.6786 262.1995 235.1607 252.4937 235.6428 231.9394 236.1249 209.8777 236.6070 190.2073 237.0892 173.2477 237.5713 157.9061 238.0534 144.0479 238.5355 131.8033 239.0176 121.8539 239.4997 115.8530 239.9819 109.6580 240.4640 101.3640 240.9461 89.39325 241.4282 78.99432 241.9103 70.72369 242.3924 63.79724 242.8746 56.33850 243.3567 47.66309 243.8388 39.46399 244.3209 32.28333 244.8030 25.91779 245.2851 21.34698 245.7673 19.07990 246.2494 18.39447 246.7315 17.79114 247.2136 17.34430 247.6957 16.87720 248.1778 16.43274 248.6600 16.31451 249.1421 15.19855 249.6242 12.44165 250.1063 9.021729 250.5884 6.873657 251.0705 6.482910 251.5527 6.529114 252.0348 6.596497 252.5169 6.733643 252.9990 6.686157 253.4811 6.323792 253.9632 5.855774 254.4454 5.632080 254.9275 5.639648 255.4096 5.909363 255.8917 6.541809 256.3738 7.723267 256.8560 8.765320 257.3381 9.255981 257.8202 9.788940 258.3023 11.54938 258.7844 15.26306 259.2665 17.89520 259.7487 18.30145 260.2308 16.12927 260.7129 15.60187 261.1950 16.73798 261.6771 19.06305 262.1592 22.35614 262.6414 27.27197 263.1235 31.53424 263.6056 34.38879 264.0877 35.79895 264.5698 37.28442 265.0519 39.04340 265.5341 40.73450 266.0162 42.10986 266.4983 43.32147 266.9804 43.58710 267.4625 42.41736 267.9446 39.84601 268.4268 37.92462 268.9089 36.80811 269.3910 36.11737 269.8731 35.44971 270.3552 34.73578 270.8373 34.27350 271.3195 33.90833 271.8016 33.74933 272.2837 35.18738 272.7658 38.74664 273.2479 42.77490 273.7300 45.59570 274.2122 46.88306 274.6943 49.05505 275.1764 53.07874 275.6585 58.35901 276.1406 61.47687 276.6227 61.95673 277.1049 61.87769 277.5870 62.87823 278.0691 65.03296 278.5512 67.56989 279.0333 70.71466 279.5154 73.98511 279.9976 75.65942 280.4797 75.58057 280.9618 74.72107 281.4439 73.35333 281.9260 71.46552 282.4081 70.67383 282.8903 71.58112 283.3724 73.24841 283.8545 73.40759 284.3366 71.97339 284.8187 69.91534 285.3008 67.40283 285.7830 64.54163 286.2651 62.85504 286.7472 62.59808 287.2293 63.30743 287.7114 64.33044 288.1935 65.66138 288.6757 66.99084 289.1578 68.06226 289.6399 68.95093 290.1220 69.84387 290.6041 70.62848 291.0862 71.82562 291.5684 74.49622 292.0505 78.50421 292.5326 82.42487 293.0147 85.66040 293.4968 88.28870 293.9789 90.52722 294.4611 92.29547 294.9432 94.07642 295.4253 96.88605 295.9074 100.3728 296.3895 102.9229 296.8716 103.1225 297.3538 102.1315 297.8359 102.3940 298.3180 103.9580 298.8001 105.8565 299.2822 106.9259 299.7643 107.6144 300.2465 109.0383 300.7286 111.3550 301.2107 114.7593 301.6928 120.2408 302.1749 127.6096 302.6570 134.7397 303.1392 140.2994 303.6213 144.3785 304.1034 147.0479 304.5855 148.6485 305.0676 148.5346 305.5497 146.2898 306.0319 141.8867 306.5140 135.0699 306.9961 125.2415 307.4782 113.1429 307.9603 99.21881 308.4424 82.81244 308.9246 66.20667 309.4067 50.08179 309.8888 35.03442 310.3709 22.51147 310.8530 13.89789 311.3351 7.972351 311.8173 4.069397 312.2994 2.561890 312.7815 1.434204 313.2636 0.6935420 313.7457 3.245972 314.2278 5.200256 314.7100 5.904236 315.1921 5.999512 315.6742 5.665466 316.1563 4.796631 316.6384 4.257446 317.1205 4.919128 317.6027 5.993652 318.0848 6.483276 318.5669 5.515686 319.0490 4.408691 319.5311 3.708923 320.0132 3.463684 320.4954 3.187256 320.9775 3.171509 321.4596 2.876404 321.9417 1.843994 322.4238 0.3281860 322.9059 2.914795 323.3881 6.252747 323.8702 10.16669 324.3523 13.04443 324.8344 13.70361 325.3165 13.88892 325.7986 14.64563 326.2808 15.57574 326.7629 17.65771 327.2450 21.69745 327.7271 27.13690 328.2092 31.76025 328.6913 33.92877 329.1735 36.70630 329.6556 41.54364 330.1377 50.48956 330.6198 57.54053 331.1019 61.54657 331.5840 63.97040 332.0662 67.65143 332.5483 72.97833 333.0304 79.02435 333.5125 85.24640 333.9946 91.46045 334.4767 99.11615 334.9589 108.3022 335.4410 118.7220 335.9231 130.0869 336.4052 142.4255 336.8873 155.3516 337.3694 168.5401 337.8515 181.9896 338.3336 197.0259 338.8158 214.2001 339.2979 231.9092 339.7800 248.6564 340.2621 263.9521 340.7442 280.9240 341.2263 299.9056 341.7085 320.7961 342.1906 342.3724 342.6727 364.8477 343.1548 387.8889 343.6369 411.1730 344.1190 434.6097 344.6012 460.0924 345.0833 487.5080 345.5654 517.2904 346.0475 550.3597 346.5296 586.4958 347.0117 625.1329 347.4939 665.5176 347.9760 708.5122 348.4581 753.8796 348.9402 801.1392 349.4223 851.1972 349.9044 903.4451 350.3866 957.2600 350.8687 1011.068 351.3508 1066.661 351.8329 1121.312 352.3150 1172.779 352.7971 1221.125 353.2793 1261.778 353.7614 1293.704 354.2435 1316.094 354.7256 1328.065 355.2077 1331.206 355.6898 1321.191 356.1720 1291.923 356.6541 1245.222 357.1362 1189.462 357.6183 1125.377 358.1004 1055.931 358.5826 982.9197 359.0647 904.8518 359.5468 828.0527 360.0289 754.6081 360.5110 684.8370 360.9931 619.2252 361.4753 558.4667 361.9574 502.4839 362.4395 451.2578 362.9216 404.6624 363.4037 363.2784 363.8858 328.9950 364.3680 299.3380 364.8501 271.6264 365.3322 245.4379 365.8143 221.6453 366.2964 200.4143 366.7785 181.5690 367.2607 165.0195 367.7428 151.3816 368.2249 139.3547 368.7070 128.3027 369.1891 119.4127 369.6712 110.0494 370.1534 99.07965 370.6355 87.48932 371.1176 78.43420 371.5997 73.23181 372.0818 68.62592 372.5639 63.30933 373.0461 56.85565 373.5282 51.10028 374.0103 46.08563 374.4924 41.63025 374.9745 37.53906 375.4566 33.84845 375.9388 30.21930 376.4209 26.40674 376.9030 22.49384 377.3851 20.66772 377.8672 21.63269 378.3493 22.38593 378.8315 19.13556 379.3136 11.77930 379.7957 6.780701 380.2778 5.763733 380.7599 7.314026 381.2420 8.257385 381.7242 8.573730 382.2063 9.040405 382.6884 10.29132 383.1705 12.10565 383.6526 13.61444 384.1347 14.62610 384.6169 15.67383 385.0990 17.31744 385.5811 19.50708 386.0632 22.03552 386.5453 25.25201 387.0274 28.55273 387.5096 30.80933 387.9917 32.01965 388.4738 33.50562 388.9559 35.74921 389.4380 39.00171 389.9201 43.73969 390.4023 51.22650 390.8844 58.92932 391.3665 64.41034 391.8486 68.50787 392.3307 74.09125 392.8128 83.22369 393.2950 93.85559 393.7771 104.6526 394.2592 115.0911 394.7413 126.3821 395.2234 139.2287 395.7055 153.0079 396.1877 166.7619 396.6698 180.3451 397.1519 193.7965 397.6340 207.8170 398.1161 222.7516 398.5982 235.1774 399.0804 248.0061 399.5625 256.3412 400.0446 256.5823 400.5267 246.2245 401.0088 231.2190 401.4909 210.0095 401.9731 184.4102 402.4552 162.1139 402.9373 144.2599 403.4194 127.8464 403.9015 111.5881 404.3836 95.49475 404.8658 79.11670 405.3479 61.74213 405.8300 45.23901 406.3121 32.14948 406.7942 22.57001 407.2763 15.71863 407.7585 11.93884 408.2406 10.72656 408.7227 9.571594 409.2048 8.496826 409.6869 7.245178 410.1690 5.614380 410.6512 3.623474 411.1333 1.132141 411.6154 2.261902 412.0975 5.465332 412.5796 6.470276 413.0617 5.648499 413.5439 4.895020 414.0260 5.739502 414.5081 7.120361 414.9902 7.468872 415.4723 6.609192 415.9544 5.350769 416.4366 4.271790 416.9187 3.234863 417.4008 2.044739 417.8829 6.8359002E-02 418.3650 1.772705 418.8471 2.005066 419.3293 0.9909670 419.8114 0.1317140 420.2935 0.1187130 420.7756 0.4051510 421.2577 0.7057500 421.7398 1.365112 422.2220 1.304321 422.7041 0.5495000 423.1862 3.147034 423.6683 4.612061 424.1504 4.341187 424.6325 3.288940 425.1147 1.384155 425.5968 1.596130 426.0789 3.545410 426.5610 3.054199 427.0431 2.811523 427.5252 5.088013 428.0074 10.78558 428.4895 16.98389 428.9716 23.69012 429.4537 30.48975 429.9358 35.80334 430.4179 39.25067 430.9001 42.48364 431.3822 46.84735 431.8643 52.39374 432.3464 55.37250 432.8285 55.57935 433.3106 53.87000 433.7928 50.85583 434.2749 46.65887 434.7570 42.19501 435.2391 37.23151 435.7212 32.58521 436.2033 30.08923 436.6855 29.62933 437.1676 29.81982 437.6497 29.51489 438.1318 29.28674 438.6139 29.94916 439.0960 31.59326 439.5782 34.28387 440.0603 38.19550 440.5424 43.33624 441.0245 49.56165 441.5066 57.16870 441.9887 65.48407 442.4709 74.37885 442.9530 83.78992 443.4351 92.89838 443.9172 100.0765 444.3993 107.5444 444.8814 116.7747 445.3636 127.8961 445.8457 141.0242 446.3278 157.3076 446.8099 175.5664 447.2920 193.2552 447.7741 206.9745 448.2563 223.7748 448.7384 245.6065 449.2205 273.2152 449.7026 302.4115 450.1847 333.1963 450.6668 365.1547 451.1490 398.0258 451.6311 432.2996 452.1132 465.7769 452.5953 497.7200 453.0774 529.2197 453.5595 566.1312 454.0417 609.2936 454.5238 651.3167 455.0059 689.1336 455.4880 722.6274 455.9701 752.1019 456.4522 776.8765 456.9344 801.1136 457.4165 828.5010 457.8986 859.0060 458.3807 891.2232 458.8628 922.2033 459.3449 957.9283 459.8271 1006.271 460.3092 1066.014 460.7913 1132.548 461.2734 1205.221 461.7555 1281.970 462.2376 1363.042 462.7198 1448.766 463.2019 1533.733 463.6840 1618.798 464.1661 1699.784 464.6482 1771.635 465.1303 1842.750 465.6125 1894.397 466.0946 1919.633 466.5767 1919.853 467.0588 1905.923 467.5409 1879.841 468.0230 1838.748 468.5052 1780.676 468.9873 1702.297 469.4694 1614.695 469.9515 1516.635 470.4336 1411.084 470.9157 1298.505 471.3979 1175.779 471.8800 1058.548 472.3621 949.4411 472.8442 849.5261 473.3263 759.2220 473.8084 678.6318 474.2906 606.8771 474.7727 544.8259 475.2548 491.4879 475.7369 442.3216 476.2190 396.6794 476.7011 355.0176 477.1833 317.2751 477.6654 283.4183 478.1475 253.4506 478.6296 228.1929 479.1117 206.2656 479.5938 186.5920 480.0760 169.0284 480.5581 153.3296 481.0402 139.8571 481.5223 127.7221 482.0044 116.0897 482.4865 104.5375 482.9687 94.73383 483.4508 88.01001 483.9329 83.07898 484.4150 78.31964 484.8971 72.93677 485.3792 68.18774 485.8614 64.62927 486.3435 62.14679 486.8256 59.15125 487.3077 54.98236 487.7898 51.11432 488.2719 48.34540 488.7541 46.94635 489.2362 45.96814 489.7183 45.50745 490.2004 45.33075 490.6825 45.30011 491.1646 45.49866 491.6468 44.96924 492.1289 43.55847 492.6110 41.15662 493.0931 36.98505 493.5752 31.04218 494.0573 24.86298 494.5395 19.09381 495.0216 13.91791 495.5037 9.733337 495.9858 6.786865 496.4679 4.127380 496.9500 0.8250730 497.4322 2.722900 497.9143 5.802673 498.3964 8.377197 498.8785 10.18933 499.3606 10.82874 499.8427 10.47015 500.3249 9.902588 500.8070 9.229065 501.2891 8.544678 501.7712 7.893250 502.2533 7.259155 502.7354 6.715881 503.2176 6.228821 503.6997 5.865540 504.1818 5.825012 504.6639 7.037781 505.1460 6.885559 505.6281 4.994690 506.1103 1.476990 506.5924 3.521790 507.0745 10.47723 507.5566 17.19220 508.0387 21.96014 508.5208 24.96075 509.0030 30.29504 509.4851 38.29132 509.9672 46.78223 510.4493 53.04395 510.9314 57.82220 511.4135 63.52185 511.8957 70.36652 512.3778 78.94855 512.8599 90.75293 513.3420 104.9957 513.8242 119.2990 514.3063 130.5662 514.7884 142.9946 515.2705 160.1399 515.7526 182.1800 516.2347 205.6770 516.7169 228.5876 517.1990 252.7757 517.6811 279.6656 518.1632 310.1985 518.6453 342.4402 519.1274 376.3523 519.6096 411.9781 520.0917 448.9665 520.5738 487.1374 521.0559 526.9219 521.5380 570.3519 522.0201 616.7682 522.5023 655.7831 522.9844 688.9944 523.4665 710.4473 523.9486 714.9076 524.4307 702.8483 524.9128 680.0665 525.3950 645.2371 525.8771 606.9161 526.3592 573.4816 526.8413 545.7871 527.3234 525.9421 527.8055 516.9039 528.2877 514.3274 528.7698 515.9572 529.2519 520.5173 529.7340 522.6559 530.2161 522.4464 530.6982 516.5640 531.1804 501.9873 531.6625 478.0623 532.1446 448.7888 532.6267 411.2664 533.1088 371.2448 533.5909 334.6224 534.0731 299.2219 534.5552 270.6351 535.0373 250.3091 535.5194 236.7963 536.0015 225.4178 536.4836 215.5898 536.9658 209.2709 537.4479 207.3240 537.9300 209.6602 538.4121 214.6912 538.8942 222.2443 539.3763 233.1434 539.8585 248.7227 540.3406 268.4907 540.8227 289.5248 541.3048 311.5225 541.7869 335.1888 542.2690 361.7566 542.7512 390.7719 543.2333 421.1006 543.7154 451.7574 544.1975 483.9606 544.6796 520.0360 545.1617 559.1933 545.6439 596.5009 546.1260 638.4846 546.6081 671.3163 547.0902 688.7493 547.5723 691.4873 548.0544 672.1073 548.5366 616.9724 549.0187 545.9875 549.5008 475.7917 549.9829 401.8599 550.4650 336.8832 550.9471 281.8477 551.4293 236.5079 551.9114 199.4133 552.3935 170.8697 552.8756 149.2260 553.3577 135.1652 553.8398 127.4874 554.3220 120.9244 554.8041 115.4453 555.2862 111.3284 555.7683 108.8829 556.2504 107.9125 556.7325 108.0695 557.2147 109.4166 557.6968 111.7012 558.1789 114.7429 558.6610 118.5710 559.1431 123.1874 559.6252 128.1030 560.1074 134.4189 560.5895 142.2697 561.0716 151.7521 561.5537 163.1128 562.0358 176.2216 562.5179 191.5763 563.0001 209.5305 563.4822 230.1348 563.9643 252.1986 564.4464 275.6277 564.9285 300.3384 565.4106 327.0951 565.8928 356.6277 566.3749 385.3307 566.8570 414.5317 567.3391 440.1139 567.8212 455.8431 568.3033 462.1854 568.7855 462.6769 569.2676 459.5920 569.7497 450.3165 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