#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:16:25 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1048 $ #$URL: svn://172.16.1.111/rod/cif/1/00/04/1000499.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000499 loop_ _publ_author_name 'del Tanago, J.G.' 'La Iglesia, A.' 'Rius, J.' 'Fernandez Santin, S.' _publ_section_title ; Calderonite, a new lead-iron-vanadate of the brackebuschite group ; _journal_name_full 'American Mineralogist' _journal_page_first 1703 _journal_page_last 1708 _journal_volume 88 _journal_year 2003 _chemical_compound_source R050547 _chemical_formula_sum 'Al0.004 As0.016 Ba0.018 Ca0.007 Cu0.034 Fe0.965 H1.494 O9 P0.003 Pb1.924 Si0.085 V1.836 Zn0.009' _chemical_name_systematic ; (Pb1.924 Ba0.018 Ca0.007) (Fe0.965 Cu0.034 Zn0.009 Al0.004) ((V1.836 Si0.085 As0.016 P0.003) O7.506 (O H)1.494) ; _space_group_IT_number 11 _symmetry_space_group_name_Hall '-P 2yb' _symmetry_space_group_name_H-M 'P 1 21/m 1' _cell_angle_alpha 90 _cell_angle_beta 112.23 _cell_angle_gamma 90 _cell_formula_units_Z 2 _cell_length_a 7.649 _cell_length_b 6.101 _cell_length_c 8.904 _cell_volume 384.635 _citation_journal_id_ASTM AMMIAY _cod_data_source_file delTanago_AMMIAY_2003_1201.cif _cod_data_source_block H1.494Al0.004As0.016Ba0.018Ca0.007Cu0.034Fe0.965O9P0.003Pb1.924Si0.085V1.836Zn0.009 _cod_original_cell_volume 384.6345 _cod_original_formula_sum ; H1.494 Al0.004 As0.016 Ba0.018 Ca0.007 Cu0.034 Fe0.965 O9 P0.003 Pb1.924 Si0.085 V1.836 Zn0.009 ; _cod_database_code 1532700 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R050547.rod _rod_data_source.block 3500000 _rod_database.code 1000499 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 1532700 COD http://www.crystallography.net/cod/1532700.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 125.1564 0.0000000E+00 125.6385 13.01935 126.1206 13.98096 126.6027 3.190002 127.0848 4.002319 127.5669 5.134094 128.0491 1.506836 128.5312 7.452393 129.0133 23.05646 129.4954 44.57208 129.9775 71.24286 130.4596 104.0829 130.9418 141.4999 131.4239 179.8065 131.9060 218.3846 132.3881 257.2704 132.8702 295.2535 133.3523 332.3522 133.8345 370.3190 134.3166 410.8483 134.7987 454.3171 135.2808 498.0153 135.7629 542.4109 136.2450 587.3142 136.7272 630.2681 137.2093 671.2084 137.6914 711.1610 138.1735 751.2824 138.6556 791.3634 139.1377 831.2292 139.6199 871.5056 140.1020 911.7782 140.5841 950.4169 141.0662 985.4766 141.5483 1020.759 142.0304 1061.155 142.5126 1107.373 142.9947 1155.291 143.4768 1195.762 143.9589 1223.052 144.4410 1253.331 144.9231 1287.115 145.4053 1323.585 145.8874 1362.672 146.3695 1406.206 146.8516 1449.537 147.3337 1490.213 147.8158 1527.799 148.2980 1566.051 148.7801 1605.761 149.2622 1646.234 149.7443 1684.939 150.2264 1723.173 150.7085 1759.366 151.1907 1792.739 151.6728 1825.458 152.1549 1853.395 152.6370 1876.033 153.1191 1894.049 153.6012 1908.344 154.0834 1920.205 154.5655 1927.284 155.0476 1928.765 155.5297 1924.078 156.0118 1914.350 156.4939 1897.197 156.9761 1874.491 157.4582 1852.976 157.9403 1835.794 158.4224 1819.126 158.9045 1800.709 159.3866 1780.568 159.8688 1758.443 160.3509 1733.052 160.8330 1705.232 161.3151 1678.849 161.7972 1657.707 162.2793 1637.307 162.7615 1614.200 163.2436 1585.151 163.7257 1555.419 164.2078 1527.035 164.6899 1499.776 165.1720 1472.201 165.6541 1443.501 166.1363 1414.132 166.6184 1384.542 167.1005 1355.928 167.5826 1326.297 168.0647 1293.664 168.5468 1258.200 169.0290 1222.254 169.5111 1187.452 169.9932 1152.996 170.4753 1117.684 170.9574 1080.188 171.4395 1042.659 171.9217 1006.399 172.4038 971.4248 172.8859 937.7236 173.3680 906.0193 173.8501 875.6595 174.3322 844.8976 174.8144 811.5698 175.2965 777.9067 175.7786 747.8005 176.2607 721.7885 176.7428 698.0421 177.2249 675.0415 177.7071 653.0526 178.1892 632.2418 178.6713 613.0886 179.1534 594.9315 179.6355 576.4718 180.1176 557.4403 180.5998 539.4818 181.0819 524.5410 181.5640 512.4207 182.0461 501.3549 182.5282 489.1967 183.0103 472.5751 183.4925 456.6760 183.9746 441.5321 184.4567 427.4674 184.9388 415.7798 185.4209 406.0771 185.9030 395.9320 186.3852 382.8810 186.8673 368.1177 187.3494 355.7310 187.8315 346.2510 188.3136 338.1411 188.7957 329.0751 189.2779 319.2273 189.7600 309.6067 190.2421 300.1907 190.7242 291.1210 191.2063 283.8073 191.6884 278.7157 192.1706 274.7382 192.6527 270.0559 193.1348 264.6619 193.6169 259.0625 194.0990 253.2720 194.5811 247.2562 195.0633 241.3573 195.5454 235.7424 196.0275 230.3965 196.5096 225.4685 196.9917 220.9646 197.4738 216.5948 197.9560 212.2297 198.4381 207.8922 198.9202 203.5311 199.4023 198.9646 199.8844 194.7246 200.3665 192.2821 200.8487 191.9976 201.3308 191.4711 201.8129 189.5861 202.2950 186.3237 202.7771 181.9069 203.2592 175.7805 203.7414 169.0714 204.2235 164.1411 204.7056 161.1812 205.1877 159.2830 205.6698 158.2487 206.1519 158.2444 206.6341 157.9481 207.1162 157.4484 207.5983 156.4729 208.0804 154.1599 208.5625 150.0831 209.0446 145.9866 209.5268 142.7933 210.0089 140.7335 210.4910 138.6154 210.9731 136.7018 211.4552 134.5304 211.9373 130.8632 212.4195 125.3026 212.9016 119.3541 213.3837 113.4818 213.8658 107.3077 214.3479 102.7535 214.8300 100.4340 215.3121 99.39417 215.7943 97.36584 216.2764 94.24597 216.7585 90.32056 217.2406 85.26929 217.7227 78.15149 218.2048 73.20789 218.6870 71.62598 219.1691 71.62146 219.6512 68.74854 220.1333 61.45239 220.6154 54.10999 221.0975 48.58838 221.5797 45.63257 222.0618 42.50073 222.5439 39.32788 223.0260 35.95105 223.5081 31.82117 223.9902 26.47754 224.4724 21.28809 224.9545 17.02295 225.4366 14.19397 225.9187 10.71313 226.4008 6.123413 226.8829 1.100708 227.3651 2.920288 227.8472 5.617065 228.3293 7.903442 228.8114 10.11475 229.2935 12.26953 229.7757 14.32520 230.2578 16.23499 230.7399 18.09656 231.2220 20.17188 231.7041 22.88171 232.1862 25.17529 232.6684 26.58423 233.1505 26.74792 233.6326 27.28259 234.1147 28.49341 234.5968 29.93079 235.0789 30.76575 235.5611 30.79053 236.0432 30.53857 236.5253 29.88318 237.0074 28.27966 237.4895 28.51807 237.9716 31.79114 238.4538 36.16431 238.9359 38.42212 239.4180 37.41589 239.9001 36.15833 240.3822 35.60925 240.8643 36.04016 241.3465 35.84009 241.8286 34.57483 242.3107 32.99109 242.7928 32.22229 243.2749 32.85876 243.7570 33.31787 244.2392 33.12952 244.7213 32.16711 245.2034 31.26855 245.6855 30.36316 246.1676 29.54578 246.6497 29.10278 247.1319 29.88025 247.6140 29.41052 248.0961 26.65906 248.5782 21.22266 249.0603 16.95410 249.5424 14.14221 250.0246 12.12646 250.5067 10.25073 250.9888 8.925293 251.4709 6.890503 251.9530 3.664063 252.4351 0.8696290 252.9173 4.874512 253.3994 8.161011 253.8815 11.18823 254.3636 14.43799 254.8457 18.00574 255.3278 21.35693 255.8100 24.26917 256.2921 26.76904 256.7742 29.60876 257.2563 33.00537 257.7384 36.43420 258.2205 39.30481 258.7026 41.31750 259.1848 43.69031 259.6669 46.76221 260.1490 50.45740 260.6311 53.68689 261.1132 56.56689 261.5953 58.85034 262.0775 60.01538 262.5596 59.34705 263.0417 59.88440 263.5238 62.54260 264.0059 66.67163 264.4880 69.19458 264.9702 69.39270 265.4523 69.26404 265.9344 70.12964 266.4165 72.34851 266.8986 74.22290 267.3807 75.44592 267.8629 76.31860 268.3450 77.91589 268.8271 80.50525 269.3092 83.29749 269.7913 85.90808 270.2734 88.20789 270.7556 90.72583 271.2377 92.85266 271.7198 95.85388 272.2019 103.2919 272.6840 116.3369 273.1661 129.9308 273.6483 141.4349 274.1304 150.4062 274.6125 160.5000 275.0946 171.6005 275.5767 183.8954 276.0588 197.8781 276.5410 213.6047 277.0231 230.2655 277.5052 247.1113 277.9873 264.1663 278.4694 282.2258 278.9515 301.3940 279.4337 321.2028 279.9158 340.8893 280.3979 360.2617 280.8800 380.5304 281.3621 402.0342 281.8442 424.6931 282.3264 446.7935 282.8085 468.2676 283.2906 489.5312 283.7727 510.5099 284.2548 531.1141 284.7369 553.2432 285.2191 578.0537 285.7012 604.8165 286.1833 631.4453 286.6654 657.9771 287.1475 684.3645 287.6296 709.8894 288.1118 734.7914 288.5939 760.5173 289.0760 788.2766 289.5581 816.2823 290.0402 840.8042 290.5223 861.9192 291.0045 881.3113 291.4866 900.2552 291.9687 918.6616 292.4508 936.4988 292.9329 954.3588 293.4150 970.9729 293.8972 984.3459 294.3793 994.7235 294.8614 1004.574 295.3435 1015.018 295.8256 1025.833 296.3077 1036.679 296.7899 1047.504 297.2720 1058.806 297.7541 1071.300 298.2362 1084.550 298.7183 1097.032 299.2004 1106.059 299.6826 1114.165 300.1647 1126.443 300.6468 1143.338 301.1289 1162.718 301.6110 1183.185 302.0931 1204.580 302.5753 1227.196 303.0574 1250.543 303.5395 1275.218 304.0216 1300.993 304.5037 1328.055 304.9858 1357.855 305.4680 1392.273 305.9501 1430.525 306.4322 1471.008 306.9143 1512.900 307.3964 1557.075 307.8785 1605.106 308.3607 1656.767 308.8428 1711.473 309.3249 1769.325 309.8070 1829.975 310.2891 1892.664 310.7712 1957.511 311.2534 2024.540 311.7355 2093.880 312.2176 2165.885 312.6997 2239.815 313.1818 2313.418 313.6639 2388.740 314.1461 2468.518 314.6282 2554.324 315.1103 2640.979 315.5924 2725.716 316.0745 2809.059 316.5566 2893.587 317.0388 2978.740 317.5209 3065.589 318.0030 3156.870 318.4851 3254.750 318.9672 3349.285 319.4493 3436.294 319.9315 3517.906 320.4136 3598.103 320.8957 3677.715 321.3778 3755.474 321.8599 3832.090 322.3420 3907.777 322.8242 3979.706 323.3063 4048.463 323.7884 4112.638 324.2705 4171.016 324.7526 4223.325 325.2347 4270.299 325.7169 4311.276 326.1990 4346.658 326.6811 4376.059 327.1632 4399.870 327.6453 4417.412 328.1274 4428.265 328.6096 4430.021 329.0917 4428.095 329.5738 4422.671 330.0559 4413.722 330.5380 4401.190 331.0201 4388.384 331.5023 4368.399 331.9844 4337.267 332.4665 4289.757 332.9486 4244.777 333.4307 4205.469 333.9128 4167.228 334.3950 4123.184 334.8771 4071.753 335.3592 4016.735 335.8413 3959.961 336.3234 3901.400 336.8055 3838.376 337.2877 3770.824 337.7698 3699.786 338.2519 3624.883 338.7340 3545.998 339.2161 3466.323 339.6982 3387.813 340.1803 3309.270 340.6624 3228.222 341.1446 3143.603 341.6267 3056.955 342.1088 2966.062 342.5909 2871.513 343.0730 2778.462 343.5551 2688.739 344.0373 2600.768 344.5194 2513.641 345.0015 2426.508 345.4836 2340.016 345.9657 2253.065 346.4478 2166.406 346.9300 2085.468 347.4121 2010.485 347.8942 1939.210 348.3763 1866.219 348.8584 1792.688 349.3405 1723.196 349.8227 1661.503 350.3048 1604.828 350.7869 1546.562 351.2690 1486.758 351.7511 1429.116 352.2332 1377.413 352.7154 1331.366 353.1975 1290.268 353.6796 1254.905 354.1617 1222.942 354.6438 1191.702 355.1259 1161.272 355.6081 1133.147 356.0902 1108.400 356.5723 1086.483 357.0544 1066.431 357.5365 1048.336 358.0186 1031.796 358.5008 1017.359 358.9829 1004.003 359.4650 989.9932 359.9471 973.2615 360.4292 956.9954 360.9113 943.0980 361.3935 931.9307 361.8756 921.8340 362.3577 914.1631 362.8398 906.8716 363.3219 897.5310 363.8040 883.1572 364.2862 868.9807 364.7683 856.0974 365.2504 844.5762 365.7325 835.5103 366.2146 831.5217 366.6967 828.3983 367.1789 823.5211 367.6610 815.2354 368.1431 806.8149 368.6252 797.8743 369.1073 788.7899 369.5894 780.9595 370.0716 775.4004 370.5537 769.9404 371.0358 763.5219 371.5179 755.2504 372.0000 748.7185 372.4821 744.6371 372.9643 741.8610 373.4464 739.2465 373.9285 738.0188 374.4106 734.3151 374.8927 726.6772 375.3748 715.1744 375.8570 703.6830 376.3391 691.6821 376.8212 680.4677 377.3033 671.5634 377.7854 665.5822 378.2675 657.6888 378.7497 646.7795 379.2318 633.9349 379.7139 621.6937 380.1960 610.3450 380.6781 597.9216 381.1602 583.1044 381.6424 566.2300 382.1245 549.2526 382.6066 532.0079 383.0887 515.1210 383.5708 499.2080 384.0529 484.2490 384.5351 469.1897 385.0172 454.0958 385.4993 438.7067 385.9814 421.8782 386.4635 403.7913 386.9456 384.6980 387.4278 363.9709 387.9099 342.8651 388.3920 323.0956 388.8741 305.3741 389.3562 288.9015 389.8383 273.2070 390.3205 257.9475 390.8026 242.7157 391.2847 226.8843 391.7668 211.2875 392.2489 196.5287 392.7310 182.9753 393.2132 169.1801 393.6953 153.8127 394.1774 138.2325 394.6595 123.9391 395.1416 112.2012 395.6237 101.2667 396.1059 90.86365 396.5880 80.92810 397.0701 70.61133 397.5522 58.44470 398.0343 46.87598 398.5164 37.40491 398.9986 31.90979 399.4807 26.27881 399.9628 21.12219 400.4449 15.70532 400.9270 8.042969 401.4091 4.630981 401.8913 15.79456 402.3734 23.22534 402.8555 26.42004 403.3376 28.61462 403.8197 29.30750 404.3018 29.60718 404.7840 30.68201 405.2661 32.67346 405.7482 35.14294 406.2303 38.39319 406.7124 42.01880 407.1945 44.65027 407.6767 46.33972 408.1588 46.87610 408.6409 45.41321 409.1230 42.15979 409.6051 40.60474 410.0872 41.42883 410.5694 42.86536 411.0515 42.46436 411.5336 40.33398 412.0157 37.01599 412.4978 31.36780 412.9799 25.06946 413.4621 21.83630 413.9442 21.60156 414.4263 22.06189 414.9084 22.43079 415.3905 22.00891 415.8727 19.47070 416.3548 13.34204 416.8369 6.865356 417.3190 3.486206 417.8011 2.023926 418.2832 0.6625980 418.7654 6.955444 419.2475 14.44153 419.7296 21.27600 420.2117 27.06006 420.6938 33.65405 421.1759 43.42383 421.6581 53.69019 422.1402 61.69299 422.6223 63.61890 423.1044 66.46399 423.5865 72.11914 424.0686 80.31140 424.5508 88.87769 425.0329 98.60681 425.5150 107.8435 425.9971 115.5905 426.4792 119.8292 426.9613 126.9308 427.4435 138.8551 427.9256 152.5530 428.4077 162.8867 428.8898 168.1855 429.3719 174.0125 429.8540 181.7954 430.3362 191.4313 430.8183 202.3140 431.3004 214.9671 431.7825 227.2356 432.2646 236.3914 432.7467 242.3861 433.2289 251.3419 433.7110 264.5876 434.1931 280.0388 434.6752 294.5298 435.1573 308.0013 435.6394 319.8704 436.1216 328.1928 436.6036 334.9983 437.0858 345.0378 437.5679 358.4772 438.0500 372.7822 438.5321 386.3239 439.0142 399.1061 439.4963 411.0934 439.9785 422.0320 440.4606 432.5668 440.9427 443.1964 441.4248 453.8259 441.9069 464.0500 442.3890 473.4118 442.8712 482.5273 443.3533 492.2610 443.8354 503.2231 444.3175 512.1971 444.7996 516.1827 445.2817 518.3781 445.7639 522.1330 446.2460 529.9131 446.7281 537.2325 447.2102 543.5642 447.6923 548.8016 448.1744 552.4301 448.6566 554.2104 449.1387 554.5781 449.6208 553.7574 450.1029 551.8227 450.5850 548.2725 451.0671 542.6921 451.5493 535.9957 452.0314 529.5576 452.5135 523.6835 452.9956 517.2422 453.4777 510.2452 453.9598 502.5276 454.4420 492.6482 454.9241 480.5377 455.4062 468.0021 455.8883 456.7247 456.3704 446.3372 456.8525 435.2557 457.3347 423.4644 457.8168 411.3521 458.2989 399.7020 458.7810 388.3881 459.2631 377.3044 459.7452 366.2095 460.2274 354.6218 460.7095 342.6910 461.1916 330.4752 461.6737 318.4901 462.1558 306.7309 462.6379 295.2786 463.1201 284.1942 463.6022 273.3393 464.0843 262.5277 464.5664 251.5857 465.0485 240.7888 465.5306 230.4941 466.0128 221.0998 466.4949 212.0944 466.9770 203.4644 467.4591 195.0738 467.9412 186.8822 468.4233 178.7859 468.9055 171.1283 469.3876 164.1339 469.8697 158.2491 470.3518 152.0944 470.8339 145.2789 471.3160 138.4630 471.7982 132.8063 472.2803 128.3318 472.7624 124.2667 473.2445 120.6483 473.7266 117.4779 474.2087 114.1741 474.6909 110.7222 475.1730 107.2520 475.6551 103.7435 476.1372 100.3290 476.6193 97.63403 477.1014 95.73877 477.5836 94.52020 478.0657 94.34320 478.5478 94.74023 479.0299 94.54761 479.5120 92.89789 479.9941 90.61810 480.4763 88.31891 480.9584 86.04938 481.4405 84.16565 481.9226 83.12683 482.4047 82.34064 482.8868 81.28778 483.3690 79.66864 483.8511 78.23431 484.3332 77.81378 484.8153 77.69330 485.2974 76.59070 485.7795 72.94379 486.2617 69.67566 486.7438 67.37793 487.2259 66.06335 487.7080 65.55743 488.1901 66.66895 488.6722 67.42944 489.1544 66.31793 489.6365 62.53015 490.1186 60.39325 490.6007 60.62720 491.0828 61.66248 491.5649 60.78217 492.0471 57.93329 492.5292 55.34998 493.0113 53.98199 493.4934 53.28088 493.9755 51.55487 494.4576 48.88348 494.9398 46.39880 495.4219 45.16876 495.9040 44.65753 496.3861 44.09857 496.8682 43.39117 497.3503 42.44342 497.8325 40.94220 498.3146 39.17438 498.7967 37.52393 499.2788 36.37897 499.7609 35.25336 500.2430 33.83063 500.7252 32.20782 501.2073 30.73474 501.6894 29.93274 502.1715 29.04767 502.6536 27.74982 503.1357 26.10889 503.6179 23.77625 504.1000 19.51727 504.5821 15.38641 505.0642 13.61499 505.5463 15.59607 506.0284 16.88135 506.5106 16.78552 506.9927 15.53912 507.4748 13.64764 507.9569 10.85315 508.4390 8.635010 508.9211 8.071228 509.4033 8.906677 509.8854 9.006592 510.3675 8.311890 510.8496 7.369995 511.3317 6.697937 511.8138 6.201294 512.2960 5.619446 512.7781 4.721985 513.2602 4.000122 513.7423 3.794739 514.2244 4.147461 514.7065 5.166382 515.1887 9.175110 515.6708 12.10419 516.1529 9.900085 516.6350 2.671692 517.1171 2.427307 517.5992 0.5608520 518.0814 2.802673 518.5635 4.054749 519.0456 1.049316 519.5277 1.285400 520.0098 2.707703 520.4919 3.333801 520.9741 3.196655 521.4562 1.716125 521.9383 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655.4846 200.8463 655.9667 208.2935 656.4488 215.0344 656.9309 219.4124 657.4130 224.0645 657.8951 231.0681 658.3773 241.6544 658.8594 250.7995 659.3415 257.9800 659.8236 264.3339 660.3057 271.3245 660.7878 278.8503 661.2700 286.5553 661.7521 294.3304 662.2342 302.3377 662.7163 311.1693 663.1984 320.4439 663.6805 329.3989 664.1627 337.3539 664.6448 345.1191 665.1269 353.0300 665.6090 361.1331 666.0911 369.3632 666.5732 377.4095 667.0554 386.0227 667.5375 395.8285 668.0196 406.8243 668.5017 416.4161 668.9838 424.1560 669.4659 431.6652 669.9481 440.3359 670.4302 449.9007 670.9123 457.3831 671.3944 462.5645 671.8765 467.3475 672.3586 473.4801 672.8408 480.3613 673.3229 487.0823 673.8050 493.4663 674.2871 499.7297 674.7692 506.5317 675.2513 512.8850 675.7335 517.6957 676.2156 519.4307 676.6977 521.3350 677.1798 524.5519 677.6619 527.9787 678.1440 529.8644 678.6262 529.5543 679.1083 529.6339 679.5904 530.9252 680.0725 532.5974 680.5546 532.7267 681.0367 531.3055 681.5189 529.1488 682.0010 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