#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 11:16:49 +0300 (Thu, 07 Jun 2018) $
#$Revision: 1055 $
#$URL: svn://172.16.1.111/rod/cif/1/00/05/1000503.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000503
loop_
_publ_author_name
'Groat, L. A.'
'Jambor, J. L.'
'Pemberton, B. C.'
_publ_section_title
;
 The crystal structure of argentojarosite, AgFe3(SO4)2(OH)6 Locality:
 Tintic Standard mine at Dividend, central Utah
;
_journal_name_full               'The Canadian Mineralogist'
_journal_page_first              921
_journal_page_last               928
_journal_paper_doi               10.2113/gscanmin.41.4.921
_journal_volume                  41
_journal_year                    2003
_chemical_compound_source        R060097
_chemical_formula_sum            'Ag Al0.12 Fe2.88 H6 O14 S2'
_chemical_name_mineral           Argentojarosite
_space_group_IT_number           166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   7.3398
_cell_length_b                   7.3398
_cell_length_c                   16.538
_cell_volume                     771.582
_exptl_crystal_density_diffrn    3.655
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_original_formula_sum        'Ag (Fe2.88 Al.12) S2 O14 H6'
_cod_database_code               9004771
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type other
_raman_measurement_device.excitation_laser_wavelength 532
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 15
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R060097.rod
_rod_data_source.block           3500000
_rod_database.code               1000503
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9004771 COD http://www.crystallography.net/cod/9004771.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
110.6202 0.0000000E+00
111.1023 0.1945340
111.5844 0.1691380
112.0665 8.8884003E-02
112.5486 5.2007999E-02
113.0308 0.3252830
113.5129 1.103708
113.9950 1.918921
114.4771 2.723267
114.9592 3.509829
115.4413 4.294170
115.9235 5.026192
116.4056 5.777046
116.8877 6.557930
117.3698 7.385487
117.8519 8.247868
118.3340 9.146584
118.8162 10.07557
119.2983 11.01781
119.7804 12.17372
120.2625 13.24705
120.7446 13.97236
121.2267 14.11591
121.7089 14.15882
122.1910 14.38400
122.6731 14.76266
123.1552 15.15513
123.6373 15.45266
124.1194 15.71758
124.6016 16.03846
125.0837 16.46287
125.5658 16.92858
126.0479 17.31593
126.5300 17.63299
127.0121 18.06999
127.4943 18.85456
127.9764 19.88184
128.4585 20.93476
128.9406 21.90725
129.4227 22.84459
129.9048 23.79772
130.3869 24.75965
130.8691 25.79255
131.3512 26.97607
131.8333 28.08623
132.3154 28.93420
132.7975 29.55531
133.2796 30.17687
133.7618 31.40100
134.2439 33.29008
134.7260 35.67763
135.2081 38.39457
135.6902 41.48260
136.1723 44.60212
136.6545 47.91816
137.1366 51.42548
137.6187 53.84238
138.1008 55.30201
138.5829 55.51365
139.0650 53.56284
139.5472 49.12857
140.0293 43.73723
140.5114 37.93760
140.9935 31.38586
141.4756 25.83999
141.9577 21.47365
142.4399 18.13055
142.9220 15.22689
143.4041 12.73679
143.8862 10.66465
144.3683 8.996155
144.8504 7.788136
145.3326 6.885357
145.8147 6.408413
146.2968 6.320301
146.7789 5.925869
147.2610 4.938248
147.7431 3.903625
148.2253 3.290184
148.7074 3.466518
149.1895 3.553883
149.6716 3.384357
150.1537 2.927834
150.6358 2.509579
151.1180 2.168903
151.6001 1.904732
152.0822 1.675102
152.5643 1.472973
153.0464 1.265980
153.5285 1.056530
154.0107 0.8419270
154.4928 0.7370870
154.9749 0.9333110
155.4570 1.189674
155.9391 1.202282
156.4212 0.6525310
156.9034 0.1042710
157.3855 0.2691310
157.8676 0.4329640
158.3497 0.4701610
158.8318 0.3156470
159.3139 5.2379999E-02
159.7961 0.1786840
160.2782 0.3869710
160.7603 0.5224690
161.2424 0.5359340
161.7245 0.3364030
162.2066 0.2072030
162.6888 0.2131880
163.1709 0.3545380
163.6530 0.6328580
164.1351 1.236782
164.6172 1.860947
165.0993 2.294205
165.5815 2.417244
166.0636 2.480164
166.5457 2.566662
167.0278 2.682568
167.5099 2.848190
167.9921 3.087357
168.4742 3.301979
168.9563 3.539806
169.4384 3.793060
169.9205 4.074371
170.4026 4.416779
170.8848 4.806534
171.3669 5.189240
171.8490 5.514214
172.3311 5.820835
172.8132 6.154057
173.2953 6.518566
173.7775 6.926506
174.2596 7.384365
174.7417 7.894913
175.2238 8.465965
175.7059 9.103928
176.1880 9.801201
176.6702 10.53572
177.1523 11.23233
177.6344 12.01439
178.1165 13.07980
178.5986 14.42691
179.0807 15.83348
179.5629 17.24329
180.0450 18.59727
180.5271 19.73792
181.0092 20.66628
181.4913 21.33784
181.9734 21.70432
182.4556 21.76844
182.9377 21.44128
183.4198 20.50565
183.9019 19.06566
184.3840 17.51762
184.8661 15.98742
185.3483 14.37340
185.8304 12.79733
186.3125 11.01357
186.7946 9.213085
187.2767 7.400188
187.7588 5.610264
188.2409 4.157234
188.7231 3.335480
189.2052 2.960430
189.6873 2.299198
190.1694 1.294991
190.6515 0.2534070
191.1336 0.4694020
191.6158 0.8834340
192.0979 1.123268
192.5800 1.203110
193.0621 1.140598
193.5442 1.067570
194.0263 0.9967990
194.5085 0.8735540
194.9906 0.5978510
195.4727 0.1701350
195.9548 0.2784810
196.4369 0.6009450
196.9190 0.8218770
197.4012 1.403122
197.8833 2.402267
198.3654 3.629154
198.8475 4.741047
199.3296 5.726425
199.8117 6.773567
200.2939 7.909630
200.7760 9.125599
201.2581 10.63731
201.7402 12.43343
202.2223 14.54319
202.7044 17.06226
203.1866 20.00013
203.6687 23.15257
204.1508 26.40672
204.6329 29.73989
205.1150 33.32848
205.5971 37.25923
206.0793 41.38860
206.5614 45.41429
207.0435 49.24889
207.5256 53.07036
208.0077 56.98333
208.4898 61.02406
208.9720 65.00164
209.4541 68.87640
209.9362 72.70512
210.4183 76.61727
210.9004 80.57898
211.3825 84.66080
211.8647 88.93989
212.3468 93.45410
212.8289 97.92928
213.3110 102.1617
213.7931 106.5141
214.2752 111.7754
214.7574 118.2047
215.2395 125.0152
215.7216 131.8710
216.2037 138.5242
216.6858 145.9031
217.1679 154.0422
217.6501 162.9290
218.1322 172.3638
218.6143 182.3541
219.0964 193.0856
219.5785 204.4576
220.0606 216.6822
220.5428 229.4132
221.0249 242.9519
221.5070 256.7951
221.9891 269.5399
222.4712 281.6297
222.9533 292.0516
223.4355 300.4350
223.9176 307.5757
224.3997 310.8105
224.8818 310.0208
225.3639 305.4330
225.8460 297.2651
226.3282 284.8371
226.8103 270.0590
227.2924 253.7898
227.7745 235.0789
228.2566 216.6660
228.7387 198.2989
229.2209 180.2861
229.7030 163.8224
230.1851 148.8155
230.6672 135.2124
231.1493 122.9778
231.6314 112.1535
232.1136 102.6166
232.5957 94.63049
233.0778 87.78993
233.5599 81.43782
234.0420 75.67806
234.5241 70.24525
235.0063 65.03279
235.4884 59.98002
235.9705 55.50478
236.4526 51.74275
236.9347 48.46145
237.4168 45.12894
237.8990 41.59708
238.3811 38.25573
238.8632 35.28259
239.3453 32.72705
239.8274 30.38265
240.3095 28.30625
240.7917 26.39583
241.2738 24.43300
241.7559 22.26228
242.2380 20.30196
242.7201 18.76139
243.2022 17.78941
243.6844 16.71692
244.1665 15.47118
244.6486 14.16125
245.1307 12.97637
245.6128 11.95651
246.0949 10.99356
246.5771 10.03683
247.0592 9.046982
247.5413 8.229298
248.0234 7.679012
248.5055 7.240467
248.9876 6.654766
249.4697 5.765633
249.9519 5.004597
250.4340 4.549568
250.9161 4.493919
251.3982 4.264210
251.8803 3.734833
252.3624 3.136948
252.8446 2.841457
253.3267 3.069324
253.8088 3.150089
254.2909 2.831028
254.7730 2.026928
255.2551 1.504856
255.7373 1.385113
256.2194 1.424957
256.7015 1.334023
257.1836 1.057728
257.6657 0.7674260
258.1479 0.4977650
258.6300 0.2515980
259.1121 1.3805000E-02
259.5942 0.2269710
260.0763 0.4480210
260.5584 0.6452600
261.0406 0.8463130
261.5227 0.9391940
262.0048 0.8405530
262.4869 0.5575330
262.9690 0.5066680
263.4511 0.8241960
263.9333 1.173149
264.4154 1.203289
264.8975 0.7878340
265.3796 0.4421730
265.8617 0.2860260
266.3438 0.2956350
266.8260 0.2065730
267.3081 1.3103000E-02
267.7902 0.2746730
268.2723 0.4888080
268.7544 0.6312180
269.2365 0.8321000
269.7187 1.122814
270.2008 1.489841
270.6829 1.850555
271.1650 2.207954
271.6471 2.550922
272.1292 2.851433
272.6114 3.094269
273.0935 3.369625
273.5756 3.661697
274.0577 3.999916
274.5398 4.532608
275.0219 5.314301
275.5041 6.118443
275.9862 6.752674
276.4683 7.176991
276.9504 7.794575
277.4325 8.705029
277.9146 9.786362
278.3968 10.67820
278.8788 11.31793
279.3610 12.07376
279.8431 13.17205
280.3252 14.62901
280.8073 15.96737
281.2894 17.13568
281.7715 18.25656
282.2537 19.67064
282.7358 21.39207
283.2179 23.24911
283.7000 25.24499
284.1821 27.33828
284.6642 29.44442
285.1464 31.54424
285.6285 33.71892
286.1106 36.07522
286.5927 38.61345
287.0748 41.24273
287.5569 43.92303
288.0391 46.67331
288.5212 49.50817
289.0033 52.44174
289.4854 55.45759
289.9675 58.55553
290.4496 61.74622
290.9318 64.95323
291.4139 68.18709
291.8960 71.44965
292.3781 74.66799
292.8602 77.86662
293.3423 81.05180
293.8245 84.17771
294.3066 87.29794
294.7887 90.68420
295.2708 94.43359
295.7529 98.45670
296.2350 102.5013
296.7172 106.5532
297.1993 110.8424
297.6814 115.7224
298.1635 121.0549
298.6456 126.3432
299.1277 131.4709
299.6099 136.6011
300.0920 141.7877
300.5741 147.1032
301.0562 152.5493
301.5383 158.5364
302.0204 164.6766
302.5026 170.2079
302.9847 175.1333
303.4668 179.2313
303.9489 182.6936
304.4310 185.2535
304.9131 186.1726
305.3953 184.9017
305.8774 181.7305
306.3595 176.9801
306.8416 170.6667
307.3237 162.9625
307.8058 153.6466
308.2880 143.0881
308.7701 132.1658
309.2522 120.4709
309.7343 108.9730
310.2164 98.57593
310.6985 89.29653
311.1807 80.73528
311.6628 72.52728
312.1449 64.79139
312.6270 57.96412
313.1091 52.40106
313.5912 47.58043
314.0734 43.12519
314.5555 39.04557
315.0376 35.49770
315.5197 32.79219
316.0018 30.55046
316.4839 28.44445
316.9661 26.22647
317.4482 24.21293
317.9303 22.64392
318.4124 21.46174
318.8945 20.24274
319.3766 18.61856
319.8588 17.04345
320.3409 15.88836
320.8230 15.67418
321.3051 15.23756
321.7872 14.04611
322.2693 12.37082
322.7515 11.01406
323.2336 10.41219
323.7157 9.969290
324.1978 9.391293
324.6799 8.575060
325.1620 7.806458
325.6442 7.080936
326.1263 6.412830
326.6084 5.849998
327.0905 5.555357
327.5726 5.243477
328.0547 4.817837
328.5369 4.229208
329.0190 3.679953
329.5011 3.181858
329.9832 2.714802
330.4653 2.265789
330.9474 1.810308
331.4296 1.413572
331.9117 1.090410
332.3938 0.8437750
332.8759 0.6437530
333.3580 0.5201950
333.8401 0.4079210
334.3223 0.2554340
334.8044 3.0222001E-02
335.2865 0.1770130
335.7686 0.3767760
336.2507 0.5538290
336.7328 0.8554360
337.2150 0.5156440
337.6971 0.3151780
338.1792 0.2467270
338.6613 0.7342660
339.1434 0.4854580
339.6255 0.5190030
340.1077 0.5553570
340.5898 0.1767370
341.0719 0.5366540
341.5540 0.1460020
342.0361 4.1976999E-02
342.5182 0.2069070
343.0004 0.1720200
343.4825 0.2372190
343.9646 0.2835710
344.4467 0.4969980
344.9288 0.8499740
345.4109 1.101456
345.8931 1.079708
346.3752 0.8875520
346.8573 0.9913160
347.3394 1.418005
347.8215 1.916420
348.3036 2.237780
348.7858 2.413195
349.2679 2.590677
349.7500 2.799171
350.2321 3.038492
350.7142 3.277937
351.1964 3.524508
351.6785 3.864386
352.1606 4.473204
352.6427 5.199167
353.1248 5.726473
353.6069 5.955517
354.0891 6.129648
354.5712 6.528526
355.0533 7.091326
355.5354 7.652977
356.0175 8.137724
356.4996 8.562935
356.9818 8.906445
357.4639 9.147942
357.9460 9.489481
358.4281 10.23502
358.9102 11.14073
359.3923 11.83963
359.8745 12.02703
360.3566 12.09200
360.8387 12.31476
361.3208 12.67765
361.8029 12.88461
362.2850 12.68420
362.7672 12.32898
363.2493 12.03282
363.7314 12.01861
364.2135 11.86361
364.6956 11.32420
365.1777 10.52179
365.6599 9.838936
366.1420 9.541176
366.6241 9.250343
367.1062 8.768984
367.5883 7.945251
368.0704 7.222145
368.5526 6.749651
369.0347 6.383924
369.5168 5.892986
369.9989 4.965206
370.4810 4.225851
370.9631 3.877529
371.4453 3.990801
371.9274 3.936689
372.4095 3.623857
372.8916 3.221870
373.3737 2.869673
373.8558 2.583897
374.3380 2.314917
374.8201 2.062471
375.3022 1.820528
375.7843 1.559629
376.2664 1.265850
376.7485 0.9775850
377.2307 0.7088660
377.7128 0.4515420
378.1949 0.2544690
378.6770 0.1225720
379.1591 5.2216999E-02
379.6412 6.7176998E-02
380.1234 0.1804220
380.6055 0.2582970
381.0876 0.2392350
381.5697 0.1336120
382.0518 2.4920000E-02
382.5339 0.2525100
383.0161 0.4341700
383.4982 0.3778340
383.9803 0.1343690
384.4624 1.4599000E-02
384.9445 5.3690001E-02
385.4266 0.2225170
385.9088 0.3076670
386.3909 0.3104000
386.8730 0.2485940
387.3551 5.5528998E-02
387.8372 0.1763650
388.3193 0.2711770
388.8015 0.1669040
389.2836 1.9005001E-02
389.7657 5.7085000E-02
390.2478 7.0261002E-02
390.7299 3.3149999E-02
391.2120 8.4738001E-02
391.6942 0.2280310
392.1763 0.3544860
392.6584 0.4541150
393.1405 0.5283390
393.6226 0.5824010
394.1047 0.6130910
394.5869 0.6062950
395.0690 0.4858800
395.5511 0.4726220
396.0332 0.7436870
396.5153 1.194389
396.9974 1.494972
397.4796 1.291311
397.9617 1.066826
398.4438 1.120831
398.9259 1.613634
399.4080 2.072037
399.8901 2.377569
400.3723 2.618187
400.8544 2.928724
401.3365 3.427956
401.8186 3.868217
402.3007 4.180664
402.7828 4.350536
403.2649 4.512764
403.7470 4.611589
404.2292 4.756210
404.7113 5.071186
405.1934 5.641493
405.6755 6.132299
406.1576 6.454336
406.6397 6.673914
407.1219 7.035395
407.6040 7.566980
408.0861 8.129383
408.5682 8.625349
409.0503 9.048889
409.5324 9.577938
410.0146 10.23715
410.4967 10.95113
410.9788 11.58615
411.4609 12.15318
411.9430 12.81168
412.4251 13.63982
412.9073 14.58995
413.3894 15.56096
413.8715 16.56054
414.3536 17.71083
414.8357 19.18707
415.3178 20.89000
415.8000 22.59707
416.2821 24.23617
416.7642 25.95081
417.2463 27.81309
417.7284 29.86490
418.2105 32.16023
418.6927 34.82587
419.1748 37.69888
419.6569 40.62368
420.1390 43.57919
420.6211 46.87063
421.1032 50.66913
421.5854 54.93021
422.0675 59.59948
422.5496 64.93036
423.0317 70.43441
423.5138 76.01195
423.9959 81.64082
424.4781 87.55219
424.9602 93.76026
425.4423 100.1363
425.9244 106.6967
426.4065 113.5971
426.8886 120.2655
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