#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:17:04 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1059 $ #$URL: svn://172.16.1.111/rod/cif/1/00/05/1000506.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000506 loop_ _publ_author_name 'Wildner, M.' 'Giester, G.' 'Lengauer, C. L.' 'McCammon, C. A.' _publ_section_title ; Structure and crystal chemistry of vivianite-type compounds: Crystal structures of erythrite and annabergite with a Mossbauer study of erythrite ; _journal_name_full 'European Journal of Mineralogy' _journal_page_first 187 _journal_page_last 192 _journal_volume 8 _journal_year 1996 _chemical_compound_source R060564 _chemical_formula_sum 'As2 Co2.01 Fe0.74 H16 Ni0.25 O16' _chemical_name_mineral Erythrite _space_group_IT_number 12 _symmetry_space_group_name_Hall '-C 2y' _symmetry_space_group_name_H-M 'C 1 2/m 1' _cell_angle_alpha 90 _cell_angle_beta 104.98 _cell_angle_gamma 90 _cell_length_a 10.251 _cell_length_b 13.447 _cell_length_c 4.764 _cell_volume 634.377 _exptl_crystal_density_diffrn 3.122 _cod_original_cell_volume 634.378 _cod_original_formula_sum 'Co2.01 Fe.74 Ni.25 As2 O16 H16' _cod_database_code 9005271 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R060564.rod _rod_data_source.block 3500000 _rod_database.code 1000506 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9005271 COD http://www.crystallography.net/cod/9005271.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 89.78320 0.0000000E+00 90.26532 3.4072999E-02 90.74744 0.5065000 91.22955 1.256805 91.71167 2.868881 92.19379 7.427643 92.67590 14.60088 93.15802 20.06075 93.64014 20.21213 94.12225 17.05305 94.60437 15.90285 95.08649 16.03725 95.56860 14.66570 96.05072 13.42712 96.53284 12.21552 97.01495 10.75038 97.49707 9.092293 97.97919 7.225548 98.46130 5.387886 98.94342 3.276802 99.42554 0.9938280 99.90765 0.7239460 100.3898 3.067558 100.8719 6.455933 101.3540 8.454971 101.8361 8.480125 102.3182 8.491425 102.8004 9.236504 103.2825 10.79854 103.7646 12.65705 104.2467 14.84264 104.7288 17.29820 105.2109 19.90538 105.6931 22.85832 106.1752 25.75378 106.6573 28.43054 107.1394 30.46010 107.6215 33.02167 108.1036 37.07050 108.5858 42.03339 109.0679 44.68817 109.5500 44.92973 110.0321 45.49025 110.5142 47.00872 110.9963 48.89658 111.4785 51.39331 111.9606 54.49612 112.4427 58.05267 112.9248 60.99905 113.4069 62.75311 113.8890 64.25666 114.3712 66.39133 114.8533 68.59831 115.3354 71.92905 115.8175 76.80099 116.2996 83.36383 116.7817 90.72830 117.2639 97.90645 117.7460 105.9215 118.2281 116.0758 118.7102 129.5300 119.1923 144.8002 119.6744 161.0539 120.1566 178.3120 120.6387 196.1786 121.1208 218.2883 121.6029 240.8911 122.0850 256.1119 122.5671 261.4825 123.0493 256.8429 123.5314 240.4161 124.0135 209.1837 124.4956 172.7947 124.9777 137.8180 125.4598 104.7242 125.9420 75.99266 126.4241 53.80679 126.9062 37.01102 127.3883 23.69482 127.8704 13.92955 128.3525 6.850235 128.8347 1.584244 129.3168 1.919373 129.7989 4.366455 130.2810 6.084579 130.7631 7.164383 131.2452 7.985672 131.7274 8.604034 132.2095 9.041534 132.6916 9.363144 133.1737 9.562073 133.6558 9.622208 134.1379 9.651794 134.6201 9.640930 135.1022 9.014526 135.5843 7.583328 136.0664 5.381836 136.5485 2.778809 137.0306 0.2275850 137.5128 3.703049 137.9949 7.879318 138.4770 12.85478 138.9591 18.41267 139.4412 24.84251 139.9233 32.20226 140.4055 38.73566 140.8876 44.52527 141.3697 49.41367 141.8518 53.17557 142.3339 55.70409 142.8160 57.34271 143.2982 58.15208 143.7803 58.01114 144.2624 57.35954 144.7445 56.00154 145.2266 54.19157 145.7087 52.48436 146.1909 50.64381 146.6730 49.19446 147.1551 48.34343 147.6372 48.43834 148.1193 48.94542 148.6014 49.96175 149.0836 51.40038 149.5657 53.03140 150.0478 53.94751 150.5299 55.72148 151.0120 59.07979 151.4941 64.66956 151.9763 71.00339 152.4584 77.93427 152.9405 85.53998 153.4226 94.35849 153.9047 103.5398 154.3868 114.5159 154.8690 128.0669 155.3511 144.6342 155.8332 163.3696 156.3153 184.5246 156.7974 207.8978 157.2795 232.0163 157.7617 257.5147 158.2438 283.3318 158.7259 308.6213 159.2080 340.2273 159.6901 364.4772 160.1722 378.0147 160.6544 380.7964 161.1365 373.3743 161.6186 349.8335 162.1007 318.7912 162.5828 287.6389 163.0649 255.3255 163.5471 226.5293 164.0292 203.8757 164.5113 187.4542 164.9934 174.1131 165.4755 163.2859 165.9576 154.3497 166.4398 146.6539 166.9219 140.7569 167.4040 135.3258 167.8861 129.6358 168.3682 123.6270 168.8503 117.3605 169.3325 110.7950 169.8146 103.9879 170.2967 97.11971 170.7788 90.07779 171.2609 83.05038 171.7430 76.19147 172.2252 69.45306 172.7073 63.12466 173.1894 57.29601 173.6715 52.00700 174.1536 47.49768 174.6357 43.87448 175.1179 41.00574 175.6000 39.01224 176.0821 38.08881 176.5642 37.06393 177.0463 34.62497 177.5284 31.09421 178.0106 27.49548 178.4927 24.39072 178.9748 21.55850 179.4569 18.73013 179.9390 15.89835 180.4211 12.93613 180.9033 9.263489 181.3854 5.113373 181.8675 1.652405 182.3496 0.2037960 182.8317 0.8973690 183.3138 1.590485 183.7960 2.491608 184.2781 3.158691 184.7602 3.006104 185.2423 2.049469 185.7244 0.4992680 186.2065 1.715210 186.6887 4.299683 187.1708 6.788452 187.6529 9.202576 188.1350 11.54425 188.6171 13.88202 189.0992 16.24615 189.5814 18.07425 190.0635 19.11624 190.5456 19.38721 191.0277 18.70020 191.5098 16.94998 191.9919 14.41547 192.4741 11.42010 192.9562 7.976257 193.4383 4.810333 193.9204 2.278046 194.4025 0.4098210 194.8846 0.4841610 195.3668 0.4516600 195.8489 0.4246220 196.3310 2.156769 196.8131 4.764801 197.2952 8.053741 197.7773 11.75006 198.2595 15.81482 198.7416 21.25067 199.2237 28.10904 199.7058 36.38663 200.1879 46.13141 200.6700 57.58044 201.1522 69.89307 201.6343 82.20187 202.1164 94.31210 202.5985 108.6381 203.0806 125.6992 203.5627 144.8939 204.0449 164.2493 204.5270 183.8349 205.0091 203.3462 205.4912 222.8115 205.9733 242.4257 206.4554 260.9635 206.9376 278.8537 207.4197 295.3492 207.9018 308.1207 208.3839 316.7542 208.8660 322.7468 209.3481 326.7674 209.8303 328.5915 210.3124 329.4905 210.7945 329.1283 211.2766 328.0268 211.7587 328.2678 212.2408 329.9246 212.7230 332.8005 213.2051 336.6813 213.6872 341.3469 214.1693 347.8140 214.6514 356.1816 215.1335 366.4316 215.6157 378.4241 216.0978 393.2759 216.5799 407.9635 217.0620 420.5732 217.5441 430.5555 218.0262 440.1374 218.5084 449.8037 218.9905 459.3645 219.4726 467.3976 219.9547 473.9072 220.4368 479.1413 220.9189 483.1389 221.4011 485.7632 221.8832 487.6819 222.3653 489.1505 222.8474 489.9860 223.3295 489.4826 223.8116 487.9643 224.2938 484.6527 224.7759 478.9713 225.2580 470.5417 225.7401 460.7641 226.2222 449.7968 226.7043 437.5599 227.1865 423.0883 227.6686 406.3376 228.1507 387.8403 228.6328 367.9266 229.1149 346.1564 229.5970 324.1031 230.0792 301.9318 230.5613 279.5582 231.0434 257.2573 231.5255 234.7635 232.0076 213.1551 232.4897 193.2843 232.9719 175.4748 233.4540 158.7344 233.9361 142.7275 234.4182 127.7052 234.9003 114.2747 235.3824 102.4657 235.8646 92.19794 236.3467 83.45334 236.8288 76.32880 237.3109 70.49536 237.7930 65.93451 238.2751 62.63443 238.7573 60.70770 239.2394 60.22836 239.7215 61.00806 240.2036 62.96921 240.6857 66.15820 241.1678 70.40469 241.6500 75.69354 242.1321 82.00360 242.6142 89.50888 243.0963 98.61649 243.5784 108.3040 244.0605 118.0549 244.5427 127.8415 245.0248 137.8491 245.5069 147.8459 245.9890 158.2059 246.4711 169.7032 246.9532 183.2188 247.4354 196.6177 247.9175 209.2097 248.3996 221.5034 248.8817 231.7192 249.3638 240.2256 249.8459 246.4722 250.3281 249.5157 250.8102 249.5556 251.2923 246.0402 251.7744 238.5031 252.2565 226.5563 252.7386 212.3506 253.2208 194.6936 253.7029 175.6749 254.1850 158.1473 254.6671 142.2109 255.1492 127.4714 255.6313 113.7817 256.1135 101.0534 256.5956 90.23065 257.0777 81.64020 257.5598 74.75577 258.0419 68.92596 258.5240 64.13223 259.0062 60.56927 259.4883 58.36636 259.9704 57.60153 260.4525 57.57736 260.9346 58.17780 261.4167 59.66498 261.8989 62.57562 262.3810 67.48706 262.8631 72.21173 263.3452 76.01172 263.8273 78.94571 264.3094 82.90350 264.7916 88.38028 265.2737 94.18951 265.7558 99.24030 266.2379 103.3177 266.7200 107.2834 267.2021 111.4732 267.6843 115.7759 268.1664 119.2711 268.6485 121.9235 269.1306 123.8289 269.6127 124.9213 270.0948 125.0454 270.5770 124.9939 271.0591 124.7954 271.5412 124.5192 272.0233 124.4931 272.5054 124.7303 272.9875 125.2375 273.4697 125.9014 273.9518 126.5587 274.4339 128.5741 274.9160 132.1352 275.3981 137.0372 275.8802 142.7661 276.3624 149.2533 276.8445 156.6535 277.3266 165.1938 277.8087 174.9180 278.2908 184.9182 278.7729 195.1071 279.2551 205.5209 279.7372 215.9232 280.2193 226.2440 280.7014 237.0977 281.1835 249.2008 281.6656 262.5121 282.1478 275.2250 282.6299 287.2195 283.1120 298.6459 283.5941 309.9452 284.0762 321.2131 284.5583 331.3772 285.0405 340.1112 285.5226 347.4015 286.0047 353.1393 286.4868 357.3528 286.9689 359.9539 287.4510 360.9751 287.9332 360.3843 288.4153 357.6988 288.8974 352.6743 289.3795 345.4488 289.8616 336.4805 290.3438 325.7040 290.8259 313.8017 291.3080 301.1398 291.7901 287.9122 292.2722 274.4733 292.7543 260.9491 293.2365 247.4387 293.7186 234.3142 294.2007 221.6976 294.6828 209.2300 295.1649 196.5249 295.6470 183.7959 296.1292 171.2101 296.6113 158.7150 297.0934 146.7159 297.5755 135.8640 298.0576 126.0527 298.5397 116.7112 299.0219 107.1137 299.5040 97.56137 299.9861 88.86887 300.4682 81.29080 300.9503 74.43927 301.4324 67.80998 301.9146 61.48578 302.3967 55.49109 302.8788 49.85509 303.3609 44.60831 303.8430 39.93021 304.3251 35.87976 304.8073 32.26675 305.2894 28.87332 305.7715 25.76273 306.2536 22.97670 306.7357 20.68001 307.2178 18.67302 307.7000 16.74825 308.1821 14.86417 308.6642 13.27769 309.1463 12.51453 309.6284 12.12439 310.1105 11.38446 310.5927 9.347733 311.0748 7.336349 311.5569 6.463654 312.0390 6.744537 312.5211 6.942413 313.0032 6.097076 313.4854 4.894485 313.9675 4.082596 314.4496 3.950089 314.9317 4.235825 315.4138 4.981461 315.8959 6.119186 316.3781 7.222015 316.8602 7.805466 317.3423 8.455170 317.8244 9.617722 318.3065 11.66328 318.7886 13.84264 319.2708 15.85919 319.7529 17.80887 320.2350 19.96913 320.7171 22.51143 321.1992 25.19572 321.6813 28.00954 322.1635 31.31685 322.6456 33.90201 323.1277 35.33366 323.6098 35.92618 324.0919 36.20522 324.5740 36.25494 325.0562 36.00073 325.5383 35.51338 326.0204 34.93132 326.5025 33.55676 326.9846 31.12355 327.4667 27.97656 327.9489 24.44078 328.4310 20.12547 328.9131 15.86479 329.3952 11.68115 329.8773 7.569504 330.3594 3.771423 330.8416 0.1626590 331.3237 2.983917 331.8058 5.416473 332.2879 6.681656 332.7700 8.033066 333.2521 9.713593 333.7343 11.60497 334.2164 13.12947 334.6985 14.19629 335.1806 15.01169 335.6627 15.69513 336.1448 16.28784 336.6270 16.59486 337.1091 16.59055 337.5912 16.30608 338.0733 15.80638 338.5554 15.10062 339.0375 14.14177 339.5197 12.72289 340.0018 10.79076 340.4839 9.655563 340.9660 9.578964 341.4481 9.757492 341.9302 9.080994 342.4124 7.481369 342.8945 5.935196 343.3766 4.813370 343.8587 3.973007 344.3408 2.646194 344.8229 0.7807620 345.3051 1.185791 345.7872 2.667191 346.2693 3.791077 346.7514 5.508774 347.2335 8.125549 347.7156 11.27567 348.1978 14.32033 348.6799 17.25659 349.1620 20.02452 349.6441 22.52107 350.1262 24.82649 350.6083 27.11253 351.0905 29.41756 351.5726 31.72310 352.0547 34.10185 352.5368 36.48819 353.0189 38.68306 353.5010 40.79643 353.9832 42.56334 354.4653 43.44626 354.9474 43.39702 355.4295 43.35632 355.9116 44.21268 356.3937 45.52565 356.8759 46.62560 357.3580 47.14648 357.8401 47.48303 358.3222 47.78207 358.8043 48.08032 359.2864 48.59201 359.7686 49.28294 360.2507 50.31847 360.7328 51.85220 361.2149 54.07764 361.6970 56.54477 362.1791 59.09984 362.6613 61.76292 363.1434 64.58275 363.6255 67.63481 364.1076 70.79427 364.5897 74.02254 365.0718 77.24240 365.5540 80.56815 366.0361 83.87845 366.5182 87.34819 367.0003 91.18774 367.4824 95.90118 367.9645 100.4960 368.4467 104.8300 368.9288 108.8339 369.4109 112.5981 369.8930 116.1553 370.3751 119.4579 370.8572 122.4897 371.3394 125.2524 371.8215 127.7193 372.3036 130.0511 372.7857 132.0783 373.2678 133.1911 373.7499 133.1502 374.2321 132.6244 374.7142 131.7981 375.1963 130.4884 375.6784 129.7496 376.1605 129.9651 376.6426 130.2577 377.1248 129.1357 377.6069 126.3652 378.0890 123.5203 378.5711 121.1078 379.0532 119.0624 379.5353 117.0408 380.0175 114.9916 380.4996 113.1349 380.9817 111.6738 381.4638 110.5976 381.9459 109.7689 382.4280 109.1764 382.9102 108.8090 383.3923 108.7213 383.8744 108.8915 384.3565 109.1277 384.8386 109.0970 385.3207 109.0728 385.8029 109.6788 386.2850 111.0376 386.7671 112.7185 387.2492 114.4066 387.7313 116.0914 388.2134 117.6708 388.6956 119.0538 389.1777 120.1176 389.6598 120.8443 390.1419 121.2891 390.6240 121.4088 391.1061 121.2657 391.5883 120.7217 392.0704 119.6519 392.5525 117.8194 393.0346 115.8209 393.5167 113.8319 393.9988 111.8823 394.4810 110.0443 394.9631 108.5015 395.4452 107.0005 395.9273 105.3834 396.4094 103.5468 396.8915 101.9323 397.3737 100.7428 397.8558 99.84256 398.3379 98.97458 398.8200 98.03156 399.3021 97.04990 399.7842 96.02606 400.2664 95.01636 400.7485 94.32358 401.2306 94.02902 401.7127 93.89558 402.1948 93.84802 402.6769 94.05515 403.1591 94.07425 403.6412 93.75183 404.1233 93.18622 404.6054 92.71454 405.0875 92.39734 405.5696 92.01593 406.0518 91.41953 406.5339 90.59641 407.0160 89.92725 407.4981 89.55957 407.9802 88.96793 408.4623 87.42886 408.9445 84.95255 409.4266 82.38109 409.9087 79.91989 410.3908 77.52599 410.8729 75.13177 411.3550 72.72818 411.8372 70.32231 412.3193 67.80334 412.8014 65.26952 413.2835 62.94868 413.7656 60.87704 414.2477 58.91667 414.7299 56.95505 415.2120 54.99316 415.6941 53.09613 416.1762 51.34155 416.6583 49.59769 417.1404 47.49689 417.6226 45.05472 418.1047 43.24355 418.5868 42.86507 419.0689 43.25159 419.5510 43.77039 420.0331 44.28203 420.5153 44.86278 420.9974 45.37817 421.4795 45.97124 421.9616 46.99284 422.4437 48.74873 422.9258 50.78481 423.4080 52.85527 423.8901 54.83540 424.3722 57.33026 424.8543 60.36653 425.3364 63.96173 425.8185 68.10814 426.3007 72.76981 426.7828 78.13168 427.2649 84.43430 427.7470 91.50372 428.2291 98.37502 428.7112 104.7653 429.1934 111.3645 429.6755 118.6599 430.1576 126.6530 430.6397 135.1611 431.1218 144.1930 431.6039 153.6683 432.0861 163.4890 432.5682 173.6270 433.0503 184.5885 433.5324 196.7502 434.0145 209.9111 434.4966 223.3520 434.9788 237.0692 435.4609 251.2381 435.9430 266.2140 436.4251 281.9300 436.9072 297.9985 437.3893 314.3518 437.8715 331.3390 438.3536 349.6216 438.8357 368.9040 439.3178 388.3575 439.7999 407.2017 440.2820 426.3225 440.7642 446.7537 441.2463 468.7232 441.7284 489.8136 442.2105 508.7736 442.6926 526.3990 443.1747 543.4723 443.6569 561.2018 444.1390 577.2565 444.6211 591.0466 445.1032 602.6180 445.5853 611.6653 446.0674 617.6183 446.5496 621.6206 447.0317 624.3530 447.5138 626.4866 447.9959 625.0784 448.4780 619.1747 448.9601 610.4398 449.4423 600.2005 449.9244 588.0839 450.4065 575.5270 450.8886 562.8088 451.3707 549.8665 451.8528 535.7700 452.3350 520.1180 452.8171 504.1702 453.2992 488.0621 453.7813 471.7038 454.2634 456.2043 454.7455 441.4661 455.2277 427.5284 455.7098 414.2209 456.1919 401.6132 456.6740 389.3343 457.1561 377.5121 457.6382 366.0327 458.1204 355.0618 458.6025 344.5361 459.0846 334.6569 459.5667 325.2945 460.0488 316.6098 460.5309 308.8588 461.0131 302.2157 461.4952 295.9089 461.9773 289.1494 462.4594 282.5834 462.9415 277.0412 463.4236 273.5934 463.9058 270.3897 464.3879 266.8499 464.8700 263.0262 465.3521 259.0453 465.8342 254.6105 466.3163 250.2200 466.7985 246.1514 467.2806 242.6779 467.7627 239.0956 468.2448 235.6748 468.7269 232.0310 469.2090 227.5878 469.6912 222.1625 470.1733 216.1626 470.6554 209.5399 471.1375 202.3577 471.6196 195.2971 472.1017 188.4261 472.5839 181.4851 473.0660 174.1591 473.5481 166.4730 474.0302 158.4251 474.5123 149.9472 474.9944 141.3214 475.4766 132.6988 475.9587 124.1756 476.4408 116.3400 476.9229 109.6534 477.4050 103.7534 477.8871 98.24377 478.3693 93.09814 478.8514 88.06378 479.3335 82.84059 479.8156 77.65340 480.2977 72.79033 480.7798 68.28577 481.2620 64.20657 481.7441 60.72653 482.2262 57.67558 482.7083 54.80298 483.1904 52.02838 483.6725 49.39627 484.1547 47.14124 484.6368 45.21263 485.1189 42.81052 485.6010 38.99022 486.0831 35.31635 486.5652 32.64717 487.0474 31.56744 487.5295 30.18837 488.0116 28.40880 488.4937 26.42802 488.9758 24.46265 489.4579 22.44612 489.9401 20.63785 490.4222 19.15463 490.9043 17.91898 491.3864 16.42151 491.8685 14.60378 492.3506 12.84848 492.8328 11.41302 493.3149 10.26924 493.7970 9.286407 494.2791 8.478806 494.7612 7.691422 495.2433 6.645065 495.7255 5.460403 496.2076 4.433090 496.6897 3.744537 497.1718 3.187859 497.6539 2.664040 498.1360 2.144562 498.6182 1.492447 499.1003 0.3931050 499.5824 0.6916730 500.0645 1.358192 500.5466 1.484512 501.0287 1.636749 501.5109 2.034332 501.9930 2.517181 502.4751 2.915390 502.9572 3.190094 503.4393 3.401367 503.9214 3.539612 504.4036 3.614494 504.8857 3.668037 505.3678 3.684326 505.8499 3.710716 506.3320 3.772011 506.8141 3.873276 507.2963 3.962807 507.7784 4.038834 508.2605 4.116142 508.7426 4.255432 509.2247 4.442726 509.7068 4.491409 510.1890 4.342216 510.6711 4.092735 511.1532 3.846863 511.6353 3.622108 512.1174 3.492577 512.5995 3.627731 513.0817 3.810547 513.5638 3.784721 514.0459 3.549416 514.5280 3.205452 515.0101 2.614128 515.4922 2.044586 515.9744 1.773598 516.4565 2.007683 516.9386 2.245789 517.4207 2.397720 517.9028 2.433479 518.3849 2.304932 518.8671 1.819336 519.3492 1.371361 519.8313 1.322243 520.3134 1.582550 520.7955 0.6478650 521.2776 2.553612 521.7598 5.364304 522.2419 6.047722 522.7240 4.096329 523.2061 2.753410 523.6882 2.155281 524.1703 1.975060 524.6525 1.785782 525.1346 1.594284 525.6167 1.599419 526.0988 1.910240 526.5809 2.390480 527.0630 2.781929 527.5452 3.110779 528.0273 3.519409 528.5094 4.327469 528.9915 5.141060 529.4736 5.380638 529.9557 4.979446 530.4379 4.722290 530.9200 5.291626 531.4021 6.127136 531.8842 6.667480 532.3663 6.529175 532.8484 6.440720 533.3306 6.615738 533.8127 6.960457 534.2948 7.281433 534.7769 7.607979 535.2590 7.848137 535.7411 7.916519 536.2233 7.826012 536.7054 7.973785 537.1875 8.439934 537.6696 9.004028 538.1517 9.567261 538.6339 10.14017 539.1160 10.51690 539.5981 10.64825 540.0802 10.70316 540.5623 10.88277 541.0444 11.17990 541.5266 11.55448 542.0087 12.02995 542.4908 12.52281 542.9729 12.88445 543.4550 13.14581 543.9371 13.43150 544.4193 13.88938 544.9014 14.35200 545.3835 14.60953 545.8656 14.63010 546.3477 14.80821 546.8298 15.66024 547.3120 16.55110 547.7941 16.93919 548.2762 16.07445 548.7583 15.59715 549.2404 15.88431 549.7225 16.55476 550.2047 16.96099 550.6868 16.98381 551.1689 16.96674 551.6510 16.94227 552.1331 16.93983 552.6152 17.23464 553.0974 17.90414 553.5795 18.48950 554.0616 18.63142 554.5437 18.40769 555.0258 18.24796 555.5079 18.17887 555.9901 18.14927 556.4722 18.10979 556.9543 18.06488 557.4364 18.00803 557.9185 17.93164 558.4006 17.85612 558.8828 17.77187 559.3649 17.68104 559.8470 17.60345 560.3291 17.54613 560.8112 17.50217 561.2933 17.50993 561.7755 17.57390 562.2576 17.50713 562.7397 17.01804 563.2218 16.61260 563.7039 16.57694 564.1860 17.16614 564.6682 17.46616 565.1503 17.50188 565.6324 17.23347 566.1145 16.48790 566.5966 15.18430 567.0787 14.10981 567.5609 13.48864 568.0430 13.15443 568.5251 12.80648 569.0072 12.43554 569.4893 11.97472 569.9714 11.20854 570.4536 10.38975 570.9357 9.963142 571.4178 9.924316 571.8999 9.903168 572.3820 9.614685 572.8641 9.282822 573.3463 9.113937 573.8284 9.207581 574.3105 9.165840 574.7926 8.838745 575.2747 8.349014 575.7568 7.849014 576.2390 7.335510 576.7211 6.819847 577.2032 6.243340 577.6853 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604.6838 3.420891 605.1660 3.319542 605.6481 3.555840 606.1302 4.301125 606.6123 5.413231 607.0944 6.221275 607.5765 6.333603 608.0587 6.173752 608.5408 6.223167 609.0229 6.423042 609.5050 6.574783 609.9871 6.418343 610.4692 6.305252 610.9514 6.564087 611.4335 7.249397 611.9156 7.601585 612.3977 7.060303 612.8798 6.450317 613.3619 6.271706 613.8441 6.774330 614.3262 7.106316 614.8083 7.205490 615.2904 7.225967 615.7725 7.398010 616.2546 7.741486 616.7368 7.878746 617.2189 7.664047 617.7010 7.347733 618.1831 7.454796 618.6652 7.879387 619.1473 8.198738 619.6295 8.104233 620.1116 7.869217 620.5937 7.737495 621.0758 7.700981 621.5579 7.723984 622.0400 7.949402 622.5222 8.097282 623.0043 7.962318 623.4864 7.463745 623.9685 7.035881 624.4506 6.687279 624.9327 6.446732 625.4149 6.344887 625.8970 6.409813 626.3791 6.545868 626.8612 6.797844 627.3433 7.038605 627.8254 7.058372 628.3076 6.867462 628.7897 6.706848 629.2718 6.680069 629.7539 6.645905 630.2360 6.265541 630.7181 5.664658 631.2003 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658.1988 30.89345 658.6809 32.71683 659.1630 33.87715 659.6451 34.48770 660.1273 35.27167 660.6094 36.25882 661.0915 37.44820 661.5736 39.04057 662.0557 40.76271 662.5378 42.07619 663.0200 42.94969 663.5021 43.68871 663.9842 44.56180 664.4663 45.40384 664.9484 45.96361 665.4305 46.06343 665.9127 46.42633 666.3948 47.38785 666.8769 48.52415 667.3590 49.38829 667.8411 49.71878 668.3232 50.34534 668.8054 51.49197 669.2875 52.77550 669.7696 53.44585 670.2517 53.48524 670.7338 53.45828 671.2159 53.47192 671.6981 53.60037 672.1802 54.04120 672.6623 54.69952 673.1444 55.27448 673.6265 55.83487 674.1086 56.06038 674.5908 55.45049 675.0729 54.15680 675.5550 53.18489 676.0371 53.13144 676.5192 53.22850 677.0013 53.22414 677.4835 53.14040 677.9656 52.64545 678.4477 51.62624 678.9298 50.40500 679.4119 49.10480 679.8940 47.71561 680.3762 46.77077 680.8583 46.34329 681.3404 45.93301 681.8225 44.94406 682.3046 43.60350 682.7867 42.41109 683.2689 41.54231 683.7510 40.60605 684.2331 39.23665 684.7152 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