#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 11:17:19 +0300 (Thu, 07 Jun 2018) $
#$Revision: 1063 $
#$URL: svn://172.16.1.111/rod/cif/1/00/05/1000508.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000508
loop_
_publ_author_name
'Moore, P. B.'
'Araki, T.'
_publ_section_title
;
 Armangite, Mn26[As6(OH)4O14][As6O18]2[CO3], a fluorite derivative
 structure
;
_journal_name_full               'American Mineralogist'
_journal_page_first              748
_journal_page_last               757
_journal_volume                  64
_journal_year                    1979
_chemical_compound_source        R100041
_chemical_formula_sum            'C As18 Mn26 O57'
_chemical_name_mineral           Armangite
_space_group_IT_number           147
_symmetry_space_group_name_Hall  '-P 3'
_symmetry_space_group_name_H-M   'P -3'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   13.491
_cell_length_b                   13.491
_cell_length_c                   8.855
_cell_volume                     1395.750
_exptl_crystal_density_diffrn    4.403
_cod_original_cell_volume        1395.749
_cod_original_formula_sum        'C Mn26 As18 O57'
_cod_database_code               9000725
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type other
_raman_measurement_device.excitation_laser_wavelength 532
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 15
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R100041.rod
_rod_data_source.block           3500000
_rod_database.code               1000508
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9000725 COD http://www.crystallography.net/cod/9000725.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
90.49219 0.0000000E+00
90.97430 0.8518100
91.45642 8.0792002E-02
91.93854 2.202742
92.42065 5.781114
92.90277 7.767318
93.38489 7.826334
93.86700 7.066313
94.34912 6.607696
94.83124 6.392165
95.31335 6.338428
95.79547 6.489595
96.27759 6.777978
96.75970 6.844344
97.24182 6.463851
97.72394 5.995486
98.20605 6.447311
98.68817 8.035732
99.17029 9.701544
99.65240 10.50162
100.1345 10.42598
100.6166 10.69553
101.0988 11.63964
101.5809 13.14373
102.0630 14.12682
102.5451 14.70188
103.0272 15.05712
103.5093 15.04139
103.9915 14.54136
104.4736 14.15693
104.9557 14.14278
105.4378 14.53189
105.9199 14.75635
106.4020 14.65568
106.8842 14.49526
107.3663 14.83807
107.8484 16.62850
108.3305 19.22864
108.8126 21.88799
109.2947 23.87964
109.7769 25.62492
110.2590 27.28767
110.7411 28.78328
111.2232 29.94521
111.7053 29.66583
112.1874 28.81474
112.6696 27.86466
113.1517 28.59681
113.6338 28.56071
114.1159 26.83365
114.5980 23.70263
115.0801 21.22052
115.5623 20.28636
116.0444 19.99055
116.5265 19.62687
117.0086 19.19560
117.4907 18.51447
117.9728 17.37807
118.4550 15.76822
118.9371 14.29796
119.4192 13.52222
119.9013 12.99071
120.3834 12.11482
120.8655 10.26798
121.3477 8.233181
121.8298 6.542405
122.3119 5.247832
122.7940 4.222141
123.2761 3.619803
123.7582 3.239855
124.2404 2.635444
124.7225 1.345011
125.2046 0.2273880
125.6867 1.613532
126.1688 2.775112
126.6509 3.675469
127.1331 4.217227
127.6152 4.434488
128.0973 4.495368
128.5794 4.450990
129.0615 4.334542
129.5436 4.205642
130.0258 4.020569
130.5079 3.891819
130.9900 4.118328
131.4721 4.705877
131.9542 5.187065
132.4363 5.151144
132.9185 4.639061
133.4006 3.926805
133.8827 3.031996
134.3648 2.014103
134.8469 1.043604
135.3290 0.1867010
135.8112 0.9181580
136.2933 2.760952
136.7754 5.395222
137.2575 8.078533
137.7396 10.48880
138.2217 12.58850
138.7039 15.27398
139.1860 18.72330
139.6681 22.49336
140.1502 26.09343
140.6323 29.55022
141.1144 32.60378
141.5966 35.12382
142.0787 37.01690
142.5608 38.68847
143.0429 40.04593
143.5250 41.22893
144.0071 42.51590
144.4893 43.82941
144.9714 45.34226
145.4535 47.10521
145.9356 49.20518
146.4177 51.41820
146.8998 53.57170
147.3820 55.81770
147.8641 58.95782
148.3462 63.61757
148.8283 68.76460
149.3104 74.10174
149.7925 79.89776
150.2747 85.53025
150.7568 90.85275
151.2389 95.88213
151.7210 100.8085
152.2031 105.5415
152.6852 110.1694
153.1674 114.8070
153.6495 119.7497
154.1316 124.3466
154.6137 128.5573
155.0958 132.3816
155.5779 135.6931
156.0601 137.9893
156.5422 139.9957
157.0243 142.2955
157.5064 145.1027
157.9885 148.1123
158.4706 151.3750
158.9528 154.9505
159.4349 158.2217
159.9170 160.2221
160.3991 162.0748
160.8812 165.0774
161.3633 170.9129
161.8455 176.9302
162.3276 181.6279
162.8097 184.3284
163.2918 188.0571
163.7739 194.7777
164.2560 202.8529
164.7382 208.3916
165.2203 210.8156
165.7024 213.3503
166.1845 217.8214
166.6666 224.9920
167.1487 232.3002
167.6309 238.6886
168.1130 244.3092
168.5951 249.3384
169.0772 253.4400
169.5593 257.3012
170.0414 261.6310
170.5236 266.9117
171.0057 271.9024
171.4878 275.6831
171.9699 278.4889
172.4520 280.9381
172.9341 282.9725
173.4163 285.0432
173.8984 287.7840
174.3805 291.7512
174.8626 295.7308
175.3447 298.4098
175.8268 300.0501
176.3090 301.9018
176.7911 305.1625
177.2732 309.1088
177.7553 312.5637
178.2374 315.2810
178.7195 317.3190
179.2017 318.6571
179.6838 319.3488
180.1659 319.6855
180.6480 319.8649
181.1301 319.8848
181.6122 319.7775
182.0944 319.7297
182.5765 319.3806
183.0586 318.0303
183.5407 315.6983
184.0228 312.9605
184.5049 310.6490
184.9871 308.4801
185.4692 305.3944
185.9513 300.8623
186.4334 295.2905
186.9155 289.4538
187.3976 283.3745
187.8798 277.0434
188.3619 270.5539
188.8440 263.7998
189.3261 256.5255
189.8082 248.2415
190.2903 239.3819
190.7725 231.3595
191.2546 224.1468
191.7367 217.5156
192.2188 211.1625
192.7009 205.0305
193.1830 199.0943
193.6652 193.3421
194.1473 187.7092
194.6294 182.2011
195.1115 176.8829
195.5936 171.4736
196.0757 165.2724
196.5579 158.2251
197.0400 151.9155
197.5221 147.4145
198.0042 144.5685
198.4863 140.5362
198.9684 135.0112
199.4506 129.0123
199.9327 124.1289
200.4148 120.4193
200.8969 117.0502
201.3790 113.6998
201.8611 110.3767
202.3433 107.1150
202.8254 103.8950
203.3075 100.7468
203.7896 97.78120
204.2717 95.00706
204.7538 92.28156
205.2360 89.37573
205.7181 86.17758
206.2002 83.91789
206.6823 82.90295
207.1644 82.45366
207.6465 81.20964
208.1287 78.92274
208.6108 76.74806
209.0929 75.26308
209.5750 74.61984
210.0571 73.84682
210.5392 72.90709
211.0214 71.87407
211.5035 70.90790
211.9856 70.05760
212.4677 69.16681
212.9498 68.01674
213.4319 66.36139
213.9140 65.64565
214.3962 66.38792
214.8783 67.74835
215.3604 67.67863
215.8425 65.71611
216.3246 63.37198
216.8067 61.23715
217.2889 59.29453
217.7710 57.67653
218.2531 56.47206
218.7352 55.54355
219.2173 54.54372
219.6994 53.41734
220.1816 52.31459
220.6637 51.33701
221.1458 50.62735
221.6279 49.58380
222.1100 47.96338
222.5921 46.09920
223.0743 44.86296
223.5564 44.50529
224.0385 44.35701
224.5206 44.16687
225.0027 44.04832
225.4848 43.55923
225.9670 42.42712
226.4491 41.01353
226.9312 40.34671
227.4133 40.93991
227.8954 41.45082
228.3775 41.15286
228.8597 39.48589
229.3418 38.40385
229.8239 38.16510
230.3060 38.44917
230.7881 38.33887
231.2702 37.52855
231.7524 36.77483
232.2345 36.45221
232.7166 36.77037
233.1987 37.01968
233.6808 37.18829
234.1629 37.28662
234.6451 37.35625
235.1272 37.43991
235.6093 37.43776
236.0914 37.22377
236.5735 36.39636
237.0556 36.38077
237.5378 37.70030
238.0199 39.71216
238.5020 40.62625
238.9841 39.50168
239.4662 38.66408
239.9483 39.19717
240.4305 41.86694
240.9126 44.00702
241.3947 45.43230
241.8768 46.43753
242.3589 47.75720
242.8410 49.77444
243.3232 51.51456
243.8053 52.38060
244.2874 51.55467
244.7695 51.83301
245.2516 53.70714
245.7337 56.49176
246.2159 58.66914
246.6980 60.06490
247.1801 61.19771
247.6622 62.19930
248.1443 62.91991
248.6264 63.88660
249.1086 65.28703
249.5907 66.83937
250.0728 67.96216
250.5549 68.52121
251.0370 68.92500
251.5191 69.31595
252.0013 69.69302
252.4834 70.03607
252.9655 70.37984
253.4476 70.66609
253.9297 70.75397
254.4118 70.62485
254.8940 70.32539
255.3761 69.88350
255.8582 69.32172
256.3403 68.50557
256.8224 67.41028
257.3046 66.08337
257.7867 64.57664
258.2688 62.71722
258.7509 61.02629
259.2330 59.72066
259.7151 58.85699
260.1973 58.09666
260.6794 57.75519
261.1615 57.23538
261.6436 55.49097
262.1257 51.86357
262.6078 48.57907
263.0900 46.36407
263.5721 45.28255
264.0542 44.43961
264.5363 43.82925
265.0184 43.44652
265.5005 43.37946
265.9827 43.86766
266.4648 43.97107
266.9469 43.42226
267.4290 42.22049
267.9111 40.54744
268.3932 38.16374
268.8754 35.69730
269.3575 33.88025
269.8396 32.80780
270.3217 31.97720
270.8038 31.29529
271.2859 30.75406
271.7681 30.37607
272.2502 30.26381
272.7323 30.10664
273.2144 29.54826
273.6965 28.50572
274.1786 27.53020
274.6608 26.84979
275.1429 26.36044
275.6250 25.15356
276.1071 23.02141
276.5892 20.77513
277.0714 19.22603
277.5535 18.42757
278.0356 17.76404
278.5177 17.20079
278.9998 16.66879
279.4819 15.84183
279.9641 14.65747
280.4462 13.40392
280.9283 12.32018
281.4104 11.42607
281.8925 10.44916
282.3746 9.308304
282.8568 8.089478
283.3389 7.037369
283.8210 6.160431
284.3031 5.372330
284.7852 4.458130
285.2673 3.461731
285.7495 3.203964
286.2316 4.106018
286.7137 5.326447
287.1958 4.774338
287.6779 2.384750
288.1600 0.1746670
288.6422 0.4125980
289.1243 0.3972930
289.6064 1.043884
290.0885 1.411224
290.5706 1.556076
291.0527 1.518753
291.5349 1.309296
292.0170 1.052658
292.4991 0.8772430
292.9812 0.7221980
293.4633 0.3792880
293.9454 0.1701510
294.4276 0.8805240
294.9097 1.812042
295.3918 2.905594
295.8739 3.815186
296.3560 4.409744
296.8381 4.682220
297.3203 4.416794
297.8024 3.527664
298.2845 2.668900
298.7666 2.591599
299.2487 3.125916
299.7308 3.742172
300.2130 4.407639
300.6951 4.943787
301.1772 5.036270
301.6593 4.694092
302.1414 4.241226
302.6235 3.785690
303.1057 3.404968
303.5878 3.256592
304.0699 3.699188
304.5520 4.208862
305.0341 4.192963
305.5162 3.682007
305.9984 2.932495
306.4805 1.933670
306.9626 0.8972020
307.4447 0.1750180
307.9268 6.3614003E-02
308.4089 0.1369630
308.8911 0.1377560
309.3732 0.1554110
309.8553 0.5686040
310.3374 2.037567
310.8195 3.780289
311.3016 4.908844
311.7838 4.949081
312.2659 5.015396
312.7480 6.031113
313.2301 7.648376
313.7122 9.015076
314.1943 9.314743
314.6765 9.523895
315.1586 10.46481
315.6407 12.54727
316.1228 14.44104
316.6049 15.11978
317.0870 15.22618
317.5692 15.80417
318.0513 17.70258
318.5334 19.82268
319.0155 21.72549
319.4976 23.39717
319.9797 24.68364
320.4619 25.16727
320.9440 25.36325
321.4261 25.85353
321.9082 27.17644
322.3903 28.45065
322.8724 29.39453
323.3546 29.98409
323.8367 30.51224
324.3188 30.98842
324.8009 31.46387
325.2830 31.97659
325.7651 32.38655
326.2473 33.00233
326.7294 34.16611
327.2115 35.74434
327.6936 36.67319
328.1757 36.11308
328.6578 35.45554
329.1400 35.38857
329.6221 36.36824
330.1042 37.33434
330.5863 38.49161
331.0684 39.63647
331.5505 40.12036
332.0327 39.25479
332.5148 38.53702
332.9969 38.64520
333.4790 40.09357
333.9611 40.94434
334.4432 41.04552
334.9254 40.63171
335.4075 40.06178
335.8896 39.20075
336.3717 38.45074
336.8538 38.02286
337.3359 37.97235
337.8180 37.55058
338.3001 36.62575
338.7823 35.53754
339.2644 34.68613
339.7465 34.10278
340.2286 33.61538
340.7107 33.30414
341.1928 33.07578
341.6750 32.26513
342.1571 30.73035
342.6392 29.08524
343.1213 27.91563
343.6034 27.24406
344.0855 26.21339
344.5677 24.57958
345.0498 22.62486
345.5319 21.05466
346.0140 19.87350
346.4961 18.92159
346.9782 18.27130
347.4604 17.81499
347.9425 17.02945
348.4246 15.77524
348.9067 14.43105
349.3888 13.70766
349.8709 13.46507
350.3531 12.91916
350.8352 11.19731
351.3173 9.015991
351.7994 7.855789
352.2815 7.825645
352.7636 8.067757
353.2458 8.049805
353.7279 7.685013
354.2100 6.771774
354.6921 4.441277
355.1742 2.100449
355.6563 1.566788
356.1385 2.676414
356.6206 3.665451
357.1027 3.009697
357.5848 1.656830
358.0669 0.7328640
358.5490 0.7678450
359.0312 0.9821400
359.5133 1.052971
359.9954 0.9444660
360.4775 0.5391620
360.9596 0.6803670
361.4417 1.929893
361.9239 2.635574
362.4060 2.504181
362.8881 2.420403
363.3702 2.957695
363.8523 3.677666
364.3344 3.915131
364.8166 2.871063
365.2987 1.866501
365.7808 1.484955
366.2629 1.827850
366.7450 2.151482
367.2271 2.470940
367.7093 2.641945
368.1914 2.541481
368.6735 1.877777
369.1556 1.287666
369.6377 0.9243550
370.1198 0.7486340
370.6020 0.4387210
371.0841 0.1355440
371.5662 0.7253800
372.0483 1.224167
372.5304 1.834541
373.0125 1.934090
373.4947 1.160545
373.9768 7.4310000E-03
374.4589 0.4011760
374.9410 0.2995300
375.4231 1.117241
375.9052 1.659637
376.3874 1.868202
376.8695 2.285728
377.3516 2.943108
377.8337 3.766434
378.3158 4.821480
378.7979 6.199532
379.2801 7.092484
379.7622 7.014206
380.2443 6.309792
380.7264 6.722305
381.2085 8.392776
381.6906 10.17009
382.1728 11.01184
382.6549 11.05897
383.1370 11.15655
383.6191 11.46089
384.1012 11.85781
384.5833 12.18971
385.0655 12.45639
385.5476 12.65936
386.0297 12.50422
386.5118 12.35880
386.9939 13.12557
387.4760 15.01536
387.9582 16.81837
388.4403 17.11201
388.9224 16.49438
389.4045 16.20911
389.8866 17.24458
390.3687 18.50432
390.8509 18.92731
391.3330 18.58178
391.8151 18.32555
392.2972 18.80699
392.7793 19.55666
393.2614 20.14552
393.7436 20.56120
394.2257 20.64601
394.7078 19.94217
395.1899 18.81447
395.6720 18.22133
396.1541 18.97007
396.6363 19.92258
397.1184 20.51926
397.6005 20.56045
398.0826 20.69585
398.5647 21.31219
399.0468 21.97693
399.5290 22.16562
400.0111 21.50016
400.4932 20.71657
400.9753 19.70876
401.4574 18.47923
401.9395 18.11481
402.4217 19.37110
402.9038 20.69122
403.3859 20.97057
403.8680 19.65990
404.3501 18.59172
404.8322 17.86883
405.3144 17.47603
405.7965 17.47333
406.2786 17.99554
406.7607 18.46078
407.2428 18.59927
407.7249 18.40240
408.2071 18.09572
408.6892 17.61630
409.1713 17.20488
409.6534 17.25505
410.1355 17.73978
410.6176 18.14395
411.0998 18.38103
411.5819 18.40051
412.0640 17.99284
412.5461 17.12718
413.0282 16.07937
413.5103 14.79530
413.9925 13.67915
414.4746 13.62832
414.9567 15.08520
415.4388 16.49560
415.9209 15.86077
416.4030 13.96899
416.8852 12.65456
417.3673 13.42928
417.8494 14.75931
418.3315 15.44818
418.8136 15.36244
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