#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 11:17:23 +0300 (Thu, 07 Jun 2018) $
#$Revision: 1064 $
#$URL: svn://172.16.1.111/rod/cif/1/00/05/1000509.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000509
loop_
_publ_author_name
'Moore, P. B.'
'Araki, T.'
_publ_section_title
;
 Armangite, Mn26[As6(OH)4O14][As6O18]2[CO3], a fluorite derivative
 structure
;
_journal_name_full               'American Mineralogist'
_journal_page_first              748
_journal_page_last               757
_journal_volume                  64
_journal_year                    1979
_chemical_compound_source        R100054
_chemical_formula_sum            'C As18 Mn26 O57'
_chemical_name_mineral           Armangite
_space_group_IT_number           147
_symmetry_space_group_name_Hall  '-P 3'
_symmetry_space_group_name_H-M   'P -3'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   13.491
_cell_length_b                   13.491
_cell_length_c                   8.855
_cell_volume                     1395.750
_exptl_crystal_density_diffrn    4.403
_cod_original_cell_volume        1395.749
_cod_original_formula_sum        'C Mn26 As18 O57'
_cod_database_code               9000725
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type other
_raman_measurement_device.excitation_laser_wavelength 532
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 15
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R100054.rod
_rod_data_source.block           3500000
_rod_database.code               1000509
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9000725 COD http://www.crystallography.net/cod/9000725.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
90.49219 0.0000000E+00
90.97430 0.3546700
91.45642 0.7077350
91.93854 0.4084190
92.42065 3.0260000E-02
92.90277 0.5491480
93.38489 2.194471
93.86700 4.031059
94.34912 4.826683
94.83124 4.701622
95.31335 4.532866
95.79547 4.797688
96.27759 5.335066
96.75970 6.335534
97.24182 7.959343
97.72394 9.845300
98.20605 11.13552
98.68817 11.95148
99.17029 12.31567
99.65240 12.05516
100.1345 10.97181
100.6166 10.84955
101.0988 12.19863
101.5809 14.65259
102.0630 16.43222
102.5451 17.41941
103.0272 17.81269
103.5093 17.71414
103.9915 17.00088
104.4736 16.78475
104.9557 17.44835
105.4378 19.31101
105.9199 20.72611
106.4020 21.58824
106.8842 21.93084
107.3663 22.06705
107.8484 22.08216
108.3305 23.59863
108.8126 26.76711
109.2947 30.94555
109.7769 34.37634
110.2590 36.75762
110.7411 37.78134
111.2232 38.66264
111.7053 40.27359
112.1874 41.32092
112.6696 40.66885
113.1517 38.56546
113.6338 36.30990
114.1159 34.40220
114.5980 32.83969
115.0801 31.41214
115.5623 30.41246
116.0444 29.36460
116.5265 27.90060
117.0086 25.34122
117.4907 22.86320
117.9728 20.95318
118.4550 19.63962
118.9371 18.44037
119.4192 17.37086
119.9013 16.25506
120.3834 14.84795
120.8655 12.65122
121.3477 10.37690
121.8298 8.543664
122.3119 7.227041
122.7940 6.139192
123.2761 5.305730
123.7582 4.567570
124.2404 3.571419
124.7225 2.015265
125.2046 0.1325080
125.6867 1.918426
126.1688 4.316378
126.6509 6.393770
127.1331 7.117372
127.6152 6.721328
128.0973 6.367880
128.5794 7.098801
129.0615 8.471539
129.5436 9.418591
130.0258 9.627888
130.5079 9.395199
130.9900 9.137358
131.4721 8.867916
131.9542 8.641092
132.4363 8.735357
132.9185 9.041817
133.4006 8.770407
133.8827 7.457813
134.3648 5.463364
134.8469 4.067188
135.3290 3.436188
135.8112 2.665302
136.2933 0.6695290
136.7754 2.622631
137.2575 6.196739
137.7396 9.902767
138.2217 13.64457
138.7039 16.79477
139.1860 18.95114
139.6681 21.16292
140.1502 25.58114
140.6323 33.02303
141.1144 39.76746
141.5966 44.22181
142.0787 45.81898
142.5608 47.49123
143.0429 49.23783
143.5250 51.05310
144.0071 52.96252
144.4893 55.14997
144.9714 57.08801
145.4535 58.26969
145.9356 57.33768
146.4177 58.52248
146.8998 62.94009
147.3820 69.65442
147.8641 74.98251
148.3462 78.05638
148.8283 80.78881
149.3104 84.43694
149.7925 89.81290
150.2747 95.01776
150.7568 99.74476
151.2389 104.0443
151.7210 108.5466
152.2031 113.5194
152.6852 118.4764
153.1674 123.1806
153.6495 127.5799
154.1316 131.7159
154.6137 135.5104
155.0958 138.9583
155.5779 142.4160
156.0601 146.1865
156.5422 149.8789
157.0243 153.1019
157.5064 154.8406
157.9885 156.9823
158.4706 160.1064
158.9528 164.3180
159.4349 168.8966
159.9170 173.5374
160.3991 178.4797
160.8812 183.9995
161.3633 190.6393
161.8455 197.5020
162.3276 204.1609
162.8097 210.3739
163.2918 216.9209
163.7739 223.6035
164.2560 230.4464
164.7382 235.9116
165.2203 242.2922
165.7024 249.5393
166.1845 257.4005
166.6666 266.2094
167.1487 274.5233
167.6309 280.9855
168.1130 286.4738
168.5951 292.7054
169.0772 301.3083
169.5593 310.6303
170.0414 319.1485
170.5236 326.2605
171.0057 333.4198
171.4878 341.6562
171.9699 350.8958
172.4520 360.7145
172.9341 371.7074
173.4163 382.9486
173.8984 393.3284
174.3805 402.5587
174.8626 411.0132
175.3447 418.8762
175.8268 426.3304
176.3090 434.2894
176.7911 444.2917
177.2732 454.9716
177.7553 463.9262
178.2374 469.9630
178.7195 474.7065
179.2017 480.2249
179.6838 486.4905
180.1659 492.6427
180.6480 498.6534
181.1301 504.1164
181.6122 508.2003
182.0944 510.4592
182.5765 511.3166
183.0586 511.7085
183.5407 511.5881
184.0228 510.2734
184.5049 506.6283
184.9871 501.2365
185.4692 496.0643
185.9513 491.9720
186.4334 488.2991
186.9155 483.4685
187.3976 477.4751
187.8798 470.9772
188.3619 464.2435
188.8440 457.3668
189.3261 451.3416
189.8082 447.1939
190.2903 444.0888
190.7725 438.5955
191.2546 430.3211
191.7367 421.7357
192.2188 415.5474
192.7009 411.5587
193.1830 408.2151
193.6652 405.2387
194.1473 402.5165
194.6294 399.3639
195.1115 395.7735
195.5936 391.7424
196.0757 387.0106
196.5579 381.5431
197.0400 376.4116
197.5221 372.5293
198.0042 369.7470
198.4863 365.1405
198.9684 358.3081
199.4506 350.5805
199.9327 344.1448
200.4148 339.1331
200.8969 333.9459
201.3790 327.8716
201.8611 320.9089
202.3433 313.6299
202.8254 305.9251
203.3075 298.0302
203.7896 290.3822
204.2717 282.9074
204.7538 275.8038
205.2360 269.1831
205.7181 263.0674
206.2002 257.1728
206.6823 251.4789
207.1644 246.0251
207.6465 240.8870
208.1287 236.1396
208.6108 231.6101
209.0929 227.1547
209.5750 222.6600
210.0571 218.8015
210.5392 215.5502
211.0214 212.9402
211.5035 211.2626
211.9856 210.9671
212.4677 210.4198
212.9498 208.5196
213.4319 204.5615
213.9140 202.4780
214.3962 203.0667
214.8783 205.0496
215.3604 205.2684
215.8425 202.8975
216.3246 200.6199
216.8067 199.8276
217.2889 201.1741
217.7710 201.6719
218.2531 200.9081
218.7352 199.4490
219.2173 198.7238
219.6994 199.1296
220.1816 199.4977
220.6637 199.3436
221.1458 198.6350
221.6279 197.4635
222.1100 195.6650
222.5921 193.4789
223.0743 191.5063
223.5564 189.9545
224.0385 188.2920
224.5206 186.3507
225.0027 184.1846
225.4848 181.4991
225.9670 177.9309
226.4491 173.9896
226.9312 171.0681
227.4133 169.8616
227.8954 168.5725
228.3775 166.3082
228.8597 162.4144
229.3418 159.0854
229.8239 156.6515
230.3060 154.6889
230.7881 152.0560
231.2702 148.2818
231.7524 144.4703
232.2345 141.1859
232.7166 138.6526
233.1987 136.0081
233.6808 133.3426
234.1629 130.5548
234.6451 127.2606
235.1272 123.1705
235.6093 119.0575
236.0914 115.2518
236.5735 111.8061
237.0556 108.5932
237.5378 105.7397
238.0199 103.0953
238.5020 100.2746
238.9841 97.15482
239.4662 94.00223
239.9483 90.77368
240.4305 86.91650
240.9126 84.42209
241.3947 83.88290
241.8768 84.51321
242.3589 84.40210
242.8410 83.33446
243.3232 81.85080
243.8053 80.12662
244.2874 77.96454
244.7695 76.09590
245.2516 74.55803
245.7337 73.24760
246.2159 71.96297
246.6980 70.64819
247.1801 69.46443
247.6622 68.47661
248.1443 67.71725
248.6264 67.09601
249.1086 66.63101
249.5907 66.26016
250.0728 65.86725
250.5549 65.41931
251.0370 65.04382
251.5191 64.81094
252.0013 64.79913
252.4834 64.63110
252.9655 64.10745
253.4476 63.43546
253.9297 63.14603
254.4118 63.68286
254.8940 64.01392
255.3761 63.58432
255.8582 62.01410
256.3403 61.01035
256.8224 60.81317
257.3046 61.06226
257.7867 61.15952
258.2688 61.01242
258.7509 60.78712
259.2330 60.59502
259.7151 60.46732
260.1973 60.40866
260.6794 60.50276
261.1615 60.54205
261.6436 60.19273
262.1257 59.23479
262.6078 58.36804
263.0900 57.88358
263.5721 57.82957
264.0542 57.70946
264.5363 57.62379
265.0184 57.31975
265.5005 56.31627
265.9827 54.32056
266.4648 52.36087
266.9469 50.83669
267.4290 49.79561
267.9111 48.40302
268.3932 46.61229
268.8754 44.63150
269.3575 42.58215
269.8396 40.28264
270.3217 38.49603
270.8038 37.55655
271.2859 37.40520
271.7681 37.08437
272.2502 36.61208
272.7323 35.93758
273.2144 35.00189
273.6965 33.76331
274.1786 32.43909
274.6608 30.92932
275.1429 29.33492
275.6250 28.41576
276.1071 28.33490
276.5892 28.46568
277.0714 28.29765
277.5535 27.81799
278.0356 27.11473
278.5177 26.05775
278.9998 24.82655
279.4819 24.18044
279.9641 24.16235
280.4462 24.51472
280.9283 25.32472
281.4104 26.63039
281.8925 27.06438
282.3746 26.14445
282.8568 24.42874
283.3389 23.54463
283.8210 23.57224
284.3031 23.79791
284.7852 23.82043
285.2673 23.63774
285.7495 23.10915
286.2316 22.08415
286.7137 20.88766
287.1958 20.32106
287.6779 20.40527
288.1600 20.39636
288.6422 19.53029
289.1243 17.99777
289.6064 17.47488
290.0885 18.39067
290.5706 19.58676
291.0527 18.97954
291.5349 16.68224
292.0170 14.32829
292.4991 12.80408
292.9812 11.95093
293.4633 11.39540
293.9454 11.20094
294.4276 10.93214
294.9097 9.869461
295.3918 8.159485
295.8739 6.558853
296.3560 5.553879
296.8381 4.910767
297.3203 4.079636
297.8024 3.028580
298.2845 2.034149
298.7666 1.482819
299.2487 1.264374
299.7308 1.015747
300.2130 0.6606750
300.6951 0.1588750
301.1772 0.7211610
301.6593 1.972855
302.1414 3.123337
302.6235 3.646439
303.1057 3.753357
303.5878 3.840576
304.0699 4.023590
304.5520 4.302933
305.0341 4.765533
305.5162 5.378052
305.9984 5.921417
306.4805 6.136642
306.9626 6.198608
307.4447 6.328384
307.9268 6.674194
308.4089 7.080399
308.8911 7.572678
309.3732 8.049004
309.8553 8.149025
310.3374 7.134514
310.8195 5.920403
311.3016 5.581993
311.7838 6.672218
312.2659 7.784821
312.7480 7.894394
313.2301 7.303795
313.7122 6.772873
314.1943 6.848640
314.6765 6.967026
315.1586 6.622917
315.6407 5.543549
316.1228 4.714508
316.6049 4.849762
317.0870 5.516388
317.5692 5.993515
318.0513 6.002655
318.5334 5.790634
319.0155 5.389450
319.4976 4.756874
319.9797 4.292587
320.4619 4.292313
320.9440 4.476295
321.4261 4.526695
321.9082 4.654228
322.3903 4.369255
322.8724 3.328400
323.3546 1.510612
323.8367 0.1096800
324.3188 1.427208
324.8009 2.445221
325.2830 3.156784
325.7651 3.037994
326.2473 3.207832
326.7294 3.961906
327.2115 5.224594
327.6936 6.378891
328.1757 7.365364
328.6578 8.247261
329.1400 9.056473
329.6221 9.745583
330.1042 10.41646
330.5863 11.07488
331.0684 11.71523
331.5505 12.33330
332.0327 13.14004
332.5148 13.67377
332.9969 13.65372
333.4790 12.68862
333.9611 12.25854
334.4432 12.48312
334.9254 13.17402
335.4075 14.07075
335.8896 15.38602
336.3717 16.48753
336.8538 17.11962
337.3359 17.23532
337.8180 17.47399
338.3001 17.94183
338.7823 18.37420
339.2644 18.41521
339.7465 17.96272
340.2286 17.56114
340.7107 17.32686
341.1928 17.24873
341.6750 17.34206
342.1571 17.66893
342.6392 17.93074
343.1213 17.77988
343.6034 17.20842
344.0855 16.88805
344.5677 17.05047
345.0498 17.40337
345.5319 17.10642
346.0140 16.13373
346.4961 15.24908
346.9782 15.09520
347.4604 15.50069
347.9425 15.60634
348.4246 15.27578
348.9067 14.80712
349.3888 14.73837
349.8709 14.97322
350.3531 14.97054
350.8352 14.32858
351.3173 13.29779
351.7994 12.24509
352.2815 11.16763
352.7636 10.32445
353.2458 10.15975
353.7279 10.41468
354.2100 10.52508
354.6921 10.02513
355.1742 9.447449
355.6563 9.603745
356.1385 10.39242
356.6206 10.77850
357.1027 9.423439
357.5848 7.498009
358.0669 6.432480
358.5490 7.142235
359.0312 7.979172
359.5133 7.867989
359.9954 7.005348
360.4775 6.052353
360.9596 5.063080
361.4417 4.280602
361.9239 3.927521
362.4060 4.203247
362.8881 4.395233
363.3702 4.215813
363.8523 3.783539
364.3344 3.296028
364.8166 2.438713
365.2987 1.872047
365.7808 2.071053
366.2629 3.208397
366.7450 3.757820
367.2271 2.724365
367.7093 1.394714
368.1914 0.9483180
368.6735 2.488121
369.1556 3.784180
369.6377 4.255402
370.1198 4.021019
370.6020 4.134552
371.0841 4.896194
371.5662 5.808693
372.0483 6.560242
372.5304 7.069519
373.0125 7.614227
373.4947 8.260574
373.9768 8.956299
374.4589 9.552086
374.9410 9.942749
375.4231 10.37116
375.9052 10.96376
376.3874 11.75224
376.8695 12.66580
377.3516 13.82849
377.8337 14.96150
378.3158 15.61252
378.7979 15.66757
379.2801 16.10872
379.7622 17.48579
380.2443 19.45102
380.7264 20.31781
381.2085 20.00507
381.6906 19.44113
382.1728 19.21638
382.6549 19.32512
383.1370 19.92740
383.6191 21.15485
384.1012 22.63556
384.5833 23.68513
385.0655 24.38908
385.5476 25.29507
386.0297 27.09511
386.5118 29.22578
386.9939 30.64789
387.4760 31.21230
387.9582 31.45885
388.4403 31.79742
388.9224 32.20334
389.4045 32.62009
389.8866 32.72301
390.3687 33.03954
390.8509 34.22343
391.3330 36.18806
391.8151 38.04199
392.2972 39.31868
392.7793 40.18069
393.2614 40.74933
393.7436 40.72653
394.2257 40.87221
394.7078 41.66147
395.1899 42.87592
395.6720 43.94182
396.1541 44.53166
396.6363 45.05057
397.1184 45.67796
397.6005 46.43867
398.0826 47.29404
398.5647 48.52216
399.0468 49.74695
399.5290 50.51221
400.0111 50.14134
400.4932 50.01158
400.9753 50.54112
401.4574 51.72784
401.9395 52.35727
402.4217 51.98984
402.9038 51.53325
403.3859 51.69296
403.8680 53.04860
404.3501 53.56656
404.8322 52.74457
405.3144 51.16847
405.7965 50.47319
406.2786 50.89197
406.7607 51.40422
407.2428 51.55826
407.7249 51.34370
408.2071 51.16821
408.6892 51.08966
409.1713 50.88245
409.6534 50.09993
410.1355 48.77638
410.6176 47.73122
411.0998 47.41136
411.5819 47.41379
412.0640 46.55505
412.5461 44.86816
413.0282 43.32887
413.5103 43.13832
413.9925 43.62326
414.4746 43.22588
414.9567 41.42615
415.4388 39.33929
415.9209 38.27974
416.4030 37.93582
416.8852 37.37756
417.3673 35.74513
417.8494 33.90436
418.3315 32.58467
418.8136 31.83652
419.2957 31.25249
419.7779 30.59398
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