#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 11:17:49 +0300 (Thu, 07 Jun 2018) $
#$Revision: 1071 $
#$URL: svn://172.16.1.111/rod/cif/1/00/05/1000514.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000514
loop_
_publ_author_name
'Mereiter, K.'
_publ_section_title
;
 Chenite, Pb4Cu(SO4)2(OH)6, from Susanna mine, Leadhills, Scotland. Note:
 Crystal is from the Paar et al (1986) mineral description paper Locality:
 Susanna mine, Leadhills, Scotland
;
_journal_name_full               'Private communication'
_journal_page_first              1
_journal_page_last               1
_journal_volume                  1
_journal_year                    2009
_chemical_compound_source        R130278
_chemical_formula_structural     Pb4Cu(SO4)2(OH)6
_chemical_formula_sum            'Cu H6 O14 Pb4 S2'
_chemical_name_mineral           Chenite
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                111.994
_cell_angle_beta                 97.765
_cell_angle_gamma                100.426
_cell_length_a                   5.7960
_cell_length_b                   7.9471
_cell_length_c                   7.9836
_cell_volume                     326.939
_exptl_crystal_density_diffrn    6.026
_cod_original_formula_sum        'Pb4 Cu S2 O14 H6'
_cod_database_code               9014000
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type other
_raman_measurement_device.excitation_laser_wavelength 532
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 15
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R130278.rod
_rod_data_source.block           3500000
_rod_database.code               1000514
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9014000 COD http://www.crystallography.net/cod/9014000.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
90.80798 0.0000000E+00
91.29010 1.573746
91.77222 2.537354
92.25433 4.255737
92.73645 6.119156
93.21857 8.330780
93.70068 7.928238
94.18280 5.143753
94.66492 2.600128
95.14703 0.7502750
95.62915 0.3121950
96.11127 0.1903080
96.59338 1.306686
97.07550 3.522339
97.55762 5.271301
98.03973 6.030014
98.52185 6.668198
99.00397 7.799423
99.48608 9.486725
99.96820 10.27916
100.4503 10.10413
100.9324 9.397583
101.4146 8.837906
101.8967 8.177429
102.3788 7.306152
102.8609 5.919266
103.3430 3.482468
103.8251 2.377838
104.3073 3.576218
104.7894 6.677597
105.2715 9.010086
105.7536 10.39653
106.2357 11.04659
106.7178 11.11983
107.2000 10.21075
107.6821 9.745377
108.1642 10.14134
108.6463 11.43158
109.1284 12.12285
109.6105 12.05626
110.0927 11.45670
110.5748 10.57600
111.0569 8.233261
111.5390 6.692261
112.0211 6.886353
112.5032 9.636856
112.9854 11.49088
113.4675 11.76588
113.9496 10.94861
114.4317 9.699890
114.9138 6.897003
115.3959 4.678070
115.8781 4.277328
116.3602 7.077179
116.8423 9.482376
117.3244 9.865021
117.8065 8.765961
118.2886 7.728973
118.7708 7.236313
119.2529 7.063751
119.7350 7.036987
120.2171 6.590118
120.6992 6.867065
121.1813 9.167282
121.6635 12.83267
122.1456 15.80780
122.6277 17.70743
123.1098 18.71620
123.5919 18.59666
124.0740 17.72455
124.5562 16.80614
125.0383 16.18018
125.5204 15.51490
126.0025 14.82310
126.4846 14.53185
126.9667 14.60004
127.4489 14.57909
127.9310 14.60201
128.4131 14.58381
128.8952 14.27563
129.3773 13.69324
129.8594 13.10344
130.3416 12.33726
130.8237 11.41575
131.3058 10.97832
131.7879 11.51651
132.2700 12.96307
132.7521 13.64357
133.2343 12.88494
133.7164 11.60085
134.1985 11.05701
134.6806 11.24680
135.1627 11.55450
135.6448 11.64881
136.1270 11.52413
136.6091 11.28954
137.0912 10.98764
137.5733 10.59743
138.0554 9.819313
138.5375 8.485359
139.0197 7.294807
139.5018 6.910721
139.9839 7.592926
140.4660 7.971443
140.9481 7.804993
141.4302 7.117195
141.9124 6.159157
142.3945 4.758453
142.8766 3.332657
143.3587 2.297867
143.8408 1.767204
144.3229 1.419403
144.8051 1.198296
145.2872 1.095917
145.7693 1.177505
146.2514 1.626160
146.7335 2.142097
147.2156 2.333130
147.6978 1.936584
148.1799 1.543953
148.6620 1.972443
149.1441 2.998337
149.6262 3.288200
150.1083 2.289536
150.5905 0.6519320
151.0726 0.5030140
151.5547 0.9958500
152.0368 1.137924
152.5189 0.9591600
153.0010 3.0685000E-02
153.4832 0.4490360
153.9653 0.3352430
154.4474 1.728867
154.9295 2.365326
155.4116 1.112885
155.8937 0.2275010
156.3759 0.8198780
156.8580 3.8215999E-02
157.3401 0.8574910
157.8222 1.499931
158.3043 1.922714
158.7864 1.968140
159.2686 1.429344
159.7507 0.5949250
160.2328 0.3546520
160.7149 1.994034
161.1970 3.111237
161.6791 2.860626
162.1613 1.514290
162.6434 0.7124480
163.1255 1.540512
163.6076 3.028664
164.0897 4.312927
164.5718 5.314537
165.0540 5.881126
165.5361 5.864204
166.0182 5.275963
166.5003 4.427055
166.9824 3.237411
167.4645 1.927116
167.9467 0.7888640
168.4288 6.2438998E-02
168.9109 0.7291560
169.3930 1.266724
169.8751 1.671997
170.3572 1.928436
170.8394 2.150742
171.3215 2.228180
171.8036 1.965515
172.2857 0.7284550
172.7678 0.5970380
173.2499 0.8786850
173.7321 9.4581999E-02
174.2142 0.8795700
174.6963 0.1922840
175.1784 2.395760
175.6605 4.033897
176.1426 3.669998
176.6248 2.417984
177.1069 1.758751
177.5890 1.859962
178.0711 2.399979
178.5532 3.150993
179.0353 4.098846
179.5175 5.134483
179.9996 6.187401
180.4817 7.283630
180.9638 8.530350
181.4459 9.983154
181.9280 11.47511
182.4102 12.92107
182.8923 14.27054
183.3744 15.36634
183.8565 15.73122
184.3386 15.72177
184.8207 16.46764
185.3029 18.36618
185.7850 20.63744
186.2671 21.95427
186.7492 22.34596
187.2313 22.61877
187.7134 23.32417
188.1956 24.39115
188.6777 25.48006
189.1598 26.60974
189.6419 27.68195
190.1240 28.40425
190.6061 28.76411
191.0883 29.08630
191.5704 29.54780
192.0525 30.16669
192.5346 31.03505
193.0167 32.14754
193.4988 33.45218
193.9810 34.65182
194.4631 35.64353
194.9452 36.85321
195.4273 38.29675
195.9094 39.96091
196.3915 41.32822
196.8737 42.17892
197.3558 42.72237
197.8379 43.85346
198.3200 45.71298
198.8021 47.47942
199.2842 48.35561
199.7664 48.32339
200.2485 48.13491
200.7306 47.91835
201.2127 47.67265
201.6948 47.32834
202.1769 46.81786
202.6591 46.43910
203.1412 46.49664
203.6233 47.02975
204.1054 47.73869
204.5875 48.56721
205.0696 49.50112
205.5518 50.56252
206.0339 51.84743
206.5160 53.06111
206.9981 53.84516
207.4802 54.08881
207.9623 54.26099
208.4445 54.38103
208.9266 54.44650
209.4087 54.79160
209.8908 55.59104
210.3729 56.43867
210.8550 56.83932
211.3372 56.54762
211.8193 56.43559
212.3014 56.87262
212.7835 57.90293
213.2656 58.20039
213.7477 57.52950
214.2299 56.42546
214.7120 55.46573
215.1941 54.62695
215.6762 53.96214
216.1583 53.56436
216.6404 53.48103
217.1226 53.24666
217.6047 52.89525
218.0868 52.40117
218.5689 51.69180
219.0510 50.61909
219.5331 49.51944
220.0153 48.41471
220.4974 47.28288
220.9795 46.40710
221.4616 45.90439
221.9437 45.51247
222.4258 44.88919
222.9080 43.91388
223.3901 42.95735
223.8722 42.10536
224.3543 41.34306
224.8364 40.71469
225.3185 40.21454
225.8007 39.83137
226.2828 39.58299
226.7649 39.61295
227.2470 39.49129
227.7291 39.06145
228.2112 38.27715
228.6934 37.63382
229.1755 37.26591
229.6576 36.95808
230.1397 36.47435
230.6218 35.78699
231.1039 34.88817
231.5861 33.62000
232.0682 31.83398
232.5503 30.72105
233.0324 30.37338
233.5145 30.54011
233.9966 31.03045
234.4788 32.27776
234.9609 33.03817
235.4430 32.78299
235.9251 31.25867
236.4072 30.57703
236.8893 31.08862
237.3715 32.14675
237.8536 32.97858
238.3357 33.57676
238.8178 33.97163
239.2999 34.10683
239.7820 33.92017
240.2642 33.92596
240.7463 34.26506
241.2284 34.67087
241.7105 34.82697
242.1926 34.70584
242.6747 34.37143
243.1569 33.76166
243.6390 32.80598
244.1211 32.10881
244.6032 31.86707
245.0853 31.70408
245.5674 31.12873
246.0496 29.77762
246.5317 28.70733
247.0138 28.33704
247.4959 28.80355
247.9780 28.45697
248.4601 26.80843
248.9423 24.81481
249.4244 23.58931
249.9065 23.61436
250.3886 23.43211
250.8707 22.60257
251.3528 21.08685
251.8350 20.05466
252.3171 19.72231
252.7992 19.65073
253.2813 19.38202
253.7634 18.78313
254.2455 18.28121
254.7277 18.01912
255.2098 18.00191
255.6919 17.73914
256.1740 17.10980
256.6561 16.38190
257.1382 15.77271
257.6204 15.18943
258.1025 14.97056
258.5846 15.39491
259.0667 16.40518
259.5488 16.56615
260.0309 15.42796
260.5131 14.09184
260.9952 13.66093
261.4773 14.63660
261.9594 15.07269
262.4415 14.41843
262.9236 12.82888
263.4058 11.99442
263.8879 12.20057
264.3700 12.66831
264.8521 12.84105
265.3342 12.72281
265.8163 12.24936
266.2985 11.22978
266.7806 9.828751
267.2627 9.024406
267.7448 9.001427
268.2269 9.195358
268.7090 9.209160
269.1912 9.008240
269.6733 8.784508
270.1554 8.599251
270.6375 8.398026
271.1196 7.895432
271.6017 6.959038
272.0839 6.083916
272.5660 5.656258
273.0481 5.743622
273.5302 5.817764
274.0123 5.822739
274.4944 5.790283
274.9766 5.866394
275.4587 6.116722
275.9408 6.225319
276.4229 5.926239
276.9050 5.179153
277.3871 4.521500
277.8693 3.956032
278.3514 3.541000
278.8335 3.484673
279.3156 3.851913
279.7977 4.198021
280.2798 4.274200
280.7620 4.078018
281.2441 3.814827
281.7262 3.466339
282.2083 3.102150
282.6904 2.827133
283.1725 2.639061
283.6547 2.560417
284.1368 2.714157
284.6189 3.058990
285.1010 3.062988
285.5831 2.638771
286.0652 2.087593
286.5474 1.851418
287.0295 1.925064
287.5116 2.065468
287.9937 2.208115
288.4758 2.342278
288.9579 2.394188
289.4401 2.363121
289.9222 2.268127
290.4043 1.962166
290.8864 1.511551
291.3685 1.475029
291.8506 2.436729
292.3328 3.929062
292.8149 4.376434
293.2970 3.710495
293.7791 2.887314
294.2612 3.035889
294.7433 3.912285
295.2255 4.544540
295.7076 4.532921
296.1897 4.119400
296.6718 3.669167
297.1539 3.188026
297.6360 2.858055
298.1182 3.014084
298.6003 3.450066
299.0824 3.629524
299.5645 3.274902
300.0466 2.740814
300.5287 2.577759
301.0109 2.736588
301.4930 2.864700
301.9751 2.706322
302.4572 2.346130
302.9393 1.942726
303.4214 1.563629
303.9036 1.083099
304.3857 0.2044750
304.8678 0.9397660
305.3499 1.883911
305.8320 2.316528
306.3141 2.390289
306.7963 2.249306
307.2784 1.875061
307.7605 1.410774
308.2426 0.8809970
308.7247 0.3452380
309.2068 5.4770999E-02
309.6890 7.5728998E-02
310.1711 2.4261000E-02
310.6532 0.2160340
311.1353 0.7424850
311.6174 1.194778
312.0995 1.132332
312.5817 0.8421400
313.0638 0.7870940
313.5459 1.420891
314.0280 2.149925
314.5101 2.588905
314.9922 2.696014
315.4744 2.796150
315.9565 2.856010
316.4386 3.057892
316.9207 3.606186
317.4028 5.157974
317.8849 6.531685
318.3671 7.079384
318.8492 6.845070
319.3313 6.792038
319.8134 7.369385
320.2955 8.194107
320.7776 8.953583
321.2598 9.559830
321.7419 10.11912
322.2240 10.60406
322.7061 11.03934
323.1882 11.55755
323.6703 12.33339
324.1525 13.09575
324.6346 13.67971
325.1167 13.79939
325.5988 14.11395
326.0809 14.86261
326.5630 15.86522
327.0452 16.62942
327.5273 16.86677
328.0094 17.08025
328.4915 17.50189
328.9736 18.45644
329.4557 18.87621
329.9379 18.23148
330.4200 17.21864
330.9021 16.99951
331.3842 18.35928
331.8663 19.46867
332.3484 19.74321
332.8306 19.01665
333.3127 18.57377
333.7948 18.39743
334.2769 18.48466
334.7590 18.95522
335.2411 20.20989
335.7233 21.00092
336.2054 20.93731
336.6875 20.07387
337.1696 19.48107
337.6517 19.28588
338.1339 19.13529
338.6160 18.67786
339.0981 17.79207
339.5802 17.04710
340.0623 16.53691
340.5444 16.26062
341.0266 16.26387
341.5087 16.61079
341.9908 16.82857
342.4729 16.53145
342.9550 15.74446
343.4371 15.25195
343.9193 15.17817
344.4014 15.23798
344.8835 15.02316
345.3656 14.55827
345.8477 13.95653
346.3298 13.03143
346.8120 11.89181
347.2941 11.19118
347.7762 10.96838
348.2583 11.09309
348.7404 11.56033
349.2225 12.27872
349.7047 12.87149
350.1868 13.15122
350.6689 13.26463
351.1510 13.43119
351.6331 13.62408
352.1152 13.81643
352.5974 13.92054
353.0795 14.04752
353.5616 14.42017
354.0437 15.25261
354.5258 16.16153
355.0079 16.76714
355.4901 17.09402
355.9722 17.32607
356.4543 17.51579
356.9364 17.69196
357.4185 17.81746
357.9006 17.75290
358.3828 18.00407
358.8649 19.22588
359.3470 20.98700
359.8291 22.42229
360.3112 22.69301
360.7933 22.86951
361.2755 23.64317
361.7576 25.15390
362.2397 26.68851
362.7218 28.02805
363.2039 29.20839
363.6860 30.28542
364.1682 30.92545
364.6503 31.82836
365.1324 33.45924
365.6145 35.78501
366.0966 37.58730
366.5787 38.42897
367.0609 38.82683
367.5430 39.11224
368.0251 39.16713
368.5072 39.28651
368.9893 39.61665
369.4714 40.04593
369.9536 40.21104
370.4357 40.31776
370.9178 39.93742
371.3999 38.82779
371.8820 36.60014
372.3641 34.63608
372.8463 33.09692
373.3284 31.73701
373.8105 30.13119
374.2926 28.12521
374.7747 26.20866
375.2568 24.51838
375.7390 23.04892
376.2211 21.62718
376.7032 20.27255
377.1853 18.88802
377.6674 17.31120
378.1495 15.50826
378.6317 13.72039
379.1138 11.88191
379.5959 10.14259
380.0780 8.993324
380.5601 8.483139
381.0422 8.105133
381.5244 7.456161
382.0065 6.610725
382.4886 6.087120
382.9707 6.022644
383.4528 6.028091
383.9349 5.454048
384.4171 4.399696
384.8992 3.416351
385.3813 2.769478
385.8634 2.354576
386.3455 1.995872
386.8276 1.691254
387.3098 1.421837
387.7919 1.167656
388.2740 0.9316100
388.7561 0.7247850
389.2382 0.5901180
389.7203 0.4402010
390.2025 0.1341170
390.6846 0.2780610
391.1667 0.5652080
391.6488 0.4205860
392.1309 0.1883930
392.6130 0.1782000
393.0952 0.5482330
393.5773 0.9224550
394.0594 1.132050
394.5415 1.234756
395.0236 1.337524
395.5057 1.607948
395.9879 1.764450
396.4700 1.623039
396.9521 1.102539
397.4342 0.7333150
397.9163 0.7520290
398.3984 0.8824310
398.8806 0.8723370
399.3627 0.4584500
399.8448 0.1892930
400.3269 0.2273330
400.8090 0.5123060
401.2911 0.5640870
401.7733 0.1355900
402.2554 0.2325060
402.7375 0.2042470
403.2196 0.5280000
403.7017 0.8647460
404.1838 0.6643910
404.6660 0.1591030
405.1481 0.2117920
405.6302 0.4158100
406.1123 0.6190190
406.5944 0.9309920
407.0765 1.336235
407.5587 1.404839
408.0408 1.041634
408.5229 0.7006910
409.0050 0.9616010
409.4871 1.773720
409.9692 2.417252
410.4514 2.726685
410.9335 2.791351
411.4156 2.614258
411.8977 2.240166
412.3798 2.175331
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