#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:25:42 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1080 $ #$URL: svn://172.16.1.111/rod/cif/1/00/05/1000522.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000522 loop_ _publ_author_name 'Merlino S' 'Pasero M' 'Bellezza M' 'Pushcharovsky D Y' 'Gobetchia E R' 'Zubkova N V' 'Pekov I V' _publ_section_title ; The crystal structure of calcium catapleiite ; _journal_name_full 'The Canadian Mineralogist' _journal_page_first 1037 _journal_page_last 1045 _journal_paper_doi 10.2113/gscanmin.42.4.1037 _journal_volume 42 _journal_year 2004 _chemical_compound_source R040005 _chemical_formula_sum 'Ca H4 O11 Si3 Zr' _chemical_name_mineral Catapleiite _space_group_IT_number 52 _symmetry_space_group_name_Hall '-P 2n 2b' _symmetry_space_group_name_H-M 'P b n n' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 7.378 _cell_length_b 12.779 _cell_length_c 10.096 _cell_volume 951.886 _cod_original_formula_sum 'Ca Zr Si3 O11 H4' _cod_database_code 9004867 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R040005.rod _rod_data_source.block 3500000 _rod_database.code 1000522 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9004867 COD http://www.crystallography.net/cod/9004867.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 125.7909 0.0000000E+00 126.2731 0.8242190 126.7552 17.73438 127.2373 60.68555 127.7194 73.20898 128.2015 45.22852 128.6837 6.234375 129.1658 6.181641 129.6479 78.70703 130.1300 118.6094 130.6121 105.1270 131.0942 69.45117 131.5764 33.82617 132.0585 8.236328 132.5406 7.083984 133.0227 10.07031 133.5048 16.66016 133.9869 37.23828 134.4691 40.08594 134.9512 34.36914 135.4333 35.80273 135.9154 54.98047 136.3975 91.10352 136.8796 125.6133 137.3618 171.1836 137.8439 205.1621 138.3260 200.0723 138.8081 162.9258 139.2902 143.9512 139.7723 195.6445 140.2545 317.8926 140.7366 407.9668 141.2187 448.8164 141.7008 460.1914 142.1829 452.3359 142.6650 418.6504 143.1472 398.7500 143.6293 450.8828 144.1114 559.2227 144.5935 655.4980 145.0756 700.0723 145.5577 708.3418 146.0399 733.6484 146.5220 794.9297 147.0041 863.0156 147.4862 916.8164 147.9683 956.1191 148.4504 985.2852 148.9326 1002.027 149.4147 1004.084 149.8968 1017.824 150.3789 1068.713 150.8610 1120.127 151.3431 1149.367 151.8252 1151.783 152.3074 1143.301 152.7895 1148.795 153.2716 1176.072 153.7537 1201.021 154.2358 1226.309 154.7179 1245.908 155.2001 1254.064 155.6822 1248.271 156.1643 1231.248 156.6464 1211.178 157.1285 1176.498 157.6106 1152.160 158.0928 1150.223 158.5749 1158.145 159.0570 1157.410 159.5391 1135.996 160.0212 1096.818 160.5033 1074.059 160.9855 1088.389 161.4676 1095.602 161.9497 1079.297 162.4318 1043.719 162.9139 1002.029 163.3960 962.4805 163.8782 925.4707 164.3603 897.6270 164.8424 894.0566 165.3245 886.9336 165.8066 856.1484 166.2887 800.7051 166.7709 736.8477 167.2530 677.0410 167.7351 621.1562 168.2172 569.8262 168.6993 504.8633 169.1814 451.6953 169.6636 454.1953 170.1457 530.7676 170.6278 615.0410 171.1099 633.3379 171.5920 597.5703 172.0741 552.0078 172.5563 498.4648 173.0384 446.1797 173.5205 432.5840 174.0026 490.3047 174.4847 549.8105 174.9668 547.4727 175.4490 487.3555 175.9311 418.1777 176.4132 372.2676 176.8953 349.3340 177.3774 329.8848 177.8595 308.1113 178.3417 290.9707 178.8238 288.6953 179.3059 298.8184 179.7880 304.8809 180.2701 279.5684 180.7522 209.6875 181.2344 165.7617 181.7165 186.2031 182.1986 217.1074 182.6807 219.5879 183.1628 184.5547 183.6449 140.5176 184.1271 139.4023 184.6092 213.5898 185.0913 273.2422 185.5734 321.4727 186.0555 350.7070 186.5376 345.6445 187.0198 296.7285 187.5019 230.3105 187.9840 213.0605 188.4661 317.8203 188.9482 381.4355 189.4303 345.3633 189.9125 270.7070 190.3946 230.0781 190.8767 262.7715 191.3588 348.1719 191.8409 387.9766 192.3230 318.6094 192.8052 275.6465 193.2873 305.4492 193.7694 377.1348 194.2515 434.6523 194.7336 442.1758 195.2157 403.2168 195.6979 380.5098 196.1800 379.1992 196.6621 382.7969 197.1442 394.3652 197.6263 409.0859 198.1084 412.1504 198.5906 390.1738 199.0727 345.3418 199.5548 317.0645 200.0369 326.7070 200.5190 334.5742 201.0011 305.7168 201.4833 244.7051 201.9654 200.4492 202.4475 218.1094 202.9296 289.2617 203.4117 332.8887 203.8938 337.6777 204.3760 323.0742 204.8581 302.1914 205.3402 275.5039 205.8223 248.9902 206.3044 222.6445 206.7865 201.1367 207.2687 199.2930 207.7508 240.4375 208.2329 288.9258 208.7150 289.4707 209.1971 232.6016 209.6792 179.0020 210.1614 186.6953 210.6435 235.1660 211.1256 281.4336 211.6077 314.4180 212.0898 334.0039 212.5719 336.7812 213.0541 314.9805 213.5362 292.3066 214.0183 283.9980 214.5004 287.2227 214.9825 296.1270 215.4646 310.7500 215.9468 328.1055 216.4289 341.5898 216.9110 363.3789 217.3931 364.6582 217.8752 315.5098 218.3573 232.2461 218.8395 162.4980 219.3216 148.1133 219.8037 181.5684 220.2858 194.3281 220.7679 172.1777 221.2500 147.3652 221.7322 135.6582 222.2143 130.1504 222.6964 126.5156 223.1785 126.7871 223.6606 131.4824 224.1427 138.1191 224.6249 146.1074 225.1070 157.0684 225.5891 176.8262 226.0712 201.4727 226.5533 219.2559 227.0354 218.1133 227.5176 195.5078 227.9997 172.1719 228.4818 141.8984 228.9639 115.3008 229.4460 97.42188 229.9281 88.23047 230.4103 83.65039 230.8924 75.06641 231.3745 53.06250 231.8566 71.25977 232.3387 181.1445 232.8208 285.0332 233.3030 338.6387 233.7851 340.3184 234.2672 312.6465 234.7493 275.9512 235.2314 221.6621 235.7135 191.5527 236.1957 198.9141 236.6778 215.1934 237.1599 226.3203 237.6420 230.9707 238.1241 236.3262 238.6062 252.8203 239.0884 290.7812 239.5705 304.0840 240.0526 284.3242 240.5347 251.6270 241.0168 202.6191 241.4989 144.8965 241.9811 11.19336 242.4632 125.3125 242.9453 188.2812 243.4274 202.8711 243.9095 24.28125 244.3916 95.00586 244.8738 65.73633 245.3559 32.31641 245.8380 137.9648 246.3201 12.83203 246.8022 90.46680 247.2843 92.25000 247.7665 140.4141 248.2486 87.96680 248.7307 66.52148 249.2128 145.6055 249.6949 168.9355 250.1770 104.6816 250.6592 155.4629 251.1413 46.37891 251.6234 22.91016 252.1055 91.66211 252.5876 107.6816 253.0697 66.26172 253.5519 3.404297 254.0340 44.52734 254.5161 76.15625 254.9982 87.84375 255.4803 56.51367 255.9624 20.89062 256.4445 15.14648 256.9267 42.49609 257.4088 77.23242 257.8909 94.36719 258.3730 90.28711 258.8551 76.56836 259.3372 30.82617 259.8194 10.12109 260.3015 6.404297 260.7836 43.94727 261.2657 97.11328 261.7478 109.2246 262.2299 72.26758 262.7121 42.38281 263.1942 28.86133 263.6763 17.15430 264.1584 15.43555 264.6405 68.68164 265.1227 102.5156 265.6048 70.75000 266.0869 32.77734 266.5690 100.1699 267.0511 109.8789 267.5332 96.10156 268.0154 82.60352 268.4975 71.82227 268.9796 61.79492 269.4617 51.49609 269.9438 40.52930 270.4259 27.06055 270.9081 7.648438 271.3902 12.03320 271.8723 29.81055 272.3544 45.24414 272.8365 52.91797 273.3186 44.89062 273.8008 23.27344 274.2829 13.58594 274.7650 27.14258 275.2471 44.45703 275.7292 55.81250 276.2113 59.90430 276.6935 47.49805 277.1756 0.7011720 277.6577 73.12695 278.1398 99.56836 278.6219 12.92383 279.1040 65.98242 279.5862 32.72266 280.0683 99.73633 280.5504 222.1680 281.0325 271.9648 281.5146 253.6426 281.9967 216.2695 282.4789 128.3184 282.9610 49.81250 283.4431 26.88281 283.9252 51.20898 284.4073 74.37695 284.8894 65.61719 285.3716 40.71094 285.8537 48.05469 286.3358 107.6387 286.8179 172.5117 287.3000 224.5605 287.7821 262.5195 288.2643 275.4238 288.7464 246.0801 289.2285 198.9180 289.7106 195.0059 290.1927 249.7266 290.6748 315.6406 291.1570 387.9551 291.6391 456.7598 292.1212 484.7930 292.6033 444.8301 293.0854 373.4023 293.5675 344.6895 294.0497 363.4336 294.5318 400.4980 295.0139 453.4961 295.4960 516.1973 295.9781 575.4258 296.4602 628.0527 296.9424 673.3477 297.4245 710.4785 297.9066 743.3848 298.3887 758.9609 298.8708 737.0352 299.3529 697.7695 299.8351 673.5762 300.3172 677.2949 300.7993 700.3027 301.2814 739.8594 301.7635 795.9727 302.2456 844.8516 302.7278 884.3926 303.2099 908.9805 303.6920 904.3984 304.1741 859.5137 304.6562 816.0469 305.1383 815.0430 305.6205 859.4805 306.1026 894.1211 306.5847 904.2285 307.0668 906.4707 307.5489 918.1504 308.0310 941.1523 308.5132 963.5000 308.9953 972.5664 309.4774 965.1523 309.9595 949.7344 310.4416 924.7812 310.9237 902.6289 311.4059 894.3809 311.8880 897.4824 312.3701 896.9102 312.8522 877.2363 313.3343 841.2363 313.8164 830.9297 314.2986 872.4707 314.7807 917.6719 315.2628 938.2754 315.7449 936.3965 316.2270 925.1387 316.7091 908.2402 317.1913 889.2227 317.6734 890.3066 318.1555 953.0312 318.6376 995.3125 319.1197 963.7969 319.6018 884.9570 320.0840 823.9121 320.5661 815.5352 321.0482 840.9121 321.5303 836.6465 322.0124 773.3457 322.4945 720.4961 322.9767 699.6797 323.4588 702.3945 323.9409 718.6113 324.4230 739.3301 324.9051 755.2090 325.3872 747.3027 325.8694 694.5273 326.3515 655.3418 326.8336 635.8867 327.3157 631.1484 327.7978 641.5859 328.2799 666.0605 328.7621 690.8281 329.2442 697.2969 329.7263 678.6270 330.2084 656.2090 330.6905 619.6367 331.1726 588.5469 331.6548 577.5684 332.1369 587.0918 332.6190 609.1680 333.1011 640.4531 333.5832 688.1543 334.0653 703.8730 334.5475 658.9492 335.0296 619.1895 335.5117 624.7891 335.9938 661.9922 336.4759 685.4922 336.9580 656.6680 337.4402 583.8828 337.9223 544.6699 338.4044 553.9648 338.8865 571.9316 339.3686 600.2129 339.8507 628.8027 340.3329 638.9492 340.8150 618.0957 341.2971 577.4590 341.7792 566.3027 342.2613 643.0117 342.7434 674.2129 343.2256 609.2617 343.7077 507.9902 344.1898 430.7637 344.6719 401.4961 345.1540 409.5703 345.6361 440.8379 346.1183 529.2305 346.6004 572.4492 347.0825 535.9824 347.5646 478.9004 348.0467 441.6836 348.5288 433.2793 349.0110 437.3652 349.4931 436.6738 349.9752 433.3438 350.4573 416.3477 350.9394 354.4961 351.4215 304.4395 351.9037 311.2988 352.3858 361.0195 352.8679 393.3984 353.3500 333.7637 353.8321 187.2734 354.3142 135.5000 354.7964 267.4180 355.2785 390.1582 355.7606 425.0000 356.2427 395.5117 356.7248 350.0586 357.2069 307.9961 357.6891 273.7207 358.1712 263.7871 358.6533 290.3730 359.1354 313.8145 359.6175 321.3750 360.0996 316.3008 360.5818 299.3184 361.0639 267.7832 361.5460 231.5703 362.0281 200.6230 362.5102 173.7812 362.9923 162.1777 363.4745 183.0254 363.9566 212.2676 364.4387 224.7383 364.9208 216.0742 365.4029 205.5352 365.8850 198.0977 366.3672 197.6953 366.8493 234.7305 367.3314 345.0820 367.8135 450.2891 368.2956 459.2852 368.7777 380.0215 369.2599 302.2324 369.7420 253.7422 370.2241 232.6562 370.7062 247.5430 371.1883 306.6777 371.6704 358.9746 372.1526 350.8789 372.6347 293.9121 373.1168 255.8516 373.5989 259.0703 374.0810 273.5996 374.5631 278.0566 375.0453 271.8750 375.5274 257.3750 376.0095 233.2461 376.4916 202.4258 376.9737 177.7734 377.4558 149.5840 377.9380 137.1348 378.4201 165.5039 378.9022 212.7559 379.3843 232.9746 379.8664 206.0547 380.3485 153.8145 380.8307 121.0918 381.3128 112.4727 381.7949 115.3477 382.2770 142.1445 382.7591 172.8887 383.2412 191.6973 383.7234 194.5020 384.2055 179.8594 384.6876 142.1367 385.1697 68.70703 385.6518 28.10156 386.1339 42.55469 386.6161 63.08789 387.0982 64.12891 387.5803 49.89844 388.0624 38.28906 388.5445 42.32617 389.0266 60.87305 389.5088 81.72656 389.9909 125.6875 390.4730 146.6543 390.9551 127.7148 391.4372 84.52148 391.9193 29.25977 392.4015 33.83789 392.8836 88.36133 393.3657 94.75781 393.8478 26.62500 394.3299 24.83789 394.8120 35.14844 395.2942 34.06250 395.7763 44.07031 396.2584 67.34570 396.7405 85.15820 397.2226 71.39844 397.7047 25.80859 398.1869 0.8164060 398.6690 14.41602 399.1511 32.44531 399.6332 33.40625 400.1153 22.51758 400.5974 15.67969 401.0796 26.16992 401.5617 45.12305 402.0438 47.80664 402.5259 27.16602 403.0080 19.08398 403.4901 62.85742 403.9723 126.2812 404.4544 158.5723 404.9365 139.4316 405.4186 107.0254 405.9007 89.60938 406.3828 85.51953 406.8650 86.53906 407.3471 90.58398 407.8292 97.30469 408.3113 104.5078 408.7934 109.5938 409.2755 124.6074 409.7577 161.2500 410.2398 206.6387 410.7219 246.9551 411.2040 279.5586 411.6861 297.7871 412.1682 292.3242 412.6504 259.3496 413.1325 230.1992 413.6146 194.2734 414.0967 171.4082 414.5788 170.6367 415.0609 192.1738 415.5431 240.7266 416.0252 325.0352 416.5073 429.3906 416.9894 480.0410 417.4715 386.1777 417.9536 348.5098 418.4358 448.0195 418.9179 584.8535 419.4000 640.0430 419.8821 583.7559 420.3642 492.0039 420.8463 482.5879 421.3285 594.3379 421.8106 684.8301 422.2927 753.7891 422.7748 805.4980 423.2569 830.8457 423.7390 835.7520 424.2212 853.2891 424.7033 912.6992 425.1854 1002.865 425.6675 1075.795 426.1496 1114.988 426.6317 1152.643 427.1139 1195.135 427.5960 1244.918 428.0781 1306.342 428.5602 1383.420 429.0423 1461.543 429.5244 1516.125 430.0066 1546.234 430.4887 1590.678 430.9708 1671.404 431.4529 1756.910 431.9350 1804.818 432.4171 1812.336 432.8993 1836.953 433.3814 1931.365 433.8635 2054.229 434.3456 2124.768 434.8277 2126.426 435.3098 2126.967 435.7920 2189.613 436.2741 2310.617 436.7562 2414.748 437.2383 2480.848 437.7204 2544.324 438.2025 2638.188 438.6847 2747.225 439.1668 2826.357 439.6489 2853.521 440.1310 2845.166 440.6131 2843.926 441.0952 2862.609 441.5774 2874.570 442.0595 2880.377 442.5416 2873.531 443.0237 2847.502 443.5058 2803.465 443.9879 2746.000 444.4701 2675.639 444.9522 2588.969 445.4343 2514.561 445.9164 2464.947 446.3985 2416.787 446.8806 2369.484 447.3628 2316.195 447.8449 2247.090 448.3270 2157.824 448.8091 2055.555 449.2912 1953.383 449.7733 1846.689 450.2555 1753.695 450.7376 1692.094 451.2197 1637.855 451.7018 1570.258 452.1839 1485.355 452.6660 1405.047 453.1482 1354.309 453.6303 1325.346 454.1124 1281.279 454.5945 1213.434 455.0766 1139.123 455.5587 1068.367 456.0409 1001.855 456.5230 945.4844 457.0051 911.1465 457.4872 878.8477 457.9693 830.0527 458.4514 766.4727 458.9336 696.3809 459.4156 617.4434 459.8978 542.3086 460.3799 510.4199 460.8620 546.5176 461.3441 570.9590 461.8262 560.4688 462.3083 536.5684 462.7905 525.6348 463.2726 530.6445 463.7547 402.7773 464.2368 495.2539 464.7189 536.6367 465.2010 529.6914 465.6832 329.6133 466.1653 378.9258 466.6474 328.3027 467.1295 273.5918 467.6116 358.0137 468.0938 186.0410 468.5759 268.2676 469.0580 249.0215 469.5401 276.2246 470.0222 202.8711 470.5043 160.5801 470.9865 218.8730 471.4686 157.3867 471.9507 179.2539 472.4328 202.4629 472.9149 202.3711 473.3970 186.4902 473.8792 185.2949 474.3613 206.8594 474.8434 222.9824 475.3255 218.9805 475.8076 195.6387 476.2897 150.0488 476.7719 57.39062 477.2540 26.34961 477.7361 58.73633 478.2182 50.53906 478.7003 66.89453 479.1824 25.04102 479.6646 0.2343750 480.1467 8.451172 480.6288 47.24805 481.1109 19.84961 481.5930 25.77734 482.0751 33.09961 482.5573 5.933594 483.0394 40.51172 483.5215 2.246094 484.0036 2.179688 484.4857 22.06836 484.9678 8.437500 485.4500 5.164063 485.9321 35.39844 486.4142 47.07422 486.8963 29.56641 487.3784 50.42773 487.8605 2.738281 488.3427 15.18945 488.8248 53.58789 489.3069 37.75977 489.7890 59.22461 490.2711 66.48633 490.7532 9.199219 491.2354 64.14648 491.7175 70.56055 492.1996 27.11914 492.6817 24.55078 493.1638 8.548828 493.6459 36.95508 494.1281 60.23828 494.6102 71.83398 495.0923 68.37109 495.5744 52.93555 496.0565 26.22070 496.5386 17.70703 497.0208 45.87500 497.5029 46.87305 497.9850 30.62891 498.4671 4.693359 498.9492 53.18945 499.4313 84.24805 499.9135 69.74609 500.3956 14.24219 500.8777 22.10938 501.3598 24.95312 501.8419 25.67969 502.3240 32.95117 502.8062 39.00000 503.2883 29.46484 503.7704 1.923828 504.2525 23.45312 504.7346 16.28516 505.2167 29.61914 505.6989 64.56836 506.1810 81.94336 506.6631 94.00000 507.1452 102.5859 507.6273 110.8457 508.1094 125.8477 508.5916 154.2539 509.0737 186.2383 509.5558 213.7480 510.0379 236.1602 510.5200 234.4668 511.0021 189.3672 511.4843 131.8711 511.9664 110.8262 512.4485 128.9473 512.9306 150.4785 513.4127 161.6094 513.8948 174.9609 514.3770 213.0176 514.8591 271.1641 515.3412 311.0117 515.8233 301.6055 516.3054 253.5410 516.7875 235.2734 517.2697 267.8672 517.7518 305.4590 518.2339 362.2598 518.7160 411.7871 519.1981 420.0859 519.6802 384.8828 520.1624 343.7715 520.6445 344.7559 521.1266 389.6230 521.6087 400.7812 522.0908 350.1836 522.5729 307.2402 523.0551 312.5449 523.5372 341.7910 524.0193 354.4766 524.5014 330.6816 524.9835 305.2461 525.4656 319.8125 525.9478 365.8496 526.4299 398.0957 526.9120 403.3418 527.3941 395.8906 527.8762 388.3984 528.3583 380.4141 528.8405 382.8066 529.3226 411.6641 529.8047 437.8145 530.2868 432.9160 530.7689 408.8203 531.2510 403.9941 531.7332 440.0488 532.2153 493.4277 532.6974 502.5176 533.1795 417.9375 533.6616 379.9512 534.1437 433.1348 534.6259 492.4414 535.1080 506.1211 535.5901 474.9434 536.0722 423.1445 536.5543 353.8008 537.0364 283.7891 537.5186 260.3184 538.0007 293.3242 538.4828 327.7891 538.9649 360.6641 539.4470 380.3906 539.9291 368.9004 540.4113 321.7695 540.8934 282.4258 541.3755 287.7969 541.8576 315.3027 542.3397 336.2812 542.8218 346.0117 543.3040 346.5020 543.7861 337.8086 544.2682 321.0488 544.7503 311.4316 545.2324 310.8613 545.7145 313.2480 546.1967 322.8848 546.6788 335.3008 547.1609 346.7090 547.6430 356.5098 548.1251 362.6914 548.6072 363.3105 549.0894 360.3770 549.5715 342.0449 550.0536 284.6777 550.5357 246.3809 551.0178 251.9727 551.4999 283.3164 551.9821 320.6094 552.4642 363.2012 552.9463 394.4121 553.4284 385.4922 553.9105 350.1641 554.3926 346.5547 554.8748 390.0859 555.3569 439.0703 555.8390 446.5820 556.3211 413.4902 556.8032 419.6309 557.2853 512.2344 557.7675 600.9375 558.2496 628.9727 558.7317 627.9082 559.2138 661.3008 559.6959 751.2207 560.1780 854.1875 560.6602 898.5234 561.1423 861.7988 561.6244 854.0762 562.1065 883.2617 562.5886 937.3340 563.0707 1027.703 563.5529 1137.561 564.0350 1242.316 564.5171 1331.105 564.9992 1411.293 565.4813 1488.268 565.9634 1562.830 566.4456 1648.867 566.9277 1752.375 567.4098 1863.867 567.8919 1979.430 568.3740 2097.584 568.8561 2200.123 569.3383 2268.826 569.8204 2335.748 570.3025 2421.994 570.7846 2523.520 571.2667 2630.916 571.7488 2740.285 572.2310 2846.928 572.7131 2939.363 573.1952 3009.521 573.6773 3088.164 574.1594 3180.189 574.6415 3275.246 575.1237 3383.201 575.6058 3489.326 576.0879 3564.756 576.5700 3592.500 577.0521 3591.246 577.5342 3592.396 578.0164 3596.123 578.4985 3571.701 578.9806 3500.246 579.4627 3416.475 579.9448 3363.270 580.4269 3335.926 580.9091 3287.051 581.3912 3195.773 581.8733 3090.945 582.3554 3004.252 582.8375 2919.527 583.3196 2781.777 583.8018 2566.793 584.2839 2327.504 584.7660 2159.828 585.2481 2097.510 585.7302 2012.727 586.2123 1886.123 586.6945 1757.293 587.1766 1639.502 587.6587 1531.717 588.1408 1431.309 588.6229 1340.270 589.1050 1245.619 589.5872 1117.910 590.0693 958.6230 590.5514 833.5918 591.0335 768.4863 591.5156 717.8867 591.9977 624.8184 592.4799 498.1191 592.9620 412.7695 593.4441 411.4395 593.9262 422.2012 594.4083 403.6582 594.8904 366.5430 595.3726 332.6992 595.8547 310.0488 596.3368 298.2656 596.8189 301.3574 597.3010 328.4922 597.7831 326.3828 598.2653 279.7734 598.7474 217.8203 599.2295 126.7695 599.7116 33.02539 600.1937 22.65234 600.6758 21.91992 601.1580 2.048828 601.6401 24.87109 602.1222 43.30469 602.6043 34.98633 603.0864 11.18164 603.5685 54.88281 604.0507 58.38867 604.5328 24.62500 605.0149 1.925781 605.4970 3.880859 605.9791 5.871094 606.4612 3.306641 606.9434 1.224609 607.4255 7.759766 607.9076 23.76172 608.3897 40.51562 608.8718 47.18945 609.3539 44.19141 609.8361 52.58789 610.3182 79.04883 610.8003 106.0684 611.2824 133.7324 611.7645 155.8008 612.2466 161.6152 612.7288 148.5254 613.2109 140.4043 613.6930 151.9141 614.1751 179.3145 614.6572 218.2734 615.1393 268.1953 615.6215 323.1973 616.1036 382.9199 616.5857 442.9238 617.0678 487.8945 617.5499 489.3555 618.0320 515.4492 618.5142 591.2441 618.9963 675.6270 619.4784 723.7012 619.9605 747.5625 620.4426 805.7773 620.9247 952.0918 621.4069 1140.518 621.8890 1234.910 622.3711 1213.963 622.8532 1225.033 623.3353 1316.812 623.8174 1445.723 624.2996 1566.539 624.7817 1680.375 625.2638 1807.768 625.7459 1973.170 626.2280 2137.732 626.7101 2264.943 627.1923 2369.455 627.6744 2477.703 628.1565 2598.621 628.6386 2744.738 629.1207 2940.564 629.6028 3214.266 630.0850 3421.918 630.5671 3487.463 631.0492 3563.234 631.5313 3686.838 632.0134 3854.330 632.4955 4086.232 632.9777 4411.482 633.4598 4664.193 633.9419 4619.432 634.4240 4366.387 634.9061 4214.295 635.3882 4217.500 635.8704 4241.293 636.3525 4192.268 636.8346 4077.688 637.3167 3944.199 637.7988 3801.396 638.2809 3634.145 638.7631 3426.299 639.2452 3202.051 639.7273 2985.561 640.2094 2777.939 640.6915 2564.072 641.1736 2330.252 641.6558 2090.141 642.1379 1897.727 642.6200 1763.066 643.1021 1632.318 643.5842 1490.592 644.0663 1348.781 644.5485 1212.672 645.0306 1080.379 645.5127 968.8027 645.9948 890.1738 646.4769 832.9004 646.9590 805.1113 647.4412 790.1855 647.9233 742.9336 648.4054 645.8086 648.8875 533.9863 649.3696 462.4609 649.8517 442.4648 650.3339 409.0195 650.8160 334.3379 651.2981 279.0391 651.7802 287.5879 652.2623 317.4023 652.7444 300.6113 653.2266 213.0781 653.7087 129.1934 654.1908 115.6113 654.6729 139.5820 655.1550 144.1406 655.6371 124.4941 656.1193 96.31641 656.6014 66.06641 657.0835 37.82227 657.5656 28.34180 658.0477 62.70898 658.5298 81.66992 659.0120 78.37891 659.4941 65.38867 659.9762 48.70898 660.4583 29.81445 660.9404 7.541016 661.4225 24.14453 661.9047 49.75977 662.3868 33.37695 662.8689 22.56445 663.3510 56.11719 663.8331 48.32812 664.3152 27.39453 664.7974 16.87695 665.2795 17.08008 665.7616 24.39062 666.2437 55.48438 666.7258 73.94531 667.2079 56.44922 667.6901 23.97461 668.1722 0.5585940 668.6543 10.95117 669.1364 8.980469 669.6185 6.488281 670.1006 32.76953 670.5828 53.07227 671.0649 66.66992 671.5470 76.48633 672.0291 80.55273 672.5112 83.37500 672.9933 89.41602 673.4755 98.68555 673.9576 111.3086 674.4397 140.1934 674.9218 161.1855 675.4039 143.0273 675.8860 102.6895 676.3682 83.69531 676.8503 102.8164 677.3324 136.6211 677.8145 151.3652 678.2966 145.1074 678.7787 135.7891 679.2609 121.1074 679.7430 107.2148 680.2251 94.44922 680.7072 84.83398 681.1893 82.22266 681.6714 88.10352 682.1536 94.62891 682.6357 108.8223 683.1178 115.0039 683.5999 76.97070 684.0820 3.359375 684.5641 44.62305 685.0463 31.75000 685.5284 16.93555 686.0105 42.24219 686.4926 28.69531 686.9747 28.27148 687.4568 60.50977 687.9390 85.98633 688.4211 81.55664 688.9032 60.08789 689.3853 46.47461 689.8674 49.14453 690.3495 58.23242 690.8317 76.87500 691.3138 93.41992 691.7959 72.00000 692.2780 10.02344 692.7601 44.15430 693.2422 56.17773 693.7244 34.22656 694.2065 8.781250 694.6886 29.00781 695.1707 55.59766 695.6528 77.66016 696.1349 82.81641 696.6171 45.22461 697.0992 15.30469 697.5813 45.09375 698.0634 9.476563 698.5455 42.81445 699.0276 54.72656 699.5098 35.96680 699.9919 23.07422 700.4740 23.77930 700.9561 18.36523 701.4382 15.42383 701.9203 70.14062 702.4025 86.56641 702.8846 27.81055 703.3667 21.05078 703.8488 57.35352 704.3309 79.18750 704.8130 78.96289 705.2952 62.19727 705.7773 47.65430 706.2594 48.68945 706.7415 52.94531 707.2236 37.44727 707.7057 6.888672 708.1879 8.851563 708.6700 2.255859 709.1521 16.56641 709.6342 44.26758 710.1163 79.21094 710.5984 81.66113 711.0806 0.9531250 711.5627 45.06250 712.0448 0.7216800 712.5269 68.27832 713.0090 96.71680 713.4911 86.42090 713.9733 78.64941 714.4554 104.2881 714.9375 141.5088 715.4196 154.9346 715.9017 146.6973 716.3839 129.4727 716.8660 102.9199 717.3481 86.03711 717.8302 101.5938 718.3123 149.7686 718.7944 182.9062 719.2766 188.4609 719.7587 193.4082 720.2408 208.0771 720.7229 225.5840 721.2050 243.2119 721.6871 256.5762 722.1693 249.5508 722.6514 197.1133 723.1335 133.6025 723.6156 124.6299 724.0977 161.8066 724.5798 180.4707 725.0620 160.9414 725.5441 132.6426 726.0262 122.6553 726.5083 130.6592 726.9904 156.1641 727.4725 221.3096 727.9547 275.3809 728.4368 315.0186 728.9189 336.8857 729.4010 327.1562 729.8831 293.2637 730.3652 269.9971 730.8474 285.3174 731.3295 315.2383 731.8116 319.4209 732.2937 305.1914 732.7758 280.0537 733.2579 321.7139 733.7401 346.3486 734.2222 354.9170 734.7043 299.1572 735.1864 326.3711 735.6685 320.2422 736.1506 312.7324 736.6328 351.7480 737.1149 305.3818 737.5970 343.6680 738.0791 348.0527 738.5612 367.8594 739.0433 354.1094 739.5255 336.2031 740.0076 347.5283 740.4897 375.3740 740.9718 402.7715 741.4539 425.7871 741.9360 445.0107 742.4182 461.1895 742.9003 475.9268 743.3824 470.6533 743.8645 424.1855 744.3466 387.5703 744.8287 372.7568 745.3109 364.7471 745.7930 353.9766 746.2751 341.0674 746.7572 331.2793 747.2393 325.7256 747.7214 325.5146 748.2036 333.4502 748.6857 347.1328 749.1678 369.1602 749.6499 396.7812 750.1320 401.6260 750.6141 354.9023 751.0963 275.9766 751.5784 240.1680 752.0605 261.3027 752.5426 289.4072 753.0247 332.7949 753.5068 363.6562 753.9890 359.7344 754.4711 330.2754 754.9532 298.7422 755.4353 262.2100 755.9174 244.4170 756.3995 276.7949 756.8817 318.5381 757.3638 310.6426 757.8459 260.0928 758.3280 227.8232 758.8101 256.7422 759.2922 312.9268 759.7744 324.3408 760.2565 289.7275 760.7386 250.7568 761.2207 200.4023 761.7028 161.3604 762.1849 152.5205 762.6671 165.5645 763.1492 180.0312 763.6313 201.0088 764.1134 208.5811 764.5955 175.2197 765.0776 147.8252 765.5598 178.2432 766.0419 239.3838 766.5240 270.8887 767.0061 246.9023 767.4882 203.3320 767.9703 190.1787 768.4525 199.8662 768.9346 180.9365 769.4167 122.8838 769.8988 77.59668 770.3809 68.53320 770.8630 81.08301 771.3452 90.19727 771.8273 96.07617 772.3094 98.45703 772.7915 85.41309 773.2736 81.75195 773.7557 119.1660 774.2379 162.1660 774.7200 152.6621 775.2021 80.03418 775.6842 15.16992 776.1663 24.31836 776.6484 66.82520 777.1306 74.68066 777.6127 54.11328 778.0948 46.57715 778.5769 67.34668 779.0590 97.35059 779.5411 113.8760 780.0233 116.8818 780.5054 112.8340 780.9875 87.49609 781.4696 77.26562 781.9517 111.4307 782.4338 148.5947 782.9160 149.5215 783.3981 117.5430 783.8802 95.42383 784.3623 110.9570 784.8444 127.6973 785.3265 118.8877 785.8087 95.70898 786.2908 73.36523 786.7729 55.79590 787.2550 42.35938 787.7371 31.64453 788.2192 26.37402 788.7014 36.20703 789.1835 62.20703 789.6656 95.91602 790.1477 147.1465 790.6298 185.7705 791.1119 168.7910 791.5941 110.7461 792.0762 92.29688 792.5583 159.8164 793.0404 193.3760 793.5225 142.8574 794.0046 81.39746 794.4868 59.69531 794.9689 69.90234 795.4510 84.37891 795.9331 92.63574 796.4152 95.43164 796.8973 94.05762 797.3795 87.79199 797.8616 70.32617 798.3437 42.48047 798.8258 23.42188 799.3079 22.92188 799.7900 37.95117 800.2722 58.58887 800.7543 90.63965 801.2364 104.5342 801.7185 90.52832 802.2006 71.15430 802.6827 46.60059 803.1649 24.78516 803.6470 15.44727 804.1291 19.43359 804.6112 28.11816 805.0933 41.32910 805.5754 54.68750 806.0576 71.65820 806.5397 84.06738 807.0218 69.49219 807.5039 28.21777 807.9860 1.977539 808.4681 16.48242 808.9503 67.69336 809.4324 105.7344 809.9145 130.2080 810.3966 128.6289 810.8787 89.77246 811.3608 54.82812 811.8430 61.95020 812.3251 104.6436 812.8072 135.7041 813.2893 176.8867 813.7714 178.7178 814.2535 87.05957 814.7357 1.572266 815.2178 16.16309 815.6999 22.31348 816.1820 55.72266 816.6641 63.38672 817.1462 65.09082 817.6284 75.81445 818.1105 92.26270 818.5926 114.7725 819.0747 138.2695 819.5568 135.5850 820.0389 92.52246 820.5211 43.02734 821.0032 50.71191 821.4853 121.8672 821.9674 132.6143 822.4495 51.54297 822.9316 7.444336 823.4138 15.25195 823.8959 68.50391 824.3780 88.13867 824.8601 74.62402 825.3422 57.29004 825.8243 15.83496 826.3065 1.050781 826.7886 51.79395 827.2707 121.9121 827.7528 153.0361 828.2349 141.6855 828.7170 116.3594 829.1992 87.05762 829.6813 66.76758 830.1633 79.90820 830.6454 116.0957 831.1276 136.3887 831.6097 135.4492 832.0918 136.2422 832.5739 156.7695 833.0560 183.9951 833.5381 179.0332 834.0203 129.4199 834.5024 92.79980 834.9845 70.90332 835.4666 61.24707 835.9487 75.56641 836.4308 96.40527 836.9130 92.68164 837.3951 54.39941 837.8772 37.01172 838.3593 77.27539 838.8414 118.2646 839.3235 125.6260 839.8057 111.5146 840.2878 93.72656 840.7699 77.43164 841.2520 61.27734 841.7341 38.35352 842.2162 19.66699 842.6984 34.16211 843.1805 73.66309 843.6626 93.55957 844.1447 82.99805 844.6268 66.41895 845.1089 64.17480 845.5911 73.09766 846.0732 80.63770 846.5553 94.76074 847.0374 84.49316 847.5195 14.22363 848.0016 41.18066 848.4838 28.04590 848.9659 26.45410 849.4480 74.04492 849.9301 116.2852 850.4122 134.8564 850.8943 104.4131 851.3765 68.17676 851.8586 53.41797 852.3407 54.66797 852.8228 61.24512 853.3049 69.50195 853.7870 77.71289 854.2692 84.37402 854.7513 89.98730 855.2334 101.9932 855.7155 115.4844 856.1976 96.31836 856.6797 34.70117 857.1619 14.00293 857.6440 5.769531 858.1261 78.11133 858.6082 115.6650 859.0903 106.3271 859.5724 101.9805 860.0546 119.6729 860.5367 128.7314 861.0188 94.09766 861.5009 38.25586 861.9830 18.87305 862.4651 59.38574 862.9473 82.27930 863.4294 59.97461 863.9115 29.57422 864.3936 10.42676 864.8757 0.7939450 865.3578 12.14160 865.8400 25.87891 866.3221 35.80371 866.8042 45.09277 867.2863 44.01465 867.7684 4.072266 868.2505 57.45312 868.7327 87.22559 869.2148 73.09668 869.6969 39.59082 870.1790 4.427734 870.6611 28.19043 871.1432 41.05664 871.6254 31.70898 872.1075 23.23340 872.5896 21.10352 873.0717 17.83789 873.5538 2.387695 874.0359 17.13281 874.5181 20.57617 875.0002 2.879883 875.4823 18.70508 875.9644 23.61133 876.4465 24.29785 876.9286 21.68262 877.4108 17.38574 877.8929 13.85156 878.3750 11.52051 878.8571 6.193359 879.3392 15.26367 879.8214 29.47461 880.3035 3.720703 880.7856 37.81445 881.2677 46.09180 881.7498 18.80664 882.2319 9.442383 882.7141 15.29297 883.1962 9.352539 883.6783 6.917969 884.1604 8.604492 884.6425 27.31250 885.1246 64.65723 885.6068 79.29980 886.0889 43.09863 886.5710 11.79590 887.0531 23.01758 887.5352 19.15625 888.0173 50.58496 888.4995 74.30762 888.9816 82.05957 889.4637 50.70020 889.9458 17.80859 890.4279 22.09570 890.9100 61.49219 891.3922 104.2100 891.8743 175.4707 892.3564 210.9971 892.8385 150.3867 893.3206 78.40039 893.8027 73.50195 894.2849 122.6553 894.7670 169.2686 895.2491 189.0811 895.7312 208.5986 896.2133 263.0439 896.6954 325.1504 897.1776 346.4883 897.6597 336.0586 898.1418 334.0068 898.6239 354.5137 899.1060 382.7021 899.5881 399.0254 900.0703 409.9189 900.5524 452.8574 901.0345 529.6562 901.5166 592.1943 901.9987 625.6699 902.4808 658.6172 902.9630 715.7334 903.4451 790.6494 903.9272 857.2812 904.4093 918.6016 904.8914 966.1055 905.3735 984.7129 905.8557 1002.894 906.3378 1042.938 906.8199 1094.249 907.3020 1134.697 907.7841 1161.104 908.2662 1191.463 908.7484 1219.860 909.2305 1265.063 909.7126 1345.558 910.1947 1442.119 910.6768 1540.033 911.1589 1632.650 911.6411 1707.257 912.1232 1755.234 912.6053 1787.221 913.0874 1801.676 913.5695 1812.619 914.0516 1844.711 914.5338 1898.343 915.0159 1963.805 915.4980 2040.910 915.9801 2119.533 916.4622 2184.146 916.9443 2237.180 917.4265 2293.303 917.9086 2352.246 918.3907 2418.590 918.8728 2495.197 919.3549 2574.795 919.8370 2648.524 920.3192 2719.857 920.8013 2808.024 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