#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 11:29:10 +0300 (Thu, 07 Jun 2018) $
#$Revision: 1136 $
#$URL: svn://172.16.1.111/rod/cif/1/00/05/1000559.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000559
loop_
_publ_author_name
'Mereiter, K.'
_publ_section_title
;
 Chenite, Pb4Cu(SO4)2(OH)6, from Susanna mine, Leadhills, Scotland. Note:
 Crystal is from the Paar et al (1986) mineral description paper Locality:
 Susanna mine, Leadhills, Scotland
;
_journal_name_full               'Private communication'
_journal_page_first              1
_journal_page_last               1
_journal_volume                  1
_journal_year                    2009
_chemical_compound_source        R130278
_chemical_formula_structural     Pb4Cu(SO4)2(OH)6
_chemical_formula_sum            'Cu H6 O14 Pb4 S2'
_chemical_name_mineral           Chenite
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                111.994
_cell_angle_beta                 97.765
_cell_angle_gamma                100.426
_cell_length_a                   5.7960
_cell_length_b                   7.9471
_cell_length_c                   7.9836
_cell_volume                     326.939
_exptl_crystal_density_diffrn    6.026
_cod_original_formula_sum        'Pb4 Cu S2 O14 H6'
_cod_database_code               9014000
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 780
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 12
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R130278.rod
_rod_data_source.block           3500000
_rod_database.code               1000559
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9014000 COD http://www.crystallography.net/cod/9014000.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
172.6772 0.0000000E+00
173.1594 7.4419999E-03
173.6415 0.1053370
174.1236 0.3473210
174.6057 0.6994510
175.0878 0.8758750
175.5699 0.6962620
176.0521 0.6134090
176.5342 0.6444870
177.0163 0.7801570
177.4984 0.8168010
177.9805 0.6179520
178.4626 0.3138350
178.9448 0.3362940
179.4269 0.4353870
179.9090 0.5113930
180.3911 0.4717040
180.8732 0.3444400
181.3553 0.2323360
181.8375 0.2313020
182.3196 0.3622760
182.8017 0.3899060
183.2838 0.2457940
183.7659 8.4201999E-02
184.2480 6.2328000E-02
184.7301 0.1709290
185.2123 0.1753220
185.6944 1.8841000E-02
186.1765 0.4531880
186.6586 0.6777230
187.1407 0.5387610
187.6228 0.3075700
188.1050 0.1741810
188.5871 0.1599310
189.0692 0.1870980
189.5513 0.1879060
190.0334 0.1625790
190.5155 0.1382100
190.9977 9.5123000E-02
191.4798 6.4727999E-02
191.9619 8.8859998E-02
192.4440 0.1781180
192.9261 0.2918380
193.4082 0.4104840
193.8904 0.5282040
194.3725 0.6144980
194.8546 0.6138380
195.3367 0.5830570
195.8188 0.6618730
196.3009 0.9277520
196.7831 1.153921
197.2652 1.087631
197.7473 0.8397270
198.2294 0.7001900
198.7115 0.8527430
199.1936 1.245687
199.6758 1.675711
200.1579 2.248346
200.6400 2.690660
201.1221 2.832859
201.6042 2.745083
202.0863 2.597441
202.5685 2.480373
203.0506 2.395027
203.5327 2.369169
204.0148 2.415529
204.4969 2.518503
204.9790 2.716208
205.4612 2.968685
205.9433 3.186024
206.4254 3.270620
206.9075 3.209879
207.3896 3.262907
207.8717 3.569693
208.3539 3.868713
208.8360 4.101049
209.3181 4.256973
209.8002 4.341293
210.2823 4.353468
210.7644 4.288017
211.2466 4.197842
211.7287 3.985228
212.2108 3.839579
212.6929 3.900116
213.1750 4.114357
213.6571 4.306883
214.1393 4.311026
214.6214 4.093044
215.1035 3.913843
215.5856 3.762091
216.0677 3.647943
216.5498 3.597061
217.0320 3.596655
217.5141 3.595789
217.9962 3.546206
218.4783 3.439882
218.9604 3.353411
219.4425 3.288109
219.9247 3.238127
220.4068 3.178928
220.8889 3.119011
221.3710 3.119507
221.8531 3.252361
222.3352 3.527391
222.8174 3.724150
223.2995 3.852053
223.7816 3.897827
224.2637 3.803804
224.7458 3.577604
225.2279 3.383455
225.7100 3.301249
226.1922 3.321796
226.6743 3.438744
227.1564 3.819458
227.6385 4.196606
228.1206 4.276875
228.6027 4.036371
229.0849 3.761866
229.5670 3.620256
230.0491 3.615353
230.5312 3.755274
231.0133 4.224514
231.4954 4.734173
231.9776 4.884449
232.4597 4.616903
232.9418 4.400513
233.4239 4.620218
233.9060 5.071747
234.3881 5.463196
234.8703 5.744289
235.3524 5.914852
235.8345 5.921717
236.3166 5.705044
236.7987 5.568817
237.2808 5.762766
237.7630 6.102304
238.2451 6.412802
238.7272 6.673325
239.2093 6.833046
239.6914 6.753229
240.1735 6.325874
240.6557 6.009325
241.1378 6.086008
241.6199 6.308084
242.1020 6.460938
242.5841 6.481485
243.0662 6.389547
243.5484 6.188663
244.0305 5.801455
244.5126 5.480799
244.9947 5.348440
245.4768 5.281157
245.9589 5.184986
246.4410 5.028900
246.9232 4.824398
247.4053 4.583780
247.8874 4.296896
248.3695 3.998631
248.8516 3.594614
249.3337 3.236593
249.8159 3.099041
250.2980 3.225502
250.7801 3.421761
251.2622 3.324371
251.7443 2.713923
252.2264 2.312349
252.7086 2.291342
253.1907 2.395897
253.6728 2.455597
254.1549 2.424757
254.6370 2.358883
255.1191 2.343903
255.6013 2.408558
256.0834 2.464617
256.5655 2.582657
257.0476 2.644247
257.5297 2.526794
258.0118 2.230967
258.4940 1.898577
258.9761 1.743410
259.4582 1.922644
259.9403 1.870272
260.4224 1.310942
260.9045 0.7789650
261.3867 0.6486260
261.8688 0.9291900
262.3509 1.347275
262.8330 1.599798
263.3151 1.659496
263.7972 1.630972
264.2794 1.406069
264.7615 1.200718
265.2436 1.155577
265.7257 1.259386
266.2078 1.401213
266.6899 1.479008
267.1721 1.490345
267.6542 1.436678
268.1363 1.282278
268.6184 1.110111
269.1005 0.9382840
269.5826 0.7805020
270.0648 0.6623460
270.5469 0.6062850
271.0290 0.6143650
271.5111 0.6465280
271.9932 0.7792700
272.4753 0.8571990
272.9575 0.7853470
273.4396 0.5993560
273.9217 0.3955480
274.4038 0.2313310
274.8859 0.1079520
275.3680 5.1573001E-02
275.8501 0.1731820
276.3322 0.2269760
276.8144 4.9993999E-02
277.2965 0.2597030
277.7786 0.4770620
278.2607 0.4723700
278.7428 0.2946430
279.2249 0.1482030
279.7071 1.2135000E-02
280.1892 7.7725999E-02
280.6713 8.8826999E-02
281.1534 5.0292999E-02
281.6355 1.3054000E-02
282.1176 7.2100002E-04
282.5998 2.0500000E-03
283.0819 2.5263000E-02
283.5640 0.1271020
284.0461 0.1457350
284.5282 4.0789001E-02
285.0103 0.3074510
285.4925 0.4699170
285.9746 0.4654710
286.4567 0.3541320
286.9388 0.2028500
287.4209 4.7954999E-02
287.9030 0.1390600
288.3852 0.1229320
288.8673 0.5064370
289.3494 0.7220030
289.8315 0.7012160
290.3136 0.5760030
290.7957 0.4769400
291.2779 0.3968080
291.7600 0.4223650
292.2421 0.6819210
292.7242 0.9837930
293.2063 1.126243
293.6884 1.085516
294.1706 0.9958670
294.6527 0.9790620
295.1348 1.036520
295.6169 1.064291
296.0990 1.087553
296.5811 1.059156
297.0633 0.8984750
297.5454 0.6193690
298.0275 0.3684760
298.5096 0.2366790
298.9917 0.2309570
299.4738 0.3022100
299.9560 0.5758370
300.4381 0.8111240
300.9202 0.8408880
301.4023 0.6990260
301.8844 0.5416310
302.3665 0.4372330
302.8487 0.3827510
303.3308 0.3661840
303.8129 0.4410620
304.2950 0.4657830
304.7771 0.2945170
305.2592 1.8821999E-02
305.7414 0.1059220
306.2235 4.5896001E-02
306.7056 0.3388230
307.1877 0.5182380
307.6698 0.5818500
308.1519 0.5920100
308.6341 0.5069430
309.1162 0.3936220
309.5983 0.3740250
310.0804 0.4854120
310.5625 0.6681000
311.0446 0.8624810
311.5268 1.071681
312.0089 1.251402
312.4910 1.349660
312.9731 1.433687
313.4552 1.611131
313.9373 1.901482
314.4195 2.166659
314.9016 2.222201
315.3837 2.095575
315.8658 2.176763
316.3479 2.734955
316.8300 3.344136
317.3121 3.630781
317.7943 3.599702
318.2764 3.492991
318.7585 3.424424
319.2406 3.421211
319.7227 3.552114
320.2048 3.980473
320.6870 4.377460
321.1691 4.560688
321.6512 4.561680
322.1333 4.466274
322.6154 4.265491
323.0975 4.051770
323.5797 4.080048
324.0618 4.454671
324.5439 4.796726
325.0260 4.932560
325.5081 4.950859
325.9902 5.049913
326.4724 5.317045
326.9545 5.585798
327.4366 5.537346
327.9187 5.101955
328.4008 4.815695
328.8829 4.874116
329.3651 5.086940
329.8472 5.232134
330.3293 5.272075
330.8114 5.312092
331.2935 5.494576
331.7756 5.831154
332.2578 5.961653
332.7399 5.713754
333.2220 5.380810
333.7041 5.144165
334.1862 5.012026
334.6683 4.966951
335.1505 5.028734
335.6326 5.174540
336.1147 5.199266
336.5968 4.995935
337.0789 4.808620
337.5610 4.756113
338.0432 4.769294
338.5253 4.705495
339.0074 4.492245
339.4895 4.210588
339.9716 4.068607
340.4537 4.119406
340.9359 4.208012
341.4180 4.331717
341.9001 4.453448
342.3822 4.523030
342.8643 4.524921
343.3464 4.505625
343.8286 4.533182
344.3107 4.650679
344.7928 4.653872
345.2749 4.499835
345.7570 4.279890
346.2391 4.006390
346.7213 3.686973
347.2034 3.395742
347.6855 3.209587
348.1676 3.135030
348.6497 3.167147
349.1318 3.474523
349.6140 3.702740
350.0961 3.604584
350.5782 3.305331
351.0603 3.120686
351.5424 3.250005
352.0245 3.596467
352.5067 3.740466
352.9888 3.342625
353.4709 3.164780
353.9530 3.442392
354.4351 3.931406
354.9172 4.388360
355.3994 4.721016
355.8815 4.915233
356.3636 4.930689
356.8457 4.593650
357.3278 4.435258
357.8099 4.509173
358.2920 4.702188
358.7741 5.002619
359.2563 5.369814
359.7384 5.679012
360.2205 5.788034
360.7026 5.658940
361.1847 5.701338
361.6668 6.080293
362.1490 6.447092
362.6311 6.709177
363.1132 6.872250
363.5953 6.937169
364.0774 6.895927
364.5595 6.800982
365.0417 6.894796
365.5238 7.424887
366.0059 7.803961
366.4880 7.941425
366.9701 7.915883
367.4522 7.753008
367.9344 7.476645
368.4165 7.198210
368.8986 7.116024
369.3807 7.342844
369.8628 7.458242
370.3449 7.509924
370.8271 7.405917
371.3092 7.003654
371.7913 6.365108
372.2734 5.722326
372.7555 5.285896
373.2376 5.050200
373.7198 4.807836
374.2019 4.561372
374.6840 4.303047
375.1661 4.004871
375.6482 3.698953
376.1303 3.436388
376.6125 3.241392
377.0946 3.100049
377.5767 3.005131
378.0588 3.010129
378.5409 2.906676
379.0230 2.522033
379.5052 2.077650
379.9873 1.737186
380.4694 1.533397
380.9515 1.403328
381.4336 1.290031
381.9157 1.193528
382.3979 1.142048
382.8800 1.195219
383.3621 1.225690
383.8442 1.137801
384.3263 0.9556570
384.8084 0.7651990
385.2906 0.5796160
385.7727 0.4249100
386.2548 0.3861890
386.7369 0.5028650
387.2190 0.5936330
387.7011 0.5010410
388.1833 0.3318200
388.6654 0.2446260
389.1475 0.3088450
389.6296 0.3881090
390.1117 0.3382010
390.5938 0.1790000
391.0760 8.0219001E-02
391.5581 0.1389110
392.0402 0.2288420
392.5223 0.1647060
393.0044 6.1179999E-02
393.4865 0.2902440
393.9687 0.5279650
394.4508 0.7090920
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395.4150 0.4399030
395.8971 0.1411770
396.3792 6.9467999E-02
396.8614 0.1848170
397.3435 0.2125000
397.8256 6.4218998E-02
398.3077 9.4378002E-02
398.7898 0.1524720
399.2719 0.1272460
399.7540 9.3473002E-02
400.2361 9.3208998E-02
400.7183 0.1008920
401.2004 2.8769000E-02
401.6825 0.2399450
402.1646 0.3746070
402.6467 0.1753230
403.1288 0.1226450
403.6110 0.2362980
404.0931 0.1052640
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405.5394 0.3897090
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409.3964 0.6771200
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410.8427 1.272081
411.3248 1.097457
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413.2533 1.283251
413.7354 1.588178
414.2175 1.922418
414.6996 2.167900
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415.6639 2.284096
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417.1102 2.813441
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418.5566 3.118930
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427.7168 10.97278
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428.6810 12.30794
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429.6453 13.20866
430.1274 13.41553
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431.5737 13.58378
432.0558 12.92702
432.5380 11.45262
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433.9843 8.366274
434.4664 8.000581
434.9485 7.599299
435.4307 7.244221
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436.3949 6.803708
436.8770 6.740166
437.3591 6.811655
437.8412 6.970100
438.3234 7.030967
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439.2876 6.671057
439.7697 7.068020
440.2518 7.648342
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441.2160 8.651052
441.6982 9.032415
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442.6624 9.631867
443.1445 9.861260
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444.1087 10.17177
444.5909 10.34195
445.0730 10.51903
445.5551 10.74783
446.0372 11.05150
446.5193 11.37377
447.0014 11.61805
447.4836 11.83431
447.9657 11.81843
448.4478 11.32541
448.9299 10.73129
449.4120 10.30398
449.8941 10.04049
450.3763 9.711045
450.8584 9.024347
451.3405 8.094857
451.8226 7.484714
452.3047 7.333372
452.7868 7.189815
453.2690 6.708627
453.7511 6.100911
454.2332 5.663634
454.7153 5.502708
455.1974 5.415990
455.6795 5.254461
456.1617 5.021802
456.6438 4.745236
457.1259 4.418674
457.6080 4.090938
458.0901 3.795403
458.5722 3.523075
459.0544 3.404606
459.5365 3.596090
460.0186 3.843986
460.5007 3.956556
460.9828 3.916714
461.4649 3.772988
461.9471 3.546640
462.4292 3.272403
462.9113 3.063920
463.3934 2.900702
463.8755 2.828532
464.3576 2.924783
464.8398 3.052888
465.3219 3.051508
465.8040 2.904542
466.2861 2.764587
466.7682 2.813113
467.2503 3.079348
467.7325 3.253446
468.2146 3.333275
468.6967 3.318198
469.1788 3.138583
469.6609 2.879181
470.1430 2.656954
470.6252 2.523727
471.1073 2.452972
471.5894 2.411281
472.0715 2.413541
472.5536 2.380217
473.0357 2.294147
473.5179 2.171549
474.0000 2.010818
474.4821 1.819601
474.9642 1.617234
475.4463 1.371649
475.9284 1.139100
476.4106 1.085280
476.8927 1.250580
477.3748 1.338951
477.8569 1.146396
478.3390 0.8282930
478.8211 0.6268970
479.3033 0.5634220
479.7854 0.5740290
480.2675 0.6796560
480.7496 0.8244840
481.2317 0.9078790
481.7138 0.9155960
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