#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:34:49 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1162 $ #$URL: svn://172.16.1.111/rod/cif/1/00/05/1000581.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000581 loop_ _publ_author_name 'Meagher, E. P.' 'Lager, G. A.' _publ_section_title ; Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structures of rutile and brookite at high temperature Sample at 25 degrees C ; _journal_name_full 'The Canadian Mineralogist' _journal_page_first 77 _journal_page_last 85 _journal_volume 17 _journal_year 1979 _chemical_compound_source R050591 _chemical_formula_sum 'O2 Ti' _chemical_name_mineral Brookite _space_group_IT_number 61 _symmetry_space_group_name_Hall '-P 2ac 2ab' _symmetry_space_group_name_H-M 'P b c a' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 9.174 _cell_length_b 5.449 _cell_length_c 5.138 _cell_volume 256.844 _exptl_crystal_density_diffrn 4.131 _cod_original_formula_sum 'Ti O2' _cod_database_code 9004137 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R050591.rod _rod_data_source.block 3500000 _rod_database.code 1000581 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9004137 COD http://www.crystallography.net/cod/9004137.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 120.9924 0.0000000E+00 121.4745 55.02539 121.9566 57.90332 122.4388 544.6201 122.9209 1431.201 123.4030 2726.730 123.8851 4361.609 124.3672 6209.611 124.8493 8349.814 125.3315 10836.04 125.8136 12767.44 126.2957 14116.11 126.7778 14777.88 127.2599 14400.98 127.7420 13071.23 128.2242 11352.90 128.7063 9948.771 129.1884 8792.408 129.6705 8153.096 130.1526 8206.117 130.6347 8551.033 131.1169 8985.129 131.5990 9418.021 132.0811 9764.582 132.5632 9833.928 133.0453 9482.178 133.5274 9004.278 134.0096 8332.610 134.4917 7566.416 134.9738 6822.565 135.4559 6137.594 135.9380 5538.961 136.4201 5133.021 136.9023 4905.885 137.3844 4817.577 137.8665 4860.721 138.3486 5027.867 138.8307 5300.582 139.3128 5674.072 139.7950 6164.788 140.2771 6760.299 140.7592 7472.569 141.2413 8280.433 141.7234 9161.561 142.2055 10109.28 142.6877 11152.92 143.1698 12313.62 143.6519 13571.99 144.1340 14935.30 144.6161 16405.54 145.0982 17989.70 145.5803 19708.53 146.0625 21556.02 146.5446 23597.10 147.0267 25875.07 147.5088 28331.23 147.9909 30913.12 148.4730 33613.68 148.9552 36420.96 149.4373 39107.46 149.9194 41877.72 150.4015 44296.82 150.8836 46362.22 151.3657 47975.24 151.8479 49000.88 152.3300 49313.95 152.8121 48893.55 153.2942 47727.23 153.7763 45679.26 154.2584 43188.07 154.7406 40332.19 155.2227 37205.87 155.7048 33971.58 156.1869 30777.59 156.6690 27606.02 157.1511 24698.98 157.6333 22089.22 158.1154 19718.69 158.5975 17571.71 159.0796 15643.64 159.5617 13909.37 160.0438 12371.84 160.5260 11019.58 161.0081 9796.890 161.4902 8719.702 161.9723 7764.515 162.4544 6893.923 162.9365 6111.729 163.4187 5405.024 163.9008 4757.258 164.3829 4165.602 164.8650 3627.310 165.3471 3149.206 165.8292 2727.593 166.3113 2347.445 166.7935 2015.641 167.2756 1721.012 167.7577 1452.958 168.2398 1210.028 168.7219 989.4209 169.2040 791.5869 169.6862 621.3853 170.1683 472.7300 170.6504 357.3594 171.1325 252.6580 171.6146 144.7920 172.0967 31.69580 172.5789 78.40039 173.0610 172.7478 173.5431 246.6189 174.0252 315.5022 174.5073 382.5991 174.9894 445.7117 175.4716 501.6235 175.9537 549.9778 176.4358 594.8794 176.9179 644.4475 177.4000 707.0598 177.8821 762.6033 178.3643 810.3308 178.8464 821.9038 179.3285 823.3684 179.8106 811.2979 180.2927 789.6643 180.7748 760.5168 181.2570 722.3572 181.7391 680.2559 182.2212 636.3281 182.7033 588.9963 183.1854 535.6472 183.6675 475.1902 184.1497 408.1150 184.6318 334.8860 185.1139 256.4717 185.5960 173.1011 186.0781 88.60229 186.5602 2.3193000E-02 187.0423 100.4343 187.5245 214.2246 188.0066 345.7192 188.4887 497.3857 188.9708 662.3533 189.4529 854.7869 189.9350 1086.300 190.4172 1354.955 190.8993 1650.629 191.3814 1993.078 191.8635 2346.792 192.3456 2678.549 192.8277 3009.647 193.3099 3265.342 193.7920 3367.175 194.2741 3306.460 194.7562 3153.825 195.2383 2851.541 195.7204 2504.417 196.2026 2191.792 196.6847 1929.638 197.1668 1717.456 197.6489 1556.362 198.1310 1452.396 198.6131 1386.241 199.0953 1362.255 199.5774 1364.062 200.0595 1381.107 200.5416 1409.493 201.0237 1449.090 201.5058 1500.047 201.9880 1565.017 202.4701 1638.309 202.9522 1715.075 203.4343 1799.003 203.9164 1893.444 204.3985 1999.675 204.8807 2116.806 205.3628 2241.894 205.8449 2364.230 206.3270 2511.463 206.8091 2683.333 207.2912 2880.048 207.7733 3100.238 208.2555 3342.349 208.7376 3610.980 209.2197 3923.889 209.7018 4308.802 210.1839 4711.521 210.6660 5161.085 211.1482 5617.606 211.6303 6048.870 212.1124 6446.381 212.5945 6777.881 213.0766 6901.926 213.5587 6797.285 214.0409 6538.684 214.5230 6065.751 215.0051 5453.872 215.4872 4813.048 215.9693 4185.427 216.4514 3588.786 216.9336 3104.447 217.4157 2738.356 217.8978 2439.736 218.3799 2202.028 218.8620 2019.758 219.3441 1878.499 219.8263 1776.470 220.3084 1709.745 220.7905 1662.808 221.2726 1636.321 221.7547 1623.846 222.2368 1620.820 222.7190 1628.633 223.2011 1653.073 223.6832 1697.154 224.1653 1761.238 224.6474 1839.230 225.1295 1931.375 225.6117 2034.213 226.0938 2147.157 226.5759 2269.400 227.0580 2396.306 227.5401 2533.563 228.0222 2668.281 228.5043 2786.587 228.9865 2885.241 229.4686 2971.156 229.9507 3045.474 230.4328 3106.997 230.9149 3161.967 231.3970 3202.839 231.8792 3247.400 232.3613 3309.087 232.8434 3389.661 233.3255 3487.023 233.8076 3600.660 234.2897 3731.256 234.7719 3872.332 235.2540 4015.662 235.7361 4176.399 236.2182 4363.490 236.7003 4581.085 237.1824 4828.752 237.6646 5101.466 238.1467 5396.816 238.6288 5748.229 239.1109 6153.064 239.5930 6627.511 240.0751 7183.408 240.5573 7823.854 241.0394 8552.750 241.5215 9370.846 242.0036 10284.33 242.4857 11284.32 242.9678 12468.50 243.4500 13660.87 243.9321 14860.87 244.4142 16018.21 244.8963 16992.87 245.3784 17650.09 245.8605 18013.96 246.3427 17934.46 246.8248 17286.57 247.3069 16340.65 247.7890 15103.31 248.2711 13643.06 248.7532 12134.28 249.2354 10730.42 249.7175 9427.002 250.1996 8277.788 250.6817 7285.193 251.1638 6420.724 251.6459 5691.056 252.1281 5084.325 252.6102 4577.803 253.0923 4150.743 253.5744 3811.744 254.0565 3505.013 254.5386 3229.851 255.0208 2980.278 255.5029 2753.971 255.9850 2550.290 256.4671 2369.646 256.9492 2213.177 257.4313 2083.272 257.9135 1958.188 258.3956 1829.330 258.8777 1712.339 259.3598 1615.400 259.8419 1536.517 260.3240 1468.324 260.8062 1405.966 261.2883 1349.386 261.7704 1292.185 262.2525 1230.217 262.7346 1171.662 263.2167 1121.390 263.6989 1077.475 264.1810 1034.991 264.6631 990.4622 265.1452 944.7002 265.6273 903.7410 266.1094 866.3799 266.5916 832.4546 267.0737 802.6655 267.5558 776.4419 268.0379 752.4685 268.5200 730.1387 269.0021 709.4678 269.4843 690.5078 269.9664 674.4385 270.4485 658.2239 270.9306 637.9612 271.4127 616.8979 271.8948 602.5364 272.3770 598.9561 272.8591 602.5708 273.3412 604.5249 273.8233 604.0493 274.3054 603.8398 274.7875 604.7458 275.2697 605.5789 275.7518 604.8757 276.2339 602.0518 276.7160 599.2322 277.1981 601.1626 277.6802 608.9204 278.1623 615.6255 278.6444 617.6448 279.1266 617.9932 279.6087 621.9897 280.0908 631.4800 280.5729 643.2129 281.0550 652.1392 281.5371 658.1709 282.0193 667.8020 282.5014 688.3237 282.9835 711.6946 283.4656 724.2400 283.9477 722.1438 284.4298 718.0950 284.9120 726.0781 285.3941 744.5962 285.8762 763.3301 286.3583 780.6897 286.8404 796.1736 287.3225 808.1868 287.8047 816.1313 288.2868 825.3359 288.7689 838.9343 289.2510 857.3191 289.7331 882.7373 290.2152 918.0654 290.6974 959.0183 291.1795 998.5752 291.6616 1036.501 292.1437 1083.798 292.6258 1145.710 293.1079 1224.163 293.5901 1321.615 294.0722 1443.104 294.5543 1578.348 295.0364 1717.733 295.5185 1862.294 296.0006 2019.699 296.4828 2195.573 296.9649 2387.206 297.4470 2585.680 297.9291 2788.640 298.4112 3000.850 298.8933 3225.913 299.3755 3462.858 299.8576 3711.488 300.3397 3973.574 300.8218 4245.826 301.3039 4522.348 301.7860 4802.051 302.2682 5087.544 302.7503 5378.022 303.2324 5676.318 303.7145 5996.341 304.1966 6347.609 304.6787 6714.048 305.1609 7070.974 305.6430 7422.058 306.1251 7800.788 306.6072 8228.737 307.0893 8693.894 307.5714 9169.875 308.0536 9650.880 308.5357 10149.44 309.0178 10672.11 309.4999 11217.26 309.9820 11791.34 310.4641 12398.36 310.9463 13033.02 311.4284 13684.15 311.9105 14349.34 312.3926 15029.39 312.8747 15729.06 313.3568 16442.31 313.8390 17156.18 314.3211 17887.40 314.8032 18596.84 315.2853 19261.42 315.7674 19880.12 316.2495 20428.58 316.7317 20912.79 317.2138 21301.72 317.6959 21565.56 318.1780 21699.34 318.6601 21713.33 319.1422 21617.54 319.6243 21409.55 320.1064 21072.43 320.5886 20580.21 321.0707 19965.69 321.5528 19281.41 322.0349 18525.78 322.5170 17719.68 322.9991 16847.84 323.4813 15931.96 323.9634 15018.72 324.4455 14115.96 324.9276 13231.65 325.4097 12379.72 325.8918 11555.52 326.3740 10773.29 326.8561 10033.08 327.3382 9338.059 327.8203 8690.679 328.3024 8093.057 328.7845 7528.072 329.2667 6984.458 329.7488 6464.766 330.2309 5975.928 330.7130 5519.827 331.1951 5097.010 331.6772 4711.916 332.1594 4364.256 332.6415 4040.037 333.1236 3732.184 333.6057 3444.045 334.0878 3175.350 334.5699 2929.453 335.0521 2699.842 335.5342 2479.779 336.0163 2272.083 336.4984 2083.901 336.9805 1922.550 337.4626 1777.460 337.9448 1632.712 338.4269 1485.630 338.9090 1346.757 339.3911 1220.679 339.8732 1105.147 340.3553 998.1582 340.8375 900.2048 341.3196 807.5518 341.8017 714.6536 342.2838 621.9951 342.7659 540.3369 343.2480 477.2542 343.7302 422.9600 344.2123 367.7771 344.6944 311.1914 345.1765 255.9849 345.6586 202.4434 346.1407 152.5762 346.6229 112.2830 347.1050 89.24878 347.5871 69.39209 348.0692 43.89380 348.5513 14.38159 349.0334 13.93970 349.5156 38.76855 349.9977 59.92456 350.4798 76.54077 350.9619 88.46094 351.4440 97.36890 351.9261 101.5330 352.4083 103.3696 352.8904 106.6213 353.3725 112.3054 353.8546 120.3489 354.3367 132.6239 354.8188 152.4957 355.3010 161.5098 355.7831 151.7209 356.2652 134.3019 356.7473 118.8667 357.2294 106.5392 357.7115 93.40820 358.1937 75.70239 358.6758 53.15283 359.1579 32.04785 359.6400 17.13257 360.1221 1.044189 360.6042 29.16650 361.0863 64.53857 361.5685 99.52148 362.0506 129.9541 362.5327 156.8147 363.0148 184.0515 363.4969 214.9973 363.9790 242.1301 364.4612 267.2354 364.9433 286.9465 365.4254 296.2651 365.9075 293.6924 366.3896 282.6055 366.8717 268.5428 367.3539 253.7148 367.8360 229.4597 368.3181 189.0974 368.8002 145.3063 369.2823 105.8925 369.7644 71.71790 370.2466 39.18860 370.7287 4.330444 371.2108 33.41858 371.6929 63.12158 372.1750 80.99658 372.6571 95.70190 373.1393 109.7059 373.6214 122.4042 374.1035 132.5481 374.5856 139.3500 375.0677 143.2905 375.5498 146.0463 376.0320 148.6536 376.5141 148.1686 376.9962 145.4076 377.4783 139.1958 377.9604 126.6967 378.4425 107.9269 378.9247 88.09619 379.4068 75.92078 379.8889 76.30054 380.3710 66.94812 380.8531 40.09192 381.3352 9.955811 381.8174 17.77649 382.2995 43.38550 382.7816 69.72522 383.2637 98.73926 383.7458 130.2561 384.2279 162.2400 384.7101 194.2183 385.1922 226.6520 385.6743 256.2506 386.1564 287.2148 386.6385 326.1436 387.1206 376.2806 387.6028 431.1252 388.0849 479.3595 388.5670 518.3479 389.0491 562.7180 389.5312 616.2732 390.0133 676.7334 390.4955 744.7781 390.9776 819.8545 391.4597 896.7566 391.9418 971.2490 392.4239 1044.149 392.9060 1117.725 393.3882 1189.624 393.8703 1266.980 394.3524 1356.199 394.8345 1453.747 395.3166 1552.584 395.7987 1647.182 396.2809 1743.748 396.7630 1850.382 397.2451 1968.318 397.7272 2090.030 398.2093 2213.273 398.6914 2338.977 399.1736 2466.579 399.6557 2595.380 400.1378 2732.087 400.6199 2881.511 401.1020 3042.100 401.5841 3209.103 402.0662 3380.341 402.5483 3560.463 403.0305 3758.982 403.5126 3974.647 403.9947 4184.702 404.4768 4375.107 404.9589 4564.942 405.4410 4774.510 405.9232 5002.191 406.4053 5231.492 406.8874 5454.973 407.3695 5668.610 407.8516 5862.536 408.3337 6034.578 408.8159 6191.900 409.2980 6343.101 409.7801 6480.334 410.2622 6594.240 410.7443 6682.805 411.2264 6739.276 411.7086 6752.918 412.1907 6712.475 412.6728 6647.903 413.1549 6557.833 413.6370 6447.851 414.1191 6322.183 414.6013 6179.966 415.0834 6016.272 415.5655 5826.363 416.0476 5611.276 416.5297 5394.500 417.0118 5180.026 417.4940 4959.564 417.9761 4726.806 418.4582 4488.164 418.9403 4253.326 419.4224 4024.850 419.9045 3803.668 420.3867 3588.746 420.8688 3380.198 421.3509 3181.077 421.8330 2998.440 422.3151 2819.958 422.7972 2636.688 423.2794 2451.719 423.7615 2275.935 424.2436 2117.737 424.7257 1976.383 425.2078 1845.541 425.6899 1728.887 426.1721 1617.128 426.6542 1502.818 427.1363 1391.819 427.6184 1291.787 428.1005 1205.615 428.5826 1125.197 429.0648 1041.740 429.5469 955.0538 430.0290 873.2129 430.5111 799.4521 430.9932 730.6990 431.4753 663.8005 431.9575 598.8876 432.4396 536.3530 432.9217 476.3577 433.4038 419.3716 433.8859 365.5898 434.3680 315.3140 434.8502 269.4050 435.3323 229.6216 435.8144 195.3132 436.2965 162.8578 436.7786 131.6128 437.2607 102.7117 437.7429 75.54785 438.2250 51.30591 438.7071 32.44482 439.1892 19.65796 439.6713 11.97656 440.1534 9.085449 440.6356 12.32959 441.1177 12.78931 441.5998 2.437500 442.0819 5.719727 442.5640 0.8984380 443.0461 15.54199 443.5282 34.86572 444.0103 50.90674 444.4925 65.16455 444.9746 86.01953 445.4567 119.0366 445.9388 151.8394 446.4209 181.6414 446.9030 211.1987 447.3852 243.2856 447.8673 278.6033 448.3494 317.2629 448.8315 361.2698 449.3136 414.1270 449.7957 454.4255 450.2779 474.2200 450.7600 489.1233 451.2421 505.2542 451.7242 520.1841 452.2063 528.1331 452.6884 525.2747 453.1706 515.3452 453.6527 507.6562 454.1348 504.4309 454.6169 496.5222 455.0990 477.2444 455.5811 455.2820 456.0633 436.2930 456.5454 420.8547 457.0275 406.0894 457.5096 389.9282 457.9917 372.7480 458.4738 355.8215 458.9560 339.5728 459.4381 322.4819 459.9202 300.6880 460.4023 277.7622 460.8844 261.0669 461.3665 255.4946 461.8487 251.2910 462.3308 242.6367 462.8129 229.5403 463.2950 210.6755 463.7771 183.7332 464.2592 155.6689 464.7414 137.9351 465.2235 132.6477 465.7056 121.5957 466.1877 96.08960 466.6698 69.01294 467.1519 51.51929 467.6341 42.57007 468.1162 33.86401 468.5983 19.65869 469.0804 2.090820 469.5625 8.487549 470.0446 3.818604 470.5268 2.489502 471.0089 10.07397 471.4910 19.14014 471.9731 22.34521 472.4552 18.55200 472.9373 11.98096 473.4195 7.304199 473.9016 4.832275 474.3837 0.3330080 474.8658 4.506836 475.3479 13.60864 475.8300 30.20703 476.3122 50.95239 476.7943 70.82031 477.2764 87.38281 477.7585 104.4585 478.2406 128.3660 478.7227 159.5125 479.2049 192.7515 479.6870 226.1533 480.1691 262.8735 480.6512 305.4724 481.1333 353.1240 481.6154 402.2971 482.0976 448.9077 482.5797 497.1257 483.0618 554.7781 483.5439 622.1265 484.0260 690.8828 484.5081 755.2598 484.9902 820.4546 485.4724 897.9702 485.9545 991.3401 486.4366 1085.223 486.9187 1170.697 487.4008 1255.856 487.8829 1351.842 488.3651 1460.335 488.8472 1574.350 489.3293 1686.384 489.8114 1797.142 490.2935 1918.609 490.7756 2051.155 491.2578 2191.399 491.7399 2339.795 492.2220 2494.262 492.7041 2651.362 493.1862 2809.791 493.6683 2972.975 494.1505 3146.462 494.6326 3331.623 495.1147 3519.664 495.5968 3712.740 496.0789 3905.162 496.5610 4098.001 497.0432 4287.937 497.5253 4472.655 498.0074 4651.288 498.4895 4818.390 498.9716 4966.335 499.4537 5097.299 499.9359 5192.001 500.4180 5240.752 500.9001 5255.914 501.3822 5250.108 501.8643 5222.709 502.3464 5167.565 502.8286 5083.104 503.3107 4968.373 503.7928 4815.220 504.2749 4623.781 504.7570 4416.876 505.2391 4203.540 505.7213 3984.433 506.2034 3765.424 506.6855 3544.252 507.1676 3328.363 507.6497 3115.800 508.1318 2911.410 508.6140 2722.933 509.0961 2550.815 509.5782 2388.824 510.0603 2232.205 510.5424 2081.231 511.0245 1942.755 511.5067 1818.662 511.9888 1705.352 512.4709 1603.815 512.9530 1511.633 513.4351 1425.513 513.9172 1344.797 514.3994 1273.076 514.8815 1216.264 515.3636 1175.277 515.8457 1135.181 516.3278 1092.759 516.8099 1055.695 517.2921 1027.986 517.7742 1007.064 518.2563 988.0149 518.7384 967.7937 519.2205 953.6531 519.7026 956.9961 520.1848 975.3071 520.6669 988.7454 521.1490 989.6785 521.6311 990.9407 522.1132 1007.444 522.5953 1037.147 523.0775 1069.479 523.5596 1103.451 524.0417 1138.642 524.5238 1173.589 525.0059 1208.848 525.4880 1246.508 525.9702 1287.183 526.4523 1331.637 526.9344 1382.124 527.4165 1440.451 527.8986 1501.240 528.3807 1563.995 528.8629 1628.854 529.3450 1697.046 529.8271 1767.488 530.3092 1837.073 530.7913 1903.614 531.2734 1968.796 531.7556 2038.031 532.2377 2111.988 532.7198 2189.840 533.2019 2273.448 533.6840 2357.172 534.1661 2440.569 534.6483 2523.131 535.1304 2602.078 535.6125 2674.454 536.0946 2742.983 536.5767 2814.993 537.0588 2890.711 537.5410 2960.645 538.0231 3020.175 538.5052 3072.214 538.9873 3121.217 539.4694 3167.722 539.9515 3209.842 540.4337 3246.457 540.9158 3279.090 541.3979 3310.757 541.8800 3340.544 542.3621 3364.611 542.8442 3381.410 543.3264 3388.948 543.8085 3380.218 544.2906 3344.823 544.7726 3306.525 545.2548 3269.042 545.7369 3226.278 546.2190 3173.259 546.7011 3110.634 547.1832 3042.486 547.6653 2972.805 548.1475 2900.068 548.6296 2818.484 549.1117 2725.123 549.5938 2631.111 550.0759 2541.888 550.5580 2451.620 551.0402 2352.831 551.5223 2245.866 552.0044 2142.131 552.4865 2051.571 552.9686 1966.868 553.4507 1873.586 553.9329 1771.095 554.4150 1668.914 554.8971 1570.750 555.3792 1477.204 555.8613 1391.396 556.3434 1314.387 556.8256 1240.407 557.3077 1169.351 557.7898 1099.664 558.2719 1030.191 558.7540 961.0166 559.2361 894.0056 559.7183 829.7354 560.2004 769.1926 560.6825 715.1160 561.1646 673.1957 561.6467 628.8284 562.1288 576.8204 562.6110 525.0404 563.0931 478.7136 563.5752 437.9728 564.0573 399.5018 564.5394 360.5081 565.0215 322.4119 565.5037 289.1387 565.9858 260.9083 566.4679 235.1979 566.9500 211.0701 567.4321 189.2098 567.9142 171.0383 568.3964 156.9185 568.8785 141.2971 569.3606 120.4033 569.8427 98.43396 570.3248 79.56421 570.8069 63.72449 571.2891 48.01929 571.7712 30.66455 572.2533 13.75281 572.7354 2.819092 573.2175 1.244385 573.6996 2.5635000E-02 574.1818 8.9109996E-03 574.6639 0.5743410 575.1460 3.137695 575.6281 7.339600 576.1102 12.30005 576.5923 17.78467 577.0745 22.78418 577.5566 25.24609 578.0387 25.19690 578.5208 22.09473 579.0029 11.78333 579.4850 2.676392 579.9672 1.708740 580.4493 7.462158 580.9314 13.68750 581.4135 19.86694 581.8956 24.09448 582.3777 23.65173 582.8599 19.50391 583.3420 14.75269 583.8241 10.01062 584.3062 7.193604 584.7883 9.432617 585.2704 18.32776 585.7526 24.50232 586.2347 26.09155 586.7168 27.19531 587.1989 29.93738 587.6810 33.26270 588.1631 34.57446 588.6453 33.08618 589.1274 32.03894 589.6095 38.19678 590.0916 53.34167 590.5737 58.47424 591.0558 47.07520 591.5380 34.68311 592.0201 29.46582 592.5022 27.69165 592.9843 24.08765 593.4664 17.59021 593.9485 8.451050 594.4307 5.542480 594.9128 21.66296 595.3949 31.83911 595.8770 34.45398 596.3591 39.46851 596.8412 55.42285 597.3234 80.56421 597.8055 101.8992 598.2876 117.0381 598.7697 132.1777 599.2518 146.4802 599.7339 162.4845 600.2161 182.8965 600.6982 207.7502 601.1803 234.9508 601.6624 263.0511 602.1445 292.0974 602.6266 322.1313 603.1088 353.7371 603.5909 384.4546 604.0730 410.4006 604.5551 437.5449 605.0372 470.4387 605.5193 508.9895 606.0015 549.0369 606.4836 587.5010 606.9657 627.3342 607.4478 674.2782 607.9299 726.7201 608.4120 774.6316 608.8942 812.7676 609.3763 848.2020 609.8584 892.1411 610.3405 946.9586 610.8226 1002.096 611.3047 1056.295 611.7869 1112.121 612.2690 1170.578 612.7511 1231.562 613.2332 1295.126 613.7153 1361.358 614.1974 1428.839 614.6796 1494.972 615.1617 1559.809 615.6438 1630.022 616.1259 1706.466 616.6080 1787.656 617.0901 1874.673 617.5723 1965.741 618.0544 2058.551 618.5365 2152.960 619.0186 2247.611 619.5007 2341.496 619.9828 2435.130 620.4650 2528.861 620.9471 2622.970 621.4292 2719.285 621.9113 2818.372 622.3934 2921.360 622.8755 3031.175 623.3577 3155.629 623.8398 3276.016 624.3219 3388.357 624.8040 3499.246 625.2861 3611.854 625.7682 3726.125 626.2504 3842.207 626.7325 3960.001 627.2145 4078.125 627.6967 4193.937 628.1788 4307.661 628.6609 4418.436 629.1430 4525.486 629.6251 4631.284 630.1072 4742.631 630.5894 4855.987 631.0715 4957.628 631.5536 5038.625 632.0357 5115.448 632.5178 5197.120 632.9999 5280.015 633.4821 5360.482 633.9642 5436.736 634.4463 5506.365 634.9284 5567.974 635.4105 5621.254 635.8926 5655.392 636.3748 5656.478 636.8569 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249.6600 690.8539 244.7688 691.3361 238.6301 691.8182 231.0604 692.3003 223.0796 692.7824 214.7922 693.2645 206.7881 693.7466 199.8203 694.2288 194.4722 694.7109 187.8666 695.1930 179.6495 695.6751 170.6466 696.1572 158.7571 696.6393 147.3760 697.1215 141.8856 697.6036 142.9473 698.0857 144.3949 698.5678 140.5858 699.0499 132.9897 699.5320 124.8000 700.0142 115.8793 700.4963 110.7017 700.9784 112.6721 701.4605 115.7777 701.9426 111.0522 702.4247 97.13770 702.9069 88.14673 703.3890 89.13013 703.8711 89.52454 704.3532 84.23389 704.8353 76.64111 705.3174 70.91736 705.7996 67.93604 706.2817 65.97852 706.7638 63.86414 707.2459 61.25000 707.7280 57.35120 708.2101 52.16870 708.6923 46.53003 709.1743 39.49561 709.6564 33.70862 710.1385 33.79675 710.6207 39.06238 711.1028 40.01416 711.5849 30.54565 712.0670 23.24329 712.5491 25.29138 713.0313 30.63232 713.5134 32.05762 713.9955 28.95239 714.4776 25.14587 714.9597 23.43481 715.4418 23.08105 715.9240 22.35156 716.4061 21.40942 716.8882 18.34180 717.3703 11.14172 717.8524 4.596924 718.3345 3.375122 718.8167 6.053223 719.2988 8.000000 719.7809 8.800537 720.2630 9.081909 720.7451 9.076416 721.2272 8.635254 721.7094 7.633057 722.1915 6.070068 722.6736 3.754517 723.1557 0.3974610 723.6378 3.208130 724.1199 5.271057 724.6021 5.739807 725.0842 4.665161 725.5663 0.5012820 726.0484 1.990845 726.5305 1.831116 727.0126 8.762512 727.4948 12.05286 727.9769 10.30853 728.4590 8.489502 728.9411 7.664612 729.4232 7.675354 729.9053 9.145081 730.3875 11.24213 730.8696 11.88202 731.3517 10.18927 731.8338 7.710632 732.3159 6.740723 732.7980 7.326355 733.2802 7.782898 733.7623 8.255310 734.2444 7.990417 734.7265 5.685181 735.2086 3.211426 735.6907 3.408325 736.1729 6.440308 736.6550 9.145142 737.1371 11.78070 737.6192 13.06909 738.1013 11.11664 738.5834 7.748291 739.0656 5.884888 739.5477 6.203430 740.0298 7.396240 740.5119 8.596680 740.9940 9.447693 741.4761 7.849731 741.9583 3.060547 742.4404 7.3546998E-02 742.9225 0.2913210 743.4046 2.576965 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