#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:37:46 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1195 $ #$URL: svn://172.16.1.111/rod/cif/1/00/06/1000609.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000609 loop_ _publ_author_name 'Tait, K. T.' 'Barkley, M. C.' 'Thompson, R. M.' 'Origlieri, M. J.' 'Evans, S. H.' 'Prewitt, C. T.' 'Yang, H.' _publ_section_title ; Bobdownsite, a new mineral species from Big Fish River, Yukon, Canada, and its structural relationship with whitlockite-type compounds Sample number R070654 ; _journal_name_full 'The Canadian Mineralogist' _journal_page_first 1065 _journal_page_last 1078 _journal_paper_doi 10.3749/canmin.49.4.1065 _journal_volume 49 _journal_year 2011 _chemical_compound_source '2 Tip Top mine, South Dakota, USA' _chemical_formula_sum 'Al0.04 Ca9 F0.84 H0.16 Mg0.96 O27.16 P6.97' _chemical_name_mineral Bobdownsite _space_group_IT_number 161 _symmetry_space_group_name_Hall 'R 3 -2"c' _symmetry_space_group_name_H-M 'R 3 c :H' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 120 _cell_length_a 10.3394 _cell_length_b 10.3394 _cell_length_c 37.0836 _cell_volume 3433.232 _exptl_crystal_density_diffrn 3.052 _cod_original_sg_symbol_H-M 'R 3 c' _cod_original_formula_sum 'Ca9 (Mg.96 Al.04) P6.97 O27.16 (F.84 H.16)' _cod_database_code 9014798 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R050109.rod _rod_data_source.block 3500000 _rod_database.code 1000609 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9014798 COD http://www.crystallography.net/cod/9014798.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 132.3306 0.0000000E+00 132.8127 0.1047360 133.2948 3.336426 133.7769 16.54272 134.2590 33.79102 134.7412 29.17358 135.2233 9.853271 135.7054 8.997314 136.1875 4.958740 136.6696 31.58154 137.1517 70.97266 137.6339 120.6345 138.1160 169.5981 138.5981 198.9163 139.0802 198.2175 139.5623 185.9365 140.0444 203.1929 140.5266 254.9944 141.0087 314.3574 141.4908 371.1465 141.9729 426.4131 142.4550 485.5261 142.9371 551.5339 143.4193 622.8718 143.9014 696.2849 144.3835 775.5149 144.8656 852.2681 145.3477 918.3105 145.8299 973.0254 146.3120 1020.594 146.7941 1058.424 147.2762 1091.573 147.7583 1125.891 148.2404 1165.641 148.7226 1207.017 149.2047 1240.526 149.6868 1262.982 150.1689 1282.692 150.6510 1302.881 151.1331 1323.781 151.6153 1345.490 152.0974 1367.552 152.5795 1389.947 153.0616 1416.388 153.5437 1448.102 154.0258 1483.573 154.5080 1527.312 154.9901 1576.193 155.4722 1620.758 155.9543 1649.309 156.4364 1654.364 156.9185 1667.660 157.4007 1695.238 157.8828 1724.978 158.3649 1751.376 158.8470 1772.844 159.3291 1790.142 159.8112 1804.897 160.2934 1820.425 160.7755 1825.860 161.2576 1816.359 161.7397 1798.793 162.2218 1783.812 162.7039 1775.833 163.1861 1766.716 163.6682 1733.686 164.1503 1663.119 164.6324 1586.821 165.1145 1504.690 165.5966 1428.385 166.0788 1369.383 166.5609 1324.508 167.0430 1283.808 167.5251 1242.806 168.0072 1231.993 168.4893 1228.318 168.9715 1216.240 169.4536 1215.680 169.9357 1212.206 170.4178 1209.199 170.8999 1210.988 171.3820 1211.030 171.8642 1196.799 172.3463 1187.317 172.8284 1203.528 173.3105 1247.505 173.7926 1296.969 174.2747 1349.797 174.7569 1397.459 175.2390 1420.395 175.7211 1398.332 176.2032 1349.993 176.6853 1315.448 177.1674 1306.293 177.6496 1286.485 178.1317 1235.136 178.6138 1157.925 179.0959 1064.117 179.5780 948.4380 180.0602 815.6543 180.5423 700.3210 181.0244 606.2441 181.5065 528.0969 181.9886 466.8640 182.4707 419.3225 182.9529 375.5510 183.4350 325.3145 183.9171 266.6345 184.3992 218.3586 184.8813 188.0630 185.3634 163.7612 185.8456 140.9880 186.3277 119.3401 186.8098 101.3733 187.2919 92.07495 187.7740 97.56177 188.2561 94.06128 188.7383 71.36621 189.2204 47.35669 189.7025 33.23560 190.1846 32.28271 190.6667 38.30103 191.1488 42.89282 191.6310 45.64526 192.1131 47.15869 192.5952 47.26196 193.0773 46.48535 193.5594 44.69458 194.0415 42.26270 194.5237 39.73730 195.0058 38.27954 195.4879 32.42065 195.9700 34.86133 196.4521 61.34424 196.9342 91.47583 197.4164 98.44312 197.8985 69.22144 198.3806 15.20605 198.8627 24.93750 199.3448 47.47681 199.8270 61.97998 200.3091 71.26587 200.7912 73.33838 201.2733 60.08545 201.7554 22.65527 202.2375 28.45801 202.7197 40.65161 203.2018 25.72388 203.6839 81.07837 204.1660 80.41602 204.6481 38.80591 205.1302 5.058838 205.6124 11.53601 206.0945 48.85352 206.5766 62.28662 207.0587 35.37805 207.5408 1.155640 208.0229 23.59180 208.5051 39.05298 208.9872 49.10437 209.4693 52.36536 209.9514 52.25623 210.4335 62.21375 210.9156 95.71045 211.3978 130.9618 211.8799 145.5483 212.3620 138.1460 212.8441 131.3278 213.3262 141.1699 213.8083 164.0275 214.2905 190.2325 214.7726 224.3752 215.2547 258.3140 215.7368 280.6495 216.2189 289.6292 216.7010 294.1627 217.1832 299.0408 217.6653 304.1202 218.1474 309.1906 218.6295 314.0985 219.1116 318.9692 219.5937 322.7361 220.0759 322.8448 220.5580 328.3097 221.0401 350.6174 221.5222 382.4253 222.0043 408.5886 222.4864 417.8722 222.9686 415.7615 223.4507 420.1536 223.9328 436.1375 224.4149 450.1263 224.8970 449.6337 225.3791 441.0408 225.8613 439.2246 226.3434 459.5449 226.8255 496.8601 227.3076 520.0052 227.7897 520.1187 228.2719 516.4508 228.7540 517.5620 229.2361 522.8726 229.7182 530.2119 230.2003 538.4718 230.6824 547.6176 231.1646 557.2661 231.6467 569.1479 232.1288 579.5134 232.6109 584.4081 233.0930 585.9448 233.5751 590.1246 234.0573 602.9216 234.5394 624.6575 235.0215 644.5753 235.5036 663.7445 235.9857 679.7371 236.4678 689.2308 236.9500 694.0133 237.4321 699.5972 237.9142 712.2820 238.3963 733.4626 238.8784 748.5845 239.3605 744.0739 239.8427 744.9247 240.3248 766.5967 240.8069 804.5043 241.2890 840.2559 241.7711 853.7764 242.2532 839.3345 242.7354 837.2526 243.2175 860.8488 243.6996 885.2161 244.1817 897.9836 244.6638 900.6624 245.1459 903.7820 245.6281 919.1587 246.1102 950.4949 246.5923 975.4441 247.0744 985.2600 247.5565 996.4401 248.0386 1018.993 248.5208 1051.515 249.0029 1084.407 249.4850 1106.795 249.9671 1114.740 250.4492 1129.099 250.9313 1152.017 251.4135 1178.545 251.8956 1209.598 252.3777 1242.936 252.8598 1273.533 253.3419 1295.542 253.8240 1307.674 254.3062 1317.155 254.7883 1323.089 255.2704 1327.145 255.7525 1329.687 256.2346 1330.389 256.7167 1328.316 257.1989 1325.275 257.6810 1323.026 258.1631 1315.220 258.6452 1299.899 259.1273 1283.514 259.6094 1271.191 260.0916 1262.416 260.5737 1251.208 261.0558 1229.092 261.5379 1190.520 262.0200 1167.913 262.5021 1174.275 262.9843 1185.829 263.4664 1187.415 263.9485 1177.137 264.4306 1164.576 264.9127 1161.096 265.3948 1170.014 265.8770 1172.147 266.3591 1160.163 266.8412 1147.869 267.3233 1142.965 267.8054 1145.430 268.2875 1150.834 268.7697 1154.999 269.2518 1156.085 269.7339 1159.429 270.2160 1162.132 270.6981 1168.220 271.1802 1185.871 271.6624 1212.572 272.1445 1233.615 272.6266 1233.240 273.1087 1206.399 273.5908 1195.873 274.0729 1208.147 274.5551 1227.323 275.0372 1250.591 275.5193 1274.492 276.0014 1292.854 276.4835 1299.796 276.9656 1294.269 277.4478 1296.481 277.9299 1310.813 278.4120 1326.763 278.8941 1338.663 279.3762 1347.858 279.8583 1360.094 280.3405 1380.507 280.8226 1409.464 281.3047 1425.847 281.7868 1428.710 282.2689 1423.483 282.7510 1408.172 283.2332 1386.221 283.7153 1365.119 284.1974 1350.562 284.6795 1341.822 285.1616 1320.539 285.6437 1276.970 286.1259 1234.012 286.6080 1198.731 287.0901 1168.275 287.5722 1138.065 288.0543 1105.531 288.5364 1070.663 289.0186 1031.672 289.5007 988.3922 289.9828 942.3477 290.4649 888.9827 290.9471 834.2699 291.4292 788.6562 291.9113 758.3370 292.3934 739.3675 292.8755 712.7744 293.3576 664.7995 293.8398 625.5336 294.3219 603.4968 294.8040 591.7712 295.2861 580.4495 295.7682 564.6143 296.2503 546.7615 296.7325 534.9383 297.2146 540.9945 297.6967 538.7324 298.1788 520.0529 298.6609 494.3526 299.1430 472.8574 299.6252 460.4001 300.1073 452.4863 300.5894 438.2910 301.0715 404.2771 301.5536 382.3801 302.0357 383.0276 302.5179 391.0154 303.0000 392.7114 303.4821 383.6331 303.9642 366.7137 304.4463 346.7836 304.9284 317.0410 305.4106 296.0013 305.8927 288.4394 306.3748 285.6611 306.8569 282.3779 307.3390 277.0754 307.8211 268.7631 308.3033 254.3372 308.7854 223.8451 309.2675 212.3188 309.7496 242.6354 310.2317 271.5918 310.7138 266.5870 311.1960 227.3589 311.6781 180.5876 312.1602 157.1009 312.6423 165.0463 313.1244 165.2882 313.6065 156.6334 314.0887 142.5476 314.5708 120.4043 315.0529 93.18512 315.5350 68.50946 316.0171 53.48553 316.4992 48.61310 316.9814 47.91339 317.4635 59.20111 317.9456 67.07648 318.4277 64.28534 318.9098 53.77850 319.3919 42.75342 319.8741 36.23822 320.3562 34.03534 320.8383 33.70459 321.3204 36.17780 321.8025 39.78375 322.2846 39.96289 322.7668 41.66412 323.2489 56.49646 323.7310 95.18237 324.2131 145.4523 324.6952 154.0775 325.1773 84.59784 325.6595 26.23718 326.1416 0.2509770 326.6237 6.776245 327.1058 4.653076 327.5879 2.218018 328.0700 9.600708 328.5522 6.568604 329.0343 15.19543 329.5164 28.91687 329.9985 24.29144 330.4806 13.34338 330.9627 5.765320 331.4449 4.444397 331.9270 5.569702 332.4091 2.707397 332.8912 6.297485 333.3733 10.10394 333.8554 2.865662 334.3376 7.783875 334.8197 18.58160 335.3018 28.78522 335.7839 37.40503 336.2660 44.03864 336.7481 48.79120 337.2303 48.71698 337.7124 38.92853 338.1945 28.50165 338.6766 22.37073 339.1587 20.52771 339.6408 21.08221 340.1230 25.00702 340.6051 31.01794 341.0872 31.22443 341.5693 20.85388 342.0514 11.57721 342.5335 13.06781 343.0157 21.61041 343.4978 27.30121 343.9799 22.37372 344.4620 12.11053 344.9441 9.199402 345.4262 16.48199 345.9084 21.84674 346.3905 11.60883 346.8726 5.063782 347.3547 12.75116 347.8368 1.982178 348.3189 14.36707 348.8011 21.04840 349.2832 17.86340 349.7653 15.55621 350.2474 20.80170 350.7295 29.64001 351.2116 34.23120 351.6938 32.42493 352.1759 29.39606 352.6580 28.54657 353.1401 29.38257 353.6222 30.32880 354.1043 31.87323 354.5865 31.76691 355.0686 24.14050 355.5507 5.110229 356.0328 7.369324 356.5149 0.6691890 356.9970 17.90802 357.4792 23.04156 357.9613 9.316589 358.4434 10.36682 358.9255 18.90216 359.4076 14.36340 359.8897 9.823669 360.3719 6.958252 360.8540 4.537109 361.3361 1.387024 361.8182 2.629211 362.3003 7.333618 362.7824 13.68536 363.2646 22.33325 363.7467 21.54761 364.2288 3.863892 364.7109 15.53925 365.1930 29.37671 365.6751 37.96313 366.1573 44.57465 366.6394 51.46405 367.1215 58.18738 367.6036 60.07220 368.0857 49.47601 368.5678 42.90155 369.0500 42.27380 369.5321 48.08160 370.0142 63.56873 370.4963 90.42059 370.9784 122.1926 371.4605 141.5763 371.9427 135.2010 372.4248 135.6144 372.9069 144.4794 373.3890 159.7699 373.8712 183.5901 374.3533 215.0817 374.8354 245.1016 375.3175 259.7336 375.7996 251.4142 376.2817 250.1509 376.7639 257.1661 377.2460 269.5967 377.7281 287.5387 378.2102 310.2612 378.6923 335.9321 379.1744 362.6139 379.6566 390.4802 380.1387 422.7669 380.6208 460.6464 381.1029 502.2498 381.5850 548.0826 382.0671 596.4539 382.5493 644.3860 383.0314 689.9454 383.5135 733.6682 383.9956 776.1000 384.4777 815.7968 384.9598 863.8501 385.4420 927.2385 385.9241 1000.719 386.4062 1080.579 386.8883 1165.573 387.3704 1254.337 387.8525 1348.021 388.3347 1446.658 388.8168 1546.216 389.2989 1643.167 389.7810 1742.655 390.2631 1848.650 390.7452 1961.196 391.2274 2082.204 391.7095 2217.696 392.1916 2360.285 392.6737 2497.186 393.1558 2625.837 393.6379 2748.743 394.1201 2853.402 394.6022 2943.825 395.0843 3089.098 395.5664 3363.905 396.0485 3649.905 396.5306 3839.656 397.0128 3939.042 397.4949 4027.519 397.9770 4148.515 398.4591 4303.503 398.9412 4498.459 399.4233 4756.556 399.9055 5021.320 400.3876 5272.336 400.8697 5517.742 401.3518 5775.883 401.8339 6055.359 402.3160 6345.394 402.7982 6622.582 403.2803 6894.922 403.7624 7139.168 404.2445 7357.703 404.7266 7549.384 405.2087 7721.445 405.6909 7869.949 406.1730 7973.953 406.6551 8007.709 407.1372 7965.979 407.6193 7890.854 408.1014 7782.109 408.5836 7639.161 409.0657 7443.799 409.5478 7214.396 410.0299 6989.205 410.5120 6795.070 410.9941 6620.072 411.4763 6417.511 411.9584 6170.286 412.4405 5928.949 412.9226 5695.290 413.4047 5480.388 413.8868 5300.095 414.3690 5160.637 414.8511 5042.408 415.3332 4924.577 415.8153 4807.754 416.2974 4695.856 416.7795 4590.432 417.2617 4490.109 417.7438 4395.545 418.2259 4306.367 418.7080 4215.533 419.1901 4118.772 419.6722 4018.471 420.1544 3918.606 420.6365 3818.982 421.1186 3724.036 421.6007 3635.198 422.0828 3554.640 422.5649 3488.791 423.0471 3449.525 423.5292 3416.314 424.0113 3365.825 424.4934 3305.656 424.9755 3270.129 425.4576 3280.571 425.9398 3321.070 426.4219 3344.579 426.9040 3343.960 427.3861 3340.782 427.8682 3331.653 428.3503 3325.007 428.8325 3331.106 429.3146 3352.146 429.7967 3383.188 430.2788 3420.067 430.7609 3469.928 431.2430 3498.585 431.7252 3494.014 432.2073 3484.004 432.6894 3488.031 433.1715 3498.471 433.6536 3491.598 434.1357 3447.657 434.6179 3375.849 435.1000 3325.764 435.5821 3318.982 436.0642 3301.123 436.5463 3259.933 437.0284 3203.771 437.5106 3136.158 437.9927 3057.476 438.4748 2982.344 438.9569 2934.105 439.4390 2914.813 439.9211 2888.103 440.4033 2838.206 440.8854 2789.366 441.3675 2761.120 441.8496 2751.496 442.3317 2742.927 442.8138 2727.404 443.2960 2706.720 443.7781 2683.465 444.2602 2657.611 444.7423 2630.796 445.2244 2602.141 445.7065 2573.925 446.1887 2553.486 446.6708 2550.700 447.1529 2545.319 447.6350 2524.148 448.1171 2491.646 448.5992 2457.597 449.0814 2425.339 449.5635 2395.827 450.0456 2371.173 450.5277 2353.054 451.0098 2337.697 451.4919 2328.187 451.9741 2319.484 452.4562 2309.000 452.9383 2295.537 453.4204 2276.010 453.9025 2245.144 454.3847 2202.346 454.8668 2178.547 455.3489 2200.374 455.8310 2214.849 456.3131 2208.363 456.7953 2187.675 457.2774 2162.569 457.7595 2137.349 458.2416 2111.760 458.7237 2085.312 459.2058 2058.723 459.6880 2028.523 460.1701 1992.641 460.6522 1954.545 461.1343 1916.337 461.6164 1877.809 462.0985 1836.312 462.5807 1787.845 463.0628 1734.554 463.5449 1682.994 464.0270 1633.270 464.5091 1586.784 464.9912 1544.206 465.4734 1505.049 465.9555 1468.362 466.4376 1437.440 466.9197 1404.503 467.4018 1361.347 467.8839 1312.280 468.3661 1269.802 468.8482 1238.379 469.3303 1214.578 469.8124 1193.957 470.2945 1179.953 470.7766 1159.567 471.2588 1123.682 471.7409 1087.657 472.2230 1064.562 472.7051 1053.450 473.1872 1044.058 473.6693 1027.876 474.1515 1005.978 474.6336 990.7245 475.1157 986.8935 475.5978 984.5368 476.0799 979.6195 476.5620 976.3599 477.0442 981.1411 477.5263 996.0036 478.0084 1013.019 478.4905 1019.571 478.9726 1013.941 479.4547 1015.125 479.9369 1026.997 480.4190 1044.833 480.9011 1070.356 481.3832 1099.994 481.8653 1121.049 482.3474 1122.159 482.8296 1113.469 483.3117 1114.181 483.7938 1124.903 484.2759 1123.741 484.7580 1095.387 485.2401 1049.795 485.7223 1013.439 486.2044 992.8480 486.6865 968.1295 487.1686 933.0733 487.6507 889.6945 488.1328 837.6791 488.6150 777.8249 489.0971 719.3175 489.5792 672.8694 490.0613 641.0126 490.5434 605.2294 491.0255 565.8338 491.5077 523.1632 491.9898 471.5798 492.4719 418.2221 492.9540 375.8870 493.4361 351.9943 493.9182 336.6339 494.4004 306.3384 494.8825 252.6989 495.3646 207.8961 495.8467 180.6788 496.3288 160.7180 496.8109 144.5190 497.2931 130.8691 497.7752 116.4902 498.2573 96.27661 498.7394 74.00146 499.2215 61.72321 499.7036 62.17444 500.1858 60.63104 500.6679 46.29132 501.1500 24.66565 501.6321 8.812500 502.1142 1.793152 502.5963 3.598328 503.0785 11.08771 503.5606 19.47272 504.0427 27.01953 504.5248 33.27539 505.0069 37.55591 505.4890 38.78345 505.9712 36.14197 506.4533 34.25134 506.9354 31.56036 507.4175 31.04553 507.8996 34.62250 508.3817 41.35089 508.8639 49.77362 509.3460 59.32861 509.8281 68.74023 510.3102 75.04053 510.7923 78.16595 511.2744 78.17090 511.7566 69.61285 512.2387 62.14496 512.7208 64.67932 513.2029 75.81702 513.6851 83.46393 514.1672 76.66119 514.6493 60.52655 515.1314 48.19940 515.6135 40.16565 516.0956 34.46539 516.5778 29.96606 517.0599 27.28876 517.5420 27.66693 518.0241 33.08887 518.5062 37.87231 518.9883 40.94580 519.4705 41.38715 519.9526 36.34937 520.4347 25.37073 520.9168 13.75983 521.3989 7.448120 521.8810 7.299133 522.3632 5.207520 522.8453 2.330322 523.3274 3.406921 523.8095 15.98535 524.2916 31.04639 524.7737 41.08093 525.2559 42.69556 525.7380 41.46674 526.2201 47.90784 526.7022 64.20685 527.1843 77.75189 527.6664 87.35760 528.1486 93.31018 528.6307 92.67163 529.1128 87.89703 529.5949 87.70605 530.0770 94.50977 530.5591 109.2952 531.0413 136.5892 531.5234 175.8914 532.0055 214.5394 532.4876 247.9900 532.9697 276.8319 533.4518 300.6107 533.9340 314.7103 534.4161 337.4181 534.8982 374.6998 535.3803 420.5504 535.8624 472.4471 536.3445 528.5764 536.8267 583.4795 537.3088 633.1945 537.7909 678.4338 538.2730 726.4208 538.7551 773.9824 539.2372 829.6324 539.7194 898.3752 540.2015 973.2502 540.6836 1047.865 541.1657 1120.817 541.6478 1194.288 542.1299 1265.898 542.6121 1338.127 543.0942 1431.315 543.5763 1557.565 544.0584 1677.949 544.5405 1767.667 545.0226 1833.792 545.5048 1888.285 545.9869 1933.636 546.4690 1966.295 546.9511 1978.592 547.4332 1977.812 547.9153 1980.096 548.3975 1989.939 548.8796 1997.120 549.3617 1989.331 549.8438 1964.486 550.3259 1937.245 550.8080 1907.004 551.2902 1875.409 551.7723 1836.280 552.2544 1798.044 552.7365 1773.152 553.2186 1767.076 553.7007 1774.855 554.1829 1788.892 554.6650 1808.922 555.1471 1836.764 555.6292 1870.179 556.1113 1915.446 556.5934 1978.397 557.0756 2055.495 557.5577 2136.076 558.0398 2226.398 558.5219 2310.292 559.0040 2370.523 559.4861 2409.646 559.9683 2440.858 560.4504 2470.144 560.9325 2490.177 561.4146 2489.137 561.8967 2463.873 562.3788 2422.048 562.8610 2365.035 563.3431 2290.655 563.8252 2192.468 564.3073 2076.335 564.7894 1953.224 565.2715 1828.663 565.7537 1705.223 566.2358 1587.512 566.7179 1476.638 567.2000 1368.470 567.6821 1255.263 568.1642 1151.141 568.6464 1069.954 569.1285 1008.558 569.6106 947.4639 570.0927 873.7325 570.5748 795.2175 571.0569 721.8905 571.5391 653.7992 572.0212 596.2614 572.5033 552.6337 572.9854 519.1638 573.4675 489.2326 573.9496 463.3271 574.4318 438.1371 574.9139 411.5413 575.3960 386.6116 575.8781 362.9848 576.3602 342.5892 576.8423 331.3373 577.3245 334.1422 577.8066 346.4877 578.2887 352.7835 578.7708 349.9258 579.2529 348.5287 579.7350 344.2950 580.2172 346.4489 580.6993 361.8448 581.1814 390.3872 581.6635 426.7841 582.1456 470.8254 582.6277 518.7252 583.1099 564.4420 583.5920 608.1478 584.0741 651.9586 584.5562 693.9410 585.0383 740.2036 585.5204 805.2718 586.0026 897.9109 586.4847 986.9383 586.9668 1066.130 587.4489 1143.467 587.9310 1230.567 588.4131 1321.869 588.8953 1399.273 589.3774 1450.900 589.8595 1482.869 590.3416 1513.318 590.8237 1543.107 591.3058 1568.999 591.7880 1593.298 592.2701 1611.071 592.7522 1616.781 593.2343 1611.608 593.7164 1604.391 594.1985 1593.488 594.6807 1586.404 595.1628 1594.088 595.6449 1615.098 596.1270 1638.682 596.6091 1659.721 597.0912 1681.912 597.5734 1711.705 598.0555 1749.575 598.5376 1795.701 599.0197 1850.213 599.5018 1912.036 599.9839 1984.796 600.4661 2064.251 600.9482 2142.265 601.4303 2214.364 601.9124 2278.172 602.3945 2329.517 602.8766 2368.218 603.3588 2393.451 603.8409 2404.938 604.3230 2402.958 604.8051 2391.612 605.2872 2369.671 605.7693 2327.883 606.2515 2253.056 606.7336 2170.791 607.2157 2094.629 607.6978 2027.075 608.1799 1977.040 608.6620 1948.204 609.1442 1928.502 609.6263 1897.165 610.1084 1848.340 610.5905 1815.538 611.0726 1796.627 611.5547 1795.325 612.0369 1820.818 612.5190 1861.180 613.0011 1897.477 613.4832 1921.984 613.9653 1953.496 614.4474 2016.252 614.9296 2107.753 615.4117 2209.444 615.8938 2322.593 616.3759 2434.811 616.8580 2529.705 617.3401 2614.906 617.8223 2721.466 618.3044 2884.752 618.7865 3027.477 619.2686 3114.968 619.7507 3168.892 620.2328 3217.507 620.7150 3265.942 621.1971 3301.436 621.6792 3312.903 622.1613 3299.963 622.6434 3261.837 623.1255 3179.734 623.6077 3107.002 624.0898 3066.334 624.5719 3035.737 625.0540 2994.198 625.5361 2939.105 626.0182 2877.100 626.5004 2815.473 626.9825 2748.280 627.4646 2662.294 627.9467 2556.767 628.4288 2447.961 628.9109 2344.477 629.3931 2244.200 629.8752 2142.665 630.3573 2037.143 630.8394 1934.102 631.3215 1837.117 631.8036 1738.937 632.2858 1637.625 632.7679 1530.847 633.2500 1413.440 633.7321 1279.633 634.2142 1141.502 634.6964 1024.318 635.1785 929.0159 635.6606 836.0989 636.1427 740.9382 636.6248 648.7180 637.1069 561.3598 637.5891 479.5009 638.0712 410.4769 638.5533 359.5961 639.0354 317.4967 639.5175 281.3244 639.9996 249.5616 640.4818 219.6512 640.9639 190.6476 641.4460 164.2483 641.9281 142.6730 642.4102 126.1232 642.8923 110.2312 643.3745 94.34195 643.8566 80.09000 644.3387 67.52502 644.8208 56.82327 645.3029 48.17432 645.7850 41.62024 646.2672 37.19617 646.7493 36.07852 647.2314 36.61575 647.7135 36.91925 648.1956 36.62967 648.6777 33.38602 649.1599 25.11517 649.6420 14.13242 650.1241 7.099915 650.6062 7.368286 651.0883 6.208435 651.5704 1.174530 652.0526 2.982391 652.5347 2.333557 653.0168 1.528381 653.4989 4.228424 653.9810 3.541107 654.4631 0.6304630 654.9453 4.800690 655.4274 12.15540 655.9095 11.73303 656.3916 1.904846 656.8737 14.27051 657.3558 10.62601 657.8380 8.565582 658.3201 23.29785 658.8022 34.23630 659.2843 39.97052 659.7665 36.47784 660.2486 29.29349 660.7307 24.77139 661.2128 24.15387 661.6949 26.00992 662.1771 34.94949 662.6592 44.96741 663.1413 11.14999 663.6234 88.42184 664.1055 163.0810 664.5876 177.7318 665.0698 154.0012 665.5519 107.2112 666.0340 34.10519 666.5161 6.804230 666.9982 37.90067 667.4803 91.87460 667.9625 85.07715 668.4446 34.35178 668.9267 8.307526 669.4088 20.56351 669.8909 15.36588 670.3730 12.77191 670.8552 13.73010 671.3373 12.32388 671.8194 5.527069 672.3015 0.2980960 672.7836 0.6020510 673.2657 1.739746 673.7479 6.643829 674.2300 15.05969 674.7121 21.14615 675.1942 20.53088 675.6763 15.53345 676.1584 8.366425 676.6406 0.1629640 677.1227 6.395447 677.6048 7.939087 678.0869 5.601471 678.5690 1.287018 679.0511 11.59299 679.5333 13.81808 680.0154 9.169067 680.4975 29.21506 680.9796 25.12048 681.4617 5.560028 681.9438 4.086395 682.4260 11.90427 682.9081 31.69513 683.3902 29.34894 683.8723 11.24737 684.3544 2.081940 684.8365 6.584351 685.3187 5.163544 685.8008 0.6826170 686.2829 10.41449 686.7650 17.69724 687.2471 21.90158 687.7292 24.39505 688.2114 23.01791 688.6935 21.57910 689.1756 25.43503 689.6577 33.10065 690.1398 35.78091 690.6219 23.54260 691.1041 7.092865 691.5862 6.990234 692.0683 21.67303 692.5504 32.51053 693.0325 33.27490 693.5146 31.72849 693.9968 37.69052 694.4789 52.43671 694.9610 58.72632 695.4431 49.05481 695.9252 40.68762 696.4073 40.76160 696.8895 43.52225 697.3716 40.61163 697.8537 31.55338 698.3358 25.35489 698.8179 32.91489 699.3000 48.39594 699.7822 54.88831 700.2643 52.02002 700.7464 45.74664 701.2285 36.03732 701.7106 27.58173 702.1927 28.59793 702.6749 42.32404 703.1570 49.68777 703.6391 44.78543 704.1212 39.79990 704.6033 40.15796 705.0854 43.62814 705.5676 47.01053 706.0497 49.29752 706.5318 50.81219 707.0139 51.57758 707.4960 51.78546 707.9781 51.96011 708.4603 51.99384 708.9424 53.49573 709.4245 58.82727 709.9066 64.06311 710.3887 61.49460 710.8708 48.16977 711.3530 39.39853 711.8351 36.55356 712.3172 37.96976 712.7993 44.49179 713.2814 53.63690 713.7635 63.91434 714.2457 75.26917 714.7278 82.90640 715.2099 79.63089 715.6920 67.10861 716.1741 56.18286 716.6563 47.43842 717.1384 41.54550 717.6205 40.20364 718.1026 41.89636 718.5847 43.19501 719.0668 44.32684 719.5490 43.35629 720.0311 37.22546 720.5132 30.84821 720.9953 31.06961 721.4774 34.33920 721.9595 34.24329 722.4417 28.68689 722.9238 24.13226 723.4059 30.08081 723.8880 44.21216 724.3701 54.30960 724.8522 61.51694 725.3344 62.39853 725.8165 53.00076 726.2986 38.55576 726.7807 30.20660 727.2628 30.98376 727.7449 30.97327 728.2271 29.33768 728.7092 26.48056 729.1913 21.34415 729.6734 16.11884 730.1555 13.74289 730.6376 15.08868 731.1198 18.96954 731.6019 25.86215 732.0840 34.13824 732.5661 38.26782 733.0482 38.10043 733.5303 37.25964 734.0125 37.85956 734.4946 38.80353 734.9767 37.11517 735.4588 31.41278 735.9409 25.43732 736.4230 14.19482 736.9052 6.964539 737.3873 12.55847 737.8694 26.19482 738.3515 37.45163 738.8336 43.11984 739.3157 44.94287 739.7979 42.63431 740.2800 38.67316 740.7621 37.35336 741.2442 38.70786 741.7263 36.67496 742.2084 26.83313 742.6906 14.17422 743.1727 9.190765 743.6548 16.41510 744.1369 19.06992 744.6190 10.74017 745.1011 4.846436 745.5833 9.458313 746.0654 18.19623 746.5475 21.45581 747.0296 16.78363 747.5117 11.35211 747.9938 10.14371 748.4760 11.68494 748.9581 14.75214 749.4402 18.82370 749.9223 21.19138 750.4044 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81.61200 804.4015 59.96536 804.8836 142.1374 805.3657 216.2675 805.8478 192.6005 806.3300 124.2332 806.8121 81.51306 807.2942 72.08377 807.7763 73.99750 808.2584 73.90063 808.7405 73.87067 809.2227 80.28244 809.7048 93.58752 810.1869 97.49039 810.6690 87.64209 811.1511 77.31744 811.6332 73.95630 812.1154 75.29013 812.5975 76.31665 813.0796 77.09149 813.5617 77.46069 814.0438 78.09665 814.5259 78.03146 815.0081 76.67444 815.4902 74.53574 815.9723 71.24179 816.4544 66.75259 816.9365 64.34796 817.4186 67.46155 817.9008 73.70108 818.3829 82.07510 818.8650 91.12418 819.3471 94.23117 819.8292 89.40610 820.3113 79.27396 820.7935 64.47028 821.2756 46.68927 821.7577 44.96878 822.2398 65.22165 822.7219 85.15771 823.2040 103.4792 823.6862 116.2818 824.1683 117.7720 824.6505 110.6746 825.1326 106.2496 825.6147 105.7219 826.0968 107.6354 826.5789 111.1089 827.0610 116.7705 827.5432 126.2407 828.0253 137.4805 828.5074 146.4870 828.9895 154.0191 829.4716 158.7686 829.9537 158.6949 830.4359 155.9559 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