#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:38:12 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1202 $ #$URL: svn://172.16.1.111/rod/cif/1/00/06/1000616.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000616 loop_ _publ_author_name 'Tait, K. T.' 'Yang, H.' 'Downs, R. T.' 'Li, C.' 'Pinch, W. W.' _publ_section_title ; The crystal structure of esperite, with a revised chemical formula, PbCa2(ZnSiO4)3, isostructural with beryllonite ; _journal_name_full 'American Mineralogist' _journal_page_first 699 _journal_page_last 705 _journal_paper_doi 10.2138/am.2010.3415 _journal_volume 95 _journal_year 2010 _chemical_compound_source '3 Franklin, New Jersey, USA' _chemical_formula_sum 'Ca2 O12 Pb Si3 Zn3' _chemical_name_mineral Esperite _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90 _cell_angle_beta 90.050 _cell_angle_gamma 90 _cell_length_a 8.7889 _cell_length_b 8.2685 _cell_length_c 15.2535 _cell_volume 1108.487 _exptl_crystal_density_diffrn 4.553 _cod_original_formula_sum 'Pb Ca2 Zn3 Si3 O12' _cod_database_code 9016115 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R060299.rod _rod_data_source.block 3500000 _rod_database.code 1000616 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9016115 COD http://www.crystallography.net/cod/9016115.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 108.7288 0.0000000E+00 109.2109 2.1970000E-03 109.6931 3.481445 110.1752 6.153564 110.6573 6.586182 111.1394 3.604980 111.6215 0.5593260 112.1036 0.7065430 112.5858 0.2866210 113.0679 1.051270 113.5500 1.215820 114.0321 1.337891 114.5142 1.865234 114.9964 2.889648 115.4785 3.771729 115.9606 3.963135 116.4427 3.530762 116.9248 3.615479 117.4069 4.906738 117.8891 6.854980 118.3712 8.359863 118.8533 9.235107 119.3354 9.495361 119.8175 8.714111 120.2996 7.001465 120.7818 6.061279 121.2639 7.796631 121.7460 12.33862 122.2281 15.63159 122.7102 15.46289 123.1923 15.29419 123.6745 16.51758 124.1566 18.88843 124.6387 21.73315 125.1208 23.09448 125.6029 20.96997 126.0850 21.19287 126.5672 25.21875 127.0493 31.03979 127.5314 36.99707 128.0135 42.55151 128.4956 48.33887 128.9777 55.37695 129.4599 65.79321 129.9420 75.05957 130.4241 82.74854 130.9062 89.04980 131.3883 94.36548 131.8704 98.81152 132.3526 102.0635 132.8347 101.9844 133.3168 99.40479 133.7989 93.69604 134.2810 82.94458 134.7632 68.02173 135.2453 53.34155 135.7274 41.53394 136.2095 32.62012 136.6916 24.74780 137.1737 15.72559 137.6559 8.045898 138.1380 5.489258 138.6201 9.114990 139.1022 12.87280 139.5843 12.48413 140.0664 10.00659 140.5486 8.129883 141.0307 8.214844 141.5128 10.38501 141.9949 15.48755 142.4770 24.39990 142.9591 30.08862 143.4413 31.62817 143.9234 30.45410 144.4055 28.47803 144.8876 27.01270 145.3697 26.31934 145.8518 25.30469 146.3340 24.33936 146.8161 22.91772 147.2982 20.05347 147.7803 16.49438 148.2624 13.83472 148.7445 13.52832 149.2267 16.63965 149.7088 18.24219 150.1909 17.24487 150.6730 15.84277 151.1551 15.53857 151.6372 16.43921 152.1194 17.49976 152.6015 17.32251 153.0836 14.98486 153.5657 14.02148 154.0478 15.17505 154.5299 17.33130 155.0121 19.28223 155.4942 20.71899 155.9763 22.41577 156.4584 25.76050 156.9405 30.75879 157.4226 35.86694 157.9048 41.15479 158.3869 46.34546 158.8690 50.73926 159.3511 54.41577 159.8332 56.67261 160.3153 56.70825 160.7975 54.54932 161.2796 51.49658 161.7617 48.89526 162.2438 46.53198 162.7259 41.67505 163.2081 30.52612 163.6902 19.18433 164.1723 12.08740 164.6544 9.608398 165.1365 9.857666 165.6186 11.26270 166.1008 14.14331 166.5829 17.37964 167.0650 19.24072 167.5471 21.30200 168.0292 25.08154 168.5113 30.82666 168.9935 36.83594 169.4756 40.33154 169.9577 40.83374 170.4398 39.33081 170.9219 35.77417 171.4040 30.70850 171.8862 23.93481 172.3683 15.49902 172.8504 6.595947 173.3325 6.5919999E-03 173.8146 1.835938 174.2967 3.942627 174.7789 7.723877 175.2610 11.44092 175.7431 12.62061 176.2252 10.06116 176.7073 5.141602 177.1894 2.445068 177.6716 3.669434 178.1537 4.747559 178.6358 5.168457 179.1179 4.914307 179.6000 3.987671 180.0821 2.379150 180.5643 6.6040002E-02 181.0464 3.058960 181.5285 8.155884 182.0106 12.33203 182.4927 13.69543 182.9748 12.76270 183.4570 11.77356 183.9391 11.51562 184.4212 12.13916 184.9033 13.84399 185.3854 17.62183 185.8675 20.85071 186.3497 20.35608 186.8318 15.98975 187.3139 13.25891 187.7960 15.98218 188.2781 21.16663 188.7602 25.79822 189.2424 29.43713 189.7245 32.11475 190.2066 32.83105 190.6887 30.15100 191.1708 30.90332 191.6530 39.88452 192.1351 52.13599 192.6172 63.78052 193.0993 73.40601 193.5814 81.82886 194.0635 90.94116 194.5457 102.4579 195.0278 110.8922 195.5099 115.8281 195.9920 117.4984 196.4741 115.7465 196.9562 110.3744 197.4384 102.2919 197.9205 94.02258 198.4026 85.61914 198.8847 76.93604 199.3668 66.86401 199.8489 56.89014 200.3311 48.74438 200.8132 43.33252 201.2953 40.12878 201.7774 37.11450 202.2595 33.67188 202.7416 31.14221 203.2238 29.76306 203.7059 29.36243 204.1880 29.72168 204.6701 30.75427 205.1522 32.36914 205.6343 34.26453 206.1165 38.05823 206.5986 40.34143 207.0807 38.96692 207.5628 35.63257 208.0449 33.48254 208.5270 34.17859 209.0092 37.32422 209.4913 41.21716 209.9734 46.45532 210.4555 51.51428 210.9376 55.92993 211.4197 59.75940 211.9019 63.31775 212.3840 67.03528 212.8661 70.17224 213.3482 70.94055 213.8303 68.39624 214.3124 65.25403 214.7946 62.29016 215.2767 59.71716 215.7588 59.00415 216.2409 61.87866 216.7230 66.23853 217.2052 68.05420 217.6873 66.23474 218.1694 64.09082 218.6515 64.31396 219.1336 66.81873 219.6157 69.22632 220.0979 70.12109 220.5800 70.87549 221.0621 73.09167 221.5442 77.20471 222.0263 81.68567 222.5084 84.81860 222.9906 86.45764 223.4727 88.89807 223.9548 93.18738 224.4369 98.40723 224.9190 103.6830 225.4011 108.8363 225.8833 114.8928 226.3654 123.5233 226.8475 135.2832 227.3296 146.7622 227.8117 156.2656 228.2938 165.8474 228.7760 177.1494 229.2581 190.4489 229.7402 203.8761 230.2223 215.0703 230.7044 223.8157 231.1865 230.6479 231.6687 238.0829 232.1508 242.2590 232.6329 240.1737 233.1150 231.4580 233.5971 218.3893 234.0792 203.4655 234.5614 185.1497 235.0435 169.2827 235.5256 155.1310 236.0077 143.2161 236.4898 134.6277 236.9719 129.2957 237.4541 125.6388 237.9362 121.4811 238.4183 116.1874 238.9004 112.2112 239.3825 111.9258 239.8646 110.9308 240.3468 105.9752 240.8289 96.82910 241.3110 85.91858 241.7931 75.93152 242.2752 66.68677 242.7573 59.51367 243.2395 55.48901 243.7216 52.40234 244.2037 48.98425 244.6858 44.99280 245.1679 40.71423 245.6501 36.28528 246.1322 31.20508 246.6143 28.70618 247.0964 31.30432 247.5785 34.29163 248.0606 34.27588 248.5428 31.13098 249.0249 27.25940 249.5070 25.07605 249.9891 24.92358 250.4712 23.67786 250.9533 19.97534 251.4355 16.31470 251.9176 14.65894 252.3997 14.95825 252.8818 15.50574 253.3639 14.98853 253.8460 13.30798 254.3282 11.23352 254.8103 7.921387 255.2924 4.893799 255.7745 3.088257 256.2566 2.535156 256.7387 3.134888 257.2209 5.531738 257.7030 9.375732 258.1851 11.69116 258.6672 10.53906 259.1493 9.076660 259.6314 9.591553 260.1136 11.89453 260.5957 14.13611 261.0778 15.43640 261.5599 15.87122 262.0420 15.97888 262.5241 15.75085 263.0063 15.11865 263.4884 13.10364 263.9705 10.02454 264.4526 8.677368 264.9347 11.70972 265.4168 16.26282 265.8990 16.75708 266.3811 11.50293 266.8632 5.809082 267.3453 3.608521 267.8274 4.511963 268.3095 5.489502 268.7917 5.274902 269.2738 4.869629 269.7559 5.561523 270.2380 7.497803 270.7201 9.895386 271.2022 12.75659 271.6844 15.87793 272.1665 17.74487 272.6486 17.31458 273.1307 16.15027 273.6128 15.95837 274.0949 16.73145 274.5771 17.39465 275.0592 16.81421 275.5413 15.32764 276.0234 14.87195 276.5055 15.71008 276.9876 17.81128 277.4698 21.69116 277.9519 26.90112 278.4340 31.22009 278.9161 32.73682 279.3982 32.09424 279.8803 32.16113 280.3625 33.05884 280.8446 34.81409 281.3267 38.43140 281.8088 42.86304 282.2909 45.59436 282.7730 44.43188 283.2552 40.55078 283.7373 37.96326 284.2194 37.49182 284.7015 36.76160 285.1836 33.73950 285.6658 29.91663 286.1479 27.64490 286.6300 28.41064 287.1121 30.96484 287.5942 32.38928 288.0764 32.03882 288.5585 32.09143 289.0406 34.11023 289.5227 36.61572 290.0048 37.85657 290.4869 37.03479 290.9691 35.44409 291.4512 35.37024 291.9333 37.26929 292.4154 39.28687 292.8975 41.29260 293.3796 43.04175 293.8618 43.95752 294.3439 43.90491 294.8260 44.13989 295.3081 47.05640 295.7902 53.76025 296.2723 57.84656 296.7545 55.86865 297.2366 52.57324 297.7187 49.69238 298.2008 47.74231 298.6829 47.49658 299.1650 50.54443 299.6472 57.37939 300.1293 62.74280 300.6114 65.92334 301.0935 67.74207 301.5756 67.66772 302.0577 66.30945 302.5399 65.40552 303.0220 66.70789 303.5041 70.07458 303.9862 72.25818 304.4683 72.51196 304.9504 72.36157 305.4326 73.15808 305.9147 73.94861 306.3968 72.92712 306.8789 68.82751 307.3610 62.19568 307.8431 55.38672 308.3253 48.42871 308.8074 41.24426 309.2895 32.77466 309.7716 24.42188 310.2537 18.17163 310.7358 14.98926 311.2180 13.62842 311.7001 11.23572 312.1822 6.814087 312.6643 3.518188 313.1464 3.125977 313.6285 3.235840 314.1107 1.561768 314.5928 2.453247 315.0749 6.983032 315.5570 9.481079 316.0391 9.684570 316.5212 8.841187 317.0034 5.374634 317.4855 2.186768 317.9676 1.022827 318.4497 1.915894 318.9318 3.625732 319.4139 5.430054 319.8961 7.530762 320.3782 7.675781 320.8603 3.348145 321.3424 0.6767580 321.8245 2.216431 322.3066 1.937134 322.7888 1.786133 323.2709 3.321045 323.7530 6.213745 324.2351 8.072876 324.7172 7.726196 325.1993 7.751221 325.6815 8.975830 326.1636 11.07312 326.6457 13.39771 327.1278 15.47668 327.6099 18.01123 328.0920 23.24731 328.5742 33.61169 329.0563 41.10913 329.5384 41.43970 330.0205 39.93787 330.5026 41.35474 330.9847 46.99524 331.4669 54.20984 331.9490 59.12317 332.4311 60.89258 332.9132 63.57666 333.3953 69.06396 333.8774 74.87146 334.3596 79.30310 334.8417 82.45898 335.3238 85.96912 335.8059 91.19165 336.2880 98.14343 336.7701 106.2513 337.2523 115.5583 337.7344 126.1580 338.2165 139.1106 338.6986 153.3387 339.1807 166.5612 339.6628 177.2198 340.1450 185.8279 340.6271 194.2950 341.1092 202.3488 341.5913 210.7545 342.0735 219.2769 342.5556 228.4343 343.0377 238.9603 343.5198 251.1826 344.0019 264.7242 344.4840 278.7532 344.9662 293.1427 345.4483 308.9664 345.9304 326.5857 346.4125 345.9363 346.8946 367.1010 347.3767 390.2202 347.8589 414.9438 348.3410 440.3149 348.8231 466.4952 349.3052 496.0719 349.7873 530.7607 350.2694 567.8651 350.7516 606.5496 351.2337 646.1898 351.7158 683.7031 352.1979 718.1025 352.6800 749.2031 353.1621 776.8057 353.6443 802.2664 354.1264 820.6587 354.6085 829.3438 355.0906 829.5667 355.5727 821.9648 356.0548 806.6594 356.5370 783.7804 357.0191 751.9125 357.5012 710.6758 357.9833 666.9692 358.4654 622.9032 358.9475 578.2134 359.4297 532.6169 359.9118 485.6497 360.3939 439.2816 360.8760 392.5848 361.3581 346.9885 361.8402 309.5615 362.3224 284.6477 362.8045 264.6700 363.2866 241.1951 363.7687 214.7401 364.2508 190.4747 364.7329 170.6754 365.2151 154.1726 365.6972 139.1039 366.1793 125.2688 366.6614 112.7397 367.1435 101.7244 367.6256 92.12219 368.1078 83.66956 368.5899 77.20728 369.0720 71.11304 369.5541 63.45068 370.0362 54.62451 370.5183 47.53186 371.0005 43.97949 371.4826 42.67554 371.9647 40.57349 372.4468 37.30933 372.9289 33.63782 373.4110 30.18103 373.8932 26.78149 374.3753 22.72644 374.8574 17.81982 375.3395 13.32935 375.8216 10.99878 376.3037 10.96069 376.7859 10.56726 377.2680 9.398560 377.7501 7.856201 378.2322 6.285889 378.7143 5.029663 379.1964 4.307251 379.6786 4.281860 380.1607 4.782715 380.6428 4.100464 381.1249 3.797190 381.6070 1.984863 382.0891 2.363647 382.5713 1.275879 383.0534 0.3123780 383.5355 0.1324460 384.0176 0.5305180 384.4997 1.100098 384.9818 2.245117 385.4640 2.852051 385.9461 2.106934 386.4282 1.291626 386.9103 1.771729 387.3924 3.589966 387.8745 5.594238 388.3567 6.611084 388.8388 6.630371 389.3209 5.619141 389.8030 2.302979 390.2851 0.5858150 390.7672 1.635132 391.2494 1.483398 391.7315 1.299194 392.2136 1.679199 392.6957 2.874268 393.1778 5.974121 393.6599 13.37463 394.1421 19.28833 394.6242 22.32983 395.1063 24.27710 395.5884 26.20227 396.0706 28.58228 396.5527 32.00830 397.0348 37.61902 397.5169 46.10864 397.9990 53.86621 398.4811 62.27344 398.9633 68.53552 399.4454 71.18848 399.9275 70.67834 400.4096 68.32520 400.8917 64.90381 401.3738 60.40820 401.8560 54.74438 402.3381 47.65271 402.8202 39.84973 403.3023 30.00073 403.7844 20.34436 404.2665 13.43494 404.7487 10.12354 405.2308 8.453735 405.7129 5.574951 406.1950 1.261963 406.6771 0.1420900 407.1592 4.504639 407.6414 9.925171 408.1235 12.80261 408.6056 13.16394 409.0877 11.76599 409.5698 7.336060 410.0519 1.690063 410.5341 0.8612060 411.0162 7.7147998E-02 411.4983 2.995361 411.9804 7.894287 412.4625 14.00818 412.9446 19.97192 413.4268 24.98547 413.9089 30.77698 414.3910 39.31140 414.8731 50.01880 415.3552 60.06189 415.8373 68.25891 416.3195 75.88599 416.8016 85.99890 417.2837 99.16357 417.7658 108.0500 418.2479 109.2737 418.7300 105.9800 419.2122 101.6144 419.6943 96.55566 420.1764 89.48267 420.6585 78.40869 421.1406 64.04065 421.6227 54.41125 422.1049 52.15698 422.5870 51.08948 423.0691 48.92896 423.5512 46.23425 424.0333 44.00452 424.5154 42.63464 424.9976 42.10876 425.4797 42.38464 425.9618 43.23254 426.4439 45.61719 426.9260 51.37585 427.4081 57.23047 427.8903 60.39783 428.3724 61.20129 428.8545 62.16357 429.3366 65.41467 429.8187 70.87781 430.3008 76.15283 430.7830 83.15259 431.2651 87.74622 431.7472 88.69946 432.2293 87.08899 432.7114 84.02014 433.1935 79.93701 433.6757 74.87927 434.1578 68.73401 434.6399 61.08496 435.1220 53.81433 435.6041 45.43579 436.0862 38.90039 436.5684 36.43701 437.0505 37.28467 437.5326 38.69702 438.0147 38.42639 438.4968 37.38757 438.9789 39.46765 439.4611 46.44922 439.9432 51.98108 440.4253 50.94421 440.9074 48.30908 441.3895 49.18848 441.8716 54.72729 442.3538 62.36267 442.8359 69.81409 443.3180 77.68127 443.8001 88.38013 444.2822 103.6882 444.7643 119.5382 445.2465 130.8170 445.7286 138.5903 446.2107 148.1716 446.6928 162.3088 447.1749 178.5400 447.6570 194.3232 448.1392 209.5608 448.6213 225.1403 449.1034 241.4388 449.5855 258.5061 450.0677 276.5549 450.5498 295.8134 451.0319 315.0688 451.5140 333.0425 451.9961 351.2953 452.4782 371.8687 452.9604 395.0905 453.4425 419.3748 453.9246 443.1838 454.4067 466.4719 454.8888 489.7076 455.3709 514.5190 455.8531 537.4380 456.3352 555.3691 456.8173 570.8959 457.2994 588.0063 457.7815 608.4741 458.2636 632.2683 458.7458 658.9694 459.2279 685.8389 459.7100 722.1929 460.1921 770.0702 460.6742 824.6329 461.1563 884.6174 461.6385 949.1401 462.1206 1016.147 462.6027 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995.3419 385.9277 995.8240 414.0779 996.3062 440.9752 996.7883 473.0088 997.2704 512.3019 997.7525 553.7761 998.2346 597.7258 998.7167 642.8552 999.1989 687.2919 999.6810 733.6228 1000.163 785.0422 1000.645 841.8043 1001.127 900.0166 1001.609 957.0876 1002.092 1018.267 1002.574 1085.971 1003.056 1158.655 1003.538 1232.771 1004.020 1310.755 1004.502 1397.944 1004.984 1494.871 1005.466 1595.670 1005.948 1693.602 1006.431 1798.074 1006.913 1916.587 1007.395 2045.448 1007.877 2184.882 1008.359 2329.123 1008.841 2468.143 1009.323 2598.240 1009.805 2716.296 1010.288 2823.554 1010.770 2911.264 1011.252 2973.578 1011.734 3005.722 1012.216 2997.906 1012.698 2950.718 1013.180 2867.715 1013.662 2751.015 1014.144 2609.503 1014.627 2444.893 1015.109 2267.887 1015.591 2100.182 1016.073 1940.040 1016.555 1779.849 1017.037 1619.832 1017.519 1467.035 1018.001 1325.487 1018.484 1195.847 1018.966 1080.024 1019.448 977.2910 1019.930 884.5659 1020.412 802.2505 1020.894 730.4121 1021.376 669.2694 1021.858 614.2268 1022.340 562.5928 1022.823 516.1799 1023.305 477.7413 1023.787 446.9812 1024.269 420.9780 1024.751 399.8661 1025.233 379.2629 1025.715 358.1926 1026.197 338.4677 1026.680 321.2858 1027.162 306.0355 1027.644 291.4644 1028.126 280.3518 1028.608 267.5312 1029.090 262.3270 1029.572 257.4370 1030.054 251.7445 1030.536 246.7205 1031.019 243.1564 1031.501 241.1558 1031.983 240.8577 1032.465 242.2104 1032.947 245.7308 1033.429 251.8464 1033.911 258.8662 1034.393 265.5884 1034.875 274.7966 1035.358 289.6055 1035.840 307.5522 1036.322 323.0597 1036.804 335.3846 1037.286 346.6852 1037.768 356.5204 1038.250 366.7145 1038.732 377.4515 1039.215 388.4330 1039.697 400.2040 1040.179 411.7834 1040.661 420.2550 1041.143 424.4503 1041.625 430.8748 1042.107 441.9645 1042.589 451.9033 1043.072 457.4968 1043.554 462.5227 1044.036 470.6771 1044.518 480.6753 1045.000 488.0609 1045.482 490.7789 1045.964 497.3561 1046.446 514.9617 1046.928 528.0229 1047.411 530.5303 1047.893 529.0891 1048.375 529.7937 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160.1913 1075.855 152.7029 1076.338 145.2863 1076.820 137.6227 1077.302 128.5085 1077.784 116.9612 1078.266 104.0576 1078.748 88.73132 1079.230 73.83569 1079.712 64.05859 1080.194 59.32434 1080.677 54.87866 1081.159 48.75305 1081.641 43.10681 1082.123 39.96021 1082.605 36.67859 1083.087 30.71191 1083.569 23.83813 1084.052 18.13245 1084.534 13.95679 1085.016 11.33093 1085.498 10.75146 1085.980 10.23938 1086.462 8.681519 1086.944 7.157104 1087.426 6.839844 1087.908 6.622925 1088.391 3.992310 1088.873 0.1855470 1089.355 0.1749270 1089.837 6.226318 1090.319 12.42883 1090.801 17.44836 1091.283 20.79102 1091.765 23.82544 1092.247 23.74866 1092.730 14.42493 1093.212 0.1170650 1093.694 7.321167 1094.176 4.287354 1094.658 1.520874 1095.140 4.787231 1095.622 6.626587 1096.104 1.600830 1096.587 4.401245 1097.069 7.066650 1097.551 6.406494 1098.033 2.757690 1098.515 3.974243 1098.997 10.09448 1099.479 16.67615 1099.961 19.45581 1100.443 13.14990 1100.926 6.545776 1101.408 7.278076 1101.890 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