#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:41:23 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1229 $ #$URL: svn://172.16.1.111/rod/cif/1/00/06/1000641.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_1000641 loop_ _publ_author_name 'Tait, K. T.' 'Barkley, M. C.' 'Thompson, R. M.' 'Origlieri, M. J.' 'Evans, S. H.' 'Prewitt, C. T.' 'Yang, H.' _publ_section_title ; Bobdownsite, a new mineral species from Big Fish River, Yukon, Canada, and its structural relationship with whitlockite-type compounds Sample number R070654 ; _journal_name_full 'The Canadian Mineralogist' _journal_page_first 1065 _journal_page_last 1078 _journal_paper_doi 10.3749/canmin.49.4.1065 _journal_volume 49 _journal_year 2011 _chemical_compound_source '3 Tip Top mine South Dakota USA' _chemical_formula_sum 'Al0.04 Ca9 F0.84 H0.16 Mg0.96 O27.16 P6.97' _chemical_name_mineral Bobdownsite _space_group_IT_number 161 _symmetry_space_group_name_Hall 'R 3 -2"c' _symmetry_space_group_name_H-M 'R 3 c :H' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 120 _cell_length_a 10.3394 _cell_length_b 10.3394 _cell_length_c 37.0836 _cell_volume 3433.232 _exptl_crystal_density_diffrn 3.052 _cod_original_sg_symbol_H-M 'R 3 c' _cod_original_formula_sum 'Ca9 (Mg.96 Al.04) P6.97 O27.16 (F.84 H.16)' _cod_database_code 9014798 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R070654.rod _rod_data_source.block 3500000 _rod_database.code 1000641 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9014798 COD http://www.crystallography.net/cod/9014798.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 118.2109 0.0000000E+00 118.6931 81.36475 119.1752 79.88965 119.6573 18.18359 120.1394 9.204590 120.6215 5.509277 121.1036 18.93018 121.5858 59.65479 122.0679 115.8945 122.5500 149.1821 123.0321 141.3081 123.5142 132.8892 123.9963 143.8462 124.4785 172.8628 124.9606 203.6475 125.4427 218.4033 125.9248 212.5918 126.4069 227.2407 126.8890 273.1445 127.3712 335.2363 127.8533 398.2715 128.3354 459.9639 128.8175 522.1421 129.2996 590.8198 129.7817 665.8481 130.2639 734.3564 130.7460 785.3413 131.2281 824.1104 131.7102 871.7417 132.1923 934.7178 132.6744 1008.453 133.1566 1092.413 133.6387 1189.368 134.1208 1276.963 134.6029 1334.983 135.0850 1361.684 135.5671 1369.285 136.0493 1327.393 136.5314 1284.635 137.0135 1283.331 137.4956 1341.341 137.9777 1429.021 138.4598 1482.439 138.9420 1481.750 139.4241 1478.220 139.9062 1480.704 140.3883 1487.508 140.8704 1494.281 141.3525 1496.685 141.8347 1497.479 142.3168 1525.216 142.7989 1599.137 143.2810 1682.696 143.7631 1777.832 144.2452 1877.289 144.7274 1968.325 145.2095 2040.505 145.6916 2090.625 146.1737 2138.877 146.6558 2189.869 147.1379 2235.811 147.6201 2271.819 148.1022 2297.562 148.5843 2317.419 149.0664 2336.716 149.5485 2357.370 150.0307 2368.197 150.5128 2356.712 150.9949 2340.383 151.4770 2340.393 151.9591 2363.721 152.4412 2395.855 152.9234 2414.151 153.4055 2419.606 153.8876 2418.467 154.3697 2404.221 154.8518 2383.946 155.3339 2379.806 155.8161 2408.732 156.2982 2445.169 156.7803 2447.772 157.2624 2406.229 157.7445 2368.531 158.2266 2379.374 158.7088 2438.626 159.1909 2485.516 159.6730 2490.773 160.1551 2480.966 160.6372 2473.294 161.1193 2475.188 161.6015 2477.967 162.0836 2449.749 162.5657 2382.863 163.0478 2318.580 163.5299 2286.944 164.0120 2253.827 164.4942 2190.483 164.9763 2088.451 165.4584 1967.866 165.9405 1857.458 166.4226 1750.773 166.9047 1661.761 167.3869 1598.698 167.8690 1552.265 168.3511 1508.978 168.8332 1458.417 169.3153 1401.814 169.7974 1363.258 170.2796 1360.769 170.7617 1360.556 171.2438 1355.999 171.7259 1346.825 172.2080 1334.541 172.6901 1319.359 173.1723 1299.162 173.6544 1290.826 174.1365 1304.030 174.6186 1318.215 175.1007 1331.656 175.5828 1339.836 176.0650 1328.548 176.5471 1280.871 177.0292 1179.450 177.5113 1094.299 177.9934 1051.577 178.4755 1009.285 178.9577 922.0093 179.4398 781.6851 179.9219 628.4287 180.4040 521.3740 180.8861 472.7202 181.3682 429.8076 181.8504 385.9878 182.3325 344.9175 182.8146 311.6284 183.2967 287.9634 183.7788 271.3418 184.2609 260.4272 184.7431 257.4199 185.2252 249.3662 185.7073 224.6240 186.1894 190.6948 186.6715 167.1299 187.1536 160.6294 187.6358 168.3076 188.1179 185.3306 188.6000 214.5986 189.0821 242.3472 189.5642 262.0762 190.0463 273.6538 190.5285 274.3794 191.0106 255.2329 191.4927 229.6357 191.9748 213.2275 192.4569 209.4038 192.9390 209.9336 193.4212 207.8730 193.9033 203.2197 194.3854 195.6416 194.8675 186.8159 195.3496 173.7925 195.8317 150.1660 196.3139 110.3096 196.7960 69.62158 197.2781 57.02539 197.7602 87.53125 198.2423 104.5107 198.7244 81.00049 199.2066 40.12939 199.6887 2.886230 200.1708 22.52832 200.6529 39.06299 201.1350 54.91162 201.6171 75.24512 202.0993 85.12939 202.5814 74.33008 203.0635 54.74219 203.5456 41.49268 204.0277 44.01758 204.5098 57.65088 204.9920 59.90137 205.4741 37.63086 205.9562 19.08740 206.4383 8.148926 206.9204 4.950684 207.4025 10.97266 207.8847 29.15918 208.3668 57.34082 208.8489 68.85303 209.3310 50.72119 209.8131 27.62939 210.2952 7.302246 210.7774 43.32080 211.2595 59.26855 211.7416 35.75586 212.2237 28.47461 212.7058 61.07129 213.1879 46.71191 213.6701 19.63232 214.1522 20.05420 214.6343 64.73291 215.1164 99.15723 215.5985 109.0732 216.0806 91.52637 216.5628 82.63867 217.0449 83.57275 217.5270 89.99121 218.0091 104.7217 218.4912 124.9062 218.9733 140.1289 219.4555 139.0151 219.9376 117.6216 220.4197 113.3350 220.9018 143.6108 221.3839 175.3042 221.8660 186.0293 222.3482 175.2705 222.8303 158.7075 223.3124 148.8511 223.7945 146.3672 224.2766 156.9902 224.7587 175.9688 225.2409 210.5776 225.7230 281.3052 226.2051 388.1216 226.6872 485.4404 227.1693 527.0444 227.6514 506.7388 228.1336 472.1582 228.6157 405.2637 229.0978 336.4985 229.5799 297.6909 230.0620 294.2993 230.5441 305.6768 231.0263 313.3232 231.5084 317.3379 231.9905 321.8074 232.4726 322.7864 232.9547 326.4075 233.4368 346.8115 233.9190 389.9849 234.4011 427.2947 234.8832 412.8977 235.3653 355.8757 235.8474 325.2878 236.3295 359.9392 236.8117 425.9023 237.2938 471.9377 237.7759 489.8022 238.2580 492.1702 238.7401 484.5557 239.2222 469.4072 239.7044 458.4260 240.1865 447.1379 240.6686 443.9780 241.1507 473.9551 241.6328 554.9590 242.1149 633.0737 242.5971 653.6440 243.0792 628.3083 243.5613 599.0732 244.0434 575.8945 244.5255 561.3396 245.0076 563.0256 245.4898 586.0120 245.9719 617.5811 246.4540 652.5066 246.9361 688.7280 247.4182 716.6184 247.9003 720.2458 248.3825 710.9170 248.8646 726.3735 249.3467 782.3264 249.8288 841.7710 250.3109 878.2610 250.7930 896.3765 251.2752 910.2854 251.7573 928.0459 252.2394 947.7656 252.7215 960.8740 253.2036 958.7375 253.6857 963.0601 254.1679 990.1641 254.6500 1034.526 255.1321 1080.030 255.6142 1117.256 256.0963 1147.428 256.5785 1178.290 257.0606 1214.903 257.5427 1244.468 258.0248 1257.690 258.5069 1258.655 258.9890 1257.336 259.4712 1258.156 259.9533 1261.065 260.4354 1266.011 260.9175 1276.560 261.3996 1284.509 261.8817 1288.607 262.3639 1286.972 262.8460 1276.009 263.3281 1242.359 263.8102 1194.619 264.2923 1183.045 264.7744 1232.818 265.2566 1282.842 265.7387 1303.174 266.2208 1303.302 266.7029 1303.256 267.1850 1316.657 267.6671 1338.625 268.1493 1345.972 268.6314 1319.537 269.1135 1304.568 269.5956 1310.423 270.0777 1339.359 270.5598 1399.312 271.0420 1512.324 271.5241 1657.588 272.0062 1747.173 272.4883 1763.042 272.9704 1744.637 273.4525 1688.809 273.9347 1619.281 274.4168 1569.017 274.8989 1553.676 275.3810 1567.276 275.8631 1587.396 276.3452 1613.344 276.8274 1650.758 277.3095 1711.928 277.7916 1779.504 278.2737 1829.625 278.7558 1847.843 279.2379 1844.934 279.7201 1851.853 280.2022 1878.465 280.6843 1895.721 281.1664 1897.010 281.6485 1886.780 282.1306 1866.806 282.6128 1835.816 283.0949 1796.776 283.5770 1759.112 284.0591 1728.182 284.5412 1689.382 285.0233 1632.343 285.5055 1568.220 285.9876 1508.425 286.4697 1458.462 286.9518 1413.413 287.4339 1363.889 287.9160 1306.344 288.3982 1250.816 288.8803 1200.637 289.3624 1151.918 289.8445 1101.037 290.3266 1046.882 290.8087 992.0771 291.2909 937.6873 291.7730 877.9595 292.2551 838.0518 292.7372 842.0195 293.2193 855.3301 293.7014 856.8201 294.1836 840.9404 294.6657 809.9961 295.1478 759.2312 295.6299 679.3516 296.1120 623.3960 296.5941 622.2183 297.0763 634.5774 297.5584 640.2312 298.0405 634.9246 298.5226 621.2415 299.0047 600.0667 299.4868 570.6687 299.9690 543.3730 300.4511 521.1191 300.9332 499.9973 301.4153 477.8862 301.8974 455.7771 302.3795 434.6125 302.8617 416.7866 303.3438 403.0203 303.8259 389.0757 304.3080 377.2129 304.7901 363.2542 305.2722 336.7156 305.7544 302.5845 306.2365 279.6985 306.7186 295.6357 307.2007 344.6768 307.6828 357.8967 308.1649 310.7737 308.6471 255.8154 309.1292 216.8887 309.6113 192.1321 310.0934 175.7817 310.5755 168.9077 311.0576 168.0811 311.5398 157.9927 312.0219 130.2275 312.5040 108.7581 312.9861 110.3777 313.4682 125.0017 313.9503 135.4236 314.4325 133.9924 314.9146 123.2583 315.3967 106.1782 315.8788 78.17065 316.3609 56.43701 316.8430 50.34888 317.3252 54.58472 317.8073 65.47607 318.2894 86.91431 318.7715 107.2363 319.2536 104.9353 319.7357 74.96069 320.2179 51.37305 320.7000 55.48340 321.1821 70.69922 321.6642 82.00269 322.1463 88.08838 322.6284 85.66919 323.1106 63.59839 323.5927 21.48315 324.0748 4.193604 324.5569 10.09448 325.0390 38.09912 325.5211 51.87305 326.0033 49.01294 326.4854 35.73828 326.9675 4.356445 327.4496 38.79102 327.9317 55.05786 328.4138 24.70020 328.8960 23.64380 329.3781 63.75098 329.8602 96.53101 330.3423 108.5862 330.8244 72.66406 331.3065 11.73096 331.7887 11.19678 332.2708 26.23926 332.7529 73.72754 333.2350 74.38403 333.7171 36.37500 334.1992 2.353516 334.6814 12.70410 335.1635 17.47925 335.6456 23.99048 336.1277 33.68140 336.6098 42.18237 337.0919 43.58862 337.5741 39.81641 338.0562 42.16235 338.5383 67.13428 339.0204 88.11597 339.5025 74.13257 339.9846 27.36670 340.4668 14.19214 340.9489 24.81885 341.4310 9.905273 341.9131 2.116699 342.3952 10.18457 342.8773 16.60742 343.3595 11.01953 343.8416 3.632813 344.3237 19.39038 344.8058 33.80811 345.2879 45.26343 345.7701 47.67261 346.2522 36.30420 346.7343 25.63086 347.2164 18.78882 347.6985 15.02417 348.1806 13.49463 348.6628 14.03540 349.1449 15.73047 349.6270 17.06909 350.1091 18.43359 350.5912 18.57056 351.0733 18.27686 351.5555 16.24536 352.0376 8.707031 352.5197 4.114746 353.0018 14.72705 353.4839 13.65991 353.9660 3.253906 354.4482 16.70654 354.9303 31.32056 355.4124 39.20923 355.8945 31.33179 356.3766 11.03052 356.8587 9.903320 357.3409 22.82324 357.8230 27.82861 358.3051 18.97363 358.7872 28.15601 359.2693 62.42139 359.7514 58.10449 360.2336 31.99194 360.7157 15.54419 361.1978 27.91553 361.6799 60.14673 362.1620 74.74341 362.6441 57.78906 363.1263 40.99316 363.6084 26.28052 364.0905 14.59229 364.5726 7.756836 365.0547 6.267334 365.5368 6.725830 366.0190 1.736084 366.5011 14.24219 366.9832 20.83398 367.4653 3.649414 367.9474 13.39307 368.4295 15.13965 368.9117 0.1423340 369.3938 23.67188 369.8759 48.76831 370.3580 75.92505 370.8401 98.30737 371.3222 114.9568 371.8044 127.4675 372.2865 132.6882 372.7686 133.7844 373.2507 139.1238 373.7328 152.6575 374.2149 174.2830 374.6971 208.0059 375.1792 265.7532 375.6613 311.5085 376.1434 312.7727 376.6255 294.5801 377.1076 294.1572 377.5898 329.1306 378.0719 378.5884 378.5540 415.9050 379.0361 440.3132 379.5182 466.7820 380.0003 499.0254 380.4825 537.8726 380.9646 583.7520 381.4467 636.6951 381.9288 692.0845 382.4109 749.2007 382.8930 808.7490 383.3752 869.9009 383.8573 930.8462 384.3394 994.2351 384.8215 1064.861 385.3036 1141.676 385.7857 1216.377 386.2679 1277.883 386.7500 1344.932 387.2321 1441.370 387.7142 1569.807 388.1963 1706.746 388.6784 1828.596 389.1606 1933.344 389.6427 2058.006 390.1248 2210.399 390.6069 2381.173 391.0890 2570.927 391.5711 2774.503 392.0533 2977.378 392.5354 3170.939 393.0175 3360.182 393.4996 3566.764 393.9817 3790.572 394.4638 4030.469 394.9460 4299.500 395.4281 4580.633 395.9102 4842.519 396.3923 5075.481 396.8744 5302.703 397.3565 5571.327 397.8387 5915.034 398.3208 6235.536 398.8029 6482.459 399.2850 6741.432 399.7671 7081.261 400.2492 7497.220 400.7314 7927.466 401.2135 8311.959 401.6956 8645.880 402.1777 9011.910 402.6598 9447.541 403.1419 9876.770 403.6241 10308.62 404.1062 10716.75 404.5883 11064.44 405.0704 11333.74 405.5525 11522.59 406.0346 11619.31 406.5168 11610.94 406.9989 11541.01 407.4810 11418.60 407.9631 11244.22 408.4452 11006.10 408.9273 10699.04 409.4095 10356.82 409.8916 10003.29 410.3737 9640.537 410.8558 9290.156 411.3379 8967.869 411.8200 8646.200 412.3022 8289.637 412.7843 7902.949 413.2664 7546.259 413.7485 7244.485 414.2306 6988.646 414.7127 6769.651 415.1949 6589.014 415.6770 6419.312 416.1591 6242.487 416.6412 6058.675 417.1233 5876.751 417.6054 5693.651 418.0876 5520.114 418.5697 5357.343 419.0518 5206.166 419.5339 5071.130 420.0160 4955.758 420.4981 4858.647 420.9803 4772.299 421.4624 4695.190 421.9445 4630.245 422.4266 4586.292 422.9087 4549.762 423.3908 4500.321 423.8730 4437.001 424.3551 4384.502 424.8372 4371.893 425.3193 4407.568 425.8014 4441.866 426.2835 4469.710 426.7657 4501.664 427.2478 4548.846 427.7299 4603.160 428.2120 4647.717 428.6941 4671.221 429.1762 4678.539 429.6584 4691.133 430.1405 4728.045 430.6226 4735.917 431.1047 4696.620 431.5868 4633.394 432.0689 4565.561 432.5511 4497.891 433.0332 4428.952 433.5153 4355.143 433.9974 4276.274 434.4795 4201.142 434.9616 4140.885 435.4438 4072.553 435.9259 3977.462 436.4080 3860.766 436.8901 3745.716 437.3722 3644.838 437.8543 3552.940 438.3365 3456.413 438.8186 3352.775 439.3007 3263.002 439.7828 3206.890 440.2649 3172.374 440.7470 3127.298 441.2292 3061.965 441.7113 2997.392 442.1934 2942.576 442.6755 2897.555 443.1576 2864.786 443.6397 2845.883 444.1219 2834.461 444.6040 2819.082 445.0861 2793.582 445.5682 2784.031 446.0503 2807.709 446.5324 2836.326 447.0146 2844.246 447.4967 2833.666 447.9788 2826.157 448.4609 2842.099 448.9430 2880.385 449.4251 2905.637 449.9073 2892.413 450.3894 2892.870 450.8715 2924.982 451.3536 2973.904 451.8357 3021.098 452.3178 3058.708 452.8000 3091.144 453.2821 3126.688 453.7642 3167.280 454.2463 3202.757 454.7284 3232.007 455.2105 3254.427 455.6927 3269.361 456.1748 3278.350 456.6569 3283.797 457.1390 3290.041 457.6212 3293.300 458.1033 3279.294 458.5854 3243.321 459.0675 3204.124 459.5496 3171.785 460.0317 3143.043 460.5139 3111.755 460.9960 3077.108 461.4781 3033.083 461.9602 2971.962 462.4423 2899.958 462.9244 2834.710 463.4066 2780.454 463.8887 2732.726 464.3708 2690.526 464.8529 2658.360 465.3350 2615.155 465.8171 2549.066 466.2993 2479.623 466.7814 2420.740 467.2635 2370.303 467.7456 2317.005 468.2277 2254.852 468.7098 2186.955 469.1920 2130.201 469.6741 2094.124 470.1562 2056.500 470.6383 2009.943 471.1204 1962.457 471.6025 1921.983 472.0847 1891.139 472.5668 1867.746 473.0489 1850.958 473.5310 1843.285 474.0131 1830.344 474.4952 1801.360 474.9774 1776.920 475.4595 1768.219 475.9416 1771.865 476.4237 1777.355 476.9058 1777.549 477.3879 1776.908 477.8701 1786.893 478.3522 1809.873 478.8343 1827.639 479.3164 1822.488 479.7985 1814.023 480.2806 1832.258 480.7628 1885.351 481.2449 1940.532 481.7270 1987.981 482.2091 2024.942 482.6912 2046.398 483.1733 2051.355 483.6555 2041.421 484.1376 2015.312 484.6197 1971.313 485.1018 1932.988 485.5839 1915.326 486.0660 1887.681 486.5482 1832.464 487.0303 1757.126 487.5124 1676.868 487.9945 1599.126 488.4766 1519.831 488.9587 1428.495 489.4409 1303.339 489.9230 1208.657 490.4051 1168.742 490.8872 1136.678 491.3693 1084.218 491.8514 1010.544 492.3336 929.7661 492.8157 848.7751 493.2978 769.7830 493.7799 704.0129 494.2620 657.7942 494.7441 610.9409 495.2263 550.6411 495.7084 486.2573 496.1905 427.5078 496.6726 375.9478 497.1547 331.9685 497.6368 298.6489 498.1190 273.4514 498.6011 248.3184 499.0832 221.2976 499.5653 194.0891 500.0474 168.5547 500.5295 144.9050 501.0117 119.7446 501.4938 85.18652 501.9759 55.86206 502.4580 45.99731 502.9401 49.01245 503.4222 45.27222 503.9044 23.98389 504.3865 5.727051 504.8686 18.77026 505.3507 5.116455 505.8328 12.54883 506.3149 11.04858 506.7971 39.26855 507.2792 52.83643 507.7613 52.02759 508.2434 50.18408 508.7255 59.25049 509.2076 76.74756 509.6898 88.65991 510.1719 94.47046 510.6540 95.55835 511.1361 91.57422 511.6182 83.70288 512.1003 70.66602 512.5825 49.93140 513.0646 34.48242 513.5467 37.81128 514.0288 54.70312 514.5109 69.51343 514.9930 79.24976 515.4752 86.45264 515.9573 93.22461 516.4394 99.49585 516.9215 104.7319 517.4036 118.6855 517.8857 122.0808 518.3679 93.95874 518.8500 48.51978 519.3321 16.71997 519.8142 12.13940 520.2963 22.33887 520.7784 22.00659 521.2606 0.5900880 521.7427 9.007080 522.2248 3.784424 522.7069 8.728760 523.1890 34.51855 523.6711 65.06030 524.1533 77.56128 524.6354 51.52173 525.1175 2.879150 525.5996 21.91016 526.0817 16.29810 526.5638 11.60010 527.0460 15.03931 527.5281 26.82983 528.0102 50.88037 528.4923 89.19482 528.9744 121.2009 529.4565 127.2014 529.9387 123.2710 530.4208 136.1926 530.9029 168.9133 531.3850 210.6172 531.8671 256.1672 532.3492 303.9924 532.8314 343.4258 533.3135 363.6809 533.7956 390.0779 534.2777 429.3804 534.7598 477.3877 535.2419 530.3247 535.7241 586.5630 536.2062 645.7976 536.6883 707.3416 537.1704 771.4807 537.6525 837.5137 538.1346 909.5747 538.6168 978.8721 539.0989 1027.627 539.5810 1075.828 540.0631 1156.537 540.5452 1286.585 541.0273 1433.544 541.5095 1563.794 541.9916 1677.748 542.4737 1777.063 542.9558 1855.890 543.4379 1931.500 543.9200 2032.263 544.4022 2153.259 544.8843 2237.643 545.3664 2252.854 545.8485 2250.213 546.3306 2264.528 546.8127 2288.939 547.2949 2300.234 547.7770 2287.441 548.2591 2262.829 548.7412 2249.680 549.2233 2246.448 549.7054 2259.495 550.1876 2306.508 550.6697 2350.998 551.1518 2369.641 551.6339 2369.093 552.1160 2371.153 552.5981 2388.753 553.0803 2417.388 553.5624 2449.131 554.0445 2485.696 554.5266 2514.578 555.0087 2516.497 555.4908 2523.560 555.9730 2575.185 556.4551 2672.174 556.9372 2758.787 557.4193 2807.655 557.9014 2838.102 558.3835 2873.174 558.8657 2912.327 559.3478 2942.443 559.8299 2957.109 560.3120 2955.682 560.7941 2935.871 561.2762 2895.759 561.7584 2837.968 562.2405 2754.727 562.7226 2658.802 563.2047 2559.553 563.6868 2457.421 564.1689 2350.761 564.6511 2236.867 565.1332 2117.431 565.6153 1996.739 566.0974 1872.446 566.5795 1752.954 567.0616 1638.200 567.5438 1531.839 568.0259 1441.085 568.5080 1367.714 568.9901 1292.440 569.4722 1197.335 569.9543 1097.022 570.4365 1015.576 570.9186 954.3665 571.4007 902.3794 571.8828 854.2031 572.3649 808.7200 572.8470 761.2642 573.3292 710.3638 573.8113 660.0823 574.2934 599.4656 574.7755 546.7966 575.2576 525.1880 575.7397 532.1208 576.2219 540.2051 576.7040 523.3728 577.1861 486.3135 577.6682 464.0786 578.1503 461.0693 578.6324 461.0496 579.1146 460.9651 579.5967 461.2117 580.0788 461.5938 580.5609 461.6646 581.0430 461.7886 581.5251 459.8936 582.0073 460.2344 582.4894 472.0789 582.9715 497.1184 583.4536 525.6975 583.9357 550.7346 584.4178 573.6902 584.9000 601.4834 585.3821 640.7888 585.8642 676.6052 586.3463 700.9084 586.8284 724.7603 587.3105 760.3696 587.7927 806.6838 588.2748 852.5920 588.7569 891.4075 589.2390 921.2507 589.7211 929.2961 590.2032 905.5352 590.6854 886.4075 591.1675 889.0806 591.6496 898.6572 592.1317 901.0002 592.6138 894.6079 593.0959 891.0081 593.5781 896.1667 594.0602 907.3750 594.5423 913.2666 595.0244 915.8804 595.5065 947.2168 595.9886 1034.861 596.4708 1152.634 596.9529 1219.573 597.4350 1171.207 597.9171 1161.080 598.3992 1212.128 598.8813 1279.719 599.3635 1337.472 599.8456 1384.666 600.3277 1431.764 600.8098 1485.628 601.2919 1543.182 601.7740 1600.594 602.2562 1661.441 602.7383 1700.166 603.2204 1696.884 603.7025 1680.610 604.1846 1685.124 604.6667 1709.159 605.1489 1722.506 605.6310 1710.577 606.1131 1687.894 606.5952 1664.290 607.0773 1641.634 607.5594 1624.114 608.0416 1614.895 608.5237 1604.610 609.0058 1571.390 609.4879 1491.400 609.9700 1446.159 610.4521 1451.676 610.9343 1474.323 611.4164 1506.237 611.8985 1542.679 612.3806 1576.961 612.8627 1605.504 613.3448 1633.206 613.8270 1664.808 614.3091 1700.930 614.7912 1746.903 615.2733 1803.505 615.7554 1871.278 616.2375 1953.516 616.7197 2049.308 617.2018 2146.312 617.6839 2257.923 618.1660 2354.943 618.6481 2409.071 619.1302 2445.637 619.6124 2508.794 620.0945 2607.943 620.5766 2705.412 621.0587 2753.390 621.5408 2749.498 622.0229 2764.818 622.5051 2819.630 622.9872 2861.650 623.4693 2871.637 623.9514 2860.952 624.4335 2838.860 624.9156 2805.615 625.3978 2775.446 625.8799 2759.226 626.3620 2751.509 626.8441 2745.934 627.3262 2741.217 627.8083 2726.854 628.2905 2695.823 628.7726 2650.256 629.2547 2598.720 629.7368 2538.359 630.2189 2476.045 630.7010 2423.943 631.1832 2360.387 631.6653 2268.990 632.1474 2151.321 632.6295 2018.691 633.1116 1876.709 633.5938 1727.087 634.0759 1567.270 634.5580 1395.692 635.0401 1239.205 635.5222 1107.139 636.0043 991.2329 636.4865 882.6636 636.9686 781.6040 637.4507 690.5867 637.9328 615.5564 638.4149 545.8279 638.8970 472.4520 639.3792 400.2422 639.8613 339.7703 640.3434 294.5917 640.8255 258.5470 641.3076 223.4916 641.7897 188.5925 642.2719 161.1569 642.7540 144.9695 643.2361 131.1310 643.7182 115.4827 644.2003 100.2059 644.6824 89.12744 645.1646 83.92603 645.6467 77.87231 646.1288 61.74646 646.6109 43.59119 647.0930 41.94019 647.5751 57.14661 648.0573 66.75366 648.5394 54.83020 649.0215 27.63342 649.5036 7.693848 649.9857 0.1534420 650.4678 7.197266 650.9500 18.71899 651.4321 26.80005 651.9142 23.44275 652.3963 11.84338 652.8784 2.086182 653.3605 1.088867 653.8427 2.108643 654.3248 17.14917 654.8069 42.45886 655.2890 50.85400 655.7711 30.66919 656.2532 4.451904 656.7354 4.337524 657.2175 5.386841 657.6996 11.51404 658.1817 12.71411 658.6638 11.71411 659.1459 6.817627 659.6281 1.710938 660.1102 2.816162 660.5923 10.52588 661.0744 16.61829 661.5565 11.23889 662.0386 3.480957 662.5208 11.90283 663.0029 13.65344 663.4850 10.45874 663.9671 2.308350 664.4492 10.29480 664.9313 30.56531 665.4135 61.41418 665.8956 76.37219 666.3777 54.61035 666.8598 23.77954 667.3419 5.860962 667.8240 0.2351070 668.3062 2.187866 668.7883 3.432129 669.2704 4.214966 669.7525 4.351929 670.2346 3.037964 670.7167 4.390625 671.1989 8.136108 671.6810 15.12451 672.1631 30.15515 672.6452 47.02771 673.1273 55.83276 673.6094 53.45569 674.0916 45.35657 674.5737 28.51086 675.0558 11.08752 675.5379 9.180298 676.0200 23.09119 676.5021 37.03027 676.9843 40.21936 677.4664 35.82935 677.9485 35.64905 678.4306 44.46423 678.9127 48.76135 679.3948 38.48010 679.8770 31.09167 680.3591 45.28772 680.8412 71.60620 681.3233 81.41882 681.8054 54.69666 682.2875 20.36023 682.7697 10.99500 683.2518 20.84131 683.7339 31.99475 684.2160 41.10315 684.6981 44.39026 685.1802 34.79321 685.6624 14.42334 686.1445 16.21814 686.6266 74.89990 687.1087 110.6460 687.5908 100.2822 688.0729 73.62268 688.5551 51.66016 689.0372 38.31055 689.5193 32.24670 690.0014 34.03333 690.4835 40.52490 690.9656 47.20007 691.4478 54.01013 691.9299 60.43701 692.4120 66.45618 692.8941 71.60779 693.3762 75.39929 693.8583 77.92651 694.3405 78.92847 694.8226 78.41125 695.3047 76.17249 695.7868 69.40015 696.2689 62.41626 696.7510 60.75989 697.2332 64.94958 697.7153 70.07300 698.1974 71.30151 698.6795 70.49988 699.1616 73.17773 699.6437 79.46631 700.1259 87.02502 700.6080 97.24573 701.0901 104.7660 701.5722 99.33545 702.0543 76.36572 702.5364 64.14294 703.0186 72.73682 703.5007 81.76343 703.9828 78.83301 704.4649 72.47961 704.9470 75.88916 705.4291 92.41565 705.9113 112.2946 706.3934 128.6719 706.8755 140.4541 707.3576 140.4529 707.8397 126.7231 708.3218 115.2472 708.8040 114.4183 709.2861 117.6183 709.7682 113.8143 710.2503 101.8203 710.7324 91.49854 711.2145 81.48706 711.6967 74.25244 712.1788 73.17102 712.6609 73.44666 713.1430 68.78796 713.6251 58.80627 714.1072 49.81958 714.5894 49.28101 715.0715 53.95911 715.5536 49.11157 716.0357 32.09387 716.5178 22.44910 716.9999 34.12207 717.4821 54.37219 717.9642 56.18762 718.4463 31.11292 718.9284 18.87451 719.4105 38.20618 719.8926 57.71313 720.3748 58.35706 720.8569 46.09705 721.3390 31.45740 721.8211 18.24829 722.3032 7.912354 722.7853 3.897095 723.2675 4.078369 723.7496 1.723145 724.2317 1.267212 724.7138 2.611816 725.1959 2.310669 725.6780 1.389160 726.1602 1.241455 726.6423 3.588867 727.1244 1.483276 727.6065 3.603271 728.0886 15.06665 728.5707 48.70654 729.0529 85.84851 729.5350 91.12610 730.0171 53.46643 730.4992 8.420166 730.9813 3.697144 731.4634 9.036255 731.9456 15.14136 732.4277 12.81299 732.9098 10.22400 733.3919 12.18738 733.8740 15.11951 734.3561 11.67432 734.8383 1.509399 735.3204 11.76428 735.8025 21.92798 736.2846 26.23242 736.7667 17.84082 737.2488 3.707764 737.7310 6.223145 738.2131 9.276001 738.6952 9.830566 739.1773 12.86108 739.6594 16.23560 740.1415 13.16956 740.6237 3.731567 741.1058 4.490356 741.5879 8.644897 742.0700 8.741821 742.5521 4.447998 743.0342 5.192627 743.5164 15.17969 743.9985 27.89001 744.4806 38.79712 744.9627 50.70166 745.4448 57.48792 745.9269 47.00415 746.4091 17.68042 746.8912 6.864014 747.3733 5.132202 747.8554 9.513672 748.3375 17.60254 748.8196 19.16467 749.3018 17.69702 749.7839 14.33130 750.2660 9.481812 750.7481 2.841675 751.2302 6.674316 751.7123 7.843628 752.1945 6.924072 752.6766 19.55786 753.1587 24.32422 753.6408 26.07263 754.1229 29.83472 754.6050 35.82080 755.0872 40.42590 755.5693 41.84033 756.0514 41.60120 756.5335 43.50061 757.0156 44.79724 757.4977 35.09558 757.9799 12.29175 758.4620 8.111450 758.9441 8.279053 759.4262 10.19531 759.9083 28.22559 760.3904 49.93823 760.8726 60.25964 761.3547 36.88538 761.8368 16.53687 762.3189 46.13989 762.8010 117.1746 763.2831 153.2614 763.7653 105.6709 764.2474 53.61499 764.7295 37.49780 765.2116 42.57190 765.6937 50.97412 766.1758 58.23547 766.6580 66.24707 767.1401 78.35046 767.6222 89.64258 768.1043 82.48938 768.5864 54.76697 769.0685 34.82446 769.5507 30.32446 770.0328 31.08118 770.5149 28.27551 770.9970 22.94055 771.4791 23.00720 771.9612 33.93774 772.4434 42.75598 772.9255 45.16638 773.4076 45.96606 773.8897 49.68018 774.3718 55.51526 774.8539 59.66663 775.3361 59.77771 775.8182 58.99219 776.3003 61.69580 776.7824 66.39832 777.2645 69.09839 777.7466 69.31091 778.2288 67.31189 778.7109 62.10706 779.1930 56.41724 779.6751 59.01831 780.1572 80.81775 780.6393 88.80859 781.1215 66.28003 781.6036 47.68298 782.0857 53.03369 782.5678 69.81543 783.0499 75.23645 783.5320 61.80859 784.0142 53.61218 784.4963 75.84167 784.9784 103.7488 785.4605 106.0430 785.9426 86.48901 786.4247 60.48401 786.9069 34.34546 787.3890 17.85132 787.8711 29.71118 788.3532 70.65479 788.8353 93.80542 789.3174 92.20581 789.7996 91.18994 790.2817 104.5353 790.7638 119.3016 791.2459 117.6750 791.7280 99.21997 792.2101 81.91541 792.6923 63.94543 793.1744 52.21924 793.6565 51.18909 794.1386 57.85986 794.6207 73.76184 795.1028 95.60889 795.5850 107.9781 796.0671 94.33154 796.5492 69.41980 797.0313 62.59875 797.5134 72.12000 797.9955 85.46887 798.4777 101.3176 798.9598 110.7144 799.4419 103.7278 799.9240 83.71228 800.4061 73.77441 800.8882 85.91235 801.3704 88.48804 801.8525 68.78101 802.3346 49.67664 802.8167 44.47351 803.2988 51.03003 803.7809 62.47754 804.2631 78.32690 804.7452 92.00342 805.2273 102.4290 805.7094 107.2334 806.1915 98.59607 806.6736 80.01721 807.1558 65.88293 807.6379 63.44397 808.1200 67.94275 808.6021 72.50623 809.0842 77.01782 809.5663 82.42627 810.0485 91.89807 810.5306 91.39929 811.0127 66.04407 811.4948 35.14954 811.9769 31.36023 812.4590 58.92725 812.9412 82.71692 813.4233 103.4135 813.9054 117.3175 814.3875 118.0519 814.8696 114.4596 815.3517 118.0743 815.8339 129.1565 816.3160 135.8615 816.7981 128.0507 817.2802 114.6808 817.7623 107.0853 818.2444 104.0472 818.7266 99.99719 819.2087 93.82849 819.6908 93.84351 820.1729 109.4000 820.6550 133.8134 821.1371 137.6750 821.6193 112.8364 822.1014 93.05994 822.5835 82.96045 823.0656 78.09460 823.5477 79.24194 824.0298 83.73865 824.5120 83.64832 824.9941 71.83130 825.4762 68.25281 825.9583 85.17322 826.4404 106.9243 826.9225 123.0133 827.4047 134.0643 827.8868 144.4926 828.3690 155.9609 828.8511 163.3135 829.3332 154.6222 829.8153 139.1156 830.2974 148.0757 830.7795 178.9779 831.2617 194.0171 831.7438 179.1477 832.2259 152.2052 832.7080 130.5397 833.1901 113.0680 833.6722 116.2207 834.1544 156.1305 834.6365 189.0558 835.1186 203.3503 835.6007 208.7910 836.0828 213.0929 836.5649 215.4198 837.0471 209.2720 837.5292 183.2687 838.0113 164.0311 838.4934 165.8484 838.9755 177.5273 839.4576 191.8656 839.9398 204.9978 840.4219 210.5183 840.9040 204.8651 841.3861 194.6735 841.8682 188.7521 842.3503 185.7351 842.8325 177.5057 843.3146 163.5481 843.7967 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