#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 11:42:10 +0300 (Thu, 07 Jun 2018) $
#$Revision: 1241 $
#$URL: svn://172.16.1.111/rod/cif/1/00/06/1000651.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000651
loop_
_publ_author_name
'Moore, P. B.'
'Araki, T.'
_publ_section_title
;
 Armangite, Mn26[As6(OH)4O14][As6O18]2[CO3], a fluorite derivative
 structure
;
_journal_name_full               'American Mineralogist'
_journal_page_first              748
_journal_page_last               757
_journal_volume                  64
_journal_year                    1979
_chemical_compound_source        R100041
_chemical_formula_sum            'C As18 Mn26 O57'
_chemical_name_mineral           Armangite
_space_group_IT_number           147
_symmetry_space_group_name_Hall  '-P 3'
_symmetry_space_group_name_H-M   'P -3'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   13.491
_cell_length_b                   13.491
_cell_length_c                   8.855
_cell_volume                     1395.750
_exptl_crystal_density_diffrn    4.403
_cod_original_cell_volume        1395.749
_cod_original_formula_sum        'C Mn26 As18 O57'
_cod_database_code               9000725
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 780
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 12
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R100041.rod
_rod_data_source.block           3500000
_rod_database.code               1000651
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9000725 COD http://www.crystallography.net/cod/9000725.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
91.53320 0.0000000E+00
92.01532 8.982727
92.49744 0.4263920
92.97955 10.56525
93.46167 27.03149
93.94379 33.44336
94.42590 33.88892
94.90802 31.72064
95.39014 28.07715
95.87225 22.45721
96.35437 17.45197
96.83649 15.08850
97.31860 14.22620
97.80072 13.50391
98.28284 10.85608
98.76495 6.271484
99.24707 4.361633
99.72919 8.076111
100.2113 11.56635
100.6934 12.49994
101.1755 11.83649
101.6577 11.72797
102.1398 14.05682
102.6219 19.03882
103.1040 25.02142
103.5861 32.92126
104.0682 40.66742
104.5504 46.76056
105.0325 51.17706
105.5146 55.31311
105.9967 60.98163
106.4788 68.64087
106.9609 76.58270
107.4431 85.09747
107.9252 93.73486
108.4073 101.5503
108.8894 107.8698
109.3715 114.1086
109.8536 122.9548
110.3358 134.8895
110.8179 146.7794
111.3000 156.8931
111.7821 165.3784
112.2642 173.6216
112.7463 181.7818
113.2285 190.1821
113.7106 199.3790
114.1927 209.7236
114.6748 220.0600
115.1569 228.5453
115.6390 234.5477
116.1212 240.3914
116.6033 247.8243
117.0854 255.9099
117.5675 263.0029
118.0496 267.5442
118.5317 269.4513
119.0139 270.6566
119.4960 271.4321
119.9781 271.6003
120.4602 271.6715
120.9423 271.3285
121.4244 270.1208
121.9066 267.7056
122.3887 264.0491
122.8708 259.2993
123.3529 252.9534
123.8350 246.2295
124.3171 239.7888
124.7993 233.6014
125.2814 227.1436
125.7635 219.6902
126.2456 210.8911
126.7277 203.0195
127.2098 196.8938
127.6920 191.3624
128.1741 185.1019
128.6562 177.8141
129.1383 170.1725
129.6204 163.0078
130.1025 156.2405
130.5847 149.4965
131.0668 142.9846
131.5489 136.4548
132.0310 128.9572
132.5131 119.5684
132.9952 109.7824
133.4774 100.7180
133.9595 92.41254
134.4416 84.78516
134.9237 78.00085
135.4058 72.17761
135.8879 66.18170
136.3701 59.14606
136.8522 52.34009
137.3343 46.72479
137.8164 42.46606
138.2985 38.83691
138.7806 34.51630
139.2628 29.09052
139.7449 23.66687
140.2270 18.20361
140.7091 12.84137
141.1912 7.550781
141.6733 2.350647
142.1555 2.566956
142.6376 6.409546
143.1197 8.705994
143.6018 10.36047
144.0839 11.52478
144.5660 12.09650
145.0482 11.86993
145.5303 10.68896
146.0124 8.633606
146.4945 6.277710
146.9766 3.501953
147.4587 0.6367800
147.9409 1.838623
148.4230 4.138550
148.9051 7.265381
149.3872 12.14514
149.8693 18.47949
150.3514 24.04596
150.8336 28.38586
151.3157 32.39203
151.7978 36.79492
152.2799 41.60065
152.7620 47.02179
153.2441 53.72076
153.7263 61.14630
154.2084 68.52734
154.6905 75.42517
155.1726 82.08508
155.6547 89.12970
156.1368 96.72284
156.6190 104.3757
157.1011 111.6589
157.5832 118.7934
158.0653 126.2840
158.5474 134.3044
159.0295 142.8740
159.5117 152.3057
159.9938 163.6152
160.4759 174.9066
160.9580 185.2819
161.4401 194.9978
161.9222 204.7829
162.4044 215.3159
162.8865 226.8052
163.3686 238.1272
163.8507 249.2178
164.3328 260.3599
164.8149 271.6566
165.2971 283.1316
165.7792 294.5221
166.2613 305.6400
166.7434 316.3442
167.2255 326.9042
167.7076 337.5108
168.1898 347.8210
168.6719 357.5504
169.1540 366.7700
169.6361 375.5977
170.1182 384.1650
170.6003 392.5358
171.0825 400.3716
171.5646 407.3478
172.0467 413.8835
172.5288 420.6237
173.0109 427.8290
173.4930 434.7867
173.9752 440.1351
174.4573 443.8679
174.9394 447.1643
175.4215 450.3013
175.9036 453.2513
176.3857 456.0316
176.8679 458.8474
177.3500 461.1451
177.8321 462.5563
178.3142 463.2188
178.7963 462.4293
179.2784 459.0168
179.7606 453.2983
180.2427 448.3136
180.7248 445.9691
181.2069 443.6272
181.6890 439.3543
182.1711 432.9799
182.6533 424.7426
183.1354 414.1841
183.6175 400.9203
184.0996 388.3914
184.5817 379.2899
185.0638 369.9562
185.5460 357.9891
186.0281 342.9120
186.5102 326.4312
186.9923 310.8533
187.4744 296.4718
187.9565 282.2577
188.4387 267.9637
188.9208 253.7772
189.4029 239.8522
189.8850 226.1704
190.3671 212.8999
190.8492 200.0283
191.3314 187.2933
191.8135 175.7419
192.2956 165.8439
192.7777 156.8372
193.2598 148.1329
193.7419 139.5196
194.2241 131.0369
194.7062 122.7974
195.1883 114.6626
195.6704 106.9388
196.1525 99.97827
196.6346 93.35077
197.1168 86.51031
197.5989 79.20898
198.0810 71.67847
198.5631 64.59296
199.0452 57.29761
199.5273 51.21606
200.0095 46.86926
200.4916 43.68768
200.9737 40.96655
201.4558 38.45105
201.9379 36.08600
202.4200 33.53540
202.9022 30.41711
203.3843 27.93170
203.8664 26.49084
204.3485 26.03790
204.8306 26.53802
205.3127 28.20087
205.7949 30.47485
206.2770 32.10822
206.7591 32.51520
207.2412 33.55066
207.7233 36.44629
208.2054 41.00751
208.6876 45.94617
209.1697 50.44568
209.6518 55.40497
210.1339 61.96869
210.6160 70.43109
211.0981 79.71124
211.5803 89.42438
212.0624 99.56128
212.5445 108.8936
213.0266 118.4022
213.5087 125.6859
213.9908 128.7165
214.4730 127.1584
214.9551 121.4345
215.4372 111.0779
215.9193 95.34412
216.4014 79.33801
216.8836 62.62659
217.3657 47.19415
217.8478 34.48669
218.3299 24.93298
218.8120 17.65009
219.2941 11.72662
219.7763 7.353088
220.2584 3.811218
220.7405 1.051331
221.2226 1.075500
221.7047 2.510315
222.1868 3.263123
222.6690 3.642883
223.1511 4.184204
223.6332 5.189636
224.1153 5.650391
224.5974 5.695374
225.0795 5.132019
225.5617 3.566895
226.0438 0.9642940
226.5259 2.070435
227.0080 4.433899
227.4901 5.512238
227.9722 7.048431
228.4544 9.260681
228.9365 11.81503
229.4186 14.54611
229.9007 17.32556
230.3828 19.99377
230.8649 22.31793
231.3471 23.90524
231.8292 26.14471
232.3113 28.72852
232.7934 31.82510
233.2755 35.89853
233.7576 41.02850
234.2398 46.56708
234.7219 51.31210
235.2040 54.45343
235.6861 58.20410
236.1682 62.89023
236.6503 67.93063
237.1325 72.96094
237.6146 77.88580
238.0967 82.63397
238.5788 86.99149
239.0609 90.72293
239.5430 94.36752
240.0252 97.83591
240.5073 101.2402
240.9894 104.6180
241.4715 107.9970
241.9536 111.5474
242.4357 115.6132
242.9179 120.4021
243.4000 124.7426
243.8821 128.3566
244.3642 131.5228
244.8463 134.6036
245.3284 137.6963
245.8106 140.4744
246.2927 142.4077
246.7748 143.4713
247.2569 144.6359
247.7390 146.3415
248.2211 148.0833
248.7033 149.2445
249.1854 149.7082
249.6675 149.7828
250.1496 149.7682
250.6317 149.6302
251.1138 149.0956
251.5960 147.5748
252.0781 145.8410
252.5602 145.1469
253.0423 145.8326
253.5244 146.3257
254.0065 144.9785
254.4887 142.3250
254.9708 139.7053
255.4529 137.8175
255.9350 136.0229
256.4171 133.2911
256.8992 129.3958
257.3813 125.4781
257.8635 122.4601
258.3456 119.9636
258.8277 117.3390
259.3098 114.2483
259.7919 111.0596
260.2740 108.3730
260.7562 106.2921
261.2383 104.2622
261.7204 102.3574
262.2025 100.1984
262.6846 97.07690
263.1667 92.33615
263.6489 87.09857
264.1310 82.96292
264.6131 80.13760
265.0952 77.50266
265.5773 74.37378
266.0594 71.28778
266.5416 68.84848
267.0237 67.34518
267.5058 66.19443
267.9879 64.61508
268.4700 62.56461
268.9521 60.32806
269.4343 57.70853
269.9164 55.08926
270.3985 52.80435
270.8806 50.94202
271.3627 49.31354
271.8448 47.68533
272.3270 46.01410
272.8091 44.49716
273.2912 43.52310
273.7733 42.49445
274.2554 41.04581
274.7375 39.09256
275.2197 36.78418
275.7018 34.04694
276.1839 30.74069
276.6660 28.00729
277.1481 26.40378
277.6302 25.17618
278.1124 24.14542
278.5945 23.22769
279.0766 22.24466
279.5587 21.04306
280.0408 19.63342
280.5229 18.11502
281.0051 16.38547
281.4872 14.60892
281.9693 12.88339
282.4514 11.23709
282.9335 9.661896
283.4156 8.175049
283.8978 6.814728
284.3799 5.594208
284.8620 4.541718
285.3441 3.531250
285.8262 2.330566
286.3083 1.128754
286.7905 0.3855900
287.2726 0.6359560
287.7547 1.688538
288.2368 1.645508
288.7189 0.9436040
289.2010 2.921204
289.6832 3.092377
290.1653 2.178192
290.6474 1.290710
291.1295 1.058777
291.6116 1.319153
292.0938 1.435028
292.5759 1.422302
293.0580 1.208771
293.5401 0.4370730
294.0222 0.3966670
294.5043 0.6634520
294.9865 6.5002002E-02
295.4686 1.006714
295.9507 1.598572
296.4328 1.519592
296.9149 1.280945
297.3970 0.8161010
297.8792 0.3060000
298.3613 0.1178590
298.8434 0.4642030
299.3255 0.7194210
299.8076 0.9295650
300.2897 1.040161
300.7719 1.695251
301.2540 3.043304
301.7361 4.601532
302.2182 6.217834
302.7003 7.843475
303.1824 9.351471
303.6646 10.42929
304.1467 10.79156
304.6288 11.46017
305.1109 12.58932
305.5930 13.80554
306.0751 14.90216
306.5573 15.95999
307.0394 17.24097
307.5215 18.97693
308.0036 21.18222
308.4857 23.37039
308.9678 25.95920
309.4500 28.13449
309.9321 29.16571
310.4142 29.55865
310.8963 30.42108
311.3784 32.63165
311.8605 35.99121
312.3427 38.62903
312.8248 39.65726
313.3069 40.97260
313.7890 43.24362
314.2711 45.90485
314.7532 48.08902
315.2354 49.32761
315.7175 50.15167
316.1996 52.20432
316.6817 57.13589
317.1638 60.63562
317.6459 61.10147
318.1281 60.70715
318.6102 61.53323
319.0923 64.19250
319.5744 67.56927
320.0565 69.74457
320.5386 69.98346
321.0208 70.71202
321.5029 72.41019
321.9850 74.24625
322.4671 75.72878
322.9492 76.80048
323.4313 77.69147
323.9135 78.63934
324.3956 79.65527
324.8777 80.59973
325.3598 81.63939
325.8419 82.46039
326.3240 82.82574
326.8062 82.84653
327.2883 82.84070
327.7704 83.07932
328.2525 83.53688
328.7346 83.73059
329.2167 83.38187
329.6989 83.06989
330.1810 83.03821
330.6631 83.11220
331.1452 83.04311
331.6273 82.70047
332.1094 82.12027
332.5916 81.40036
333.0737 80.48030
333.5558 79.51622
334.0379 78.63983
334.5200 77.68481
335.0021 76.45546
335.4843 74.89182
335.9664 73.19502
336.4485 71.70465
336.9306 70.48203
337.4127 69.26788
337.8948 68.45789
338.3770 67.32477
338.8591 65.18890
339.3412 62.11800
339.8233 58.95815
340.3055 56.58957
340.7876 55.11243
341.2697 53.51520
341.7518 51.66042
342.2339 49.81732
342.7160 48.20515
343.1982 46.68439
343.6803 44.87735
344.1624 42.36533
344.6445 39.38849
345.1266 37.31560
345.6087 37.18930
346.0909 36.26530
346.5730 32.77029
347.0551 28.22778
347.5372 24.77112
348.0193 23.38527
348.5014 23.05328
348.9836 21.76956
349.4657 19.11592
349.9478 16.81299
350.4299 15.80588
350.9120 15.03394
351.3941 13.73674
351.8763 11.77611
352.3584 9.576828
352.8405 7.359039
353.3226 5.060211
353.8047 3.532516
354.2868 3.763931
354.7690 3.988510
355.2511 2.802383
355.7332 0.5295100
356.2153 1.359528
356.6974 1.401871
357.1795 0.2230990
357.6617 0.4737090
358.1438 3.012741
358.6259 5.236847
359.1080 5.193863
359.5901 3.963425
360.0722 3.295532
360.5544 4.105118
361.0365 5.421722
361.5186 5.884583
362.0007 5.419632
362.4828 4.680695
362.9649 3.587341
363.4471 2.545425
363.9292 2.075500
364.4113 2.326675
364.8934 2.714752
365.3755 2.795822
365.8576 2.618668
366.3398 2.496353
366.8219 2.609512
367.3040 2.621048
367.7861 2.064774
368.2682 1.006012
368.7503 0.1094820
369.2325 9.1399997E-02
369.7146 5.6853998E-02
370.1967 0.6582340
370.6788 2.052155
371.1609 3.529785
371.6430 4.686874
372.1252 5.489197
372.6073 5.807220
373.0894 5.122696
373.5715 4.342712
374.0536 4.141037
374.5357 4.472946
375.0179 5.097107
375.5000 5.939056
375.9821 6.971268
376.4642 8.172531
376.9463 9.719711
377.4284 11.00941
377.9106 11.60771
378.3927 11.84526
378.8748 12.41631
379.3569 13.56151
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380.3211 14.40239
380.8033 12.55786
381.2854 12.00154
381.7675 14.03056
382.2496 16.64075
382.7317 18.36002
383.2138 19.09503
383.6960 19.37241
384.1781 19.52911
384.6602 19.57402
385.1423 19.66362
385.6244 19.66238
386.1065 19.83878
386.5887 20.40591
387.0708 21.18515
387.5529 21.84380
388.0350 22.22878
388.5171 22.52016
388.9992 23.13202
389.4814 24.63652
389.9635 25.55818
390.4456 25.46135
390.9277 25.08255
391.4098 25.01212
391.8919 25.32855
392.3741 25.74301
392.8562 25.94276
393.3383 25.88153
393.8204 25.97827
394.3025 26.80620
394.7846 27.19498
395.2668 26.21330
395.7489 24.55441
396.2310 23.59608
396.7131 24.20802
397.1952 25.83694
397.6773 26.53117
398.1595 25.67168
398.6416 24.85646
399.1237 24.17126
399.6058 23.68280
400.0879 23.58136
400.5700 23.85704
401.0522 24.10069
401.5343 23.67752
402.0164 22.39758
402.4985 21.60550
402.9806 21.94429
403.4627 22.22313
403.9449 21.66179
404.4270 20.59439
404.9091 19.95827
405.3912 20.53172
405.8733 21.87967
406.3554 22.58328
406.8376 22.42223
407.3197 22.15245
407.8018 21.98666
408.2839 21.91728
408.7660 21.93971
409.2481 22.04951
409.7303 22.25394
410.2124 22.52562
410.6945 22.87459
411.1766 23.47888
411.6587 24.54228
412.1408 25.69930
412.6230 26.64940
413.1051 27.38692
413.5872 27.86920
414.0693 27.91780
414.5514 27.80971
415.0335 27.92111
415.5157 28.20149
415.9978 28.19920
416.4799 27.59383
416.9620 26.73749
417.4441 26.33286
417.9262 26.35626
418.4084 26.72105
418.8905 27.78490
419.3726 29.22841
419.8547 30.00594
420.3368 29.63055
420.8189 28.91672
421.3011 29.14775
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