#\#CIF_2.0
#------------------------------------------------------------------------------
#$Date: 2018-06-07 11:42:26 +0300 (Thu, 07 Jun 2018) $
#$Revision: 1245 $
#$URL: svn://172.16.1.111/rod/cif/1/00/06/1000655.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1000655
loop_
_publ_author_name
'Hawthorne, F. C.'
_publ_section_title
;
 The crystal chemistry of the amphiboles: V. The structure and chemistry
 of arfvedsonite
;
_journal_name_full               'The Canadian Mineralogist'
_journal_page_first              346
_journal_page_last               356
_journal_volume                  14
_journal_year                    1976
_chemical_compound_source        R110049
_chemical_formula_sum
'Al0.306 Ca0.158 Fe4.52 H2 K1.414 Mg0.11 Mn0.13 Na2.428 O24 Si7.84 Ti0.094'
_chemical_name_mineral           Arfvedsonite
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_cell_angle_alpha                90
_cell_angle_beta                 104.101
_cell_angle_gamma                90
_cell_length_a                   10.007
_cell_length_b                   18.077
_cell_length_c                   5.332
_cell_volume                     935.477
_exptl_crystal_density_diffrn    3.545
_cod_original_formula_sum
'Si7.84 Al.306 Fe4.52 Ti.094 Mn.13 Mg.11 Na2.428 Ca.158 K1.414 O24 H2'
_cod_database_code               9004105
_raman_determination_method      experimental
_raman_measurement_device.location 'Arizona University'
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.model  'Nicolet Almega XR'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.5
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 780
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 4
_raman_measurement_device.power_on_sample 12
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 400
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_rod_data_source.file            R110049.rod
_rod_data_source.block           3500000
_rod_database.code               1000655
loop_
_raman_complementary.id
_raman_complementary.method
1 XRD
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9004105 COD http://www.crystallography.net/cod/9004105.html
;
XRD analysis data was done.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
129.2086 0.0000000E+00
129.6907 6.028076
130.1729 11.60547
130.6550 17.17676
131.1371 12.26123
131.6192 3.751953
132.1013 1.620117
132.5834 2.114014
133.0656 1.333496
133.5477 1.514648
134.0298 0.4377440
134.5119 6.561523
134.9940 17.56055
135.4761 33.24829
135.9583 53.29834
136.4404 80.16064
136.9225 108.5190
137.4046 137.5862
137.8867 168.1914
138.3688 201.4214
138.8510 238.2168
139.3331 277.5366
139.8152 316.1335
140.2973 358.1943
140.7794 394.5020
141.2615 424.9814
141.7437 447.8948
142.2258 455.4822
142.7079 440.6377
143.1900 407.1226
143.6721 367.1230
144.1542 317.4653
144.6364 265.7788
145.1185 217.6641
145.6006 172.5295
146.0827 134.7146
146.5648 107.5608
147.0469 88.52344
147.5291 76.83740
148.0112 73.57349
148.4933 76.12036
148.9754 78.35034
149.4575 78.12622
149.9396 81.76318
150.4218 90.38892
150.9039 103.4656
151.3860 120.2998
151.8681 140.5894
152.3502 164.3806
152.8323 190.8940
153.3145 222.7927
153.7966 255.1724
154.2787 286.0913
154.7608 316.8276
155.2429 349.9661
155.7250 387.6763
156.2072 429.9883
156.6893 475.6672
157.1714 526.5430
157.6535 578.4849
158.1356 629.9089
158.6177 680.8193
159.0999 732.8884
159.5820 788.4341
160.0641 848.7356
160.5462 901.4817
161.0283 948.8574
161.5104 987.6555
161.9926 1016.477
162.4747 1035.050
162.9568 1041.434
163.4389 1032.028
163.9210 1007.221
164.4031 970.3025
164.8853 915.6440
165.3674 850.8232
165.8495 786.8833
166.3316 724.4656
166.8137 664.6169
167.2958 607.6633
167.7780 553.3716
168.2601 502.8577
168.7422 457.6838
169.2243 416.9629
169.7064 377.8494
170.1885 339.0569
170.6707 303.7104
171.1528 273.9282
171.6349 248.9849
172.1170 225.5378
172.5991 199.6873
173.0812 171.0461
173.5634 148.2798
174.0455 135.2498
174.5276 125.9456
175.0097 118.5046
175.4918 112.6804
175.9739 108.9617
176.4561 108.1138
176.9382 110.6887
177.4203 114.3467
177.9024 118.4949
178.3845 123.9871
178.8666 131.1875
179.3488 140.1731
179.8309 150.9954
180.3130 163.6091
180.7951 177.9666
181.2772 194.7056
181.7593 214.3210
182.2415 235.5840
182.7236 257.9546
183.2057 281.1821
183.6878 304.6343
184.1699 327.1765
184.6520 346.9548
185.1342 369.9822
185.6163 398.7834
186.0984 429.8296
186.5805 459.7939
187.0626 487.1887
187.5447 512.7729
188.0269 536.8528
188.5090 560.0808
188.9911 580.2163
189.4732 596.2344
189.9553 608.7419
190.4374 619.1633
190.9196 628.2280
191.4017 634.3281
191.8838 634.8579
192.3659 629.8516
192.8480 623.1594
193.3301 617.3884
193.8123 611.5383
194.2944 601.7493
194.7765 586.2073
195.2586 567.1079
195.7407 548.1113
196.2228 529.5977
196.7050 508.6248
197.1871 482.3345
197.6692 450.9651
198.1513 418.9241
198.6334 384.9907
199.1155 352.3235
199.5977 322.7866
200.0798 296.4297
200.5619 272.7063
201.0440 250.9863
201.5261 231.0190
202.0082 212.9666
202.4904 195.9927
202.9725 181.6157
203.4546 171.1902
203.9367 164.6438
204.4188 160.3352
204.9009 156.1936
205.3831 151.4900
205.8652 149.4204
206.3473 152.6987
206.8294 156.4551
207.3115 157.5708
207.7936 155.6714
208.2758 152.8657
208.7579 152.1282
209.2400 154.1492
209.7221 157.1196
210.2042 161.0085
210.6863 165.6477
211.1685 171.0217
211.6506 177.0867
212.1327 183.6860
212.6148 190.5864
213.0969 197.5186
213.5790 205.4250
214.0612 214.3904
214.5433 224.1514
215.0254 234.8467
215.5075 246.3735
215.9896 258.2214
216.4717 269.5925
216.9539 280.3689
217.4360 290.9456
217.9181 301.9932
218.4002 312.5291
218.8823 322.0046
219.3644 330.2681
219.8466 336.7388
220.3287 340.9460
220.8108 343.4417
221.2929 340.6760
221.7750 329.7144
222.2571 314.1492
222.7393 298.0400
223.2214 282.1770
223.7035 266.2781
224.1856 250.0681
224.6677 233.6331
225.1498 217.1538
225.6320 199.2429
226.1141 181.6694
226.5962 167.3508
227.0783 156.8865
227.5604 149.3440
228.0425 144.3115
228.5247 141.4141
229.0068 139.7175
229.4889 138.9524
229.9710 139.1741
230.4531 140.6199
230.9352 143.5925
231.4174 147.2615
231.8995 150.8962
232.3816 154.6243
232.8637 158.8789
233.3458 163.4636
233.8279 168.6907
234.3101 175.8777
234.7922 185.9827
235.2743 196.4810
235.7564 205.8262
236.2385 214.4343
236.7206 223.2039
237.2028 232.7368
237.6849 242.8035
238.1670 252.7764
238.6491 263.7859
239.1312 272.7690
239.6133 278.2231
240.0955 281.2161
240.5776 283.5632
241.0597 286.2598
241.5418 289.1660
242.0239 291.7866
242.5060 295.6167
242.9882 296.7932
243.4703 294.0396
243.9524 288.2686
244.4345 280.8770
244.9166 272.7595
245.3987 263.5327
245.8809 251.5520
246.3630 235.6162
246.8451 218.0767
247.3272 198.5967
247.8093 178.1313
248.2914 157.9626
248.7736 138.7673
249.2557 120.2854
249.7378 101.6140
250.2199 80.53687
250.7020 62.15161
251.1841 48.06836
251.6663 36.72607
252.1484 26.47803
252.6305 16.45801
253.1126 6.974121
253.5947 1.282471
254.0768 7.202148
254.5590 12.97827
255.0411 19.20557
255.5232 25.20020
256.0053 30.30469
256.4874 34.21387
256.9695 37.04028
257.4517 39.04785
257.9338 40.41748
258.4159 40.58008
258.8980 39.03638
259.3801 36.51392
259.8622 33.70923
260.3444 30.87305
260.8265 27.92017
261.3086 24.68140
261.7907 20.91772
262.2728 17.22290
262.7549 13.57080
263.2371 10.00342
263.7192 6.760498
264.2013 3.869873
264.6834 0.8107910
265.1655 3.293213
265.6476 9.182373
266.1298 14.31641
266.6119 18.12842
267.0940 21.48315
267.5761 25.14917
268.0582 29.29688
268.5403 33.64062
269.0225 37.90112
269.5046 42.11011
269.9867 46.03809
270.4688 50.28540
270.9509 53.88013
271.4330 55.08496
271.9152 53.90942
272.3973 53.53760
272.8794 57.58569
273.3615 66.45215
273.8436 72.78760
274.3257 74.21167
274.8079 74.67725
275.2900 77.09326
275.7721 81.60986
276.2542 87.14795
276.7363 93.17676
277.2184 99.61035
277.7006 105.8513
278.1827 111.1021
278.6648 116.7505
279.1469 124.2979
279.6290 133.4587
280.1111 141.8926
280.5933 147.6194
281.0754 151.7632
281.5575 158.2720
282.0396 169.0728
282.5217 179.8667
283.0038 187.8696
283.4860 193.4907
283.9681 198.9082
284.4502 205.0347
284.9323 211.6033
285.4144 217.8264
285.8965 223.1448
286.3787 229.4258
286.8608 238.7971
287.3429 250.2249
287.8250 259.8196
288.3071 265.5522
288.7892 269.9238
289.2714 276.7834
289.7535 286.3704
290.2356 295.8411
290.7177 303.8713
291.1998 310.7825
291.6819 317.5635
292.1641 324.5483
292.6462 331.1882
293.1283 337.4995
293.6104 343.4282
294.0925 347.1382
294.5746 347.4189
295.0568 345.0532
295.5389 341.5747
296.0210 337.2075
296.5031 331.5740
296.9852 324.0723
297.4673 315.0376
297.9495 304.8442
298.4316 293.4717
298.9137 281.1082
299.3958 267.5188
299.8779 252.2698
300.3600 237.8938
300.8422 226.7080
301.3243 217.5107
301.8064 208.6495
302.2885 199.9889
302.7706 191.1683
303.2527 181.3640
303.7349 170.4092
304.2170 160.2946
304.6991 152.3673
305.1812 145.6965
305.6633 138.8774
306.1454 131.4153
306.6276 124.6891
307.1097 120.4678
307.5918 118.5962
308.0739 116.0642
308.5560 111.4386
309.0381 106.1685
309.5203 101.6429
310.0024 97.78455
310.4845 95.07605
310.9666 94.66260
311.4487 95.63208
311.9308 94.66846
312.4130 90.11963
312.8951 84.93787
313.3772 82.11267
313.8593 81.31628
314.3414 80.32532
314.8235 77.79736
315.3057 74.35486
315.7878 71.67358
316.2699 70.36279
316.7520 69.03040
317.2341 65.91931
317.7162 62.01001
318.1984 59.50793
318.6805 60.14380
319.1626 62.25195
319.6447 62.89136
320.1268 61.61084
320.6089 61.14990
321.0911 63.87695
321.5732 68.17285
322.0553 71.94336
322.5374 75.00659
323.0195 77.17358
323.5016 77.72314
323.9838 76.51465
324.4659 75.28418
324.9480 74.03003
325.4301 73.62573
325.9122 75.43750
326.3943 79.99634
326.8765 84.35803
327.3586 85.96899
327.8407 85.34583
328.3228 85.34814
328.8049 86.82654
329.2870 88.86816
329.7692 90.93213
330.2513 92.95825
330.7334 93.89856
331.2155 91.94849
331.6976 88.66040
332.1797 88.24548
332.6619 92.23926
333.1440 96.01501
333.6261 94.57397
334.1082 89.89075
334.5903 86.54102
335.0724 85.47534
335.5546 86.70032
336.0367 91.31091
336.5188 99.68994
337.0009 107.1205
337.4830 109.7690
337.9651 110.0153
338.4473 112.3373
338.9294 117.7749
339.4115 124.4927
339.8936 131.3118
340.3757 138.2399
340.8578 145.1395
341.3400 151.9620
341.8221 158.7736
342.3042 165.2251
342.7863 170.8984
343.2684 178.4047
343.7505 190.3577
344.2327 205.0503
344.7148 218.0024
345.1969 227.6638
345.6790 237.0630
346.1611 249.6581
346.6432 264.9897
347.1254 281.9525
347.6075 301.3406
348.0896 321.6158
348.5717 341.1154
349.0538 359.8671
349.5359 376.9125
350.0181 390.8042
350.5002 402.2351
350.9823 414.7778
351.4644 428.5237
351.9465 443.2458
352.4286 460.4048
352.9108 479.1343
353.3929 495.3467
353.8750 506.8959
354.3571 514.5327
354.8392 520.4017
355.3214 524.7924
355.8035 527.2888
356.2856 527.7131
356.7677 526.1394
357.2498 522.6862
357.7319 517.3634
358.2141 510.2217
358.6962 500.9288
359.1783 489.2970
359.6604 476.7932
360.1425 462.2896
360.6246 447.7159
361.1068 435.2344
361.5889 424.8402
362.0710 414.7957
362.5531 403.2822
363.0352 390.4240
363.5173 380.6536
363.9995 375.9033
364.4816 371.9429
364.9637 366.5714
365.4458 360.3833
365.9279 355.0059
366.4100 351.2494
366.8922 348.9561
367.3743 347.7889
367.8564 347.2820
368.3385 348.4111
368.8206 353.5299
369.3027 359.4014
369.7849 361.8927
370.2670 359.9424
370.7491 356.0878
371.2312 353.8416
371.7133 354.0684
372.1954 353.3572
372.6776 351.5742
373.1597 349.0750
373.6418 346.6040
374.1239 343.7747
374.6060 339.0554
375.0881 330.9126
375.5703 319.5066
376.0524 309.2167
376.5345 301.5776
377.0166 293.2294
377.4987 282.6580
377.9808 271.0649
378.4630 260.0361
378.9451 250.3007
379.4272 241.7506
379.9093 234.3662
380.3914 230.2904
380.8735 223.5802
381.3557 211.8606
381.8378 199.2600
382.3199 188.8599
382.8020 180.9795
383.2841 173.9453
383.7662 165.8744
384.2484 156.5857
384.7305 147.2288
385.2126 137.7224
385.6947 128.2271
386.1768 118.1871
386.6589 108.2581
387.1411 99.72583
387.6232 93.49194
388.1053 88.82947
388.5874 83.18054
389.0695 75.91101
389.5516 69.21521
390.0338 63.28235
390.5159 58.25732
390.9980 54.58289
391.4801 52.31433
391.9622 50.36047
392.4443 47.18481
392.9265 42.69324
393.4086 38.35486
393.8907 34.70398
394.3728 30.97937
394.8549 26.52637
395.3370 21.68713
395.8192 17.60413
396.3013 14.97839
396.7834 13.47156
397.2655 12.56702
397.7476 12.70154
398.2297 12.24500
398.7119 9.945557
399.1940 6.893311
399.6761 4.367554
400.1582 2.729858
400.6403 1.536743
401.1224 0.4160160
401.6046 0.6535640
402.0867 1.612549
402.5688 2.452515
403.0509 3.160156
403.5330 3.799683
404.0151 4.380371
404.4973 4.667725
404.9794 4.048096
405.4615 3.211060
405.9436 3.573486
406.4257 5.415405
406.9078 7.427979
407.3900 8.885498
407.8721 9.599609
408.3542 9.009033
408.8363 5.423706
409.3184 1.978760
409.8005 1.292358
410.2827 2.576416
410.7648 3.067261
411.2469 1.511230
411.7290 1.439331
412.2111 4.419800
412.6932 7.407471
413.1754 10.45520
413.6575 13.65283
414.1396 16.85864
414.6217 19.93811
415.1038 22.85876
415.5859 25.73730
416.0681 28.84473
416.5502 32.31799
417.0323 34.10486
417.5144 32.27295
417.9965 31.03564
418.4786 32.30664
418.9608 35.40369
419.4429 38.69275
419.9250 41.30554
420.4071 43.93311
420.8892 48.66199
421.3713 59.26331
421.8535 66.01440
422.3356 66.66931
422.8177 65.12268
423.2998 63.88635
423.7819 63.54370
424.2640 63.81189
424.7462 64.53613
425.2283 65.76965
425.7104 66.58887
426.1925 66.97864
426.6746 66.92053
427.1567 66.36194
427.6389 65.36365
428.1210 63.90430
428.6031 61.88635
429.0852 59.75757
429.5673 58.55579
430.0494 58.58093
430.5316 58.43994
431.0137 58.11279
431.4958 57.30237
431.9779 55.81274
432.4600 53.62354
432.9421 50.81482
433.4243 47.12952
433.9064 42.80957
434.3885 38.83704
434.8706 35.20068
435.3527 32.00464
435.8348 29.67749
436.3170 27.75842
436.7991 25.39050
437.2812 22.07666
437.7633 18.67151
438.2454 16.15845
438.7275 14.36511
439.2097 12.07751
439.6918 8.532715
440.1739 4.864136
440.6560 2.978638
441.1381 2.927490
441.6202 2.860840
442.1024 2.476440
442.5845 1.703857
443.0666 0.2840580
443.5487 1.751953
444.0308 3.780273
444.5129 5.444214
444.9951 6.680420
445.4772 7.149658
445.9593 5.435303
446.4414 4.689575
446.9235 6.587036
447.4056 9.840454
447.8878 12.62708
448.3699 14.31396
448.8520 15.23413
449.3341 15.94836
449.8162 15.82288
450.2983 16.40137
450.7805 14.13770
451.2626 11.75513
451.7447 9.672729
452.2268 8.259399
452.7089 8.407227
453.1910 11.01929
453.6732 15.03906
454.1553 15.84558
454.6374 11.59644
455.1195 7.113037
455.6016 2.247192
456.0837 1.902466
456.5659 3.976563
457.0480 3.910889
457.5301 3.413208
458.0122 3.999390
458.4943 5.666992
458.9764 8.520264
459.4586 13.61646
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