#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-04-26 13:27:53 +0300 (Thu, 26 Apr 2018) $ #$Revision: 465 $ #$URL: svn://172.16.1.111/rod/cif/2/10/00/2100002.rod $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2100002 loop_ _publ_author_name 'Toman, K.' _publ_section_title ; Ordering in olivenite-adamite solid solutions Locality: Tsumeb, Southwest Africa ; _journal_name_full 'Acta Crystallographica, Section B' _journal_page_first 715 _journal_page_last 721 _journal_paper_doi 10.1107/S0567740878003933 _journal_volume 34 _journal_year 1978 _chemical_compound_source R050583 _chemical_formula_sum 'As Cu0.86 H O5 Zn1.14' _chemical_name_mineral Zincolivenite _space_group_IT_number 58 _symmetry_space_group_name_Hall '-P 2 2n' _symmetry_space_group_name_H-M 'P n n m' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 8.50 _cell_length_b 8.52 _cell_length_c 5.99 _cell_volume 433.796 _exptl_crystal_density_diffrn 4.366 _cod_original_formula_sum 'As Zn1.14 Cu.86 O5 H' _cod_database_code 9011188 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R050583.rod _rod_data_source.block 3500000 _rod_database.code 2100002 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9011188 COD http://www.crystallography.net/cod/9011188.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 142.6650 0.0000000E+00 143.1472 8.8623002E-02 143.6293 4.577148 144.1114 22.18811 144.5935 36.30481 145.0756 34.72803 145.5577 22.00293 146.0399 17.28516 146.5220 26.63220 147.0041 32.59668 147.4862 32.28296 147.9683 25.80432 148.4504 17.38843 148.9326 8.332520 149.4147 2.183594 149.8968 5.425903 150.3789 9.497070 150.8610 26.70068 151.3431 38.79822 151.8252 43.97168 152.3074 43.24438 152.7895 35.96960 153.2716 13.99646 153.7537 3.760254 154.2358 15.89575 154.7179 35.02673 155.2001 48.30188 155.6822 50.33081 156.1643 44.00537 156.6464 38.39282 157.1285 31.07910 157.6106 27.66577 158.0928 30.78809 158.5749 37.63159 159.0570 44.37085 159.5391 48.63379 160.0212 50.81226 160.5033 55.24432 160.9855 58.69299 161.4676 67.13928 161.9497 85.94427 162.4318 112.1252 162.9139 137.2571 163.3960 154.4248 163.8782 163.3109 164.3603 176.7980 164.8424 198.2694 165.3245 221.2670 165.8066 242.5109 166.2887 261.6390 166.7709 277.6345 167.2530 287.5393 167.7351 291.6482 168.2172 302.7487 168.6993 324.6655 169.1814 350.0074 169.6636 369.9556 170.1457 382.5110 170.6278 391.5449 171.1099 400.4324 171.5920 407.1083 172.0741 419.0204 172.5563 445.8484 173.0384 478.4857 173.5205 499.0959 174.0026 497.8882 174.4847 493.4249 174.9668 506.0020 175.4490 533.9810 175.9311 556.2497 176.4132 547.0085 176.8953 507.7544 177.3774 497.8798 177.8595 574.3235 178.3417 645.4760 178.8238 646.3859 179.3059 572.3957 179.7880 474.5682 180.2701 409.8905 180.7522 386.9586 181.2344 360.2906 181.7165 315.3006 182.1986 269.4156 182.6807 234.3120 183.1628 213.0896 183.6449 198.8175 184.1271 179.3137 184.6092 149.1042 185.0913 124.8536 185.5734 108.9273 186.0555 98.20203 186.5376 90.86957 187.0198 86.14594 187.5019 83.05804 187.9840 78.83313 188.4661 70.43103 188.9482 64.92590 189.4303 65.37451 189.9125 68.12781 190.3946 69.67126 190.8767 68.33368 191.3588 63.69604 191.8409 53.39801 192.3230 27.90637 192.8052 7.453552 193.2873 4.684082 193.7694 8.524109 194.2515 4.682251 194.7336 7.374756 195.2157 26.25641 195.6979 31.97913 196.1800 14.18347 196.6621 1.072571 197.1442 1.791626 197.6263 11.32477 198.1084 20.12952 198.5906 16.70886 199.0727 1.359070 199.5548 5.479858 200.0369 4.710571 200.5190 15.48822 201.0011 13.65833 201.4833 0.7336430 201.9654 7.879211 202.4475 1.053833 202.9296 26.20996 203.4117 46.77887 203.8938 61.19330 204.3760 71.43445 204.8581 77.76752 205.3402 80.03186 205.8223 82.47180 206.3044 87.41504 206.7865 95.17120 207.2687 107.1347 207.7508 126.4295 208.2329 149.5009 208.7150 170.2226 209.1971 187.5585 209.6792 205.2462 210.1614 227.0826 210.6435 251.5734 211.1256 275.4625 211.6077 296.4280 212.0898 316.1016 212.5719 338.1780 213.0541 363.4554 213.5362 389.9833 214.0183 415.3407 214.5004 440.4644 214.9825 468.2167 215.4646 502.6699 215.9468 541.5897 216.4289 573.5154 216.9110 590.0651 217.3931 611.6095 217.8752 656.7767 218.3573 717.2245 218.8395 768.6617 219.3216 786.9149 219.8037 775.4992 220.2858 780.8714 220.7679 822.3386 221.2500 860.8722 221.7322 877.9600 222.2143 876.5965 222.6964 868.7963 223.1785 865.5010 223.6606 867.3607 224.1427 858.9470 224.6249 830.3732 225.1070 799.3044 225.5891 773.6995 226.0712 752.2001 226.5533 728.1826 227.0354 693.9778 227.5176 647.6786 227.9997 605.4715 228.4818 569.9207 228.9639 536.5231 229.4460 504.5027 229.9281 473.5595 230.4103 443.3009 230.8924 413.9659 231.3745 386.0856 231.8566 356.0983 232.3387 319.7887 232.8208 284.8544 233.3030 253.6787 233.7851 226.9603 234.2672 205.6383 234.7493 192.1117 235.2314 190.9340 235.7135 180.6735 236.1957 152.2722 236.6778 123.7029 237.1599 103.7677 237.6420 93.50720 238.1241 89.95428 238.6062 90.79865 239.0884 99.54730 239.5705 100.6328 240.0526 92.79059 240.5347 79.95575 241.0168 59.56769 241.4989 33.92200 241.9811 13.36328 242.4632 11.55469 242.9453 39.84979 243.4274 51.10553 243.9095 32.38324 244.3916 8.898560 244.8738 4.146545 245.3559 4.517883 245.8380 1.102661 246.3201 5.298035 246.8022 7.583984 247.2843 9.762695 247.7665 15.09961 248.2486 18.13232 248.7307 13.03705 249.2128 8.5387997E-02 249.6949 14.68842 250.1770 23.84912 250.6592 27.00641 251.1413 24.26428 251.6234 6.632141 252.1055 10.90863 252.5876 13.78931 253.0697 1.067261 253.5519 13.35883 254.0340 13.37512 254.5161 6.377930 254.9982 19.59576 255.4803 23.15076 255.9624 22.51038 256.4445 18.87109 256.9267 13.13666 257.4088 11.35767 257.8909 22.19653 258.3730 48.87256 258.8551 70.51086 259.3372 84.99817 259.8194 95.13580 260.3015 103.7094 260.7836 110.7209 261.2657 116.9259 261.7478 121.8566 262.2299 124.9430 262.7121 136.8845 263.1942 162.5654 263.6763 193.9804 264.1584 227.8068 264.6405 263.0676 265.1227 292.8300 265.6048 306.1855 266.0869 302.0654 266.5690 318.7775 267.0511 377.1720 267.5332 443.3636 268.0154 487.5877 268.4975 508.3230 268.9796 525.4184 269.4617 554.0191 269.9438 595.1021 270.4259 638.9183 270.9081 689.5237 271.3902 739.7964 271.8723 781.2811 272.3544 814.5212 272.8365 851.0109 273.3186 900.7485 273.8008 963.1387 274.2829 1022.782 274.7650 1079.775 275.2471 1133.716 275.7292 1186.263 276.2113 1236.867 276.6935 1279.634 277.1756 1305.750 277.6577 1318.955 278.1398 1342.497 278.6219 1396.336 279.1040 1445.301 279.5862 1462.030 280.0683 1448.519 280.5504 1426.740 281.0325 1409.358 281.5146 1393.594 281.9967 1369.726 282.4789 1339.133 282.9610 1299.375 283.4431 1248.055 283.9252 1185.678 284.4073 1114.629 284.8894 1031.611 285.3716 943.4302 285.8537 868.9719 286.3358 815.4984 286.8179 767.6759 287.3000 717.4357 287.7821 665.7554 288.2643 617.4826 288.7464 574.3857 289.2285 536.2867 289.7106 502.0583 290.1927 474.6287 290.6748 446.3907 291.1570 409.4304 291.6391 368.0244 292.1212 336.4376 292.6033 322.3400 293.0854 318.3668 293.5675 310.1473 294.0497 297.3529 294.5318 282.6830 295.0139 264.8394 295.4960 245.8956 295.9781 231.2362 296.4602 223.5647 296.9424 218.8510 297.4245 209.1415 297.9066 192.5284 298.3887 180.2681 298.8708 179.5472 299.3529 184.7969 299.8351 185.8954 300.3172 179.7520 300.7993 170.9285 301.2814 166.2964 301.7635 166.5806 302.2456 163.6906 302.7278 153.3915 303.2099 139.6898 303.6920 126.2415 304.1741 112.9659 304.6562 103.9106 305.1383 106.4717 305.6205 121.5520 306.1026 130.9920 306.5847 130.8822 307.0668 124.5727 307.5489 112.4770 308.0310 95.11810 308.5132 79.77356 308.9953 73.46771 309.4774 77.79382 309.9595 84.40601 310.4416 92.56335 310.9237 102.0210 311.4059 114.7986 311.8880 130.8853 312.3701 142.6971 312.8522 141.0114 313.3343 126.5575 313.8164 118.3518 314.2986 121.0704 314.7807 125.5630 315.2628 126.6880 315.7449 124.9923 316.2270 123.2066 316.7091 122.6735 317.1913 123.5708 317.6734 126.5948 318.1555 133.1837 318.6376 139.9846 319.1197 146.7222 319.6018 152.7688 320.0840 157.0283 320.5661 159.1701 321.0482 158.7991 321.5303 154.0933 322.0124 142.8558 322.4945 131.1210 322.9767 117.0038 323.4588 103.8771 323.9409 98.20959 324.4230 102.8922 324.9051 112.2801 325.3872 114.9100 325.8694 105.8361 326.3515 98.67603 326.8336 98.88495 327.3157 99.34222 327.7978 91.31281 328.2799 72.87103 328.7621 50.77472 329.2442 33.94080 329.7263 24.45734 330.2084 16.24695 330.6905 7.868469 331.1726 1.692688 331.6548 1.126831 332.1369 5.629089 332.6190 9.856262 333.1011 7.768127 333.5832 2.690796 334.0653 7.581604 334.5475 1.159424 335.0296 4.979858 335.5117 2.871033 335.9938 5.381958 336.4759 11.94702 336.9580 10.47461 337.4402 1.126282 337.9223 5.332947 338.4044 7.994995 338.8865 8.915527 339.3686 7.349182 339.8507 4.475586 340.3329 2.610474 340.8150 3.239746 341.2971 5.429138 341.7792 4.653442 342.2613 8.282776 342.7434 12.34540 343.2256 4.546997 343.7077 27.23389 344.1898 38.58411 344.6719 32.29517 345.1540 15.34674 345.6361 3.326599 346.1183 3.356201 346.6004 5.028809 347.0825 2.947266 347.5646 11.81714 348.0467 14.79144 348.5288 10.75018 349.0110 4.102234 349.4931 0.3231200 349.9752 3.463867 350.4573 2.338623 350.9394 9.142456 351.4215 20.25647 351.9037 25.33630 352.3858 24.50732 352.8679 22.51349 353.3500 22.17090 353.8321 23.56506 354.3142 29.88251 354.7964 49.34369 355.2785 63.38306 355.7606 60.61957 356.2427 47.78223 356.7248 38.25281 357.2069 40.39850 357.6891 50.42706 358.1712 57.29047 358.6533 58.68378 359.1354 62.25568 359.6175 74.09027 360.0996 88.50586 360.5818 98.15619 361.0639 99.08716 361.5460 98.58032 362.0281 107.3702 362.5102 126.5888 362.9923 145.3644 363.4745 162.4440 363.9566 175.7939 364.4387 182.9534 364.9208 183.3043 365.4029 180.2583 365.8850 173.2569 366.3672 163.8714 366.8493 160.9105 367.3314 167.7282 367.8135 179.6038 368.2956 193.3713 368.7777 208.7717 369.2599 220.7787 369.7420 226.5470 370.2241 227.7581 370.7062 226.2170 371.1883 221.5577 371.6704 217.4459 372.1526 218.0924 372.6347 222.3823 373.1168 224.0593 373.5989 224.3349 374.0810 220.4371 374.5631 206.2678 375.0453 183.1730 375.5274 164.3456 376.0095 158.6663 376.4916 163.2538 376.9737 164.2094 377.4558 159.7263 377.9380 154.9460 378.4201 153.6254 378.9022 153.5372 379.3843 148.7520 379.8664 134.2355 380.3485 115.8667 380.8307 106.1131 381.3128 111.9724 381.7949 113.5333 382.2770 106.7512 382.7591 96.57047 383.2412 87.35522 383.7234 80.05295 384.2055 73.62784 384.6876 66.54529 385.1697 57.48364 385.6518 53.87006 386.1339 61.71420 386.6161 68.50635 387.0982 67.54825 387.5803 60.04395 388.0624 50.39795 388.5445 41.30310 389.0266 33.32629 389.5088 30.73492 389.9909 45.20651 390.4730 51.16833 390.9551 37.06543 391.4372 14.42471 391.9193 2.405701 392.4015 6.424164 392.8836 2.252045 393.3657 1.860016 393.8478 5.982483 394.3299 8.579895 394.8120 10.38629 395.2942 11.40805 395.7763 9.509369 396.2584 4.867340 396.7405 1.275940 397.2226 4.312378 397.7047 14.04614 398.1869 18.02121 398.6690 9.220276 399.1511 2.082397 399.6332 8.662872 400.1153 23.42780 400.5974 31.81122 401.0796 21.70114 401.5617 1.816284 402.0438 5.866028 402.5259 1.395447 403.0080 10.04507 403.4901 13.22531 403.9723 13.20953 404.4544 12.22305 404.9365 11.75314 405.4186 10.57004 405.9007 6.631439 406.3828 0.7032780 406.8650 2.394714 407.3471 0.2231140 407.8292 4.748047 408.3113 4.556641 408.7934 1.674835 409.2755 4.901276 409.7577 0.8538820 410.2398 9.981384 410.7219 14.35663 411.2040 12.51953 411.6861 9.151886 412.1682 9.171509 412.6504 13.24548 413.1325 14.34772 413.6146 6.540039 414.0967 1.254089 414.5788 7.975250 415.0609 23.15515 415.5431 35.63077 416.0252 38.39905 416.5073 33.37872 416.9894 29.60358 417.4715 26.66647 417.9536 25.55734 418.4358 26.72974 418.9179 29.62698 419.4000 35.27710 419.8821 43.50516 420.3642 50.22461 420.8463 47.61172 421.3285 29.10147 421.8106 19.52002 422.2927 26.42752 422.7748 35.11841 423.2569 38.57343 423.7390 37.23431 424.2212 35.41077 424.7033 36.55118 425.1854 40.03943 425.6675 41.89417 426.1496 40.74561 426.6317 40.27740 427.1139 45.28497 427.5960 50.59464 428.0781 48.36606 428.5602 34.00598 429.0423 16.78336 429.5244 9.348938 430.0066 11.95584 430.4887 12.63947 430.9708 6.447205 431.4529 1.535980 431.9350 5.564819 432.4171 5.494324 432.8993 4.434113 433.3814 5.565796 433.8635 6.273468 434.3456 1.411041 434.8277 20.07193 435.3098 33.75137 435.7920 24.48441 436.2741 5.290771 436.7562 20.40366 437.2383 6.545135 437.7204 10.15839 438.2025 12.85721 438.6847 5.576996 439.1668 1.312347 439.6489 6.614471 440.1310 18.40155 440.6131 28.45898 441.0952 39.31061 441.5774 44.76331 442.0595 42.00296 442.5416 35.23019 443.0237 27.02448 443.5058 18.44730 443.9879 11.07144 444.4701 6.986023 444.9522 6.891449 445.4343 5.207367 445.9164 1.863678 446.3985 6.669464 446.8806 6.186920 447.3628 1.680084 447.8449 4.554443 448.3270 11.58740 448.8091 18.85135 449.2912 25.67352 449.7733 33.25580 450.2555 35.80344 450.7376 24.50259 451.2197 12.93796 451.7018 13.94766 452.1839 29.38239 452.6660 43.40793 453.1482 39.92657 453.6303 23.23502 454.1124 13.96356 454.5945 16.33002 455.0766 22.06714 455.5587 25.85892 456.0409 27.69519 456.5230 26.64087 457.0051 17.64636 457.4872 9.424255 457.9693 10.67978 458.4514 20.12100 458.9336 31.71964 459.4156 44.69217 459.8978 54.80954 460.3799 49.75162 460.8620 13.09552 461.3441 6.484589 461.8262 14.97736 462.3083 49.37436 462.7905 66.51865 463.2726 61.37000 463.7547 48.36847 464.2368 42.16238 464.7189 43.39346 465.2010 44.97330 465.6832 44.32611 466.1653 46.45776 466.6474 54.79745 467.1295 66.42371 467.6116 77.39990 468.0938 85.08569 468.5759 90.46091 469.0580 95.49417 469.5401 100.0361 470.0222 104.6929 470.5043 107.1867 470.9865 111.5810 471.4686 123.0923 471.9507 140.9468 472.4328 155.9276 472.9149 157.5314 473.3970 150.2147 473.8792 151.0701 474.3613 162.9022 474.8434 176.6646 475.3255 186.0981 475.8076 193.3863 476.2897 203.2679 476.7719 217.5612 477.2540 233.1733 477.7361 249.7593 478.2182 266.1524 478.7003 277.2249 479.1824 279.7660 479.6646 281.5879 480.1467 296.8393 480.6288 334.1692 481.1109 356.8069 481.5930 351.9719 482.0751 340.3599 482.5573 333.4314 483.0394 333.1589 483.5215 340.5074 484.0036 357.3759 484.4857 381.3965 484.9678 396.8474 485.4500 400.0845 485.9321 398.7151 486.4142 394.7368 486.8963 386.3010 487.3784 368.4054 487.8605 341.4785 488.3427 315.6162 488.8248 303.0282 489.3069 304.6658 489.7890 305.9045 490.2711 308.0733 490.7532 307.5082 491.2354 301.0752 491.7175 290.6357 492.1996 280.7191 492.6817 271.6028 493.1638 264.2371 493.6459 260.0247 494.1281 258.4240 494.6102 257.9649 495.0923 261.4939 495.5744 265.7355 496.0565 264.9913 496.5386 258.9674 497.0208 250.8837 497.5029 237.1131 497.9850 224.3449 498.4671 219.2406 498.9492 222.2551 499.4313 230.9642 499.9135 244.7023 500.3956 262.5918 500.8777 273.0622 501.3598 267.1255 501.8419 264.4855 502.3240 272.5977 502.8062 283.6723 503.2883 286.9650 503.7704 279.9372 504.2525 272.0833 504.7346 279.3559 505.2167 305.4840 505.6989 319.0112 506.1810 310.2633 506.6631 298.7596 507.1452 291.8571 507.6273 289.4026 508.1094 290.8249 508.5916 298.9376 509.0737 307.2360 509.5558 306.0475 510.0379 295.6471 510.5200 283.9480 511.0021 273.7764 511.4843 263.3827 511.9664 249.2657 512.4485 230.6899 512.9306 214.3772 513.4127 203.2182 513.8948 194.4390 514.3770 185.7463 514.8591 176.8337 515.3412 168.0869 515.8233 160.1221 516.3054 152.9932 516.7875 143.1899 517.2697 121.8022 517.7518 108.1989 518.2339 113.4655 518.7160 122.6105 519.1981 118.8069 519.6802 100.5270 520.1624 79.92374 520.6445 71.32874 521.1266 75.07913 521.6087 77.04895 522.0908 76.82263 522.5729 75.30670 523.0551 73.12775 523.5372 70.03641 524.0193 65.19128 524.5014 57.25946 524.9835 50.02762 525.4656 48.46600 525.9478 51.39432 526.4299 52.27670 526.9120 49.10907 527.3941 44.29697 527.8762 40.41284 528.3583 37.47302 528.8405 34.82794 529.3226 33.38303 529.8047 31.36392 530.2868 26.72821 530.7689 20.49026 531.2510 14.93842 531.7332 11.07056 532.2153 9.628021 532.6974 12.96274 533.1795 26.46198 533.6616 34.83746 534.1437 35.93573 534.6259 34.09808 535.1080 31.00845 535.5901 27.33121 536.0722 23.80386 536.5543 20.59448 537.0364 18.13260 537.5186 18.05096 538.0007 20.82513 538.4828 24.17004 538.9649 27.24716 539.4470 30.49725 539.9291 35.25079 540.4113 42.21365 540.8934 46.12518 541.3755 43.05231 541.8576 35.79071 542.3397 27.96799 542.8218 20.09747 543.3040 13.08496 543.7861 7.759796 544.2682 3.903076 544.7503 0.3277890 545.2324 10.26895 545.7145 13.83099 546.1967 3.451019 546.6788 11.33322 547.1609 21.65756 547.6430 25.58710 548.1251 27.77505 548.6072 34.83731 549.0894 46.48380 549.5715 50.69568 550.0536 43.63599 550.5357 35.46774 551.0178 29.83218 551.4999 25.55304 551.9821 21.01981 552.4642 15.47540 552.9463 9.890198 553.4284 6.118073 553.9105 4.014465 554.3926 3.099335 554.8748 3.457062 555.3569 4.270355 555.8390 4.040100 556.3211 2.932892 556.8032 5.637970 557.2853 17.61151 557.7675 27.79340 558.2496 31.02444 558.7317 28.93466 559.2138 23.63266 559.6959 16.02319 560.1780 7.793365 560.6602 1.514465 561.1423 2.499176 561.6244 5.699432 562.1065 10.28528 562.5886 11.86096 563.0707 5.741272 563.5529 4.034912 564.0350 9.338776 564.5171 4.995178 564.9992 0.3211360 565.4813 9.033691 565.9634 31.61429 566.4456 42.39322 566.9277 31.39862 567.4098 14.83981 567.8919 11.30618 568.3740 19.19006 568.8561 23.25998 569.3383 15.21579 569.8204 8.234619 570.3025 14.13846 570.7846 27.87103 571.2667 37.28827 571.7488 36.88809 572.2310 29.33734 572.7131 18.77423 573.1952 1.442078 573.6773 8.696350 574.1594 8.767517 574.6415 4.974274 575.1237 2.409729 575.6058 11.46390 576.0879 18.93161 576.5700 22.96875 577.0521 24.96286 577.5342 26.66803 578.0164 28.07892 578.4985 30.00302 578.9806 33.50613 579.4627 36.25146 579.9448 34.49573 580.4269 28.89481 580.9091 25.72797 581.3912 30.56320 581.8733 34.24591 582.3554 27.91058 582.8375 15.37140 583.3196 6.659882 583.8018 6.038605 584.2839 9.888428 584.7660 11.95468 585.2481 11.10196 585.7302 11.69586 586.2123 15.73749 586.6945 19.16891 587.1766 19.51776 587.6587 18.42746 588.1408 18.76602 588.6229 22.15225 589.1050 25.90152 589.5872 24.86612 590.0693 19.24475 590.5514 14.56592 591.0335 11.55002 591.5156 10.51352 591.9977 12.26123 592.4799 16.49918 592.9620 21.64954 593.4441 29.85086 593.9262 36.59808 594.4083 39.61499 594.8904 39.15674 595.3726 34.71463 595.8547 26.26709 596.3368 17.24179 596.8189 12.41315 597.3010 11.87497 597.7831 15.06619 598.2653 27.34088 598.7474 37.78122 599.2295 43.01251 599.7116 44.13947 600.1937 42.90921 600.6758 39.78931 601.1580 35.19025 601.6401 29.12900 602.1222 21.83768 602.6043 12.96902 603.0864 0.1542660 603.5685 6.999725 604.0507 5.282074 604.5328 33.12570 605.0149 42.93530 605.4970 15.19186 605.9791 7.491882 606.4612 6.109344 606.9434 6.782776 607.4255 16.57169 607.9076 19.25647 608.3897 16.72665 608.8718 9.364044 609.3539 2.577087 609.8361 6.230713 610.3182 4.049561 610.8003 13.29578 611.2824 17.08798 611.7645 17.21744 612.2466 13.71088 612.7288 6.069946 613.2109 2.454987 613.6930 13.02155 614.1751 29.66318 614.6572 36.89603 615.1393 33.55713 615.6215 28.00732 616.1036 24.97562 616.5857 23.97754 617.0678 23.24762 617.5499 25.72467 618.0320 24.33386 618.5142 12.46838 618.9963 1.315094 619.4784 2.243011 619.9605 12.60892 620.4426 19.98026 620.9247 14.78131 621.4069 3.061981 621.8890 1.947723 622.3711 13.78802 622.8532 21.77811 623.3353 18.83084 623.8174 13.37112 624.2996 16.06381 624.7817 26.12146 625.2638 30.26797 625.7459 18.38297 626.2280 5.013824 626.7101 3.175995 627.1923 9.129364 627.6744 11.07803 628.1565 4.273346 628.6386 4.243713 629.1207 2.486206 629.6028 12.93832 630.0850 24.76373 630.5671 34.06641 631.0492 38.21219 631.5313 32.99341 632.0134 22.85748 632.4955 12.72025 632.9777 3.492889 633.4598 1.323273 633.9419 5.799530 634.4240 20.58447 634.9061 28.16882 635.3882 26.03568 635.8704 20.52716 636.3525 14.94443 636.8346 9.912689 637.3167 9.589386 637.7988 20.19916 638.2809 26.62381 638.7631 23.67987 639.2452 17.25848 639.7273 12.04169 640.2094 8.896118 640.6915 7.117035 641.1736 6.190460 641.6558 6.083710 642.1379 7.554047 642.6200 11.50122 643.1021 12.98715 643.5842 9.299927 644.0663 3.745789 644.5485 1.843231 645.0306 7.327332 645.5127 6.776489 645.9948 9.406250 646.4769 25.39502 646.9590 26.83401 647.4412 17.86707 647.9233 8.963745 648.4054 4.224976 648.8875 3.262482 649.3696 6.545959 649.8517 15.94992 650.3339 19.82880 650.8160 12.49469 651.2981 6.234436 651.7802 3.738770 652.2623 5.222076 652.7444 12.77179 653.2266 28.31625 653.7087 40.21841 654.1908 34.46823 654.6729 19.69031 655.1550 16.33990 655.6371 26.45132 656.1193 36.16876 656.6014 36.05008 657.0835 28.98434 657.5656 25.91382 658.0477 33.93317 658.5298 36.15994 659.0120 27.23077 659.4941 16.88965 659.9762 11.73105 660.4583 11.16083 660.9404 10.80704 661.4225 7.357086 661.9047 4.611298 662.3868 7.489044 662.8689 15.72867 663.3510 25.45285 663.8331 36.51010 664.3152 45.99625 664.7974 50.66592 665.2795 50.08929 665.7616 47.90936 666.2437 42.63440 666.7258 37.58316 667.2079 33.68375 667.6901 30.52347 668.1722 27.78421 668.6543 25.16321 669.1364 24.82584 669.6185 28.79272 670.1006 34.89972 670.5828 38.69467 671.0649 40.79306 671.5470 38.59317 672.0291 27.15921 672.5112 14.04083 672.9933 7.683075 673.4755 8.348053 673.9576 10.92093 674.4397 14.76944 674.9218 19.26834 675.4039 25.96292 675.8860 32.76187 676.3682 33.79840 676.8503 26.18594 677.3324 17.01828 677.8145 19.62341 678.2966 36.63943 678.7787 43.97787 679.2609 35.97449 679.7430 26.41504 680.2251 18.49643 680.7072 13.10245 681.1893 12.23880 681.6714 16.75665 682.1536 21.79562 682.6357 26.71552 683.1178 29.75607 683.5999 26.07144 684.0820 16.48734 684.5641 9.045593 685.0463 8.502350 685.5284 12.25497 686.0105 13.97040 686.4926 11.42157 686.9747 11.68668 687.4568 18.18277 687.9390 24.16882 688.4211 27.11493 688.9032 27.46161 689.3853 25.60190 689.8674 20.86057 690.3495 16.89749 690.8317 17.21701 691.3138 20.42892 691.7959 24.19312 692.2780 28.03699 692.7601 30.69333 693.2422 30.72537 693.7244 29.16602 694.2065 30.95126 694.6886 40.86816 695.1707 46.66422 695.6528 47.07816 696.1349 44.45956 696.6171 38.77444 697.0992 31.16357 697.5813 23.53973 698.0634 15.12149 698.5455 10.00620 699.0276 15.85364 699.5098 29.41348 699.9919 39.16849 700.4740 42.94736 700.9561 42.51645 701.4382 37.97354 701.9203 30.41315 702.4025 28.66202 702.8846 41.94489 703.3667 48.52893 703.8488 40.06088 704.3309 30.06052 704.8130 30.82620 705.2952 40.27774 705.7773 46.58115 706.2594 41.82266 706.7415 32.85831 707.2236 29.53021 707.7057 30.92038 708.1879 29.86249 708.6700 24.21658 709.1521 19.99356 709.6342 23.41281 710.1163 33.92325 710.5984 40.80365 711.0806 42.83707 711.5627 42.44470 712.0448 36.36282 712.5269 31.75433 713.0090 37.19495 713.4911 50.36929 713.9733 58.96240 714.4554 53.00488 714.9375 40.63895 715.4196 34.66745 715.9017 34.44983 716.3839 34.94757 716.8660 35.32104 717.3481 36.04199 717.8302 38.30859 718.3123 42.29315 718.7944 41.62030 719.2766 27.69937 719.7587 20.88147 720.2408 32.60654 720.7229 47.78391 721.2050 50.36786 721.6871 40.79608 722.1693 33.08929 722.6514 38.08755 723.1335 48.08450 723.6156 50.21939 724.0977 45.37634 724.5798 40.34808 725.0620 37.17307 725.5441 32.46957 726.0262 20.73291 726.5083 1.971619 726.9904 3.282227 727.4725 21.22260 727.9547 37.68954 728.4368 34.29575 728.9189 24.52689 729.4010 18.58783 729.8831 17.99863 730.3652 21.06357 730.8474 28.76459 731.3295 37.44672 731.8116 43.57349 732.2937 46.41217 732.7758 39.55704 733.2579 20.03345 733.7401 2.306610 734.2222 1.469666 734.7043 16.83801 735.1864 29.53244 735.6685 43.44839 736.1506 49.04129 736.6328 37.19614 737.1149 22.84137 737.5970 18.77570 738.0791 24.01614 738.5612 28.33408 739.0433 26.47427 739.5255 21.26987 740.0076 13.38705 740.4897 4.729980 740.9718 1.673035 741.4539 5.676392 741.9360 14.18283 742.4182 26.28983 742.9003 40.68436 743.3824 44.89893 743.8645 31.52328 744.3466 20.57394 744.8287 12.92133 745.3109 9.648163 745.7930 14.47232 746.2751 24.81805 746.7572 31.46884 747.2393 28.42859 747.7214 24.34531 748.2036 29.29941 748.6857 37.45920 749.1678 35.36508 749.6499 21.82370 750.1320 9.164032 750.6141 7.261719 751.0963 12.97571 751.5784 13.63843 752.0605 7.242584 752.5426 1.402405 753.0247 3.541443 753.5068 7.091797 753.9890 9.733826 754.4711 10.83057 754.9532 8.384644 755.4353 0.2769470 755.9174 8.368683 756.3995 11.57169 756.8817 12.87106 757.3638 16.63623 757.8459 22.33835 758.3280 25.44196 758.8101 22.94116 759.2922 17.26797 759.7744 13.46606 760.2565 11.70163 760.7386 10.34924 761.2207 9.473206 761.7028 8.583008 762.1849 7.553497 762.6671 6.236115 763.1492 4.049347 763.6313 0.3363950 764.1134 2.532196 764.5955 1.388977 765.0776 5.309601 765.5598 4.694489 766.0419 0.2464290 766.5240 6.676392 767.0061 15.64429 767.4882 22.20712 767.9703 17.35281 768.4525 4.129425 768.9346 1.148804 769.4167 10.74301 769.8988 19.64816 770.3809 21.56580 770.8630 18.42499 771.3452 13.27856 771.8273 3.536987 772.3094 0.4592590 772.7915 8.578491 773.2736 14.98804 773.7557 7.564575 774.2379 4.027130 774.7200 4.257568 775.2021 9.834808 775.6842 21.48682 776.1663 13.26144 776.6484 2.571289 777.1306 4.593903 777.6127 4.820343 778.0948 11.18094 778.5769 9.454163 779.0590 2.309235 779.5411 8.217468 780.0233 22.33749 780.5054 28.40173 780.9875 19.98541 781.4696 14.07047 781.9517 10.14520 782.4338 20.70212 782.9160 27.73743 783.3981 31.43781 783.8802 21.77484 784.3623 28.74075 784.8444 28.49585 785.3265 28.87018 785.8087 38.87531 786.2908 33.88217 786.7729 25.14090 787.2550 14.93033 787.7371 10.81891 788.2192 11.17624 788.7014 12.21820 789.1835 14.32748 789.6656 12.25937 790.1477 2.654968 790.6298 5.998596 791.1119 7.145355 791.5941 2.322784 792.0762 3.750183 792.5583 15.29593 793.0404 22.33990 793.5225 20.84680 794.0046 16.54742 794.4868 11.41885 794.9689 7.126190 795.4510 6.240662 795.9331 10.01941 796.4152 16.39737 796.8973 25.73672 797.3795 35.54883 797.8616 38.95178 798.3437 35.49066 798.8258 27.74374 799.3079 15.72314 799.7900 6.530579 800.2722 14.98038 800.7543 48.25644 801.2364 65.28754 801.7185 52.22806 802.2006 41.57556 802.6827 46.34210 803.1649 56.86624 803.6470 62.99771 804.1291 63.62891 804.6112 63.84360 805.0933 63.66443 805.5754 65.58203 806.0576 73.26538 806.5397 83.74759 807.0218 92.33636 807.5039 97.78976 807.9860 100.3499 808.4681 99.35468 808.9503 96.82141 809.4324 99.05963 809.9145 106.2428 810.3966 113.9869 810.8787 123.0407 811.3608 127.3922 811.8430 118.6238 812.3251 99.80603 812.8072 93.30109 813.2893 104.4081 813.7714 120.3884 814.2535 147.5808 814.7357 171.9902 815.2178 182.4981 815.6999 183.1441 816.1820 183.3639 816.6641 185.4729 817.1462 192.9001 817.6284 214.1755 818.1105 239.8870 818.5926 252.0468 819.0747 252.4064 819.5568 256.5590 820.0389 271.8265 820.5211 293.0128 821.0032 312.6482 821.4853 330.7042 821.9674 343.7168 822.4495 347.2535 822.9316 358.4080 823.4138 386.4503 823.8959 422.4935 824.3780 455.8181 824.8601 486.3741 825.3422 515.0030 825.8243 539.3931 826.3065 566.8703 826.7886 597.6966 827.2707 632.5981 827.7528 675.2252 828.2349 724.7419 828.7170 774.4594 829.1992 820.8754 829.6813 864.7307 830.1633 900.8495 830.6454 934.0304 831.1276 985.4623 831.6097 1058.524 832.0918 1129.694 832.5739 1182.538 833.0560 1221.723 833.5381 1260.995 834.0203 1302.398 834.5024 1342.778 834.9845 1382.612 835.4666 1418.921 835.9487 1450.716 836.4308 1478.202 836.9130 1500.946 837.3951 1518.312 837.8772 1532.178 838.3593 1541.966 838.8414 1549.270 839.3235 1555.061 839.8057 1558.995 840.2878 1557.971 840.7699 1552.698 841.2520 1552.207 841.7341 1562.447 842.2162 1583.207 842.6984 1616.736 843.1805 1661.170 843.6626 1705.125 844.1447 1745.620 844.6268 1790.493 845.1089 1846.647 845.5911 1912.685 846.0732 1983.756 846.5553 2059.190 847.0374 2141.014 847.5195 2234.754 848.0016 2329.471 848.4838 2421.630 848.9659 2509.889 849.4480 2592.360 849.9301 2672.164 850.4122 2737.576 850.8943 2778.611 851.3765 2811.032 851.8586 2855.740 852.3407 2895.895 852.8228 2899.882 853.3049 2860.094 853.7870 2799.880 854.2692 2737.526 854.7513 2669.651 855.2334 2589.452 855.7155 2497.930 856.1976 2398.078 856.6797 2290.793 857.1619 2182.372 857.6440 2077.204 858.1261 1975.430 858.6082 1874.903 859.0903 1772.119 859.5724 1680.811 860.0546 1603.971 860.5367 1536.550 861.0188 1474.795 861.5009 1420.115 861.9830 1376.064 862.4651 1342.328 862.9473 1319.642 863.4294 1311.336 863.9115 1311.096 864.3936 1312.654 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480.4173 891.8743 438.3419 892.3564 404.2320 892.8385 388.9640 893.3206 376.4646 893.8027 349.9479 894.2849 314.4255 894.7670 287.8597 895.2491 279.5023 895.7312 272.0146 896.2133 245.4151 896.6954 213.2937 897.1776 198.4576 897.6597 197.3134 898.1418 193.5192 898.6239 181.4354 899.1060 168.2403 899.5881 162.6174 900.0703 162.6166 900.5524 156.2735 901.0345 142.8624 901.5166 132.3386 901.9987 127.2895 902.4808 125.5186 902.9630 126.6349 903.4451 128.6453 903.9272 122.4444 904.4093 101.9243 904.8914 85.98553 905.3735 78.36066 905.8557 71.62051 906.3378 61.49838 906.8199 51.41461 907.3020 45.96378 907.7841 46.40497 908.2662 47.23560 908.7484 49.92386 909.2305 49.43045 909.7126 38.26865 910.1947 26.14944 910.6768 25.42645 911.1589 35.68634 911.6411 45.09357 912.1232 47.05771 912.6053 46.24619 913.0874 48.87921 913.5695 51.25198 914.0516 45.15060 914.5338 31.89352 915.0159 19.52786 915.4980 11.84473 915.9801 8.874176 916.4622 12.92673 916.9443 22.22095 917.4265 24.38440 917.9086 19.18771 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