#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:17:00 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1058 $ #$URL: svn://172.16.1.111/rod/cif/2/10/00/2100046.rod $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2100046 loop_ _publ_author_name 'Baur, W. H.' 'Khan, A. A.' _publ_section_title ; Rutile-type compounds. IV. SiO2, GeO2 and a comparison with other rutile-type structures ; _journal_issue 11 _journal_name_full 'Acta Crystallographica, Section B' _journal_page_first 2133 _journal_page_last 2139 _journal_paper_doi 10.1107/S0567740871005466 _journal_volume 27 _journal_year 1971 _chemical_compound_source R060563 _chemical_formula_sum 'O2 Sn' _chemical_name_mineral Cassiterite _space_group_IT_number 136 _symmetry_space_group_name_Hall '-P 4n 2n' _symmetry_space_group_name_H-M 'P 42/m n m' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 4.7380 _cell_length_b 4.7380 _cell_length_c 3.1865 _cell_volume 71.533 _exptl_crystal_density_diffrn 6.997 _cod_original_formula_sum 'Sn O2' _cod_database_code 9007533 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R060563.rod _rod_data_source.block 3500000 _rod_database.code 2100046 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9007533 COD http://www.crystallography.net/cod/9007533.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 89.78320 0.0000000E+00 90.26532 0.9230350 90.74744 2.979431 91.22955 4.488281 91.71167 8.092102 92.19379 20.57321 92.67590 40.04459 93.15802 54.79886 93.64014 53.03931 94.12225 39.93820 94.60437 30.50308 95.08649 28.45547 95.56860 30.13922 96.05072 29.82928 96.53284 28.81708 97.01495 28.74338 97.49707 27.78470 97.97919 23.27817 98.46130 17.35736 98.94342 12.85007 99.42554 10.25110 99.90765 10.36752 100.3898 14.21445 100.8719 18.65558 101.3540 18.80981 101.8361 13.66879 102.3182 8.134338 102.8004 3.945282 103.2825 1.240326 103.7646 0.7077940 104.2467 2.020020 104.7288 2.556396 105.2109 2.055603 105.6931 1.229065 106.1752 1.478699 106.6573 6.894928 107.1394 16.53412 107.6215 26.23752 108.1036 38.50629 108.5858 51.81674 109.0679 57.20502 109.5500 48.60046 110.0321 36.88535 110.5142 27.90024 110.9963 22.76727 111.4785 19.00253 111.9606 16.58487 112.4427 15.45230 112.9248 14.83389 113.4069 14.30478 113.8890 14.35611 114.3712 15.38519 114.8533 17.08426 115.3354 20.08514 115.8175 25.67078 116.2996 34.32834 116.7817 40.72604 117.2639 41.33331 117.7460 39.12381 118.2281 38.13876 118.7102 41.80017 119.1923 44.96091 119.6744 44.17899 120.1566 38.30020 120.6387 32.40640 121.1208 29.12244 121.6029 27.73264 122.0850 27.40894 122.5671 26.68149 123.0493 27.15857 123.5314 31.53677 124.0135 42.13983 124.4956 51.97827 124.9777 53.59802 125.4598 48.23935 125.9420 41.37802 126.4241 35.59912 126.9062 30.78320 127.3883 26.87225 127.8704 23.91095 128.3525 22.20508 128.8347 21.73691 129.3168 22.58716 129.7989 23.88544 130.2810 25.48727 130.7631 27.30011 131.2452 28.43616 131.7274 28.94193 132.2095 29.07947 132.6916 28.45151 133.1737 26.84274 133.6558 24.58179 134.1379 21.68811 134.6201 18.28143 135.1022 15.39233 135.5843 13.66721 136.0664 13.02429 136.5485 12.38617 137.0306 11.98685 137.5128 11.84247 137.9949 11.58435 138.4770 10.88632 138.9591 11.79596 139.4412 15.87695 139.9233 23.52911 140.4055 28.26709 140.8876 29.70215 141.3697 28.58578 141.8518 25.82635 142.3339 20.66714 142.8160 15.58597 143.2982 11.37399 143.7803 8.058197 144.2624 5.712097 144.7445 4.774750 145.2266 4.675354 145.7087 4.062439 146.1909 2.153015 146.6730 0.7210690 147.1551 0.5733950 147.6372 3.409058 148.1193 5.150330 148.6014 5.365814 149.0836 4.427124 149.5657 3.607819 150.0478 2.945618 150.5299 2.390533 151.0120 1.917633 151.4941 0.8799440 151.9763 0.6730040 152.4584 1.934052 152.9405 4.290436 153.4226 5.876099 153.9047 5.590485 154.3868 5.109253 154.8690 5.339020 155.3511 7.328705 155.8332 9.030121 156.3153 10.40372 156.7974 11.36407 157.2795 11.22476 157.7617 8.913940 158.2438 6.005035 158.7259 3.604065 159.2080 1.823364 159.6901 0.6654050 160.1722 0.3700870 160.6544 0.8757020 161.1365 1.284424 161.6186 1.181793 162.1007 0.8417050 162.5828 0.5586850 163.0649 0.3109130 163.5471 0.3514400 164.0292 1.252472 164.5113 2.984955 164.9934 3.994476 165.4755 2.780212 165.9576 0.5157470 166.4398 1.316284 166.9219 1.839874 167.4040 1.986023 167.8861 2.457977 168.3682 3.325684 168.8503 3.893585 169.3325 3.469727 169.8146 2.474609 170.2967 1.595856 170.7788 1.454712 171.2609 1.363739 171.7430 0.3700260 172.2252 1.753632 172.7073 3.358063 173.1894 2.624146 173.6715 0.3296200 174.1536 1.746368 174.6357 2.770569 175.1179 3.128876 175.6000 3.218719 176.0821 3.046417 176.5642 2.755646 177.0463 2.371399 177.5284 1.954041 178.0106 1.695251 178.4927 1.910370 178.9748 2.301178 179.4569 2.250458 179.9390 1.579559 180.4211 0.9148560 180.9033 1.314453 181.3854 2.514008 181.8675 3.264496 182.3496 2.434174 182.8317 0.6492000 183.3138 0.6476140 183.7960 1.256439 184.2781 1.455719 184.7602 1.360687 185.2423 1.041901 185.7244 1.093536 186.2065 2.121368 186.6887 3.865204 187.1708 5.438965 187.6529 6.818726 188.1350 7.834167 188.6171 7.872345 189.0992 6.964020 189.5814 6.235138 190.0635 6.680359 190.5456 8.089874 191.0277 8.921631 191.5098 8.891418 191.9919 8.397827 192.4741 8.112762 192.9562 8.027710 193.4383 8.322693 193.9204 9.278290 194.4025 10.85260 194.8846 12.34607 195.3668 13.73660 195.8489 14.93460 196.3310 15.60745 196.8131 15.68634 197.2952 15.75140 197.7773 16.11279 198.2595 16.76755 198.7416 17.89435 199.2237 19.65024 199.7058 21.76965 200.1879 23.44003 200.6700 24.58978 201.1522 25.70108 201.6343 27.02600 202.1164 28.54709 202.5985 30.56488 203.0806 33.33600 203.5627 36.49286 204.0449 38.61795 204.5270 39.39474 205.0091 40.14886 205.4912 41.92038 205.9733 44.76715 206.4554 47.61414 206.9376 50.37701 207.4197 53.03409 207.9018 55.48917 208.3839 57.54907 208.8660 59.90042 209.3481 63.10181 209.8303 67.45520 210.3124 71.58466 210.7945 75.15088 211.2766 78.34238 211.7587 82.18829 212.2408 86.85751 212.7230 91.85928 213.2051 96.85120 213.6872 101.6575 214.1693 107.0904 214.6514 113.2525 215.1335 120.0992 215.6157 127.1132 216.0978 134.2502 216.5799 141.7194 217.0620 149.7875 217.5441 158.6648 218.0262 167.4576 218.5084 175.9806 218.9905 184.4821 219.4726 193.6440 219.9547 203.4951 220.4368 214.1877 220.9189 225.7748 221.4011 238.6322 221.8832 251.7152 222.3653 264.9086 222.8474 278.2459 223.3295 292.5435 223.8116 307.5454 224.2938 323.2976 224.7759 339.9644 225.2580 357.6180 225.7401 375.7950 226.2222 394.9074 226.7043 414.5102 227.1865 433.5388 227.6686 450.9824 228.1507 468.8337 228.6328 488.1127 229.1149 509.5020 229.5970 530.5366 230.0792 550.3088 230.5613 569.5688 231.0434 590.7230 231.5255 613.7418 232.0076 638.2131 232.4897 663.8837 232.9719 691.2733 233.4540 718.6948 233.9361 746.0014 234.4182 773.4810 234.9003 802.6166 235.3824 834.2363 235.8646 866.3422 236.3467 897.9183 236.8288 928.5781 237.3109 959.6331 237.7930 991.6108 238.2751 1024.044 238.7573 1054.847 239.2394 1085.407 239.7215 1112.227 240.2036 1134.462 240.6857 1153.680 241.1678 1164.846 241.6500 1168.406 242.1321 1163.786 242.6142 1149.235 243.0963 1124.116 243.5784 1089.894 244.0605 1047.092 244.5427 993.8771 245.0248 935.9616 245.5069 871.4577 245.9890 802.7737 246.4711 735.8942 246.9532 669.3386 247.4354 606.0173 247.9175 547.5064 248.3996 493.4318 248.8817 444.3008 249.3638 400.5265 249.8459 361.4550 250.3281 326.0151 250.8102 294.4919 251.2923 266.0146 251.7744 239.9996 252.2565 216.6582 252.7386 195.9847 253.2208 178.4900 253.7029 163.3004 254.1850 148.6839 254.6671 134.1475 255.1492 121.0976 255.6313 110.3060 256.1135 102.1478 256.5956 93.85828 257.0777 85.24121 257.5598 76.77020 258.0419 69.14740 258.5240 62.69006 259.0062 56.51572 259.4883 50.21732 259.9704 43.83603 260.4525 38.41125 260.9346 34.16632 261.4167 30.68347 261.8989 27.56174 262.3810 24.92181 262.8631 22.39578 263.3452 19.81714 263.8273 17.16278 264.3094 15.34277 264.7916 14.53152 265.2737 14.23019 265.7558 13.84732 266.2379 13.13947 266.7200 13.21323 267.2021 14.45975 267.6843 16.75586 268.1664 18.91711 268.6485 20.89819 269.1306 22.82397 269.6127 24.79376 270.0948 26.82828 270.5770 28.76797 271.0591 30.57321 271.5412 32.24060 272.0233 33.74197 272.5054 34.94601 272.9875 36.27539 273.4697 37.93552 273.9518 39.89240 274.4339 42.45422 274.9160 45.57254 275.3981 49.35394 275.8802 54.14450 276.3624 59.82730 276.8445 66.75198 277.3266 74.91428 277.8087 84.25156 278.2908 95.73947 278.7729 109.3337 279.2551 125.2498 279.7372 143.6128 280.2193 164.5047 280.7014 187.8584 281.1835 214.1155 281.6656 243.2572 282.1478 274.1639 282.6299 307.2464 283.1120 341.1689 283.5941 375.3460 284.0762 410.1667 284.5583 439.5501 285.0405 463.9936 285.5226 482.4061 286.0047 483.7650 286.4868 466.8296 286.9689 436.7343 287.4510 396.1633 287.9332 345.6789 288.4153 296.4359 288.8974 252.8405 289.3795 214.4084 289.8616 181.1974 290.3438 153.3263 290.8259 129.8793 291.3080 110.3345 291.7901 94.66852 292.2722 81.66885 292.7543 71.63721 293.2365 63.85709 293.7186 56.95016 294.2007 50.98169 294.6828 45.70377 295.1649 40.96667 295.6470 36.79883 296.1292 33.12366 296.6113 30.00089 297.0934 27.34705 297.5755 25.07669 298.0576 23.16602 298.5397 21.45410 299.0219 19.83084 299.5040 18.27768 299.9861 16.76434 300.4682 15.25381 300.9503 13.90448 301.4324 12.87488 301.9146 12.16318 302.3967 11.68951 302.8788 11.63385 303.3609 11.73047 303.8430 11.60922 304.3251 11.23300 304.8073 10.73956 305.2894 10.30576 305.7715 9.831421 306.2536 9.050659 306.7357 7.376495 307.2178 5.586609 307.7000 4.631958 308.1821 4.658539 308.6642 4.779175 309.1463 4.212189 309.6284 3.326721 310.1105 2.685638 310.5927 2.873505 311.0748 3.139832 311.5569 2.832581 312.0390 1.950928 312.5211 1.203094 313.0032 1.087280 313.4854 1.266052 313.9675 1.395325 314.4496 1.379120 314.9317 1.258484 315.4138 0.9068600 315.8959 0.3971250 316.3781 0.1232300 316.8602 0.3598020 317.3423 0.8596190 317.8244 1.483215 318.3065 2.482727 318.7886 3.167145 319.2708 3.097076 319.7529 2.514648 320.2350 2.085358 320.7171 2.133240 321.1992 2.263168 321.6813 2.263229 322.1635 2.040039 322.6456 1.918152 323.1277 1.946136 323.6098 2.112900 324.0919 2.401505 324.5740 3.192032 325.0562 3.743973 325.5383 3.735123 326.0204 2.959595 326.5025 2.339081 326.9846 2.015030 327.4667 1.884735 327.9489 1.823883 328.4310 2.066116 328.9131 2.105042 329.3952 1.736633 329.8773 0.9294590 330.3594 0.3788450 330.8416 0.2662350 331.3237 0.3025360 331.8058 0.2855680 332.2879 0.1716610 332.7700 7.1990997E-02 333.2521 3.1326000E-02 333.7343 0.1415100 334.2164 0.2090760 334.6985 0.2280880 335.1806 0.1545870 335.6627 2.6047001E-02 336.1448 0.2940520 336.6270 0.5092320 337.1091 0.6790470 337.5912 0.8524780 338.0733 1.103455 338.5554 1.473221 339.0375 1.792114 339.5197 1.959900 340.0018 1.956787 340.4839 2.022705 340.9660 2.202072 341.4481 2.391464 341.9302 2.513657 342.4124 2.584274 342.8945 2.426300 343.3766 1.761093 343.8587 0.7814330 344.3408 0.5870670 344.8229 1.286392 345.3051 2.116852 345.7872 2.348785 346.2693 2.076462 346.7514 1.888809 347.2335 1.964066 347.7156 2.109924 348.1978 1.907715 348.6799 1.388824 349.1620 0.9022220 349.6441 0.7097170 350.1262 0.7077030 350.6083 0.6477660 351.0905 0.4718930 351.5726 0.3603820 352.0547 0.6556090 352.5368 1.203018 353.0189 1.542374 353.5010 1.303284 353.9832 0.7932890 354.4653 0.3446350 354.9474 3.5797000E-02 355.4295 0.3104550 355.9116 0.5228580 356.3937 0.6007080 356.8759 0.4272770 357.3580 0.4144440 357.8401 1.205551 358.3222 1.342224 358.8043 0.9231260 359.2864 0.5502010 359.7686 0.7669530 360.2507 1.045929 360.7328 0.9027710 361.2149 6.3079998E-02 361.6970 0.9671020 362.1791 1.494629 362.6613 1.710403 363.1434 1.751923 363.6255 1.448380 364.1076 1.156906 364.5897 1.051697 365.0718 1.186508 365.5540 1.377487 366.0361 1.650009 366.5182 1.942032 367.0003 2.178986 367.4824 2.378799 367.9645 2.491577 368.4467 2.457184 368.9288 2.259293 369.4109 2.156006 369.8930 2.191422 370.3751 2.281021 370.8572 2.376968 371.3394 2.531784 371.8215 2.591187 372.3036 2.517532 372.7857 2.341125 373.2678 2.165802 373.7499 1.978027 374.2321 1.822174 374.7142 1.740707 375.1963 1.780472 375.6784 1.694443 376.1605 1.434952 376.6426 1.113647 377.1248 0.9358520 377.6069 0.9417270 378.0890 0.8462220 378.5711 0.4811710 379.0532 9.0163998E-02 379.5353 0.3591310 380.0175 0.2895810 380.4996 0.1091160 380.9817 4.5469999E-03 381.4638 4.9500000E-02 381.9459 2.4307000E-02 382.4280 5.5725001E-02 382.9102 0.2279970 383.3923 0.6966090 383.8744 1.419144 384.3565 1.944138 384.8386 1.812119 385.3207 1.300629 385.8029 0.9468080 386.2850 0.7886050 386.7671 0.8434300 387.2492 1.328812 387.7313 2.048096 388.2134 2.545166 388.6956 2.476105 389.1777 2.181610 389.6598 1.898178 390.1419 1.640533 390.6240 1.505997 391.1061 1.775894 391.5883 2.107834 392.0704 2.103577 392.5525 1.211044 393.0346 0.5840000 393.5167 1.061951 393.9988 2.252090 394.4810 3.052811 394.9631 2.786560 395.4452 2.265869 395.9273 1.857040 396.4094 1.581329 396.8915 1.482468 397.3737 1.718918 397.8558 2.084427 398.3379 2.324829 398.8200 2.424530 399.3021 2.377716 399.7842 2.018906 400.2664 1.348923 400.7485 1.165649 401.2306 1.743835 401.7127 2.536453 402.1948 3.230453 402.6769 3.901825 403.1591 4.284531 403.6412 4.253296 404.1233 3.972321 404.6054 3.859482 405.0875 3.966660 405.5696 4.089081 406.0518 4.087341 406.5339 3.951569 407.0160 4.188339 407.4981 4.907074 407.9802 5.691498 408.4623 5.977524 408.9445 5.779999 409.4266 5.707077 409.9087 5.922394 410.3908 6.366577 410.8729 6.961365 411.3550 7.703476 411.8372 8.402603 412.3193 8.966461 412.8014 9.389862 413.2835 9.644684 413.7656 9.707779 414.2477 9.695053 414.7299 9.671417 415.2120 9.676926 415.6941 9.766602 416.1762 9.945038 416.6583 10.22838 417.1404 10.72185 417.6226 11.41574 418.1047 11.96414 418.5868 11.86899 419.0689 11.65813 419.5510 11.85507 420.0331 13.18793 420.5153 14.20425 420.9974 14.07961 421.4795 13.22302 421.9616 12.60304 422.4437 12.65869 422.9258 12.80617 423.4080 12.73679 423.8901 12.26288 424.3722 12.18590 424.8543 12.98792 425.3364 14.02870 425.8185 14.66391 426.3007 14.44374 426.7828 14.53494 427.2649 15.19804 427.7470 16.32274 428.2291 17.27083 428.7112 17.93970 429.1934 18.58437 429.6755 19.39342 430.1576 20.41347 430.6397 21.32784 431.1218 22.02379 431.6039 22.76942 432.0861 24.19812 432.5682 26.37308 433.0503 28.13484 433.5324 28.94830 434.0145 29.10883 434.4966 29.58315 434.9788 30.36900 435.4609 31.30560 435.9430 32.38019 436.4251 33.55211 436.9072 34.71381 437.3893 35.92436 437.8715 36.85637 438.3536 37.01172 438.8357 36.57756 439.3178 36.07008 439.7999 35.91624 440.2820 35.71101 440.7642 35.12695 441.2463 34.15433 441.7284 32.82611 442.2105 30.62738 442.6926 28.27507 443.1747 26.48009 443.6569 26.04498 444.1390 25.46382 444.6211 24.02759 445.1032 22.08252 445.5853 20.61821 446.0674 20.15413 446.5496 19.86563 447.0317 19.42010 447.5138 18.68188 447.9959 18.21449 448.4780 17.95422 448.9601 18.03705 449.4423 18.62627 449.9244 19.90706 450.4065 21.24806 450.8886 22.61960 451.3707 24.02646 451.8528 25.29852 452.3350 26.31177 452.8171 27.48073 453.2992 29.14143 453.7813 31.30899 454.2634 33.32587 454.7455 35.18108 455.2277 36.95651 455.7098 38.58705 456.1919 40.13776 456.6740 42.27637 457.1561 45.34384 457.6382 48.94406 458.1204 52.36823 458.6025 55.67696 459.0846 58.95111 459.5667 62.04309 460.0488 65.24448 460.5309 68.98921 461.0131 73.36270 461.4952 78.06354 461.9773 83.02600 462.4594 88.08388 462.9415 93.06975 463.4236 97.48724 463.9058 102.1362 464.3879 107.5691 464.8700 113.6513 465.3521 119.6763 465.8342 125.4375 466.3163 131.1981 466.7985 137.1154 467.2806 143.0728 467.7627 149.4566 468.2448 156.3416 468.7269 163.4314 469.2090 170.4310 469.6912 177.2070 470.1733 184.4711 470.6554 192.1573 471.1375 200.3211 471.6196 210.0727 472.1017 221.7487 472.5839 234.1509 473.0660 247.3827 473.5481 261.3780 474.0302 273.3831 474.5123 283.4978 474.9944 290.8209 475.4766 294.6001 475.9587 294.6003 476.4408 289.3650 476.9229 277.3587 477.4050 260.4892 477.8871 240.5324 478.3693 217.8436 478.8514 195.5549 479.3335 174.6488 479.8156 155.7821 480.2977 140.1051 480.7798 128.1427 481.2620 118.3200 481.7441 109.8381 482.2262 102.9172 482.7083 97.88446 483.1904 95.85893 483.6725 94.74963 484.1547 93.91403 484.6368 93.33798 485.1189 93.20100 485.6010 93.86401 486.0831 94.71338 486.5652 95.41245 487.0474 95.77103 487.5295 96.43155 488.0116 97.65442 488.4937 98.97437 488.9758 99.80008 489.4579 100.1624 489.9401 99.90343 490.4222 98.83585 490.9043 97.14078 491.3864 95.66727 491.8685 94.45941 492.3506 93.13541 492.8328 91.31256 493.3149 89.12601 493.7970 87.13870 494.2791 85.38638 494.7612 83.86118 495.2433 82.60196 495.7255 81.55353 496.2076 80.56168 496.6897 79.57693 497.1718 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524.1703 0.8260800 524.6525 2.342529 525.1346 3.993286 525.6167 4.875000 526.0988 4.391785 526.5809 3.402588 527.0630 3.607452 527.5452 4.817383 528.0273 5.948944 528.5094 6.249023 528.9915 6.181641 529.4736 6.323822 529.9557 6.729218 530.4379 6.962585 530.9200 6.605194 531.4021 6.025146 531.8842 5.599518 532.3663 5.721252 532.8484 5.580170 533.3306 4.785126 533.8127 3.607941 534.2948 2.647064 534.7769 2.009399 535.2590 1.514130 535.7411 1.256653 536.2233 1.218262 536.7054 0.5868840 537.1875 0.9311830 537.6696 2.471222 538.1517 3.390717 538.6339 3.610535 539.1160 4.213257 539.5981 5.318024 540.0802 6.632538 540.5623 8.048218 541.0444 9.453461 541.5266 10.22357 542.0087 9.920776 542.4908 9.164825 542.9729 8.883118 543.4550 8.937500 543.9371 8.781311 544.4193 7.796143 544.9014 6.671997 545.3835 6.046600 545.8656 5.998077 546.3477 5.894348 546.8298 5.581726 547.3120 5.041962 547.7941 4.246582 548.2762 2.530975 548.7583 1.466309 549.2404 1.572144 549.7225 2.270203 550.2047 2.564697 550.6868 2.175171 551.1689 1.925842 551.6510 2.045044 552.1331 2.481537 552.6152 2.873413 553.0974 3.197327 553.5795 3.613495 554.0616 4.337677 554.5437 5.290955 555.0258 5.928070 555.5079 6.184937 555.9901 6.432556 556.4722 7.032684 556.9543 7.923553 557.4364 9.007568 557.9185 10.41235 558.4006 11.74796 558.8828 12.48981 559.3649 12.92636 559.8470 13.75165 560.3291 15.52972 560.8112 17.48346 561.2933 19.19363 561.7755 20.63477 562.2576 22.46005 562.7397 25.42505 563.2218 28.21460 563.7039 30.15744 564.1860 30.88489 564.6682 31.68954 565.1503 32.46722 565.6324 33.47614 566.1145 35.08081 566.5966 37.34961 567.0787 39.80087 567.5609 42.37296 568.0430 45.03278 568.5251 47.65836 569.0072 50.27203 569.4893 52.81424 569.9714 55.15503 570.4536 57.48682 570.9357 60.09903 571.4178 62.97775 571.8999 66.03009 572.3820 69.18039 572.8641 72.45163 573.3463 75.79889 573.8284 79.21310 574.3105 82.80243 574.7926 86.82779 575.2747 90.96216 575.7568 94.77066 576.2390 97.93243 576.7211 101.2003 577.2032 104.5719 577.6853 108.1310 578.1674 112.0858 578.6495 116.5375 579.1317 121.1063 579.6138 125.7673 580.0959 130.4568 580.5780 134.4784 581.0601 137.8111 581.5422 141.0967 582.0244 145.1440 582.5065 149.5374 582.9886 153.0949 583.4707 155.6712 583.9528 158.0558 584.4349 160.6376 584.9171 163.4870 585.3992 166.7647 585.8813 171.6331 586.3634 175.8294 586.8455 178.0277 587.3276 178.7921 587.8098 179.5649 588.2919 180.5535 588.7740 181.7104 589.2561 183.1877 589.7382 184.9904 590.2203 186.1447 590.7025 186.6514 591.1846 186.5573 591.6667 185.7647 592.1488 184.2062 592.6309 182.5633 593.1130 180.7826 593.5952 179.1498 594.0773 178.4349 594.5594 178.2863 595.0415 177.1501 595.5236 174.2502 596.0057 170.8444 596.4879 168.6280 596.9700 167.0246 597.4521 164.6965 597.9342 160.3914 598.4163 155.7350 598.8984 151.5394 599.3806 147.7856 599.8627 144.2007 600.3448 140.9905 600.8269 137.7015 601.3090 133.9976 601.7911 129.6206 602.2733 125.8406 602.7554 122.9823 603.2375 120.2665 603.7196 116.8282 604.2017 112.4951 604.6838 108.9460 605.1660 106.3932 605.6481 104.5920 606.1302 103.5677 606.6123 103.1003 607.0944 102.1292 607.5765 99.82562 608.0587 97.24817 608.5408 95.64313 609.0229 94.81708 609.5050 94.02063 609.9871 92.56519 610.4692 91.27332 610.9514 90.78098 611.4335 91.16818 611.9156 91.36758 612.3977 90.79697 612.8798 90.25391 613.3619 90.17816 613.8441 90.56848 614.3262 91.42642 614.8083 92.69293 615.2904 94.51041 615.7725 97.11523 616.2546 100.5385 616.7368 104.1793 617.2189 107.7984 617.7010 111.8987 618.1831 117.4469 618.6652 124.2517 619.1473 131.6247 619.6295 139.2998 620.1116 147.2634 620.5937 155.2543 621.0758 163.3866 621.5579 172.5139 622.0400 183.0509 622.5222 194.4981 623.0043 206.5295 623.4864 219.0620 623.9685 232.4835 624.4506 246.5579 624.9327 261.7587 625.4149 278.4496 625.8970 296.4424 626.3791 316.0668 626.8612 337.5064 627.3433 360.2812 627.8254 383.7651 628.3076 407.9640 628.7897 433.0921 629.2718 459.3784 629.7539 486.4405 630.2360 513.9410 630.7181 541.5750 631.2003 568.0041 631.6824 593.7087 632.1645 617.1345 632.6466 638.2465 633.1287 656.5710 633.6108 668.0667 634.0930 671.8833 634.5751 668.2708 635.0572 656.8281 635.5393 637.0362 636.0214 611.9806 636.5035 580.2050 636.9857 544.7828 637.4678 507.5151 637.9499 468.0709 638.4320 429.9074 638.9141 393.3722 639.3962 358.8351 639.8784 326.7213 640.3605 297.3198 640.8426 270.5764 641.3247 246.9146 641.8068 225.6962 642.2889 205.9793 642.7711 188.0878 643.2532 172.2314 643.7353 159.6100 644.2174 148.2640 644.6995 137.1729 645.1816 126.5084 645.6638 117.2312 646.1459 110.3246 646.6280 104.0052 647.1101 97.56491 647.5922 91.00479 648.0743 85.35837 648.5565 80.89276 649.0386 76.98026 649.5207 73.30908 650.0028 69.83530 650.4849 66.42993 650.9670 63.12100 651.4492 59.82639 651.9313 56.34811 652.4134 52.85767 652.8955 49.84625 653.3776 47.59189 653.8597 45.34631 654.3419 42.37683 654.8240 39.11960 655.3061 36.33136 655.7882 34.73853 656.2703 33.06866 656.7524 30.90692 657.2346 28.45056 657.7167 26.28799 658.1988 24.47391 658.6809 22.81558 659.1630 21.27133 659.6451 19.84030 660.1273 18.57239 660.6094 17.44214 661.0915 16.23816 661.5736 14.58704 662.0557 12.81573 662.5378 11.69223 663.0200 11.24548 663.5021 10.69086 663.9842 9.199707 664.4663 7.508240 664.9484 6.313690 665.4305 5.912720 665.9127 5.509979 666.3948 4.884827 666.8769 4.218506 667.3590 3.689758 667.8411 3.396942 668.3232 3.048431 668.8054 2.599579 669.2875 2.128021 669.7696 1.775299 670.2517 1.543762 670.7338 1.346680 671.2159 1.091003 671.6981 0.9488220 672.1802 1.294281 672.6623 2.035339 673.1444 2.845215 673.6265 3.860138 674.1086 4.627411 674.5908 4.529755 675.0729 3.743866 675.5550 3.410400 676.0371 4.302704 676.5192 5.354065 677.0013 6.026703 677.4835 6.246368 677.9656 6.924438 678.4477 8.300323 678.9298 9.708282 679.4119 10.55670 679.8940 10.84387 680.3762 11.59988 680.8583 12.88010 681.3404 14.49811 681.8225 16.45285 682.3046 18.57687 682.7867 20.59036 683.2689 22.44910 683.7510 24.08771 684.2331 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