#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 11:27:56 +0300 (Thu, 07 Jun 2018) $ #$Revision: 1115 $ #$URL: svn://172.16.1.111/rod/cif/2/10/00/2100052.rod $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2100052 loop_ _publ_author_name 'Rossell, H. J.' _publ_section_title ; Calzirtite - A fluorite-related superstructure ; _journal_name_full 'Acta Crystallographica, Section B' _journal_page_first 593 _journal_page_last 595 _journal_paper_doi 10.1107/S0567740882003446 _journal_volume 38 _journal_year 1982 _chemical_compound_source Synthetic _chemical_formula_sum 'Ca O8 Ti Zr2.5' _chemical_name_mineral Calzirtite _space_group_IT_number 142 _symmetry_space_group_name_Hall '-I 4bd 2c' _symmetry_space_group_name_H-M 'I 41/a c d :2' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 15.2203 _cell_length_b 15.2203 _cell_length_c 10.1224 _cell_volume 2344.930 _exptl_crystal_density_diffrn 5.031 _cod_original_sg_symbol_H-M 'I 41/a c d' _cod_original_formula_sum 'Ca Ti Zr2.5 O8' _cod_database_code 9015981 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R080084.rod _rod_data_source.block 3500000 _rod_database.code 2100052 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9015981 COD http://www.crystallography.net/cod/9015981.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 97.34460 0.0000000E+00 97.82672 2.836060 98.30884 5.935669 98.79095 8.937744 99.27307 10.80627 99.75519 8.668579 100.2373 7.225464 100.7194 8.762695 101.2015 8.381470 101.6837 9.140259 102.1658 9.438110 102.6479 7.691650 103.1300 4.990601 103.6121 3.612061 104.0942 5.332886 104.5764 8.489990 105.0585 10.98584 105.5406 11.41052 106.0227 10.58630 106.5048 11.09412 106.9869 13.82031 107.4691 16.80237 107.9512 19.62512 108.4333 23.44299 108.9154 28.22083 109.3975 31.79492 109.8796 32.18628 110.3618 32.62866 110.8439 34.99744 111.3260 37.22375 111.8081 38.30676 112.2902 38.02490 112.7723 36.83276 113.2544 35.36816 113.7366 33.89502 114.2187 31.48950 114.7008 27.52686 115.1829 23.01758 115.6650 18.80005 116.1471 15.16418 116.6293 11.97009 117.1114 8.954102 117.5935 6.129150 118.0756 3.389771 118.5577 0.5104980 119.0398 2.334839 119.5220 4.797852 120.0041 6.920410 120.4862 8.283081 120.9683 8.273926 121.4504 6.386719 121.9325 4.058228 122.4147 2.469116 122.8968 1.690552 123.3789 0.8770750 123.8610 0.5982670 124.3431 2.249634 124.8252 3.431519 125.3074 3.552124 125.7895 3.556763 126.2716 5.580078 126.7537 10.65930 127.2358 15.99841 127.7179 21.25159 128.2001 26.05994 128.6822 29.93689 129.1643 32.39233 129.6464 33.59314 130.1285 35.47241 130.6107 38.19348 131.0928 41.55505 131.5749 46.08459 132.0570 51.28748 132.5391 56.19141 133.0212 59.83826 133.5034 61.99524 133.9855 64.61304 134.4676 67.01831 134.9497 70.29187 135.4318 75.95178 135.9139 83.76636 136.3960 91.18750 136.8782 94.77014 137.3603 93.35229 137.8424 94.49890 138.3245 100.2784 138.8066 108.2008 139.2887 115.7000 139.7709 122.3801 140.2530 127.8639 140.7351 131.0493 141.2172 132.1539 141.6993 133.3893 142.1814 135.7678 142.6636 139.0228 143.1457 142.2096 143.6278 145.0641 144.1099 147.8268 144.5920 150.7159 145.0741 153.7225 145.5563 156.8647 146.0384 160.3627 146.5205 164.3223 147.0026 167.6655 147.4847 169.5839 147.9668 171.2278 148.4490 173.3157 148.9311 175.9518 149.4132 178.6367 149.8953 180.3284 150.3774 179.6321 150.8595 181.1421 151.3417 186.5111 151.8238 192.9188 152.3059 198.0001 152.7880 200.8804 153.2701 202.5986 153.7522 205.6135 154.2344 212.6526 154.7165 217.8309 155.1986 220.5957 155.6807 221.5070 156.1628 221.4581 156.6449 220.8683 157.1271 219.6941 157.6092 217.6725 158.0913 214.7727 158.5734 211.2511 159.0555 207.1427 159.5376 202.4922 160.0198 197.2943 160.5019 191.3622 160.9840 184.9156 161.4661 179.0067 161.9482 175.0505 162.4303 170.3690 162.9125 162.2885 163.3946 150.9471 163.8767 140.3024 164.3588 133.1367 164.8409 128.2266 165.3230 123.4374 165.8052 118.7543 166.2873 113.7284 166.7694 107.1237 167.2515 97.88037 167.7336 90.75513 168.2157 89.62024 168.6979 91.38464 169.1800 92.53406 169.6621 91.26624 170.1442 88.66614 170.6263 87.97778 171.1084 90.80798 171.5906 93.03381 172.0727 92.24634 172.5548 90.31836 173.0369 89.95581 173.5190 93.00977 174.0011 99.04309 174.4833 104.3582 174.9654 108.6941 175.4475 112.3864 175.9296 114.8317 176.4117 116.6193 176.8938 118.8168 177.3760 122.2970 177.8581 127.1163 178.3402 131.9269 178.8223 137.1219 179.3044 142.1998 179.7865 146.6691 180.2687 150.7117 180.7508 154.9359 181.2329 159.8505 181.7150 165.5653 182.1971 171.5886 182.6792 179.2655 183.1614 186.0487 183.6435 190.0026 184.1256 191.2317 184.6077 191.8190 185.0898 193.7159 185.5719 196.9851 186.0541 199.0110 186.5362 199.2430 187.0183 198.4739 187.5004 197.4847 187.9825 196.3784 188.4646 194.6154 188.9468 191.5491 189.4289 187.3518 189.9110 182.4435 190.3931 177.0222 190.8752 170.9128 191.3573 163.7794 191.8395 155.5271 192.3216 146.3949 192.8037 135.8746 193.2858 124.6294 193.7679 114.1692 194.2500 106.1471 194.7322 99.56897 195.2143 90.76917 195.6964 78.03027 196.1785 65.69177 196.6606 56.11755 197.1427 48.61755 197.6249 41.77881 198.1070 34.52637 198.5891 27.00623 199.0712 20.79419 199.5533 16.69751 200.0354 13.14880 200.5176 9.532471 200.9997 5.971313 201.4818 2.843262 201.9639 0.5244140 202.4460 0.9703370 202.9281 2.458130 203.4103 4.303833 203.8924 5.786743 204.3745 6.681885 204.8566 7.013428 205.3387 6.888062 205.8208 6.390259 206.3030 5.499756 206.7851 4.306641 207.2672 2.404663 207.7493 0.5949710 208.2314 0.6102290 208.7135 1.369507 209.1957 2.314941 209.6778 4.128662 210.1599 7.059814 210.6420 8.696777 211.1241 7.881348 211.6062 7.027710 212.0884 7.047363 212.5705 8.109497 213.0526 10.32141 213.5347 14.02112 214.0168 19.44788 214.4989 23.85022 214.9811 27.14697 215.4632 29.61157 215.9453 31.16089 216.4274 31.88184 216.9095 32.42578 217.3916 33.51355 217.8737 35.09192 218.3559 35.57971 218.8380 33.06335 219.3201 30.68408 219.8022 31.70447 220.2843 36.36682 220.7664 41.38403 221.2486 44.03723 221.7307 44.80994 222.2128 45.75378 222.6949 46.90527 223.1770 48.48950 223.6591 50.77954 224.1413 53.80786 224.6234 57.33472 225.1055 61.46692 225.5876 65.94702 226.0697 70.34216 226.5518 74.69177 227.0340 78.78735 227.5161 82.16418 227.9982 84.60339 228.4803 87.05701 228.9624 90.10901 229.4445 93.47961 229.9267 96.86401 230.4088 100.0394 230.8909 103.2264 231.3730 107.0002 231.8551 111.8301 232.3372 116.0175 232.8194 118.2781 233.3015 119.7809 233.7836 121.9542 234.2657 125.5459 234.7478 129.8926 235.2299 133.4181 235.7121 135.6541 236.1942 138.0447 236.6763 141.5426 237.1584 145.2036 237.6405 147.8628 238.1227 148.9010 238.6048 149.1412 239.0869 150.9307 239.5690 156.2075 240.0511 159.5341 240.5332 159.2866 241.0154 157.2047 241.4975 154.7478 241.9796 152.5304 242.4617 150.6417 242.9438 149.4441 243.4259 149.8751 243.9081 149.4718 244.3902 147.6853 244.8723 145.1824 245.3544 142.5331 245.8365 139.9513 246.3186 137.4132 246.8008 134.8353 247.2829 132.3213 247.7650 129.5944 248.2471 126.6860 248.7292 123.5531 249.2113 119.7893 249.6935 115.3380 250.1756 111.0428 250.6577 108.6139 251.1398 110.0841 251.6219 110.5684 252.1040 109.2920 252.5862 107.4865 253.0683 105.9241 253.5504 104.9156 254.0325 104.8132 254.5146 106.2798 254.9967 110.5471 255.4789 114.2303 255.9610 116.5953 256.4431 118.8032 256.9252 121.7826 257.4073 125.7819 257.8894 130.6125 258.3716 136.0861 258.8537 142.4910 259.3358 148.9075 259.8179 154.6683 260.3000 160.8541 260.7821 168.5668 261.2643 177.9694 261.7464 188.1555 262.2285 198.2118 262.7106 208.1263 263.1927 218.3475 263.6748 228.6523 264.1570 239.3896 264.6391 250.9611 265.1212 263.3632 265.6033 276.0626 266.0854 288.7494 266.5675 301.3119 267.0497 312.3271 267.5318 320.8494 268.0139 328.3904 268.4960 335.6821 268.9781 342.8435 269.4602 350.9041 269.9424 360.8651 270.4245 372.4032 270.9066 383.1155 271.3887 392.9926 271.8708 401.9445 272.3529 409.6973 272.8351 416.4062 273.3172 422.9615 273.7993 429.9316 274.2814 437.0557 274.7635 443.6595 275.2456 449.4410 275.7278 454.9358 276.2099 460.9619 276.6920 467.3643 277.1741 472.5941 277.6562 475.6041 278.1383 476.9546 278.6205 478.2046 279.1026 479.3441 279.5847 480.2585 280.0668 481.2083 280.5489 482.0582 281.0310 481.8579 281.5132 480.1190 281.9953 477.1101 282.4774 473.7117 282.9595 470.0912 283.4416 465.2017 283.9237 458.0503 284.4059 448.9500 284.8880 439.1272 285.3701 428.5042 285.8522 418.0719 286.3343 409.2292 286.8164 401.8950 287.2986 393.7310 287.7807 383.2273 288.2628 370.8114 288.7449 357.9437 289.2270 344.4966 289.7091 331.2874 290.1913 318.4438 290.6734 306.1125 291.1555 294.7013 291.6376 285.2771 292.1197 276.9478 292.6018 267.1692 293.0840 255.3152 293.5661 243.6467 294.0482 233.6681 294.5303 224.9268 295.0124 216.5527 295.4945 208.8228 295.9767 201.0892 296.4588 191.7219 296.9409 179.9857 297.4230 169.2167 297.9051 161.2578 298.3872 155.1528 298.8694 150.2173 299.3515 146.7528 299.8336 143.4238 300.3157 138.3416 300.7978 131.2219 301.2799 124.0281 301.7621 116.8969 302.2442 110.3427 302.7263 105.1343 303.2084 101.6016 303.6905 98.23547 304.1726 92.95801 304.6548 85.64502 305.1369 79.78882 305.6190 77.65686 306.1011 76.12463 306.5832 72.39087 307.0653 66.36841 307.5475 60.74927 308.0296 58.13062 308.5117 58.24414 308.9938 57.71094 309.4759 55.90576 309.9580 53.57300 310.4402 51.30835 310.9223 49.04456 311.4044 46.46887 311.8865 42.88818 312.3686 38.73132 312.8507 35.90747 313.3329 34.99438 313.8150 34.50903 314.2971 33.58228 314.7792 32.44421 315.2613 31.54077 315.7434 31.23975 316.2256 31.17139 316.7077 30.46863 317.1898 28.88599 317.6719 27.28467 318.1540 25.91663 318.6361 24.77417 319.1183 24.02612 319.6004 23.90710 320.0825 23.64490 320.5646 21.94373 321.0467 18.52881 321.5288 15.42114 322.0110 13.18677 322.4931 11.59741 322.9752 10.67578 323.4573 10.44775 323.9394 10.41663 324.4215 10.50098 324.9037 10.68896 325.3858 9.545532 325.8679 5.877563 326.3500 1.705933 326.8321 2.141602 327.3142 5.443359 327.7964 7.178833 328.2785 5.425171 328.7606 1.150635 329.2427 0.7786870 329.7248 0.7308350 330.2069 3.211670 330.6891 5.838989 331.1712 8.230103 331.6533 9.477539 332.1354 8.581909 332.6175 6.586792 333.0996 5.586426 333.5818 5.744507 334.0639 6.389160 334.5460 7.885986 335.0281 9.441772 335.5102 10.05139 335.9923 9.310303 336.4745 7.931152 336.9566 6.468506 337.4387 4.876587 337.9208 4.046143 338.4029 5.031372 338.8850 6.375244 339.3671 6.523560 339.8492 5.285156 340.3314 3.920776 340.8135 3.760742 341.2956 4.488159 341.7777 3.856323 342.2598 0.5261230 342.7419 2.889648 343.2241 4.033936 343.7062 3.261841 344.1883 2.244873 344.6704 1.504883 345.1525 1.112061 345.6346 1.448364 346.1168 2.839966 346.5989 3.959229 347.0810 3.100342 347.5631 1.357056 348.0452 0.7126460 348.5273 2.127563 349.0095 4.440552 349.4916 6.956177 349.9737 9.713013 350.4558 10.71875 350.9379 7.693604 351.4200 3.128662 351.9022 1.111938 352.3843 2.411377 352.8664 4.655640 353.3485 6.678711 353.8306 8.444946 354.3127 9.781006 354.7949 10.57361 355.2770 11.01807 355.7591 11.03186 356.2412 10.59351 356.7233 11.03723 357.2054 13.88074 357.6876 17.57263 358.1697 19.35376 358.6518 18.64502 359.1339 17.64758 359.6160 18.33691 360.0981 20.43848 360.5803 22.43298 361.0624 24.28076 361.5445 25.85608 362.0266 26.82080 362.5087 27.27942 362.9908 28.05115 363.4730 29.71851 363.9551 31.94653 364.4372 33.67175 364.9193 34.60681 365.4014 35.55701 365.8835 36.88074 366.3657 38.44409 366.8478 39.90112 367.3299 41.07373 367.8120 42.36182 368.2941 44.66064 368.7762 48.45837 369.2584 51.06860 369.7405 51.28162 370.2226 50.62805 370.7047 50.49487 371.1868 51.07410 371.6689 52.00269 372.1511 53.01562 372.6332 54.11963 373.1153 55.00696 373.5974 55.45166 374.0795 55.93347 374.5616 56.50439 375.0438 57.28931 375.5259 58.68164 376.0080 61.00208 376.4901 63.83545 376.9722 65.68616 377.4543 64.97571 377.9365 65.31531 378.4186 68.15796 378.9007 71.73267 379.3828 73.98230 379.8649 74.37280 380.3470 73.96240 380.8292 74.23682 381.3113 75.51416 381.7934 76.52954 382.2755 77.23267 382.7576 77.75952 383.2397 78.08740 383.7219 78.29504 384.2040 78.55762 384.6861 78.84851 385.1682 79.15430 385.6503 79.68921 386.1324 80.90137 386.6146 82.40894 387.0967 84.37805 387.5788 86.17834 388.0609 87.07446 388.5430 86.76416 389.0251 85.75916 389.5073 85.09204 389.9894 84.96082 390.4715 85.21777 390.9536 85.97461 391.4357 86.79187 391.9178 87.42041 392.4000 87.77637 392.8821 87.90576 393.3642 87.75220 393.8463 87.36230 394.3284 87.93445 394.8105 90.62170 395.2927 92.96692 395.7748 93.76294 396.2569 93.57910 396.7390 93.58496 397.2211 94.50793 397.7032 95.97607 398.1854 96.77417 398.6675 96.29175 399.1496 96.69104 399.6317 99.84692 400.1138 103.6558 400.5959 106.3981 401.0781 107.6575 401.5602 108.2267 402.0423 108.7733 402.5244 109.2966 403.0065 109.6094 403.4886 109.3926 403.9708 109.5605 404.4529 110.9442 404.9350 113.0828 405.4171 114.8475 405.8992 115.2957 406.3813 115.5199 406.8635 117.4807 407.3456 121.4053 407.8277 124.7897 408.3098 125.9451 408.7919 125.8662 409.2740 126.3682 409.7562 127.8268 410.2383 129.5354 410.7204 131.0254 411.2025 132.3789 411.6846 133.7770 412.1667 135.1743 412.6489 136.9933 413.1310 140.0460 413.6131 144.3110 414.0952 148.1189 414.5773 150.8658 415.0594 153.0442 415.5416 154.7896 416.0237 156.3156 416.5058 158.6295 416.9879 162.5847 417.4700 167.8462 417.9521 172.3823 418.4343 175.0468 418.9164 178.2774 419.3985 182.9347 419.8806 188.4555 420.3627 194.2210 420.8448 200.0470 421.3270 205.5842 421.8091 210.1659 422.2912 212.9911 422.7733 216.9070 423.2554 222.9677 423.7375 229.3370 424.2197 234.8027 424.7018 239.4490 425.1839 244.0658 425.6660 249.2802 426.1481 254.8078 426.6302 259.1439 427.1124 260.9938 427.5945 263.4320 428.0766 266.9849 428.5587 271.1965 429.0408 275.7120 429.5229 280.3898 430.0051 285.1995 430.4872 290.2808 430.9693 295.9058 431.4514 300.6036 431.9335 304.2410 432.4156 306.9772 432.8978 308.1130 433.3799 308.3436 433.8620 309.3091 434.3441 312.1871 434.8262 316.3630 435.3083 320.3127 435.7905 324.4122 436.2726 327.1813 436.7547 327.3425 437.2368 326.3163 437.7189 325.1591 438.2010 324.0526 438.6832 322.9470 439.1653 322.2552 439.6474 321.6945 440.1295 319.4194 440.6116 314.3724 441.0938 309.0724 441.5759 305.9332 442.0580 304.3521 442.5401 302.5836 443.0222 301.0657 443.5043 298.5279 443.9865 293.0417 444.4686 284.9362 444.9507 277.0142 445.4328 270.7527 445.9149 265.2997 446.3970 258.6907 446.8792 250.6642 447.3613 242.5628 447.8434 234.6333 448.3255 226.8771 448.8076 219.3452 449.2897 212.0004 449.7719 204.7364 450.2540 197.5312 450.7361 190.3804 451.2182 182.5613 451.7003 172.8356 452.1824 163.8981 452.6646 157.4196 453.1467 152.2005 453.6288 146.1339 454.1109 138.2739 454.5930 129.6431 455.0751 122.2564 455.5573 117.0186 456.0394 111.2813 456.5215 104.8768 457.0036 98.20215 457.4857 91.03516 457.9678 83.72424 458.4500 77.07257 458.9321 71.74707 459.4142 67.59174 459.8963 63.65900 460.3784 60.11597 460.8605 56.52075 461.3427 52.68140 461.8248 48.74158 462.3069 44.97717 462.7890 41.45532 463.2711 37.53705 463.7532 31.92175 464.2354 24.81152 464.7175 19.82043 465.1996 18.41736 465.6817 17.52203 466.1638 14.52264 466.6459 10.28192 467.1281 7.016113 467.6102 6.057556 468.0923 5.849304 468.5744 4.738831 469.0565 2.789368 469.5386 0.8001100 470.0208 0.9484250 470.5029 2.549805 470.9850 4.349792 471.4671 6.632446 471.9492 7.816895 472.4313 6.386719 472.9135 4.320862 473.3956 3.687927 473.8777 4.658386 474.3598 6.494873 474.8419 8.833374 475.3240 11.54346 475.8062 13.27100 476.2883 13.68970 476.7704 13.67651 477.2525 13.15436 477.7346 12.38873 478.2167 11.78082 478.6989 11.39941 479.1810 10.81818 479.6631 9.330811 480.1452 6.561401 480.6273 4.867432 481.1094 5.317383 481.5916 5.771667 482.0737 5.795654 482.5558 5.300354 483.0379 4.135437 483.5200 2.153687 484.0021 0.1546630 484.4843 1.712708 484.9664 2.234985 485.4485 3.355225 485.9306 6.007690 486.4127 8.837036 486.8948 10.90540 487.3770 12.29370 487.8591 13.66058 488.3412 15.23334 488.8233 17.07843 489.3054 19.59064 489.7875 22.88489 490.2697 25.59595 490.7518 26.77051 491.2339 27.02069 491.7160 27.54889 492.1981 28.15881 492.6802 29.61292 493.1624 33.03766 493.6445 37.20496 494.1266 39.91974 494.6087 40.86774 495.0908 42.10052 495.5729 45.71136 496.0551 51.64349 496.5372 55.82526 497.0193 56.46130 497.5014 57.70422 497.9835 61.90326 498.4656 67.10895 498.9478 70.32355 499.4299 70.63556 499.9120 69.81946 500.3941 70.48773 500.8762 73.15857 501.3583 75.25311 501.8405 76.15204 502.3226 77.09497 502.8047 78.71484 503.2868 80.66791 503.7689 82.09875 504.2510 82.45435 504.7331 82.70496 505.2152 84.90234 505.6974 89.44373 506.1795 93.54517 506.6616 97.10760 507.1437 99.52502 507.6258 99.65057 508.1079 97.99829 508.5901 97.27313 509.0722 99.18518 509.5543 102.5833 510.0364 106.1578 510.5185 109.8734 511.0006 112.9053 511.4828 114.6324 511.9649 115.6249 512.4470 116.9396 512.9291 118.3668 513.4113 120.6631 513.8934 124.8789 514.3755 129.5282 514.8576 132.8716 515.3397 134.9006 515.8218 136.9351 516.3040 140.0560 516.7861 144.0093 517.2682 146.9202 517.7503 147.2146 518.2324 148.4177 518.7145 151.3531 519.1967 155.0472 519.6788 158.8311 520.1609 162.4484 520.6430 165.6095 521.1251 167.7452 521.6072 168.9307 522.0894 171.5918 522.5715 177.1099 523.0536 181.9145 523.5357 184.0168 524.0178 185.1875 524.4999 187.6253 524.9821 191.9907 525.4642 196.5502 525.9463 199.7880 526.4284 201.8594 526.9105 203.4915 527.3926 204.6130 527.8748 205.6198 528.3569 206.8375 528.8390 208.2109 529.3211 209.5868 529.8032 211.4224 530.2853 213.0310 530.7675 213.4788 531.2496 213.4011 531.7317 214.3344 532.2138 216.7205 532.6959 219.2633 533.1780 220.3505 533.6602 219.8062 534.1423 219.3940 534.6244 219.6573 535.1065 219.5243 535.5886 218.7115 536.0707 217.2040 536.5529 214.6957 537.0350 211.1415 537.5171 207.6024 537.9992 206.0253 538.4813 206.8197 538.9634 206.9725 539.4456 206.8085 539.9277 205.4522 540.4098 201.3385 540.8919 196.0178 541.3740 192.6313 541.8561 192.8357 542.3383 194.3576 542.8204 195.1028 543.3025 195.0067 543.7846 193.0207 544.2667 188.0297 544.7488 182.7197 545.2310 180.3758 545.7131 180.6484 546.1952 180.5928 546.6773 180.0310 547.1594 178.7882 547.6415 176.0284 548.1237 172.5130 548.6058 170.2405 549.0879 170.0752 549.5700 170.6732 550.0521 169.6826 550.5342 166.0181 551.0164 164.1617 551.4985 166.1358 551.9806 167.5941 552.4627 166.2648 552.9448 163.0729 553.4269 159.8412 553.9091 157.4025 554.3912 155.6191 554.8733 154.3412 555.3554 153.6213 555.8375 152.9657 556.3196 152.1246 556.8018 151.5630 557.2839 152.3392 557.7660 153.6460 558.2481 153.1429 558.7302 149.0560 559.2123 143.9503 559.6945 140.2651 560.1766 137.8124 560.6587 135.9114 561.1408 134.4907 561.6229 133.1071 562.1050 131.1684 562.5872 128.5878 563.0693 126.0381 563.5514 123.3194 564.0335 120.8575 564.5156 119.1258 564.9977 117.7646 565.4799 116.0717 565.9620 113.7795 566.4441 111.2280 566.9262 108.9835 567.4083 107.1723 567.8904 105.1445 568.3726 102.9528 568.8547 100.4547 569.3368 97.56940 569.8189 94.34143 570.3010 90.75330 570.7831 86.65851 571.2653 82.71777 571.7474 79.37500 572.2295 76.72882 572.7116 75.93439 573.1937 78.16443 573.6758 79.81311 574.1580 77.13580 574.6401 71.22278 575.1222 66.34167 575.6043 63.87299 576.0864 61.40253 576.5685 57.28265 577.0507 52.54688 577.5328 49.00433 578.0149 47.07697 578.4970 45.83136 578.9791 44.31500 579.4612 42.52118 579.9434 40.66815 580.4255 38.04565 580.9076 36.22827 581.3897 36.12195 581.8718 36.62634 582.3539 36.59326 582.8361 35.74841 583.3182 34.53003 583.8003 32.98499 584.2824 31.28595 584.7645 30.93359 585.2466 32.38812 585.7288 33.87354 586.2108 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719.2750 33.60065 719.7571 33.87921 720.2393 33.61169 720.7214 33.21265 721.2035 32.94861 721.6856 33.11835 722.1677 33.65729 722.6498 34.48096 723.1320 36.00653 723.6141 37.71582 724.0962 38.23853 724.5783 37.57623 725.0604 37.06104 725.5425 37.40112 726.0247 38.38165 726.5068 39.53259 726.9889 40.87933 727.4710 42.04388 727.9531 42.49481 728.4352 43.34955 728.9174 45.88019 729.3995 48.72913 729.8816 49.80170 730.3637 48.61719 730.8458 47.53357 731.3279 48.69745 731.8101 51.09906 732.2922 53.05054 732.7743 54.46710 733.2564 55.52264 733.7385 56.29688 734.2206 56.88470 734.7028 57.21875 735.1849 57.12445 735.6670 57.78229 736.1491 60.15088 736.6312 62.36554 737.1133 63.93390 737.5955 65.47314 738.0776 67.69183 738.5597 70.42859 739.0418 72.66388 739.5239 73.54449 740.0060 74.17310 740.4882 76.06342 740.9703 78.85413 741.4524 81.17883 741.9345 82.72028 742.4166 84.26843 742.8987 86.49017 743.3809 89.28088 743.8630 92.08160 744.3451 94.91620 744.8272 97.72687 745.3093 101.0076 745.7914 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