#------------------------------------------------------------------------------
#$Date: 2017-11-22 17:59:43 +0200 (Wed, 22 Nov 2017) $
#$Revision: 309 $
#$URL: svn://172.16.1.111/rod/cif/3/50/01/3500111.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500111
loop_
_publ_author_name
'El Mendili, Y'
_publ_section_title
;
 Raman spectrum of commercial Bi2O3
;
_journal_name_full               'Personal communication to ROD'
_journal_year                    2017
_chemical_compound_source        'commercial Alfa Aesar 99.5%'
_chemical_formula_structural     'Bi2 O3'
_chemical_formula_sum            'Bi2 O3'
_chemical_name_mineral           Sphaerobismoite
_chemical_name_systematic        'Bi2 O3'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 67.07
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.83
_cell_length_b                   8.14
_cell_length_c                   7.48
_raman_determination_method      experimental
_[local]_chemical_compound_color white
_[local]_chemical_compound_state Solid
_raman_measurement_device.location ENSICAEN
_raman_measurement_device.company 'Thermo Scientific'
_raman_measurement_device.name   DXR
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 20
_raman_measurement_device.microscope_numerical_aperture 0.25
_raman_measurement_device.excitation_laser_type other
_raman_measurement_device.excitation_laser_wavelength 785
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 3
_raman_measurement_device.power_on_sample 1
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1.3
_raman_measurement_device.diffraction_grating 900
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 30
_raman_measurement.range_min     5.050586e+001
_raman_measurement.range_max     2.000186e+003
_rod_data_source.file            Bi2O3.rod
_rod_data_source.block           1000005
_rod_database.code               3500111
_solsa_sample.id                 CN-AA00-0120
_raman_measurement.datetime_initiated 2017-10-10
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 neon_lamp
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 1010004 COD http://www.crystallography.net/cod/1010004.html
;
no XRD analysis data.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
5.050586e+001 1.052434e+003
5.147009e+001 9.927986e+002
5.243433e+001 9.071523e+002
5.339856e+001 8.087949e+002
5.436279e+001 6.988782e+002
5.532703e+001 5.784172e+002
5.629126e+001 4.653499e+002
5.725549e+001 3.634414e+002
5.821973e+001 2.758518e+002
5.918396e+001 2.073540e+002
6.014819e+001 1.558650e+002
6.111243e+001 1.259392e+002
6.207666e+001 1.248887e+002
6.304089e+001 1.544541e+002
6.400513e+001 2.140454e+002
6.496936e+001 3.048093e+002
6.593359e+001 4.261498e+002
6.689783e+001 5.566868e+002
6.786206e+001 6.944761e+002
6.882629e+001 8.379070e+002
6.979053e+001 9.562764e+002
7.075476e+001 1.021959e+003
7.171899e+001 1.059510e+003
7.268323e+001 1.106394e+003
7.364746e+001 1.147428e+003
7.461169e+001 1.205980e+003
7.557593e+001 1.306858e+003
7.654016e+001 1.436082e+003
7.750439e+001 1.641571e+003
7.846863e+001 1.952419e+003
7.943286e+001 2.359786e+003
8.039709e+001 2.873284e+003
8.136133e+001 3.531000e+003
8.232556e+001 4.320064e+003
8.328979e+001 5.148979e+003
8.425403e+001 6.071690e+003
8.521826e+001 6.979529e+003
8.618250e+001 7.693424e+003
8.714673e+001 8.218998e+003
8.811096e+001 8.531692e+003
8.907520e+001 8.568428e+003
9.003943e+001 8.291665e+003
9.100366e+001 7.845811e+003
9.196790e+001 7.308562e+003
9.293213e+001 6.682364e+003
9.389636e+001 6.058223e+003
9.486060e+001 5.461512e+003
9.582483e+001 4.897411e+003
9.678906e+001 4.375643e+003
9.775330e+001 3.900844e+003
9.871753e+001 3.479679e+003
9.968176e+001 3.102530e+003
1.006460e+002 2.779737e+003
1.016102e+002 2.495396e+003
1.025745e+002 2.239008e+003
1.035387e+002 2.011127e+003
1.045029e+002 1.809769e+003
1.054672e+002 1.639199e+003
1.064314e+002 1.497165e+003
1.073956e+002 1.367777e+003
1.083599e+002 1.247648e+003
1.093241e+002 1.139668e+003
1.102883e+002 1.046956e+003
1.112526e+002 9.699902e+002
1.122168e+002 9.119067e+002
1.131810e+002 8.780685e+002
1.141453e+002 8.550476e+002
1.151095e+002 8.626801e+002
1.160737e+002 9.052017e+002
1.170380e+002 9.839373e+002
1.180022e+002 1.107608e+003
1.189664e+002 1.285735e+003
1.199307e+002 1.528999e+003
1.208949e+002 1.794088e+003
1.218591e+002 2.130500e+003
1.228234e+002 2.466218e+003
1.237876e+002 2.750432e+003
1.247518e+002 2.973956e+003
1.257161e+002 3.115125e+003
1.266803e+002 3.119361e+003
1.276445e+002 2.941542e+003
1.286088e+002 2.687211e+003
1.295730e+002 2.314823e+003
1.305372e+002 1.875001e+003
1.315015e+002 1.458730e+003
1.324657e+002 1.117830e+003
1.334299e+002 8.547126e+002
1.343942e+002 6.621036e+002
1.353584e+002 5.537164e+002
1.363226e+002 4.886891e+002
1.372869e+002 4.490354e+002
1.382511e+002 4.357977e+002
1.392153e+002 4.398091e+002
1.401796e+002 4.498070e+002
1.411438e+002 4.684011e+002
1.421080e+002 4.909620e+002
1.430723e+002 5.174203e+002
1.440365e+002 5.483245e+002
1.450007e+002 5.829080e+002
1.459650e+002 6.202810e+002
1.469292e+002 6.622467e+002
1.478934e+002 7.173356e+002
1.488577e+002 7.902748e+002
1.498219e+002 8.727217e+002
1.507861e+002 9.675369e+002
1.517504e+002 1.071007e+003
1.527146e+002 1.175632e+003
1.536788e+002 1.277130e+003
1.546431e+002 1.377016e+003
1.556073e+002 1.467176e+003
1.565715e+002 1.557692e+003
1.575358e+002 1.632580e+003
1.585000e+002 1.684359e+003
1.594642e+002 1.711115e+003
1.604285e+002 1.711469e+003
1.613927e+002 1.679350e+003
1.623569e+002 1.604818e+003
1.633212e+002 1.519603e+003
1.642854e+002 1.426050e+003
1.652496e+002 1.329977e+003
1.662139e+002 1.239702e+003
1.671781e+002 1.156549e+003
1.681423e+002 1.081747e+003
1.691066e+002 1.020337e+003
1.700708e+002 9.777642e+002
1.710350e+002 9.414696e+002
1.719993e+002 9.025145e+002
1.729635e+002 8.610681e+002
1.739277e+002 8.166754e+002
1.748920e+002 7.667081e+002
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1.768204e+002 6.617437e+002
1.777847e+002 6.156550e+002
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1.797132e+002 5.361643e+002
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1.874270e+002 2.369154e+002
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1.893555e+002 1.714189e+002
1.903197e+002 1.427225e+002
1.912840e+002 1.164316e+002
1.922482e+002 9.400220e+001
1.932124e+002 7.782263e+001
1.941767e+002 7.328528e+001
1.951409e+002 6.867114e+001
1.961051e+002 6.362073e+001
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1.999621e+002 3.913269e+001
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2.028548e+002 2.942505e+001
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2.047832e+002 2.206433e+001
2.057475e+002 1.909143e+001
2.067117e+002 1.870361e+001
2.076759e+002 2.128845e+001
2.086402e+002 2.281079e+001
2.096044e+002 2.231470e+001
2.105686e+002 2.053345e+001
2.115329e+002 1.767480e+001
2.124971e+002 1.367297e+001
2.134613e+002 9.853760e+000
2.144256e+002 7.091431e+000
2.153898e+002 5.134766e+000
2.163540e+002 5.271118e+000
2.173183e+002 8.907471e+000
2.182825e+002 1.524487e+001
2.192467e+002 2.287793e+001
2.202110e+002 3.091431e+001
2.211752e+002 4.087964e+001
2.221394e+002 5.459705e+001
2.231037e+002 7.208569e+001
2.240679e+002 9.122809e+001
2.250321e+002 1.109815e+002
2.259964e+002 1.319492e+002
2.269606e+002 1.516478e+002
2.279248e+002 1.716853e+002
2.288891e+002 1.894789e+002
2.298533e+002 2.028314e+002
2.308175e+002 2.109720e+002
2.317818e+002 2.126810e+002
2.327460e+002 2.063136e+002
2.337102e+002 1.849445e+002
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2.366029e+002 1.277446e+002
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2.462453e+002 2.448950e+001
2.472095e+002 6.822388e+000
2.481737e+002 -6.699951e+000
2.491380e+002 -1.411523e+001
2.501022e+002 -1.787549e+001
2.510664e+002 -2.029773e+001
2.520307e+002 -2.141125e+001
2.529949e+002 -2.177148e+001
2.539591e+002 -2.185236e+001
2.549234e+002 -2.148407e+001
2.558876e+002 -1.990704e+001
2.568518e+002 -1.646954e+001
2.578160e+002 -1.187872e+001
2.587803e+002 -8.221375e+000
2.597445e+002 -8.347961e+000
2.607087e+002 -6.788208e+000
2.616730e+002 -1.447144e-001
2.626372e+002 1.093298e+001
2.636014e+002 2.358392e+001
2.645657e+002 3.566931e+001
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2.674584e+002 7.016858e+001
2.684226e+002 8.285187e+001
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2.703511e+002 1.111088e+002
2.713153e+002 1.255875e+002
2.722795e+002 1.388517e+002
2.732438e+002 1.505784e+002
2.742080e+002 1.604799e+002
2.751722e+002 1.681460e+002
2.761365e+002 1.743411e+002
2.771007e+002 1.795751e+002
2.780649e+002 1.843621e+002
2.790292e+002 1.887468e+002
2.799934e+002 1.917717e+002
2.809576e+002 1.933486e+002
2.819219e+002 1.971085e+002
2.828861e+002 2.044940e+002
2.838503e+002 2.149422e+002
2.848146e+002 2.264855e+002
2.857788e+002 2.384349e+002
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2.886715e+002 2.871095e+002
2.896357e+002 3.069346e+002
2.906000e+002 3.261445e+002
2.915642e+002 3.433964e+002
2.925284e+002 3.654804e+002
2.934927e+002 3.892887e+002
2.944569e+002 4.195888e+002
2.954211e+002 4.583409e+002
2.963854e+002 5.063041e+002
2.973496e+002 5.639875e+002
2.983138e+002 6.299628e+002
2.992781e+002 7.001152e+002
3.002423e+002 7.927125e+002
3.012065e+002 9.044514e+002
3.021708e+002 1.042737e+003
3.031350e+002 1.215381e+003
3.040992e+002 1.425321e+003
3.050635e+002 1.666919e+003
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3.098847e+002 3.295476e+003
3.108489e+002 3.606486e+003
3.118131e+002 3.881786e+003
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3.204912e+002 2.486555e+003
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