#------------------------------------------------------------------------------ #$Date: 2018-07-20 14:21:17 +0300 (Fri, 20 Jul 2018) $ #$Revision: 1268 $ #$URL: svn://172.16.1.111/rod/cif/3/50/01/3500170.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_3500170 loop_ _publ_author_name 'El Mendili, Y' 'Secchi, M' 'Zannatta, M' _journal_name_full 'Personal communication to ROD' _journal_year 2018 _chemical_compound_source 'commercial KMnO4 Alfa Aesar 99%' _chemical_formula_structural 'K Mn O4' _chemical_formula_sum 'K Mn O4' _chemical_name_systematic 'potassium permanganate' _space_group_IT_number 62 _symmetry_space_group_name_Hall '-P 2ac 2n' _symmetry_space_group_name_H-M 'P n m a' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 9.128 _cell_length_b 5.728 _cell_length_c 7.436 _raman_determination_method experimental _[local]_chemical_compound_color Green _[local]_chemical_compound_state Solid _raman_measurement_device.location 'University of Trento' _raman_measurement_device.company Horiba _raman_measurement_device.model Aramis _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 100 _raman_measurement_device.microscope_numerical_aperture 0.80 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 633 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 2 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 600 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 5 _raman_measurement.datetime_initiated 2018-01-18 _rod_data_source.file KMnO4.rod _rod_data_source.block 3500020 _rod_database.code 3500170 loop_ _raman_complementary.id _raman_complementary.method 1 EDX loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 silicon_wafer loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 1521179 COD http://www.crystallography.net/cod/1521179.html ; no XRD analysis data. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 102.305 903 104.549 955 106.791 944 109.033 987 111.274 991 113.514 1008 115.755 1023.5 117.994 989 120.233 1002 122.471 968 124.708 958.5 126.944 968 129.18 982 131.415 962.5 133.65 954 135.884 951 138.117 963 140.35 886 142.58 941.5 144.812 920 147.043 908.5 149.273 926 151.502 916.5 153.73 910 155.958 881 158.185 883 160.411 886 162.637 893 164.863 897 167.086 883 169.311 888 171.533 857.5 173.756 845 175.977 868.5 178.199 867 180.419 843 182.639 862 184.858 845 187.076 858 189.295 854 191.511 856 193.727 833 195.943 850 198.159 844 200.373 844.5 202.586 844 204.799 813 207.011 854 209.225 840 211.435 811 213.646 804.5 215.856 809 218.065 833 220.273 838.5 222.481 798.5 224.688 811 226.895 824.5 229.101 782 231.304 759 233.509 778 235.713 770 237.917 778 240.12 765 242.32 773.5 244.522 772 246.723 785.5 248.923 754 251.121 774 253.321 757 255.518 763 257.715 755.5 259.913 760 262.108 734 264.304 754.5 266.498 744 268.692 774.5 270.885 780 273.077 748 275.27 754 277.461 744 279.651 754.5 281.842 739.5 284.031 735 286.219 760.5 288.407 732 290.596 740.5 292.782 749 294.968 704 297.153 740 299.338 702.5 301.522 728 303.705 711 305.888 719.5 308.07 731 310.252 728 312.433 722 314.613 736 316.793 717 318.972 732.5 321.15 737.5 323.328 718 325.504 683 327.681 699 329.857 690 332.032 677 334.205 708 336.38 691.5 338.553 724 340.725 694 342.897 709 345.069 714 347.239 730 349.409 717 351.578 748 353.747 717 355.914 734 358.081 741.5 360.248 769.5 362.414 762 364.58 777 366.744 749 368.908 726 371.071 752 373.235 759 375.397 764 377.558 762 379.718 757 381.878 770.5 384.038 734 386.198 748 388.356 778 390.514 761 392.671 769 394.827 767.5 396.983 767.5 399.138 798.5 401.291 786.5 403.445 770 405.598 782 407.751 782.5 409.903 779 412.055 773 414.204 755 416.354 792.5 418.504 785.5 420.652 800 422.8 802.5 424.948 794 427.094 803 429.241 772 431.386 794 433.531 807 435.675 826.5 437.819 785.5 439.961 824.5 442.104 806.5 444.245 814.5 446.386 806 448.527 839 450.667 824.5 452.805 823.5 454.945 854.5 457.082 854.5 459.219 849 461.356 843 463.491 844 465.627 846 467.763 834.5 469.896 848.5 472.03 835 474.163 881 476.295 854 478.426 875.5 480.557 897.5 482.686 905 484.816 894.5 486.945 884 489.074 898.5 491.202 895.5 493.329 915 495.455 887 497.581 923.5 499.707 887 501.83 910.5 503.955 894 506.079 897 508.201 902.5 510.323 935 512.444 937.5 514.566 933.5 516.685 931.5 518.805 904.5 520.924 941.5 523.043 924 525.16 920 527.277 939.5 529.394 958 531.51 929 533.624 942.5 535.74 957 537.854 927 539.967 945.5 542.079 975 544.191 962.5 546.303 999 548.415 989 550.525 1037.5 552.634 1032.5 554.743 1049.5 556.852 1096 558.96 1076 561.065 1102.5 563.172 1147.5 565.278 1186.5 567.384 1196 569.489 1273.5 571.593 1281.5 573.695 1292 575.798 1336 577.901 1307 580.003 1323 582.103 1344.5 584.204 1348 586.303 1306 588.402 1327 590.501 1279.5 592.598 1300 594.696 1281 596.792 1252.5 598.888 1269 600.984 1298.5 603.078 1272 605.173 1317.5 607.266 1271 609.359 1302 611.452 1303.5 613.543 1330.5 615.634 1313 617.724 1327.5 619.814 1364.5 621.903 1355 623.993 1366 626.081 1361.5 628.168 1369 630.255 1318 632.341 1359 634.427 1358 636.512 1352 638.596 1334 640.679 1345 642.762 1363 644.845 1359 646.927 1331 649.008 1305 651.088 1300 653.168 1319 655.248 1318.5 657.327 1279 659.405 1257 661.483 1253 663.559 1215 665.636 1210 667.713 1202 669.787 1181 671.861 1167 673.936 1152.5 676.008 1105 678.082 1063.5 680.154 1065 682.225 1054 684.297 1007 686.367 1006 688.436 971.5 690.505 932 692.574 927 694.642 939 696.709 923 698.776 902 700.842 883.5 702.907 850 704.972 848 707.036 830.5 709.1 827 711.163 798.5 713.226 789 715.288 765 717.349 817.5 719.41 790 721.469 752 723.529 790 725.588 765 727.647 745 729.703 737.5 731.761 729 733.818 715 735.873 730 737.929 735 739.983 713 742.037 710 744.09 723.5 746.144 717 748.195 700 750.248 713.5 752.298 695 754.348 710 756.399 678 758.448 677 760.496 691.5 762.545 691 764.593 670 766.639 663.5 768.685 672.5 770.731 679.5 772.776 687.5 774.82 680 776.864 641 778.907 665 780.95 627.5 782.992 698 785.034 655 787.075 690 789.115 681.5 791.155 663 793.195 688.5 795.234 697 797.27 716.5 799.308 757 801.345 790 803.381 848 805.417 896.5 807.452 985.5 809.486 1194 811.52 1349 813.553 1416.5 815.586 1507.5 817.618 1758 819.65 2014.5 821.68 2225 823.71 1966 825.74 1555 827.769 1276.5 829.797 1083.5 831.826 968 833.853 946 835.88 906.5 837.905 863 839.931 858 841.957 840.5 843.981 883.5 846.005 948 848.028 1066.5 850.051 1221.5 852.073 1143 854.094 1004.5 856.115 866.5 858.134 768 860.154 730.5 862.174 728 864.192 716 866.211 718 868.227 693 870.244 678 872.261 681 874.275 683.5 876.291 695.5 878.306 650.5 880.319 688.5 882.333 674 884.345 654 886.358 667 888.369 634.5 890.38 644 892.39 634.5 894.399 619 896.409 646.5 898.418 627 900.425 624.5 902.432 639 904.44 656.5 906.446 635 908.452 629 910.457 674 912.461 685.5 914.465 683.5 916.468 682.5 918.471 674.5 920.474 693.5 922.475 697 924.476 684 926.477 676 928.477 645 930.477 616.5 932.476 626 934.473 601.5 936.471 592 938.468 596.5 940.464 586 942.46 560.5 944.456 590 946.45 578.5 948.445 574.5 950.437 580.5 952.431 576.5 954.423 570.5 956.415 573.5 958.406 569.5 960.398 577.5 962.387 581 964.377 589.5 966.366 576.5 968.354 558 970.342 554 972.329 552.5 974.315 586.5 976.303 570 978.288 564.5 980.273 581 982.257 566 984.241 563 986.224 567 988.207 553 990.189 561.5 992.171 558.5 994.151 566 996.131 559 998.111 524 1000.09 559.5 1002.07 537 1004.05 547.5 1006.03 543 1008 537.5 1009.98 554.5 1011.95 547.5 1013.93 549 1015.9 536 1017.88 544.5 1019.85 534 1021.82 527 1023.8 560 1025.77 536.5 1027.74 550.5 1029.71 523.5 1031.68 524.5 1033.65 524 1035.62 517 1037.59 519.5 1039.56 510 1041.52 511.5 1043.49 536 1045.46 513 1047.42 530 1049.39 517.5 1051.35 522 1053.32 515.5 1055.28 501 1057.24 508 1059.2 526.5 1061.17 540 1063.13 529.5 1065.09 517.5 1067.05 512.5 1069.01 502 1070.97 508 1072.92 511 1074.88 508 1076.84 513 1078.8 515 1080.75 504 1082.71 520 1084.66 509 1086.62 524.5 1088.57 510 1090.52 506 1092.48 520.5 1094.43 506 1096.38 522 1098.33 504 1100.28 492 1102.23 510.5 1104.18 509 1106.13 523 1108.08 507 1110.03 509.5 1111.97 516.5 1113.92 475 1115.87 498 1117.81 514 1119.76 512 1121.7 526.5 1123.65 481 1125.59 504 1127.53 512 1129.47 518.5 1131.42 506.5 1133.36 487 1135.3 505.5 1137.24 509 1139.18 504 1141.11 509 1143.05 510 1144.99 499.5 1146.93 505.5 1148.86 517.5 1150.8 517 1152.74 494.5 1154.67 503 1156.6 498 1158.54 512 1160.47 518.5 1162.4 514.5 1164.34 516.5 1166.27 518.5 1168.2 500 1170.13 515 1172.06 504.5 1173.99 507 1175.92 531 1177.85 508 1179.78 534 1181.7 510 1183.63 539 1185.55 548.5 1187.48 493 1189.41 522 1191.33 527.5 1193.25 516 1195.18 493 1197.1 530.5 1199.02 535 1200.94 494 1202.86 503 1204.79 525 1206.71 508 1208.63 484 1210.54 505 1212.46 499 1214.38 506 1216.3 516 1218.22 506 1220.13 500.5 1222.05 519.5 1223.96 518.5 1225.88 516 1227.79 532.5 1229.71 499 1231.62 514 1233.53 528.5 1235.44 492 1237.35 488 1239.26 508.5 1241.18 517 1243.08 497.5 1244.99 519.5 1246.9 514.5 1248.81 482.5 1250.72 494.5 1252.63 514.5 1254.53 494 1256.44 506.5 1258.34 488 1260.25 499.5 1262.15 498 1264.06 479 1265.96 489 1267.86 493.5 1269.76 501 1271.67 465 1273.57 487 1275.47 472 1277.37 482 1279.27 482.5 1281.17 477 1283.06 504 1284.96 503.5 1286.86 475 1288.76 479 1290.65 492 1292.55 483 1294.44 482.5 1296.34 472 1298.23 477.5 1300.13 473 1302.02 465 1303.91 494 1305.8 486 1307.7 471.5 1309.59 475 1311.48 496 1313.37 456 1315.26 487 1317.15 461 1319.03 478.5 1320.92 440.5 1322.81 470 1324.7 463 1326.58 470 1328.47 452 1330.35 436 1332.24 456 1334.12 464 1336 455 1337.89 451 1339.77 466.5 1341.65 452.5 1343.53 464 1345.41 457.5 1347.29 443.5 1349.17 443 1351.05 459.5 1352.93 445.5 1354.81 448.5 1356.69 462 1358.56 412 1360.44 450.5 1362.32 436.5 1364.19 451.5 1366.07 433 1367.94 439 1369.81 441 1371.69 430 1373.56 433 1375.43 435.5 1377.31 425.5 1379.18 439.5 1381.05 428 1382.92 435.5 1384.79 422 1386.66 438 1388.52 415 1390.39 439.5 1392.26 438.5 1394.13 443.5 1395.99 437 1397.86 440 1399.73 422 1401.59 423 1403.45 427 1405.32 414 1407.18 441.5 1409.04 431 1410.91 427 1412.77 423 1414.63 423 1416.49 424 1418.35 404.5 1420.21 429 1422.07 424 1423.93 421 1425.79 434.5 1427.64 425.5 1429.5 427.5 1431.36 415 1433.21 424 1435.07 422.5 1436.93 431 1438.78 420 1440.63 415 1442.49 418.5 1444.34 429 1446.19 446 1448.04 418 1449.89 428.5 1451.75 411 1453.6 417 1455.45 424 1457.3 430 1459.14 414 1460.99 433.5 1462.84 418.5 1464.69 438 1466.53 425 1468.38 434.5 1470.23 420.5 1472.07 447 1473.92 428 1475.76 444.5 1477.6 447 1479.45 425 1481.29 437 1483.13 428 1484.97 418 1486.81 429.5 1488.65 427 1490.49 443 1492.33 423 1494.17 444.5 1496.01 423.5 1497.85 425 1499.69 434 1501.52 422.5 1503.36 433.5 1505.19 447 1507.03 441 1508.87 407 1510.7 400.5 1512.53 431.5 1514.37 429.5 1516.2 422 1518.03 422.5 1519.86 441 1521.69 439.5 1523.53 406 1525.36 426.5 1527.19 426.5 1529.02 431 1530.84 432.5 1532.67 443.5 1534.5 417.5 1536.33 419.5 1538.15 433 1539.98 426 1541.8 432 1543.63 438 1545.45 440.5 1547.28 434 1549.1 437 1550.93 443.5 1552.75 439.5 1554.57 445 1556.39 433 1558.21 423.5 1560.03 442 1561.85 445 1563.67 441 1565.49 435 1567.31 421.5 1569.13 426.5 1570.95 442.5 1572.76 442.5 1574.58 458 1576.39 440.5 1578.21 446 1580.03 439.5 1581.84 438.5 1583.65 459 1585.47 429 1587.28 473.5 1589.09 471 1590.9 475 1592.72 470.5 1594.53 486.5 1596.34 492.5 1598.15 502.5 1599.96 522.5 1601.76 508 1603.57 539.5 1605.38 563.5 1607.19 565.5 1609 588.5 1610.8 615.5 1612.61 619.5 1614.41 623.5 1616.22 651.5 1618.02 611.5 1619.83 633.5 1621.63 671 1623.43 662.5 1625.23 703 1627.04 710.5 1628.84 747.5 1630.64 767.5 1632.44 742 1634.24 702 1636.04 698.5 1637.84 639.5 1639.63 633 1641.43 598 1643.23 601 1645.03 537 1646.82 555.5 1648.62 545.5 1650.42 528.5 1652.21 511.5 1654 516.5 1655.8 496 1657.59 492 1659.38 487.5 1661.18 483.5 1662.97 507.5 1664.76 487.5 1666.55 488 1668.34 474 1670.13 493 1671.92 457.5 1673.71 453.5 1675.5 479.5 1677.29 459.5 1679.07 448.5 1680.86 460 1682.65 446.5 1684.43 449.5 1686.22 468.5 1688 470.5 1689.79 459 1691.57 455 1693.35 445 1695.14 460.5 1696.92 460.5 1698.7 453 1700.48 457 1702.26 438 1704.04 446 1705.83 461 1707.6 436.5 1709.38 438 1711.16 443.5 1712.94 429.5 1714.72 425 1716.49 407.5 1718.27 424 1720.05 429 1721.82 424.5 1723.6 426.5 1725.37 440 1727.15 425.5 1728.92 414.5 1730.69 418 1732.47 439 1734.24 407 1736.01 409.5 1737.78 412 1739.55 433 1741.32 416.5 1743.09 426 1744.86 407.5 1746.63 393.5 1748.4 407 1750.16 403 1751.93 415 1753.7 431 1755.46 421.5 1757.23 397.5 1759 388 1760.76 399 1762.52 420 1764.29 413 1766.05 406.5 1767.82 392 1769.58 384 1771.34 397 1773.1 402.5 1774.86 394 1776.62 412 1778.38 404 1780.14 421.5 1781.9 395 1783.66 387 1785.42 398 1787.17 394.5 1788.93 392.5 1790.69 391 1792.44 401.5 1794.2 385 1795.95 400 1797.71 385.5 1799.46 372 1801.22 382.5 1802.97 397.5 1804.72 394 1806.48 394.5 1808.23 391.5 1809.98 393.5 1811.73 404.5 1813.48 388.5 1815.23 400.5 1816.98 394.5 1818.73 382.5 1820.48 377.5 1822.22 398 1823.97 372 1825.72 403.5 1827.46 374 1829.21 375.5 1830.96 377 1832.7 387.5 1834.44 365.5 1836.19 369 1837.93 373 1839.68 373.5 1841.42 379 1843.16 371.5 1844.9 382 1846.64 365.5 1848.38 355.5 1850.12 373.5 1851.86 365.5 1853.6 370.5 1855.34 366.5 1857.08 353.5 1858.82 362.5 1860.56 353 1862.29 374.5 1864.03 354 1865.77 351 1867.5 344.5 1869.24 375.5 1870.97 352 1872.7 366.5 1874.44 340.5 1876.17 344.5 1877.9 351.5 1879.63 357 1881.37 352.5 1883.1 339 1884.83 351 1886.56 361.5 1888.29 346 1890.02 353 1891.75 356 1893.47 351 1895.2 357 1896.93 348.5 1898.66 324 1900.38 363 1902.11 361 1903.83 343.5 1905.56 354 1907.28 348 1909.01 350 1910.73 312 1912.45 335.5 1914.18 344 1915.9 330 1917.62 326 1919.34 342.5 1921.06 343 1922.78 343.5 1924.5 341.5 1926.22 350.5 1927.94 343.5 1929.66 326 1931.38 315 1933.1 316 1934.81 336.5 1936.53 342 1938.24 356 1939.96 345 1941.68 321.5 1943.39 362.5 1945.1 330.5 1946.82 327 1948.53 327 1950.24 334.5 1951.96 336 1953.67 339 1955.38 341.5 1957.09 334 1958.8 318 1960.51 341.5 1962.22 331 1963.93 352 1965.64 347.5 1967.35 356.5 1969.05 344.5 1970.76 329 1972.47 350 1974.17 352 1975.88 350.5 1977.58 327 1979.29 337 1980.99 350 1982.7 330 1984.4 340.5 1986.1 340 1987.81 337 1989.51 341 1991.21 309 1992.91 343 1994.61 338 1996.31 335.5 1998.01 324 1999.71 327