#------------------------------------------------------------------------------
#$Date: 2018-07-20 14:21:17 +0300 (Fri, 20 Jul 2018) $
#$Revision: 1268 $
#$URL: svn://172.16.1.111/rod/cif/3/50/01/3500176.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500176
loop_
_publ_author_name
'El Mendili, Y'
'Secchi, M'
'Zannatta, M'
_journal_name_full               'Personal communication to ROD'
_journal_year                    2018
_chemical_compound_source        'commercial powder C STARCK BERLIN'
_chemical_formula_structural     'W O2'
_chemical_formula_sum            'O2 W'
_chemical_name_mineral           'Tungsten dioxide'
_chemical_name_systematic        'tungsten(IV) oxide'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 120.678(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.5769(2)
_cell_length_b                   4.8986(1)
_cell_length_c                   5.6644(2)
_cell_volume                     133.089(7)
_raman_determination_method      experimental
_[local]_chemical_compound_color Black
_[local]_chemical_compound_state Solid
_raman_measurement_device.location 'University of Trento'
_raman_measurement_device.company Horiba
_raman_measurement_device.model  Aramis
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 100
_raman_measurement_device.microscope_numerical_aperture 0.80
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 633
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 2
_raman_measurement_device.power_on_sample 12
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 600
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 5
_raman_measurement.datetime_initiated 2018-01-18
_rod_data_source.file            WO2.rod
_rod_data_source.block           3500019
_rod_database.code               3500176
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 silicon_wafer
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 1548686 COD http://www.crystallography.net/cod/1548686.html
;
 Entry contains the XRD analysis data of the same compound.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
102.305 14236.1
104.549 13164.7
106.791 12357
109.033 11623.3
111.274 11000.2
113.514 10571.8
115.755 10287.7
117.994 10102.6
120.233 10249.7
122.471 10773.3
124.708 12120.9
126.944 15064.6
129.18 20549.6
131.415 26898.7
133.65 28803.4
135.884 24116.3
138.117 17354.1
140.35 12563.3
142.58 10078.2
144.812 8702.11
147.043 8016.78
149.273 7616.78
151.502 7397.89
153.73 7258.33
155.958 7264.22
158.185 7269.33
160.411 7297.67
162.637 7342.56
164.863 7333.78
167.086 7404.67
169.311 7397.33
171.533 7426.11
173.756 7432.56
175.977 7573.78
178.199 7747.78
180.419 7998.56
182.639 8272.67
184.858 8485
187.076 8493.78
189.295 8289.56
191.511 8101.89
193.727 7693.22
195.943 7426.78
198.159 7252
200.373 7148.89
202.586 7075.56
204.799 7093.67
207.011 7230.44
209.225 7344.11
211.435 7252
213.646 7276.89
215.856 7371.78
218.065 7459.33
220.273 7603.89
222.481 7580.89
224.688 7371.33
226.895 7228.33
229.101 7202.11
231.304 7204
233.509 7309.78
235.713 7502.22
237.917 7773.11
240.12 7947.11
242.32 8224.56
244.522 8494.67
246.723 8847.56
248.923 9347.22
251.121 9999.22
253.321 10819.9
255.518 12013.1
257.715 13613.8
259.913 15935.8
262.108 19285
264.304 23674.3
266.498 28370
268.692 31506.1
270.885 31461.6
273.077 27910.6
275.27 22639
277.461 17756.8
279.651 14119.8
281.842 11529.9
284.031 9883.56
286.219 8794.67
288.407 8108.67
290.596 7727.89
292.782 7505.44
294.968 7363.44
297.153 7121.44
299.338 6828.11
301.522 6507.33
303.705 6317.22
305.888 6210.44
308.07 6259.89
310.252 6394
312.433 6723.11
314.613 7151.89
316.793 7738.67
318.972 8441
321.15 9111.89
323.328 9955
325.504 10749.9
327.681 11344
329.857 11381.9
332.032 10687.3
334.205 9320.89
336.38 7833
338.553 6647.67
340.725 5900.22
342.897 5387.67
345.069 5167.78
347.239 5039.22
349.409 5037.56
351.578 4965.11
353.747 4794.56
355.914 4515.67
358.081 4244.78
360.248 4076
362.414 3921.67
364.58 3898.11
366.744 3893.44
368.908 3875.67
371.071 3927.22
373.235 3916.67
375.397 3855.22
377.558 3760.11
379.718 3629.44
381.878 3450.56
384.038 3381.56
386.198 3315.67
388.356 3292.56
390.514 3275.78
392.671 3279.11
394.827 3124.67
396.983 3009
399.138 2876.22
401.291 2744.22
403.445 2643.44
405.598 2578.33
407.751 2533.11
409.903 2490.89
412.055 2519.78
414.204 2550.67
416.354 2655
418.504 2756.22
420.652 2737.78
422.8 2748
424.948 2715.56
427.094 2741.56
429.241 2793
431.386 2880.44
433.531 2951.67
435.675 3053.44
437.819 3015.78
439.961 2902.33
442.104 2764.67
444.245 2702.44
446.386 2721.89
448.527 2731.56
450.667 2728.67
452.805 2590.67
454.945 2419.33
457.082 2294.22
459.219 2189.44
461.356 2119.22
463.491 2084.78
465.627 2047.67
467.763 2033.78
469.896 2006.78
472.03 2024.56
474.163 2012.11
476.295 1996
478.426 2026.89
480.557 2020.78
482.686 2052.44
484.816 2058.56
486.945 2079.89
489.074 2105.11
491.202 2105.78
493.329 2142.22
495.455 2202.67
497.581 2176.11
499.707 2180.78
501.83 2243.44
503.955 2296.22
506.079 2313.67
508.201 2332
510.323 2362.22
512.444 2443.11
514.566 2458.56
516.685 2475.44
518.805 2544.11
520.924 2592
523.043 2602.67
525.16 2662.44
527.277 2689.67
529.394 2762.56
531.51 2789.89
533.624 2857.89
535.74 2881.89
537.854 2954.22
539.967 3019.89
542.079 3054.67
544.191 3144.44
546.303 3195.11
548.415 3287.78
550.525 3296.33
552.634 3390.22
554.743 3453.44
556.852 3510.78
558.96 3606.67
561.065 3699.56
563.172 3756.44
565.278 3846.67
567.384 3906.22
569.489 3966.44
571.593 4061.67
573.695 4126.89
575.798 4216.89
577.901 4251.67
580.003 4356.22
582.103 4386
584.204 4482.11
586.303 4585.22
588.402 4643.44
590.501 4696.22
592.598 4767.22
594.696 4828.11
596.792 4900.44
598.888 4995.11
600.984 5047.11
603.078 5133.78
605.173 5192.89
607.266 5264.56
609.359 5384.11
611.452 5438
613.543 5492
615.634 5579.11
617.724 5660.89
619.814 5794.89
621.903 5809.11
623.993 5931.33
626.081 6019.44
628.168 6052.89
630.255 6184.56
632.341 6286.44
634.427 6321.78
636.512 6478
638.596 6569.33
640.679 6664.33
642.762 6734.67
644.845 6860.67
646.927 6998
649.008 7076.67
651.088 7169.44
653.168 7315
655.248 7414.89
657.327 7568
659.405 7701.56
661.483 7829.22
663.559 7960.44
665.636 8124.11
667.713 8326.89
669.787 8491.89
671.861 8708.89
673.936 9002.56
676.008 9202.33
678.082 9496.67
680.154 9884.44
682.225 10347
684.297 10798.8
686.367 11314.8
688.436 11893.6
690.505 12524.2
692.574 13274.6
694.642 14288.6
696.709 15290.4
698.776 16590.8
700.842 18019.6
702.907 19485.1
704.972 21210.1
707.036 23041.3
709.1 24689.1
711.163 26292.1
713.226 27646.3
715.288 28198.7
717.349 28347.4
719.41 27692.6
721.469 26459.9
723.529 24634.7
725.588 22584
727.647 20461.3
729.703 18427.1
731.761 16531
733.818 14867.7
735.873 13453.4
737.929 12246.4
739.983 11167.7
742.037 10302.2
744.09 9562.56
746.144 8980.56
748.195 8463.55
750.248 8004.89
752.298 7667.67
754.348 7502.11
756.399 7317.44
758.448 7232.33
760.496 7245.67
762.545 7318.89
764.593 7459.44
766.639 7660.22
768.685 7974.22
770.731 8402.22
772.776 8911.33
774.82 9491.44
776.864 10286.4
778.907 11264.8
780.95 12388.8
782.992 13779.7
785.034 15430.9
787.075 17433.3
789.115 19853.3
791.155 22655.3
793.195 25860.7
795.234 29659
797.27 33496.8
799.308 37641.2
801.345 41541.3
803.381 44950.8
805.417 47267.6
807.452 48465.4
809.486 48116
811.52 46705.1
813.553 43985.8
815.586 40810.8
817.618 37402.8
819.65 33828.7
821.68 30346
823.71 27271.8
825.74 24276.2
827.769 21846
829.797 19658.6
831.826 17737.4
833.853 16115.9
835.88 14747.4
837.905 13476.7
839.931 12350.2
841.957 11465.4
843.981 10609.6
846.005 9862.45
848.028 9283
850.051 8723.22
852.073 8145.89
854.094 7779.22
856.115 7342.33
858.134 7009.22
860.154 6672.78
862.174 6323
864.192 6046
866.211 5756.22
868.227 5493.11
870.244 5242.56
872.261 4980
874.275 4781.89
876.291 4593.44
878.306 4381.56
880.319 4174.67
882.333 4008.11
884.345 3810
886.358 3702.22
888.369 3498.67
890.38 3340.33
892.39 3206.33
894.399 3090.22
896.409 2984
898.418 2866.78
900.425 2775.78
902.432 2657.22
904.44 2576.44
906.446 2464.11
908.452 2399.67
910.457 2307.11
912.461 2221.78
914.465 2153.44
916.468 2048.56
918.471 1999.33
920.474 1917.33
922.475 1885.56
924.476 1817.78
926.477 1762.11
928.477 1728.67
930.477 1637.44
932.476 1618.44
934.473 1585.67
936.471 1520.11
938.468 1487.33
940.464 1445.33
942.46 1412.89
944.456 1375.56
946.45 1350.22
948.445 1295.33
950.437 1282.22
952.431 1251.44
954.423 1232
956.415 1199.78
958.406 1163.56
960.398 1148
962.387 1124
964.377 1108.44
966.366 1085.78
968.354 1072.22
970.342 1039.56
972.329 1033.33
974.315 1009.11
976.303 986.778
978.288 982
980.273 967.556
982.257 938.222
984.241 908.556
986.224 898.444
988.207 887
990.189 867.222
992.171 849.333
994.151 845.111
996.131 828.111
998.111 801
1000.09 802.667
1002.07 783.556
1004.05 777.889
1006.03 758
1008 747.667
1009.98 736.222
1011.95 721.222
1013.93 698.333
1015.9 690
1017.88 670
1019.85 655
1021.82 640.333
1023.8 629.111
1025.77 615.111
1027.74 596.667
1029.71 589.667
1031.68 585.778
1033.65 564.889
1035.62 563.222
1037.59 549.111
1039.56 551.889
1041.52 549.222
1043.49 544.667
1045.46 532.222
1047.42 513.889
1049.39 518.556
1051.35 510.444
1053.32 502.111
1055.28 490.778
1057.24 495.889
1059.2 483.333
1061.17 471.778
1063.13 478.889
1065.09 473.556
1067.05 466.333
1069.01 466.111
1070.97 463.111
1072.92 454.111
1074.88 448.333
1076.84 444.556
1078.8 453.444
1080.75 441.889
1082.71 434
1084.66 433.444
1086.62 430.222
1088.57 433.111
1090.52 432.556
1092.48 421.111
1094.43 419.444
1096.38 416.889
1098.33 426.889
1100.28 420.222
1102.23 422.667
1104.18 422.444
1106.13 414.556
1108.08 407.111
1110.03 407.889
1111.97 398.111
1113.92 406
1115.87 400.111
1117.81 401.222
1119.76 397.778
1121.7 412
1123.65 397.333
1125.59 390.556
1127.53 392.444
1129.47 389
1131.42 393.556
1133.36 390.111
1135.3 406.222
1137.24 403.111
1139.18 397.556
1141.11 394.778
1143.05 397.333
1144.99 390.222
1146.93 391.444
1148.86 385.222
1150.8 378.222
1152.74 390.222
1154.67 398
1156.6 378.333
1158.54 380.556
1160.47 388.667
1162.4 376.444
1164.34 378
1166.27 371.444
1168.2 375.444
1170.13 376.222
1172.06 377.556
1173.99 370.667
1175.92 364.111
1177.85 369.444
1179.78 367.222
1181.7 364.778
1183.63 356.778
1185.55 356.444
1187.48 351.333
1189.41 367.444
1191.33 352.667
1193.25 357.556
1195.18 352.667
1197.1 364.111
1199.02 350.667
1200.94 348.444
1202.86 344.444
1204.79 338.111
1206.71 337.889
1208.63 349.222
1210.54 346.556
1212.46 343.222
1214.38 342.556
1216.3 347
1218.22 349.111
1220.13 344.778
1222.05 345.889
1223.96 336.111
1225.88 335
1227.79 330.333
1229.71 338.222
1231.62 329.889
1233.53 336.667
1235.44 343.333
1237.35 329.444
1239.26 324.111
1241.18 324.556
1243.08 331.333
1244.99 322.111
1246.9 320.667
1248.81 317.556
1250.72 328
1252.63 323.111
1254.53 318.444
1256.44 317.889
1258.34 317.667
1260.25 318.444
1262.15 306.222
1264.06 308.111
1265.96 316
1267.86 314.333
1269.76 306.111
1271.67 302.556
1273.57 303.667
1275.47 302.667
1277.37 305.778
1279.27 299.222
1281.17 301.333
1283.06 291.444
1284.96 295.222
1286.86 298
1288.76 295.556
1290.65 285.333
1292.55 287
1294.44 287.444
1296.34 290.222
1298.23 285.222
1300.13 283.444
1302.02 275.333
1303.91 274.778
1305.8 274.111
1307.7 279.222
1309.59 277.778
1311.48 272.333
1313.37 277.778
1315.26 264.556
1317.15 270.222
1319.03 268
1320.92 261.222
1322.81 262.111
1324.7 261.111
1326.58 255.222
1328.47 260.889
1330.35 252.889
1332.24 251.778
1334.12 255.778
1336 260.444
1337.89 260.111
1339.77 246
1341.65 243.889
1343.53 253.889
1345.41 250.333
1347.29 249.444
1349.17 241.444
1351.05 248.556
1352.93 246.333
1354.81 241.889
1356.69 246.889
1358.56 244.556
1360.44 246.778
1362.32 247.778
1364.19 238.333
1366.07 237.889
1367.94 236.222
1369.81 241.444
1371.69 241.222
1373.56 237.222
1375.43 234.778
1377.31 239.556
1379.18 240.444
1381.05 247.333
1382.92 233.444
1384.79 242.667
1386.66 235.667
1388.52 243.222
1390.39 241.667
1392.26 240.778
1394.13 242.556
1395.99 231.778
1397.86 245.667
1399.73 238.778
1401.59 241.667
1403.45 247.556
1405.32 247.222
1407.18 236.667
1409.04 235.889
1410.91 237.111
1412.77 236.889
1414.63 226
1416.49 224.889
1418.35 227.889
1420.21 239.111
1422.07 234
1423.93 221.444
1425.79 224.778
1427.64 228.667
1429.5 226.889
1431.36 224.667
1433.21 234.667
1435.07 222.333
1436.93 222.444
1438.78 221.222
1440.63 216.111
1442.49 210.556
1444.34 221.556
1446.19 209.778
1448.04 208.889
1449.89 215.333
1451.75 211.667
1453.6 211.444
1455.45 213
1457.3 201.889
1459.14 198.889
1460.99 205.556
1462.84 205
1464.69 208.333
1466.53 198
1468.38 199.222
1470.23 192.556
1472.07 197.222
1473.92 190.111
1475.76 191.222
1477.6 191
1479.45 188.556
1481.29 188.444
1483.13 187.667
1484.97 189
1486.81 179.556
1488.65 173.333
1490.49 174.333
1492.33 181.778
1494.17 175.333
1496.01 171.222
1497.85 174
1499.69 174.667
1501.52 168.556
1503.36 173.778
1505.19 164.222
1507.03 163.222
1508.87 160.222
1510.7 160.111
1512.53 161.889
1514.37 156.111
1516.2 157.333
1518.03 151.889
1519.86 155.222
1521.69 157
1523.53 156.222
1525.36 152.889
1527.19 156.111
1529.02 156.667
1530.84 140.889
1532.67 154.222
1534.5 146.444
1536.33 149.222
1538.15 148.111
1539.98 144.222
1541.8 151.778
1543.63 150.111
1545.45 148.667
1547.28 147.111
1549.1 139.889
1550.93 142.667
1552.75 149
1554.57 143.333
1556.39 142.111
1558.21 134.667
1560.03 140
1561.85 135.111
1563.67 146.444
1565.49 143.667
1567.31 135.778
1569.13 141
1570.95 140.556
1572.76 141.778
1574.58 136.222
1576.39 142.333
1578.21 139.222
1580.03 134.889
1581.84 141.556
1583.65 139
1585.47 136
1587.28 136
1589.09 139.333
1590.9 129.667
1592.72 131.333
1594.53 140
1596.34 134.444
1598.15 137.778
1599.96 137.556
1601.76 138.778
1603.57 133.556
1605.38 130.889
1607.19 131.778
1609 137.889
1610.8 131.556
1612.61 126
1614.41 130.444
1616.22 123.333
1618.02 128.111
1619.83 126.556
1621.63 134.111
1623.43 129.889
1625.23 123.778
1627.04 125.222
1628.84 122.222
1630.64 123.556
1632.44 121.222
1634.24 119.556
1636.04 123.333
1637.84 119
1639.63 118.556
1641.43 120.111
1643.23 111.556
1645.03 116
1646.82 122
1648.62 120.778
1650.42 120.778
1652.21 109.111
1654 115.556
1655.8 112.667
1657.59 115.444
1659.38 115.778
1661.18 117.556
1662.97 117.111
1664.76 114.889
1666.55 114.333
1668.34 111.444
1670.13 107.222
1671.92 111
1673.71 112.778
1675.5 109.333
1677.29 105.889
1679.07 112.333
1680.86 108.222
1682.65 104.778
1684.43 111
1686.22 104.778
1688 106.889
1689.79 103.111
1691.57 104.333
1693.35 106.889
1695.14 98.8889
1696.92 104.222
1698.7 105.222
1700.48 107.222
1702.26 109.444
1704.04 106.111
1705.83 102
1707.6 104.222
1709.38 107.222
1711.16 112
1712.94 102.111
1714.72 102.778
1716.49 106.222
1718.27 103.222
1720.05 103.667
1721.82 99.5556
1723.6 99.2222
1725.37 102.222
1727.15 105.222
1728.92 103.667
1730.69 97.8889
1732.47 99.2222
1734.24 103.222
1736.01 101
1737.78 103.556
1739.55 106.111
1741.32 98.6667
1743.09 100.778
1744.86 101.444
1746.63 98.8889
1748.4 99.8889
1750.16 95
1751.93 100.778
1753.7 94.1111
1755.46 101.222
1757.23 102.111
1759 100.111
1760.76 98.5556
1762.52 97.4444
1764.29 99.1111
1766.05 102
1767.82 98.2222
1769.58 99
1771.34 95
1773.1 93.2222
1774.86 97.2222
1776.62 98.2222
1778.38 102
1780.14 97.5556
1781.9 103.111
1783.66 94.7778
1785.42 98.8889
1787.17 102.556
1788.93 99.7778
1790.69 99.1111
1792.44 98.2222
1794.2 100.111
1795.95 101.556
1797.71 94.8889
1799.46 96.5556
1801.22 97
1802.97 98.4444
1804.72 100.889
1806.48 94.1111
1808.23 95.1111
1809.98 93.2222
1811.73 99.2222
1813.48 96.5555
1815.23 93.3333
1816.98 95.1111
1818.73 95.6667
1820.48 95.7778
1822.22 99
1823.97 97.7778
1825.72 102.778
1827.46 96.5556
1829.21 95
1830.96 94.6667
1832.7 96.3333
1834.44 93.3333
1836.19 93.5556
1837.93 93.8889
1839.68 98.5556
1841.42 99.4444
1843.16 101.222
1844.9 93
1846.64 95.2222
1848.38 93.5555
1850.12 93
1851.86 92.7778
1853.6 92.4444
1855.34 89.8889
1857.08 93.4444
1858.82 92
1860.56 95.7778
1862.29 93.7778
1864.03 95.6667
1865.77 95.8889
1867.5 92.2222
1869.24 90.5556
1870.97 90.6667
1872.7 92.5556
1874.44 92.3333
1876.17 89.8889
1877.9 97.2222
1879.63 91
1881.37 92.1111
1883.1 91.2222
1884.83 87.7778
1886.56 85.8889
1888.29 96.6667
1890.02 83.7778
1891.75 90.5556
1893.47 94.4444
1895.2 90.7778
1896.93 90.6667
1898.66 88.3333
1900.38 91
1902.11 94.5555
1903.83 95.7778
1905.56 87.4445
1907.28 88.1111
1909.01 91.3333
1910.73 92.3333
1912.45 92.3333
1914.18 90.5556
1915.9 88.7778
1917.62 91.4444
1919.34 90.7778
1921.06 91.6667
1922.78 88
1924.5 93.2222
1926.22 95.5556
1927.94 93.1111
1929.66 92.3333
1931.38 90.5556
1933.1 97.2222
1934.81 97.7778
1936.53 102.222
1938.24 92.4444
1939.96 97.6667
1941.68 97.3333
1943.39 102.778
1945.1 100.222
1946.82 95.4444
1948.53 100
1950.24 96.1111
1951.96 106.556
1953.67 100.667
1955.38 108.111
1957.09 102.556
1958.8 102.889
1960.51 103
1962.22 111
1963.93 108.778
1965.64 108.111
1967.35 105.556
1969.05 111.444
1970.76 112
1972.47 110.667
1974.17 113.333
1975.88 109.111
1977.58 109.333
1979.29 111.444
1980.99 111.778
1982.7 115.222
1984.4 113.333
1986.1 114.778
1987.81 113.222
1989.51 112.556
1991.21 113.222
1992.91 115.778
1994.61 114
1996.31 112.778
1998.01 107.111
1999.71 109.444