#------------------------------------------------------------------------------
#$Date: 2018-02-06 16:23:35 +0200 (Tue, 06 Feb 2018) $
#$Revision: 400 $
#$URL: svn://172.16.1.111/rod/cif/3/50/01/3500185.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500185
loop_
_publ_author_name
'El Mendili, Y'
'Secchi, M'
'Zannatta, M'
_publ_section_title
;
 Raman spectrum of commercial Bi2O3
;
_journal_name_full               'Personal communication to ROD'
_journal_year                    2018
_chemical_compound_source        'commercial Alfa Aesar 99.5%'
_chemical_formula_structural     'Bi2 O3'
_chemical_formula_sum            'Bi2 O3'
_chemical_name_mineral           Sphaerobismoite
_chemical_name_systematic        'Bi2 O3'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 67.07
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.83
_cell_length_b                   8.14
_cell_length_c                   7.48
_raman_determination_method      experimental
_[local]_chemical_compound_color white
_[local]_chemical_compound_state Solid
_raman_measurement_device.location 'University of Trento'
_raman_measurement_device.company Horiba
_raman_measurement_device.model  Aramis
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.50
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 633
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 2
_raman_measurement_device.power_on_sample 12
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 600
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_raman_measurement.datetime_initiated 2018-01-15
_rod_data_source.file            Bi2O3.rod
_rod_data_source.block           3500020
_rod_database.code               3500185
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 silicon_wafer
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 1010004 COD http://www.crystallography.net/cod/1010004.html
;
no XRD analysis data.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
102.279 44050.5
104.522 38560.3
106.766 34223.8
109.007 30840.3
111.248 28089.3
113.489 26113.3
115.728 24803.3
117.967 24918
120.207 26949
122.445 32223
124.682 39162.5
126.919 43566.8
129.155 42801.5
131.39 36373
133.624 28088
135.858 21990.3
138.09 19297
140.323 18848
142.555 19334
144.786 19862.5
147.017 20618
149.247 21600.8
151.475 22880.8
153.704 24748.5
155.932 27058.8
158.158 29561.8
160.385 31452
162.612 31706.5
164.836 30266
167.061 27523
169.284 25213.3
171.508 23552.5
173.729 22420.8
175.952 21347.3
178.172 20077.3
180.394 18785
182.613 17681.5
184.833 16555.3
187.051 15608.5
189.268 14707.8
191.486 14013.3
193.702 13486.5
195.917 13080
198.134 12714.8
200.348 12485.5
202.561 12189.3
204.774 11938.5
206.986 11648
209.198 11418.5
211.409 11116.3
213.621 11001.8
215.83 10941.5
218.039 10834
220.248 10840.3
222.456 10844
224.663 10978.5
226.868 11344.5
229.074 11665
231.279 11915
233.484 12066.5
235.688 11782.5
237.892 11432.3
240.093 11081
242.295 10860.5
244.497 10720.5
246.698 10642.3
248.897 10402.3
251.096 10285.8
253.295 10038.8
255.492 9754.75
257.69 9701.5
259.886 9716.75
262.083 9724.5
264.277 9887.5
266.473 10116.8
268.666 10324.5
270.86 10736
273.052 11163
275.245 11489.5
277.436 11550.8
279.626 11581.3
281.816 11318.8
284.006 11272.5
286.194 11342.3
288.382 11417.8
290.569 11689.5
292.757 12051.8
294.943 12427
297.128 13055
299.313 14047
301.497 15600.3
303.68 17964.3
305.863 21628.3
308.045 27228
310.227 34595.5
312.408 42840.8
314.588 48789.5
316.768 50179
318.947 46339
321.125 39515.3
323.302 32537.8
325.479 27010
327.656 22744.3
329.832 19715.3
332.007 17395
334.181 15629
336.355 14357.3
338.528 13256.5
340.7 12554.5
342.872 11921.8
345.043 11362.5
347.214 10780.5
349.383 10367.8
351.553 10007.3
353.721 9566.75
355.889 9232.5
358.056 8861.75
360.224 8540.5
362.389 8192.5
364.554 7925.25
366.72 7674.5
368.883 7331.5
371.046 6987.75
373.209 6772
375.372 6496
377.533 6262.5
379.694 6094
381.854 5932
384.013 5777.25
386.172 5681.5
388.33 5532.75
390.487 5433
392.644 5380
394.801 5377.5
396.957 5284.75
399.112 5204.75
401.266 5203.25
403.42 5250
405.574 5161.5
407.726 5203.5
409.878 5134
412.029 5127.25
414.179 5082.5
416.33 5022.5
418.48 4979.25
420.627 4984.5
422.776 5051
424.922 5035.25
427.07 5235.25
429.216 5319.75
431.361 5501.75
433.507 5603.25
435.65 5654
437.794 5685.5
439.937 5614
442.078 5702
444.221 5767.25
446.361 5878.5
448.503 6128.5
450.642 6430.25
452.781 6881.5
454.919 7513
457.058 8277.75
459.195 9220
461.331 10320.3
463.467 11477.5
465.602 12291.5
467.737 12927.5
469.871 12874
472.004 12324.5
474.137 11347.5
476.269 10146.5
478.401 8857.75
480.532 7882.25
482.662 7049.25
484.792 6325.5
486.921 5785.25
489.05 5239.5
491.178 4840
493.304 4521.5
495.431 4286.25
497.557 4055.25
499.682 3825
501.806 3728.25
503.931 3599.25
506.054 3497.25
508.176 3381.5
510.299 3318.25
512.42 3236.75
514.541 3155.5
516.661 3125
518.781 3040.5
520.9 2994.75
523.019 2885.25
525.136 2816.75
527.253 2704
529.37 2647.75
531.485 2533.25
533.6 2481
535.714 2390.25
537.83 2354.5
539.943 2245
542.055 2180
544.167 2113.5
546.278 2069
548.389 2004.5
550.499 1917.5
552.609 1866.5
554.718 1824
556.826 1744.25
558.934 1699.75
561.041 1662.5
563.148 1627
565.254 1576
567.359 1591
569.464 1544.75
571.569 1562
573.671 1493.5
575.774 1499
577.877 1517.75
579.977 1493.75
582.079 1454.5
584.18 1446.25
586.279 1429.25
588.378 1453.25
590.476 1399.5
592.574 1398
594.671 1370.5
596.768 1376.5
598.864 1339.5
600.96 1337.75
603.054 1304.75
605.148 1270
607.242 1311
609.335 1241.5
611.427 1252.75
613.519 1215
615.61 1207
617.7 1161
619.79 1183.25
621.879 1132.5
623.968 1160.5
626.055 1144.25
628.144 1133.75
630.231 1132.75
632.317 1114.5
634.403 1091.75
636.486 1100.75
638.571 1092.5
640.655 1047
642.738 1041.5
644.821 1058.25
646.903 1029
648.984 1003.5
651.064 989.25
653.144 948.75
655.224 938.5
657.302 909
659.381 848.25
661.459 886
663.535 888.5
665.612 962.75
667.687 1110.5
669.763 1274.25
671.837 1282
673.912 1195.25
675.985 1051
678.058 884
680.13 817
682.201 749.5
684.273 737
686.343 713.75
688.412 700
690.481 749.5
692.551 752
694.618 758.5
696.686 712.75
698.752 684
700.818 640.5
702.883 602
704.948 575.5
707.013 570
709.076 562
711.139 561.5
713.202 544.5
715.264 523.25
717.326 527.5
719.385 511
721.445 496.5
723.505 503.25
725.564 495.75
727.623 485.5
729.68 482.25
731.737 491.5
733.794 484
735.849 485.25
737.905 488
739.959 482
742.014 458.5
744.067 465.25
746.12 471
748.172 464.25
750.224 453.75
752.275 454.25
754.325 463.5
756.376 452.5
758.424 463.75
760.473 454.25
762.521 456.5
764.569 456.75
766.616 454.5
768.662 447.75
770.707 450.5
772.752 444.75
774.797 439.25
776.841 445.25
778.884 437.25
780.927 434.75
782.969 430.5
785.01 407.75
787.051 421.75
789.092 417.25
791.132 428.5
793.171 414.25
795.209 417.5
797.247 408
799.285 413.5
801.322 407.5
803.357 400
805.393 405.75
807.428 406.75
809.463 390.25
811.497 398.5
813.529 409.5
815.563 388.25
817.594 375
819.625 386
821.657 389.25
823.687 365.25
825.717 376.25
827.746 381.5
829.774 360
831.801 370.75
833.83 379
835.856 369.25
837.882 367
839.908 377
841.932 366.5
843.957 378.75
845.982 396.5
848.005 394.25
850.027 392.25
852.05 404
854.07 403.75
856.091 391.5
858.111 383
860.131 371.5
862.15 367.5
864.169 367.75
866.187 362.75
868.204 354.25
870.221 352.25
872.238 341.75
874.252 352.5
876.268 352.75
878.283 356
880.296 343.5
882.31 342.5
884.322 337.5
886.335 345.75
888.345 341.5
890.356 330.5
892.367 339.5
894.376 321
896.386 338.5
898.395 326.75
900.402 313.25
902.409 321.5
904.417 333
906.423 330
908.429 333
910.434 328
912.438 333.5
914.442 334.5
916.445 329.5
918.448 331
920.451 325.5
922.452 324.5
924.453 325
926.454 318
928.454 329.75
930.454 330.75
932.451 334.75
934.45 316.75
936.448 312
938.445 320.25
940.441 316
942.437 317.25
944.433 315
946.427 309
948.422 293.75
950.415 307
952.408 307.75
954.4 305
956.393 301.25
958.383 307.75
960.374 303.75
962.365 305.25
964.354 302
966.342 311.25
968.332 309
970.319 300.25
972.306 300.5
974.293 303
976.279 300.25
978.265 300.25
980.25 299.25
982.234 296
984.218 294
986.202 300.25
988.184 288.75
990.166 303.25
992.147 299.5
994.128 292
996.109 291
998.089 296.5
1000.07 294
1002.05 297
1004.02 288.5
1006 294.25
1007.98 289
1009.96 291.5
1011.93 285.75
1013.91 289
1015.88 282.5
1017.86 285.5
1019.83 302.25
1021.8 295.75
1023.77 311.25
1025.75 291
1027.72 300
1029.69 293.5
1031.66 314
1033.63 316.25
1035.6 314
1037.57 328.75
1039.53 328
1041.5 327.5
1043.47 366
1045.43 365.75
1047.4 398
1049.36 426.5
1051.33 467
1053.29 516.25
1055.26 588
1057.22 766.25
1059.18 1002
1061.14 1234
1063.11 1437.5
1065.06 1790.25
1067.03 2499
1068.98 3485.75
1070.94 4346.5
1072.9 4310.5
1074.86 3469.25
1076.82 2303
1078.77 1331.25
1080.73 757
1082.69 519.75
1084.64 381
1086.59 336.75
1088.55 307
1090.5 283
1092.45 274
1094.41 266.25
1096.36 270.75
1098.31 266.25
1100.26 268.5
1102.21 255.5
1104.16 254
1106.11 247.5
1108.06 246.5
1110 245.5
1111.95 232.75
1113.9 242.75
1115.84 236
1117.79 242.25
1119.73 234
1121.68 238.25
1123.62 231.75
1125.57 235
1127.51 228.5
1129.45 224.25
1131.39 213
1133.33 214.25
1135.27 213.75
1137.21 207
1139.15 211
1141.09 207
1143.03 202.25
1144.97 199.75
1146.9 199.5
1148.84 190.5
1150.78 175.25
1152.71 189
1154.65 184.25
1156.58 186.75
1158.52 172.25
1160.45 174.5
1162.38 167
1164.31 181.5
1166.25 174.5
1168.18 175.25
1170.11 166.25
1172.04 174.75
1173.97 167.75
1175.9 167.75
1177.83 168
1179.75 166
1181.68 155.5
1183.61 165.75
1185.53 165.25
1187.46 152.5
1189.38 155.25
1191.31 165.5
1193.23 161.25
1195.16 161
1197.08 173
1199 151.5
1200.92 168.5
1202.84 167.5
1204.76 160.5
1206.68 171
1208.6 168.5
1210.52 168.75
1212.44 173.75
1214.36 174
1216.28 170.5
1218.19 180.75
1220.11 162.5
1222.03 180
1223.94 170
1225.86 179.5
1227.77 179.75
1229.68 175.5
1231.6 182.25
1233.51 177.25
1235.42 184.75
1237.33 178.5
1239.24 187.75
1241.15 192.75
1243.06 202.5
1244.97 198
1246.88 197.25
1248.79 207.25
1250.7 205.75
1252.6 218.5
1254.51 215
1256.42 218.5
1258.32 221.25
1260.23 222.5
1262.13 239
1264.04 228
1265.94 232.5
1267.84 241.5
1269.74 246.25
1271.64 237.25
1273.55 246.25
1275.45 250.75
1277.35 257
1279.25 253.5
1281.14 254.5
1283.04 263.5
1284.94 265.75
1286.84 268
1288.74 284.75
1290.63 289
1292.53 310.5
1294.42 307
1296.32 311.5
1298.21 339
1300.11 328.75
1302 337
1303.89 345.5
1305.78 356.5
1307.67 364.25
1309.57 358
1311.46 373
1313.34 371
1315.23 400
1317.12 415.25
1319.01 395.25
1320.9 421
1322.79 425.75
1324.67 443.25
1326.56 451.25
1328.45 466.75
1330.33 478
1332.21 508.25
1334.1 521
1335.98 564.5
1337.86 582.5
1339.75 601
1341.63 624.5
1343.51 645.25
1345.39 662.75
1347.27 662.75
1349.15 684.75
1351.03 686.5
1352.91 757.25
1354.79 769
1356.66 769.5
1358.54 852.5
1360.42 869.5
1362.29 944.5
1364.17 979.75
1366.04 1005.5
1367.92 966.25
1369.79 929.25
1371.67 881.75
1373.54 818
1375.41 757.5
1377.28 701
1379.15 640.5
1381.03 635
1382.9 620.25
1384.76 640.5
1386.63 665
1388.5 681.5
1390.37 684.75
1392.24 729.75
1394.11 743.25
1395.97 766
1397.84 764
1399.7 762.5
1401.57 769.5
1403.43 770
1405.3 724.5
1407.16 729
1409.02 695.25
1410.89 658.75
1412.75 650.25
1414.61 630.5
1416.47 584.75
1418.33 574.75
1420.19 568
1422.05 540.25
1423.91 526.5
1425.77 494.5
1427.62 491
1429.48 448
1431.34 436
1433.19 423
1435.05 401.25
1436.9 394.75
1438.76 367.75
1440.61 366.75
1442.47 346.75
1444.32 328.5
1446.17 301
1448.02 300
1449.87 293.5
1451.73 285.75
1453.58 284.5
1455.42 274
1457.27 273.25
1459.12 261.75
1460.97 255.75
1462.82 242.25
1464.67 243.25
1466.51 242.25
1468.36 230.5
1470.2 216.75
1472.05 212
1473.89 217.5
1475.74 205.25
1477.58 209.5
1479.42 203.25
1481.27 203.25
1483.11 204.25
1484.95 192.75
1486.79 177.75
1488.63 181
1490.47 173
1492.31 164
1494.15 170.5
1495.99 165.5
1497.83 153.5
1499.66 150.75
1501.5 142.75
1503.34 139.5
1505.17 141
1507.01 135
1508.84 131.5
1510.68 125.5
1512.51 128
1514.35 121
1516.18 117.25
1518.01 115
1519.84 114.25
1521.67 111.25
1523.5 111
1525.33 112.25
1527.16 102.25
1528.99 94
1530.82 102
1532.65 97
1534.48 100.75
1536.3 94.25
1538.13 91.5
1539.96 93
1541.78 94
1543.61 92
1545.43 88
1547.26 90
1549.08 81
1550.9 83.5
1552.73 84.25
1554.55 82.25
1556.37 86
1558.19 82.5
1560.01 81
1561.83 82.75
1563.65 73.5
1565.47 80.75
1567.29 73.5
1569.11 69
1570.92 75.75
1572.74 74.75
1574.56 67
1576.37 72.75
1578.19 75
1580 75.25
1581.82 66.5
1583.63 71.5
1585.45 66
1587.26 66.75
1589.07 69
1590.88 62
1592.69 66.75
1594.51 61.5
1596.32 60.5
1598.13 58.5
1599.94 68
1601.74 63
1603.55 61.5
1605.36 66.25
1607.17 59
1608.97 62
1610.78 62.25
1612.59 61.25
1614.39 56
1616.2 55
1618 56.75
1619.81 57.5
1621.61 59
1623.41 52.75
1625.21 60
1627.02 60.75
1628.82 54.75
1630.62 55.25
1632.42 55
1634.22 57.5
1636.02 55.5
1637.82 54
1639.61 51
1641.41 57.5
1643.21 55.25
1645.01 55
1646.8 56.25
1648.6 52.5
1650.39 59.75
1652.19 55.25
1653.98 57
1655.78 55.5
1657.57 53.75
1659.36 51.75
1661.16 53
1662.95 51.25
1664.74 53
1666.53 54.25
1668.32 55.5
1670.11 53.5
1671.9 53
1673.69 53.25
1675.48 58.75
1677.26 55.25
1679.05 63
1680.84 64
1682.63 72.25
1684.41 78.25
1686.2 96
1687.98 111.5
1689.77 152.25
1691.55 202
1693.33 250
1695.12 290.75
1696.9 294.25
1698.68 273
1700.46 255.75
1702.24 207.5
1704.02 170.5
1705.8 151.5
1707.58 119.5
1709.36 118
1711.14 104.75
1712.92 102.75
1714.7 87.25
1716.47 81.75
1718.25 77.25
1720.03 71.25
1721.8 62
1723.58 62
1725.35 63.5
1727.13 57
1728.9 59.5
1730.67 62.75
1732.44 57.5
1734.22 59.75
1735.99 59.75
1737.76 61.25
1739.53 56.25
1741.3 54.25
1743.07 62.25
1744.84 53.5
1746.61 55.5
1748.38 52.5
1750.14 53.25
1751.91 51.5
1753.68 54
1755.44 49.25
1757.21 52.75
1758.98 49.5
1760.74 52
1762.5 54
1764.27 53.5
1766.03 50.5
1767.79 52.5
1769.56 47
1771.32 47.75
1773.08 48.5
1774.84 47.25
1776.6 52.25
1778.36 53
1780.12 50
1781.88 47.75
1783.64 50
1785.4 52.25
1787.15 44.5
1788.91 48.25
1790.67 46.75
1792.42 47.5
1794.18 50.5
1795.93 47
1797.69 49
1799.44 51
1801.2 42.5
1802.95 47
1804.7 47.25
1806.46 48.25
1808.21 45.5
1809.96 48.75
1811.71 48.75
1813.46 49.5
1815.21 50.5
1816.96 48
1818.71 50.75
1820.46 51.5
1822.2 44.5
1823.95 46
1825.7 49.25
1827.44 48
1829.19 49
1830.94 49.25
1832.68 47.75
1834.42 53.25
1836.17 49
1837.91 48.5
1839.66 49.75
1841.4 49.5
1843.14 51.5
1844.88 48.25
1846.62 49.75
1848.36 51.75
1850.1 50
1851.84 51.25
1853.58 50
1855.32 49.5
1857.06 47.25
1858.8 52
1860.54 51.5
1862.27 47.5
1864.01 50.75
1865.74 48.5
1867.48 50.25
1869.22 48
1870.95 54.25
1872.68 43.75
1874.42 51.25
1876.15 49
1877.88 52
1879.61 52.25
1881.35 52.25
1883.08 54
1884.81 53.5
1886.54 49.75
1888.27 49.5
1890 51.5
1891.73 51.5
1893.45 49.75
1895.18 54.5
1896.91 53.25
1898.64 49.25
1900.36 50.25
1902.09 47
1903.81 53.5
1905.54 50.25
1907.26 51.25
1908.99 51.25
1910.71 51.25
1912.43 55.5
1914.16 54.5
1915.88 52
1917.6 50.5
1919.32 51.75
1921.04 51.5
1922.76 51.5
1924.48 56.75
1926.2 45.5
1927.92 50.25
1929.64 45.5
1931.36 44.5
1933.08 46
1934.79 50
1936.51 46
1938.23 45
1939.94 43.5
1941.66 47.75
1943.37 40.75
1945.08 49.25
1946.8 45.5
1948.51 43.25
1950.22 45
1951.94 40.5
1953.65 41.5
1955.36 49
1957.07 41.75
1958.78 43
1960.49 39.5
1962.2 44.5
1963.91 45.5
1965.62 43.5
1967.33 46.5
1969.03 44.5
1970.74 44.5
1972.45 49
1974.15 46.5
1975.86 44
1977.56 43.5
1979.27 45.5
1980.97 49.75
1982.68 45.75
1984.38 44.5
1986.08 46.75
1987.79 47.25
1989.49 44.25
1991.19 44.25
1992.89 48
1994.59 46.5
1996.29 47.5
1997.99 48.5
1999.69 50.5