#------------------------------------------------------------------------------ #$Date: 2018-02-06 16:23:51 +0200 (Tue, 06 Feb 2018) $ #$Revision: 404 $ #$URL: svn://172.16.1.111/rod/cif/3/50/01/3500189.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_3500189 loop_ _publ_author_name 'El Mendili, Y' 'Secchi, M' 'Zannatta, M' _publ_section_title ; Raman spectrum of commercial CaHPO4 ; _journal_name_full 'Personal communication to ROD' _journal_year 2018 _chemical_compound_source 'commercial Aldrich pur' _chemical_formula_structural 'Ca H O4 P' _chemical_formula_sum 'Ca H O4 P' _chemical_name_mineral Monetite _chemical_name_systematic Monetite _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 96.18 _cell_angle_beta 103.82 _cell_angle_gamma 88.34 _cell_formula_units_Z 4 _cell_length_a 6.916 _cell_length_b 6.619 _cell_length_c 6.946 _cell_volume 306.966 _raman_determination_method experimental _[local]_chemical_compound_color white _[local]_chemical_compound_state Solid _raman_measurement_device.location 'University of Trento' _raman_measurement_device.company Horiba _raman_measurement_device.model Aramis _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.50 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 633 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 2 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 600 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 300 _raman_measurement.datetime_initiated 2018-01-15 _rod_data_source.file CaHPO4.rod _rod_data_source.block 3500020 _rod_database.code 3500189 loop_ _raman_complementary.id _raman_complementary.method 1 EDX loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 silicon_wafer loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 2106084 COD http://www.crystallography.net/cod/2106084.html ; no XRD analysis data. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 102.279 11580.6 104.522 11642.4 106.766 11752 109.007 11663.3 111.248 11820.3 113.489 11767.7 115.728 11431.1 117.967 11269.1 120.207 11263.6 122.445 11311.1 124.682 11332.7 126.919 11456.6 129.155 11665.7 131.39 11779.9 133.624 11717.3 135.858 11805.1 138.09 11858.7 140.323 11912.3 142.555 12085.6 144.786 12270.8 147.017 12335.6 149.247 12194.6 151.475 11988.1 153.704 11934.8 155.932 11803.3 158.158 11852 160.385 11674.1 162.612 11552.4 164.836 11378.4 167.061 11448.2 169.284 11504.6 171.508 11576.9 173.729 11588.6 175.952 11615.1 178.172 11659.4 180.394 11677 182.613 11844.7 184.833 11993.9 187.051 11955.2 189.268 11865.3 191.486 11741.7 193.702 11682.1 195.917 11635.6 198.134 11536.3 200.348 11394.7 202.561 11264.7 204.774 11209.3 206.986 11098 209.198 11068.6 211.409 11066.6 213.621 10959.6 215.83 10973.8 218.039 10949.7 220.248 10939 222.456 10947.8 224.663 10911.7 226.868 10903.1 229.074 10964.7 231.279 10951.9 233.484 10940.9 235.688 10849.7 237.892 10741.3 240.093 10630.4 242.295 10564.4 244.497 10478.9 246.698 10458 248.897 10445.6 251.096 10440.9 253.295 10426.7 255.492 10496.9 257.69 10511.6 259.886 10556 262.083 10636.9 264.277 10655.7 266.473 10749.7 268.666 10764.4 270.86 10844.3 273.052 10850.8 275.245 10875.8 277.436 10885.7 279.626 10874.7 281.816 10827.8 284.006 10798.8 286.194 10588.7 288.382 10459.4 290.569 10391 292.757 10289.4 294.943 10157 297.128 10078.4 299.313 10050.4 301.497 10007.2 303.68 9975.89 305.863 9910.89 308.045 9903.33 310.227 9921.33 312.408 9878.11 314.588 9848.45 316.768 9920.89 318.947 9894.11 321.125 9900.56 323.302 9948.33 325.479 9938.67 327.656 9954.78 329.832 9967 332.007 10018.1 334.181 10036.3 336.355 10079.2 338.528 10070.2 340.7 10070.8 342.872 10167.9 345.043 10175.1 347.214 10148.4 349.383 10292.7 351.553 10190.1 353.721 10293.1 355.889 10355.3 358.056 10324.9 360.224 10382.8 362.389 10476.4 364.554 10516.7 366.72 10529.3 368.883 10717.6 371.046 10752.8 373.209 10963.2 375.372 11033.1 377.533 11245.9 379.694 11442.9 381.854 11701 384.013 12084.7 386.172 12493.8 388.33 13042 390.487 13730.1 392.644 14437.8 394.801 15150.8 396.957 15681.9 399.112 15912 401.266 15724.2 403.42 15496.7 405.574 15197.8 407.726 15037.4 409.878 14946 412.029 15174.8 414.179 15639.8 416.33 16461.8 418.48 17524.4 420.627 18620.9 422.776 19420.9 424.922 19568.2 427.07 19121.3 429.216 18464 431.361 17910.1 433.507 17389.9 435.65 17005.1 437.794 16347.2 439.937 15595.2 442.078 14848.1 444.221 14094.9 446.361 13520.7 448.503 13103.1 450.642 12780.4 452.781 12580.1 454.919 12397.4 457.058 12299.2 459.195 12310.6 461.331 12267.7 463.467 12319 465.602 12201.3 467.737 12248.1 469.871 12293.4 472.004 12336.9 474.137 12384.2 476.269 12379 478.401 12382.8 480.532 12335.8 482.662 12350.4 484.792 12346.9 486.921 12293.9 489.05 12185.3 491.178 12121.1 493.304 12096.6 495.431 12055.3 497.557 11968.9 499.682 11856.7 501.806 11872.2 503.931 11779.3 506.054 11771.2 508.176 11776.4 510.299 11760.4 512.42 11830.2 514.541 11779.1 516.661 11794.4 518.781 11973.6 520.9 12013.3 523.019 12141.4 525.136 12212.6 527.253 12276.3 529.37 12349.1 531.485 12456.3 533.6 12627.7 535.714 12721.1 537.83 12933.6 539.943 13064.3 542.055 13277 544.167 13445.4 546.278 13706.2 548.389 13779 550.499 13818 552.609 13974.6 554.718 14037.1 556.826 14145.8 558.934 14392.7 561.041 14719.8 563.148 15239 565.254 15680.1 567.359 15763.2 569.464 15654.3 571.569 15367.9 573.671 15246.7 575.774 15395.4 577.877 15547.8 579.977 15697.2 582.079 15492.1 584.18 15059.7 586.279 14650.8 588.378 14509.4 590.476 15054.1 592.574 16012.4 594.671 16714.7 596.768 16598.6 598.864 15704.4 600.96 14572.8 603.054 13621.1 605.148 12934.9 607.242 12593.4 609.335 12356.4 611.427 12105.6 613.519 12047.4 615.61 11876.2 617.7 11743.6 619.79 11725.4 621.879 11612.7 623.968 11479 626.055 11418.1 628.144 11324.2 630.231 11331.7 632.317 11210.9 634.403 11117.3 636.486 11069.7 638.571 11028.9 640.655 10963 642.738 10926.1 644.821 10908.6 646.903 10890.6 648.984 10833.3 651.064 10807.2 653.144 10764.6 655.224 10718.8 657.302 10715.3 659.381 10650.6 661.459 10611.2 663.535 10625.4 665.612 10572 667.687 10566.9 669.763 10537.6 671.837 10514.3 673.912 10462.2 675.985 10442.6 678.058 10444.7 680.13 10398.9 682.201 10411.4 684.273 10385.3 686.343 10370.3 688.412 10320.3 690.481 10268.9 692.551 10287.6 694.618 10297.1 696.686 10239.2 698.752 10274 700.818 10229.2 702.883 10230.1 704.948 10188.1 707.013 10170.6 709.076 10126.1 711.139 10175.3 713.202 10202.9 715.264 10171.4 717.326 10209.3 719.385 10211.7 721.445 10191 723.505 10187.1 725.564 10178.8 727.623 10266.6 729.68 10239.6 731.737 10299 733.794 10275.2 735.849 10250.8 737.905 10294.3 739.959 10300.2 742.014 10288.3 744.067 10317.1 746.12 10321.8 748.172 10348.4 750.224 10388.1 752.275 10374 754.325 10406.8 756.376 10401.6 758.424 10475.3 760.473 10511.7 762.521 10462.4 764.569 10516.7 766.616 10565.2 768.662 10583.4 770.707 10650.3 772.752 10610.8 774.797 10642.8 776.841 10605.9 778.884 10645.9 780.927 10647.1 782.969 10672.1 785.01 10691.8 787.051 10723.2 789.092 10788.7 791.132 10741.8 793.171 10762.1 795.209 10783.4 797.247 10777.1 799.285 10847.8 801.322 10815.7 803.357 10854.1 805.393 10846.2 807.428 10836.1 809.463 10817.1 811.497 10893.7 813.529 10881 815.563 10873.3 817.594 10878.7 819.625 10910.7 821.657 10936.8 823.687 10957.3 825.717 10934.7 827.746 11010 829.774 10928.7 831.801 11043.9 833.83 11028.4 835.856 11054.6 837.882 11103.6 839.908 11081.6 841.932 11154.1 843.957 11119.2 845.982 11176 848.005 11221.4 850.027 11283.3 852.05 11305.8 854.07 11423 856.091 11475.2 858.111 11450 860.131 11559 862.15 11665.3 864.169 11734 866.187 11846.9 868.204 11950.2 870.221 12069.6 872.238 12220.4 874.252 12373.7 876.268 12555.6 878.283 12769 880.296 12946 882.31 13241.1 884.322 13527.7 886.335 13905 888.345 14338.4 890.356 14766.4 892.367 15245.7 894.376 15755.3 896.386 16348.9 898.395 16931.2 900.402 17473.2 902.409 17950.6 904.417 18338.1 906.423 18518.4 908.429 18442 910.434 18349.3 912.438 17915.3 914.442 17489.4 916.445 17216 918.448 16811.8 920.451 16526.4 922.452 16426.2 924.453 16219.9 926.454 16147.1 928.454 16104 930.454 16293.1 932.451 16274.6 934.45 16441.2 936.448 16516.7 938.445 16757.7 940.441 17023.4 942.437 17263.1 944.433 17594.4 946.427 17927.3 948.422 18121.6 950.415 18433.1 952.408 18720.3 954.4 18938.1 956.393 19127.7 958.383 19362.1 960.374 19531.1 962.365 19671.2 964.354 19874 966.342 20107.6 968.332 20250.1 970.319 20548.4 972.306 20878.7 974.293 21302.9 976.279 21771.4 978.265 22244 980.25 22927.1 982.234 23395.9 984.218 24199.2 986.202 24801 988.184 25423.4 990.166 25924.6 992.147 26285.4 994.128 26272.8 996.109 26042.3 998.089 25434.2 1000.07 24713.8 1002.05 23613.9 1004.02 22400.7 1006 21274.2 1007.98 20028.3 1009.96 19011.9 1011.93 18008.7 1013.91 17178.4 1015.88 16363.9 1017.86 15825.1 1019.83 15336.9 1021.8 14945.6 1023.77 14558.3 1025.75 14172.2 1027.72 13887.3 1029.69 13650 1031.66 13489.9 1033.63 13307.1 1035.6 13190.8 1037.57 13044.1 1039.53 12969.4 1041.5 12901.3 1043.47 12939.7 1045.43 12925.1 1047.4 12904.6 1049.36 12907.3 1051.33 12966.9 1053.29 12946.7 1055.26 12960.6 1057.22 13086.4 1059.18 13102.9 1061.14 13229.8 1063.11 13191 1065.06 13341.4 1067.03 13363.7 1068.98 13417.2 1070.94 13444.3 1072.9 13454.4 1074.86 13479 1076.82 13389.3 1078.77 13475.2 1080.73 13453.9 1082.69 13496.1 1084.64 13525.7 1086.59 13559.6 1088.55 13705.1 1090.5 13880.9 1092.45 14044.3 1094.41 14272.4 1096.36 14391.9 1098.31 14562.3 1100.26 14648.7 1102.21 14512.9 1104.16 14276 1106.11 13982 1108.06 13668 1110 13386.4 1111.95 13088.4 1113.9 12894.4 1115.84 12820.3 1117.79 12689.6 1119.73 12677 1121.68 12663.8 1123.62 12686.7 1125.57 12812.1 1127.51 12951.2 1129.45 13101 1131.39 13391.1 1133.33 13703.9 1135.27 13996.6 1137.21 14263.7 1139.15 14358.7 1141.09 14244.9 1143.03 13953.3 1144.97 13529.3 1146.9 13184 1148.84 12884.2 1150.78 12634.6 1152.71 12475.8 1154.65 12392.3 1156.58 12236.4 1158.52 12240.1 1160.45 12110.9 1162.38 12053.2 1164.31 11969.2 1166.25 11857.9 1168.18 11813 1170.11 11672.7 1172.04 11574.1 1173.97 11522.2 1175.9 11476.6 1177.83 11367.4 1179.75 11386.7 1181.68 11308.6 1183.61 11250.7 1185.53 11195.9 1187.46 11182.2 1189.38 11097.2 1191.31 11037.7 1193.23 10977.9 1195.16 10946.6 1197.08 10959.9 1199 10854.6 1200.92 10798.4 1202.84 10846.7 1204.76 10780.9 1206.68 10702.8 1208.6 10698.1 1210.52 10664.1 1212.44 10720 1214.36 10664 1216.28 10636.1 1218.19 10569 1220.11 10564 1222.03 10577.1 1223.94 10562.2 1225.86 10519.6 1227.77 10516.1 1229.68 10497.3 1231.6 10450.2 1233.51 10393 1235.42 10454.2 1237.33 10367.4 1239.24 10375.9 1241.15 10384.3 1243.06 10341.2 1244.97 10345.8 1246.88 10327 1248.79 10322.1 1250.7 10282.6 1252.6 10277.1 1254.51 10294.1 1256.42 10309.8 1258.32 10292.4 1260.23 10252.3 1262.13 10267.9 1264.04 10253.3 1265.94 10233.4 1267.84 10271.4 1269.74 10216.4 1271.64 10189.1 1273.55 10253.1 1275.45 10266.8 1277.35 10280.4 1279.25 10284.7 1281.14 10225.8 1283.04 10255.4 1284.94 10204.7 1286.84 10196.2 1288.74 10264.4 1290.63 10187.4 1292.53 10242.2 1294.42 10261.2 1296.32 10201.9 1298.21 10214.1 1300.11 10194.1 1302 10268 1303.89 10173.2 1305.78 10170.3 1307.67 10161.8 1309.57 10161.3 1311.46 10184.3 1313.34 10206.7 1315.23 10200.1 1317.12 10216.6 1319.01 10224.2 1320.9 10252.6 1322.79 10237.2 1324.67 10255.2 1326.56 10252.8 1328.45 10235.3 1330.33 10230 1332.21 10235.1 1334.1 10276.9 1335.98 10311.1 1337.86 10317.4 1339.75 10287.2 1341.63 10306.9 1343.51 10307.6 1345.39 10316.2 1347.27 10327.1 1349.15 10320.7 1351.03 10305.4 1352.91 10280.8 1354.79 10291.6 1356.66 10290.4 1358.54 10313.6 1360.42 10252.3 1362.29 10268.1 1364.17 10273.3 1366.04 10245.6 1367.92 10257.3 1369.79 10285.7 1371.67 10306.3 1373.54 10189.9 1375.41 10265.2 1377.28 10235.9 1379.15 10211.7 1381.03 10237.1 1382.9 10218.6 1384.76 10218.2 1386.63 10268.9 1388.5 10275.7 1390.37 10245.1 1392.24 10241.3 1394.11 10215.8 1395.97 10213.1 1397.84 10263.4 1399.7 10216 1401.57 10190.2 1403.43 10225 1405.3 10244.6 1407.16 10200.8 1409.02 10206.1 1410.89 10210.8 1412.75 10264 1414.61 10263.8 1416.47 10285.3 1418.33 10243.3 1420.19 10224.2 1422.05 10215.4 1423.91 10210.2 1425.77 10249.8 1427.62 10228.6 1429.48 10227.8 1431.34 10144 1433.19 10225.3 1435.05 10199.2 1436.9 10205.4 1438.76 10227 1440.61 10241.4 1442.47 10220.8 1444.32 10237.1 1446.17 10265.6 1448.02 10247 1449.87 10228.8 1451.73 10206.7 1453.58 10237.7 1455.42 10211 1457.27 10267 1459.12 10290.2 1460.97 10297.6 1462.82 10253.9 1464.67 10309 1466.51 10245.2 1468.36 10306.9 1470.2 10290.3 1472.05 10282.6 1473.89 10342.3 1475.74 10278.1 1477.58 10214.8 1479.42 10263.4 1481.27 10301.8 1483.11 10271.8 1484.95 10280.8 1486.79 10266.8 1488.63 10309.8 1490.47 10259.3 1492.31 10303.6 1494.15 10219.8 1495.99 10299 1497.83 10307.9 1499.66 10283.8 1501.5 10300.4 1503.34 10269.4 1505.17 10283.6 1507.01 10265.4 1508.84 10275.3 1510.68 10238.3 1512.51 10264.6 1514.35 10267.6 1516.18 10308.4 1518.01 10297 1519.84 10266.3 1521.67 10209.3 1523.5 10265.9 1525.33 10282.1 1527.16 10272.3 1528.99 10236.7 1530.82 10240.6 1532.65 10270.1 1534.48 10239.9 1536.3 10289.6 1538.13 10253.9 1539.96 10244.8 1541.78 10212.1 1543.61 10278 1545.43 10235.1 1547.26 10202.8 1549.08 10220.6 1550.9 10170.9 1552.73 10229.2 1554.55 10242.4 1556.37 10186.8 1558.19 10192.8 1560.01 10218.3 1561.83 10250.6 1563.65 10237.8 1565.47 10241.4 1567.29 10194.2 1569.11 10177.7 1570.92 10153.3 1572.74 10210.2 1574.56 10206.9 1576.37 10183.1 1578.19 10211.7 1580 10182.6 1581.82 10174.2 1583.63 10191.4 1585.45 10210.8 1587.26 10097.9 1589.07 10204.3 1590.88 10222.8 1592.69 10182.1 1594.51 10194.4 1596.32 10190.2 1598.13 10211.9 1599.94 10207 1601.74 10217.1 1603.55 10213.9 1605.36 10186.1 1607.17 10155.3 1608.97 10222.3 1610.78 10281.3 1612.59 10252.8 1614.39 10238.6 1616.2 10202 1618 10228.2 1619.81 10221.7 1621.61 10220.4 1623.41 10257.9 1625.21 10216.6 1627.02 10181.1 1628.82 10172.9 1630.62 10252.3 1632.42 10252.4 1634.22 10196 1636.02 10186.2 1637.82 10193.8 1639.61 10230.8 1641.41 10242 1643.21 10267.7 1645.01 10242.1 1646.8 10221.3 1648.6 10210.9 1650.39 10251.2 1652.19 10227.1 1653.98 10235 1655.78 10217.9 1657.57 10227.2 1659.36 10232.2 1661.16 10222 1662.95 10243.3 1664.74 10226.9 1666.53 10224.8 1668.32 10166.9 1670.11 10184.9 1671.9 10181.3 1673.69 10194.4 1675.48 10159.2 1677.26 10163.8 1679.05 10188.7 1680.84 10271.2 1682.63 10178.3 1684.41 10179.4 1686.2 10165.6 1687.98 10163.2 1689.77 10146.1 1691.55 10200 1693.33 10156 1695.12 10154.9 1696.9 10197.6 1698.68 10134.2 1700.46 10169 1702.24 10125 1704.02 10075.6 1705.8 10080.6 1707.58 10089.4 1709.36 10093.3 1711.14 10069.8 1712.92 10024.1 1714.7 10024.6 1716.47 10037.4 1718.25 9998.33 1720.03 9951.78 1721.8 9960.78 1723.58 10009.4 1725.35 9996.44 1727.13 9951.33 1728.9 9932.89 1730.67 9997 1732.44 9945.78 1734.22 9942.33 1735.99 9918.78 1737.76 9891.67 1739.53 9912 1741.3 9862.44 1743.07 9862.89 1744.84 9873.44 1746.61 9776 1748.38 9859.89 1750.14 9821.22 1751.91 9838.89 1753.68 9787.78 1755.44 9788.67 1757.21 9779 1758.98 9788.67 1760.74 9734.22 1762.5 9756.78 1764.27 9735.11 1766.03 9721.67 1767.79 9659.78 1769.56 9729 1771.32 9694.56 1773.08 9671.67 1774.84 9634.44 1776.6 9619.33 1778.36 9641.56 1780.12 9668.89 1781.88 9652.89 1783.64 9603.89 1785.4 9629.67 1787.15 9617.89 1788.91 9590.56 1790.67 9579.89 1792.42 9595.11 1794.18 9633 1795.93 9538 1797.69 9552.56 1799.44 9534.56 1801.2 9480 1802.95 9507.22 1804.7 9491.33 1806.46 9566.67 1808.21 9500.78 1809.96 9491.89 1811.71 9465.33 1813.46 9477.78 1815.21 9474 1816.96 9470.33 1818.71 9488.78 1820.46 9429.44 1822.2 9450.33 1823.95 9432.11 1825.7 9411.22 1827.44 9365.45 1829.19 9358.89 1830.94 9413.33 1832.68 9373.89 1834.42 9417.78 1836.17 9381.33 1837.91 9360.44 1839.66 9338 1841.4 9372 1843.14 9347.89 1844.88 9358.33 1846.62 9302.89 1848.36 9292 1850.1 9367.78 1851.84 9325.55 1853.58 9293.56 1855.32 9216 1857.06 9311.11 1858.8 9263.22 1860.54 9241.33 1862.27 9282.67 1864.01 9236.11 1865.74 9226.89 1867.48 9243.44 1869.22 9215.89 1870.95 9172.22 1872.68 9202.44 1874.42 9194.11 1876.15 9187.11 1877.88 9244.33 1879.61 9172.11 1881.35 9145.22 1883.08 9118.67 1884.81 9123.89 1886.54 9141.44 1888.27 9161.67 1890 9137.33 1891.73 9098.11 1893.45 9098.89 1895.18 9076.78 1896.91 9137 1898.64 9031.56 1900.36 9036.78 1902.09 9093.22 1903.81 9072.44 1905.54 9062.56 1907.26 9015.22 1908.99 9059.78 1910.71 9024.89 1912.43 9002 1914.16 8998.22 1915.88 9029.44 1917.6 9028.78 1919.32 9019.44 1921.04 9043.78 1922.76 8995.44 1924.48 8969.67 1926.2 8985.89 1927.92 8957.44 1929.64 8978.11 1931.36 8914.44 1933.08 8940.33 1934.79 8927.44 1936.51 8903.33 1938.23 8891.22 1939.94 8865.78 1941.66 8895.67 1943.37 8881.33 1945.08 8845.44 1946.8 8843.33 1948.51 8824 1950.22 8863.11 1951.94 8829.78 1953.65 8856.11 1955.36 8812.56 1957.07 8854.44 1958.78 8826 1960.49 8821.78 1962.2 8862.33 1963.91 8854.78 1965.62 8849.11 1967.33 8836.22 1969.03 8811.56 1970.74 8806.78 1972.45 8810.44 1974.15 8820.89 1975.86 8819.11 1977.56 8818.67 1979.27 8757 1980.97 8777.33 1982.68 8799.67 1984.38 8783.22 1986.08 8772.33 1987.79 8800.78 1989.49 8771 1991.19 8777.78 1992.89 8709.44 1994.59 8771.67 1996.29 8743.22 1997.99 8736.55 1999.69 8708.22