#------------------------------------------------------------------------------
#$Date: 2018-02-06 16:24:32 +0200 (Tue, 06 Feb 2018) $
#$Revision: 414 $
#$URL: svn://172.16.1.111/rod/cif/3/50/01/3500199.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500199
loop_
_publ_author_name
'El Mendili, Y'
'Secchi, M'
'Zannatta, M'
_publ_section_title
;
 Raman spectrum of commercial Nahcolite
;
_journal_name_full               'Personal communication to ROD'
_journal_year                    2018
_chemical_compound_source        'commercial powder Alfa aesar 99.7% 14707'
_chemical_formula_structural     'Na H C O3'
_chemical_formula_sum            'C H Na O3'
_chemical_name_mineral           Nahcolite
_chemical_name_systematic        'Na H C O3'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.32
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.51(4)
_cell_length_b                   9.70(4)
_cell_length_c                   3.53(3)
_raman_determination_method      experimental
_[local]_chemical_compound_color white
_[local]_chemical_compound_state Solid
_raman_measurement_device.location 'University of Trento'
_raman_measurement_device.company Horiba
_raman_measurement_device.model  Aramis
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.50
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 633
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 2
_raman_measurement_device.power_on_sample 12
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1
_raman_measurement_device.diffraction_grating 600
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 10
_raman_measurement.datetime_initiated 2018-01-15
_rod_data_source.file            NaHCO3.rod
_rod_data_source.block           3500020
_rod_database.code               3500199
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 silicon_wafer
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 1011016 COD http://www.crystallography.net/cod/1011016.html
;
no XRD analysis data.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
102.279 1189
104.522 1333
106.766 1909
109.007 3585
111.248 7418
113.489 11691
115.728 12248
117.967 8601
120.207 4486
122.445 2543
124.682 1995
126.919 1696
129.155 1379
131.39 1136
133.624 1144
135.858 1358
138.09 1978
140.323 3598
142.555 6605
144.786 9133
147.017 8816
149.247 6355
151.475 4133
153.704 3065
155.932 2372
158.158 1742
160.385 1355
162.612 1309
164.836 1483
167.061 1522
169.284 1353
171.508 960
173.729 729
175.952 572
178.172 596
180.394 651
182.613 739
184.833 686
187.051 595
189.268 524
191.486 468
193.702 505
195.917 512
198.134 593
200.348 780
202.561 1044
204.774 1310
206.986 1395
209.198 1414
211.409 1336
213.621 1170
215.83 973
218.039 884
220.248 872
222.456 1052
224.663 1294
226.868 1599
229.074 1686
231.279 1580
233.484 1366
235.688 1061
237.892 827
240.093 693
242.295 587
244.497 545
246.698 462
248.897 432
251.096 386
253.295 356
255.492 359
257.69 351
259.886 315
262.083 312
264.277 305
266.473 300
268.666 288
270.86 291
273.052 253
275.245 270
277.436 262
279.626 246
281.816 264
284.006 248
286.194 228
288.382 223
290.569 244
292.757 237
294.943 235
297.128 236
299.313 233
301.497 238
303.68 221
305.863 241
308.045 217
310.227 232
312.408 239
314.588 229
316.768 243
318.947 246
321.125 237
323.302 256
325.479 274
327.656 262
329.832 259
332.007 264
334.181 245
336.355 221
338.528 215
340.7 223
342.872 208
345.043 217
347.214 233
349.383 212
351.553 227
353.721 216
355.889 189
358.056 197
360.224 196
362.389 190
364.554 199
366.72 199
368.883 200
371.046 192
373.209 197
375.372 187
377.533 195
379.694 193
381.854 193
384.013 205
386.172 207
388.33 197
390.487 209
392.644 201
394.801 189
396.957 200
399.112 199
401.266 188
403.42 182
405.574 191
407.726 204
409.878 195
412.029 192
414.179 183
416.33 182
418.48 194
420.627 195
422.776 189
424.922 176
427.07 170
429.216 177
431.361 176
433.507 197
435.65 194
437.794 168
439.937 186
442.078 179
444.221 164
446.361 171
448.503 185
450.642 184
452.781 174
454.919 169
457.058 165
459.195 170
461.331 176
463.467 188
465.602 196
467.737 182
469.871 164
472.004 172
474.137 176
476.269 167
478.401 159
480.532 179
482.662 177
484.792 185
486.921 194
489.05 191
491.178 184
493.304 185
495.431 177
497.557 188
499.682 173
501.806 173
503.931 185
506.054 188
508.176 183
510.299 192
512.42 160
514.541 184
516.661 168
518.781 183
520.9 171
523.019 172
525.136 197
527.253 186
529.37 171
531.485 170
533.6 168
535.714 173
537.83 170
539.943 182
542.055 182
544.167 185
546.278 170
548.389 173
550.499 192
552.609 182
554.718 170
556.826 172
558.934 182
561.041 176
563.148 161
565.254 170
567.359 176
569.464 154
571.569 175
573.671 174
575.774 187
577.877 189
579.977 177
582.079 193
584.18 193
586.279 183
588.378 198
590.476 185
592.574 201
594.671 184
596.768 176
598.864 189
600.96 172
603.054 171
605.148 185
607.242 185
609.335 188
611.427 189
613.519 189
615.61 201
617.7 184
619.79 193
621.879 208
623.968 202
626.055 193
628.144 188
630.231 207
632.317 205
634.403 210
636.486 213
638.571 208
640.655 213
642.738 209
644.821 278
646.903 395
648.984 556
651.064 558
653.144 443
655.224 301
657.302 304
659.381 439
661.459 685
663.535 752
665.612 593
667.687 375
669.763 303
671.837 317
673.912 293
675.985 303
678.058 362
680.13 435
682.201 631
684.273 946
686.343 1485
688.412 2034
690.481 2039
692.551 1613
694.618 1094
696.686 732
698.752 739
700.818 848
702.883 778
704.948 572
707.013 364
709.076 295
711.139 240
713.202 244
715.264 222
717.326 231
719.385 216
721.445 211
723.505 191
725.564 195
727.623 197
729.68 203
731.737 199
733.794 204
735.849 193
737.905 179
739.959 184
742.014 196
744.067 191
746.12 199
748.172 183
750.224 206
752.275 187
754.325 208
756.376 194
758.424 188
760.473 192
762.521 179
764.569 186
766.616 199
768.662 196
770.707 196
772.752 198
774.797 199
776.841 188
778.884 192
780.927 199
782.969 189
785.01 195
787.051 204
789.092 185
791.132 201
793.171 204
795.209 201
797.247 195
799.285 198
801.322 204
803.357 189
805.393 208
807.428 200
809.463 203
811.497 211
813.529 214
815.563 198
817.594 201
819.625 214
821.657 193
823.687 213
825.717 211
827.746 215
829.774 212
831.801 241
833.83 247
835.856 284
837.882 294
839.908 293
841.932 276
843.957 236
845.982 212
848.005 185
850.027 216
852.05 212
854.07 192
856.091 193
858.111 205
860.131 196
862.15 216
864.169 195
866.187 206
868.204 205
870.221 195
872.238 220
874.252 213
876.268 195
878.283 189
880.296 195
882.31 194
884.322 194
886.335 202
888.345 202
890.356 219
892.367 217
894.376 206
896.386 198
898.395 196
900.402 208
902.409 208
904.417 207
906.423 193
908.429 211
910.434 207
912.438 212
914.442 194
916.445 204
918.448 205
920.451 219
922.452 215
924.453 216
926.454 211
928.454 209
930.454 207
932.451 212
934.45 218
936.448 222
938.445 215
940.441 218
942.437 218
944.433 209
946.427 211
948.422 218
950.415 212
952.408 212
954.4 237
956.393 216
958.383 216
960.374 209
962.365 220
964.354 224
966.342 227
968.332 214
970.319 229
972.306 222
974.293 234
976.279 230
978.265 233
980.25 227
982.234 254
984.218 263
986.202 282
988.184 298
990.166 343
992.147 388
994.128 412
996.109 435
998.089 429
1000.07 394
1002.05 374
1004.02 373
1006 352
1007.98 330
1009.96 327
1011.93 293
1013.91 312
1015.88 309
1017.86 329
1019.83 322
1021.8 340
1023.77 338
1025.75 392
1027.72 407
1029.69 377
1031.66 449
1033.63 477
1035.6 542
1037.57 702
1039.53 908
1041.5 1177
1043.47 1995
1045.43 4264
1047.4 9105
1049.36 13585
1051.33 13398
1053.29 8847
1055.26 4419
1057.22 2060
1059.18 1195
1061.14 808
1063.11 622
1065.06 527
1067.03 473
1068.98 472
1070.94 393
1072.9 390
1074.86 353
1076.82 330
1078.77 313
1080.73 311
1082.69 288
1084.64 304
1086.59 288
1088.55 281
1090.5 276
1092.45 291
1094.41 251
1096.36 270
1098.31 267
1100.26 273
1102.21 261
1104.16 262
1106.11 265
1108.06 261
1110 265
1111.95 267
1113.9 276
1115.84 259
1117.79 279
1119.73 276
1121.68 253
1123.62 263
1125.57 249
1127.51 291
1129.45 277
1131.39 250
1133.33 267
1135.27 261
1137.21 279
1139.15 269
1141.09 257
1143.03 273
1144.97 218
1146.9 268
1148.84 262
1150.78 269
1152.71 257
1154.65 269
1156.58 264
1158.52 270
1160.45 257
1162.38 246
1164.31 257
1166.25 270
1168.18 256
1170.11 260
1172.04 257
1173.97 272
1175.9 264
1177.83 278
1179.75 243
1181.68 254
1183.61 280
1185.53 256
1187.46 266
1189.38 271
1191.31 284
1193.23 307
1195.16 268
1197.08 317
1199 299
1200.92 316
1202.84 317
1204.76 309
1206.68 294
1208.6 342
1210.52 335
1212.44 353
1214.36 337
1216.28 350
1218.19 346
1220.11 367
1222.03 386
1223.94 395
1225.86 399
1227.77 417
1229.68 449
1231.6 451
1233.51 465
1235.42 489
1237.33 479
1239.24 538
1241.15 599
1243.06 626
1244.97 661
1246.88 750
1248.79 811
1250.7 900
1252.6 964
1254.51 1064
1256.42 1181
1258.32 1259
1260.23 1382
1262.13 1584
1264.04 1732
1265.94 1960
1267.84 2223
1269.74 2349
1271.64 2501
1273.55 2466
1275.45 2406
1277.35 2201
1279.25 1962
1281.14 1680
1283.04 1408
1284.94 1198
1286.84 1073
1288.74 903
1290.63 818
1292.53 712
1294.42 636
1296.32 559
1298.21 531
1300.11 485
1302 473
1303.89 432
1305.78 416
1307.67 376
1309.57 394
1311.46 373
1313.34 332
1315.23 331
1317.12 338
1319.01 323
1320.9 309
1322.79 309
1324.67 310
1326.56 291
1328.45 285
1330.33 288
1332.21 262
1334.1 244
1335.98 247
1337.86 267
1339.75 256
1341.63 274
1343.51 263
1345.39 249
1347.27 270
1349.15 251
1351.03 266
1352.91 257
1354.79 246
1356.66 239
1358.54 251
1360.42 267
1362.29 246
1364.17 245
1366.04 248
1367.92 237
1369.79 232
1371.67 243
1373.54 249
1375.41 242
1377.28 248
1379.15 225
1381.03 254
1382.9 244
1384.76 228
1386.63 250
1388.5 245
1390.37 235
1392.24 224
1394.11 248
1395.97 250
1397.84 234
1399.7 253
1401.57 238
1403.43 240
1405.3 243
1407.16 228
1409.02 234
1410.89 250
1412.75 255
1414.61 246
1416.47 256
1418.33 266
1420.19 261
1422.05 270
1423.91 281
1425.77 284
1427.62 282
1429.48 311
1431.34 346
1433.19 409
1435.05 550
1436.9 737
1438.76 938
1440.61 985
1442.47 860
1444.32 685
1446.17 521
1448.02 466
1449.87 449
1451.73 458
1453.58 509
1455.42 573
1457.27 662
1459.12 740
1460.97 786
1462.82 823
1464.67 788
1466.51 684
1468.36 606
1470.2 485
1472.05 439
1473.89 377
1475.74 351
1477.58 329
1479.42 288
1481.27 303
1483.11 267
1484.95 272
1486.79 254
1488.63 235
1490.47 258
1492.31 252
1494.15 230
1495.99 244
1497.83 249
1499.66 265
1501.5 228
1503.34 243
1505.17 216
1507.01 225
1508.84 207
1510.68 239
1512.51 216
1514.35 237
1516.18 221
1518.01 233
1519.84 229
1521.67 212
1523.5 225
1525.33 210
1527.16 216
1528.99 221
1530.82 210
1532.65 231
1534.48 226
1536.3 217
1538.13 232
1539.96 215
1541.78 222
1543.61 209
1545.43 209
1547.26 226
1549.08 218
1550.9 219
1552.73 216
1554.55 208
1556.37 216
1558.19 220
1560.01 231
1561.83 208
1563.65 217
1565.47 209
1567.29 224
1569.11 222
1570.92 224
1572.74 219
1574.56 220
1576.37 222
1578.19 229
1580 219
1581.82 230
1583.63 215
1585.45 222
1587.26 222
1589.07 239
1590.88 231
1592.69 232
1594.51 224
1596.32 217
1598.13 219
1599.94 230
1601.74 231
1603.55 256
1605.36 247
1607.17 244
1608.97 264
1610.78 268
1612.59 255
1614.39 291
1616.2 310
1618 311
1619.81 340
1621.61 396
1623.41 437
1625.21 462
1627.02 473
1628.82 440
1630.62 438
1632.42 382
1634.22 366
1636.02 309
1637.82 289
1639.61 278
1641.41 254
1643.21 263
1645.01 249
1646.8 242
1648.6 211
1650.39 217
1652.19 230
1653.98 226
1655.78 217
1657.57 231
1659.36 229
1661.16 235
1662.95 229
1664.74 235
1666.53 234
1668.32 245
1670.11 265
1671.9 278
1673.69 292
1675.48 302
1677.26 306
1679.05 303
1680.84 299
1682.63 322
1684.41 310
1686.2 323
1687.98 316
1689.77 284
1691.55 320
1693.33 304
1695.12 297
1696.9 307
1698.68 305
1700.46 275
1702.24 271
1704.02 251
1705.8 249
1707.58 231
1709.36 228
1711.14 236
1712.92 210
1714.7 240
1716.47 224
1718.25 224
1720.03 228
1721.8 228
1723.58 234
1725.35 244
1727.13 230
1728.9 237
1730.67 233
1732.44 221
1734.22 213
1735.99 227
1737.76 226
1739.53 234
1741.3 228
1743.07 212
1744.84 199
1746.61 210
1748.38 217
1750.14 211
1751.91 211
1753.68 218
1755.44 206
1757.21 214
1758.98 211
1760.74 221
1762.5 217
1764.27 219
1766.03 213
1767.79 203
1769.56 208
1771.32 216
1773.08 222
1774.84 224
1776.6 196
1778.36 210
1780.12 209
1781.88 214
1783.64 210
1785.4 213
1787.15 214
1788.91 209
1790.67 215
1792.42 214
1794.18 212
1795.93 206
1797.69 217
1799.44 210
1801.2 223
1802.95 215
1804.7 228
1806.46 232
1808.21 231
1809.96 221
1811.71 213
1813.46 215
1815.21 227
1816.96 235
1818.71 218
1820.46 229
1822.2 239
1823.95 213
1825.7 239
1827.44 247
1829.19 241
1830.94 230
1832.68 233
1834.42 260
1836.17 237
1837.91 258
1839.66 252
1841.4 246
1843.14 243
1844.88 226
1846.62 237
1848.36 252
1850.1 258
1851.84 245
1853.58 245
1855.32 245
1857.06 250
1858.8 251
1860.54 230
1862.27 244
1864.01 240
1865.74 248
1867.48 250
1869.22 215
1870.95 219
1872.68 227
1874.42 237
1876.15 232
1877.88 235
1879.61 239
1881.35 235
1883.08 240
1884.81 237
1886.54 248
1888.27 245
1890 245
1891.73 276
1893.45 243
1895.18 245
1896.91 259
1898.64 262
1900.36 260
1902.09 271
1903.81 269
1905.54 279
1907.26 297
1908.99 281
1910.71 304
1912.43 304
1914.16 291
1915.88 284
1917.6 305
1919.32 307
1921.04 301
1922.76 311
1924.48 280
1926.2 276
1927.92 288
1929.64 290
1931.36 284
1933.08 280
1934.79 255
1936.51 274
1938.23 296
1939.94 248
1941.66 253
1943.37 240
1945.08 255
1946.8 238
1948.51 221
1950.22 254
1951.94 249
1953.65 230
1955.36 247
1957.07 234
1958.78 238
1960.49 250
1962.2 227
1963.91 231
1965.62 229
1967.33 225
1969.03 233
1970.74 210
1972.45 233
1974.15 231
1975.86 227
1977.56 229
1979.27 225
1980.97 209
1982.68 239
1984.38 232
1986.08 229
1987.79 242
1989.49 247
1991.19 232
1992.89 223
1994.59 238
1996.29 227
1997.99 224
1999.69 241
