#------------------------------------------------------------------------------
#$Date: 2018-09-06 11:24:34 +0300 (Thu, 06 Sep 2018) $
#$Revision: 1277 $
#$URL: svn://172.16.1.111/rod/cif/3/50/02/3500216.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500216
loop_
_publ_author_name
'Kumar, A.'
'Cassetta, M.'
'El Mendili, Y.'
'Zanatta, M.'
'Daldosso, N.'
'Mariotto, G.'
_publ_section_title
;
 Raman spectrum of commercial Al2O3
;
_journal_name_full               'Personal communication to ROD'
_journal_year                    2018
_chemical_compound_source        'commercial powder Alfa Aesar 99%'
_chemical_formula_structural     'O3 Al2'
_chemical_formula_sum            'Al2 O3'
_chemical_name_mineral           Corundum
_chemical_name_systematic        'Aluminium oxide'
_space_group_IT_number           167
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-R 3 2"c'
_symmetry_space_group_name_H-M   'R -3 c :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            6
_cell_length_a                   4.7606(5)
_cell_length_b                   4.7606(5)
_cell_length_c                   12.994(1)
_cod_original_formula_sum        'O3 Al2'
_raman_determination_method      experimental
_[local]_chemical_compound_color Brown
_[local]_chemical_compound_state Solid
_raman_measurement_device.location 'University of Verona'
_raman_measurement_device.company Horiba
_raman_measurement_device.model  LabRamHR800
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.50
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 633
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 1
_raman_measurement_device.power_on_sample 0.6
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1.5
_raman_measurement_device.diffraction_grating 600
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 50
_raman_measurement.datetime_initiated 2018-01-22
_rod_data_source.file            alphaAl2O3.rod.txt
_rod_data_source.block           0000001
_rod_database.code               3500216
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 silicon_wafer
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 1000017 COD http://www.crystallography.net/cod/1000017.html
;
no XRD analysis data.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
150.04601 34993.398
151.323 22122.801
152.59801 14905.2
153.87399 10743.4
155.151 8082.7998
156.425 6259.7998
157.701 5018.7998
158.97701 4191.3999
160.25101 3466.3999
161.526 3017.8
162.80099 2643.6001
164.075 2286.8
165.349 2023.4
166.62399 1856
167.896 1680.6
169.17101 1549.6
170.44299 1423
171.716 1338.8
172.98801 1265.6
174.26199 1210.8
175.535 1165.2
176.806 1125.4
178.078 1120.6
179.349 1116.2
180.621 1105.6
181.892 1108.6
183.164 1156.4
184.43401 1201.2
185.705 1228
186.97501 1291
188.246 1405
189.515 1651.2
190.785 1952.2
192.054 2442.2
193.32401 3317.6001
194.593 4631.3999
195.862 6199.3999
197.13 7177.7998
198.39799 6855.7998
199.66701 5875.3999
200.93401 4813.7998
202.203 3747.8
203.47 2843
204.737 2180.6001
206.005 1738
207.271 1469.4
208.539 1271
209.80499 1149
211.07001 1059
212.33701 1008
213.603 962.59998
214.868 937
216.134 894
217.399 863.59998
218.66299 848.20001
219.929 843.20001
221.19299 859.20001
222.457 843
223.72099 839
224.98599 843.79999
226.24899 876.59998
227.51199 925
228.776 934.20001
230.039 937.59998
231.30099 953.79999
232.564 884.79999
233.827 865.20001
235.089 843
236.351 802.59998
237.612 792.20001
238.873 777.20001
240.136 797
241.397 789.40002
242.657 810.40002
243.918 803
245.17799 833
246.438 817.20001
247.698 843.59998
248.959 845.20001
250.218 894.79999
251.47701 869.59998
252.73599 912.20001
253.995 918.79999
255.25301 962
256.51199 937
257.76999 980.79999
259.02802 1036.8
260.28699 1034.6
261.54501 1077.4
262.802 1158.2
264.05899 1190
265.31601 1275.8
266.573 1346
267.82901 1458.4
269.086 1579.8
270.34201 1731.6
271.59799 1968.8
272.853 2238.6001
274.10901 2631.3999
275.36401 3131
276.61899 3938.3999
277.87399 5181.2002
279.129 7176.6001
280.383 10529.8
281.638 15754.2
282.89001 22277
284.14401 26890.4
285.39801 26959
286.651 23218.4
287.905 17777
289.15799 12658.6
290.41 8924
291.66299 6431.6001
292.91599 5038.3999
294.168 4197.2002
295.418 3821.2
296.67001 3728.6001
297.922 3853.8
299.173 4266.6001
300.42499 4916.6001
301.67599 5886
302.92499 6919
304.17599 7593.2002
305.42599 7460
306.677 6812.6001
307.927 5943.6001
309.17499 5090.2002
310.42499 4344.6001
311.67401 3771.3999
312.923 3212.6001
314.17099 2780
315.42001 2484.3999
316.668 2213.2
317.91699 1992.8
319.16299 1830.8
320.41101 1675.6
321.659 1570.2
322.905 1510.6
324.15302 1449.6
325.39999 1387.6
326.647 1293
327.89301 1282.2
329.13901 1197.2
330.384 1200.2
331.63 1155.2
332.87601 1133.8
334.121 1102.6
335.366 1096
336.612 1081.2
337.85599 1052
339.10101 1029.6
340.34399 1000.8
341.58899 1015
342.83301 995.79999
344.07599 952.79999
345.32001 950.20001
346.56201 939
347.806 949
349.048 951.79999
350.29099 976.40002
351.53201 959.40002
352.77499 973
354.01599 1006.2
355.259 1008
356.5 983.40002
357.742 966.59998
358.98199 935.40002
360.224 916.40002
361.46399 895.20001
362.70499 908.79999
363.944 894
365.185 898.79999
366.42401 921.40002
367.66299 925.20001
368.90399 917
370.142 948.40002
371.38199 943.79999
372.62 942.79999
373.858 981.20001
375.09698 968.40002
376.33499 1009.0667
377.57401 1050
378.811 1050.8
380.048 1061.2
381.28601 1080.6
382.52301 1112.6
383.759 1118.4
384.99701 1158.2
386.233 1181.8
387.46799 1239
388.70401 1318.4
389.94101 1343.2
391.17599 1423
392.41101 1515.6
393.647 1653
394.88199 1811.8
396.116 2035.8
397.35101 2349.6001
398.58499 2838.2
399.82001 3433
401.05301 4267.6001
402.28699 5372.2002
403.51999 6475.3999
404.755 7176.6001
405.987 7051.6001
407.22 6345.7998
408.452 5226.3999
409.685 4142.7998
410.91699 3327.2
412.14899 2729.3999
413.38199 2324.3999
414.61301 2000.6
415.84399 1749
417.07501 1595.8
418.306 1480.8
419.53699 1386.4
420.767 1286.6
421.99799 1259
423.228 1201.6
424.45901 1206.6
425.689 1139.8
426.918 1134
428.147 1123.4
429.37601 1131.6
430.60501 1090.4
431.83401 1129.6
433.06299 1125.2
434.29099 1099.8
435.51901 1123.6
436.74701 1137.2
437.97501 1142.6
439.202 1159.2
440.42899 1165.4
441.65601 1186.4
442.883 1185.2
444.10999 1213.2
445.33499 1252.4
446.56201 1254.4
447.78799 1292.2
449.01401 1330.4
450.23901 1380.6
451.465 1435.4
452.69 1486.8
453.91501 1555.2
455.14001 1618.4
456.36499 1670.2
457.58801 1750
458.81299 1858.8
460.03699 1919
461.26099 2075.3999
462.48499 2226
463.70801 2351.6001
464.92999 2585.8
466.15302 2804.3999
467.37601 3099.8
468.599 3438.6001
469.82001 3787.6001
471.043 4232.3999
472.26501 4683.3999
473.487 5180
474.70901 5669
475.92899 6191.7998
477.151 6646
478.37201 7252.2002
479.59201 7689
480.81201 7977.3999
482.03299 8172
483.254 8070.3999
484.47198 7851.3999
485.69299 7427.7998
486.91199 7008.6001
488.13101 6390.2002
489.35001 5849.2002
490.56799 5319.3999
491.78699 4843.3999
493.00601 4506.7998
494.22299 4082.6001
495.44199 3849.2
496.66 3602.3999
497.87701 3495.8
499.095 3308
500.311 3187.2
501.52899 3093.2
502.745 3073.2
503.96201 3013.2
505.17899 3007.3999
506.39401 3028
507.61099 3014.2
508.82599 3031.2
510.04199 3082.6001
511.25699 3204.2
512.47302 3314.3999
513.68701 3465.6001
514.90198 3689.2
516.11603 3864.8
517.33099 4185.3999
518.54498 4517.6001
519.75897 4861.7998
520.97198 5375.6001
522.185 5800.6001
523.39899 6364.6001
524.612 6813.7998
525.82501 7290
527.03802 7535.7998
528.24902 7595.6001
529.46301 7482.3999
530.67401 7225
531.88702 6727.6001
533.09802 6239
534.30902 5609
535.521 5052
536.73199 4599.6001
537.94202 4168.6001
539.15399 3767.3999
540.36298 3446
541.573 3189
542.784 2997.6001
543.99402 2729.2
545.203 2626.8
546.41199 2435.3999
547.62201 2337.8
548.83099 2238
550.039 2180
551.24701 2108.6001
552.45697 2055.2
553.66498 1984
554.87201 1906.2
556.08002 1869.2
557.289 1822.2
558.49597 1760.2
559.703 1707.8
560.909 1697.2
562.11603 1660.4
563.32202 1606.8
564.53003 1598.4
565.73602 1556.6
566.94202 1556.8
568.14697 1507.6
569.35303 1506.6
570.55798 1465
571.763 1462.4
572.96802 1454.8
574.17401 1436.6
575.37799 1398.4
576.58197 1435
577.78601 1369.6
578.98999 1377.8
580.19397 1348.6
581.39697 1360.6
582.60101 1331.6
583.80402 1313.2
585.00702 1343.6
586.20898 1323.4
587.41199 1300
588.61401 1292.8
589.81598 1284.2
591.01801 1293.2
592.21997 1280.8
593.422 1273.2
594.62299 1290.6
595.82397 1287.6
597.02502 1330.2
598.22601 1314.2
599.427 1335.4
600.62598 1320.6
601.82599 1326.2
603.026 1345.6
604.22601 1349
605.42603 1376.2
606.625 1350.2
607.82397 1339.2
609.02301 1353.2
610.22101 1340.8
611.41998 1340.6
612.61798 1325.6
613.81702 1359.6
615.01501 1337
616.21301 1333.8
617.409 1295.4
618.60699 1300.8
619.80402 1347.2
621.00098 1313.8
622.19702 1352
623.39398 1327.2
624.591 1336.4
625.78699 1332.4
626.98199 1329.8
628.17798 1365.6
629.37402 1372.2
630.57001 1413
631.76398 1404.6
632.95898 1443.4
634.15399 1472.2
635.34802 1464.2
636.54199 1531.8
637.737 1527.4
638.92999 1585.2
640.12402 1601.8
641.31799 1661.8
642.51099 1687.8
643.70398 1765
644.896 1824.6
646.09003 1903.8
647.28302 1944.8
648.474 1982.2
649.66699 2010.4
650.85797 2033.4
652.04999 2119.2
653.24103 2175
654.43298 2188.8
655.62299 2194.8
656.815 2209
658.00598 2222
659.19598 2193.8
660.38702 2221
661.57703 2223.2
662.76599 2228.2
663.95599 2221.2
665.14502 2257
666.33502 2245
667.52399 2300.3999
668.71399 2337.2
669.90198 2393.3999
671.091 2450.6001
672.27899 2488.8
673.466 2596.6001
674.65503 2716
675.84198 2848.6001
677.03101 3015.6001
678.21802 3094.8
679.40399 3324.8
680.59198 3505.2
681.77802 3760.6001
682.96399 4034.2
684.15198 4345.3999
685.33698 4737.6001
686.52301 5177.2002
687.71002 5698.2002
688.89502 6227.7998
690.08002 6980
691.26599 7735.2002
692.45001 8495.4004
693.63501 9451.7998
694.81897 10591.6
696.00403 11686.2
697.18799 12670.6
698.37201 13717.6
699.55499 14528.8
700.73901 15140
701.92297 15198.8
703.10602 15223.6
704.289 14486.8
705.47101 13646.2
706.65399 12646.4
707.83698 11501.4
709.01898 10289.8
710.20099 9179.4004
711.383 8243.2002
712.56403 7224
713.745 6484.3999
714.927 5825.6001
716.10901 5207.2002
717.289 4773
718.46997 4367.3999
719.65002 4011.8
720.83002 3625.3999
722.01001 3338.3999
723.19 3133
724.37 2940.6001
725.54901 2750.2
726.72803 2563.6001
727.90698 2413.8
729.086 2303
730.26501 2155
731.44299 2093
732.62201 2002.8
733.79999 1897
734.97803 1855.4
736.15503 1780.4
737.33301 1739.6
738.51001 1648.4
739.68799 1577
740.86499 1545.4
742.04102 1499.6
743.21802 1452.4
744.39502 1375.8
745.56897 1357.6
746.745 1331.4
747.92102 1281.4
749.09698 1274.4
750.27301 1251.4
751.448 1209
752.62299 1158
753.797 1144.2
754.97198 1135.4
756.146 1106
757.32098 1072.8
758.495 1055.6
759.66803 1029.6
760.841 1018.8
762.01501 1019
763.18903 990.40002
764.362 975.40002
765.534 1008.4
766.70697 1038.8
767.88 979.96667
769.05103 960.79999
770.22302 949.40002
771.39502 947
772.56799 946.79999
773.73798 935.20001
774.90997 940
776.08099 964.40002
777.25098 948.20001
778.422 961.79999
779.59302 955.59998
780.763 977.79999
781.93298 949
783.10199 989.20001
784.27301 984.20001
785.44299 988.79999
786.61102 1027.8
787.78101 1041
788.94897 1015.4
790.11798 1038
791.28699 1036.2
792.45502 1055.4
793.62402 1078.2
794.79102 1095.6
795.95898 1097.8
797.12598 1103
798.29401 1102.8
799.461 1091.8
800.62799 1091.8
801.79498 1083.4
802.96198 1073.8
804.12799 1078.8
805.29498 1066.4
806.46002 1064.2
807.62701 1048.6
808.79199 1059.8
809.95599 1006
811.12299 1012.8
812.28699 957
813.453 957.79999
814.617 952.79999
815.78101 922.59998
816.94598 908.59998
818.10999 902.20001
819.27301 868.20001
820.43799 875.40002
821.60101 853.79999
822.763 830.79999
823.92798 839.59998
825.09003 818.59998
826.25201 825
827.41602 802.79999
828.578 804
829.73999 792.20001
830.901 801.20001
832.06403 781.20001
833.22498 790.79999
834.38599 800.79999
835.547 762.59998
836.70898 785.40002
837.87 769.59998
839.03003 775.59998
840.19 767.20001
841.34998 784.59998
842.51202 780
843.67102 774.59998
844.83099 774.79999
845.98999 764.79999
847.14899 764.79999
848.30798 766.79999
849.46802 770
850.62701 770.59998
851.78497 763.59998
852.94299 750.59998
854.10101 748.40002
855.25897 748.79999
856.41699 748.20001
857.57397 742.79999
858.73102 749
859.888 736.40002
861.04498 750
862.20203 739.40002
863.35901 726
864.51501 724.40002
865.67102 712.79999
866.82703 727.79999
867.98297 715.59998
869.13898 701.59998
870.29401 689
871.45001 703.79999
872.60498 694.20001
873.76001 687.40002
874.91498 689
876.06897 697.20001
877.224 684.40002
878.37799 680.59998
879.53198 659.59998
880.68597 687.59998
881.84003 656.59998
882.992 687.20001
884.14502 653
885.29797 672.59998
886.45099 660.79999
887.604 675
888.75702 669.40002
889.90802 658
891.06 651.79999
892.21198 663
893.36401 671.79999
894.51599 667.20001
895.66602 657
896.81799 672.40002
897.96899 652.59998
899.12 646.59998
900.26898 656.40002
901.41998 667.79999
902.57098 664.79999
903.72101 653.79999
904.87 660.79999
906.02002 695.20001
907.16998 658
908.31799 670.79999
909.46698 676.79999
910.617 654.20001
911.76398 661.20001
912.91302 656.59998
914.06201 672.40002
915.20898 686.20001
916.35797 688
917.50403 707.40002
918.65198 705.59998
919.79999 694.20001
920.94702 717.79999
922.09399 711.79999
923.23999 718.20001
924.38702 733.40002
925.53302 716.79999
926.67999 726.59998
927.82501 738.20001
928.97101 762.79999
930.11603 766
931.26202 739.20001
932.40698 760.59998
933.55298 775.79999
934.69702 772.59998
935.84198 777.59998
936.98602 801.59998
938.13098 809
939.27502 810.59998
940.41901 828.40002
941.56201 835.20001
942.70502 844.79999
943.84998 863.40002
944.992 854.40002
946.13599 886.79999
947.27802 903.20001
948.41998 911.79999
949.56403 911.79999
950.70502 918.20001
951.84698 909.59998
952.98999 927
954.13098 907.59998
955.27197 913.20001
956.414 948.40002
957.55499 954.20001
958.69501 959
959.83698 973.20001
960.97699 981.20001
962.117 994.40002
963.25702 977
964.39801 939.20001
965.53699 953.79999
966.677 953
967.81598 937.20001
968.95502 934.79999
970.09497 895
971.23401 894.20001
972.37201 887.79999
973.51001 871.59998
974.64801 879.20001
975.78601 884
976.92499 874.79999
978.06299 917.79999
979.20001 926.79999
980.33698 920
981.474 960.20001
982.61102 980.79999
983.74799 1010.8
984.88397 1115.6
986.021 1250.2
987.15698 1426.6
988.29303 1789.4
989.42902 2414
990.565 3883.8
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