#------------------------------------------------------------------------------
#$Date: 2018-09-06 13:04:52 +0300 (Thu, 06 Sep 2018) $
#$Revision: 1301 $
#$URL: svn://172.16.1.111/rod/cif/3/50/02/3500238.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500238
loop_
_publ_author_name
'Kumar, A.'
'Cassetta, M.'
'El Mendili, Y.'
'Zanatta, M.'
'Daldosso, N.'
'Mariotto, G.'
_publ_section_title
;
 Raman spectrum of commercial GeO2
;
_journal_name_full               'Personal communication to ROD'
_journal_year                    2018
_chemical_compound_source        'commercial Alfa Aesar 99.99%'
_chemical_formula_structural     'Ge O2'
_chemical_formula_sum            'Ge O2'
_chemical_name_mineral           Argutite
_chemical_name_systematic        'Germanium dioxide'
_space_group_IT_number           199
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-P 4n 2n'
_symmetry_space_group_name_H-M   'P 42/m n m'
_cell_angle_alpha                90.0
_cell_angle_beta                 90.0
_cell_angle_gamma                90.0
_cell_formula_units_Z            2
_cell_length_a                   4.40656(5)
_cell_length_b                   4.40656(5)
_cell_length_c                   2.86186(3)
_raman_determination_method      experimental
_[local]_chemical_compound_color white
_[local]_chemical_compound_state Solid
_raman_measurement_device.location 'University of Verona'
_raman_measurement_device.company Horiba
_raman_measurement_device.model
'LabRamHR800_raman_measurement_device.optics_type microscope'
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.50
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 633
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 1
_raman_measurement_device.power_on_sample 6
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1.5
_raman_measurement_device.diffraction_grating 600
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 100
_raman_measurement.datetime_initiated 2018-01-22
_rod_data_source.file            GeO2.txt
_rod_data_source.block           0000001
_rod_database.code               3500238
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 silicon_wafer
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 2101851 COD http://www.crystallography.net/cod/2101851.html
;
no XRD analysis data.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.intensity
150.04601 158.95207
151.323 150.81184
152.59801 172.73586
153.87399 254.28677
155.151 228.86398
156.425 249.71759
157.701 302.38544
158.97701 397.89209
160.25101 498.06256
161.526 803.45966
162.80099 1414.295
164.075 3227.7817
165.349 6168.9072
166.62399 7718.2588
167.896 5525.6855
169.17101 2730.1138
170.44299 1235.818
171.716 701.54779
172.98801 461.52783
174.26199 419.12225
175.535 307.76663
176.806 293.07349
178.078 287.40579
179.349 226.18852
180.621 220.59723
181.892 226.05585
183.164 284.74002
184.43401 283.68591
185.705 302.65771
186.97501 266.67886
188.246 259.92615
189.515 254.63435
190.785 275.5679
192.054 269.75082
193.32401 255.55948
194.593 224.21695
195.862 256.31204
197.13 220.25511
198.39799 277.43613
199.66701 289.84216
200.93401 237.30832
202.203 306.98822
203.47 282.92859
204.737 277.10498
206.005 295.30719
207.271 322.16904
208.539 410.04431
209.80499 636.77917
211.07001 806.36188
212.33701 932.15802
213.603 956.60291
214.868 818.69434
216.134 606.61121
217.399 391.7757
218.66299 359.18719
219.929 364.61261
221.19299 349.89661
222.457 292.61633
223.72099 243.57188
224.98599 299.15247
226.24899 178.59097
227.51199 271.06476
228.776 240.16394
230.039 273.10953
231.30099 276.90137
232.564 211.51773
233.827 245.56998
235.089 259.26843
236.351 207.00192
237.612 279.98196
238.873 230.19647
240.136 285.0256
241.397 309.31097
242.657 327.24161
243.918 414.1972
245.17799 598.79791
246.438 881.63354
247.698 947.1048
248.959 844.99982
250.218 615.75012
251.47701 384.73529
252.73599 475.95538
253.995 492.60938
255.25301 628.50818
256.51199 626.23224
257.76999 855.59949
259.02802 990.40204
260.28699 1348.829
261.54501 1688.8993
262.802 1810.2145
264.05899 1876.5638
265.31601 1641.9468
266.573 1456.7635
267.82901 1114.8251
269.086 867.70966
270.34201 685.03906
271.59799 585.60175
272.853 396.20782
274.10901 410.43716
275.36401 322.71002
276.61899 250.01765
277.87399 331.55768
279.129 284.73169
280.383 256.74771
281.638 254.58801
282.89001 249.49045
284.14401 173.40689
285.39801 256.55664
286.651 213.34874
287.905 175.16518
289.15799 223.62283
290.41 202.12361
291.66299 248.64697
292.91599 178.4043
294.168 231.00241
295.418 229.05344
296.67001 222.71674
297.922 267.41388
299.173 182.95241
300.42499 177.31409
301.67599 202.51703
302.92499 216.17128
304.17599 202.83818
305.42599 196.34734
306.677 156.87939
307.927 248.65297
309.17499 144.07652
310.42499 169.51465
311.67401 166.19276
312.923 230.903
314.17099 180.85332
315.42001 239.82698
316.668 160.44124
317.91699 270.87891
319.16299 202.77417
320.41101 238.0824
321.659 195.42334
322.905 262.21259
324.15302 313.01538
325.39999 364.65942
326.647 387.73376
327.89301 496.04828
329.13901 479.59308
330.384 386.97845
331.63 320.78543
332.87601 226.62431
334.121 292.90216
335.366 259.21078
336.612 274.74176
337.85599 267.31964
339.10101 212.72009
340.34399 254.56885
341.58899 197.63026
342.83301 178.33098
344.07599 251.07083
345.32001 206.03249
346.56201 180.64088
347.806 192.86255
349.048 260.93167
350.29099 273.82159
351.53201 259.7587
352.77499 286.11005
354.01599 330.10626
355.259 288.91663
356.5 245.17368
357.742 211.05188
358.98199 296.77597
360.224 300.51337
361.46399 295.69702
362.70499 292.30243
363.944 284.95233
365.185 234.41646
366.42401 314.52542
367.66299 283.06329
368.90399 289.0148
370.142 250.21939
371.38199 267.23822
372.62 222.30074
373.858 164.59242
375.09698 157.30482
376.33499 217.85452
377.57401 286.22504
378.811 308.43976
380.048 198.88338
381.28601 305.34787
382.52301 307.64951
383.759 250.58601
384.99701 207.73679
386.233 240.93036
387.46799 224.7605
388.70401 290.21069
389.94101 326.08215
391.17599 328.79675
392.41101 325.13892
393.647 333.50278
394.88199 394.90125
396.116 415.13568
397.35101 492.99011
398.58499 449.88013
399.82001 461.59003
401.05301 482.94214
402.28699 514.51587
403.51999 549.5238
404.755 584.54462
405.987 580.21448
407.22 655.50507
408.452 692.42987
409.685 681.57501
410.91699 752.55438
412.14899 862.16156
413.38199 809.98798
414.61301 844.25598
415.84399 931.15173
417.07501 1057.873
418.306 1113.0229
419.53699 1224.7983
420.767 1235.0077
421.99799 1270.6375
423.228 1407.3007
424.45901 1615.1837
425.689 1804.0996
426.918 2037.8495
428.147 2293.4255
429.37601 2478.6274
430.60501 2983.6567
431.83401 4022.1118
433.06299 4500.1938
434.29099 5706.3076
435.51901 7255.6475
436.74701 9314.4141
437.97501 11490.206
439.202 13645.432
440.42899 15383.484
441.65601 16276.96
442.883 16460.863
444.10999 15918.59
445.33499 15058.557
446.56201 14174.337
447.78799 12910.349
449.01401 11492.985
450.23901 10274.055
451.465 8949.3438
452.69 7821.0635
453.91501 6949.8076
455.14001 6114.7773
456.36499 5355.7729
457.58801 4637.4058
458.81299 4188.251
460.03699 3555.7275
461.26099 3086.6299
462.48499 2595.5557
463.70801 2338.9131
464.92999 1911.1014
466.15302 1766.1088
467.37601 1584.9396
468.599 1344.796
469.82001 1267.489
471.043 1142.5936
472.26501 1049.3292
473.487 954.88916
474.70901 948.87256
475.92899 759.49316
477.151 766.92639
478.37201 719.98834
479.59201 688.28162
480.81201 717.59784
482.03299 711.13239
483.254 613.2912
484.47198 539.2915
485.69299 666.49695
486.91199 630.73895
488.13101 695.00348
489.35001 605.69305
490.56799 639.41101
491.78699 687.14667
493.00601 581.90546
494.22299 648.69946
495.44199 633.10577
496.66 637.54089
497.87701 650.20416
499.095 581.88501
500.311 680.00055
501.52899 632.92871
502.745 584.48956
503.96201 672.26886
505.17899 723.6698
506.39401 725.3056
507.61099 877.15247
508.82599 931.83374
510.04199 1047.1317
511.25699 1116.0574
512.47302 1297.201
513.68701 1384.7767
514.90198 1517.9709
516.11603 1503.9915
517.33099 1431.2294
518.54498 1354.0953
519.75897 1345.1827
520.97198 1199.0981
522.185 1153.0345
523.39899 1180.7887
524.612 1068.3696
525.82501 901.17267
527.03802 764.79736
528.24902 757.25409
529.46301 577.31744
530.67401 645.41711
531.88702 500.72906
533.09802 490.27216
534.30902 466.63654
535.521 480.81805
536.73199 504.22516
537.94202 429.65955
539.15399 377.7048
540.36298 430.38605
541.573 368.0831
542.784 310.79633
543.99402 315.73566
545.203 343.30176
546.41199 351.08789
547.62201 301.29016
548.83099 327.51733
550.039 341.77103
551.24701 345.64496
552.45697 321.13055
553.66498 401.84546
554.87201 281.78677
556.08002 284.7428
557.289 282.31409
558.49597 219.11662
559.703 317.13831
560.909 175.18518
562.11603 310.64761
563.32202 286.53448
564.53003 321.23267
565.73602 285.35974
566.94202 279.50677
568.14697 301.67944
569.35303 234.26529
570.55798 288.67676
571.763 422.3078
572.96802 352.35889
574.17401 418.62433
575.37799 403.11868
576.58197 478.63251
577.78601 450.16547
578.98999 456.31769
580.19397 423.68933
581.39697 561.88544
582.60101 655.29535
583.80402 620.92914
585.00702 532.58203
586.20898 620.45874
587.41199 678.14966
588.61401 651.66351
589.81598 597.19653
591.01801 697.14844
592.21997 666.91913
593.422 732.50806
594.62299 783.9209
595.82397 748.55145
597.02502 769.40051
598.22601 584.06805
599.427 591.55377
600.62598 574.86719
601.82599 545.59387
603.026 359.7392
604.22601 383.90265
605.42603 343.48367
606.625 361.88785
607.82397 393.30902
609.02301 325.14923
610.22101 320.21088
611.41998 285.48547
612.61798 318.78287
613.81702 314.89352
615.01501 268.22629
616.21301 306.97607
617.409 347.55225
618.60699 323.13785
619.80402 333.74377
621.00098 316.76776
622.19702 159.01286
623.39398 268.07239
624.591 223.14789
625.78699 253.04443
626.98199 265.16211
628.17798 292.29395
629.37402 217.24136
630.57001 218.20596
631.76398 268.19617
632.95898 252.39841
634.15399 263.41718
635.34802 233.85681
636.54199 260.91385
637.737 290.9826
638.92999 237.87624
640.12402 278.78146
641.31799 322.10471
642.51099 289.64719
643.70398 356.00574
644.896 265.58438
646.09003 272.37195
647.28302 225.37869
648.474 273.61011
649.66699 335.04935
650.85797 231.11151
652.04999 259.18677
653.24103 279.48065
654.43298 231.5878
655.62299 257.11713
656.815 257.45569
658.00598 272.01279
659.19598 261.98935
660.38702 219.17694
661.57703 255.18445
662.76599 289.61041
663.95599 311.64865
665.14502 209.30521
666.33502 232.97456
667.52399 302.26132
668.71399 317.36041
669.90198 271.28131
671.091 241.01346
672.27899 246.56488
673.466 202.53392
674.65503 324.9104
675.84198 257.90921
677.03101 324.31619
678.21802 272.74365
679.40399 220.19011
680.59198 272.04385
681.77802 266.91858
682.96399 263.20831
684.15198 338.30566
685.33698 283.82751
686.52301 223.75964
687.71002 287.30344
688.89502 322.26733
690.08002 327.44556
691.26599 314.43448
692.45001 304.04425
693.63501 289.06424
694.81897 332.70105
696.00403 400.34912
697.18799 472.01453
698.37201 383.89261
699.55499 519.7876
700.73901 457.69397
701.92297 435.21368
703.10602 403.14914
704.289 337.4986
705.47101 322.46408
706.65399 339.24066
707.83698 367.42993
709.01898 193.23598
710.20099 327.65479
711.383 333.48615
712.56403 226.93405
713.745 211.39511
714.927 232.06622
716.10901 287.75024
717.289 235.45303
718.46997 343.36493
719.65002 254.15457
720.83002 290.03418
722.01001 290.3873
723.19 196.15338
724.37 201.93195
725.54901 201.92499
726.72803 232.33081
727.90698 200.5499
729.086 161.78011
730.26501 205.0235
731.44299 206.88065
732.62201 217.74792
733.79999 170.42998
734.97803 213.32407
736.15503 270.83258
737.33301 193.75066
738.51001 152.48306
739.68799 289.62494
740.86499 240.18063
742.04102 282.55048
743.21802 281.73004
744.39502 167.92017
745.56897 184.13106
746.745 259.34772
747.92102 238.97522
749.09698 240.21379
750.27301 216.66466
751.448 280.12854
752.62299 250.40436
753.797 245.29349
754.97198 202.79068
756.146 252.1022
757.32098 254.02173
758.495 247.55432
759.66803 256.50064
760.841 218.05849
762.01501 216.02377
763.18903 208.39914
764.362 217.98895
765.534 201.19046
766.70697 188.80132
767.88 150.2213
769.05103 285.25735
770.22302 238.50145
771.39502 160.75583
772.56799 294.41739
773.73798 337.0976
774.90997 228.78188
776.08099 209.27943
777.25098 216.38916
778.422 221.90567
779.59302 197.63326
780.763 230.77263
781.93298 283.52136
783.10199 205.48242
784.27301 266.84863
785.44299 210.8266
786.61102 206.6196
787.78101 238.61664
788.94897 309.02832
790.11798 252.2467
791.28699 247.47446
792.45502 245.31339
793.62402 250.16025
794.79102 245.42041
795.95898 300.08682
797.12598 271.36514
798.29401 197.85028
799.461 212.14656
800.62799 203.25156
801.79498 297.76578
802.96198 360.8884
804.12799 236.02199
805.29498 261.76263
806.46002 234.91573
807.62701 238.67355
808.79199 276.24426
809.95599 298.82465
811.12299 274.00827
812.28699 303.40619
813.453 247.20728
814.617 251.42149
815.78101 269.04428
816.94598 205.67305
818.10999 294.31204
819.27301 251.56079
820.43799 287.21362
821.60101 222.07788
822.763 233.35359
823.92798 273.42944
825.09003 277.11996
826.25201 244.61812
827.41602 292.31976
828.578 298.43274
829.73999 187.75345
830.901 284.08368
832.06403 284.61725
833.22498 300.56299
834.38599 311.5159
835.547 282.4751
836.70898 237.64059
837.87 321.41394
839.03003 278.59778
840.19 299.38837
841.34998 280.78555
842.51202 311.38559
843.67102 288.19897
844.83099 319.81702
845.98999 339.24359
847.14899 301.27649
848.30798 260.31702
849.46802 269.16183
850.62701 362.81512
851.78497 388.87643
852.94299 367.1452
854.10101 478.61963
855.25897 442.50085
856.41699 564.18799
857.57397 537.08368
858.73102 535.78522
859.888 497.49292
861.04498 548.00653
862.20203 503.526
863.35901 414.25177
864.51501 486.78516
865.67102 421.72479
866.82703 365.46997
867.98297 398.6214
869.13898 422.37805
870.29401 456.74176
871.45001 459.50958
872.60498 406.28491
873.76001 421.26575
874.91498 434.65161
876.06897 481.04559
877.224 638.24176
878.37799 776.64636
879.53198 986.65472
880.68597 1382.469
881.84003 1437.6887
882.992 1290.5168
884.14502 890.94775
885.29797 619.58478
886.45099 542.625
887.604 505.47089
888.75702 404.32147
889.90802 375.7811
891.06 415.04242
892.21198 396.70966
893.36401 238.18021
894.51599 443.45612
895.66602 333.13947
896.81799 359.42322
897.96899 353.31372
899.12 357.00922
900.26898 302.11108
901.41998 389.61481
902.57098 308.92151
903.72101 354.23499
904.87 346.95374
906.02002 513.87482
907.16998 274.40045
908.31799 355.9325
909.46698 386.06714
910.617 309.40286
911.76398 327.54855
912.91302 357.09454
914.06201 387.84344
915.20898 371.99982
916.35797 333.15512
917.50403 302.11981
918.65198 384.88531
919.79999 392.85321
920.94702 405.62592
922.09399 327.40192
923.23999 433.383
924.38702 358.1651
925.53302 359.95212
926.67999 391.14078
927.82501 359.93542
928.97101 392.53198
930.11603 383.93195
931.26202 359.33392
932.40698 395.54022
933.55298 315.54724
934.69702 378.56021
935.84198 427.17377
936.98602 399.79242
938.13098 433.21075
939.27502 324.23364
940.41901 341.65942
941.56201 438.28833
942.70502 473.31995
943.84998 464.35028
944.992 476.58807
946.13599 439.62433
947.27802 399.86621
948.41998 438.30939
949.56403 548.95209
950.70502 473.60089
951.84698 506.25079
952.98999 529.49933
954.13098 468.78229
955.27197 466.83844
956.414 464.89441
957.55499 462.95367
958.69501 461.01605
959.83698 459.0766
960.97699 457.14185
962.117 455.20844
963.25702 553.64838
964.39801 582.91602
965.53699 536.38745
966.677 466.4588
967.81598 538.13361
968.95502 580.20874
970.09497 623.88287
971.23401 493.30267
972.37201 575.02386
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