#------------------------------------------------------------------------------ #$Date: 2019-06-11 16:00:37 +0300 (Tue, 11 Jun 2019) $ #$Revision: 1337 $ #$URL: svn://172.16.1.111/rod/cif/3/50/02/3500269.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_3500269 loop_ _publ_author_name 'Kumar, Arun' 'Zanatta, M.' 'Nazzareni, S' 'Daldosso, N.' 'Mariotto, G.' _publ_section_title ; Raman spectrum of CuFeS2 ; _journal_name_full 'Personal communication to ROD' _journal_year 2019 _chemical_compound_source 'natural'_chemical_formula_structural 'Cu Fe S2' _chemical_formula_sum 'Cu Fe S2' _chemical_name_systematic 'Copper iron sulfide' _space_group_IT_number 111 _symmetry_cell_setting tetragonal _symmetry_Int_Tables_number 111 _symmetry_space_group_name_Hall 'P -4 2' _symmetry_space_group_name_H-M 'P -4 2 m' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 2 _cell_length_a 5.27 _cell_length_b 5.27 _cell_length_c 5.194 _cell_volume 144.3 _raman_determination_method experimental _[local]_chemical_compound_color white _[local]_chemical_compound_state Solid _raman_measurement_device.location 'University of Verona' _raman_measurement_device.company 'Thermo Scientific_raman_measurement_device.model DXR2' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.50 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 633 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 1 _raman_measurement_device.power_on_sample 8 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1.5 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 60 _raman_measurement.datetime_initiated 2019-05-13 _rod_data_source.file CuFeS2.txt _rod_data_source.block /var/www/html/rod/tmp/uploads/1560257623.5013-06A4055A28351D0A.rod _rod_database.code 3500269 loop_ _raman_complementary.id _raman_complementary.method 1 EDX loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 silicon_wafer loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 1010318 COD http://www.crystallography.net/cod/1010318.html ; no XRD analysis data. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.raw_intensity _raman_spectrum.intensity 50.491089 32.407318 3.9045475 51.455318 31.83526 3.4100304 52.419559 31.20384 2.8560078 53.38379 30.23764 1.96706 54.34802 29.14461 0.95114 55.31226 28.64934 0.53283 56.27649 28.80446 0.76478 57.24072 30.27771 2.3147 58.20496 31.57769 3.69122 59.16919 32.63491 4.82483 60.13342 33.16119 5.42736 61.09766 33.47988 5.82215 62.06189 34.17064 6.58887 63.02612 34.93203 7.42608 63.99036 33.97686 6.54658 64.95459 35.99732 8.64257 65.91882 41.39694 14.11758 66.88306 53.44234 26.23823 67.84729 67.63101 40.502 68.81152 78.21883 51.16477 69.77576 85.04865 58.06942 70.73999 87.46391 60.55935 71.70422 86.67457 59.84454 72.66846 82.63246 55.87682 73.63269 72.36228 45.68089 74.59692 60.56266 33.95537 75.56116 51.16671 24.63338 76.52539 44.37712 17.91761 77.48962 40.70371 14.31787 78.45386 38.56015 12.24785 79.41809 37.79894 11.56003 80.38232 38.3017 12.13605 81.34656 40.16792 14.07538 82.31079 43.56535 17.54577 83.27502 49.3172 23.37045 84.23926 58.22181 32.34774 85.20349 65.66412 39.8626 86.16772 71.62924 45.90012 87.13196 77.41327 51.75641 88.09619 80.97099 55.38625 89.06042 81.54353 56.03077 90.02466 77.6808 52.23988 90.98889 69.24703 43.8778 91.95313 61.85835 36.56068 92.91736 55.59431 30.36805 93.88159 49.90078 24.7458 94.84583 45.70741 20.62356 95.81006 43.06867 18.05581 96.77429 40.88103 15.93903 97.73853 39.72504 14.85375 98.70276 42.66154 17.86082 99.66699 50.14328 25.41299 100.6312 72.74158 48.08158 101.5955 89.77719 65.18735 102.5597 100.9902 76.47037 103.5239 104.7696 80.31964 104.4882 102.6962 78.31597 105.4524 97.69057 73.37993 106.4166 88.97121 64.73002 107.3809 70.95435 46.78248 108.3451 56.57375 32.47105 109.3093 45.58044 21.54677 110.2736 39.60236 15.63759 111.2378 36.49767 12.60166 112.202 34.28101 10.45361 113.1663 33.22216 9.46325 114.1305 34.0647 10.37412 115.0947 34.52034 10.89796 116.059 34.59889 11.04458 117.0232 34.06677 10.58038 117.9874 33.31834 9.89974 118.9517 32.54063 9.18968 119.9159 31.61785 8.3344 120.8801 30.46039 7.24431 121.8444 29.61246 6.46362 122.8086 29.11633 6.03458 123.7728 29.00087 5.98608 124.7371 29.12564 6.17767 125.7013 29.46372 6.58243 126.6655 30.13431 7.31956 127.6298 31.11133 8.36299 128.59399 32.0849 9.40283 129.5582 33.06739 10.45145 130.52251 34.46858 11.91864 131.48669 35.51863 13.03455 132.4509 36.18372 13.76535 133.41521 36.13486 13.78208 134.37939 35.65225 13.36492 135.3436 35.28632 13.0643 136.30791 35.0742 12.91736 137.27209 35.20257 13.11076 138.2363 35.28087 13.25396 139.20061 35.31017 13.34803 140.16479 35.37889 13.48138 141.129 35.36245 13.52943 142.09331 35.16185 13.39319 143.0575 34.70099 12.99655 144.0217 33.84686 12.2065 144.98599 33.08639 11.50999 145.9502 32.44574 10.93315 146.9144 31.82181 10.3729 147.87869 31.34608 9.96072 148.8429 31.05512 9.73316 149.8071 31.05856 9.79987 150.77139 31.36906 10.17352 151.7356 31.61215 10.47961 152.6998 31.78033 10.71066 153.66409 31.76421 10.75728 154.6283 31.75103 10.80669 155.5925 31.75074 10.86887 156.55679 31.76145 10.94191 157.521 31.78673 11.02939 158.4852 31.83449 11.13921 159.44949 31.91507 11.28172 160.4137 32.07172 11.50017 161.3779 32.21349 11.7036 162.34219 32.33385 11.88549 163.3064 32.35652 11.96955 164.2706 32.37532 12.04961 165.23489 32.4712 12.20662 166.1991 32.70018 12.4966 167.1633 33.15417 13.01145 168.12759 33.51263 13.43064 169.0918 33.7482 13.7268 170.056 33.9411 13.98017 171.02029 33.98992 14.08932 171.9845 33.86494 14.02454 172.9487 33.44619 13.66585 173.91299 32.74203 13.02163 174.8772 32.111 12.4504 175.8414 31.57858 11.97765 176.80569 31.13708 11.59569 177.7699 30.79247 11.31048 178.7341 30.54259 11.11987 179.69839 30.41575 11.05218 180.6626 30.39063 11.08607 181.6268 30.42865 11.18297 182.59109 30.54698 11.36005 183.5553 30.82969 11.70138 184.5195 31.09142 12.02159 185.4838 31.32213 12.31066 186.448 31.59099 12.63774 187.4122 31.79625 12.9011 188.3765 31.87614 13.03896 189.3407 31.77226 12.99291 190.3049 31.44862 12.72697 191.2692 31.11139 12.44732 192.2334 30.78336 12.17673 193.1976 30.41323 11.86391 194.1619 30.09277 11.60064 195.1261 29.84157 11.40649 196.0903 29.64993 11.27177 197.0546 29.52478 11.20342 198.0188 29.49198 11.22729 198.983 29.56162 11.35346 199.9473 29.83863 11.68688 200.9115 30.10482 12.00935 201.8757 30.33959 12.30027 202.84 30.66896 12.68566 203.8042 30.94681 13.01941 204.7684 31.05147 13.17983 205.7327 30.92187 13.10587 206.6969 30.48931 12.72881 207.6611 30.00911 12.30399 208.6254 29.50201 11.85215 209.5896 28.78379 11.18905 210.5538 28.15481 10.61507 211.5181 27.70271 10.21784 212.4823 27.52325 10.09312 213.4465 27.58327 10.20775 214.4108 27.69773 10.3767 215.375 27.83157 10.56491 216.3392 27.88707 10.67464 217.3035 28.04524 10.88692 218.2677 28.31773 11.21339 219.2319 28.73156 11.68107 220.1962 29.26372 12.26696 221.1604 29.89308 12.94992 222.1246 30.6747 13.78502 223.0889 31.69007 14.85374 224.0531 32.65406 15.87095 225.0173 33.5009 16.77089 225.9816 34.05534 17.3783 226.9458 34.59901 17.97482 227.91 35.22182 18.65035 228.8743 36.02213 19.50326 229.8385 36.9639 20.4975 230.8027 37.85226 21.4382 231.767 38.64595 22.28412 232.7312 39.23169 22.92195 233.6954 39.82207 23.5643 234.6597 40.44448 24.23856 235.6239 41.05943 24.90523 236.5881 41.72731 25.62471 237.5524 42.50407 26.45295 238.5166 43.42392 27.42415 239.4808 44.50441 28.55587 240.4451 45.64563 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32.04647 310.83411 44.26999 31.77863 311.79831 45.02405 32.57504 312.7626 46.94028 34.5335 313.72681 50.94022 38.57555 314.69101 56.1743 43.85164 315.6553 61.49844 49.21767 316.61951 66.97643 54.73744 317.58371 73.20026 61.00293 318.548 78.06296 65.9072 319.51221 80.32123 68.20691 320.47641 78.24383 66.17084 321.4407 74.4972 62.46543 322.40491 70.2466 58.25593 323.36911 65.39986 53.45018 324.3334 60.19811 48.28933 325.29761 55.1784 43.31039 326.26181 50.5397 38.71235 327.2261 46.2224 34.43561 328.19031 42.38446 30.63811 329.15451 39.19907 27.49305 330.1188 36.79436 25.12856 331.08301 34.92237 23.29668 332.04721 33.42755 21.84186 333.01151 32.43346 20.88766 333.97571 31.8548 20.34878 334.93991 31.37207 19.90572 335.90421 30.80495 19.37817 336.86841 30.10445 18.71712 337.83261 29.36485 18.01686 338.79691 28.65257 17.34382 339.76111 27.76528 16.49565 340.72531 26.94695 15.71634 341.68961 26.39223 15.20053 342.65381 26.00178 14.84888 343.61801 25.81067 14.69646 344.58231 26.15224 15.07661 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24.06948 380.25891 35.41124 25.68859 381.22311 34.80379 25.11573 382.18741 31.88336 22.22979 383.15161 28.04007 18.42088 384.11581 24.55943 14.97453 385.08011 21.31233 11.76161 386.04431 18.50798 8.99134 387.00851 16.27663 6.79397 387.97281 14.90707 5.45828 388.93701 14.15997 4.74496 389.90121 13.65319 4.27185 390.86551 13.21025 3.86249 391.82971 12.83047 3.51618 392.79391 12.51151 3.23059 393.75821 12.25562 3.00798 394.72241 12.09695 2.88248 395.68661 12.0009 2.8195 396.65091 11.90859 2.76017 397.61511 11.80511 2.68956 398.57932 11.70124 2.61846 399.54361 11.61556 2.56546 400.50781 11.55554 2.53801 401.47198 11.51989 2.53484 402.43631 11.50557 2.5529 403.40051 11.51459 2.59419 404.36469 11.56733 2.67911 405.32901 11.64418 2.78805 406.29321 11.7068 2.88265 407.25739 11.73219 2.93992 408.22171 11.73615 2.97567 409.18591 11.74829 3.0195 410.15009 11.78378 3.08658 411.11441 11.84349 3.17779 412.07861 11.92237 3.28807 413.04279 12.02437 3.42136 414.00711 12.17902 3.60722 414.97131 12.35119 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4.97405 2.45593 1672.332 4.97372 2.4568 1673.296 4.98097 2.46526 1674.26 4.98406 2.46957 1675.224 4.98126 2.46801 1676.189 4.97611 2.46408 1677.153 4.9774 2.46662 1678.1169 4.99023 2.4807 1679.0811 4.99791 2.48963 1680.046 4.97743 2.47042 1681.01 4.91942 2.41369 1681.974 4.87056 2.3661 1682.938 4.85809 2.35493 1683.902 4.89293 2.39106 1684.8669 4.91183 2.41126 1685.8311 4.89884 2.39958 1686.795 4.85509 2.35715 1687.759 4.83951 2.3429 1688.724 4.86587 2.37059 1689.688 4.91846 2.42452 1690.652 4.95301 2.46042 1691.616 4.96875 2.47752 1692.5811 4.9673 2.47743 1693.545 4.94535 2.45685 1694.509 4.87166 2.38454 1695.473 4.81716 2.33142 1696.438 4.80804 2.32369 1697.402 4.90226 2.41931 1698.366 4.95824 2.4767 1699.33 4.96184 2.48171 1700.2939 4.89719 2.41849 1701.259 4.86544 2.38817 1702.223 4.88997 2.41413 1703.187 4.95168 2.47729 1704.151 4.98574 2.5128 1705.116 4.96624 2.49476 1706.08 4.93185 2.46184 1707.0439 4.91224 2.4437 1708.0081 4.9212 2.45414 1708.973 4.93388 2.46831 1709.937 4.947 2.48292 1710.901 4.9869 2.52432 1711.865 4.98966 2.52858 1712.829 4.92602 2.46647 1713.7939 4.78853 2.3305 1714.7581 4.69341 2.2369 1715.722 4.69088 2.23591 1716.686 4.74091 2.28749 1717.651 4.76294 2.31107 1718.615 4.68441 2.2341 1719.579 4.60304 2.15429 1720.543 4.58458 2.13741 1721.5081 4.74014 2.29455 1722.472 4.87752 2.43351 1723.436 4.93551 2.49309 1724.4 4.88466 2.44384 1725.365 4.83041 2.3912 1726.329 4.80809 2.3705 1727.293 4.81289 2.37691 1728.257 4.80847 2.37413 1729.2209 4.77408 2.34136 1730.186 4.72373 2.29266 1731.15 4.67906 2.24964 1732.114 4.6366 2.20883 1733.078 4.60784 2.18173 1734.043 4.60157 2.17713 1735.007 4.62137 2.1986 1735.9709 4.65815 2.23707 1736.9351 4.71735 2.29795 1737.9 4.80381 2.38611 1738.864 4.87914 2.46314 1739.828 4.92818 2.51389 1740.792 4.94966 2.53708 1741.756 4.94158 2.53072 1742.7209 4.8776 2.46847 1743.6851 4.78609 2.37871 1744.649 4.71618 2.31053 1745.613 4.70274 2.29884 1746.578 4.70174 2.29959 1747.542 4.66219 2.26181 1748.506 4.55835 2.15973 1749.47 4.46978 2.07294 1750.4351 4.48538 2.09033 1751.399 4.60563 2.21236 1752.363 4.71979 2.32831 1753.327 4.76397 2.37429 1754.292 4.74593 2.35805 1755.256 4.70306 2.317 1756.22 4.60575 2.22151 1757.184 4.48895 2.10654 1758.1479 4.44223 2.06164 1759.113 4.49552 2.11677 1760.077 4.5892 2.21229 1761.041 4.63449 2.25944 1762.005 4.62044 2.24724 1762.97 4.59742 2.22609 1763.934 4.62218 2.25272 1764.8979 4.70302 2.33543 1765.8621 4.75185 2.38615 1766.827 4.70636 2.34253 1767.791 4.5609 2.19897 1768.755 4.4854 2.12537 1769.719 4.51418 2.15606 1770.683 4.60993 2.25372 1771.6479 4.64762 2.29333 1772.6121 4.605 2.25263 1773.576 4.53671 2.18627 1774.54 4.50843 2.15993 1775.505 4.53524 2.18868 1776.469 4.56797 2.22335 1777.433 4.59016 2.2475 1778.397 4.6056 2.2649 1779.3621 4.59622 2.25749 1780.326 4.54566 2.2089 1781.29 4.4552 2.12041 1782.254 4.40954 2.07673 1783.219 4.44135 2.11054 1784.183 4.5058 2.17699 1785.147 4.52312 2.19631 1786.111 4.43179 2.10698 1787.075 4.34894 2.02614 1788.04 4.32702 2.00624 1789.004 4.48194 2.16318 1789.968 4.56684 2.25011 1790.932 4.54842 2.23372 1791.897 4.39171 2.07905 1792.861 4.29695 1.98634 1793.825 4.29909 1.99054 1794.7889 4.36655 2.06005 1795.754 4.42605 2.12162 1796.718 4.4688 2.16643 1797.682 4.50433 2.20404 1798.646 4.5367 2.23848 1799.61 4.57938 2.28325 1800.575 4.60636 2.31232 1801.5389 4.61575 2.32381 1802.5031 4.60706 2.31721 1803.467 4.5845 2.29677 1804.432 4.53713 2.25151 1805.396 4.47384 2.19033 1806.36 4.41908 2.1377 1807.324 4.37922 2.09996 1808.2889 4.34965 2.07252 1809.2531 4.32698 2.052 1810.217 4.28427 2.01143 1811.181 4.27313 2.00244 1812.146 4.32919 2.06065 1813.11 4.4736 2.20721 1814.074 4.57875 2.31453 1815.038 4.57576 2.31371 1816.002 4.49456 2.23468 1816.967 4.42223 2.16453 1817.931 4.38829 2.13278 1818.895 4.37707 2.12375 1819.859 4.37484 2.12371 1820.824 4.40721 2.15828 1821.788 4.42265 2.17592 1822.752 4.36543 2.12092 1823.7159 4.2142 1.9719 1824.681 4.11778 1.8777 1825.645 4.23035 1.9925 1826.609 4.48864 2.25301 1827.573 4.66554 2.43215 1828.537 4.58691 2.35576 1829.502 4.3821 2.15319 1830.4659 4.26092 2.03426 1831.4301 4.27507 2.05067 1832.394 4.3369 2.11475 1833.359 4.37595 2.15607 1834.323 4.39033 2.17271 1835.287 4.3904 2.17505 1836.251 4.38428 2.17121 1837.2159 4.37097 2.16018 1838.1801 4.34373 2.13523 1839.144 4.28425 2.07804 1840.108 4.20706 2.00315 1841.073 4.15247 1.95086 1842.037 4.11901 1.9197 1843.001 4.10966 1.91266 1843.965 4.14143 1.94674 1844.929 4.22488 2.03251 1845.894 4.29977 2.10972 1846.858 4.30557 2.11784 1847.822 4.23809 2.05269 1848.786 4.19018 2.00712 1849.751 4.21363 2.03291 1850.715 4.28614 2.10776 1851.679 4.30988 2.13386 1852.6429 4.26869 2.09501 1853.608 4.19228 2.02097 1854.572 4.12214 1.95318 1855.536 4.04743 1.88084 1856.5 4.00452 1.8403 1857.464 4.03252 1.87067 1858.429 4.16938 2.00991 1859.3929 4.25664 2.09955 1860.3571 4.26708 2.11237 1861.321 4.20503 2.05271 1862.286 4.15939 2.00947 1863.25 4.13278 1.98526 1864.214 4.12 1.97488 1865.178 4.11643 1.97372 1866.1429 4.14114 2.00084 1867.1071 4.15185 2.01396 1868.071 4.12701 1.99153 1869.035 4.0211 1.88805 1870 3.96517 1.83455 1870.964 3.99181 1.86361 1871.928 4.09413 1.96836 1872.892 4.1383 2.01498 1873.856 4.07017 1.94929 1874.821 3.96685 1.84841 1875.785 3.89926 1.78327 1876.749 3.86476 1.75122 1877.713 3.87305 1.76197 1878.678 3.94116 1.83253 1879.642 4.11118 2.00501 1880.606 4.2199 2.1162 1881.5699 4.21879 2.11757 1882.535 4.1396 2.04085 1883.499 4.07533 1.97905 1884.463 4.04472 1.95092 1885.427 4.02911 1.9378 1886.391 4.0176 1.92878 1887.356 4.01056 1.92423 1888.3199 4.00584 1.922 1889.2841 4.00225 1.92091 1890.248 4.00013 1.92129 1891.213 4.00401 1.92768 1892.177 4.03459 1.96077 1893.141 4.06946 1.99815 1894.105 4.07513 2.00632 1895.0699 4.01041 1.94412 1896.0341 3.93219 1.86843 1896.998 3.87135 1.81012 1897.962 3.83079 1.77208 1898.927 3.80191 1.74573 1899.891 3.78622 1.73257 1900.855 3.78208 1.73097 1901.819 3.77988 1.73131 1902.783 3.76594 1.71991 1903.748 3.75275 1.70927 1904.712 3.75966 1.71872 1905.676 3.80638 1.768 1906.64 3.85347 1.81764 1907.605 3.87408 1.84081 1908.569 3.86705 1.83634 1909.533 3.85345 1.82531 1910.4969 3.84446 1.81888 1911.462 3.83922 1.81621 1912.426 3.83377 1.81334 1913.39 3.82866 1.8108 1914.354 3.82083 1.80555 1915.318 3.80615 1.79345 1916.283 3.78326 1.77314 1917.2469 3.75508 1.74755 1918.2111 3.72504 1.72009 1919.175 3.69351 1.69116 1920.14 3.65829 1.65854 1921.104 3.59527 1.59811 1922.068 3.51983 1.52527 1923.032 3.50778 1.51582 1923.9969 3.60009 1.61074 1924.9611 3.72319 1.73644 1925.925 3.75781 1.77367 1926.889 3.68557 1.70404 1927.854 3.59274 1.61383 1928.818 3.53619 1.55989 1929.782 3.51877 1.5451 1930.746 3.5134 1.54234 1931.71 3.51547 1.54703 1932.675 3.52578 1.55997 1933.639 3.55184 1.58867 1934.603 3.6032 1.64266 1935.567 3.65576 1.69784 1936.532 3.68455 1.72927 1937.496 3.68664 1.734 1938.46 3.67218 1.72217 1939.424 3.62951 1.68215 1940.389 3.55347 1.60876 1941.353 3.51993 1.57786 1942.317 3.55599 1.61657 1943.281 3.62541 1.68863 1944.245 3.65232 1.7182 1945.21 3.60174 1.67027 1946.174 3.54814 1.61933 1947.1379 3.52582 1.59967 1948.1021 3.56835 1.64485 1949.067 3.57932 1.65849 1950.031 3.53143 1.61326 1950.995 3.43804 1.52254 1951.959 3.39382 1.48098 1952.924 3.46753 1.55737 1953.8879 3.55037 1.64287 1954.8521 3.57232 1.6675 1955.816 3.43336 1.53121 1956.781 3.33494 1.43547 1957.745 3.30715 1.41035 1958.709 3.35172 1.45761 1959.673 3.39189 1.50046 1960.637 3.43031 1.54156 1961.6021 3.45552 1.56946 1962.566 3.45533 1.57195 1963.53 3.38916 1.50847 1964.494 3.3325 1.4545 1965.459 3.30659 1.43129 1966.423 3.31474 1.44212 1967.387 3.33144 1.46151 1968.351 3.36585 1.49862 1969.316 3.40315 1.53862 1970.28 3.41802 1.55619 1971.244 3.39039 1.53125 1972.208 3.3483 1.49186 1973.172 3.30453 1.45079 1974.137 3.25448 1.40345 1975.101 3.21305 1.36472 1976.0649 3.19262 1.347 1977.0291 3.1868 1.34388 1977.994 3.17662 1.33641 1978.958 3.14107 1.30358 1979.922 3.1061 1.27132 1980.886 3.10101 1.26893 1981.851 3.14346 1.31409 1982.8149 3.17706 1.35041 1983.7791 3.15459 1.33066 1984.743 3.08475 1.26353 1985.708 3.02646 1.20796 1986.672 3.01832 1.20253 1987.636 3.03836 1.2253 1988.6 3.04075 1.2304 1989.564 3.00285 1.19522 1990.5291 2.97643 1.17152 1991.493 3.03507 1.23289 1992.457 3.18017 1.38071 1993.421 3.28704 1.4903 1994.386 3.25631 1.4623 1995.35 3.1198 1.32851 1996.314 3.02458 1.23601 1997.278 2.99233 1.20649 1998.243 2.99136 1.20825 1999.207 2.97703 1.19665 2000.171 2.94459 1.16693 2001.135 2.92316 1.14824 2002.099 2.94521 1.17302 2003.064 3.01151 1.24205 2004.028 3.04112 1.27439 2004.9919 3.01542 1.25142 2005.9561 2.95802 1.19675 2006.921 2.91804 1.1595 2007.885 2.89772 1.14192 2008.849 2.88922 1.13615 2009.813 2.89117 1.14083 2010.778 2.90889 1.16129 2011.7419 2.91645 1.17158 2012.7061 2.90899 1.16686 2013.67 2.89032 1.15092 2014.635 2.87694 1.14028 2015.599 2.87271 1.13878 2016.563 2.86878 1.13758 2017.527 2.85927 1.13081 2018.491 2.84337 1.11765 2019.4561 2.82212 1.09914 2020.42 2.78226 1.06201 2021.384 2.72796 1.01045 2022.348 2.71791 1.00313 2023.313 2.81304 1.101 2024.277 2.91441 1.20511 2025.241 2.95343 1.24686 2026.205 2.83862 1.13479 2027.17 2.76324 1.06214 2028.134 2.75142 1.05306 2029.098 2.80012 1.1045 2030.062 2.83843 1.14554 2031.026 2.87331 1.18316 2031.991 2.88825 1.20084 2032.955 2.86981 1.18513 2033.9189 2.77106 1.08912 2034.8831 2.69128 1.01207 2035.848 2.64493 0.96845 2036.812 2.63056 0.95682 2037.776 2.63256 0.96155 2038.74 2.6608 0.99253 2039.705 2.69801 1.03248 2040.6689 2.73151 1.0687 2041.6331 2.78513 1.12505 2042.597 2.80357 1.14623 2043.562 2.73998 1.08537 2044.526 2.60662 0.95474 2045.49 2.51542 0.86627 2046.454 2.54807 0.90166 2047.418 2.62547 0.98178 2048.3831 2.65525 1.01429 2049.3469 2.59732 0.95909 2050.311 2.5414 0.9059 2051.2749 2.54455 0.91178 2052.24 2.59823 0.96818 2053.2041 2.63141 1.00409 2054.168 2.59786 0.97327 2055.1321 2.53027 0.9084 2056.0969 2.47441 0.85527 2057.061 2.43041 0.81399 2058.0249 2.40194 0.78824 2058.989 2.39029 0.77931 2059.9541 2.39522 0.78696 2060.918 2.41845 0.81291 2061.8821 2.50723 0.90441 2062.8459 2.61043 1.01034 2063.811 2.61318 1.0158 2064.7749 2.4698 0.87513 2065.739 2.31198 0.72003 2066.7029 2.26813 0.67889 2067.667 2.33715 0.75063 2068.6321 2.42132 0.83752 2069.5959 2.50798 0.92688 2070.5601 2.58031 1.00192 2071.5239 2.58072 1.00504 2072.489 2.47764 0.90467 2073.4529 2.36207 0.7918 2074.417 2.34451 0.77695 2075.3811 2.44226 0.87741 2076.345 2.51506 0.95291 2077.3101 2.50099 0.94154 2078.2739 2.42443 0.86768 2079.238 2.37618 0.82213 2080.2019 2.36491 0.81355 2081.167 2.36927 0.82061 2082.1311 2.37074 0.82478 2083.095 2.37074 0.82747 2084.0591 2.36541 0.82484 2085.0229 2.35657 0.81868 2085.988 2.34306 0.80786 2086.9519 2.31508 0.78257 2087.916 2.25032 0.7205 2088.8799 2.19268 0.66555 2089.845 2.17816 0.65371 2090.8091 2.25543 0.73367 2091.7729 2.30253 0.78344 2092.7371 2.30062 0.78421 2093.7019 2.25819 0.74446 2094.666 2.23696 0.7259 2095.6299 2.27088 0.7625 2096.594 2.30108 0.79537 2097.5591 2.29194 0.7889 2098.5229 2.2027 0.70233 2099.4871 2.15173 0.65402 2100.4509 2.16907 0.67403 2101.416 2.23115 0.73877 2102.3799 2.27343 0.78371 2103.344 2.26581 0.77875 2104.3081 2.25551 0.77111 2105.272 2.26565 0.78391 2106.2371 2.30591 0.82682 2107.2009 2.33187 0.85543 2108.165 2.32556 0.85177 2109.1289 2.30103 0.82989 2110.094 2.28039 0.81189 2111.0581 2.25163 0.78578 2112.022 2.24265 0.77944 2112.9861 2.28291 0.82233 2113.9509 2.37681 0.91887 2114.915 2.42915 0.97386 2115.8789 2.37106 0.91839 2116.843 2.26319 0.81315 2117.8081 2.18625 0.73885 2118.772 2.16021 0.71544 2119.7361 2.15454 0.71239 2120.7 2.16705 0.72752 2121.665 2.1944 0.75749 2122.6289 2.20842 0.77413 2123.593 2.19353 0.76185 2124.5569 2.15803 0.72897 2125.521 2.11001 0.68356 2126.4861 2.04031 0.61646 2127.45 1.98362 0.56238 2128.4141 1.97014 0.55151 2129.3779 1.99355 0.57752 2130.343 2.019 0.60557 2131.3069 2.03226 0.62142 2132.271 2.04085 0.6326 2133.2351 2.05385 0.64819 2134.199 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