#------------------------------------------------------------------------------
#$Date: 2019-06-12 15:44:44 +0300 (Wed, 12 Jun 2019) $
#$Revision: 1346 $
#$URL: svn://172.16.1.111/rod/cif/3/50/02/3500278.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500278
loop_
_publ_author_name
'Kumar, A.'
'Zanatta, M.'
'Bersani, D'
'Daldosso, N.'
'Mariotto, G.'
_publ_section_title
;
 Raman spectrum of CaCO3
;
_journal_name_full               'Personal communication to ROD'
_journal_year                    2019
_chemical_compound_source
'natural'_chemical_formula_structural     Ca(CO3)'
_chemical_formula_sum            'C Ca O3'
_chemical_name_mineral           Calcite
_space_group_IT_number           167
_symmetry_space_group_name_Hall  '-R 3 2"c'
_symmetry_space_group_name_H-M   'R -3 c :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   5.0492
_cell_length_b                   5.0492
_cell_length_c                   17.3430
_cell_volume                     382.913
_raman_determination_method      experimental
_[local]_chemical_compound_color white
_[local]_chemical_compound_state Solid
_raman_measurement_device.location 'University of Verona'
_raman_measurement_device.company
'Thermo Scientific_raman_measurement_device.model DXR2'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.50
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 633
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 1
_raman_measurement_device.power_on_sample 8
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1.5
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 30
_raman_measurement.datetime_initiated 2019-04-11
_rod_data_source.file            CaCO3.txt
_rod_data_source.block
/var/www/html/rod/tmp/uploads/1560343397.0344-06A4055A28351D0A.rod
_rod_database.code               3500278
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 silicon_wafer
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 9007286 COD http://www.crystallography.net/cod/9007286.html
;
no XRD analysis data.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.raw_intensity
_raman_spectrum.intensity
33.324951 6.9905152 6.1930356
34.289181 8.9173193 7.8554254
35.253422 11.55328 10.228017
36.217651 15.53821 13.950624
37.181881 20.93762 19.088753
38.146118 27.787531 25.678415
39.110352 35.407711 33.039383
40.074581 41.387699 38.761189
41.038818 44.248161 41.364502
42.003052 47.353802 44.21402
42.967289 49.408581 46.013687
43.931519 50.85619 47.207211
44.89576 51.895119 47.993073
45.859989 52.749199 48.5951
46.824219 53.477692 49.072552
47.78846 54.038719 49.383537
48.752689 54.440781 49.536564
49.716919 54.89576 49.743515
50.68116 55.367779 49.968506
51.64539 55.82275 50.177441
52.609619 56.19717 50.30682
53.57386 56.353729 50.219322
54.53809 56.17432 49.796852
55.502319 55.748981 49.129433
56.46656 55.699692 48.839043
57.43079 56.312901 49.212132
58.395031 57.522491 50.182579
59.359261 58.55983 50.981747
60.32349 59.167629 51.352348
61.287731 59.293751 51.242229
62.251961 59.025318 50.738529
63.21619 58.664169 50.143074
64.180428 58.043941 49.28949
65.144661 57.126259 48.139416
66.108887 56.527561 47.30928
67.073128 56.44846 46.999687
68.037361 56.9697 47.291382
69.001587 57.862881 47.955967
69.965828 58.59499 48.460415
70.930061 59.135689 48.774403
71.894287 59.453602 48.866535
72.858528 59.64378 48.83186
73.822762 59.68491 48.649071
74.786987 59.567478 48.308655
75.751228 59.348412 47.867519
76.715462 59.100239 47.398205
77.679703 58.777889 46.855633
78.643929 58.34301 46.201454
79.608162 58.117321 45.757366
80.572403 58.206692 45.629261
81.536629 58.67186 45.877861
82.50087 59.230709 46.221043
83.465103 59.542309 46.317886
84.429337 59.51524 46.076954
85.39357 59.073341 45.422096
86.357803 58.825809 44.962494
87.322037 58.772202 44.697716
88.28627 58.930809 44.646038
89.250504 59.21088 44.716717
90.214737 59.58548 44.882805
91.17897 60.117409 45.2071
92.143204 60.81419 45.697136
93.107437 61.280041 45.957108
94.071671 61.465988 45.938057
95.035896 61.369289 45.637234
96.000137 61.167309 45.231991
96.964371 60.907749 44.770039
97.928596 60.544319 44.205086
98.892838 60.097961 43.558052
99.857071 59.839199 43.099487
100.8213 59.817261 42.878597
101.7855 60.025421 42.888657
102.7498 60.342289 43.008263
103.714 60.824001 43.293587
104.6782 61.554722 43.828758
105.6425 62.414619 44.493927
106.6067 62.963501 44.848938
107.5709 63.001411 44.693829
108.5352 62.37859 43.878788
109.4994 61.935699 43.244537
110.4636 61.809669 42.927982
111.4279 62.06963 42.998219
112.3921 62.545189 43.284901
113.3563 62.92226 43.473919
114.3206 63.162781 43.527191
115.2848 63.203499 43.381489
116.249 63.352661 43.345051
117.2133 63.634838 43.442421
118.1775 64.077499 43.701103
119.1417 64.581909 44.022346
120.106 65.035721 44.293774
121.0702 65.40815 44.484642
122.0344 65.672928 44.568657
122.9987 66.102173 44.817924
123.9629 66.712982 45.249565
124.9271 67.530746 45.88895
125.8914 68.394913 46.57552
126.8556 69.216293 47.220104
127.8198 69.997177 47.824978
128.7841 70.743057 48.395611
129.74831 71.452438 48.930546
130.71249 72.024223 49.328663
131.6768 72.391113 49.522648
132.64101 72.989929 49.949341
133.6053 73.934731 50.722778
134.5695 75.234352 51.851822
135.53371 76.853706 53.301373
136.498 78.695213 54.973812
137.4622 80.66095 56.771259
138.42641 82.657188 58.599979
139.3907 85.231079 61.00708
140.3549 88.224693 63.834682
141.31911 91.379631 66.824364
142.2834 95.306442 70.586647
143.2476 100.6588 75.77523
144.21181 106.6814 81.634819
145.1761 112.4824 87.273529
146.1403 123.773 98.402596
147.10451 138.6304 113.09919
148.0688 155.56509 129.87381
149.033 179.7047 153.8541
149.99719 216.397 190.38782
150.9615 269.30869 243.14162
151.9257 339.78561 313.46136
152.88989 404.11459 377.63394
153.8542 469.90601 443.26965
154.81841 545.39642 518.6051
155.78259 598.5647 571.6192
156.7469 613.85602 586.7569
157.71111 582.33539 555.0835
158.67529 512.14148 484.73746
159.6396 445.02151 417.46606
160.60381 379.54749 351.84137
161.56799 313.02328 285.16714
162.5323 256.11389 228.10844
163.49651 211.00481 182.85075
164.46069 179.49789 151.19597
165.425 157.6635 129.21436
166.38921 139.42281 110.82716
167.35339 125.2396 96.498138
168.3177 116.0466 87.159996
169.28191 108.2208 79.189766
170.24609 101.8055 72.630707
171.2104 97.075363 67.757492
172.17461 93.28846 63.828197
173.13879 89.974953 60.372982
174.1031 87.188301 57.445286
175.06731 84.943153 55.059776
176.03149 82.922211 52.899143
176.9958 81.15403 50.991936
177.96001 79.633774 49.333324
178.92419 78.266533 47.8284
179.8885 77.031357 46.456184
180.85271 75.937653 45.226112
181.81689 74.971603 44.124371
182.7812 74.099167 43.116867
183.74541 73.330879 42.214191
184.70959 72.73877 41.488346
185.6739 72.161247 40.777721
186.63811 71.608543 40.092575
187.60229 71.076561 39.428795
188.5666 70.561317 38.782394
189.53081 70.056953 38.147522
190.495 69.552856 37.513554
191.4593 69.044319 36.875774
192.42349 68.565903 36.268768
193.3877 68.105957 35.680862
194.35201 67.623573 35.07114
195.31619 67.244263 34.565132
196.2804 67.032578 34.227375
197.24471 67.02784 34.097183
198.20889 67.205467 34.149994
199.1731 67.366409 34.186737
200.13741 67.517227 34.213963
201.10159 67.701187 34.274963
202.0658 67.789879 34.241306
203.03011 67.739754 34.069439
203.99429 67.452789 33.661354
204.9585 67.075752 33.163807
205.92281 66.850433 32.818573
206.88699 66.819763 32.668606
207.8512 67.096237 32.826389
208.81551 67.315331 32.927376
209.77969 67.503967 32.998524
210.7439 67.655457 33.033119
211.70821 67.777634 33.038986
212.67239 67.856392 33.002037
213.6366 67.849007 32.879543
214.60091 67.749237 32.665237
215.56509 67.693283 32.495354
216.5293 67.689247 32.377968
217.49361 67.751129 32.327076
218.45779 67.865807 32.329571
219.422 68.056793 32.408962
220.38631 68.386078 32.627209
221.35049 68.776337 32.907021
222.3147 69.074539 33.095356
223.27901 69.24456 33.156063
224.24319 69.186409 32.989185
225.2074 69.210167 32.904785
226.17171 69.302696 32.889713
227.13589 69.471741 32.951733
228.1001 69.697456 33.070988
229.06441 69.965927 33.233543
230.02859 70.255669 33.417946
230.9928 70.568092 33.625587
231.95711 71.012451 33.965698
232.9213 71.634048 34.483627
233.8855 72.626953 35.373409
234.84979 73.533401 36.177273
235.814 74.293877 36.835724
236.7782 74.793907 37.234283
237.74249 75.187073 37.526505
238.7067 75.723137 37.962177
239.6709 76.405411 38.544605
240.63519 77.246811 39.286694
241.5994 78.158508 40.099617
242.5636 79.116501 40.959373
243.52789 80.087341 41.832504
244.4921 81.165024 42.813015
245.4563 82.390846 43.942204
246.42059 83.719147 45.174381
247.3848 85.151337 46.510986
248.349 86.889977 48.154568
249.31329 88.933144 50.103191
250.2775 91.478867 52.554897
251.2417 94.109894 55.092434
252.20599 96.821457 57.711014
253.1702 99.452873 60.249969
254.1344 102.2426 62.94775
255.09869 105.4716 66.085312
256.0629 109.1408 69.663589
257.02719 113.2653 73.697662
257.99139 117.8049 78.147369
258.9556 122.7563 83.009369
259.91989 127.7657 87.929855
260.88409 133.4536 93.529358
261.8483 139.9427 99.930573
262.81259 146.95711 106.85758
263.77679 154.6642 114.47778
264.741 163.7802 123.50737
265.70529 174.1787 133.81995
266.66949 185.15601 144.71185
267.6337 198.6517 158.12263
268.59799 214.3524 173.73888
269.56219 229.90269 189.20522
270.5264 248.96941 208.18846
271.49069 273.81461 232.95067
272.4549 302.89691 261.9505
273.4191 335.39841 294.36993
274.38339 378.77789 337.66791
275.3476 434.07339 392.88235
276.3118 506.2334 464.96176
277.27609 584.63867 543.28699
278.2403 669.50232 628.07098
279.2045 781.94012 740.42957
280.16879 899.38928 857.80005
281.133 986.08447 944.41693
282.0972 1042.114 1000.3687
283.06149 1066.937 1025.1144
284.0257 1059.375 1017.4756
284.9899 1018.653 976.67712
285.95419 913.552 871.50024
286.9184 800.52661 758.39948
287.8826 695.65002 653.44775
288.84689 596.47949 554.2027
289.8111 504.12399 461.7731
290.7753 424.73071 382.30615
291.73959 358.8519 316.35416
292.7038 314.82059 272.25009
293.668 276.54031 233.89752
294.63229 243.7083 200.99364
295.5965 218.2597 175.4736
296.5607 197.3461 154.48903
297.52499 179.22141 136.29379
298.4892 164.48241 121.4847
299.4534 153.3093 110.24193
300.41769 143.2796 100.14301
301.3819 134.40421 91.198822
302.3461 127.401 84.127243
303.31039 120.9957 77.654015
304.2746 115.1735 71.764328
305.2388 109.9287 66.452461
306.20309 105.2806 61.737698
307.1673 101.2156 57.60648
308.1315 97.858292 54.183376
309.09579 95.379509 51.63921
310.06 93.054543 49.249294
311.0242 90.86396 46.994171
311.98849 88.853752 44.919838
312.9527 86.894737 42.897129
313.9169 84.973701 40.912804
314.8812 83.015427 38.891647
315.8454 81.099129 36.912891
316.8096 79.363129 35.114838
317.7739 77.838509 33.528561
318.7381 76.581703 32.210518
319.7023 75.476898 31.044882
320.6666 74.518623 30.026176
321.6308 73.827019 29.274544
322.595 73.161118 28.549021
323.5593 72.433884 27.762556
324.5235 71.555519 26.825365
325.4877 70.573563 25.784979
326.452 69.692207 24.845585
327.4162 68.950043 24.045776
328.3804 68.476318 23.514809
329.3447 68.000931 22.982557
330.3089 67.505287 22.430447
331.2731 66.971687 21.840771
332.2374 66.424911 21.238297
333.2016 65.880859 20.638937
334.1658 65.299492 20.002649
335.1301 64.688942 19.337553
336.0943 64.17807 18.772522
337.0585 63.778919 18.319595
338.0228 63.6054 18.09267
338.987 63.409 17.84325
339.9512 63.168892 17.550495
340.9155 62.883381 17.212706
341.8797 62.57814 16.855564
342.8439 62.279881 16.505775
343.8082 61.952221 16.126953
344.7724 61.580261 15.704206
345.7366 61.307079 15.380601
346.7009 61.127621 15.151083
347.6651 61.25383 15.227601
348.6293 61.312931 15.237374
349.5936 61.299339 15.174814
350.5578 61.097511 14.924382
351.522 60.85273 14.631355
352.4863 60.679131 14.409865
353.4505 60.637489 14.320694
354.4147 60.752621 14.38865
355.379 60.812881 14.402086
356.3432 60.800758 14.343495
357.3074 60.616032 14.112653
358.2717 60.439449 13.890302
359.2359 60.286388 13.691823
360.2001 60.166481 13.526846
361.1644 60.063919 13.379557
362.1286 59.963459 13.234718
363.0928 59.858109 13.085334
364.0571 59.7467 12.930228
365.0213 59.64571 12.785887
365.9855 59.560089 12.657255
366.9498 59.50172 12.556209
367.914 59.434151 12.446304
368.8782 59.345291 12.315445
369.8425 59.204632 12.133118
370.8067 59.051289 11.938443
371.7709 58.931229 11.777384
372.7352 58.884899 11.690382
373.6994 58.93549 11.700634
374.6636 58.961651 11.686786
375.6279 58.937611 11.623058
376.5921 58.787239 11.433331
377.5563 58.63512 11.242179
378.5206 58.500881 11.069228
379.4848 58.42012 10.950081
380.44901 58.35535 10.847245
381.4133 58.265659 10.719806
382.3775 58.13187 10.54859
383.34171 57.949749 10.329358
384.306 57.781212 10.124023
385.2702 57.644371 9.9507046
386.23441 57.589821 9.8599901
387.1987 57.51181 9.7461233
388.1629 57.382702 9.5814734
389.12711 57.12558 9.2891216
390.0914 56.829521 8.9581375
391.0556 56.591351 8.6853523
392.01981 56.474751 8.5344448
392.9841 56.503738 8.5294266
393.9483 56.53492 8.5269098
394.91251 56.533119 8.4917154
395.8768 56.396629 8.3221273
396.841 56.269402 8.1621075
397.80521 56.16864 8.0288534
398.7695 56.152931 7.9809461
399.7337 56.170071 7.9661875
400.69791 56.177269 7.9417849
401.6622 56.17889 7.912096
402.6264 56.17889 7.881083
403.59061 56.155121 7.8265929
404.5549 56.089611 7.7306509
405.5191 55.84919 7.4600906
406.48331 55.64193 7.2229805
407.4476 55.501091 7.052578
408.4118 55.52784 7.0500512
409.37601 55.602711 7.095933
410.3403 55.636349 7.1008639
411.3045 55.578251 7.0143452
412.26871 55.433201 6.8411565
413.233 55.296902 6.6769972
414.1972 55.192131 6.5446491
415.16141 55.103809 6.429029
416.1257 55.060699 6.3588958
417.0899 55.064308 6.3357615
418.05411 55.245941 6.4909267
419.0184 55.440552 6.6593423
419.9826 55.545559 6.7384291
420.94681 55.417709 6.5849323
421.9111 55.094372 6.236217
422.87531 54.837879 5.9546189
423.83951 54.75695 5.8488541
424.8038 55.032009 6.0993419
425.76801 55.279999 6.3230305
426.73221 55.39204 6.4110365
427.6965 55.202881 6.1981049
428.66071 54.94566 5.9173775
429.62491 54.73378 5.6822548
430.5892 54.702961 5.6284513
431.55341 54.79623 5.6989989
432.51761 54.83519 5.7154975
433.4819 54.707809 5.5659118
434.44611 54.26189 5.0980477
435.41031 53.881031 4.6954994
436.3746 53.701241 4.4942737
437.33881 53.951881 4.7237358
438.30301 54.25116 5.0020885
439.2673 54.45517 5.1854229
440.23151 54.469742 5.1795731
441.19571 54.372231 5.0618906
442.16 54.278118 4.9478536
443.12421 54.237808 4.8878698
444.0885 54.25732 4.8879533
445.0527 54.271938 4.8833904
446.01691 54.248009 4.8405256
446.9812 54.10677 4.6805935
447.9454 53.978081 4.5334568
448.90961 53.912769 4.4499402
449.8739 54.009609 4.5288134
450.8381 54.169621 4.6711011
451.80231 54.283741 4.767736
452.7666 54.25465 4.7213974
453.7308 54.080509 4.5302467
454.69501 53.92804 4.3610039
455.6593 53.890808 4.3072333
456.6235 54.10358 4.5037017
457.58771 54.307522 4.6915727
458.552 54.376179 4.744391
459.5162 54.17477 4.5273762
460.48041 53.88224 4.21947
461.4447 53.64138 3.9634624
462.40891 53.5396 3.8467646
463.37311 53.55695 3.8494236
464.3374 53.60281 3.8808188
465.30161 53.622341 3.886112
466.26581 53.593342 3.8430998
467.2301 53.540958 3.7769253
468.19431 53.482868 3.7052686
469.15851 53.462479 3.6715343
470.1228 53.448391 3.6443217
471.08701 53.430019 3.6130464
472.05121 53.357052 3.5273943
473.0155 53.266621 3.4244957
473.97971 53.219849 3.3654742
474.94391 53.280602 3.4141946
475.9082 53.467411 3.5891857
476.87241 53.62775 3.737922
477.83661 53.66658 3.7653625
478.8009 53.43745 3.5250549
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