#------------------------------------------------------------------------------
#$Date: 2019-06-12 15:53:40 +0300 (Wed, 12 Jun 2019) $
#$Revision: 1347 $
#$URL: svn://172.16.1.111/rod/cif/3/50/02/3500279.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500279
loop_
_publ_author_name
'Kumar, A.'
'Zanatta, M.'
'Bersani, D'
'Daldosso, N.'
'Mariotto, G.'
_publ_section_title
;
 Raman spectrum of CaCO3
;
_journal_name_full               'Personal communication to ROD'
_journal_year                    2019
_chemical_compound_source        natural
_chemical_formula_sum            'C Ca O3'
_chemical_formula_weight         100.09
_chemical_name_common            aragonite
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2a'
_symmetry_space_group_name_H-M   'P m c n'
_cell_angle_alpha                90.0
_cell_angle_beta                 90.0
_cell_angle_gamma                90.0
_cell_formula_units_Z            4
_cell_length_a                   4.961830(13)
_cell_length_b                   7.96914(2)
_cell_length_c                   5.742852(15)
_cell_volume                     227.0811(10)
_raman_determination_method      experimental
_[local]_chemical_compound_color white
_[local]_chemical_compound_state Solid
_raman_measurement_device.location 'University of Verona'
_raman_measurement_device.company
'Thermo Scientific_raman_measurement_device.model DXR2'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.50
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 633
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 1
_raman_measurement_device.power_on_sample 8
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1.5
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 30
_raman_measurement.datetime_initiated 2019-04-12
_rod_data_source.file            CaCO3Argonite.txt
_rod_data_source.block
/var/www/html/rod/tmp/uploads/1560343555.3674-06A4055A28351D0A.rod
_rod_database.code               3500279
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 silicon_wafer
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 2100187 COD http://www.crystallography.net/cod/2100187.html
;
no XRD analysis data.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.raw_intensity
_raman_spectrum.intensity
40.074581 72.486595 69.231247
41.038818 76.886589 73.269112
42.003052 81.700691 77.722069
42.967289 84.675011 80.336212
43.931519 86.472748 81.774757
44.89576 87.434669 82.378464
45.859989 88.174416 82.760963
46.824219 88.908028 83.138298
47.78846 89.559639 83.434601
48.752689 90.107796 83.628418
49.716919 90.739975 83.907227
50.68116 91.369171 84.184006
51.64539 91.936592 84.399971
52.609619 92.405746 84.518631
53.57386 92.606667 84.37001
54.53809 92.375008 83.789764
55.502319 91.822449 82.889572
56.46656 91.763809 82.484245
57.43079 92.601295 82.975998
58.395031 94.244156 84.274063
59.359261 95.574448 85.260513
60.32349 96.106812 85.449966
61.287731 95.67347 84.67466
62.251961 94.561417 83.221581
63.21619 93.812416 82.132492
64.180428 93.624947 81.605858
65.144661 94.013649 81.656334
66.108887 94.432076 81.737465
67.073128 94.750175 81.7192
68.037361 94.924538 81.558113
69.001587 95.037621 81.336678
69.965828 95.312599 81.278061
70.930061 95.835121 81.467903
71.894287 96.655327 81.956352
72.858528 97.306946 82.277122
73.822762 97.742966 82.383209
74.786987 97.955566 82.2668
75.751228 98.007507 81.990623
76.715462 97.972786 81.6287
77.679703 97.789536 81.119156
78.643929 97.398071 80.402306
79.608162 97.259499 79.93924
80.572403 97.502731 79.858879
81.536629 98.204552 80.238014
82.50087 99.021881 80.733543
83.465103 99.544235 80.934998
84.429337 99.670258 80.741013
85.39357 99.309097 80.060738
86.357803 99.132515 79.565926
87.322037 99.143951 79.260017
88.28627 99.368881 79.168495
89.250504 99.690659 79.174698
90.214737 100.03526 79.204597
91.17897 100.41556 79.271088
92.143204 100.82626 79.368851
93.107437 101.23466 79.465187
94.071671 101.60476 79.524101
95.035896 101.94046 79.549484
96.000137 102.31856 79.618134
96.964371 102.78956 79.780548
97.928596 103.36835 80.051636
98.892838 104.03036 80.406784
99.857071 104.69026 80.760696
100.8213 105.18316 80.948471
101.7855 105.48036 80.941406
102.7498 106.04706 81.204666
103.714 107.10026 81.955322
104.6782 108.74486 83.298225
105.6425 110.83976 85.092247
106.6067 112.87466 86.827148
107.5709 114.80116 88.454491
108.5352 116.58696 89.941963
109.4994 118.29656 91.354103
110.4636 120.11126 92.872177
111.4279 122.19256 94.657669
112.3921 124.13456 96.304726
113.3563 125.18486 97.060921
114.3206 125.22886 96.811615
115.2848 124.00816 95.29847
116.249 122.47496 93.473663
117.2133 120.40956 91.117455
118.1775 117.65736 88.075294
119.1417 114.85836 84.987167
120.106 112.69436 82.534828
121.0702 111.27566 80.828651
122.0344 110.67906 79.945389
122.9987 110.25906 79.239502
123.9629 109.94306 78.638481
124.9271 109.69296 78.104156
125.8914 109.63146 77.759232
126.8556 109.82976 77.674934
127.8198 110.29866 77.862053
128.7841 111.04396 78.326347
129.74831 112.01266 79.01487
130.71249 113.23196 79.954811
131.6768 114.66156 81.105812
132.64101 116.38276 82.549248
133.6053 118.25886 84.148354
134.5695 120.08746 85.700783
135.53371 122.10446 87.442406
136.498 125.22436 90.287697
137.4622 129.32535 94.114899
138.42641 134.30615 98.822701
139.3907 140.95105 105.19536
140.3549 149.40504 113.37792
141.31911 159.67955 123.38178
142.2834 171.68745 135.1198
143.2476 184.65755 147.82082
144.21181 196.83806 159.73303
145.1761 205.98586 168.61328
146.1403 225.37215 187.73282
147.10451 255.87398 217.96869
148.0688 299.40015 261.22961
149.033 349.38116 310.94623
149.99719 404.08484 365.38623
150.9615 470.27084 431.30933
151.9257 550.37347 511.14981
152.88989 600.13318 560.64819
153.8542 612.87384 573.12817
154.81841 584.72748 544.72198
155.78259 543.31506 503.05051
156.7469 495.07697 454.55405
157.71111 436.21695 395.43646
158.67529 370.14127 329.10397
159.6396 314.63895 273.34555
160.60381 272.15106 230.60237
161.56799 246.09517 204.29192
162.5323 223.58687 181.52977
163.49651 204.03157 161.72141
164.46069 187.57677 145.01428
165.425 173.81947 131.00537
166.38921 162.18767 119.12273
167.35339 152.74585 109.4308
168.3177 145.67445 102.11002
169.28191 140.56535 96.752281
170.24609 137.04945 92.988487
171.2104 134.89355 90.585396
172.17461 134.84215 90.28756
173.13879 137.33185 92.531555
174.1031 142.22755 97.182259
175.06731 149.46095 104.17141
176.03149 160.06227 114.5292
176.9958 177.05125 131.27536
177.96001 204.20006 158.18207
178.92419 226.82417 180.56483
179.8885 240.85905 194.35904
180.85271 244.98116 198.24121
181.81689 240.60155 193.62239
182.7812 232.54155 185.32387
183.74541 219.40706 171.95158
184.70959 196.35185 148.6593
185.6739 177.91496 129.98601
186.63811 164.74977 116.58515
187.60229 158.04655 109.64698
188.5666 155.14537 106.51151
189.53081 153.15335 104.28594
190.495 152.17497 103.07471
191.4593 152.37805 103.04561
192.42349 152.92834 103.36445
193.3877 153.32394 103.52929
194.35201 152.52956 102.50481
195.31619 153.43256 103.17844
196.2804 156.52046 106.03765
197.24471 160.02797 109.31714
198.20889 164.73155 113.79342
199.1731 178.43297 127.26822
200.13741 201.44624 150.05553
201.10159 232.90416 181.28819
202.0658 275.01465 223.17412
203.03011 333.85294 281.78848
203.99429 424.87515 372.58749
204.9585 522.79633 470.28613
205.92281 587.82874 535.09668
206.88699 616.07074 563.11749
207.8512 599.01874 545.84497
208.81551 566.78674 513.39313
209.77969 516.91046 463.29767
210.7439 436.42645 382.59515
211.70821 355.42645 301.37729
212.67239 289.60684 235.34052
213.6366 241.80125 187.31842
214.60091 211.72685 157.02815
215.56509 186.70506 131.79118
216.5293 167.82805 112.69965
217.49361 157.23085 101.88856
218.45779 148.56876 93.013252
219.422 141.33615 85.568092
220.38631 135.84055 79.860558
221.35049 131.65547 75.464241
222.3147 128.03975 71.637917
223.27901 125.01456 68.402748
224.24319 122.70506 65.883942
225.2074 120.73116 63.701385
226.17171 119.09326 61.855453
227.13589 117.95076 60.505585
228.1001 116.95626 59.304356
229.06441 115.90176 58.043739
230.02859 114.68136 56.617893
230.9928 113.29766 55.029381
231.95711 112.24666 53.774178
232.9213 111.57036 52.894337
233.8855 111.32716 52.448223
234.84979 111.37366 52.292423
235.814 111.66386 52.380974
236.7782 111.99656 52.512657
237.74249 112.63786 52.953537
238.7067 114.01606 54.131973
239.6709 116.13666 56.053429
240.63519 119.01295 58.731186
241.5994 122.60046 62.120785
242.5636 126.96636 66.289413
243.52789 132.92725 72.053619
244.4921 138.86024 77.790573
245.4563 144.15425 82.889145
246.42059 149.07495 87.615013
247.3848 153.54135 91.887215
248.349 156.61086 94.76313
249.31329 158.11717 96.076447
250.2775 157.10835 94.875259
251.2417 155.61827 93.193413
252.20599 153.59145 90.975418
253.1702 150.15186 87.345276
254.1344 146.56296 83.566429
255.09869 144.30026 81.114365
256.0629 143.70966 80.335014
257.02719 145.41635 81.853546
257.99139 146.86305 83.112694
258.9556 148.15817 84.220863
259.91989 150.30695 86.183258
260.88409 151.40245 87.093002
261.8483 150.85597 86.361351
262.81259 147.74525 83.066032
263.77679 142.65475 77.791542
264.741 138.06364 73.017029
265.70529 133.92046 68.691002
266.66949 129.97336 64.561676
267.6337 126.94146 61.348133
268.59799 124.83076 59.056351
269.56219 124.37746 58.422565
270.5264 124.47416 58.339367
271.49069 124.39226 58.078125
272.4549 124.17376 57.680882
273.4191 123.83266 57.16161
274.38339 123.16456 56.315903
275.3476 122.10266 55.076984
276.3118 120.01276 52.810631
277.27609 118.14846 50.770443
278.2403 116.62016 49.06683
279.2045 115.62366 47.895592
280.16879 114.95006 47.047802
281.133 114.27436 46.198498
282.0972 113.55406 45.305161
283.06149 112.67916 44.257763
284.0257 111.97856 43.385246
284.9899 111.45286 42.688187
285.95419 111.35266 42.417175
286.9184 111.25546 42.149731
287.8826 111.04786 41.772453
288.84689 110.67036 41.225807
289.8111 110.14706 40.533932
290.7753 109.62686 39.845718
291.73959 109.10016 39.151531
292.7038 108.59406 38.478508
293.668 108.07316 37.791241
294.63229 107.55756 37.109802
295.5965 106.84166 36.22863
296.5607 106.22266 35.444897
297.52499 105.87326 34.931297
298.4892 105.95556 34.849953
299.4534 106.51546 35.24675
300.41769 106.89056 35.45927
301.3819 107.06425 35.470947
302.3461 106.76686 35.01207
303.31039 106.49335 34.577599
304.2746 106.27036 34.194183
305.2388 106.10096 33.86491
306.20309 106.00496 33.609547
307.1673 106.00086 33.446632
308.1315 106.11506 33.402546
309.09579 106.37466 33.504372
310.06 106.62636 33.598846
311.0242 106.83976 33.655544
311.98849 107.06036 33.719948
312.9527 107.18576 33.689701
313.9169 107.19886 33.547672
314.8812 106.97046 33.164646
315.8454 106.62736 32.667458
316.8096 106.42166 32.308193
317.7739 106.43886 32.172325
318.7381 106.91016 32.491089
319.7023 107.24326 32.672173
320.6666 107.42016 32.697556
321.6308 107.18886 32.315266
322.595 106.90926 31.885185
323.5593 106.67546 31.50141
324.5235 106.51746 31.193947
325.4877 106.42656 30.954102
326.452 106.34586 30.724941
327.4162 106.30086 30.532007
328.3804 106.34006 30.423777
329.3447 106.37256 30.309336
330.3089 106.38356 30.173912
331.2731 106.33026 29.974691
332.2374 106.27396 29.772949
333.2016 106.24856 29.602627
334.1658 106.31406 29.523699
335.1301 106.46396 29.529657
336.0943 106.54296 29.465225
337.0585 106.52225 29.30158
338.0228 106.11906 28.755922
338.987 105.84056 28.335472
339.9512 105.69226 28.045708
340.9155 105.91656 28.129017
341.8797 106.23016 28.302132
342.8439 106.46176 28.39374
343.8082 106.54686 28.339314
344.7724 106.46316 28.116585
345.7366 106.40476 27.919647
346.7009 106.35306 27.72987
347.6651 106.32016 27.559395
348.6293 106.29776 27.399899
349.5936 106.31516 27.280664
350.5578 106.45996 27.289331
351.522 106.63046 27.324163
352.4863 106.73236 27.290871
353.4505 106.68916 27.112955
354.4147 106.47316 26.762722
355.379 106.30516 26.460947
356.3432 106.22086 26.243351
357.3074 106.35046 26.240129
358.2717 106.48356 26.240868
359.2359 106.59846 26.223883
360.2001 106.71146 26.205463
361.1644 106.78876 26.151802
362.1286 106.79676 26.02932
363.0928 106.63576 25.738297
364.0571 106.24396 25.216925
365.0213 106.01736 24.861227
365.9855 106.01796 24.733194
366.9498 106.65576 25.242807
367.914 107.19656 25.655884
368.8782 107.53456 25.866629
369.8425 107.56266 25.767912
370.8067 107.39636 25.475264
371.7709 107.16606 25.119068
372.7352 106.83666 24.664215
373.6994 106.36236 24.064922
374.6636 106.01906 23.597082
375.6279 105.84436 23.298285
376.5921 105.98656 23.316841
377.5563 106.18306 23.39015
378.5206 106.39986 23.48419
379.4848 106.68866 23.650694
380.44901 106.98446 23.824636
381.4133 107.21596 23.934713
382.3775 107.37486 23.972641
383.34171 107.47056 23.947815
384.306 107.51096 23.868114
385.2702 107.50776 23.74527
386.23441 107.21306 23.331358
387.1987 107.00926 23.008778
388.1629 106.93456 22.815735
389.12711 107.24956 23.012835
390.0914 107.67556 23.32136
391.0556 107.93706 23.465822
392.01981 107.85096 23.263123
392.9841 107.34816 22.64414
393.9483 106.99146 22.171694
394.91251 106.88526 21.95019
395.8768 107.32825 22.278288
396.841 107.78156 22.61713
397.80521 108.15396 22.875505
398.7695 108.46046 23.068384
399.7337 108.69666 23.191401
400.69791 108.86786 23.249844
401.6622 108.97375 23.243391
402.6264 109.01546 23.173178
403.59061 109.03976 23.085979
404.5549 109.03896 22.974091
405.5191 108.91125 22.735729
406.48331 108.78316 22.497389
407.4476 108.66996 22.274353
408.4118 108.57296 22.06794
409.37601 108.49716 21.883144
410.3403 108.45276 21.730145
411.3045 108.46756 21.636772
412.26871 108.54556 21.607004
413.233 108.63686 21.590942
414.1972 108.72706 21.5742
415.16141 108.81556 21.556166
416.1257 108.89386 21.528326
417.0899 108.95986 21.488605
418.05411 109.06816 21.491587
419.0184 109.16316 21.481665
419.9826 109.21396 21.42795
420.94681 109.16446 21.274342
421.9111 109.02096 21.027122
422.87531 108.87436 20.777218
423.83951 108.73546 20.535408
424.8038 108.59236 20.289793
425.76801 108.48215 20.077473
426.73221 108.43496 19.928562
427.6965 108.49756 19.889832
428.66071 108.58576 19.87711
429.62491 108.64316 19.833973
430.5892 108.66306 19.753721
431.55341 108.66916 19.660076
432.51761 108.69966 19.591221
433.4819 108.78036 19.572939
434.44611 108.89156 19.58556
435.41031 109.04096 19.636774
436.3746 109.18236 19.680357
437.33881 109.46796 19.868538
438.30301 109.63716 19.94071
439.2673 109.60536 19.812252
440.23151 109.06956 19.180182
441.19571 108.32296 18.337702
442.16 107.81866 17.737888
443.12421 107.87826 17.702368
444.0885 108.64296 18.372318
445.0527 109.40246 19.037455
446.01691 109.85476 19.395769
446.9812 109.61156 19.05895
447.9454 109.27806 18.632221
448.90961 109.05966 18.320965
449.8739 109.11886 18.287668
450.8381 109.31016 18.386858
451.80231 109.47006 18.455023
452.7666 109.48436 18.377945
453.7308 109.35286 18.155449
454.69501 109.23806 17.950024
455.6593 109.21186 17.833557
456.6235 109.21106 17.742865
457.58771 109.32236 17.764639
458.552 109.54336 17.896475
459.5162 110.24686 18.511181
460.48041 110.98476 19.160652
461.4447 111.44586 19.533686
462.40891 111.27676 19.276878
463.37311 110.61156 18.524338
464.3374 109.97986 17.805651
465.30161 109.66626 17.405432
466.26581 109.81386 17.46677
467.2301 110.01956 17.586561
468.19431 110.05366 17.535112
469.15851 109.83016 17.226427
470.1228 109.54396 16.855383
471.08701 109.31276 16.539703
472.05121 109.10276 16.245579
473.0155 108.95506 16.014093
473.97971 108.93386 15.909478
474.94391 109.13546 16.028008
475.9082 109.59206 16.401876
476.87241 110.02166 16.749111
477.83661 110.25276 16.898191
478.8009 110.08666 16.650412
479.76511 109.82696 16.309381
480.72931 109.64366 16.045105
481.6936 109.68626 16.007057
482.65781 109.82516 16.065666
483.62201 109.92896 16.089518
484.5863 109.89736 15.978312
485.55051 109.74335 15.745044
486.51471 109.57846 15.501228
487.479 109.44686 15.291039
488.44321 109.31246 15.078399
489.40741 109.22616 14.914192
490.3717 109.24226 14.852717
491.33591 109.50196 15.035192
492.30011 109.82556 15.281901
493.2644 110.07836 15.458137
494.22861 110.18966 15.493212
495.19281 110.19026 15.417925
496.1571 110.14426 15.296356
497.12131 110.07326 15.150132
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1733.269 76.210732 1.4771626
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1735.197 76.171249 1.5272295
1736.161 75.865089 1.2658403
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1738.09 75.776642 1.2669719
1739.054 75.884491 1.4195839
1740.0179 75.912079 1.4919319
1740.983 75.865509 1.4901704
1741.947 75.797989 1.4674047
1742.911 75.728668 1.4428355
1743.875 75.649635 1.408551
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1800.765 72.953705 1.3459469
1801.729 72.877785 1.3144841
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1804.6219 73.479828 2.0499039
1805.5861 73.425362 2.0398736
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1807.515 73.476997 2.1803942
1808.479 73.650246 2.3980517
1809.443 73.814346 2.6065547
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1811.3719 74.101212 2.9822481
1812.3361 74.21125 3.1366732
1813.3 74.292862 3.2626584
1814.264 74.319412 3.3335748
1815.229 74.315712 3.3742781
1816.193 74.281708 3.3846252
1817.157 74.096985 3.244246
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1819.0861 72.746025 1.9820012
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1821.014 71.898979 1.2235889
1821.978 71.856575 1.2254899
1822.943 71.827049 1.2403063
1823.907 71.825691 1.2832375
1824.871 71.79026 1.2920879
1825.835 71.607552 1.1536524
1826.799 71.254036 0.84440202
1827.764 70.964867 0.59954011
1828.728 70.945976 0.62489849
1829.692 71.21463 0.9377929
1830.656 71.338242 1.1056365
1831.621 71.229378 1.0410413
1832.585 70.960899 0.81677818
1833.549 70.757561 0.65764636
1834.5129 70.602676 0.54696029
1835.478 70.513145 0.50166935
1836.442 70.54052 0.57322454
1837.406 70.739761 0.81663841
1838.37 70.891258 1.0122987
1839.334 70.886322 1.0515171
1840.299 70.667915 0.87730086
1841.2629 70.51918 0.77270252
1842.2271 70.48996 0.78761524
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1844.156 70.542946 0.92887425
1845.12 70.408157 0.83818609
1846.084 70.215218 0.68933743
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1850.905 69.762192 0.45667678
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1852.834 70.034927 0.81751633
1853.798 70.152168 0.9787724
1854.762 70.123901 0.99451095
1855.726 69.879662 0.79426682
1856.691 69.575996 0.53463757
1857.655 69.328102 0.33071914
1858.619 69.104012 0.15059449
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1861.512 68.74308 -0.078454942
1862.476 68.760056 -0.017554021
1863.4399 69.077896 0.34420183
1864.405 69.545029 0.85528946
1865.369 69.76899 1.123145
1866.333 69.422478 0.82051736
1867.297 68.985779 0.4276922
1868.261 68.762787 0.24856354
1869.226 69.024826 0.55449986
1870.1899 69.200851 0.77436733
1871.1541 69.106575 0.72392786
1872.118 68.72364 0.38481393
1873.083 68.389481 0.094508357
1874.047 68.216667 -0.034506023
1875.011 68.15757 -0.049815163
1875.975 68.132111 -0.031497251
1876.9399 68.110771 -0.0090261381
1877.9041 68.122871 0.046834756
1878.868 68.198586 0.16629289
1879.832 68.393211 0.40465161
1880.797 68.523926 0.57913196
1881.761 68.475792 0.57470846
1882.725 68.276009 0.41862416
1883.689 68.094261 0.28056437
1884.653 68.011871 0.24185076
1885.618 67.983177 0.2568711
1886.582 67.938225 0.25557187
1887.546 67.857201 0.2181893
1888.51 67.756386 0.16100441
1889.475 67.612892 0.061173175
1890.439 67.405746 -0.10236605
1891.403 67.300018 -0.16449955
1892.3669 67.554779 0.13384399
1893.332 68.07177 0.69445521
1894.296 68.404831 1.0710753
1895.26 68.133865 0.8436566
1896.224 67.569702 0.32302818
1897.188 67.309441 0.1062893
1898.153 67.478806 0.3192088
1899.1169 67.762596 0.64649761
1900.0811 67.878792 0.80618477
1901.045 67.834969 0.80583513
1902.01 67.719086 0.73345745
1902.974 67.50589 0.56371039
1903.938 67.210732 0.31198829
1904.902 67.026398 0.17107818
1905.8669 67.025902 0.21403734
1906.8311 67.128731 0.36027023
1907.795 67.179558 0.45448297
1908.759 67.163025 0.48132303
1909.724 67.130775 0.49247763
1910.688 67.174362 0.57941163
1911.652 67.330132 0.77851528
1912.616 67.375046 0.8667509
1913.58 67.110687 0.64570069
1914.545 66.576927 0.15528524
1915.509 66.31633 -0.062029868
1916.473 66.425995 0.090903983
1917.437 66.723412 0.43157637
1918.402 66.88649 0.63794088
1919.366 66.90081 0.69549036
1920.33 66.834755 0.67265075
1921.2939 66.690735 0.5718329
1922.259 66.371811 0.2961469
1923.223 66.238815 0.20632648
1924.187 66.387032 0.39770433
1925.151 66.760468 0.81428826
1926.115 66.941185 1.0381399
1927.08 66.856857 0.99697644
1928.0439 66.650917 0.83414286
1929.0081 66.445847 0.6721707
1929.972 66.110405 0.37980801
1930.937 65.921661 0.23417301
1931.901 65.946976 0.30253831
1932.865 66.2864 0.68499935
1933.829 66.450218 0.89184046
1934.7939 66.326225 0.81089973
1935.7581 66.062172 0.58984625
1936.722 65.911545 0.48219928
1937.686 66.014328 0.62794828
1938.651 66.112915 0.7695303
1939.615 66.091942 0.79149413
1940.579 65.888145 0.63062036
1941.543 65.726845 0.51222777
1942.507 65.646835 0.47511181
1943.472 65.633636 0.50484067
1944.436 65.635948 0.55001658
1945.4 65.649429 0.60634726
1946.364 65.672745 0.67249739
1947.329 65.719765 0.76238066
1948.293 65.872551 0.95797193
1949.257 65.941696 1.0699072
1950.2209 65.82946 1.0004463
1951.186 65.540367 0.75416219
1952.15 65.279427 0.53596669
1953.114 65.109291 0.40856114
1954.078 65.015167 0.35715204
1955.042 64.977692 0.36237603
1956.007 65.102295 0.52970684
1956.9709 65.201859 0.67193937
1957.9351 65.165588 0.67832822
1958.899 64.958466 0.5138436
1959.864 64.76738 0.36542368
1960.828 64.661522 0.30217302
1961.792 64.631531 0.3147735
1962.756 64.66037 0.38618863
1963.7209 64.863785 0.63220698
1964.6851 65.076347 0.88731956
1965.649 65.150688 1.0041893
1966.613 65.0504 0.94641393
1967.578 64.897659 0.83621371
1968.542 64.708 0.68903589
1969.506 64.505432 0.52893317
1970.47 64.405769 0.47171974
1971.434 64.643311 0.7516942
1972.399 64.987122 1.1379708
1973.363 65.001732 1.1949821
1974.327 64.501175 0.73680997
1975.291 63.981415 0.2594184
1976.256 63.999947 0.32034537
1977.22 64.557182 0.91991705
1978.184 65.016472 1.4215261
1979.1479 64.976158 1.4235156
1980.113 64.537682 1.0273738
1981.077 64.203476 0.73543817
1982.041 63.9729 0.5471161
1983.005 63.84864 0.46509299
1983.969 63.912201 0.57087368
1984.934 64.222748 0.92366672
1985.8979 64.434532 1.1776377
1986.8621 64.238075 1.0233561
1987.826 63.604546 0.43197933
1988.791 63.199738 0.069350012
1989.755 63.127609 0.039340794
1990.719 63.278099 0.23193267
1991.683 63.420708 0.4166263
1992.6479 63.592812 0.63084072
1993.6121 63.683159 0.76324403
1994.576 63.568359 0.69047809
1995.54 63.135315 0.29944992
1996.505 62.828667 0.034843206
1997.469 62.703415 -0.04842693
1998.433 62.738358 0.028479945
1999.397 62.801125 0.13319379
2000.361 62.936684 0.31068221
2001.326 63.060059 0.4760167
2002.29 63.09404 0.55189222
2003.254 62.932114 0.43184257
2004.218 62.83271 0.3742981
2005.183 62.859764 0.44323552
2006.147 63.015335 0.64062995
2007.111 63.049408 0.71650845
2008.075 62.827499 0.53638768
2009.04 62.541473 0.29217914
2010.004 62.355064 0.14752205
2010.968 62.380096 0.21428801
2011.932 62.424797 0.30070454
2012.896 62.504768 0.42237365
2013.861 62.620407 0.57973427
2014.825 62.64241 0.64339894
2015.7889 62.397858 0.44048959
2016.7531 62.100677 0.1849397
2017.718 61.973099 0.09900979
2018.682 62.289665 0.45716459
2019.646 62.554344 0.76341343
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3990.54 14.625237 3.1913517
3991.5039 14.382187 2.9568276
3992.468 14.602326 3.1853726
3993.4319 14.828597 3.4199221
3994.396 14.597237 3.1967182
3995.3611 14.361187 2.9687073
3996.325 14.605237 3.2206602
3997.2891 14.873426 3.4966276
3998.2529 14.743067 3.3739166
3999.218 14.459806 3.0981865
4000.1819 14.117106 2.7628784
