#------------------------------------------------------------------------------ #$Date: 2019-06-12 16:20:40 +0300 (Wed, 12 Jun 2019) $ #$Revision: 1348 $ #$URL: svn://172.16.1.111/rod/cif/3/50/02/3500280.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_3500280 loop_ _publ_author_name 'Kumar, A.' 'Zanatta, M.' 'Bersani, D' 'Daldosso, N.' 'Mariotto, G.' _publ_section_title ; Raman spectrum of Ca Mg O6 Si2 ; _journal_name_full 'Personal communication to ROD' _journal_year 2019 _chemical_compound_source 'natural'_chemical_formula_structural 'Ca Mg (Si O3)2' _chemical_formula_sum 'Ca Mg O6 Si2' _chemical_name_mineral Diopside _chemical_name_systematic 'Calcium magnesium catena-silicate' _space_group_IT_number 15 _symmetry_cell_setting monoclinic _symmetry_Int_Tables_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90 _cell_angle_beta 74.16 _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 9.71 _cell_length_b 8.89 _cell_length_c 5.24 _cell_volume 435.2 _raman_determination_method experimental _[local]_chemical_compound_color white _[local]_chemical_compound_state Solid _raman_measurement_device.location 'University of Verona' _raman_measurement_device.company 'Thermo Scientific_raman_measurement_device.model DXR2' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.50 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 633 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 1 _raman_measurement_device.power_on_sample 8 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1.5 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 60 _raman_measurement.datetime_initiated 2019-04-15 _rod_data_source.file CaMgO6Si2.txt _rod_data_source.block /var/www/html/rod/tmp/uploads/1560345541.7095-06A4055A28351D0A.rod _rod_database.code 3500280 loop_ _raman_complementary.id _raman_complementary.method 1 EDX loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 silicon_wafer loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 1011057 COD http://www.crystallography.net/cod/1011057.html ; no XRD analysis data. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.raw_intensity _raman_spectrum.intensity 50.68116 1630.712 49.314484 51.64539 1641.897 57.944405 52.609619 1652.662 66.152321 53.57386 1662.0031 72.933891 54.53809 1668.683 77.052414 55.502319 1672.8149 78.62059 56.46656 1677.988 81.227837 57.43079 1683.51 84.181877 58.395031 1688.5699 86.671661 59.359261 1692.89 88.419357 60.32349 1695.782 88.736763 61.287731 1696.799 87.177155 62.251961 1696.463 84.262497 63.21619 1696.667 81.885544 64.180428 1697.854 80.489426 65.144661 1700.033 80.083237 66.108887 1702.811 80.274124 67.073128 1706.042 80.915581 68.037361 1709.604 81.886139 69.001587 1713.262 82.950317 69.965828 1716.674 83.766678 70.930061 1719.496 83.990707 71.894287 1721.356 83.250847 72.858528 1722.96 82.252617 73.822762 1724.322 81.010559 74.786987 1725.561 79.643417 75.751228 1726.791 78.264969 76.715462 1728.105 76.968567 77.679703 1729.701 75.952179 78.643929 1731.645 75.281586 79.608162 1734.009 75.028915 80.572403 1736.963 75.364319 81.536629 1740.761 76.541595 82.50087 1744.998 78.155716 83.465103 1749.176 79.709007 84.429337 1753.228 81.134117 85.39357 1756.814 82.091064 86.357803 1760.326 82.972305 87.322037 1763.535 83.548332 88.28627 1766.595 83.973312 89.250504 1769.38 84.121384 90.214737 1771.78 83.882431 91.17897 1773.738 83.199432 92.143204 1775.0959 81.914307 93.107437 1777.197 81.370544 94.071671 1780.118 81.644562 95.035896 1784.202 83.079575 96.000137 1788.4091 84.635757 96.964371 1792.332 85.905899 97.928596 1795.91 86.829208 98.892838 1798.926 87.188354 99.857071 1801.714 87.317596 100.8213 1803.5601 86.503036 101.7855 1804.774 85.054565 102.7498 1806.0959 83.711723 103.714 1808.079 83.028503 104.6782 1810.97 83.251144 105.6425 1814.736 84.346741 106.6067 1819.162 86.100716 107.5709 1823.963 88.227821 108.5352 1828.876 90.464668 109.4994 1833.104 92.014908 110.4636 1836.574 92.80545 111.4279 1839.4139 92.963654 112.3921 1841.793 92.659348 113.3563 1843.843 92.024292 114.3206 1845.624 91.117935 115.2848 1846.8979 89.703064 116.249 1848.358 88.47242 117.2133 1849.801 87.222672 118.1775 1851.257 85.984276 119.1417 1852.907 84.938156 120.106 1854.9969 84.329941 121.0702 1857.745 84.37822 122.0344 1861.248 85.179779 122.9987 1865.327 86.555229 123.9629 1869.91 88.433334 124.9271 1874.953 90.769318 125.8914 1879.726 92.83345 126.8556 1883.594 93.99118 127.8198 1886.229 93.914139 128.7841 1887.847 92.818054 129.74831 1890.703 92.958656 130.71249 1894.468 94.00647 131.6768 1898.525 95.344269 132.64101 1906.0031 100.10158 133.6053 1917.119 108.49493 134.5695 1931.0909 119.74292 135.53371 1948.318 134.24434 136.498 1972.0601 155.25876 137.4622 2008.2889 188.75853 138.42641 2065.811 243.54994 139.3907 2106.6851 281.6915 140.3549 2125.967 298.23953 141.31911 2119.4861 289.02307 142.2834 2097.355 264.15439 143.2476 2074.1851 238.24579 144.21181 2048.272 209.59233 145.1761 2017.537 176.11516 146.1403 1993.6379 149.47256 147.10451 1977.29 130.37952 148.0688 1969.5129 119.85545 149.033 1965.86 113.45418 149.99719 1963.197 108.0416 150.9615 1961.705 103.79797 151.9257 1961.728 101.06818 152.88989 1961.701 98.286781 153.8542 1962.1071 95.936661 154.81841 1962.8149 93.887115 155.78259 1964.333 92.646332 156.7469 1966.641 92.193741 157.71111 1969.556 92.347015 158.67529 1972.866 92.893646 159.6396 1976.2061 93.468704 160.60381 1979.568 94.064484 161.56799 1983.031 94.759903 162.5323 1986.5341 95.493637 163.49651 1990.296 96.485161 164.46069 1994.6169 98.03421 165.425 1998.941 99.584763 166.38921 2002.2321 100.10117 167.35339 2004.078 99.171143 168.3177 2003.694 96.009384 169.28191 2003.425 92.961693 170.24609 2003.29 90.046661 171.2104 2003.6689 87.643799 172.17461 2004.585 85.777054 173.13879 2006.196 84.60408 174.1031 2008.74 84.362328 175.06731 2012.123 84.958771 176.03149 2016.02 86.067757 176.9958 2019.985 87.243164 177.96001 2023.934 88.401611 178.92419 2027.998 89.673981 179.8885 2032.564 91.446564 180.85271 2038.113 94.20137 181.81689 2043.975 97.267876 182.7812 2047.9399 98.435776 183.74541 2049.3569 97.054855 184.70959 2046.634 91.532936 185.6739 2045.339 87.437241 186.63811 2046.162 85.458801 187.60229 2049.8501 86.344315 188.5666 2054.574 88.264091 189.53081 2058.0969 88.982101 190.495 2059.7781 87.857224 191.4593 2059.105 84.376648 192.42349 2059.2229 81.686264 193.3877 2060.7161 80.370087 194.35201 2064.2639 81.107101 195.31619 2068.3589 82.390488 196.2804 2072.248 83.467087 197.24471 2075.543 83.947952 198.20889 2078.186 83.776352 199.1731 2081.1951 83.969513 200.13741 2084.4529 84.410263 201.10159 2088.1631 85.302673 202.0658 2091.699 86.019699 203.03011 2095.145 86.645569 203.99429 2098.575 87.254799 204.9585 2101.4641 87.322189 205.92281 2103.043 86.077911 206.88699 2102.9089 83.120293 207.8512 2100.6731 78.059799 208.81551 2100.0161 74.576942 209.77969 2101.6909 73.425308 210.7439 2106.5049 75.411896 211.70821 2112.291 78.369492 212.67239 2117.5591 80.808472 213.6366 2121.5359 81.955276 214.60091 2124.0081 81.596222 215.56509 2126.5161 81.272591 216.5293 2129.26 81.183884 217.49361 2133.0029 82.093117 218.45779 2136.686 82.942017 219.422 2140.3491 83.770187 220.38631 2143.791 84.375961 221.35049 2147.5149 85.263275 222.3147 2152.3301 87.241142 223.27901 2158.2661 90.33873 224.24319 2165.5769 94.810776 225.2074 2172.593 98.98732 226.17171 2179.218 102.77165 227.13589 2185.677 106.38972 228.1001 2191.3979 109.26898 229.06441 2196.1909 111.21915 230.02859 2200.28 112.4653 230.9928 2203.717 113.05858 231.95711 2205.7661 112.26295 232.9213 2206.2471 109.89896 233.8855 2204.4939 105.30013 234.84979 2202.8491 100.80881 235.814 2201.5569 96.669708 236.7782 2200.3081 92.573456 237.74249 2199.5 88.917061 238.7067 2199.7319 86.300415 239.6709 2200.803 84.52227 240.63519 2202.447 83.31633 241.5994 2204.021 82.040047 242.5636 2205.3521 80.520378 243.52789 2207.3091 79.625847 244.4921 2209.199 78.663979 245.4563 2210.989 77.601746 246.42059 2212.4561 76.21582 247.3848 2213.467 74.373657 248.349 2215.1919 73.244873 249.31329 2217.1631 72.36174 250.2775 2220.519 72.86322 251.2417 2223.0979 72.587196 252.20599 2225.3359 71.969673 253.1702 2227.384 71.162018 254.1344 2229.417 70.338959 255.09869 2231.5 69.565292 256.0629 2233.447 68.655586 257.02719 2235.0869 67.43811 257.99139 2236.8279 66.321556 258.9556 2238.708 65.343987 259.91989 2240.7251 64.502762 260.88409 2243.0891 64.008499 261.8483 2245.856 63.916679 262.81259 2248.76 63.961582 263.77679 2251.7029 64.04538 264.741 2254.9241 64.407173 265.70529 2258.3521 64.975357 266.66949 2263.3689 67.132385 267.6337 2266.7949 67.698418 268.59799 2268.937 66.980011 269.56219 2268.8259 64.008545 270.5264 2268.4331 60.755199 271.49069 2269.0481 58.5093 272.4549 2270.7229 57.323242 273.4191 2273.375 57.114475 274.38339 2276.5969 57.475006 275.3476 2280.251 58.267899 276.3118 2285.478 60.633747 277.27609 2289.8469 62.14106 278.2403 2293.146 62.578747 279.2045 2294.019 60.590332 280.16879 2293.9719 57.681503 281.133 2295.3491 56.197227 282.0972 2298.5991 56.585754 283.06149 2304.98 60.104801 284.0257 2310.1101 62.373489 284.9899 2313.822 63.223938 285.95419 2315.2949 61.835117 286.9184 2316.4331 60.111919 287.8826 2317.938 58.755478 288.84689 2319.6111 57.567078 289.8111 2321.448 56.542862 290.7753 2323.876 56.109856 291.73959 2326.78 56.152657 292.7038 2331.5029 58.01482 293.668 2335.584 59.235249 294.63229 2339.438 60.228439 295.5965 2342.1411 60.071239 296.5607 2345.2371 60.30706 297.52499 2349.5649 61.774712 298.4892 2355.8879 65.237938 299.4534 2364.332 70.822479 300.41769 2371.219 74.849937 301.3819 2376.335 77.106827 302.3461 2378.5959 76.509048 303.31039 2380.0779 75.132156 304.2746 2381.0239 73.219963 305.2388 2380.583 69.921082 306.20309 2380.252 66.732101 307.1673 2381.644 65.266937 308.1315 2384.999 65.764908 309.09579 2390.3569 68.26593 310.06 2396.502 71.554703 311.0242 2402.9341 75.130913 311.98849 2409.012 78.353027 312.9527 2415.0659 81.551895 313.9169 2421.134 84.765274 314.8812 2426.521 87.297684 315.8454 2432.177 90.099907 316.8096 2439.9299 94.999435 317.7739 2450.0229 102.23927 318.7381 2462.251 111.6149 319.7023 2478.2771 124.78911 320.6666 2498.1101 141.77037 321.6308 2532.6499 173.45926 322.595 2563.0991 201.05807 323.5593 2583.1379 218.24677 324.5235 2588.7351 220.99464 325.4877 2581.897 211.30779 326.452 2571.2361 197.79851 327.4162 2556.9299 180.64482 328.3804 2533.511 154.37897 329.3447 2513.7161 131.73744 330.3089 2497.4729 112.64862 331.2731 2485.967 98.297699 332.2374 2477.4309 86.916985 333.2016 2471.1541 77.79641 334.1658 2467.9009 71.700256 335.1301 2467.6079 68.564697 336.0943 2468.1919 66.307106 337.0585 2469.4231 64.697456 338.0228 2470.7639 63.197891 338.987 2472.1689 61.763573 339.9512 2473.26 60.016048 340.9155 2474.832 58.74995 341.8797 2476.7661 57.847008 342.8439 2479.3469 57.591599 343.8082 2482.467 57.876045 344.7724 2485.792 58.366432 345.7366 2490.2219 59.962666 346.7009 2495.0071 61.91468 347.6651 2499.738 63.813629 348.6293 2505.499 66.743538 349.5936 2513.0349 71.448929 350.5578 2522.582 78.166733 351.522 2534.0549 86.811279 352.4863 2547.1819 97.110535 353.4505 2563.5591 110.66124 354.4147 2584.0129 128.28957 355.379 2601.23 142.68178 356.3432 2614.6289 153.25717 357.3074 2623.6799 159.48566 358.2717 2629.427 162.4109 359.2359 2631.843 162.00644 360.2001 2627.6321 154.97601 361.1644 2620.3799 144.90512 362.1286 2613.615 135.32291 363.0928 2607.532 126.42363 364.0571 2602.0791 118.1553 365.0213 2598.0049 111.26707 365.9855 2595.5649 106.01421 366.9498 2596.592 104.22922 367.914 2597.2339 102.06038 368.8782 2596.6819 98.698936 369.8425 2593.6819 92.890343 370.8067 2589.8069 86.208206 371.7709 2586.906 80.501404 372.7352 2586.0161 76.806534 373.6994 2587.594 75.580902 374.6636 2589.4419 74.626556 375.6279 2590.958 73.341415 376.5921 2589.2561 68.83976 377.5563 2589.0381 65.823296 378.5206 2591.075 65.062729 379.4848 2595.3301 66.522003 380.44901 2601.9231 70.320457 381.4133 2610.969 76.572891 382.3775 2621.408 84.219986 383.34171 2632.604 92.625519 384.306 2649.6331 106.86516 385.2702 2673.7671 128.21144 386.23441 2719.2241 170.88214 387.1987 2761.28 210.15283 388.1629 2795.5 241.58925 389.12711 2825.4709 268.77811 390.0914 2846.72 287.24622 391.0556 2855.02 292.76715 392.01981 2844.2581 279.22745 392.9841 2811.668 243.86086 393.9483 2779.1069 208.5251 394.91251 2750.6841 177.32904 395.8768 2726.604 150.47701 396.841 2705.6321 126.73497 397.80521 2687.458 105.79233 398.7695 2673.364 88.931023 399.7337 2662.4851 75.286667 400.69791 2654.249 64.286736 401.6622 2649.457 56.732224 402.6264 2648.364 52.878586 403.59061 2648.908 50.663532 404.5549 2650.2561 49.254066 405.5191 2652.396 48.638256 406.48331 2654.115 47.603207 407.4476 2655.0029 45.738529 408.4118 2654.083 42.067974 409.37601 2652.6411 37.877106 410.3403 2651.8091 34.297573 411.3045 2652.637 32.380001 412.26871 2655.2141 32.213371 413.233 2657.843 32.100048 414.1972 2660.0161 31.532915 415.16141 2661.4131 30.191463 416.1257 2662.385 28.426491 417.0899 2663.0281 26.334734 418.05411 2662.353 22.926674 419.0184 2662.084 19.926214 419.9826 2663.4221 18.535034 420.94681 2667.6709 20.056364 421.9111 2674.1899 23.849562 422.87531 2680.126 27.061909 423.83951 2684.1411 28.355263 424.8038 2685.3301 26.824089 425.76801 2685.793 24.569023 426.73221 2686.708 22.768051 427.6965 2687.929 21.274685 428.66071 2689.2759 19.909504 429.62491 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463.37311 2784.447 18.856007 464.3374 2788.99 20.768105 465.30161 2792.844 21.993919 466.26581 2795.5349 22.059113 467.2301 2796.741 20.641645 468.19431 2796.377 17.656836 469.15851 2793.738 12.399599 470.1228 2791.4299 7.4754314 471.08701 2791.199 4.6311817 472.05121 2794.2581 5.0794754 473.0155 2799.7251 7.9380245 473.97971 2805.8521 11.45927 474.94391 2811.3401 14.34416 475.9082 2815.6411 16.044378 476.87241 2819.146 16.951279 477.83661 2822.272 17.481865 478.8009 2825.8191 18.43594 479.76511 2828.7061 18.732731 480.72931 2830.3979 17.837101 481.6936 2830.3989 15.252926 482.65781 2829.8611 12.132849 483.62201 2830.03 9.7222176 484.5863 2831.6311 8.7461605 485.55051 2834.5381 9.0789413 486.51471 2837.9609 9.930294 487.479 2841.0811 10.481367 488.44321 2843.2151 10.049345 489.40741 2845.134 9.4049664 490.3717 2847.6699 9.3800411 491.33591 2851.9651 11.117397 492.30011 2856.7639 13.361174 493.2644 2861.0969 15.141689 494.22861 2864.208 15.703321 495.19281 2866.4861 15.434738 496.1571 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19.419184 1892.3669 2185.5649 19.698067 1893.332 2185.1311 21.300327 1894.296 2184.656 22.8578 1895.26 2181.8589 22.092033 1896.224 2178.1709 20.434177 1897.188 2176.5649 20.857124 1898.153 2178.0491 24.370983 1899.1169 2179.783 28.131306 1900.0811 2179.1289 29.502703 1901.045 2176.3721 28.769814 1902.01 2173.54 27.962528 1902.974 2171.4399 27.883865 1903.938 2169.8301 28.29418 1904.902 2168.3 28.783058 1905.8669 2166.8621 29.36475 1906.8311 2165.395 29.914324 1907.795 2163.6121 30.146442 1908.759 2161.469 30.017166 1909.724 2159.1311 29.693811 1910.688 2156.8889 29.462824 1911.652 2154.989 29.572821 1912.616 2153.019 29.611443 1913.58 2150.99 29.589672 1914.545 2148.791 29.398949 1915.509 2146.2891 28.901638 1916.473 2142.658 27.273851 1917.437 2138.5271 25.144978 1918.402 2135.5381 24.158642 1919.366 2134.616 25.235832 1920.33 2133.9871 26.604893 1921.2939 2132.8269 27.441353 1922.259 2130.7959 27.407879 1923.223 2128.9341 27.539965 1924.187 2126.948 27.546417 1925.151 2124.7041 27.29369 1926.115 2122.2791 26.858435 1927.08 2119.345 25.914783 1928.0439 2117.009 25.56588 1929.0081 2116.4041 26.946796 1929.972 2119.5259 32.052876 1930.937 2121.384 35.895897 1931.901 2120.7329 37.226231 1932.865 2117.1609 35.634258 1933.829 2113.157 33.608994 1934.7939 2108.678 31.109219 1935.7581 2104.4231 28.830391 1936.722 2101.335 27.716639 1937.686 2100.0769 28.431536 1938.651 2098.9751 29.303247 1939.615 2097.0491 29.347305 1940.579 2093.845 28.111847 1941.543 2091.4561 27.690126 1942.507 2090.938 29.137806 1943.472 2091.6819 31.848232 1944.436 2091.439 33.568142 1945.4 2089.145 33.235565 1946.364 2086.0979 32.148346 1947.329 2083.4641 31.474968 1948.293 2081.002 30.969761 1949.257 2079.144 31.06732 1950.2209 2078.156 32.033268 1951.186 2077.8899 33.721874 1952.15 2076.646 34.428978 1953.114 2073.6641 33.396549 1954.078 2070.0649 31.745428 1955.042 2067.1189 30.745878 1956.007 2065.3721 30.946007 1956.9709 2064.3411 31.858469 1957.9351 2063.7739 33.233528 1958.899 2063.3279 34.727909 1959.864 2062.3811 35.721996 1960.828 2060.575 35.853214 1961.792 2058.1389 35.353012 1962.756 2055.6499 34.798294 1963.7209 2053.981 35.064056 1964.6851 2052.489 35.503559 1965.649 2050.21 35.15416 1966.613 2046.5439 33.416237 1967.578 2043.084 31.884766 1968.542 2040.972 31.697798 1969.506 2040.015 32.664173 1970.47 2039.229 33.799995 1971.434 2038.608 35.099281 1972.399 2038.1021 36.514164 1973.363 2037.504 37.833237 1974.327 2036.666 38.910732 1975.291 2035.321 39.479683 1976.256 2033.0291 39.101948 1977.22 2029.899 37.882668 1978.184 2027.093 36.98576 1979.1479 2025.816 37.616295 1980.113 2025.62 39.328327 1981.077 2024.192 39.804642 1982.041 2020.291 37.806313 1983.005 2015.868 35.284389 1983.969 2014.176 35.491802 1984.934 2015.876 39.091473 1985.8979 2017.434 42.545624 1986.8621 2016.475 43.481407 1987.826 2012.827 41.726349 1988.791 2009.538 40.330448 1989.755 2007.132 39.814041 1990.719 2005.295 39.865074 1991.683 2003.024 39.48037 1992.6479 1999.978 38.320896 1993.6121 1997.254 37.48011 1994.576 1995.771 37.878384 1995.54 1996.042 40.029022 1996.505 1995.071 40.937946 1997.469 1992.2209 39.964142 1998.433 1988.036 37.653816 1999.397 1984.767 36.257706 2000.361 1982.813 36.174973 2001.326 1981.532 36.765652 2002.29 1980.257 37.35849 2003.254 1978.285 37.252735 2004.218 1977.187 38.01918 2005.183 1977.788 40.484783 2006.147 1980.109 44.666885 2007.111 1980.511 46.928211 2008.075 1976.9 45.174885 2009.04 1972.104 42.236897 2010.004 1968.5389 40.526031 2010.968 1968.5959 42.435516 2011.932 1968.384 44.074352 2012.896 1967.803 45.342316 2013.861 1966.629 46.017525 2014.825 1964.937 46.171062 2015.7889 1961.416 44.493881 2016.7531 1957.354 42.27417 2017.718 1954.285 41.04739 2018.682 1954.101 42.701885 2019.646 1953.651 44.08876 2020.61 1952.094 44.366825 2021.575 1949.54 43.648037 2022.5389 1947.793 43.732521 2023.5031 1947.787 45.556557 2024.467 1948.226 47.823544 2025.432 1947.417 48.842682 2026.396 1944.033 47.283127 2027.36 1940.467 45.539909 2028.324 1938.005 44.898796 2029.288 1936.868 45.580971 2030.2531 1936.155 46.687386 2031.217 1935.292 47.639915 2032.181 1933.969 48.130692 2033.145 1931.9399 47.913624 2034.11 1928.976 46.761654 2035.074 1926.089 45.683075 2036.038 1924.123 45.52372 2037.002 1923.292 46.497444 2037.967 1923.009 48.019508 2038.931 1922.807 49.618641 2039.895 1922.3199 50.930927 2040.859 1921.139 51.54755 2041.823 1919.119 51.323242 2042.788 1916.762 50.76189 2043.752 1914.7419 50.533936 2044.7159 1913.327 50.909256 2045.6801 1911.922 51.292862 2046.645 1909.623 50.782295 2047.609 1906.635 49.578995 2048.573 1904.233 48.959919 2049.5371 1902.902 49.410149 2050.501 1901.881 50.168144 2051.4661 1900.291 50.357574 2052.4299 1898.149 49.990906 2053.394 1896.0229 49.638702 2054.3579 1894.198 49.58535 2055.323 1892.667 49.826321 2056.2871 1891.306 50.233688 2057.251 1890.13 50.823681 2058.2151 1888.995 51.453274 2059.1799 1887.549 51.771305 2060.144 1885.589 51.572212 2061.1079 1883.974 51.715771 2062.072 1883.765 53.263908 2063.0371 1885.313 56.568909 2064.001 1885.025 58.033867 2064.9651 1881.799 56.55928 2065.929 1876.993 53.502537 2066.894 1873.719 51.977978 2067.8579 1872.976 52.980324 2068.822 1872.54 54.288353 2069.7859 1871.7729 55.262875 2070.75 1870.564 55.794044 2071.7151 1868.323 55.293098 2072.679 1864.057 52.763023 2073.6431 1858.9919 49.432419 2074.6069 1855.631 47.803574 2075.572 1855.217 49.12204 2076.5359 1855.5551 51.188354 2077.5 1855.6899 53.050072 2078.4641 1855.292 54.377045 2079.429 1854.42 55.229408 2080.3931 1852.489 55.019466 2081.3569 1850.016 54.265182 2082.321 1847.886 53.852425 2083.2859 1847.266 54.949059 2084.25 1846.3149 55.711411 2085.2141 1844.776 55.883949 2086.178 1842.7469 55.564011 2087.1431 1841.465 55.991371 2088.1069 1841.36 57.591644 2089.071 1841.376 59.311386 2090.0349 1840.251 59.887768 2091 1836.781 58.119392 2091.9641 1833.511 56.54731 2092.928 1831.538 56.269848 2093.8921 1831.02 57.445953 2094.856 1831.1169 59.23455 2095.821 1831.433 61.242455 2096.7849 1831.21 62.707211 2097.749 1829.58 62.763458 2098.7129 1826.562 61.42939 2099.678 1823.304 59.855377 2100.6421 1820.677 58.908813 2101.606 1818.834 58.743801 2102.5701 1817.416 59.002304 2103.5349 1816.191 59.453106 2104.499 1814.738 59.672646 2105.4629 1812.814 59.418728 2106.427 1810.509 58.782406 2107.3921 1808.1281 58.069756 2108.355 1805.254 56.858295 2109.3201 1802.194 55.462624 2110.2839 1800.203 55.131958 2111.249 1801.302 57.891388 2112.2119 1802.822 61.066086 2113.177 1802.02 61.920555 2114.1411 1798.489 60.042366 2115.105 1794.442 57.645786 2116.0691 1791.028 55.880577 2117.0339 1788.304 54.804695 2117.998 1786.424 54.569572 2118.9619 1786.23 56.018082 2119.926 1786.699 58.127979 2120.8911 1786.387 59.456543 2121.855 1785.009 59.715118 2122.8191 1783.5811 59.922073 2123.783 1782.782 60.755524 2124.748 1782.442 62.048149 2125.7119 1781.538 62.772629 2126.676 1779.933 62.79459 2127.6399 1778.041 62.527157 2128.604 1776.4561 62.56514 2129.5691 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