#------------------------------------------------------------------------------
#$Date: 2019-06-12 16:31:35 +0300 (Wed, 12 Jun 2019) $
#$Revision: 1351 $
#$URL: svn://172.16.1.111/rod/cif/3/50/02/3500283.rod $
#------------------------------------------------------------------------------
#
# This file is available in the Raman Open Database (ROD),
# http://solsa.crystallography.net/rod/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3500283
loop_
_publ_author_name
'Kumar, A.'
'Zanatta, M.'
'Bersani, D'
'Daldosso, N.'
'Mariotto, G.'
_publ_section_title
;
 Raman spectrum of Fe3O4
;
_journal_name_full               'Personal communication to ROD'
_journal_year                    2019
_chemical_compound_source        natural
_chemical_formula_sum            'Fe3 O4'
_space_group_IT_number           216
_symmetry_space_group_name_Hall  'F -4 2 3'
_symmetry_space_group_name_H-M   'F -4 3 m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   8.3941
_cell_length_b                   8.3941
_cell_length_c                   8.3941
_cell_volume                     591.456
_cod_original_formula_sum        O4Fe3
_raman_determination_method      experimental
_[local]_chemical_compound_color white
_[local]_chemical_compound_state Solid
_raman_measurement_device.location 'University of Verona'
_raman_measurement_device.company
'Thermo Scientific_raman_measurement_device.model DXR2'
_raman_measurement_device.optics_type microscope
_raman_measurement_device.microscope_system dispersive
_raman_measurement_device.microscope_objective_magnification 50
_raman_measurement_device.microscope_numerical_aperture 0.50
_raman_measurement_device.excitation_laser_type helium-neon
_raman_measurement_device.excitation_laser_wavelength 633
_raman_measurement_device.configuration simple
_raman_measurement_device.resolution 1
_raman_measurement_device.power_on_sample 8
_raman_measurement_device.direction_polarization unoriented
_raman_measurement_device.spot_size 1.5
_raman_measurement.environment   Air
_raman_measurement.environment_details
;
 The sample was measured in air.
;
_raman_measurement.temperature   300
_raman_measurement.pressure      100
_raman_measurement.background_subtraction no
_raman_measurement.background_subtraction_details
;
 No background subtraction method was applied.
;
_raman_measurement.baseline_correction no
_raman_measurement.baseline_correction_details
;
 No baseline correction method was applied.
;
_raman_measurement.integration_time 30
_raman_measurement.datetime_initiated 2019-04-19
_rod_data_source.file            Fe3O4.txt
_rod_data_source.block
/var/www/html/rod/tmp/uploads/1560346129.0959-06A4055A28351D0A.rod
_rod_database.code               3500283
loop_
_raman_complementary.id
_raman_complementary.method
1 EDX
loop_
_raman_measurement_device_calibration.id
_raman_measurement_device_calibration.standard
1 silicon_wafer
loop_
_rod_related_entry.id
_rod_related_entry.code
_rod_related_entry.database
_rod_related_entry.uri
_rod_related_entry.description
1 1539747 COD http://www.crystallography.net/cod/1539747.html
;
no XRD analysis data.
;
loop_
_raman_spectrum.raman_shift
_raman_spectrum.raw_intensity
_raman_spectrum.intensity
50.68116 95.277412 10.843681
51.64539 95.194206 10.824753
52.609619 95.10553 10.800327
53.57386 94.982063 10.741086
54.53809 94.729683 10.55291
55.502319 94.37059 10.257994
56.46656 94.211647 10.163208
57.43079 94.376167 10.391859
58.395031 94.805923 10.885729
59.359261 95.063469 11.207363
60.32349 94.936058 11.144024
61.287731 94.34082 10.612835
62.251961 93.411926 9.7479706
63.21619 92.632668 9.0327253
64.180428 92.045113 8.5091591
65.144661 91.642281 8.1703081
66.108887 91.376961 7.9689412
67.073128 91.272469 7.9283957
68.037361 91.345993 8.0658493
69.001587 91.523041 8.3068056
69.965828 91.639397 8.4870567
70.930061 91.6912 8.6027441
71.894287 91.662979 8.6383944
72.858528 91.519333 8.5586052
73.822762 91.218018 8.3211355
74.786987 90.742989 7.9099388
75.751228 90.186996 7.4177713
76.715462 89.692177 6.9867649
77.679703 89.267441 6.6258259
78.643929 88.922668 6.3448462
79.608162 88.661293 6.1472492
80.572403 88.533241 6.0829744
81.536629 88.571533 6.1850309
82.50087 88.649521 6.3267784
83.465103 88.595306 6.3363156
84.429337 88.331093 6.1358457
85.39357 87.788399 5.6568918
86.357803 87.49192 5.4241476
87.322037 87.497093 5.4930525
88.28627 87.853287 5.9129667
89.250504 88.283081 6.4064817
90.214737 88.602982 6.7901001
91.17897 88.834381 7.0852122
92.143204 88.973877 7.2884197
93.107437 88.911507 7.2897573
94.071671 88.535912 6.9778709
95.035896 87.826973 6.3326435
96.000137 87.133926 5.7033005
96.964371 86.642891 5.2759733
97.928596 86.384644 5.0814276
98.892838 86.326767 5.0872593
99.857071 86.273376 5.0975795
100.8213 86.201347 5.0892611
101.7855 86.12603 5.0776539
102.7498 86.054367 5.0697112
103.714 86.010773 5.0898333
104.6782 86.011162 5.1539388
105.6425 86.046333 5.2528424
106.6067 86.083794 5.3540297
107.5709 86.131058 5.4650264
108.5352 86.192253 5.5899639
109.4994 86.118347 5.5798016
110.4636 85.836739 5.3619442
111.4279 85.301331 4.8902941
112.3921 84.662308 4.315033
113.3563 84.18512 3.9016161
114.3206 83.91333 3.69361
115.2848 83.90284 3.7469046
116.249 83.887894 3.7957513
117.2133 83.873421 3.8450847
118.1775 83.871361 3.9068346
119.1417 83.850304 3.9496002
120.106 83.77449 3.9376247
121.0702 83.635262 3.8622351
122.0344 83.420647 3.7114701
122.9987 83.255592 3.6102853
123.9629 83.128639 3.5472052
124.9271 83.034286 3.5167375
125.8914 82.95594 3.5022931
126.8556 82.89505 3.5053139
127.8198 82.869164 3.5433514
128.7841 82.879967 3.6180964
129.74831 82.83181 3.6338866
130.71249 82.701698 3.5677373
131.6768 82.481987 3.4120097
132.64101 82.290939 3.2849541
133.6053 82.153671 3.2116985
134.5695 82.059357 3.1814024
135.53371 81.992409 3.1784909
136.498 81.939621 3.1897604
137.4622 81.923622 3.2378302
138.42641 82.002731 3.3810265
139.3907 81.986053 3.4284534
140.3549 81.834099 3.3406162
141.31911 81.497231 3.0678844
142.2834 81.099533 2.7343457
143.2476 80.844139 2.543124
144.21181 80.76857 2.5317433
145.1761 80.950867 2.7782545
146.1403 81.026627 2.9182398
147.10451 80.993347 2.9492061
148.0688 80.820793 2.8409207
149.033 80.578133 2.662544
149.99719 80.300873 2.4495888
150.9615 79.959846 2.1728942
151.9257 79.556137 1.8335285
152.88989 79.263527 1.6052794
153.8542 79.151207 1.5573554
154.81841 79.254471 1.7250242
155.78259 79.382942 1.917922
156.7469 79.446098 2.0455356
157.71111 79.397003 2.0609145
158.67529 79.263641 1.9920449
159.6396 79.223877 2.0168037
160.60381 79.333214 2.190681
161.56799 79.684357 2.6063864
162.5323 79.929672 2.9162908
163.49651 80.00071 3.051939
164.46069 79.827431 2.9432893
165.425 79.554832 2.7353535
166.38921 79.433403 2.6786051
167.35339 79.516373 2.8262777
168.3177 79.904617 3.2792585
169.28191 80.113571 3.5529668
170.24609 80.094872 3.5990438
171.2104 79.765846 3.3348274
172.17461 79.415291 3.0491035
173.13879 79.268089 2.9667513
174.1031 79.397072 3.1606226
175.06731 79.816513 3.6449711
176.03149 80.134033 4.02742
176.9958 80.272476 4.2308264
177.96001 80.173607 4.1969433
178.92419 80.091507 4.1798539
179.8885 80.094543 4.2479353
180.85271 80.18969 4.4081478
181.81689 80.363892 4.6474409
182.7812 80.586227 4.9349008
183.74541 80.87072 5.284543
184.70959 81.29731 5.7763066
185.6739 81.665749 6.2099543
186.63811 81.997139 6.6065755
187.60229 82.309502 6.9841957
188.5666 82.557533 7.2975235
189.53081 82.680763 7.4860663
190.495 82.650108 7.5207548
191.4593 82.439613 7.3756399
192.42349 82.196297 7.1977243
193.3877 81.957253 7.0241132
194.35201 81.770958 6.9032879
195.31619 81.524071 6.7218866
196.2804 81.154846 6.4181824
197.24471 80.620354 5.9492493
198.20889 79.928871 5.3233418
199.1731 79.242813 4.7028923
200.13741 78.522797 4.0485215
201.10159 77.680183 3.2715771
202.0658 76.982361 2.6394553
203.03011 76.477341 2.2001719
203.99429 76.229103 2.0176964
204.9585 76.11937 1.9737525
205.92281 75.969177 1.8893876
206.88699 75.779587 1.7656493
207.8512 75.572144 1.6240911
208.81551 75.33831 1.4561796
209.77969 75.09005 1.2738643
210.7439 74.783539 1.0333328
211.70821 74.510162 0.8259716
212.67239 74.306213 0.68806267
213.6366 74.164207 0.61212873
214.60091 74.075043 0.58907461
215.56509 74.005371 0.58553839
216.5293 73.964302 0.61063719
217.49361 73.979118 0.69165945
218.45779 74.008247 0.78701878
219.422 74.05687 0.90190506
220.38631 74.132408 1.0437465
221.35049 74.232361 1.2100258
222.3147 74.348923 1.3929496
223.27901 74.48307 1.5934963
224.24319 74.643913 1.8207636
225.2074 74.769333 2.0126414
226.17171 74.852867 2.1626742
227.13589 74.877113 2.2534416
228.1001 74.874763 2.3176475
229.06441 74.857178 2.3666587
230.02859 74.7957 2.3718011
230.9928 74.69194 2.3346961
231.95711 74.687843 2.3972943
232.9213 74.819397 2.5955665
233.8855 75.234177 3.0771008
234.84979 75.588127 3.4978435
235.814 75.844681 3.821218
236.7782 75.945808 3.9891977
237.74249 75.968727 4.0790091
238.7067 76.039337 4.2165389
239.6709 76.160027 4.4041805
240.63519 76.346687 4.6578355
241.5994 76.489639 4.8678064
242.5636 76.574966 5.0201864
243.52789 76.568222 5.0805345
244.4921 76.575058 5.1544895
245.4563 76.654297 5.3008823
246.42059 76.835693 5.5494719
247.3848 77.1054 5.8863993
248.349 77.362457 6.21071
249.31329 77.583252 6.4987979
250.2775 77.746658 6.7295251
251.2417 77.910271 6.9604926
252.20599 78.102913 7.2205286
253.1702 78.404663 7.5897012
254.1344 78.716179 7.9686708
255.09869 78.910629 8.2306166
256.0629 78.91626 8.303771
257.02719 78.611908 8.0669804
257.99139 78.485809 8.0084715
258.9556 78.561447 8.1517315
259.91989 78.96611 8.6240597
260.88409 79.428253 9.1538906
261.8483 79.880302 9.6736631
262.81259 80.334389 10.195515
263.77679 80.773087 10.702002
264.741 81.142021 11.138761
265.70529 81.403709 11.468315
266.66949 81.338257 11.470752
267.6337 81.473183 11.673603
268.59799 81.820969 12.089354
269.56219 82.590843 12.92722
270.5264 83.476227 13.880627
271.49069 84.271019 14.743483
272.4549 84.945602 15.486161
273.4191 85.47934 16.08802
274.38339 86.013519 16.690365
275.3476 86.535133 17.280172
276.3118 86.947021 17.760284
277.27609 87.431503 18.31303
278.2403 88.011063 18.96088
279.2045 88.816902 19.835045
280.16879 89.710892 20.797394
281.133 90.469116 21.624008
282.0972 91.027046 22.250362
283.06149 91.196777 22.488556
284.0257 91.539787 22.900051
284.9899 92.055687 23.484474
285.95419 92.985657 24.483006
286.9184 93.918533 25.484463
287.8826 94.742477 26.377029
288.84689 95.363838 27.067047
289.8111 95.824417 27.59631
290.7753 96.361504 28.202114
291.73959 96.980026 28.889389
292.7038 97.841042 29.819187
293.668 98.61422 30.661175
294.63229 99.320213 31.436024
295.5965 100.0108 32.195492
296.5607 100.6262 32.879795
297.52499 101.1277 33.450245
298.4892 101.4979 33.88942
299.4534 101.7261 34.186619
300.41769 101.8507 34.380268
301.3819 101.8626 34.461239
302.3461 101.6696 34.337334
303.31039 101.4434 34.180271
304.2746 101.1986 34.004631
305.2388 100.9566 33.831825
306.20309 100.7146 33.659058
307.1673 100.4652 33.47892
308.1315 100.2201 33.303104
309.09579 99.985283 33.137611
310.06 99.690773 32.912449
311.0242 99.303047 32.594101
311.98849 98.86351 32.223984
312.9527 98.289352 31.719265
313.9169 97.569237 31.068619
314.8812 96.581238 30.150131
315.8454 95.445908 29.084332
316.8096 94.395592 28.103577
317.7739 93.455872 27.233459
318.7381 92.651253 26.498463
319.7023 91.955009 25.871868
320.6666 91.365517 25.352066
321.6308 91.09066 25.146919
322.595 90.746063 24.872063
323.5593 90.196678 24.392456
324.5235 89.249496 23.515072
325.4877 88.005173 22.34058
326.452 86.903053 21.308323
327.4162 86.001747 20.476906
328.3804 85.473541 20.018612
329.3447 84.959343 19.574366
330.3089 84.433098 19.118092
331.2731 83.886192 18.64119
332.2374 83.329811 18.154842
333.2016 82.774101 17.669193
334.1658 82.215431 17.180609
335.1301 81.656113 16.69141
336.0943 81.119911 16.225349
337.0585 80.604279 15.779887
338.0228 80.093597 15.33941
338.987 79.581383 14.89742
339.9512 79.056908 14.443196
340.9155 78.509987 13.966562
341.8797 77.985359 13.512239
342.8439 77.525253 13.122467
343.8082 77.13945 12.80703
344.7724 76.818626 12.556593
345.7366 76.55246 12.36084
346.7009 76.316933 12.195759
347.6651 76.258293 12.207584
348.6293 76.119987 12.139771
349.5936 75.908447 11.998754
350.5578 75.504799 11.665648
351.522 75.060211 11.291631
352.4863 74.691368 10.993387
353.4505 74.465446 10.838087
354.4147 74.410782 10.854067
355.379 74.287567 10.801529
356.3432 74.076447 10.661102
357.3074 73.555832 10.211207
358.2717 73.121628 9.8477535
359.2359 72.809822 9.6067171
360.2001 72.72023 9.5879192
361.1644 72.732826 9.671339
362.1286 72.730087 9.7394419
363.0928 72.677147 9.7573652
364.0571 72.562393 9.7135067
365.0213 72.467216 9.6892414
365.9855 72.406067 9.699028
366.9498 72.49041 9.8543358
367.914 72.508301 9.9432087
368.8782 72.423576 9.9294872
369.8425 72.114967 9.6919127
370.8067 71.721497 9.3694925
371.7709 71.397659 9.1167269
372.7352 71.197304 8.9874706
373.6994 71.142273 9.0035572
374.6636 71.121849 9.0542717
375.6279 71.112823 9.1164103
376.5921 71.20079 9.2755594
377.5563 71.233231 9.3792019
378.5206 71.189682 9.4068832
379.4848 70.946373 9.2348175
380.44901 70.637421 8.9971323
381.4133 70.407753 8.8387556
382.3775 70.322678 8.8249865
383.34171 70.416946 8.9905815
384.306 70.530518 9.1755066
385.2702 70.642311 9.3586664
386.23441 70.724373 9.5121145
387.1987 70.800323 9.6594782
388.1629 70.859467 9.7900467
389.12711 70.94902 9.9510431
390.0914 71.02124 10.094734
391.0556 71.034203 10.179178
392.01981 70.939049 10.155524
392.9841 70.714104 10.002106
393.9483 70.555588 9.9151278
394.91251 70.496567 9.9276619
395.8768 70.677933 10.180607
396.841 70.834442 10.408709
397.80521 70.919441 10.565316
398.7695 70.895309 10.612817
399.7337 70.817574 10.606724
400.69791 70.742561 10.603372
401.6622 70.670509 10.603002
402.6264 70.599442 10.603628
403.59061 70.593353 10.66925
404.5549 70.663132 10.81076
405.5191 70.940353 11.159722
406.48331 71.160088 11.451215
407.4476 71.269577 11.632483
408.4118 71.128616 11.563312
409.37601 70.908737 11.415236
410.3403 70.746628 11.324951
411.3045 70.725601 11.375755
412.26871 70.846092 11.568096
413.233 70.974892 11.768763
414.1972 71.080482 11.94623
415.16141 71.203339 12.140976
416.1257 71.254547 12.264095
417.0899 71.219254 12.300718
418.05411 70.91906 12.072456
419.0184 70.600487 11.825833
419.9826 70.42334 11.720643
420.94681 70.549042 11.918315
421.9111 70.925598 12.366859
422.87531 71.253922 12.767178
423.83951 71.412468 12.997729
424.8038 71.279068 12.936355
425.76801 71.118896 12.848213
426.73221 71.029083 12.830441
427.6965 71.029449 12.902868
428.66071 71.078133 13.023613
429.62491 71.145126 13.162682
430.5892 71.293167 13.382814
431.55341 71.49543 13.657173
432.51761 71.656212 13.890061
433.4819 71.733101 14.039072
434.44611 71.663033 14.041129
435.41031 71.58474 14.034971
436.3746 71.518867 14.041251
437.33881 71.410347 14.004883
438.30301 71.316071 13.982769
439.2673 71.273407 14.012283
440.23151 71.40506 14.216116
441.19571 71.631279 14.514524
442.16 71.81147 14.766916
443.12421 71.856697 14.884347
444.0885 71.723793 14.823661
445.0527 71.559357 14.731442
446.01691 71.412773 14.657085
446.9812 71.320198 14.636749
447.9454 71.238708 14.6275
448.90961 71.168709 14.629745
449.8739 71.106499 14.639795
450.8381 71.05896 14.664514
451.80231 71.026207 14.704025
452.7666 70.989937 14.740032
453.7308 70.950882 14.773252
454.69501 70.957077 14.851728
455.6593 71.054527 15.021469
456.6235 71.388863 15.428096
457.58771 71.671753 15.78328
458.552 71.765312 15.949145
459.5162 71.441139 15.697274
460.48041 70.998718 15.32716
461.4447 70.673172 15.073931
462.40891 70.614403 15.087473
463.37311 70.786057 15.331445
464.3374 71.026642 15.644357
465.30161 71.260681 15.950718
466.26581 71.49649 16.25885
467.2301 71.676964 16.511658
468.19431 71.769043 16.676067
469.15851 71.71331 16.692663
470.1228 71.638733 16.690424
471.08701 71.623421 16.747444
472.05121 71.702507 16.898865
473.0155 71.855637 17.124338
473.97971 72.04171 17.382746
474.94391 72.214157 17.627529
475.9082 72.350067 17.835783
476.87241 72.508293 18.066345
477.83661 72.735474 18.36586
478.8009 73.18634 18.889069
479.76511 73.628609 19.403671
480.72931 73.937767 19.785164
481.6936 73.967339 19.887074
482.65781 73.887497 19.879562
483.62201 73.874237 19.938633
484.5863 74.064651 20.20138
485.55051 74.437157 20.64621
486.51471 74.824539 21.105915
487.479 75.088577 21.442278
488.44321 75.109787 21.535805
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1930.937 12.51796 4.8807735
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1932.865 12.44804 4.8199739
1933.829 12.37713 4.7536464
1934.7939 12.2973 4.6784201
1935.7581 12.2279 4.6136332
1936.722 12.20172 4.592083
1937.686 12.27293 4.6679373
1938.651 12.34263 4.7423015
1939.615 12.37434 4.7786865
1940.579 12.37326 4.7822967
1941.543 12.33419 4.7479339
1942.507 12.2261 4.6445656
1943.472 12.06995 4.4931583
1944.436 11.95394 4.3819022
1945.4 11.89521 4.3279409
1946.364 11.88009 4.3176055
1947.329 11.90627 4.3485913
1948.293 12.03222 4.4793577
1949.257 12.12429 4.5762606
1950.2209 12.12663 4.5834484
1951.186 12.04272 4.5044084
1952.15 11.98577 4.4523392
1953.114 12.01392 4.4853854
1954.078 12.08267 4.5590482
1955.042 12.13857 4.6198764
1956.007 12.18646 4.6727161
1956.9709 12.20565 4.6968679
1957.9351 12.15998 4.6561747
1958.899 12.03195 4.5331388
1959.864 11.9506 4.4568033
1960.828 12.02592 4.5371494
1961.792 12.19141 4.7076826
1962.756 12.30392 4.8252511
1963.7209 12.27315 4.799562
1964.6851 12.19697 4.7284741
1965.649 12.1485 4.685113
1966.613 12.12894 4.6706772
1967.578 12.12797 4.6748538
1968.542 12.16157 4.7136116
1969.506 12.21836 4.7755766
1970.47 12.24261 4.8050184
1971.434 12.16254 4.7301569
1972.399 12.04595 4.6187968
1973.363 12.01903 4.5971184
1974.327 12.13146 4.714807
1975.291 12.24089 4.8295112
1976.256 12.18019 4.7741094
1977.22 11.95096 4.5501881
1978.184 11.76585 4.3704038
1979.1479 11.76605 4.3759465
1980.113 11.91455 4.5298119
1981.077 12.0244 4.6450381
1982.041 12.0845 4.7105322
1983.005 12.10781 4.7392526
1983.969 12.10289 4.7397604
1984.934 12.06421 4.7065306
1985.8979 12.02762 4.6754026
1986.8621 12.02116 4.6744223
1987.826 12.0469 4.705658
1988.791 12.05444 4.7187166
1989.755 12.04358 4.7133875
1990.719 12.01429 4.6896448
1991.683 11.95617 4.6370897
1992.6479 11.84791 4.5344176
1993.6121 11.75438 4.4464884
1994.576 11.72733 4.425055
1995.54 11.7931 4.496459
1996.505 11.84065 4.5496655
1997.469 11.85414 4.5688252
1998.433 11.84215 4.562521
1999.397 11.84973 4.5758042
2000.361 11.89693 4.6287255
2001.326 11.94451 4.6820517
2002.29 11.96077 4.7040663
2003.254 11.92399 4.6730604
2004.218 11.88495 4.639811
2005.183 11.84514 4.6058159
2006.147 11.8044 4.5709023
2007.111 11.77185 4.5441952
2008.075 11.75119 4.5293965
2009.04 11.73506 4.5191517
2010.004 11.71712 4.5071087
2010.968 11.68686 4.4827623
2011.932 11.67227 4.4741035
2012.896 11.68478 4.4925632
2013.861 11.72547 4.5392256
2014.825 11.75334 4.5730801
2015.7889 11.77079 4.5965328
2016.7531 11.76784 4.5996037
2017.718 11.73591 4.5737176
2018.682 11.62757 4.4714327
2019.646 11.53663 4.3865652
2020.61 11.48065 4.3366766
2021.575 11.46113 4.3232718
2022.5389 11.47214 4.3404083
2023.5031 11.54376 4.4181733
2024.467 11.63374 4.5143151
2025.432 11.69088 4.5776405
2026.396 11.67097 4.5639286
2027.36 11.64633 4.5455036
2028.324 11.65353 4.5589371
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